Table Of Content

Chemistry Journal of Organometallic Chemistry 590 (1999) 267 Author Index of Volume 590 Al-Allaf, T.A.K., 25 Howard, J.A.K., 169, 180 Otsa, E., 149 Alder, M.J., 123 Hrnéiar, P., 261 Ozkar, S., 208 Ang, H.G., | Huang, X., 234 Ang, S.G., | Huang, X.-Y., 242 Pallin, V., 149 Hughes, A.K., 169 Pan, Y., 242 Baker, P.K., 77 Hu, H., 242 Pastor, A., 202 Batsanov, A.S., 169, 180 Pedersen, B., 129 Beckert, R., 104 Imhof, W., 104 Pelter, A., 227 Biesemans, M., 88 Itoh, M., 36 Perjéssy, A., 261 Billert, T., 104 Iwata, K., 36 Petrova, L.A., 222 Binfeng, L., 234 Pritchard, R.G., 123 Borisov, A.P., 222 Jiang, C., 138 Brauchle, C., 129 Jin, X.-P., 242 Rademacher, P., 227 Bridgewater, B.M., 169 Johans, A.W., 77 Raubenheimer, H.G., 158 Bruce, M.I., 184 Jong, S.-J., 42 Rickard, C.E.F., 52 Bryce, M.R., 180 Roberts, R.M.G., 71 Bubnov, Y.N., 227 Kawachi, A., 15 Kehr, G., 93 Salteris, C.S., 63 Collin, J., 248 Kelly, B.D., 184 Santes, V., 237 Cronje, S., 158 Ke, M., 184 Santos, I., 248 Cross, W.I., 123 Kemmer, M., 88 Scherer, W., 129 Czap, N., 7 Kinart, C.M., 258 Schmailzlin, E., 129 Kinart, W.J., 258 Schneider, J.J., 7 Dash, A.K., 46 Kobayashi, M., 36 Screttas, C.G., 63 Davies, D.A., 71 Kolehmainen, E., 261 Shen, Y.-Z., 242 Deetlefs, M., 158 Kostas, I.D., 63 Silver, J., 71 de la Luz, V., 237 Kruger, G.J., 158 Skelton, B.W., 184 Demuth, W., 153 Kumar Dey, D., 88 Smith, M.E., 184 Domingos, A., 248 Kumar Saha, M., 88 Solan, G.A., 115 Dong, G., 242 Spickermann, D., 7 Dorfler, U., 71 Laschi, F., 7 Stander, Y., 158 Drew, M.G.B., 77 Latif, L.A., 77 Steele, B.R., 63 Du, S., 1 Lehmann, C.W., 7 Stichbury, J.C., 115 Lin, C.-H., 42 Stolarzewicz, A., 153 Fang, J.-M., 42 Liu, L.-K., 138 Farfan, N., 237 Liu, Y.-Y., 46 Tamao, K., 15 Flower, K.R., 123 Long, N.J., 115 Tanaka, Y., 15 Fontani, M., 7 Loos, D., 261 Tekkaya, A., 208 Low, P.J., 184 Terzis, A., 63 Galindo, A., 202 Lu, T.-H., 46 Thompson, C., 158 Gibson, V.C., 115 Tung, S.-F., 46 Gielen, M., 88 Mackie, S.C., 253 Tuulmets, A., 149 Giuseppone, N., 248 MacLaren, D.C., 253 Tylak, I., 258 Gobel, A., 104 Maercker, A., 153 Gomez, E., 237 Makhaev, V.D., 222 Wagner, G., 129 Gorls, H., 104 Marais, E.K., 158 Wang, L.-Y., 242 Gramlich, V., 88 Martin, J., 115 Wen, Y.-S., 138 Green, A., 180 Mathieu, R., 119 White, A.H., 184 Gridnev, I.D., 227 Mathur, P., 46 Willbold, S., 93 Grobelny, Z., 153 Ma, Y., 234 Willem, R., 88 Gurskii, M.E., 227 Maynard, N.P., 52 Wilson, C., 169 Meehan, M.M., 77 Woodgate, P.D., 52 Haas, U., 77 Meerholz, K., 129 Wrackmeyer, B., 71, 93 Herberhold, M., 71 Micha-Screttas, M., 63 Heropoulos, G.A., 63 Mitra, S., 88 Yan, Y.K., 138 Herrmann, R., 129 Montilla, F., 202 Horner, G.M., 52 Zanello, P., 7 Hor, T.S.A., 138 Nawar, N., 217 Zanin, S., 77 PII: S0022-328X(99)00512-4 ic Chemistry Journal of Organometallic Chemistry 590 (1999) 269-274 Subject Index of Volume 590 2-OC(O)Me-C, H.}]:2EtOH, 123 Acetylene Mechanism of the reaction of acetylene with Grignard reagents, 149 Bidentate phosphines Acylferrocenes New rhodium-ruthenium heterobimetallic complexes with bridg- The reactions of acylferrocenes with samarium diiodide: reduc- ing bi- or tri-dentate phosphine ligands, 217 tion, deoxygenation, reductive coupling and rearrange- Binaphthol ment, 42 (R)-Binaphthoxy diiodide lanthanides, 248 Acyl halides Bis-aryl-oxalimidoylchloride A novel method for the synthesis of (Z)-a-selenyl-«,B-unsaturated Chiral diazadiene and $-ketoimine ligands from the reaction of ketones via acylation of (£)-a-selanylvinylstannanes, N,N’-bis-aryl-oxalimidoylchlorides with (S)-prolinol and 234 their reactivity towards iron carbonyls, 104 Adducts 3-Borabicyclo[3.3.1}nonanes Reactions of zwitterionic n?-(alkyn-l-yl-borate)alkenyltin com- Conformational behavior of 3-borabicyclo[3.3.1}nonanes: 1. Study pounds with Lewis bases, 93 of molecular dynamics in 3-methoxy-7«-phenyl-1,5- Alkoxides dimethyl-3-borabicyclo[3.3.1]nonane, 227 (R)-Binaphthoxy diiodide lanthanides, 248 Boron Alkyl Interphase transmetallation of copper(II) by spiroboronates, 52 Synthesis and characterization of oxo-imido and alkyl-imido Reactions of zwitterionic n*-(alkyn-l-yl-borate)alkenyltin com- complexes of molybdenum(VI), 202 pounds with Lewis bases, 93 Alkynes Butatrienylidene Reactions of zwitterionic n?