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Journal of Organometallic Chemistry 1998: Vol 560 Index PDF

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of rear metallic Chemistry Journal of Organometallic Chemistry 560 (1998) 275 Author index of Volume 560 Abhyankar, R.M., 131 Khorshev, S.Y., 21 Ramaswamy, K., 131 Abu-Orabi, S., 69 Kokubo, K., 217 Ramondo, F., 183 Agarwala, U.C., 35 Kowalewska, A., 41 Reina, R., 147 Alt, H.G., 69 Kropotova, V.Y., 21 Rickard, C.E., 197 Romao, C.C., 117 Antonaroli, S., 137 Kihn, F.E., 117 Roshchin, A.I1., 163 Arimitsu, K., 253 Rossell, O., 147 Author, A., 273, 275, 277 Lewinski, J., 89 Licht, E.H., 69 Baker, P.K., 191 Saak, W., 125 Li, X.-W., 211 Balakrishna, M.S., 131 Sahay, A.N., 35 Lopes, A.D., 117 Barclay, T., 155 Schenk, W.A., 257 Lorberth, J., 211 Schoell, N.J., 15 Beddoes, R.L., 265 Schollhammer, P., 245 Bengali, A.A., 55 Mackie, S.C., 63 Seco, M., 147 Berry, S.W., 63 Mahon, M.F., 95 Sharma, P., 35 Bochkarev, L.N., 21 Mai, J.-F., 223 Singh Sisodia, O., 35 Bumagin, N.A., 163 Mansilla, N., 27 Singh, Y., 197 Cabrera, A., 35 Martinez-Cruz, L.A., 27 Sotomayor, J., 117 Chihara, T., 47 Massa, W., 211 Soum, A., 109 Cole, S., 55 Matsumasa, K., 217 Stanczyk, W., 41 Cordes, W., 155 Matsumoto, A., 47 Stilter, A., 125 Crociani, B., 137 Meehan, M.M., 191 Stubbe, M., 257 Suzuki, N., 47 Mesubi, M.A., 95 DeGrace, S.A., 63 Milius, W., 69 Szepes, L., 7 Delgado, E., 27 Mingotaud, A.-F., 109 Sztaray, B., 7 de Montauzon, D., 147 Mise, T., 47 Devaud, M., 103 Talarmin, J., 245 Miura, M., 217 Dinger, M.B., 169, 233 Tani, K., 253 Molloy, K.C., 95 Domenicano, A., 183 Thomas, S., | Moloney, M.G., 77 Thompson, R.M., 77 Drew, M.G., 191 Moorcroft, D., 265 Tiekink, E.R., 1 Dulaney, K.E., 55 Muir, K.W., 245 Tornero, J., 27 Eaborn, C., 41 Torres, R., 27 Ebert, K.H., 211 Nédelec, J.Y., 103 Toscano, A., 35 Nicholson, B.K., 169 T. Robinson, W., 169 Ferrer, M., 147 Nikitinsky, A.V., 21 Troupel, M., 103 Fukin, G.K., 21 Nomura, M., 217 N. Zakharov, L., 21 Ueda, K., 253 Garcia, M.A., 27 Underhill, A.E., 191 Goncalves, I.S., 117 Ogafrain, M., 103 Gupta, B.D., 155 Vass, G., 7 Ohmori, H., 47 von Schnering, H.G., 125 Hagel, M., 257 Omotowa, B.A., 95 Hanusa, T.P., 15 Orlov, N.A., 21 Wakatsuki, Y., 47 Hargittai*,, I., 183 Overby, J.S., 15 Weidenbruch, M., 125 Henderson, W., 169, 233 Whiteley, M.W., 265 Hernandez, E., 27 Pandey, D.S., 35 Wocadlo, S., 211 Héroguez, V., 109 Parker, E.E., 191 Woodgate, P.D., 197 Hinchliffe, J.R., 265 Parola, A.J., 117 Wright, E., 77 Paul, D.R., 77 Ikegami, Y., 47 Peters, K., 125 Yamagata, T., 253 Pétillon*,, F.Y., 245 Yamaguchi, Y., 47 Jha, N.K., 35 Pina, F., 117 Yamamoto, Y., 223 Julia, A., 147 Portalone, G., 183 Young, C.G., | Kataoka, Y., 253 Kel’chevski, S.M., 163 Qanungo, K., 155 Zachara, J., 89 Elsevier Science S.A. ournal O metallic Chemistry Journal of Organometallic Chemistry 560 (1998) 277-281 Subject index of Volume 560 Ab initio MO calculations Arsine Molecular structure of phenylsilane: a study by gas-phase electron Synthesis and characterization of some arene hydrido-complexes diffraction and ab initio molecular orbital calculations, 183 [Ru(7°-arene)(EPh,),H]* (y°-arene= benzene, p-cymene