Table Of Content

4) ¥ 2 ELSEVIER Journal of Organometallic Chemistry 571 (1998) 305 Author index of Volume 571 Ahlers, W., 83 Hogarth, G., 43 Rajesh, T., 183 Ahigrén, M., 129 Hoépfi, H., 2! Rao, N., 183 Arthurs, M., 43 Horatek, M., 77 Rausch, M.D., 171 Asfari, Z., 103 Huck, S., 107 Rossell, O., 123 Atwood, D.A., 15 Hu, Q.-M., 55 Ruf, M., 91 Huttner, G., 231, 281 Basato, M., 115 Santillan, R Belsky, V.K., 243 Jacobi, A., 231, 281 Sappa, E., 25! Bennett, M.A., 139 Jin, Z., 201 Schmitz. F.J.. ! Beziat, Y., 189 Jones, N.G., 195 Schober. P.. 281 Bickerton, J.C., 43 Seco, M., 123 Blagodatskikh, I.V., 31 Kabir, S.E., 91 Segalés, G., 123 Bown, M., 139 Katsoulis, D.E., 31 Shchegolikhina, O.1., 31 Breunig, H.J., 299 Khvostov, A.V., 243 Shen, J., 205 Brunet, J.-J., 7 King, P.J., 25! Siebert, W., 107 Briining, K., 145 Knox, S.A.R., 251 Singer, A., 15 Biichner, K., 267 Komulainen, J., 129 Sizov, A.L., 243 Bulychev, B.M., 243 Kubal, G., 43 Song, L.-C., 55 Byrnes, M.J., 139 Sowerby, D.B., 291 . Laitinen, R.S 4+ Stépnitka, P., 77 Castiglioni, M., 251 Lakshmi, M., 18 Stevens, E.D., 205 Castillo, D., 21 Lang, H., 145 Sun, C.-X., 55 Cea-Olivares, R., 15 Leglaye, P Sun, J., 55 Chauvin, R., 7 Li, R.-X., 223 Cheng, L., 149 Liu, X., 201 Thewalt, U., 77 Chen, R., 201 Li, X.-J., 223 Thirase, K., 215 Chien, J.C.W., 171 Lu, G.-L., 55 Tin. K.-C.. 223 Coville, N.J., 149 Lyssenko, K.A., 31 Tiripicchio, A., 123 Cristau, H.-J., 189 Tommasi, D., 115 nyey na» i, h MMaackhs,i ¢, K.Z, .B7 7 ll TTrruojuiplello,, JM..,, 21 37 , . Mak, T.C.W., 223 Truter, M.R., 43 Dothem, E., 3 Malisch, W., 215 Turner, P.. 195 Donnadieu, B.. 7 Metz. A.. 267 , . Eckert-Maksi¢c, M., 65 Molodtsova, Y.A., 31 Ustinov, B.B., 243 Morton-Blake, D.A., 43 Erker, G., 83 Mufioz-Hernandez, M.-A., 15 Vahrenkamp, H., 9! Farfan. N.. 2? Vicens, J., 103 Ferreira, V.F., | Nedelec, J.Y., 3 Field, L.D., 195 Neibecker, D., 7 Wadepohl, H., 267 Foster. P.. 171 Neumayer, M., 215 Wagner, G., 261 Frohlich, R., 83 Nolan, S.P., 205 Wang, B., 97 Winterhalter, U., 231 Gasc, M.-B., 189 Ogafrain, M., 37 Wong, N.-B., 223 Geze, A., 189 Oilunkaniemi, R., 129 Gibbons, M.N., 291 Xie, W., 97 Ginsberg, A.. 107 Pedersen, B., 261 Xu. S.. 97 Giordano, R., 251 Pellinghelli, M.A., 123 Glasovac, Z., 65 Periasamy, M., 183 Yang, J., 55 Gunzelmann, N., 215 Pozdniakova, Y.A., 31 Yangkou Mbianda, X., 189 Pritzkow, H., 107, 267 Yang, Q.-C., 223 Haar, C.M., 205 Probst, J., 299 Youn, J.-H., 261 Hall, C.D., 103 Pulpoka, B., 103 Herrmann, M., 267 Pursiainen, J., 129 Zecca, M., 115 Herrmann, R., 261 Zhou, X., 97 Hiller, J., 77 Qin, X.-D., 55 Zsolnai, L., 281 PIT $0022-328X(98)01011-0 4; ~~ ELSEVIER Journal of Organometallic Chemistry 571 (1998) 307-311 Subject index of Volume 571 Ab initio calculations n°-Arene-y °-(2,3-dihydro-1 ,3-diborolyl)rhodium Molecular and electronic structure of some silacyclopropaben- Syntheses, structures and reactivity of 7°-arene- °-2,3-dihydro-di- zenes: the reversed Mills—Nixon effect, 65 borolyl-rhodium complexes, 107 Acylnickel complexes Asymmetric synthesis Nickel—bipyridine catalysed electrosynthesis of ketones from or