Table Of Content

Oe metallic Chemistry LSEVIE Journal of Organometallic Chemistry 553 (1998) 525-526 Author Index of Volume 553 A-ihara, N.-a., 493 Farfan, N., 221 Kreibl, F.R., 103 Abrahams, I., 23 Fischer, A., 111 Kriiger, C., 477 Aitola, E., 173 Fischer, R.W., 443 Kruger, G.J., 83 Alonso, F., 463 Flérke, U., 497 Kucken, S., 39 Alt, H.G., 205 Kiihn, F.E., 443 Amouri, H., 483 Garcia, M.H., 115 Kunai, A., 487 Ansari, M.A., 141 Garkusha, O.G., 59 Kunkely, H., 517 Antelmann, B., 433 Gerbrandij, A.W., 115 Arif, A.M., 277 Geyer, A., 331 Lang, H., 31 Ginyama, H., 163 Larina, L., 129 Barba, L., 345 Gipson, S.L., 269 Lazell, M., 23 Baum, G., 511 Goovaerts, E., 115 Le Bras, J., 483 Bayon, J.C., 199 Graf, M., 371 Lee, G.-H., 417 Beckhaus, R., 427 Gustafsson, ‘M.,:173 Lee, T.-Y., 397 Bildstein, B., 73 Gutierrez; A,, 221 Lehotkay, Th., 103 Bishop, L.A., 53 Lensink, C., 387 Bodensieck, U., 307 Hardt, T., 241 Leskela, M., 173 Borisov, G.K., 59 Harima, Y., 487 Lightfoot, P., 473 Borner, A., 99 Hart, S.L., 507 Lin, Y.-C., 417 Bottcher, H.-C., 371 Haupt, H.-J., 497 Liu, N., 157 Breu, J., 285 Heinemann, O., 477 Liu, Q., 179 Bricout, H., 469 Herrmann, W.A., 443 Liu, Z., 269 Brintzinger, H.-H., 331 HeBler, A., 39 Lokshin, B.V., 59 Bruhn, C., 371 Hiller, J., 15 Brill, R., 83 Holz, J., 99 Mach, K., 15 Brunner, H., 285 Hopfl, H., 221 Manassero, M., 405 Brusilovets, A.I., 379 Huttner, G., 433 McCamley, A., 507 McCormack, P.J., 507 Calhorda, M.J., 115 Iglesias, M., 193 Mealli, C., 115 Cassetta, A., 345 Inomata, S., | Medvedeva, A., 129 Castillo, D., 221 Ishikawa, M., 487 Medvedeva, A.S., 481 Chang, C.-W., 417 Ito, S., 135 Mendes, P., 115 Cinellu, M.A., 405 Merlic, C.A., 183 Cingolani, A., 345 Jaaskelainen, S., 453 Merzweiler, K., 371 Cole-Hamilton, D.J., 473 Jaitner, P., 103 Messerle, L., 397 Jany, G., 173 Meyer, W.H., 83 Damrau, H.-R.H., 331 Dang, H.-S., 67 Jerzykiewicz, L.B., 379 Migita, T., 493 Jolly, P.W., 477 Miliani, M., 345 Daran, J.-C., 221 Davies, A.G., 67 Jones, P.G., 111 Milius, W., 205 Jutzi, P., 317 Minghetti, G., 405 Davies, S.G., 463 Mochida, K., 163 Demina, M., 129 Demina, M.M., 481 Kawano, Y., | Moinet, C., 253 Khan, S.I., 141 Monflier, E., 469 Dias, A.R., 115 Ding, M., 179 Kira, M., 163 Mortreux, A., 469 Dobado, J.A., 173 Klaui, W., 241 Motevalli, M., 23 Dorta, R., 307 Kless, A., 99 Duarte, M.T., 115 Klinga, M., 173 Nakano, T., 493 Kohler, K., 31 Neumann, B., 317 Edelmann, F.T., 393 Kool, L.B., 53 Nief, F., 503 Enokido, T., 493 Kopacka, H., 73 Noda, S., 493 Ernst, R.D., 277 Kosugi, M., 493 Nodono, M., 487 Evans, W.J., 141 Kramkowski, P., 511 Novokshonov, V.V., 481 Elsevier Science S.A. 526 Author Index of Volume 553 Ogino, H., | Santillan, R., 221 Ueno, Y., 487 Ohshita, J., 487 Santos, A., 193 Utko, J., 379 Okazaki, M., | Schaper, F., 331 Oster, J., 427 Scheer, M., 511 Vaissermann, J., 483 Schmutzler, R., 111 Varga, V., 15 Pakkanen, T.A., 453 Schweiger, M., 73 Velikanov, A., 129 Peifer, B., 205 Serra, M.E.S., 199 Verhovnik, G.P.J., 477 Pellei, M., 345 Shah, S.A.A., 23 Vogler, A., 517 Pereira, J.P.R., 199 Sheldrick, W.S., 39 Voronkov, M., 129 Pereira, M.M., 199 Sinbandhit, S., 253 Voronkov, M.G., 481 Periasamy, M., 91 Smethurst, C.A.P., 463 Vos, D., 277 Petri, S.H.A., 317 Sobota, P., 379 Petters, D., 497 Stammler, H.-G., 317 Wachter, W.M., 443 Pettinari, C., 345 Stelzer, O., 39 Wang, Y., 417 Piedade, M.F.M., 115 Stoccoro, S., 405 Watanabe, T., 487 Pierre, F., 253 Stoeckli-Evans, H., 307 Weeber, A., 331 Pifferi, A., 345 Stricker, A., 253 Wenseleers, W., 115 Plack, V., 111 Sullivan, A.C., 23 Weston, W.S., 473 PolaSek, M., 15 Sun, G.-R., 111 Winter, A., 285 Poremba, P., 393 Sun, J., 149 Winterhalter, U., 433 Pritzkow, H.,.31 Siiss-Fink, G., 307 Wu, F., 183 Y Prosenc."M.<Pt} 3st? : * ** Wurst, K., 73, 103 Rao, MIEN. 9.rgd9 EP ~,o deo r : +"O P“sas k& a&Us 4%h ashi, Me Poe ?2) 163. - “Rising BMS Xu, S., 149 “Stamaik Is * sRaubenhéaner, H.G:.8 3° Taylor, .P.C..,S 07 ie at >R¥inke, r -99 s- “3. Thewalt, i a -+* Yamashita, K., 487 Yi, C.S., 157 Repo, T.; 173 Thompson, C., 83 Ricard, L., 503 Tian, G., 149 Yoshifuji, M., 135 Rivarola, E., 345 Ting, P.