Acylpyrazol-5-one derivatives or hexamethylbenzene; E = P, As or Sb). Crystal structure Triphenylantimony(V) derivatives of acylpyrazol-5-ones, 95 of [Ru(7°-C,H,)(PPh;),H]BF,, 35 Aggregate Azido ligand Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of A dimolybdenum(III) azido compound: its decomposition into the nonametallic gold(III)-silver(1)-sulfido aggregates amido and nitrido derivatives. Crystal structure of [{LAu(u-S),AuL},Ag,X,] * (L=cycloaurated JN,N- [Mo,(O)/N)Cp,(SMe),], 245 dimethylbenzylamine ligand; X = Cl, Br), by thiourea desul- furisation, 169 Benzofuranes Alkene complexes Synthesis of benzofurans via Pd? * -catalyzed oxidative cyclization Preparation and reactions of palladium(0)—olefin complexes with of 2-allylphenols, 163 iminophosphine ligands, 137 Bi—Bi bond Alkenes Synthesis and crystal structure of tetrakis(2,4,6-trimethylphenyl) Rhodium-catalyzed reaction of aroyl chlorides with alkynes or dibismuthoxide, 211 alkenes in the presence of disilanes, 217 Bidentate Alkynes Transition metal chemistry of phosphorus based ligands. Rutheni- Rhodium-catalyzed reaction of aroyl chlorides with alkynes or um(II) chemistry of bis(phosphino)amines, X,PN(R)PX, alkenes in the presence of disilanes, 217 (R =H or Ph, X = Ph; R = Ph, X, = O,C,H,), 131 Allyl Bis(oxime)complexes Reactions of the cycloheptatrienyl complexes [MX(CO),(7-C,;H,)] Steric cis influence and lateral compression of the metallabicycle in (M = Mo, X = Br; M = W, X = I) with CNBu’: X-ray crys- bis(dioxime) vitamin B,, models, 155 tal structure of [WI(CO),(CNBu’),(y?-C,H,)], 265 Bis(phosphino)amines 2-Allylphenols Transition metal chemistry of phosphorus based ligands. Rutheni- Synthesis of benzofurans via Pd? * -catalyzed oxidative cyclization um(II) chemistry of bis(phosphino)amines, X,PN(R)PX, of 2-allylphenols, 163 (R =H or Ph, X = Ph; R = Ph, X, = O,C,H,), 131 Aluminium Bond angle Structure characterisation of the organoaluminium intermediate Synthesis and crystal structure of tetrakis(2,4,6-trimethylphenyl) resulting from the alkylation of a chelated carbonyl group. dibismuthoxide, 211 Molecular structure of the trinuclear [MeAI][C,,H )04] Bond distance {[AlMe,], compound, 89 Synthesis and crystal structure of tetrakis(2,4,6-trimethylphenyl) Amido ligand dibismuthoxide, 211 A dimolybdenum(III) azido compound: its decomposition into Borasiloxanes amido and nitrido derivatives. Crystal structure of Synthesis of difunctional borasiloxanes and their behavior in metathesis reactions, 109 [Mo,(O)(N)Cp;(SMe),], 245 Anchimeric assistance 1,3-Migration of a phenyl group in the conversion of (Me,Si), Carbon monoxide (PhMe,Si)CSiMePhX into (Me,Si),(Ph,MeSi)CSiMe,Y Electrochemical generation of a nickel—carbonyl complex, catalyst species, 41 for the electroreductive coupling of organic halides and Antimony carbon monoxide into ketones, 103 Triphenylantimony(V) derivatives of acylpyrazol-5-ones, 95 Carbonyl Arene hydrido complexes Synthesis and diastereoselective functionalisation of tricar- Synthesis and characterization of some arene hydrido-complexes bonyl[(3a,7a)-octahydro-3-substituted-2-(7 °-phenyl)benzo- [Ru(7°-arene)(EPh,),H]* (°-arene= benzene, p-cymene