-(alkyn-l-yl-borate)alkenyltin com- Syntheses of complexes containing substituted 4-ethynylquinolines pounds with Lewis bases, 93 or 1-azabuta-1,3-dienes by addition of imines to a cationic Amine N-oxide butatrienylidene-ruthenium complex, 184 Rhenium(I) methoxo carbonyl complexes containing tetraphosphine or triphosphine ligands; facile separation and X-ray '5C- and '’O-NMR spectroscopy crystallographic studies of d//- and meso-[{Re,(p- Characterization of electronic properties of the Cr(CO), group in OMe).,(CO),} (u,p'-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetra- chromium, tricarbonyl [3-{(n°-aryl)methylene]-Z-1(3H)- phosphadecane)], 138 isobenzofuranones] using spectral and theoretical methods, Arene 261 Studies of the bonding in iron(II) cyclopentadienyl and arene Carbene complexes sandwich compounds. Part 5. An interpretation of the *’Fe Group 6 carbene complexes derived from lithiated azoles and the Mossbauer spectroscopic data of dibromoborylferrocenes, crystal structure of a molybdenum thiazolinylidene com- and related molecules, 71 plex, 158 Arsinido Carbonyl The reactions of bis(trifluoromethyl) phosphine and arsine with Acetylenic bond reduction anchored on (CO),Fe,(p-Se,): synthesis trinuclear ruthenium carbonyl cluster: molecular structures and characterization of [(CO),Fe,{p-SeC(H)=C(R)Se}] and of the trinuclear and double-linked trinuclear clusters [{(CO),Fe,Se,},{pu-C(H)—C(R)}] (R = 3-Th, 2-Th; Th= [Ru,(CO),)(u-H), {p-P(CF3)>} >] and [{Ru,(CO),o(p- C,H,S), 46 H)}>{u-P(CF;)>}>], 1 Carbonyl—methoxo complex 1-Azabuta-1,3-dienes Rhenium(I) methoxo carbonyl complexes containing tetraphos- Syntheses of complexes containing substituted 4-ethynylquinolines phine or triphosphine ligands; facile separation and X-ray or l-azabuta-1,3-dienes by addition of imines to a cationic crystallographic studies of d/l- and meso-[{Re,(p- butatrienylidene-ruthenium complex, 184 OMe),(CO),} >(u,p'-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetra- Azo enophile The effect of solvent on the reactions of allyltin (IV) compounds phosphadecane)], 138 with singlet oxygen, 4-phenyl-1,2,4-triazoline-3,5-dione and Chirality diethyl azodicarboxylate, 258 (R)-Binaphthoxy diiodide lanthanides, 248 Azolinylidene complexes Chiral metallocene Group 6 carbene complexes derived from lithiated azoles and the Sterically demanding cyclopentadienyl chemistry: synthesis of iron crystal structure of a molybdenum thiazolinylidene com- and zirconium complexes of 1-phenyl-3-methyl-4,5,6,7-te- plex, 158 trahydroindenyl, 169 Azophosphines Chromium Azo-containing phosphine complexes of palladium(II) and platin- Ligand substitution kinetics in M(CO),(n?'?-norbornadiene) com- um(II) and their effectiveness in the Heck reaction: crystal plexes (M = Cr, Mo, W): displacement of norbornadiene and molecular structure of [PdCl,{PPh,{1-(4-MeC,H,N,)- by bis(diphenylphosphino)alkanes, 208 PII: $0022-328X(99)00513-6 270 Subject Index of Volume 590/ Journal of Organometallic Chemistry 590 (1999) 269-274 Synthesis, structure and spectroelectrochemistry of bis(n°-1,4-tri- Diazadiene tert-butyl-benzene)chromium(0) and _ bis(n°-1,2,4-tri-tert- Chiral diazadiene and f-ketoimine ligands from the reaction of butyl-cyclopentadienyl)cobalt(II). Dia- and paramagnetic N,N’-bis-aryl-oxalimidoylchlorides with (S)-prolinol and sandwich complexes derived from sterically highly demand- their reactivity towards iron carbonyls, 104 ing m-ligands, 7 Dibromoboryl ferrocenes Chromium, tricarbonyl Studies of the bonding in iron(II) cyclopentadienyl and arene Characterization of electronic properties of the Cr(CO), group in sandwich compounds. Part 5. An interpretation of the °’Fe chromium, tricarbonyl [3-[(n°-aryl)methylene]-Z-1(3H)- Mossbauer spectroscopic data of dibromoborylferrocenes, isobenzofuranones] using spectral and theoretical methods, and related molecules, 71 261 Dicarbonyl(methylcyclopentadienyl)(2 - (diethylamino) - 2 - oxoethyl) Cluster iron(II) The reactions of bis(trifluoromethyl) phosphine and arsine with Conformational analysis of dicarbonyl(methylcyclopentadienyl)(2- trinuclear ruthenium carbonyl cluster: molecular structures (diethylamino)-2-oxoethyl)iron(II): a spectroscopic and of the trinuclear and double-linked trinuclear clusters molecular mechanics study, 253 [Ru,(CO),)(u-H), {p-P(CF ;),} 5] and [{Ru,(CO), o(p- 2-(Dimethylamino)phenyl group H)}>{p-P(CF;),}>], 1 Cobalt Synthesis and structures of a series of Ge-M (M = C, Si, and Sn) Synthesis, structure and spectroelectrochemistry of bis(n°-1,4-tri- compounds derived from germyllithium containing three tert-butyl-benzene)chromium(0) and _ bis(n°-1,2,4-tri-tert- 2-(dimethylamino)phenyl groups on germanium, 15 butyl-cyclopentadienyl)cobalt(II]). Dia- and paramagnetic Dimethyltin complex sandwich complexes derived from sterically highly demand- Synthesis, spectroscopy and _ structure of ([N-(2-car- ing m-ligands, 7 boxyphenyl)salicylideneiminato]dimethyltin(IV), 88 Conformation Diphosphinoalkanes Conformational behavior of 3-borabicyclo[3.3.1}nonanes: |. Study Ligand substitution kinetics in M(CO),(n*?-norbornadiene) com- of molecular dynamics in 3-methoxy-7«-phenyl-1,5- plexes (M = Cr, Mo, W): displacement of norbornadiene dimethyl-3-borabicyclo[3.3.1}nonane, 227 by bis(diphenylphosphino)alkanes, 208 Conformational dynamics 1 ,3-Dithiole Conformational analysis of dicarbonyl(methylcyclopentadieny]l)(2- A novel n-donor—n-acceptor system: 1-(4,5-dimethyl-1 ,3-dithiol-2- (diethylamino)-2-oxoethyl)iron(II): a spectroscopic and ylidene)-1-ferrocenyl-3,3-dicyanopropene, 180 molecular mechanics study, 253 Double linked Copper(II) The reactions of bis(trifluoromethyl) phosphine and arsine with Interphase transmetallation of copper(II) by spiroboronates, 52 trinuclear ruthenium carbonyl cluster: molecular structures 15-Crown-5 of the trinuclear and double-linked trinuclear clusters New facts concerning the reaction of K~ , K * (15-crown-5), with [Ru,(CO),)(u-H),{u-P(CF;).}>] and {Ru,(CO),o(p- phenyl glycidyl ether: unexpected formation of potassium cyclopropoxide, 153 H)},{p-P(CF,),}>] , | Crystal structure A novel r-donor—n-acceptor system: 1-(4,5-dimethyl-1 ,3-dithiol-2- EHT calculation ylidene)-1-ferrocenyl-3,3-dicyanopropene, 180 Characterization of electronic properties of the Cr(CO), group in Synthesis and structures of a series of Ge-M (M = C, Si, and Sn) chromium, tricarbonyl [3-{(n°-aryl)methylene]-Z-1(3H)- compounds derived from germyllithium containing three isobenzofuranones] using spectral and theoretical methods, 2-(dimethylamino)phenyl groups on germanium, 15 261 Synthesis of lithium @-(m- and _p-lithiophenoxy)alkoxides Electrochemistry modified with magnesium 2-ethoxyethoxide. Crystal struc- Synthesis, structure and spectroelectrochemistry of bis(n°-1,4-tri- tures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4- tert-butyl-benzene)chromium(0) and_ bis(n°-1,2,4-tri-tert- (3-hydroxypropoxy)phenyl]mercury, 63 butyl-cyclopentadienyl)cobalt(II). Dia- and paramagnetic Cyclooctadiene complexes sandwich complexes derived from sterically highly demand- Reactions of organotin(IV) compounds with platinum complexes: ing n-ligands, 7 Part II. Oxidative addition of SnR,Cl,_ . to [Pt(COD),] (E)-a-Selenylvinylstannanes and subsequent reactions with tertiary phosphines, 25 A novel method for the synthesis of (Z)-a-selenyl-«,fh-unsaturated Cyclopentadienyl ketones via acylation of (£)-a-selanylvinylstannanes, 234 Sterically demanding cyclopentadienyl chemistry: synthesis of iron Ethene polymerization and zirconium complexes of 1-phenyl-3-methyl-4,5,6,7-te- Titanium and zirconium complexes bearing (S,S’)-ferrocenyldithi- trahydroindenyl, 169 olate ligands, 115 Studies of the bonding in iron(II) cyclopentadienyl and arene 4-Ethynylquinoline sandwich compounds. Part 5. An interpretation of the *’Fe Mossbauer spectroscopic data of dibromoborylferrocenes, Syntheses of complexes containing substituted 4-ethynylquinolines or l-azabuta-1,3-dienes by addition of imines to a cationic and related molecules, 71 Cymantrene butatrienylidene-ruthenium complex, 184 Ferrocenylethenylsilatranes and a cymantrenylsilatrane, 129 Ferocene dithiolate Dehydrochlorination Titanium and zirconium complexes bearing (S,S’)-ferrocenyldithi- Preparation of vinylsilane from monosilane and vinyl chloride, 36 olate ligands, 115 Deoxygenation Ferrocene The reactions of acylferrocenes with samarium diiodide: reduc- A novel n-donor—n-acceptor system: 1-(4,5-dimethyl-1,3-dithiol-2- tion, deoxygenation, reductive coupling and rearrange- ylidene)-1-ferrocenyl-3,3-dicyanopropene, 180 ment, 42 Ferrocenylethenylsilatranes and a cymantrenylsilatrane, 129 Subject Index of Volume 590/ Journal of Organometallic Chemistry 590 (1999) 269-274 271 Solid-state mechanochemical synthesis of ferrocene, 222 B-Ketoimine Sterically demanding cyclopentadienyl chemistry: synthesis of iron Chiral diazadiene and B-ketoimine ligands from the reaction of and zirconium complexes of 1|-phenyl-3-methyl-4,5,6,7-te- N,N’-bis-aryl-oxalimidoylchlorides with (S)-prolinol and trahydroindenyl, 169 their reactivity towards iron carbonyls, 104 Kinetics Germane Mechanism of the reaction of acetylene with Grignard reagents, Synthesis and structures of a series of Ge-M (M =C, Si, and Sn) 149 compounds derived from germyllithium containing three 2-(dimethylamino)phenyl groups on germanium, 15 Lanthanides Germyllithium (R)-Binaphthoxy diiodide lanthanides, 248 Synthesis and structures of a series of Ge-M (M = C, Si, and Sn) Lithium compounds derived from germyllithium containing three Synthesis of lithium @-(m- and _p-lithiophenoxy)alkoxides 2-(dimethylamino)phenyl groups on germanium, 15 modified with magnesium 2-ethoxyethoxide. Crystal struc- Grignard reagent tures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4- Mechanism of the reaction of acetylene with Grignard reagents, (3-hydroxypropoxy)phenyl]mercury, 63 149 Lithium naphthalene Group 6 metals Synthesis of lithium @-(m- and_p-lithiophenoxy)alkoxides Group 6 carbene complexes derived from lithiated azoles and the modified with magnesium 2-ethoxyethoxide. Crystal struc- crystal structure of a molybdenum thiazolinylidene com- tures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4- plex, 158 (3-hydroxypropoxy)phenyl]mercury, 63 Luminescent Heck Synthesis and _ characterisation of alkyl-N,N’-bis(salicyli- Azo-containing phosphine complexes of palladium(II) and platin- dene)ethylenediamino- and alkyl-N,N’-bis(salicylidene)-1 ,2- um(II) and their effectiveness in the Heck reaction: crystal phenylenediaminogallium or indium complexes: crystal and molecular structure of [PdCl,{PPh,{1-(4-MeC,H,N,)- structure of methyl-N,N’-bis(salicylidene)-1,2-phenylenedi- 2-OC(O)Me-C,,,H.}]-2EtOH, 123 aminoindium, 242 Heterometallic complexes New rhodium-ruthenium heterobimetallic complexes with bridg- Magnesium ing bi- or tri-dentate phosphine ligands, 217 Synthesis of lithium @-(m- and _p-lithiophenoxy)alkoxides modified with magnesium 2-ethoxyethoxide. Crystal struc- Imido tures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4- Synthesis and characterization of oxo-imido and alkyl—imido (3-hydroxypropoxy)phenyl]mercury, 63 complexes of molybdenum(VI), 202 Mechanism Intramolecular charge-transfer Mechanism of the reaction of acetylene with Grignard reagents, A novel n-donor—m1-acceptor system: 1-(4,5-dimethyl-1,3-dithiol-2- 149 ylidene)-1-ferrocenyl-3,3-dicyanopropene, 180 Mechanochemistry IR Solid-state mechanochemical synthesis of ferrocene, 222 Conformational analysis of dicarbonyl(methylcyclopentadienyl)(2- Mercury (diethylamino)-2-oxoethyl)iron(II): a spectroscopic and Synthesis of lithium @-(m- and _p-lithiophenoxy)alkoxides molecular mechanics study, 253 modified with magnesium 2-ethoxyethoxide. Crystal struc- Iron tures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4- Acetylenic bond reduction anchored on (CO),Fe.,(p-Se,): synthesis (3-hydroxypropoxy)phenyl]mercury, 63 and characterization of [(CO),Fe,{p-SeC(H)=C(R)Se}] and Metal atoms [{(CO),Fe,Se,}>{u-C(H)—C(R)}] (R =3-Th, 2-Th; Th= Synthesis, structure and spectroelectrochemistry of bis(n°-1,4-tri- C,H,S), 46 tert-butyl-benzene)chromium(0) and_ bis(n°-1,2,4-tri-tert- Studies of the bonding in iron(II) cyclopentadienyl and arene butyl-cyclopentadienyl)cobalt(II). Dia- and paramagnetic sandwich compounds. Part 5. An interpretation of the °’Fe sandwich complexes derived from sterically highly demand- Mossbauer spectroscopic data of dibromoborylferrocenes, ing n-ligands, 7 and related molecules, 71 Metalloene reactions Iron carbonyls The effect of solvent on the reactions of allyltin (IV) compounds Chiral diazadiene and f-ketoimine ligands from the reaction of with singlet oxygen, 4-phenyl-1,2,4-triazoline-3,5-dione and N,N'-bis-aryl-oxalimidoylchlorides with (S)-prolinol and diethyl azodicarboxylate, 258 their reactivity towards iron carbonyls, 104 Molecular dynamics Sterically demanding cyclopentadienyl chemistry: synthesis of iron Conformational behavior of 3-borabicyclo[3.3.1}nonanes: |. Study and zirconium complexes of 1-phenyl-3-methyl-4,5,6,7-te- of molecular dynamics in 3-methoxy-7a-phenyl-1,5- trahydroindenyl, 169 dimethyl-3-borabicyclo[3.3.1]nonane, 227 IR spectroscopy Molecular mechanics Characterization of electronic properties of the Cr(CO), group in Conformational analysis of dicarbonyl(methylcyclopentadienyl)(2- chromium, tricarbonyl [3-{(n°-aryl)methylene]-Z-1(3H)- (diethylamino)-2-oxoethyl)iron(II): a spectroscopic and isobenzofuranones] using spectral and theoretical methods, molecular mechanics study, 253 261 Molecular structure Isobenzofuranone The reactions of bis(trifluoromethyl) phosphine and arsine with Characterization of electronic properties of the Cr(CO), group in trinuclear ruthenium carbonyl cluster: molecular structures chromium, tricarbonyl [3-[(n°-aryl)methylene]-Z-1(3H)- of the trinuclear and double-linked trinuclear clusters isobenzofuranones] using spectral and theoretical methods, [Ru3(CO)s)(u-H),{H-P(CF3)>} 2] and [{Ru,(CO),(u- 261 H)}>{u-P(CF;)>}>], 1 272 Subject Index of Volume 590/ Journal of Organometallic Chemistry 590 (1999) 269-274 Molybdenum and molecular structure of [PdCl,{PPh,{1-(4-MeC,H,N,)- Ligand substitution kinetics in M(CO),(n*?-norbornadiene) com- 2-OC(O)Me-C,,,H;}];>2EtOH, 123 plexes (M =Cr, Mo, W): displacement of norbornadiene Phase transfer by bis(diphenylphosphino)alkanes, 208 Interphase transmetallation of copper(II) by spiroboronates, 52 Synthesis and characterization of oxo-imido and alkyl-imido Phenoxyalcohols complexes of molybdenum(VI), 202 Synthesis of lithium @-(m- and _p-lithiophenoxy)alkoxides Synthesis and structural analysis of the mixed-ligand seven-coor- modified with magnesium 2-ethoxyethoxide. Crystal struc- dinate complexes [MI,(CO),{P(OR),}{Ph,P(CH,P)Ph,,,} ] tures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4- (M= M o, R = Me, Et, n= 1; R= Et, ‘Pr, Ph, n=2; M= (3-hydroxypropoxy)phenyl]mercury, 63 W, R = Ph, n= 1; R = Me, Et, ‘Pr, n = 2). A system where Phenyl glycidyl ether the ligand cone angle and ligand ‘bite’ angle do not affect New facts concerning the reaction of K~ , K * (15-crown-5), with the coordination geometry, 77 phenyl glycidyl ether: unexpected formation of potassium Monosilane cyclopropoxide, 153 Preparation of vinylsilane from monosilane and vinyl chloride, 36 Phosphido Mossbauer The reactions of bis(trifluoromethyl) phosphine and arsine with Studies of the bonding in iron(II) cyclopentadienyl and arene trinuclear ruthenium carbonyl cluster: molecular structures