-C., 417 Rocha Gonsalves, A.M.d’A.., 19 Tobita, H., | Zhang, Y., 149 Toupet, L., 253 Zhou, X., 149 Sakhaii, P., 111 Toyota, K., 13 Ziller, J.W., 141 Sansoni, M., 405 Turner, ig : Zucca, A., 405 ournal ofOrgano. metallic ee! Chemistry ELSEVIER Journal of Organometallic Chemistry 553 (1998) 527-535 Subject Index of Volume 553 Absorption spectra Allyl iodide Electronic spectrum and photoreactivity of dimethyl(1,5-cyclo- Synthesis of ruthenium vinylidene complexes with dppe ligand and octadiene)-platinum(1) (H. Kunkely and A. Vogler), 517 their cyclopropenation reaction (C.-W. Chang, P.-C. Ting, Y.-C. Acetylenic alcohols Lin, G.-H. Lee and Y. Wang), 417 Universal method for trimethylsilylation of acetylenic alcohols and Allylsilanes . glycols (M. Demina, A. Velikanov, A. Medvedeva, L. Larina and Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of M. Voronkov), 129 allylic stannanes and silanes with methyl propiolate (H.-S. Dang Acetylenic glycols and A.G. Davies), 67 Universal method for trimethylsilylation of acetylenic alcohols and Allylstannanes glycols (M. Demina, A. Velikanov, A. Medvedeva, L. Larina and Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of M. Voronkov), 129 allylic stannanes and silanes with methyl propiolate (H.-S. Dang Acrylic acids and A.G. Davies), 67 Asymmetric transfer hydrogenation of acrylic acids catalyzed by Aluminium(ID) rhodium(I1) complexes of diphosphine ligands (A.M.d’A. Synthesies, properties and crystal structures of ionic [Al,( ,?- Rocha Gonsalves, J.C. Bayon, M.M. Pereira, M.E.S. Serra and thffo),(EtOH),CJlCI,, , [Al,(4,7?-thffo),Cl, AIEtCl,] and te- J.P.R. Pereira), 199 tranuclear [AlI,( u.7?-thffo),( u-OEv),Cl,] (thffo = OCH ,CH Acylation (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. L.B. Jerzykiewicz), 379 Wu), 183 Alumoxanes Acylgold(1) organyls as ligands Synthesies, properties and crystal structures of ionic [Al,( .?- First examples of acylgold(1) complexes RCOAuPPh, (R = Me, n-Bu, thffo),(EtOH),CJlCI,, , [Al ,(4,7?-thffo),Cl, JAIEtCl,] and te- t-Bu, Ph) trapped as oxygen coordinated ligands L at one of tranuclear [AlI,( u.7?-thffo),( u-OEU,Cl,] (thffo’=-OCH,CH rhenium atoms in Re,( u-PPh,),(CO),(ax-L) (H.-J. Haupt, D. (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets. and Petters and U. Flérke), 497 L.B. Jerzykiewicz), 379 Alkali metal Arene Synthesis and structure of alkali metal ‘ate’ complexes in the yt- Electrochemical reduction of some [(7°-Cyclopentadieny!) (7°-arene) trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, iron(ID][PR, ]c omplexes bearing an imine or a nitrone function in J.W. Ziller and S.I. Khan), 141 benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Alkene Moinet, S. Sinbandhit and L. Toupet), 253 The CoCl, /Ph(Et), N:BH , /CO system: Reactions of the borane and Aryl cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- Alkoxide gangsmetallen. CLXVI. Molekulare Organorhenium-Vorstufen fiir Synthesis and structure of alkali metal ‘ate’ complexes in the yt- CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, R.W. Fischer), 443 J.W. Ziller and S.I. Khan), 141 Arylpalladium complexes Alkoxides Thioethercarboxylates in palladium chemistry: First proof of hemil- Synthesies, properties and crystal structures of ionic [AI,( b.n?- abile properties of S—O ligands (W.H. Meyer, R. Brill, H.G. thffo),(EtOH),CJlCI,, , [Al,(2.n°-thffo),Cl, [AIEtCl,] and te- Raubenheimer, C. Thompson and G.J. Kruger), 83 tranuclear [Al,( .77-thffo),( u-OEt),Cl,] (thffo = OCH,CH Asymmetric (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and Asymmetric transfer hydrogenation of acrylic acids catalyzed by L.B. Jerzykiewicz), 379 rhodium(1) complexes of diphosphine ligands (A.M.d’A. Alkyl Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- J.P.R. Pereira), 199 gangsmetallen. CLXVI- Molekulare Organorhenium-Vorstufen fiir ‘Ate’ complex CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and Synthesis and structure of alkali metal ‘ate’ complexes in the yt- R.W. Fischer), 443 trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, Allylgermanes J.W. Ziller and S.I. Khan), 141 Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- | .4-benzodiazepin-2-ones manes with allylic chlorides at room temperature (T. Nakano, T. C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 tion. Crystal structure of (L)Au[P(C,,HCH ,-4),] (HL = 7-chloro- Elsevier Science S.A. Subject Index of Volume 553 | ,3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- Carbonylative cyclisations AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, The CoCl, /Ph(Et), N:BH ,/CO system: Reactions of the borane and M. Manassero and M. Sansoni), 405 cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 Carbonyls Heteroligand substitution in clusters of ruthenium and cobalt (T.M. Bis(diphenylphosphany|ethane type ligands Risinen, S. Jaiskeléinen and T.A. Pakkanen), 453 Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- Carbyne phenylphosphany|)ethane transition metal chelates (H. Brunner, A. Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von Winter and J. Breu), 285 Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fir Bis(phosphinoethy| amines die ring6ffnende metathetische Polymerisation von Cycloolefinen Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und (W. Klaui und T. Hardt), 241 Templatreaktionen PH-funktioneller Bis(phosphinoetahmyinle (A. Catalysis HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 A thermodynamic study of the electron transfer chain catalyzed Borinates substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. Study of cyclic borinates obtained from piperidine- and piperazine Liu and S.L. Gipson), 269 alcohols by spectroscopic methods and X-ray crystallography (H. Asymmetric transfer hydrogenation of acrylic acids catalyzed by H6épfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. rhodium(I1) complexes of diphosphine ligands (A.M.d’A. Daran), 221 Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and Boron complexes J.P.R. Pereira), 199 Study of cyclic borinates obtained from piperidine- and piperazine para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst alcohols by spectroscopic methods and X-ray crystallography (H. precursors in ethene polymerization (G. Jany, M. Gustafsson, T. H6pfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskelia), 173 Darah); 221 Catalytic carbonylation _ Bridging water . Modelling intermediates in the catalytic carbonylation of CH,I, to Formation and X-ray structure of [{O(Ph, SiONa), }, - (NaOH) - (HO) malonate esters; Evidence for a ketene pathway (W.S. Weston, P. -(7 pyridine)]- (tolu-e( pnyriedi)ne ) incorporating a unique as- Lightfoot and D.J. Cole-Hamilton), 473 sembly of three fused Na,O, cubane units and a jz, -water molecule _ Cerium (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. Cyclooctatetraenyl complexes of the early transition metals and lan- Sullivan), 23 thanides. X. The first organometallic triple decker sandwich com- Butadiene plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 Tetraferrocenyl-[3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka C—H-Activation and K. Wurst), 73 Different reaction modes of supermesitylphosphaalkyne with Butatriene [W(CO),thf]-unusual C-H-activation forming an indanyl sub- Tetraferrocenyl-(3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka stituent (P. Kramkowski, M. Scheer and G. Baum), 511 and K. Wurst), 73 Chelate Synthesies, properties and crystal structures of ionic [Al,( ,n?- thffo),(EtOH),CJlCl,, , [Al,(4,?-thffo),Cl, [AIEtCl,] and te- Coo tranuclear [AI,( ,7?-thffo),( u-OEt),Cl,] (thffo = OCH,CH Reactions of fullerenols C,)(OH), (x = 12, 18) with trialkoxysilanes (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and (RO),Si(CH,),X (R = Me, X = Cl; R = Et, X = NH,) (M. Igle- L.B. Jerzykiewicz), 379 sias and A. Santos), 193 Chiral Carbene ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von plexes—syntheses, crystal structures and structural dynamics in Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fiir solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, die ring6ffnende metathetische Polymerisation von Cycloolefinen F. Schaper and H.