Reaktionen von Ph,SbH und p-TolSbH, mit organischen ganic halides and carbon monoxide: kinetic and mechanis- Verbindungen, 299 tic investigations, 37 Azobenzene Aldehydes Insertion of CO and SO, into the N—N bond of [Fe(CO),(u- Ph,N,)], 91 Reaktionen von Ph,SbH und p-TolSbH, mit organischen Azulene Verbindungen, 299 Molecules with potential applications for non-linear optics: the Alkane elimination combination of ferrocene and azulene, 261 Inorganic rings with group 13 organometallics and iminodiphos- phinechalcogenides, 15 | ,8-Bis(diphenylphosphinomethy])naphthalene Alkoholysis Synthesis and characterization of ruthenium complexes of 1,8- Silictumorganische Dendrimere mit verschiedenen Dendronen bis(diphenylphosphinomethyl)naphthalene (BDNA) and 145 their catalytic hydrogenation reactions to 2,f-unsaturated Alkoxysilanes trimethylsilylation aldehydes, 223 A new approach to the synthesis of cage-like metallasiloxanes, 31 Bis(trimethylsilyl)acetylene bridge Alkylation Bis{(7 °-cyclooctatetraene)titanium] complex with perpendicularly Reductive-alkylation and aromatic coupling reactions of 1,4-ben- bridging bis(trimethylsilyl)acetylene, 77 zoquinone derivatives promoted by ethylaluminum dichlo- B3LYP calculations ride, | Molecular and electronic structure of some silacyclopropaben- Alkyne, benzyne ligands zenes: the reversed Mills—Nixon effect, 65 Homogeneous hydrogenation of alkynes and of 1,4-cyclohexadi- Bond alternations ene in the presence of the clusters Ru,(CO)(,- Molecular and electronic structure of some silacyclopropaben- PPh,)(C,H,), Ru,(CO), ,(44-PPh)\(C,H,), zenes: the reversed Mills—Nixon effect, 65 Ru,(CO).(u-PPh.,).(HC.Ph) and Ru,(CO), (ue Boron complexes PPh)\(C,Ph,), 251 X-ray crystallographic study of boroxazolidones obtained from Alkyny! metallocene cation L-ornithine, L-methionine, kainic acid and 2,6-pyridinedi- Reaction of (c-alkynyl) Group 4 metallocene cation complexes carboxylic acid, 21 with alkyl- and arylisocyanides, 83 Boroxazolidines Aluminum X-ray crystallographic study of boroxazolidones obtained from Inorganic rings with group 13 organometallics and iminodiphos- L-ornithine, L-methionine, kainic acid and 2,6-pyridinedi- phinechalcogenides, 15 carboxylic acid, 21 Reductive-alkylation and aromatic coupling reactions of 1,4-ben- Boroxazolidones X-ray crystallographic study of boroxazolidones obtained from zoquinone derivatives promoted by ethylaluminum dichlo- L-ornithine, L-methionine, kainic acid and 2,6-pyridinedi- ride, | carboxylic acid, 21 a-Amino acids Bridged-cyclopentadiene X-ray crystallographic study of boroxazolidones obtained from Synthesis, structure and properties of hexamethyltrisilane-bridged L-ornithine, L-methionine, kainic acid and 2,6-pyridinedi- biscyclopentadienyl tetracarbonyl di-iron, 97 carboxylic acid, 21 ansa-Metallocenes Cage-like metallasiloxanes ansa-Y tterbocenes( + 3) with a short bridge and bulky sub- A new approach to the synthesis of cage-like metallasiloxanes, 31 stituents: synthesis and crystal structure of meso- Calixarenes (CH,),Sif3-(CH,),SiYCO.CKH ,TH}F,) , Novel redox-active calixarenes, 103 rac-(CH,),C[3-‘BuC.H,], Yb(z,-Cl),Li(OEt,),, and [meso- Carbide clusters (CH,),C{3-"BuC.H,}, Yb(z,-OCH,)],, 243 Iron/gold carbide clusters containing Fe,Au or Fe,Au, skeletons Antimony X-ray crystal structure of [Fe,CAu,(CO),,(dppm)}, 123 Preparation and crystal structures of [u-SbPh,],[Mo(CO)(7°- Carbon monoxide C.H,)],*CHC1, and SbPh[{Fe(CO).