xazole]Jchromium(0) complexes, 197 or hexamethylbenzene; E = P, As or Sb). Crystal structure Carbonyl alkylation of [Ru(7°-C,H,)(PPh;),H]BF,., 35 Structure characterisation of the organoaluminium intermediate (7 6-Arene)ruthenium resulting from the alkylation of a chelated carbonyl group. Preparations and structures of (7°-arene)ruthenium(II) complexes Molecular structure of the trinuclear [MeAI][C,>9»0H4 ] bearing 1,1’-bis(diphenylphosphinomethyl)ferrocene or 1,1’- [AlMe,], compound, 89 bis(diphenylphosphino)ferrocene, 223 Carbonylation catalysis Aroyl chrolides Electrochemical generation of a nickel—carbonyl complex, catalyst Rhodium-catalyzed reaction of aroyl chlorides with alkynes or for the electroreductive coupling of organic halides and alkenes in the presence of disilanes, 217 carbon monoxide into ketones, 103 Elsevier Science S.A. 278 Subject index Catalysis Crystal structures Ligand exchange and catalysis in phenylation reactions mediated An octahedral stannylmanganese stannylene complex, 125 by lead tetracarboxylates, 77 Cyanide bridges Synthesis of benzofurans via Pd? * -catalyzed oxidative cyclization Synthesis and characterization of binuclear transition metal—rhe- of 2-allylphenols, 163 nium(VII) complexes with bridging cyanide ligands, 117 Cationic Cyclocarboborasiloxanes Reductive dimerization of dialkyl acetylenedicarboxylate cata- Synthesis of difunctional borasiloxanes and their behavior in lyzed by [Rh(binap)(MeOH),]CIO, in methanol, 253 metathesis reactions, 109 Transition metal chemistry of phosphorus based ligands. Rutheni- Cycloheptatrienyl um(II) chemistry of bis(phosphino)amines, X,PN(R)PX, Reactions of the cycloheptatrienyl complexes [MX(CO),(7-C,H,)] (R =H or Ph, X = Ph; R = Ph, X, = O,C,H,), 131 (M = Mo, X = Br; M = W, X = I) with CNBu‘: X-ray crys- CC activation tal structure of [WI(CO),(CNBu’),(7°-C,H,)], 265 Reduction reactions of the metallocene complex (y°- Cyclooctatetraene C;H,CMe,C,H,),ZrCl,, 69 Photoelectron spectroscopy of mono and binuclear iron and CH activation chromium cyclooctatetraene complexes, 7 Reduction reactions of the metallocene complex (°- Cyclopentadienyl C;H,CMe,C,H,),ZrCl,, 69 A dimolybdenum(III) azido compound: its decomposition into Chiral auxiliaries amido and nitrido derivatives. Crystal structure of Enantioselective organic syntheses using chiral transition metal [Mo,(O)(N)Cp;(SMe),], 245 complexes V. (2S,3S)-Bis(dibenzophospholyl)butane, a Synthesis and characterization of oxo- and thiophosphorylcy- rigid (S,S)-CHIRAPHOS analog, 257 clopentadienyl Ti(IV) thiolate complexes. Crystal struc- Chromium tures of [(y°-C;H,P(S)Ph,)(y°-C;H,SiMe,)TiCl,] and Synthesis and characterization of chromocenes containing bulky [((y°-CH,P(S)Ph,),Ti(SPh),]-C,H,,O, 27 cyclopentadienyl ligands, 15 Synthesis and diastereoselective functionalisation of tricarbonyl Desulfurisation {(3a,7a)-octahydro-3-substituted-2-(7 °-phenyl)benzoxazole] Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of chromium(0) complexes, 197 the nonametallic gold(III)-silver(I)-sulfido aggregates Chromocenes [{LAu(u-S),AuL} ,Ag,X,] * (L = cycloaurated N,N- Synthesis and characterization of chromocenes containing bulky dimethylbenzylamine