sandwich compounds. Part 5. An interpretation of the *’Fe of the trinuclear and double-linked trinuclear clusters Mossbauer spectroscopic data of dibromoborylferrocenes, [Ru;(CO),)(u-H),{u-P(CF 3)>} 2] and [{Ru,(CO),o(p- and related molecules, 71 H)}>{u-P(CF3)>}>], 1 Multinuclear aggregates Phosphine Rhenium(l) methoxo carbonyl complexes containing tetraphos- Synthesis and structural analysis of the mixed-ligand seven-coor- phine or triphosphine ligands; facile separation and X-ray dinate complexes [MI,(CO),{P(OR),}{Ph,P(CH,P)Ph,,, } ] crystallographic studies of d//- and meso-[{Re,(p- (M= M o, R = Me, Et, n= 1; R= Et, ‘Pr, Ph, n =2; M= OMe),(CO),} >(u,p'-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetra- W, R = Ph, n= 1; R = Me, Et, ‘Pr, n = 2). A system where phosphadecane)], 138 the ligand cone angle and ligand ‘bite’ angle do not affect the coordination geometry, 77 NMR Phosphine complexes Conformational analysis of dicarbonyl(methylcyclopentadienyl)(2- Reactions of organotin(IV) compounds with platinum complexes: (diethylamino)-2-oxoethyl)iron(I]): a spectroscopic and Part II. Oxidative addition of SnR,Cl,_ . to [Pt(COD),] molecular mechanics study, 253 and subsequent reactions with tertiary phosphines, 25 Reactions of zwitterionic n?-(alkyn-1l-yl-borate)alkenyltin com- Phosphite pounds with Lewis bases, 93 Synthesis and structural analysis of the mixed-ligand seven-coor- NMR spectra dinate complexes [MI,(CO),{P(OR),}{Ph,P(CH,),, PPh,} ] Synthesis, spectroscopy and structure of [N-(2-carboxyphenyl)- (M= M o, R = Me, Et, n= 1; R= Et, ‘Pr, Ph, n=2; M= salicylideneiminato]dimethyltin(IV), 88 W, R = Ph, n=1; R = Me, Et, ‘Pr, n = 2). A system where NMR spectroscopy the ligand cone angle and ligand ‘bite’ angle do not affect Synthesis and characterization of two cyclic organosiloxanes by the coordination geometry, 77 multinuclear NMR spectroscopy and X-ray crystallogra- Pinacol phy, 237 The reactions of acylferrocenes with samarium diiodide: reduc- Non-linear optics tion, deoxygenation, reductive coupling and rearrange- Ferrocenylethenylsilatranes and a cymantrenylsilatrane, 129 ment, 42 Norbornadiene Platinum Ligand substitution kinetics in M(CO),(n*?-norbornadiene) com- Azo-containing phosphine complexes of palladium(II) and platin- plexes (M = Cr, Mo, W): displacement of norbornadiene um(II) and their effectiveness in the Heck reaction: crystal by bis(diphenylphosphino)alkanes, 208 and molecular structure of [PdCl,{PPh,{1-(4-MeC,H,N,)- 2-OC(O)Me-C,,,H;}]-2EtOH, 123 Organometallic complex Platinum complexes Synthesis and _ characterisation of alkyl-N,N’-bis(salicyli- Reactions of organotin(IV) compounds with platinum complexes: dene)ethylenediamino- and alkyl-N,N’-bis(salicylidene)-,12 - Part II. Oxidative addition of SnR,Cl,_ . to [Pt(COD),] phenylenediaminogallium or indium complexes: crystal and subsequent reactions with tertiary phosphines, 25 structure of methyl-N,N’-bis(salicylidene)-1,2-phenylenedi- Potassium anion aminoindium, 242 New facts concerning the reaction of K~ , K * (15-crown-5), with Organotin complexes phenyl glycidyl ether: unexpected formation of potassium Reactions of organotin(IV) compounds with platinum complexes: cyclopropoxide, 153 Part II. Oxidative addition of SnR,Cl,_ . to [Pt(COD),] Potassium cyclopropoxide and subsequent reactions with tertiary phosphines, 25 New facts concerning the reaction of K~ , K * (15-crown-5), with Oxaallyliron phenyl glycidyl ether: unexpected formation of potassium Conformational analysis of dicarbonyl(methylcyclopentadienyl)(2- cyclopropoxide, 153 (diethylamino)-2-oxoethyl)iron(II): a spectroscopic and 2,6-Pyridinediol molecular mechanics study, 253 Synthesis and characterization of two cyclic organosiloxanes by Oxo multinuclear NMR spectroscopy and X-ray crystallogra- Synthesis and characterization of oxo-imido and alkyl-imido phy, 237 complexes of molybdenum(VI), 202 Rearrangement Palladium The reactions of acylferrocenes with samarium