(7°-C.H,)},, 291 New reactivity of (RC=CCH,OH)Co(CO), complexes in the Pau- Arene clusters son—Khand reaction in the presence of CF ,;COOH: synthe- Organometallic cluster complexes with face-capping arene ligands, sis of methyl substituted cyclopentenones, 183 10. A study of the influence of substituents on the synthesis Carbon monoxide insertion of organometallic cluster complexes of the type Insertion of CO and SO, into the N-N bond of [Fe(CO)<y- [{(C.H.)Co} (4,-97:97:9?-alkenylarene)], 267 Ph,N,)}, 91 PIT $0022-328X(98)01012-2 308 Subject index arbosilane Cyclopentadieny! Silictumorganische Dendrimere mit verschiedenen Dendronen, 145 Organometallic cluster complexes with face-capping arene ligands, arbosiloxane 10. A study of the influence of substituents on the synthesis Silictumorganische Dendrimere mit verschiedenen Dendronen, 145 of organometallic cluster complexes of the type atalysis [{(C.H.)Co} (44-97: 7:9?-alkenylarene)}, 267 Organometallic chemistry in the solid state, 149 Cyclopentenones hiral auxiliary New reactivity of (RC=CCH,OH)Co(CO), complexes in the Pau- Chiral modifizierte Dicarbonyl(cyclopentadieny])ferrio-phosphane son—Khand reaction in the presence of CF ,;COOH: synthe- Synthese und Bestimmung der Inversionsbarriere am Phos- sis of methyl substituted cyclopentenones, 183 phido-Phosphor: Obergangsmetall-substituierte Phosphane, Arsane und Stibane, 65, 215 Dioxirane innamaldehyde Dioxirane oxidation of substituted vinylphosphonates: a novel Synthesis and characterization of ruthenium complexes of | ,8-bis(- efficient route to 1,2-epoxyalkylphosphonates, 189 diphenylphosphinomethyl)naphthalene (BDNA) and their d°-Metal—isocyanide complex catalytic hydrogenation reactions to 2,f-unsaturated alde- Reaction of (o-alkynyl) Group 4 metallocene cation complexes with hydes, 223 alkyl- and arylisocyanides, 83 itral Synthesis and characterization of ruthenium complexes of 1 ,8-bis(- Electrochemistry diphenylphosphinomethyl)naphthalene (BDNA) and their Molecules with potential applications for non-linear optics: the catalytic hydrogenation reactions to 2,f-unsaturated alde- combination of ferrocene and azulene, 261 hydes, 223 Electrophiles ‘obalt Synthesis of doubly-bridged Fe/Se and Fe/Te complexes via reac- New reactivity of (RC=CCH,OH)Co,(CO), complexes in the Pau- tions of the [MgX]* salts of anions [(u-RE\(y- son—Khand reaction in the presence of CF ,;COOH: synthe- CO)Fe(CO),] (E=Se,Te). Crystal structure of sis of methyl substituted cyclopentenones, 183 (u-p-MeC,H,Te)(u-PhC=NPh)Fe(CO),, 55 Organometallic cluster complexes with face-capping arene ligands, Electrophilic addition 10. A study of the influence of substituents on the synthesis lron/gold carbide clusters containing Fe,Au or Fe.Au, skeletons of organometallic cluster complexes of the type X-ray crystal structure of [Fe,CAu(CO),,(dppm)], 123 [{(C,H.)Co} ,(4,-97:9?:?