Table Of Content

Journal of Organometallic Chemistry 588 (1999) 289-291 Contents of Volume 588 Regular Papers Dendritic carbosilanes containing hydroxy groups on the periphery a es 6-5 eee eA se we EA eR OE Ow Ee EAS EAS SOOO ee ww Preparation of dendritic carbosilanes containing ethynyl groups and dicobalt hexacarbonyl clusters on the periphery ee er ee eee or ee re en ae ee ee ee Pe er eee ee ee ere | Catalytic propargylation of aldehydes with allenyltributylstannane by ytterbium triflate . e-8 68 8°O.8 2: ee © 2s 6S Se oe ew. 66.8. Oe 6 Oe C4 2.0 6-8. 8 Oe eS. Se SS. OO #2. 26 le ee Oe Oce’ 6. SS So ee ee See Cationic species derived from the n'-amidosilyl-n°-cyclopentadienyl dimethyl titanium complex. Crystal structure of [Ti{n>-C,;H,SiMe,. [n'-N(2,6-Me,C,H,)]} {CH,B(C,F.),}(C.F;)] ae. Gee, . Ge, ale, Ge HU, Fe DS ccc ce we ee ee ete ee ee ees PS EP Te CVA i I 22 1-(2,4,6-Tri-tertiarybutylphenyl)-3,5-di-tert-butyl-1,2,4-triphosphole: a possibly stable, fully aromatic, compound with planar tricoordinate phosphorus * Fi SS BCPrerrererere rat eee ee eh wee a oe eee oe ee eee eee 28 Preparation of Mo, Co and iron group heterometallic clusters linked by cyclotetradeca-1,8-diyne ligand ae. Se, Wee. Wee Ge. BOR, See DU eect ee eee ee eee ee CORR Se FSG 7s ORR 32 Solid state, structural and solution studies on _ bis(2-methylbenzyl)-selenide, methyl(2,4,6-tri-t-butylphenyl)-selenide, bis(2,4,6-tri- methylphenyl)-diselenide, and bis(2,4,6-tri--butylphenyl)-diselenide P.M. Dickson, M.A.D. McGowan, B. Yearwood, M.J. Heeg, J.P. Oliver... 2... 2... 2. ee ee ee ee ns 42 Synthesis and characterization of sterically hindered arylsilanes containing the 2,4,6-trimethoxyphenyl ligand (TMP): X-ray structures of (TMP)SiH,, (TMP).,SiH,, and (TMP),SiH ey a I ie ie i ii hd ee ke Oe i ee a 51 Vibrational and electronic spectra of tetrahedral molecules (Me,M),M’ (M = Si, Sn; M’ = Si, Ge) with heteronuclear M—M’ bonds L.A. Leites, S.S. Bukalov, 1.A. Garbuzova, V.Y. Lee, E.G. Baskir, M.P. Egorov, O.M. Nefedov.................255. 60 Rhodium complexes containing bidentate imidazolyl ligands: synthesis and structure es 8a 8, Fee Fs, BAS FPS TCC TRC Tee eee eee ee 69 Is there a continuum from organosamarium hydroxo to oxo compounds? Crystal structures of [{(Me,Si),C;H;},Sm],(u-O)(u-OH,) and three distinct crystalline forms of [{(Me,Si),C;H,},Sm(p-OH)}, eS & eS ee FH Be ee ee ee ie ee ee ee a a a 78 Homogeneous hydrogenation of diphenylacetylene in the presence of Ru,(CO),L,; (L=PPh;, PEt,). The crystal structure of Ru,(CO),,.(PEt,),: a reaction intermediate? Ge, Ge, Ge, I OE I ee eee es Meer e es 83 Preparation, chemistry, and structure of new ruthenium complexes B. Sohmeiter, 1. Golibers, D. Reshel, Z. Goa, ¥. GVO. 0 ww ce eee rcr rere ec nveeeserseseseees 92 The synthesis and crystal structures of the first examples of six-membered inorganic iridacycles containing the [(Ph,PE),N]~ ligand (E =S or Se) ee ee ee os Oa 8 ache Me awe Ae ew ae Oe ee eee we oe Bee ee eee ee oes YY Synthesis and Lewis acidity of triorganosilyl and triorganostannyl esters of orthoboric, metaboric, and arylboronic acids ee ee, Oe PC ce ae bk ak eS hee 86 ON Oe RE Oe 08 8 ee ROO ee bee 107 290 Contents of Volume 588 / Journal of Organometallic Chemistry 588 (1999) 289-291 Synthesis, structural characterisation and electrochemistry of ruthenium carbonyl clusters derived from ferrocenyl(formyl)acetylene a Ee a eee eee ee ee eee Se eee ee ae ee ee ee 113 Synthesis, fluxional behavior and structures of diethyldithiophosphate molybdenum complexes: crystal structures of [Et,N][Mo(CO),- {n?-S,P(OEt),}] and [Mo(CH,CN)(n?-C,H,)(CO), {n?-S,P(OEt), }] OE Oe Se ee ee eee ee ee ee Cee ee ee ee Dicyclopentadienyl zirconium and hafnium complexes with the bridged (dimethylsilanodiyl)dicyclopentadienyl [(SiMe,)(n°-C;H,),./ ligand. X-ray molecular structure of [Zr{(SiMe,)(n°-C,H,),}(CH,Ph)],(p-O) es ee I, Gee I, OO, bn kok be OR CRM ADAH ROOK ORO DO ORS RDO I Ee Coca at ee ee Die ne Cee er ie Gs Ge 2 ies 2.6 tise ee i ewe bie 6 CES bee Cb eo a 143 153 Regular Papers A new synthesis of chloroheterocycles via metal—halogen exchange between trichloroacetyl derivatives and heteroaromatic lithium and Grignard reagents C. Boga, E. Del Vecchio, L. Forlani, L. Milanesi, P.E. Todesco. .. 