-H. Brintzinger), 331 (W. Klaui und T. Hardt), 241 Synthesis of racemic chiral-at-metal complexes of the group 4 metals Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. by a lithium chloride catalysed ligand redistribution reaction (S.L. Wu), 183 Hart, A. McCamley, P.J. McCormack and P.C. Taylor), 507 Carbon—hydrogen bond activation Chiral diphosphine Thermal reactions of alkyl(hydridohydrosily)iridium(ID com- Asymmetric transfer hydrogenation of acrylic acids catalyzed by plexes: generation of a hydrido(silylene)iridium(1) species via the rhodium(I) complexes of diphosphine ligands (A.M.d’A. reductive elimination of alkane and 1,2-H-shift from the silicon Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and atom to the Ir(I) metal center (M. Okazaki, H. Tobita, Y. Kawano, J.P.R. Pereira), 199 S. Inomata and H. Ogino), | Chirality transfer Carbonyl Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. phenylphosphanyiethane transition metal chelates (H. Brunner, A. Wu), 183 Winter and J. Breu), 285 Synthesis of triruthenium clusters containing mixed bridging phos- Chiral phosphite phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- Synthesis and __ characterization of Ti(C 5H; 2,4-C,H,,) PBu{ 4‘-PC,y,) ,] and the electron-deficient complex [Ru,( y- [POCH,CH(O)C,H,O] and Ti(2,4-C,H,,), [POCH,CH(O) COXCO),( u-H),( u-PBu} ),(Bu, PH)] (M. Graf, K. Merzweiler, C,H,O] chiral phosphite adducts of an open and a half open C. Bruhn and H.-C. Béttcher), 371 titanocene (D. Vos, A.M. Arif and R.D. Ernst), 277 Carbonylation Chromium The CoCl, /Ph(Et), N:BH ,/CO system: Reactions of the borane and A facile access to CpCr (acac)Cl and related systems (O. Heinemann, cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 Subject Index of Volume 553 529 Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. Synthesis and structure of sulfonamido cyclopentadiene titanium com- Wu), 183 plexes: X-ray structure of Ti(n°:0-C;H,CH,CH,NSO,C, Cluster H,CH,)CI, (C. Lensink), 387 Fixation of triruthenium clusters on melamine: synthesis and structure Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base of [Ru,( ,-H{ 4X,,7?C-NHC,ON,(N)H,), }], cis-[{Ru,(2,- complex bearing C,-symmetric tetradentate ligand: crystal struc- HXC3O.77:) 43,,9°-}NHC,,N,({NH,) }] and trans-{{Ru,( y- ture of [(m°-C 5H.) Yb 4-OC 5) H 59 N,O)],( u-THFX THF) (Q. Liu HCO) },{ 43.77: 43.n°-NHC,N,(NH,)}] (R. Dorta, H. and M. Ding), 179 Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 Synthesis of triruthenium clusters containing mixed bridging phos- Synthesis of triruthenium clusters containing mixed bridging phos- phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- phido ligands: X-ray crystal structures of [Ru,(CO),( u-H) p- PBXu u-P'Cy,) ,] and the electron-deficient complex [Ru, ( y- PBXu u-‘PCy,,) ,] and the electron-deficient complex [Ru,( y- COXCO),( -H),( u-PBu5 ),(Bu, PH)] (M. Graf, K. Merzweiler, COXCO),( u-H),( u-PBu’, ),(Bu PH)] (M. Graf, K. Merzweiler, C. Bruhn and H.-C. Bottcher), 371 C. Bruhn and H.-C. Béttcher), 371 C,-symmetry Cobalt carbonyl reagents Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base The CoCl, /Ph(Et), N:BH ,/CO system: Reactions of the borane and complex bearing C,-symmetric tetradentate ligand: crystal struc- cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 ture of [(m°-C 5H.) Yb( 4-OC 5) H 5) NO)],( u-THFX THF) (Q. Liu 7-Complex and M. Ding), 179 Synthesis, structural characterisation and dynamic behaviour of penta- Cumulene fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 Tetraferrocenyl-(3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka Complexes and K. Wurst), 73 Wasserlisliche Phosphane VII. Synthese, Koordinationschemie und CVD Templatreaktionen PH-funktioneller Bis(phosphinoethylamine (A. Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 gangsmetallen. CLXVI. Molekulare Organorhenium-Vorstufen fiir Conducting polymer CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and Synthesis and properties of dithienosiloles (J. Ohshita, M. Nodono, T. R.W. Fischer), 443 Watanabe, Y. Ueno, A. Kunai, Y. Harima, K. Yamashita and M. Cyclooctatetraenyl complexes Ishikawa), 487 Cyclooctatetraenyl complexes of the early transition metals and lan- Configuration thanides. X. The first organometallic triple decker sandwich com- ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 plexes—syntheses, crystal structures and structural dynamics in Cyclopentadiene solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, Synthesis and structure of sulfonamido cyclopentadiene titanium com- F. Schaper and H.