-alkenylarene)], 267 Epoxidation CO-bridged anions Dioxirane oxidation of substituted vinylphosphonates: a novel Synthesis of doubly-bridged Fe/Se and Fe/Te complexes via reac- efficient route to 1,2-epoxyalkylphosphonates, 189 tions of the [MgX]* salts of anions [(#-RE)(z- 1,2-Epoxyphosphonate CO)Fe,(CO),] (E=Se,Te). Crystal structure of Dioxirane oxidation of substituted vinylphosphonates: a novel (u-p-MeC,H,Te)(u-PhC=NPh)Fe(CO),, 55 efficient route to 1,2-epoxyalkylphosphonates, 189 Complexation Extended Hiickei calculations Novel redox-active calixarenes, 103 Substituted cyclopentadienyl compounds. Part V. NMR and ex- CO-substitution tended Hiickel studies of the isomeric preferences of some Improved synthesis of KHCr(CO), and comparative coordination main group metal cyclopentadienide compounds and a chemistry from KHCr(CO),. and KHFe(CO),, 7 reinvestigation of the crystal structure of thallium(I) tri- Crystal structure cyanovinylcyclopentadienide, 43 ansa-Y tterbocenes( + 3) with a short bridge and bulky substituents synthesis and crystal structure of meso-(CH,),Si[3- Fe—Fe bond (CH,),SiC.H,], YoCK THF), rac-(CH,),C{3- Synthesis, structure and properties of hexamethyltrisilane-bridged ‘BuC,H,],Yb(z,-Cl),Li(OEt,),, and biscyclopentadieny! tetracarbony! di-iron, 97 [meso-~(CH,),C[3-‘BuC,H,], Yb(4,-OCH,)},, 243 Ferrio-phosphane Bis[(°-cyclooctatetraene)titanium] complex with perpendicularly Chiral modifizierte Dicarbonyl(cyclopentadienyl)ferrio-phosphane bridging bis(trimethylsilyl)acetylene, 77 Synthese und Bestimmung der Inversionsbarriere am Phos- P—H bond activation at a tungsten(0) centre: synthesis and charac- phido-Phosphor: Obergangsmetall-substituierte Phosphane, terisation of WH(PPh,)\(dppe),, 195 Arsane und Stibane, 65, 215 Substituted cyclopentadienyl compounds. Part V. NMR and ex- Ferrocene tended Hiickel studies of the isomeric preferences of some Molecules with potential applications for non-linear optics: the main group metal cyclopentadienide compounds and a combination of ferrocene and azulene, 261 reinvestigation of the crystal structure of thallium(I) tri- Fluxionality cyanovinylcyclopentadienide, 43 Substituted cyclopentadienyl compounds. Part V. NMR and ex- Synthesis, structure and properties of hexamethyltrisilane-bridged tended Hiickel studies of the isomeric preferences of some biscyclopentadieny! tetracarbonyl di-iron, 97 main group metal cyclopentadienide compounds and a Cyclooctatetraene dianion reinvestigation of the crystal structure of thallium(I) tri- Bis{(7*-cyclooctatetraene)titanium] complex with perpendicularly cyanovinylcyclopentadienide, 43 bridging bis(trimethylsilyl)acetylene, 77 Functionalized tripod ligands Cyclopentadiene Synthesis, coordination chemistry and polymerfixation of the Preparation and crystal structures of [«-SbPh,],[Mo(CO).