ligand; X=Cl, Br), by thiourea cyclopentadienyl ligands, 15 desulfurisation, 169 Cis- influences Di- and trimolybdenum complex Steric cis influence and lateral compression of the metallabicycle A dimolybdenum(III) azido compound: its decomposition into in bis(dioxime) vitamin B,, models, 155 amido and nitrido derivatives. Crystal structure of Clusters [Mo,(O)(N)Cp;(SMe),], 245 Synthesis, characterization and electrochemical studies of the het- Dicarbonyl erometallic diclusters [{Fe(u“-CO)(CO),(u-PPh,)Au}.,(di- Dicarbonyl dithio ligand complexes of tungsten(I]), | phosphine)] (diphosphine = dppm, dppip, dppe, dppp), 147 Dicarbonylcyclopentadienyl(2-oxopropyl)iron(I1) Conformational dynamics The conformational dynamics of dicarbonylcyclopentadienyl(2- The conformational dynamics of dicarbonylcyclopentadienyl(2- oxopropyl)iron(II): An infrared and molecular mechanics oxopropyl)iron(II): An infrared and molecular mechanics study, 63 study, 63 Dimerization Copper Reductive dimerization of dialkyl acetylenedicarboxylate cata- Synthesis of germylcopper compounds by hydride method. Crys- lyzed by [Rh(binap)(MeOH),]CIO, in methanol, 253 tal structure of (C.F ;),GeCu(PPh,),, 21 Diphosphine Crystal structure Synthesis, characterization and electrochemical studies of the het- A dimolybdenum(III) azido compound: its decomposition into erometallic diclusters [{Fe(u-CO)(CO),.(u- amido and nitrido derivatives. Crystal structure of [Mo,(O) PPh,)Au}.,(diphosphine)] (diphosphine=dppm, dppip, (N)Cp;(SMe),], 245 dppe, dppp), 147 Dicarbonyl dithio ligand complexes of tungsten(II), | Disilanes Organogold(III) metallacyclic chemistry. Part 4. Synthesis, char- Rhodium-catalyzed reaction of aroyl chlorides with alkynes or acterisation, and biological activity of gold(III)-thiosalicy- alkenes in the presence of disilanes, 217 late and -salicylate complexes, 233 Dithio ligand Seven-coordinate thiophene-3-acetonitrile complexes of tung- Dicarbony! dithio ligand complexes of tungsten(II), | sten(II). Crystal structures of [WI,(CO),{NCCH,(3- Dpmf—Ru complexes C,H,S)},] and [WI,(CO),{NCCH,(3-C,H,S)}(AsPh,)], 191 Preparations and structures of (7°-arene)ruthenium(II) complexes Structure characterisation of the organoaluminium intermediate bearing _1,1’-bis(diphenylphosphinomethyl)ferrocene — or resulting from the alkylation of a chelated carbonyl group. 1,1’-bis(diphenylphosphino)ferrocene, 223 Molecular structure of the trinuclear [MeAI][C,>>9 H04 ] Dppf—Ru complexes [AlMe,], compound, 89 Preparations and structures of (7 °-arene)ruthenium(II) complexes Synthesis and characterization of chromocenes containing bulky bearing —_1,1’-bis(diphenylphosphinomethyl)ferrocene — or cyclopentadienyl ligands, 15 1,1’-bis(diphenylphosphino)ferrocene, 223 Synthesis and crystal structure of tetrakis(2,4,6-trimethylphenyl) dibismuthoxide, 211 Electrochemistry Synthesis and diastereoselective functionalisation of tricar- Preparations and structures of (7°-arene)ruthenium(II) complexes bonyl{(3a,7a)-octahydro-3-substituted-2-(7 °-phenyl)benzo- bearing —_1,1’-bis(diphenylphosphinomethyl)ferrocene — or xazolejchromium(0) complexes, 197 1,1’-bis(diphenylphosphino)ferrocene, 223 Subject index 279 