-H. Brintzinger), 331 plexes: X-ray structure of Ti(n*:o-C;H,CH,CH,NSO,C, Conformational analysis H,CH,)CI, (C. Lensink), 387 Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- Cyclopentadieny| phenylphosphany)ethane transition metal chelates (H. Brunner, A. A facile access to CpCr (acac)Cl and related systems (O. Heinemann, Winter and J. Breu), 285 P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 Coordinative N — B bond Electrochemical reduction of some [(7°-Cyclopentadieny!) (°-arene) Study of cyclic borinates obtained from piperidine- and piperazine iron(II) |[PF, ] complexes bearing an imine or a nitrone function in alcohols by spectroscopic methods and X-ray crystallography (H. benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Ho6pfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. Moinet, S. Sinbandhit and L. Toupet), 253 Daran), 221 Synthesis and characterization of a series of sila-bridged diiron com- Copper(I) fluoride plexes (E)[(m°-t-BuC,H ,) Fe(CO)],( u-CO), (E = Me,Si, Synthese und Reaktionsverhalten monomerer Bis(?-Alkin)- Me,SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. Kohler, and trans-(Me,Si)[n°-t-BuC,H ,)Fe(CO)],( u-CO), (Y. Zhang, H. Pritzkow und H. Lang), 31 S. Xu, G. Tian, X. Zhou and J. Sun), 149 Copper(I) hydride Synthese und Reaktionsverhalten monomerer Bis(7?-Alkin)- Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. K@hler, H. Pritzkow und H. Lang), 31 Copper-mediated coupling reaction A convenient synthesis of a sterically protected 1,4-diphosphabu- Delocalization tatriene and its pentacarbonyltungsten complexes (S. Ito, K. Toy- Organometallic nickel(II) complexes with substituted benzonitrile lig- ota and M. Yoshifuji), 135 ands. Synthesis, electrochemical studies and non-linear optical Crystal structure properties. The X-ray crystal structure of [Ni(m°-C,H,) Formation and X-ray structure of [(O(Ph,SiONa),}, - (NaOH) - (HO) {P(C,.H;),;(NCC,H,N[HPR,] (A.R. Dias, M.H. Garcia, P. -(7 pyridine)]- (tolu-e( pnyreidi)ne ) incorporating a unique as- Mendes, M.F.M. Piedade, M.T. Duarte, M.J. Calhorda, C. Mealli, sembly of three fused Na,O, cubane units and a . ,-water molecule W. Wenseleers, A.W. Gerbrandij and E. Goovaerts), 115 (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. Dialkylketone Sullivan), 23 The CoCl, /Ph(EN:tBH) ,,/C O system: Reactions of the borane and Synthesies, properties and crystal structures of ionic [Al,( ,n?- cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 thffo),(EtOH),CJlCI,, , [Al,(4,?-thffo),Cl, [AIEtC],] and te- DIAZEPAM tranuclear [Al,( ,7?-thffo),( 4-OEt),Cl,] (thffo = OCH,CH C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- (CH ,),;0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and tion. Crystal structure of (L)Au[P(C,,H,CH ,-4),] (HL = 7-chloro- L.B. Jerzykiewicz), 379 1 ,3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- Subject Index of Volume 553 AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and M. Manassero and M. Sansoni), 405 J.P.R. Pereira), 199 Dicyclopentadienylzinc (Cp, Zn) Fullerenol Vibrational spectra and structure of dicyclopentadienylzine (O.G. Reactions of fullerenols C,,(OH), (x = 12, 18) with trialkoxysilanes Garkusha, B.V. Lokshin and G.K. Borisov), 59 (RO),Si(CH,),X (R = Me, X = Cl; R = Et, X = NH,) (M. Igle- Digermane sias and A. Santos), 193 Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- Fulvalene manes with allylic chlorides at room temperature (T. Nakano, T. Synthesis, structural characterisation and dynamic behaviour of penta- Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 Dimerisation Functionalised cyclopentadieny| Different reaction modes of supermesitylphosphaalkyne with Funktionalisierte cyclopentadienylliganden fiir den aufbau von [W(CO).thf]-unusual C-H-activation forming an indanyl sub- tripod-komplexen: synthese und komplexchemie (B. Antelmann, stituent (P. Kramkowski, M. Scheer and G. Baum), 511 G. Huttner und U. Winterhalter), 433 | .4-Diphosphabutatriene A convenient synthesis of a sterically protected 1,4-diphosphabu- Germanium tatriene and its pentacarbonyltungsten complexes (S. Ito, K. Toy- Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- ota and M. Yoshifuji), 135 manes with allylic chlorides at room temperature (T. Nakano, T. Dirhenium complexes Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 First examples of acylgold(1) complexes RCOAuPPh, (R = Me, n-Bu, Germy| radical t-Bu, Ph) trapped as oxygen coordinated ligands L at one of Photochemical reactions of digermanyl-substituted naphthalenes: The rhenium atoms in Re,( u-PPh,),(CO),(ax-L) (H.