(7°- tripod-ligand HOC,H,CH,C(CH,PPh,),, 281 C;H,)},:CHCI, and SbPh[{Fe(CO)(7°-C.H,)],, 291 Cyclopentadienides Gallium Substituted cyclopentadienyl compounds. Part V. NMR and ex- Inorganic rings with group 13 organometallics and iminodiphos- tended Hiickel studies of the isomeric preferences of some phinechalcogenides, 15 main group metal cyclopentadienide compounds and a Gold and iron fragments reinvestigation of the crystal structure of thallium(lI) tri- Iron/gold carbide clusters containing Fe,Au or Fe,Au, skeletons cyanovinylcyclopentadienide, 43 X-ray crystal structure of [Fe,CAu,(CO),,(dppm)], 123 Subje: t index Group 4 metallocenes Isomerisation Reaction of (¢-alkynyl) Group 4 metallocene cation complexes with Organometallic chemistry in the solid state, 149 alkyl- and arylisocyanides, 83 Isomerization Thermally induced endo to exo isomerization in the o-xylylene Homogeneous catalysis complexes of zerovalent ruthenium and osmium, M(» Homogeneous hydrogenation of alkynes and of | ,4-cyclohexadiene C,.Me,){7*-o-~(CH,).C,Me,} (M = Ru, Os), 139 in the presence of the clusters Ru,(CO)(u-PPh.).(C,H,) Ru,(CO), ,(4,-PPh\(C,H,), Ru,(CO).(u-PPh,).(HC.Ph) Kainic acid and Ru,(CO), ,(u,-PPh\(C.Ph,), 251 X-ray crystallographic study of boroxazolidones obtained from Hydride ornithine, L-methionine, kainic acid and 2,6-pyridinedicar P—H bond activation at a tungsten(0) centre: synthesis and charac boxylic acid, 21 terisation of WH(PPh.,)\(dppe),, 195 Ketones Hydridocarbonylchromates Reaktionen von Ph,SbH und p-TolSbH, mit organischen Improved synthesis of KHCr(CO), and comparative coordination Verbindungen, 299 chemistry from KHCr(CO), and KHFe(CO),, 7 Hydridocarbonylferrates Linkage isomers Improved synthesis of KHCr(CO), and comparative coordination Thermally induced endo to exo isomerization in the o-xylylene chemistry from KHCr(CO), and KHFe(CO),, 7 complexes of zerovalent ruthenium and osmium Hydrogenation M(°-C,.Me,){n*-o-(CH.).C,Me,} (M = Ru, Os), 139 Homogeneous hydrogenation of alkynes and of 1,4-cyclohexadiene in the presence of the clusters Ru,(CO),(u-PPh,).(C,.H,) Metal carbonyl! clusters Ru,(CO), ,(a,-PPh\C,H,) Ru,(CO).(u-PPh,).(HC.Ph) Homogeneous hydrogenation of alkynes and of | ,4-cyclohexadiene and Ru,(CO), ,(4,-PPh\(C.Ph,), 251 in the presence of the clusters Ru,(CO)~(y-PPh,).(C,H,), Reaktionen von Ph,SbH und p-TolSbH, mit organischen Ru,(CO), (44-PPh\C,.H,) Ru,(CO).(u-PPh,).(HC,Ph) Verbindungen, 299 and Ru,(CO), ,(4,-PPh\(C.,Ph.), 251 Rhodium COD complexes of mixed donor set tripod ligands Metathesis coordination chemistry and catalysis, 231 Silicrumorganische Dendrimere mit verschiedenen Dendronen, 145 Mixed donor set ligands Synthesis and characterization of ruthenium complexes of | ,8-bis(- Rhodium COD complexes of mixed donor set tripod ligands diphenylphosphinomethyl)naphthalene (BDNA) and their coordination chemistry and catalysis, 231 catalytic hydrogenation reactions to a,f-unsaturated alde Molybdenum complexes hydes, 223 Synthesis, coordination chemistry and polymerfixation of the Hydrogen bonding tripod-ligand HOC,H,CH,C(CH,PPh,),, 281 Rhodium COD complexes of mixed donor set tripod ligands coordination chemistry and catalysis, 231 Nickel carbonyl bipyridine