Electroreduction Isocyanide Electrochemical generation of a nickel—carbonyl complex, catalyst Reactions of the cycloheptatrienyl complexes [MX(CO).,(7-C,H,)] for the electroreductive coupling of organic halides and (M = Mo, X = Br; M = W, X = I) with CNBu’: X-ray crys- carbon monoxide into ketones, 103 tal structure of [WI(CO),(CNBu’),(7°-C,H,)], 265 Electrospray Organogold(III) metallacyclic chemistry. Part 4. Synthesis, char- Laser flash photolysis acterisation, and biological activity of gold(III)-thiosalicy- A kinetic and spectroscopic study of the interaction between a late and -salicylate complexes, 233 M(CO),; (M = Cr, W) fragment and ethyl diazoacetate, 55 Electrospray mass spectrometry Lead(IV) Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of Ligand exchange and catalysis in phenylation reactions mediated the nonametallic gold(III)-silver(I)-sulfido aggregates by lead tetracarboxylates, 77 [{LAu(u-S),AuL},Ag,X,] * (L = cycloaurated N,N- Ligand dimethylbenzylamine ligand; X=Cl, Br), by thiourea A kinetic and spectroscopic study of the interaction between a M(CO),; (M = Cr, W) fragment and ethyl diazoacetate, 55 desulfurisation, 169 Ligand modification Fe/Re binuclear complexes Ligand exchange and catalysis in phenylation reactions mediated by lead tetracarboxylates, 77 Synthesis and characterization of binuclear transition metal—rhe- nium(VII) complexes with bridging cyanide ligands, 117 FT-IR Manganese An octahedral stannylmanganese stannylene complex, 125 The conformational dynamics of dicarbonylcyclopentadienyl(2- Mercury(II) oxopropyl)iron(II): An infrared and molecular mechanics Ligand exchange and catalysis in phenylation reactions mediated study, 63 by lead tetracarboxylates, 77 Metallacycle Gas-phase electron diffraction Organogold(III) metallacyclic chemistry. Part 4. Synthesis, char- Molecular structure of phenylsilane: a study by gas-phase electron acterisation, and biological activity of gold(III)-thiosalicy- diffraction and ab initio molecular orbital calculations, 183 late and -salicylate complexes, 233 Germanium Metallocene complexes Synthesis of germylcopper compounds by hydride method. Crys- Reduction reactions of the metallocene complex (y°- tal structure of (C,F;),GeCu(PPh,),, 21 C;H,CMe,C,H,),ZrCl,, 69 Gold Metallocenes Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of Synthesis and characterization of chromocenes containing bulky the nonametallic gold(III)-silver(I)-sulfido aggregates cyclopentadienyl ligands, 15 [{LAu(z-S),AuL} ,Ag,X,]* (L=cycloaurated N,N- Molecular mechanics dimethylbenzylamine ligand; X=Cl, Br), by thiourea The conformational dynamics of dicarbonylcyclopentadienyl(2- desulfurisation, 169 oxopropyl)iron(II): An infrared and molecular mechanics Organogold(III) metallacyclic chemistry. Part 4. Synthesis, char- study, 63 acterisation, and biological activity of gold(III)-thiosalicy- Molecular structure late and -salicylate complexes, 233 Molecular structure of phenylsilane: a study by gas-phase electron diffraction and ab initio molecular orbital calculations, 183 Hapticity Molybdenum Reactions of the cycloheptatrienyl complexes [MX(CO),(4-C,H,)] Reactions of the cycloheptatrienyl complexes [MX(CO),(7-C,H,)] (M = Mo, X = Br; M = W, X = I) with CNBu’: X-ray crys- (M = Mo, X = Br; M = W, X = I) with CNBu’: X-ray crys- tal structure of [WI(CO),(CNBu’),(7?