diiodide: reduc- Azo-containing phosphine complexes of palladium(II) and platin- tion, deoxygenation, reductive coupling and rearrange- um(II) and their effectiveness in the Heck reaction: crystal ment, 42 Subject Index of Volume 590/ Journal of Organometallic Chemistry 590 (1999) 269-274 273 Reduction Singlet oxygen The reactions of acylferrocenes with samarium diiodide: reduc- The effect of solvent on the reactions of allyltin (IV) compounds tion, deoxygenation, reductive coupling and rearrange- with singlet oxygen, 4-phenyl-1,2,4-triazoline-3,5-dione and ment, 42 diethyl azodicarboxylate, 258 Resonance stabilization Solid-state reactions Conformational analysis of dicarbonyl(methylcyclopentadienyl)(2- Solid-state mechanochemical synthesis of ferrocene, 222 (diethylamino)-2-oxoethyl)iron(I]): a spectroscopic and Solvation effects molecular mechanics study, 253 Mechanism of the reaction of acetylene with Grignard reagents, Rhenium carbonyl 149 Rhenium(I) methoxo carbonyl complexes containing tetraphos- Solvent effect phine or triphosphine ligands; facile separation and X-ray The effect of solvent on the reactions of allyltin (IV) compounds crystallographic studies of d//- and meso-[{Re,(p- with singlet oxygen, 4-phenyl-1,2,4-triazoline-3,5-dione and OMe).(CO),} >(u,p’-1,1,4,7,10,10-hexaphenyl-1 ,4,7,10-tetra- diethyl azodicarboxylate, 258 phosphadecane)], 138 Spiroboronate Rhodium Interphase transmetallation of copper(II) by spiroboronates, 52 New rhodium-—ruthenium heterobimetallic complexes with bridg- (S)-Prolinol ing bi- or tri-dentate phosphine ligands, 217 Chiral diazadiene and {-ketoimine ligands from the reaction of Ruthenium N,N’-bis-aryl-oxalimidoylchlorides with (S)-prolinol and New rhodium-—ruthenium heterobimetallic complexes with bridg- their reactivity towards iron carbonyls, 104 ing bi- or tri-dentate phosphine ligands, 217 Stannane Syntheses of complexes containing substituted 4-ethynylquinolines Synthesis and structures of a series of Ge~-M (M = C, Si, and Sn) or l-azabuta-1,3-dienes by addition of imines to a cationic compounds derived from germyllithium containing three butatrienylidene-ruthenium complex, 184 2-(dimethylamino)phenyl groups on germanium, 15 Substitution Samarium diiodide Ligand substitution kinetics in M(CO),(n??-norbornadiene) com- The reactions of acylferrocenes with samarium diiodide: reduction, deoxygenation, reductive coupling and rearrange- plexes (M=Cr, Mo, W): displacement of norbornadiene ment, 42 by bis(diphenylphosphino)alkanes, 208 Sandwich complexes Synthesis Synthesis, structure and spectroelectrochemistry of bis(n°-1,4-tri- A novel method for the synthesis of (Z )-a-selenyl-«,B-unsaturated tert-butyl-benzene)chromium(0) and_ bis(n°-1,2,4-tri-tert- ketones via acylation of (£)-«-selanylvinylstannanes, 234 butyl-cyclopentadienyl)cobalt(II). Dia- and paramagnetic Solid-state mechanochemical synthesis of ferrocene, 222 sandwich complexes derived from sterically highly demanding m-ligands, 7 Tetraphosphine Schiff base Rhenium(1) methoxo carbonyl complexes containing tetraphos- Synthesis and_ characterisation of alkyl-N,N’-bis(salicyli- phine or triphosphine ligands; facile separation and X-ray dene)ethylenediamino- and alkyl-N,N’-bis(salicylidene)-1 ,2- crystallographic studies of d//- and meso-[{Re,(p- phenylenediaminogallium or indium complexes: crystal OMe),(CO),} (u.p'-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetra- structure of methyl-N,N’-bis(salicylidene)-1,2-phenylenedi- phosphadecane)], 138 aminoindium, 242 Thermal reaction Synthesis, spectroscopy and structure of [N-(2-carboxyphenyl)- Preparation of vinylsilane from monosilane and vinyl chloride, 36 salicylideneiminato]dimethyltin(IV), 88 Thiopheneacetylene Second-sphere coordination Acetylenic bond reduction anchored on (CO),Fe,(p-Se,): synthesis Interphase transmetallation of copper(II) by spiroboronates, 52 and characterization of [(CO),Fe, {u-SeC(H)=C(R)Se}] and Selenium [{(CO),Fe,Se,},{u-C(H)—C(R)}] (R =3-Th, 2-Th; Th= Acetylenic bond reduction anchored on (CO),Fe,(p-Se,): synthesis C,H,S), 46 and characterization of [(CO),Fe,{p-SeC(H)=C(R)Se}] and Tin [{(CO),Fe,Se,}>{u-C(H)—C(R)}] (R =3-Th, 2-Th; Th= Reactions of zwitterionic n?