Table Of Content

sa) ELSEVIER Volume 567, Numbers 1-2, 15 September 1998 Contents Special Issue: GEOM CONCOORD ’97 I 5 ee ging oie eck Oe ee wee ie aoa eS 0s Bee Rik, ee 4 ee Oe FAO OF LE we we ae ee New screening methodologies or combinatorial chemistry applied to asymmetric catalysts EE coe Se he ae oes CES Oe AOE RE RDM E DEORE OWLS CCE LS £8 6 EE DEES eS. ee eS 3 New types of hydrogen bonds rr re, 8 8 ad web 6 6 6 8 6S 6 666-8 0 hw ak b Obie Ow Oe eee be eS 7 Complexation on rhodium of bidentate and potentially hemilabile phosphorous ligands I. Le Gall, P. Laurent, E. Soulier, J.-Y. Salatin and H. des AbDayes . 0. ccc cee ee eee cere rete wee eee 13 Stereoselective synthesis of y-aminoallyltins from vinyltin acetals a hee dar le OR we See wlO e Boe 60'S 2 0 ee are Oe 8 8 Slee ee 21 Electron transfer catalysis of the hydrogenolysis of acyl dicarbonyl cyclopentadienyliron complexes by tributyltin hydride ES rr eee ee re re ee ee ee ee ee ae ee 25 Hydroboration—azide alkylation as efficient tandem reactions for the synthesis of chiral non racemic substituted pyrrolidines ee 0 aa Sle eke ee EE A AT ek OEE a ee bbc Wee Uheee a are eLalars 31 Organosamariums: preparation using diiodosamarium and reactivity in tetrahydropyran PP PE a) Cee PRET TEP OUR TES PECL TOT Cee 39 Extension of the Heck reaction to the arylation of activated thiophenes L. Lavenot, C. Gozzi, K. lig, I. Orlova, V. Penalva and M. Lemaire. . 0... te tcc tee ee ewe ee teens 49 Activation and regioselective ortho-functionalization of phenols promoted by ‘Cp*lIr’ fragment: synthesis, structures and applications to organic synthesis. Cp* = C;Me, ee a "a en a ke ele wale ee’ b ace ee. ecco en woe ee eae ee 57 Cyclomanganated (7 °-arene)tricarbonylchromium complexes: synthesis and reactivity ee as i a a ae bale han oe kN BG Ande 8 Oa aid pee we ee oe eee ees 65 New chiral rhenium complexes of unsaturated alcohols: preparation and reactivity i ees, So, Ses ea I IO, GE ne. 5 os eet + ak ee 6k we ee eee oe oe ee eR ole eee Oem 75 Reaction of aminocarbene complexes of chromium with alkynes 10. From large to small cyclic amines: single versus double alkyne insertions S. Lafollée-Bezzenine, A. Parlier, H. Rudler, J. Vaissermann and J.-C. Daran.....00..00. .ee.e .ee.e e0ee. e0ee 83 Reaction of aminocarbene complexes of chromium with alkynes 9. From nitrogen ylid complexes toward alkaloid frameworks i, Es eis SOU, Sec ew ig © 0 Pea BOO ok 6 Hk Oe A Ow 6 EE wee e are bk ae ak 101 Interaction of dihydropyridines with alkoxycarbene complexes of tungsten: formation and use as cyclopropanation reagents of pyridinium ylid complexes B. Martin-Vaca, H. Rudler, M. Audouin, M. Nicolas, T. Durand-Réville and B. Vissiére................20000000s 119 Synthesis of borylindenides; structure of [Li(N,N’,N”-Me,-1,3,5-C;H,N;)][l-C,.H,{B(NMe;,),}] eee. Se: ee I SD a 3, See es we ule le és we EG S400 dS dee baa’ Salar e ex 127 Optically active nitrogen ligands in asymmetric catalysis. Effect of nitrogen substitution on the enantioselective hydride transfer reduction of acetophenone a F. Touchard, M. Bernard, F. Fache, F. Delbecq, V. Guiral, P. Sautet and M. Lemaire .................2..2.2000005 Contents New synthesis of the nanobuilding block {(BuSn),,0,,(OH),}*a*n d exchange properties of {(BuSn),,0,,(OH),}(O,SC,H,CH;), eg 4-6 6 bk- 6 4k o Oe 6 a we Se 4 6 Ose e SOR eS ee Oe ee wa bee eee shan eee 137 New reactors and methods for the investigation of homogeneous catalysis eg a ee le aw a b- e R e O eret OS a Oe a ew Me ew hee ere 143 Titanocene and zirconocene complexes in phosphinine chemistry a anid ee. Alec why Oa We A be be ee ee ae eee ae ee 151 Stereochemistry in palladium- and nickel-catalyzed addition of phenylmagnesium bromide to unsaturated carbohydrates Oelle Sw Rie a ie Be See ere eee ec Aa eae aa 8-0 eb 08 157 Enantioselective ruthenium-mediated hydrogenation: developments and applications EE SE ee ee ee ee ee ae ee re eae ee 163 Synthesis of enynes and epoxyenynes by coupling: use of a new set of catalysts based on Pd—Ag salts I lr eh Sost ule dhe ve GENS pei ek Akg. Snee NCS: -08 Oe Bn le aa Oe oR a ane 6 S08: oe! © eae 173 Newly designed acylsilanes as versatile tools in organic synthesis B.F. Bonini, M. Comes-Franchini, M. Fochi, G. Mazzanti and A. Ricci... . 2... 2. ee ee ee es 181 Selective synthesis of ferrocenes G.G.A. Balavoine, J.-C. Daran, G. Iftime, E. Manoury and C. Moreau-Bossuet......00.0.0.0 ..e.ee.ee.e.ae 191 Chiral phosphorus(III) triflates. On the nature of the phosphorus—oxygen interaction ee ee eG, OUD OTUIE GE LE, EIS bc 6c ec Se eh ee eee ee hee eee ea ewe eee ewes 199 Mono and diphosphine borane complexes grafted on polypyrrole matrix: direct use as supported ligands for Rh and Pd catalysis ee 6 ek ed 6 o-w & 66 we SCO Te OOD AR A Oa OS oe RA ee ee oe 219 I ry. eS me Se ge Ea aids iat ited Se ee ake Be SO ee OW ROO ey ee eae ee eb kas 235 i i a i gna Tei ik ti BOG Wk lp eS Sra tke ee Ma ke RO LGN Re Ct ace 0 wee 237 The publisher encourages the submission of articles in electronic form thus saving time and avoiding rekeying errors. A leaflet describing our requirements is available from the publisher upon request.