-C,H,)], 265 tal structure of [WI(CO),(CNBu’),(?-C,H,)], 265 Heterometallic Mono and binuclear complexes Synthesis, characterization and electrochemical studies of the het- Photoelectron spectroscopy of mono and binuclear iron and erometallic diclusters [{Fe (4-CO)(CO),(u-PPh,)A,u(}di - chromium cyclooctatetraene complexes, 7 phosphine)] (diphosphine = dppm, dppip, dppe, dppp), 147 Monodentate 1-Hexene Transition metal chemistry of phosphorus based ligands. Rutheni- Structural characterization of ansa-zirconocene dichloride bearing um(II) chemistry of bis(phosphino)amines, X,PN(R)PX, a vicinal di-tert-butylcyclopentadienyl ligand and high (R =H or Ph, X = Ph; R = Ph, X, = O,C,H,), 131 pressure polymerization of 1-hexene catalyzed by sterically Mononuclear hindered zirconocene complexes, 47 Transition metal chemistry of phosphorus based ligands. Rutheni- High pressure um(II) chemistry of bis(phosphino)amines, X,PN(R)PX, Structural characterization of ansa-zirconocene dichloride bearing (R =H or Ph, X = Ph; R = Ph, X, = O,C,H,), 131 a vicinal di-tert-butylcyclopentadienyl ligand and high Mo/Re binuclear complexes pressure polymerization of 1-hexene catalyzed by sterically Synthesis and characterization of binuclear transition metal—rhe- hindered zirconocene complexes, 47 nium(VII) complexes with bridging cyanide ligands, 117 Hydride method Synthesis of germylcopper compounds by hydride method. Crys- Nickel—bipyridine complexes tal structure of (C,F;),GeCu(PPh,),, 21 Electrochemical generation of a nickel-carbonyl complex, catalyst for the electroreductive coupling of organic halides and Iron carbon monoxide into ketones, 103 An octahedral stannylmanganese stannylene complex, 125 Nitrido ligand Isocoumarines A dimolybdenum(II]) azido compound: its decomposition into Synthesis of benzofurans via Pd? * -catalyzed oxidative cyclization amido and nitrido derivatives. Crystal structure of of 2-allylphenols, 163 [Mo,(O)(N)Cp;(SMe),], 245 280 Subject index Olefin polymerization Ring-closing metathesis Structural characterization of ansa-zirconocene dichloride bearing Synthesis of difunctional borasiloxanes and their behavior in a vicinal di-tert-butylcyclopentadienyl ligand and high metathesis reactions, 109 pressure polymerization of 1-hexene catalyzed by sterically Ruthenium hindered zirconocene complexes, 47 Enantioselective organic syntheses using chiral transition metal Olefin rotation complexes V. (25S,3S)-Bis(dibenzophospholyl)butane, a Preparation and reactions of palladium(0)—olefin complexes with rigid (S,S)-CHIRAPHOS analog, 257 iminophosphine ligands, 137 Synthesis and characterization of some arene hydrido-complexes Organosilanes [Ru(7°-arene)(EPh,),H]* (°-arene = benzene, p-cymene 1,3-Migration of a phenyl group in the conversion of (Me,Si), or hexamethylbenzene; E = P, As or Sb). Crystal structure (PhMe,Si)CSiMePhX into (Me,Si),(Ph,MeSi)CSiMe,Y of [Ru(7°-C,H,)(PPh,;),H]BF,, 35 species, 41 Ruthenium(I]) complexes Oxidation addition Transition metal chemistry of phosphorus based