0... ee ee ee eee eee eww ee eee eee 155 Diphenyl-2-pyridylphosphine as a bidentate ligand in the coordination of dicobalt octacarbonyl; X-ray crystal structures of Co,(CO),(- P,N-PPh,py){p-HC=CSiMe,}, and Co,(CO),,.(u-P,N-PPh,py) F.-E. Hong, Y.-C. Chang, R.-E. Chang, C.-C. Lin, S.-L. Wang, F.-L. Liao... 2... ee eee Synthesis, structure, and characterization of lanthanide complexes bearing 1|,3-diphenyltriazenido ligands D. Pfeiffer, I.A. Guzei, L.M. Liable-Sands, M.J. Heeg, A.L. Rheingold, C.H. Winter .... 2... 2 ee ee 167 Force-field parameterisation, synthesis and crystal structure of a novel tricarbonylchromium arene complex S.J. Hughes, J.R. Moss, K.J. Naidoo, J.F. Kelly, A.S. Bateamov. . 0... tt ee ee twee eee eee wee eee eases 176 New chiral diphosphinites: synthesis of Rh complexes. Heterogenisation on zeolites EE ee ee a ee ee ee ee ee ee ee ee ee ee 186 The photochemistry of (.-RC,H)Co,(CO), species (R = H or C,H), important intermediates in the Pauson—Khand reaction EN EE a ee ee ee ee 195 Reduction of rhenium decacarbonyl by samarium(II): synthesis and structure of the spiked triangular anion [HRe,(CO),,]~ ES PE ee ee ee ee ET ET CEE CE TEEPE CELT TT Tee 200 A novel ruthenium carbene dimer that is active in the metathesis of internal alkenes; the crystal structure of Ru,(=CHPh),(CF,CO,),(p- CF,CO,),(PCy,).(u-H,O) Te a a ee ee a ae ee 205 Syntheses, reactivities and crystal structures of triosmium clusters with imidazo(1,2-a)pyridine ligand J. Akther, K.A. Azam, A.R. Das, M.B. Hursthouse, S.E. Kabir, K.M. Abdul Malik, E. Rosenberg, M. Tesmer, H. Vahrenkamp . 211 Synthesis and molecular structure of phenyl and tolylgermatranes ee ee Te Cale bbe e ee OPC KOE PERCE SO RR Ow O's CoH EO ROR Oe 222 Diborane(4)yl and bridged borylene complexes from 1,2-dipyrrolidino- and 1,2-dipiperidinodiborane(4) derivatives ve eee ee ee eT eee eee ee eee ee nee eee eee eee Synthesis of azetidinylidene complexes from [(CO);M(CH,CI,)], phenylacetylene and imines and oxidative decomplexation to give B-lactams A ge i 8 ed kk ee ee A ERE SO OR ak ee OO 6 6 O08 bb OS 0 235 Anionische 1,2-(O-—N)- und neutrale 1,2-(N +O, O-N)-Silylgruppen-Wanderung — Synthese isomerer Tris(silyl)hydroxylamine und eines Silylaminodisiloxans i cana. ko « 6 bw 6 ee eed b 6b Oe NO Ok ORO ee 8 Oe eee 242 Contents of Volume 588 / Journal of Organometallic Chemistry 588 (1999) 289-291 291 Metallkomplexe mit biologisch wichtigen Liganden, CXXII: Carbonyl-Rhenium- und Palladium—Enolat-Komplexe aus Schiff-Basen von Glycin- und Peptidestern. C-C-Kupplung und [2 + 3]-Cycloadditionen AC Ni,i ch ehcp a: Wie he ae be dc lr do be he A ae AK Os EE see eae ce 247 Synthesis and crystal structures of two trigonal bipyramidal Sb(V) compounds, R,SbBr, and R,Sb(S,PPh.,), (R = Me,SiCH,) i Eeereeeee, Dae. eee, ee. GU, Gk. DOU, I i ce eee eee ewer bbb vctetabeseesbieews 256 Syntheses and chemistry of Tris(2-pyridyl)phosphine complexes of Group VI transition metals. X-ray structural studies of the molybdenum complexes Cod. Bue, Vm. Pee, 3-0. Gee, BD. Wu, Girdd, Doo, BBE Pee. 2. ce ee ee rece ewe rests eeeneee 260 Synthesis and reactions of mono- and dipalladium complexes containing 2-thienyl and 2,5 (or 2,5’) -bridged thienylene (or dithienylene) ligand: new dipalladium complex formation connected by thioketene part via C-S bond cleavage of thiophene ee ey ee Se Se a MINS CI 06.6 5 bk 6 66 6s CERO EEO SESS eR OOS ROE EE RES Eee a ewe Ro 268 ES Se eae ee oa ae ed ake eet TELE Ox aa © ce SE tee ie ke 2 a ee ee ee ke ae 279 281 ee EE abe 0s.S 66 Wo 8s hl ee ahah ACs Ee Ce as eae eee 283 I SS, Ne ls he aoa a Sa aco tk Ds ico c OL eek ee el ects deals eee bere Bek ok i ks elc as a 9 ee eo tL 289