complexes Hydrolytic stability Nickel—bipyridine catalysed electrosynthesis of ketones from or- X-ray crystallographic study of boroxazolidones obtained from ganic halides and carbon monoxide: kinetic and mechanistic L-ornithine, L-methionine, kainic acid and 2,6-pyridinedicar investigations, 37 boxylic acid, 21 Hydrosilylation NMR spectroscopy Trends in the structure and bonding of [MCI,{(C,H,S)ECH,},] Silictumorganische Dendrimere mit verschiedenen Dendronen, 145 (M = Pd, Pt; E= Te, Se), 129 Non-linear optics Imidodiphosphinates Molecules with potential applications for non-linear optics: the Inorganic rings with group 13 organometallics and iminodiphos combination of ferrocene and azulene, 261 phinechalcogenides, 15 Nuclear magnetic resonance Interconversions Substituted cyclopentadienyl compounds. Part V. NMR and ex Thermally induced endo to exo isomerization in the o-xylylene tended Hiickel studies of the isomeric preferences of some complexes of zerovalent ruthenium and osmium main group metal cyclopentadienide compounds and a M(7°-C,.Me,){7*-0-(CH,).C,Me,} (M = Ru, Os), 139 reinvestigation of the crystal structure of thallium(I) tri- Inversion barrier cyanovinylcyclopentadienide, 43 Chiral modifizierte Dicarbonyl(cyclopentadienyl)ferrio-phosphane Synthese und Bestimmung der Inversionsbarriere am Phos- Olefines phido-Phosphor: Ubergangsmetall-substituierte Phosphane, Reaktionen von Ph,SbH und p-TolSbH, mit organischen Arsane und Stibane, 65, 215 Verbindungen, 299 IR and NMR spectroscopy Organic halides carbonylation catalysis Novel redox-active calixarenes, 103 Nickel—bipyridine catalysed electrosynthesis of ketones from or- Iron ganic halides and carbon monoxide: kinetic and mechanistic Insertion of CO and SO, into the N-N bond of [Fe(CO)<u investigations, 37 Ph,N,)], 91 Organoantimonyhydrides Synthesis of doubly-bridged Fe/Se and Fe/Te complexes via reac- Reaktionen von Ph,SbH und p-TolSbH, mit organischen tions of the [MgX] salts of anions [(”-RE)(yp- Verbindungen, 299 CO)Fe,(CO),] (E=Se,Te). Crystal structure of Organosilicon Dendrimers (u-p-MeC,.H,Te)(u-PhC=NPh)Fe(CO),, 55 Silictumorganische Dendrimere mit verschiedenen Dendronen, 145 Iron complexes Oxidation Synthesis, coordination chemistry and polymerfixation of the Dioxirane oxidation of substituted vinylphosphonates: a novel tripod-ligand HOC,H,CH,C(CH,PPh,),, 281 efficient route to 1,2-epoxyalkylphosphonates, 189 Isocyanide insertion B -Oxothioethers Reaction of (a-alkynyl) Group 4 metallocene cation complexes with Mono- and polynuclear complexes from the reaction of palladium alkyl- and arylisocyanides, 83 acetate with a-substituted thioethers and thiols, 115 310 Subjec t index Palladium complex Sandwich compounds Trends in the structure and bonding of [MCI,{(C,H,S)ECH,},] Syntheses, structures and reactivity of 7°-arene-y °-2,3-dihydro-di- (M = Pd, Pt; E= Te, Se), 129 borolyl-rhodium complexes, 107 Palladium complexes Selenium Mono- and polynuclear complexes from the reaction of palladium Inorganic rings with group 13 organometallics and iminodiphos- acetate with a-substituted