ligands. Rutheni- Preparation and reactions of palladium(0)—olefin complexes with um(II) chemistry of bis(phosphino)amines, X,PN(R)PX, iminophosphine ligands, 137 (R =H or Ph, X = Ph; R = Ph, X, = O,C,H,), 131 Salicylate Palladium Organogold(III) metallacyclic chemistry. Part 4. Synthesis, char- Preparation and reactions of palladium(0)—olefin complexes with acterisation, and biological activity of gold(III)-thiosalicy- iminophosphine ligands, 137 late and -salicylate complexes, 233 Palladium(I1) Seven-coordinate Synthesis of benzofurans via Pd? * -catalyzed oxidative cyclization Seven-coordinate thiophene-3-acetonitrile complexes of tung- of 2-allylphenols, 163 sten(II). Crystal structures of [WI,(CO),{NCCH,(3- Pentacarbonyl fragment C,H,S)},] and [WI,(CO), {N CCH,(3-C,H,S)}(AsPh,)], 191 A kinetic and spectroscopic study of the interaction between a Silicon M(CO), (M = Cr, W) fragment and ethyl diazoacetate, 55 Molecular structure of phenylsilane: a study by gas-phase electron Phenylation diffraction and ab initio molecular orbital calculations, 183 Ligand exchange and catalysis in phenylation reactions mediated Silver by lead tetracarboxylates, 77 Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of 1,3-phenyl migration the nonametallic gold(III)-silver(I)-sulfido aggregates 1,3-Migration of a phenyl group in the conversion of (Me,Si), [{LAu(uz-S),AuL},Ag,X,]* (L = cycloaurated N,N- (PhMe,Si)CSiMePhX into (Me,Si).(Ph,MeSi)CSiMe,Y dimethylbenzyiamine ligand; X=Cl, Br), by thiourea species, 41 desulfurisation, 169 Phenylsilane Stannylene Molecular structure of phenylsilane: a study by gas-phase electron An octahedral stannylmanganese stannylene complex, 125 diffraction and ab initio molecular orbital calculations, 183 Stereoselection Phosphine Synthesis and diastereoselective functionalisation of tricarbonyl Synthesis and characterization of some arene hydrido-complexes [(3a,7a)-octahydro-3-substituted-2-( °-phenyl)benzoxazole] [Ru(7°-arene(EPh,),H]* (7°-ar= ebennzeene , p-cymene chromium(0) complexes, 197 or hexamethylbenzene; E = P, As or Sb). Crystal structure Stibine of [Ru(7°-C,H,)(PPh,),H]BF,, 35 Synthesis and characterization of some arene hydrido-complexes Phosphine ligands [Ru(7°-arene)(EPh,),H]* (°-arene = benzene, p-cymene Enantioselective organic syntheses using chiral transition metal or hexamethylbenzene; E = P, As or Sb). Crystal structure complexes V. (25S,3S)-Bis(dibenzophospholyl)butane, a of [Ru(7°-C,H,)(PPh,;),H]BF,, 35 rigid (S,S)-CHIRAPHOS analog, 257 Sulfide Phospholes Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of Enantioselective organic syntheses using chiral transition metal the nonametallic gold(III)-silver(I)-sulfido aggregates complexes V. (25S,3S)-Bis(dibenzophospholyl)butane, a [{LAu(u-S),AuL} ,Ag,X,] * (L=cycloaurated JN,N- rigid (S,S)-CHIRAPHOS analog, 257 dimethylbenzylamine ligand; X=Cl, Br), by thiourea Photoelectron spectroscopy desulfurisation, 169 Photoelectron spectroscopy of mono and binuclear iron and chromium cyclooctatetraene complexes, 7 tert-Butyl group Pyrazolylborate Structural characterization of ansa-zirconocene dichloride bearing Dicarbonyl dithio ligand complexes of tungsten(II), 1 