-J. Haupt, D. germyl! migration to the aromatic ring (K. Mochida, H. Ginyama, Petters and U. Flérke), 497 M. Takahashi and M. Kira), 163 Dithiacylohexane Gold Heteroligand substitution in clusters of ruthenium and cobalt (T.M. C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- Riisinen, S. Jéiskeliinen and T.A. Pakkanen), 453 tion. Crystal structure of (L)Au[P(C,,HCH ,-4),] (HL = 7-chloro- | 3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- Electrochemical reduction AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, Electrochemical reduction of some [(7°-Cyclopentadieny!) (7°-arene) M. Manassero and M. Sansoni), 405 iron(II) |[PF, ]c omplexes bearing an imine or a nitrone function in Group metal benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Synthesis of racemic chiral-at-metal complexes of the group 4 metals Moinet, S. Sinbandhit and L. Toupet), 253 by a lithium chloride catalysed ligand redistribution reaction (S.L. Electrochemistry Hart, A. McCamley, P.J. McCormack and P.C. Taylor), 507 Tetraferrocenyl-[3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka and K. Wurst), 73 Electron-transfer Hafnium A thermodynamic study of the electron transfer chain catalyzed para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. precursors in ethene polymerization (G. Jany, M. Gustafsson, T. Liu and S.L. Gipson), 269 Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskela), 173 Ene reaction Hapticity Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- allylic stannanes and silanes with methyl propiolate (H.-S. Dang plexes—syntheses, crystal structures and structural dynamics in and A.G. Davies), 67 solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, Ethylene F. Schaper and H.-H. Brintzinger), 331 A facile access to CpCr (acac)CI and related systems (O. Heinemann, Head-to-tail dimerization of acrylic compounds P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 Ruthenium-mediated selective head-to-tail dimerization of acrylic and a, B-unsaturated carbonyl compounds: generation of an acrylate- Ferrocene hydride complex C;Me;Ru(PCy,;(CH,=CHCO,EvH (C.S. Yi Tetraferrocenyl-{3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka and N. Liu), 157 and K. Wurst), 73 Hemilability Ferrocenecarboxaldehyde Thioethercarboxylates in palladium chemistry: First proof of hemil- Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-|,3- abile properties of S—O ligands (W.H. Meyer, R. Brill, H.G. oxazolidin-5-ones (F. Alonso, $.G. Davies and C.A.P. Smethurst), Raubenheimer, C. Thompson and G.J. Kruger), 83 463 Heterogeneous catalysis Fluorine Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- and H.G. Alt), 205 silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. Hydride Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Utility of hydridotributyltin as both reductant and hydride transfer Formates reagent in organotransition metal chemistry I. A convenient syn- Asymmetric transfer hydrogenation of acrylic acids catalyzed by thesis of the organoditantalum(IV) hydrides (7-C ;Me,R),Ta,( p- rhodium(I1) complexes of diphosphine ligands (A.M.d’A. H),Cl, (R = Me, Et) from (m-C;Me,R)TaCl,, and probes of the Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and possible reaction pathways (T.-Y. Lee and L. Messerle), 397 J.P.R. Pereira), 199 Hydridotri(buty)tin Formic acid Utility of hydridotributyltin as both reductant and hydride transfer Asymmetric transfer hydrogenation of acrylic acids catalyzed by reagent in organotransition metal chemistry I. A convenient syn- rhodium(1) complexes of diphosphine ligands (A.M.d’A. thesis of the organoditantalum(IV) hydrides (n-C;Me,R),Ta>( p- Subject Index of Volume 553 531 H),Cl, (R = Me, Et) from (7-C,Me,R)TaCl,, and probes of the Synthese und Reaktionsverhalten monomerer Bis(?-Alkin)- possible reaction pathways (T.-Y. Lee and L. Messerle), 397 Kupfer(1)-Fluorid- und-Kupfer(1)-Hydrid-Komplexe (K. K6hler, Hydroboration H. Pritzkow und H. Lang), 31 The CoCl, /Ph(Et), N:BH,/CO system: Reactions of the borane and Melamine cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 Fixation of triruthenium clusters on melamine: synthesis and structure Hydroquinone of [Ru,( 2>-HXCO)o{ ~3,n?