thioethers and thiols, 115 phinechalcogenides, 15 Synthesis of doubly-bridged Fe/Se and Fe/Te complexes via reac- Phosphide P—H bond activation at a tungsten(0) centre: synthesis and charac- tions of the [MgX]* salts of anions [(u-RE\«- terisation of WH(PPh.,)(dppe),, 195 CO)Fe(CO),] (E = Se,Te) Crystal structure of Phosphido, phosphinidene bridges (u-p-MeC,H,Te)(u-PhC=NPh)Fe,(CO),, 55 Homogeneous hydrogenation of alkynes and of | ,4-cyclohexadiene Trends in the structure and bonding of [MCI,{(C,H,S)ECH,}, in the presence of the clusters Ru,(CO).(u-PPh.).(C,H,), (M = Pd, Pt; E= Te, Se), 129 Silacycloproparenes Ru,(CO), ,(4,-PPh\(C,H,), Ru,(CO),(u-PPh,),(HC,Ph) Molecular and electronic structure of some silacyclopropabenzenes and Ru,(CO), ,(4,-PPh\(C,Ph,), 251 the reversed Mills— Nixon effect, 65 Phosphine ligand Solid state reactions Synthetic and thermochemical studies of reactions of the 16-electron Organometallic chemistry in the solid state, 149 ruthenium complex [(Ph,PNMeNMePPh,),RuCIjBF, with Subinidine H,, CH,CN and CO, 205 Preparation and crystal structures of [u-SbPh,},[Mo(CO).(7°- Phosphine substitution C.H,)],"CHCI1, and SbPh[{[Fe(CO).(7°-C.H,)],, 291 Insertion of CO and SO, into the N-N bond of [Fe,(CO),(y- Styrene Ph,N,)], 91 Thermoregulated phase-transfer ligands and catalysis. Part VI Platinum complex Two-phase hydroformylation of styrene catalyzed by the Trends in the structure and bonding of [MCI,{(C,H,S)ECH,},] thermoregulated phase-transfer catalyst OPGPP/Rh, 201 (M = Pd, Pt; E= Te, Se), 129 Sulfur dioxide insertion P-ligands Insertion of CO and SO, into the N-N bond of [Fe(CO)(y- Improved synthesis of KHCr(CO), and comparative coordination Ph,N,)], 91 chemistry from KHCr(CO), and KHFe(CO),, 7 Sulphur ligand Polymer bound ligands Mono- and polynuclear complexes from the reaction of palladium Synthesis, coordination chemistry and polymerfixation of the acetate with a-substituted thioethers and thiols, 115 tripod-ligand HOC,H,CH,C(CH,PPh,),, 281 Polymerization Tellurium Synthesis and polymerization behavior of tetrahydro-2-methylben- Synthesis of doubly-bridged Fe/Se and Fe/Te complexes via reac- zindenyltitanium and zirconium compounds, 171 tions of the [MgX]* salts of anions [(u-RE\(yz- Primary and secondary phosphane complexes CO)Fe(CO),] (E=Se,Te). Crystal structure of Chiral modifizierte Dicarbonyl(cyclopentadienyl)ferrio-phosphane (u-p-MeC,.H,Te)(u-PhC=NPh)Fe(CO),, 55 Synthese und Bestimmung der Inversionsbarriere am Phos- Trends in the structure and bonding of [MCI,{(C,H,S)ECH;},] phido-Phosphor: Obergangsmetall-substituierte Phosphane, (M = Pd, Pt; E= Te, Se), 129 Arsane und Stibane, 65, 215 Tetrahydro-2-methylbenzindenyltitanium Propargyl alcohol Synthesis and polymerization behavior of tetrahydro-2-methylben- New reactivity of (RC=CCH,OH)Co,(CO), complexes in the Pau- zindenyltitanium and zirconium compounds, 171 son—Khand reaction in the presence of CF,COOH: synthe- TFA sis of methyl substituted cyclopentenones, 183 New reactivity of (RC#=CCH,OH)Co(CO), complexes in the Pau- son—Khand reaction in the presence of CF ,;COOH: synthe- Quinones sis of methyl substituted cyclopentenones, 183 Reductive-alkylation and aromatic coupling reactions of | ,4-benzo- Thermochemistry quinone derivatives promoted by ethylaluminum dichloride, Synthetic and thermochemical studies of reactions of the 16-electron l ruthenium complex [(Ph,PNMeNMePPh,),RuCl]BF, with H,, CH,CN and CO, 205 Thiolate Reduction Mono- and polynuclear complexes from the reaction of palladium Reductive-alkylation and aromatic coupling reactions of | ,4-benzo- acetate with a-substituted thioethers and thiols, 115 quinone derivatives promoted by ethylaluminum dichloride, Titanium l Bis{(7°-cyclooctatetraene)titanium] complex with perpendicularly Reversed Mills—Nixon effect bridging bis(trimethylsilyl)acetylene, 77 Molecular and electronic structure of some silacyclopropabenzenes Triple-decker complexes the reversed Mills—Nixon effect, 65 Syntheses, structures and reactivity of 7°-arene-y °-2,3-dihydro-di- Rhodium COD complexes borolyl-rhodium complexes, 107 Rhodium COD complexes of mixed donor set tripod ligands TRPTC coordination chemistry and catalysis, 231 Thermoregulated phase-transfer ligands and catalysis. Part VI Ruthenium Two-phase hydroformylation of styrene catalyzed by the Synthetic and thermochemical studies of reactions of the 16-electron thermoregulated phase-transfer catalyst OPGPP/Rh, 201 ruthenium complex [(Ph,PNMeNMePPh,),RuCIjBF, with Tungsten H,, CH,CN and CO, 205 P—H bond activation at a tungsten(0) centre: synthesis and charac- Ruthenium complex terisation of WH(PPh,)(dppe),, 195 Synthesis and characterization of ruthenium complexes of 1 ,8-bis(- Two-phase hydroformylation diphenylphosphinomethyl)naphthalene (BDNA) and their Thermoregulated phase-transfer ligands and catalysis. Part VI catalytic hydrogenation reactions to 2,f-unsaturated alde- Two-phase hydroformylation of styrene catalyzed by the hydes, 223 thermoregulated phase-transfer catalyst OPGPP/Rh, 201 Unsaturated complex X-ray single structure analysis Synthetic and thermochemical studieso f reactionso f the | 6-electr or approach to the synthesis of cage-like metallasiloxanes ruthenium complex [(Ph,PNMeNMePPh.).RuCljBF, wit! ri ture H.,, CH,CN and CO, 205 ! s of doubly-bridged Fe/Se and Fe/Te complexes via reac tions of the [MgxX] salts of anions [(”7-RE\(,- Vinylphosphonate CO)Fe(CO) (E = Se,Te) Crystal structure MeC,H, TeX u-PhC-NPh)Fe,(CO) Dioxirane oxidation ed vinylphosphonates efficient route 2-epoxyalkylphosphonates Water-soluble pn sphine € rbocenes( 3) with a short bridge and bulky substituents Thermoregulated -transier ligands and catalysis. Part nthesis and crystal structure of meso-(CH,),Si[3-(CH,) VI. Two-phase hy oformylation of styrene catalyzed by SiC.H,], YbCK THF), rac4(CH,),.C{3-"BuC.H,], Yb(z,-Cl) the thermoregulated phase-transfer catalyst OPGPP/RI Lv OEt,),, and [meso-(CH,),C[3-‘BuC.H,], Yb(z,-OCH,)] UI X-ray crystallography Zirconiur Trends in the str and bonding of L.{(C,H,S)ECH Synthe ind polymerization behavior of tetrahydro-2-methylben r (M = Pd, Pt; F Te, Se) 29 ndenyltitanium and zirconium compounds 171