a vicinal di-tert-butylcyclopentadienyl ligand and high pressure polymerization of 1-hexene catalyzed by sterically Reaction mechanism hindered zirconocene complexes, 47 1,3-Migration of a phenyl group in the conversion of (Me,Si), Tetrakis(2,4,6,-trimethylphenyl)dibismuth (PhMe,Si)CSiMePhX into (Me,Si),(Ph,MeSi)CSiMe,Y Synthesis and crystal structure of tetrakis(2,4,6-trimethylphenyl) species, 41 dibismuthoxide, 211 Re(VII) oxides Thiolate Synthesis and characterization of binuclear transition metal—rhe- Synthesis and characterization of oxo- and thiophosphorylcy- nium(VII) complexes with bridging cyanide ligands, 117 clopentadienyl Ti(IV) thiolate complexes. Crystal struc- Rhodium tures of [(7°-C;H,P(S)Ph,)(y°-C;H,SiMe,)TiCl,] and Reductive dimerization of dialkyl acetylenedicarboxylate cata- [(7°-C;H,P(S)Ph,),Ti(SPh),]-C,H oO, 27 lyzed by [Rh(binap)(MeOH),]CIO, in methanol, 253 Thiolato-bridged complexes Rhodium catalyst A dimolybdenum(III) azido compound: its decomposition into Rhodium-catalyzed reaction of aroyl chlorides with alkynes or amido and nitrido derivatives. Crystal structure of [Mo,(O) alkenes in the presence of disilanes, 217 (N)Cp;(SMe),], 245 Subject index 281 Thiophene-3-acetonitrile Reactions of the cycloheptatrienyl complexes [MX(CO),(7-C,H,)] Seven-coordinate thiophene-3-acetonitrile complexes of tung- (M = Mo, X = Br; M = W, X = 1) with CNBu’: X-ray crys- tal structure of [WI(CO),(CNBu’),(7°-C,H,)], 265 sten(I]). Crystal structures of [WI,(CO),{NCCH, (3-C,H,S)},] and [WI,(CO),{NCCH,(3-C,H,S)}(AsPh,)], Tungsten(II) Seven-coordinate thiophene-3-acetonitrile complexes of tung- 19] sten(I]). Crystal structures of [WI,(CO),{NCCH,(3- Thiosalicylate C,H,S)}.,] and [WI{, NCC(H,(3C-C,HO,S))}(As,Ph,) ], 191 Organogold(III) metallacyclic chemistry. Part 4. Synthesis, char- acterisation, and biological activity of gold(III)-thiosalicy- Vitamin B,, model late and -salicylate complexes, 233 Steric cis influence and lateral compression of the metallabicycle Thiourea in bis(dioxime) vitamin B,, models, 155 Organogold(III) Metallacyclic Chemistry. Part 3. Self-assembly of the nonametallic gold(III)-silver(1)-sulfido aggregates X-ray [{LAu(u-S),AuL},Ag,X,]* (L=cycloaurated WN,N- Triphenylantimony(V) derivatives of acylpyrazol-5-ones, 95 dimethylbenzylamine ligand; X=Cl, Br), by thiourea X-ray diffraction desulfurisation, 169 Synthesis of germylcopper compounds by hydride method. Crys- tal structure of (C,F;),GeCu(PPh,),, 21 Titanium Synthesis and characterization of oxo- and thiophosphorylcy- Zirconium clopentadienyl Ti(IV) thiolate complexes. Crystal struc- Reduction reactions of the metallocene complex (7°-C;H,CMe, tures of [(y°-C;H,P(S)Ph,)(y°-C;H,SiMe,)TiCl,] and C,H,),ZrCl,, 69 [(7°-C;H,P(S)Ph,),Ti(SPh),]-C,H,0 , 27 Zirconocene Triphenylantimony Structural characterization of ansa-zirconocene dichloride bearing Triphenylantimony(V) derivatives of acylpyrazol-5-ones, 95 a vicinal di-fert-butylcyclopentadienyl ligand and high Tungsten pressure polymerization of 1-hexene catalyzed by sterically Dicarbonyl dithio ligand complexes of tungsten(II), | hindered zirconocene complexes, 47

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