-(alkyn-1l-yl-borate)alkenyltin com- C,H,S), 46 pounds with Lewis bases, 93 Seven-coordinate Titanium Synthesis and structural analysis of the mixed-ligand seven-coor- Titanium and zirconium complexes bearing (S,S’)-ferrocenyldithi- dinate complexes [MI,(CO),{P(OR),} {Ph,P(CH.,),, PPh,}] olate ligands, 115 (M= M o, R= Me, Et, n=1; R= Et, ‘Pr, Ph, n =2; M= Transmetallation W, R=Ph, n=1; R= Me, Et, ‘Pr, n= 2). A system where Group 6 carbene complexes derived from lithiated azoles and the the ligand cone angle and ligand ‘bite’ angle do not affect crystal structure of a molybdenum thiazolinylidene com- the coordination geometry, 77 plex, 158 Silane Trialkylgallium Synthesis and structures of a series of Ge-M (M = C, Si, and Sn) Synthesis and _ characterisation of alkyl-N,N’-bis(salicyli- compounds derived from germyllithium containing three dene)ethylenediamino- and alkyl-N,N’-bis(salicylidene)-1 ,2- 2-(dimethylamino)phenyl groups on germanium, 15 phenylenediaminogallium or indium complexes: crystal Silatrane Ferrocenylethenylsilatranes and a cymantrenylsilatrane, 129 structure of methyl-N,N’-bis(salicylidene)-1,2-phenylenedi- Siloxane aminoindium, 242 Synthesis and characterization of two cyclic organosiloxanes by Trialkylindium multinuclear NMR spectroscopy and X-ray crystallogra- Synthesis and characterisation of alkyl-N,N’-bis(salicylidene)- phy, 237 ethylenediamino - and alkyl - N,N’ - bis(salicylidene) - 1,2- 274 Subject Index of Volume 590 / Journal of Organometallic Chemistry 590 (1999) 269-274 phenylenediaminogallium or indium complexes: crystal structure Wood of methyl-N,N’-bis(salicylidene)-1,2-phenylenediaminoin- Interphase transmetallation of copper(II) by spiroboronates, 52 dium, 242 Tridentate phosphines X-ray New rhodium-—ruthenium heterobimetallic complexes with bridg- Acetylenic bond reduction anchored on (CO),Fe,(y-Se,): synthesis ing bi- or tri-dentate phosphine ligands, 217 and characterization of [(CO),Fe,{p-SeC(H)=C(R)Se}] and Triphosphine [{(CO),Fe,Se,},{p-C(H)—C(R)}] (R =3-Th, 2-Th; Th= Rhenium(I) methoxo carbonyl complexes containing tetraphos- C,H,S), 46 phine or triphosphine ligands; facile separation and X-ray X-ray structure crystallographic studies of d//- and meso-[{Re,(p- Synthesis and characterization of two cyclic organosiloxanes by OMe).,(CO),} >(p,p'-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetra- multinuclear NMR spectroscopy and X-ray crystallogra- phosphadecane)], 138 phy, 237 Tungsten Synthesis, spectroscopy and structure of [N-(2-carboxyphenyl)- Ligand substitution kinetics in M(CO),(n*?-norbornadiene) com- salicylideneiminato]dimethyltin(IV), 88 plexes (M = Cr, Mo, W): displacement of norbornadiene by bis(diphenylphosphino)alkanes, 208 Synthesis and structural analysis of the mixed-ligand seven-coor- Zirconium dinate complexes [MI,(CO),{P(OR),}{Ph,P(CH,P)Ph,,,}] Sterically demanding cyclopentadienyl chemistry: synthesis of iron (M= M o, R= Me, Et, n= 1; R= Et, ‘Pr, Ph, n =2; M= and zirconium complexes of 1-phenyl-3-methyl-4,5,6,7-te- W, R = Ph, n= 1; R = Me, Et, ‘Pr, nm = 2). A system where trahydroindenyl, 169 the ligand cone angle and ligand ‘bite’ angle do not affect Titanium and zirconium complexes bearing (S,S’)-ferrocenyldithi- the coordination geometry, 77 olate ligands, 115 (Z )-x-Selenyl-x,B-unsaturated ketones Vinyl chloride A novel method for the synthesis of (Z)-«-selenyl-«,B-unsaturated Preparation of vinylsilane from monosilane and vinyl chloride, 36 ketones via acylation of (£)-«-selanylvinylstannanes, 234 Vinylsilane Zwitterionic compounds Preparation of vinylsilane from monosilane and vinyl chloride, Reactions of zwitterionic n?-(alkyn-1l-yl-borate)alkenyltin com- 36 pounds with Lewis bases, 93