-NHC,N,(NH,),}], cis-[{Ru,( p,- n*-quinone, 7°-semiquinone and 7°-hydroquinone complexes of pen- HXC4O3.77): 43,.9°-}NHC,.N,({NH,) }] and trans-[{Ru,( >- tamethylcyclopentadieny! iridium. X-ray molecular structure of H\CO),}{ 43,.77?:43.n’°-NHC,N,(NH,)}] (R. Dorta, H. [Cp * Ir(y*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 Vaissermann), 483 Metal carbony! Synthesis and characterization of a series of sila-bridged diiron com- Indenyl plexes (E)[(m°-t-Bu,CH ,)Fe(CO)],( u-CO), (E = Me,Si, para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst Me,SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- precursors in ethene polymerization (G. Jany, M. Gustafsson, T. and trans-(Me, Si)[n°-t-BuC ,H ,)Fe(CO)],( u-CO), (Y. Zhang, Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskela), 173 S. Xu, G. Tian, X. Zhou and J. Sun), 149 Iron Metalla—phospha—carbon ring system A thermodynamic study of the electron transfer chain catalyzed Conversion of 1?-phosphinocarbene complexes into tungstaphos- substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. phabicyclo[1.1.0]butanone units (Th. Lehotkay, K. Wurst, P. Jait- Liu and S.L. Gipson), 269 ner and F.R. Kreibl), 103 Electrochemical reduction of some [(°-Cyclopentadieny]) (7°-arene) Metallasiloxane iron(II) |[PF, ]c omplexes bearing an imine or a nitrone function in Formation and X-ray structure of [{O(Ph, SiONa),}, - (NaOH) - (HO) benzylic position of the arene ligand (F. Pierre, A. Stricker, C. -(7 pyridine)]- (tolu-e( pnyriedi)ne ) incorporating a unique as- Moinet, S. Sinbandhit and L. Toupet), 253 sembly of three fused Na,O, cubane units and a . ,-water molecule Synthesis and characterization of a series of sila-bridged diiron com- (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. plexes (E)[(m°-t-Bu;CH ,)Fe(CO)],( u-CO), (E = Me,Si, Sullivan), 23 Me, SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- Metallocene and trans-(Me, Si)[n°-t-BuC ;H ,)Fe(CO)],( u-CO), (Y. Zhang, Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius S. Xu, G. Tian, X. Zhou and J. Sun), 149 and H.G. Alt), 205 Tetraferroceny|-{(3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka ansa-Metallocene and K. Wurst), 73 ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- Iron complexes plexes—syntheses, crystal structures and structural dynamics in Funktionalisierte cyclopentadienylliganden fiir den aufbau von solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, tripod-komplexen: synthese und komplexchemie (B. Antelmann, F. Schaper and H.-H. Brintzinger), 331 G. Huttner und U. Winterhalter), 433 Metallocenes Isomerization Synthesis of racemic chiral-at-metal complexes of the group 4 metals Isomerization of olefins in a two-phase system by homogeneous by a lithium chloride catalysed ligand redistribution reaction (S.L. water-soluble nickel complexes (H. Bricout, A. Mortreux and E. Hart, A. McCamley, P.J. McCormack and P.C. Taylor), 507 Monflier), 469 Metalloene reaction Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of Labelling studies allylic stannanes and silanes with methyl propiolate (H.-S. Dang Modelling intermediates in the catalytic carbonylation of CH,I, to and A.G. Davies), 67 malonate esters; Evidence for a ketene pathway (W.S. Weston, P. Metathesis Lightfoot and D.J. Cole-Hamilton), 473 Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- Lanthanide manes with allylic chlorides at room temperature (T. Nakano, T. Synthesis, structural characterisation and dynamic behaviour of penta- Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 1-methylimidazole derivative Laser photolysis Tin(IV) and organotin(IV) complexes containing mono or bidentate Photochemical reactions of digermanyl-substituted naphthalenes: The N-donor ligands. III. 1l-methylimidazole derivatives: synthesis, germyl migration to the aromatic ring (K. Mochida, H. Ginyama, spectroscopic and structural characterization (C. Pettinari, M. M. Takahashi and M. Kira), 163 Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi and E. Rivarola), 345 Macrocycles | ,2-migration Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und Thermal reactions of alkyl(hydridoXhydrosily)iridium(UILD) com- Templatreaktionen PH-funktioneller Bis(phosphinoethy])amine (A. plexes: generation of a hydrido(silylene)iridium(1) species via the HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 reductive elimination of alkane and 1,2-H-shift from the silicon Magnesium atom to the Ir(I) metal center (M. Okazaki, H. Tobita, Y. Kawano, ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- S. Inomata and H. Ogino), |! plexes—syntheses, crystal structures and structural dynamics in Migration solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, Photochemical reactions of digermanyl-substituted naphthalenes: The F. Schaper and H.-H. Brintzinger), 331 germyl migration to the aromatic ring (K. Mochida, H. Ginyama, Mechanism M. Takahashi and M. Kira), 163 Modelling intermediates in the catalytic carbonylation of CH,1I, to Molybdenum(0) malonate esters; Evidence for a ketene pathway (W.S. Weston, P. Studies on the formation of uniform 7*-coordinated triphos-Mo(0)- Lightfoot and D.J. Cole-Hamilton), 473 complexes (A. Kless, J. Holz, H. Reinke and A. Borner), 99 532 Subject Index of Volume 553 Molybdenum Organodimetallics Silyl-Komplexe des Molybdins und Wolframs. Synthese, Reaktivitat Utility of hydridotributyltin as both reductant and hydride transfer und Struktur (S.H.A. Petri, B. Neumann, H.-G. Stammler und P. reagent in organotransition metal chemistry I. A convenient syn- Jutzi), 317 thesis of the organoditantalum(IV) hydrides (7-C;Me,R),Ta,( p- Multi-cluster H),Cl, (R = Me, Et) from (7-C;Me,R)TaCl,, and probes of the Fixation of triruthenium clusters on melamine: synthesis and structure possible reaction pathways (T.-Y. Lee and L. Messerle), 397 of [Ru,( 4,-HXCO).{ u3.7?-NHC,N,(NH,),}], cis-[{Ru,( »- Organolanthanides HXCO) }.{ 43.77: 3.9?-NHC,N,(NH,)}] and trans-[{Ru,( p>- Cyclooctatetraeny! complexes of the early transition metals and lan- HCO) },{ 43.7: 43.n°-NHC,N,(NH,)}] (R. Dorta, H. thanides. X. The first organometallic triple decker sandwich com- Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 Organometallic Ni Naphthylgermane Organometallic nickel(I]) complexes with substituted benzonitrile lig- Photochemical reactions of digermanyl-substituted naphthalenes: The ands. Synthesis, electrochemical studies and non-linear optical germyl! migration to the aromatic ring (K. Mochida, H. Ginyama, properties. The X-ray crystal structure of [Ni(m°-C;H,{P(C, M. Takahashi and M. Kira), 163 H,;),4NCC,H,N[HP,R] (A.R. Dias, M.H. Garcia, P. Mendes, N-donor ligand M.F.M. Piedade, M.T. Duarte, M.J. Calhorda, C. Mealli, W. Tin(IV) and organotin(IV) complexes containing mono or bidentate Wenseleers, A.W. Gerbrandij and E. Goovaerts), 115 N-donor ligands. III. 1l-methylimidazole derivatives: synthesis, Organosilicon polymer spectroscopic and structural characterization (C. Pettinari, M. Synthesis and properties of dithienosiloles (J. Ohshita, M. Nodono, T. Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi Watanabe, Y. Ueno, A. Kunai, Y. Harima, K. Yamashita and M. and E. Rivarola), 345 Ishikawa), 487 Neodymium Organotin(IV) complex Cyclooctatetraenyl complexes of the early transition metals and lan- Tin(V) and organotin(IV) complexes containing mono or bidentate thanides. X. The first organometallic triple decker sandwich com- N-donor ligands. III. 1-methylimidazole derivatives: synthesis, plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 spectroscopic and structural characterization (C. Pettinari, M. Nickel Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi Isomerization of olefins in a two-phase system by homogeneous and E. Rivarola), 345 water-soluble nickel complexes (H. Bricout, A. Mortreux and E. Organoytterbium complex Monflier), 469 Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base Nitrile orbitals complex bearing C,-symmetric tetradentate ligand: crystal struc- Organometallic nickel(II) complexes with substituted benzonitrile lig- ture of [(7°-C;H.)Yb( 4-OC 5) H49N,O)],( u-THFXTHF) (Q. Liu ands. Synthesis, electrochemical studies and non-linear optical and M. Ding), 179 properties. The X-ray crystal structure of [Ni(m°-C;H,XP(C, Oxazolidinone H,),4NCC,H,N)JH[P,R, ] (A.R. Dias, M.H. Garcia, P. Mendes, Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-1,3- M.F.M. Piedade, M.T. Duarte, M.J. Calhorda, C. Mealli, W. oxazolidin-5-ones (F. Alonso, $.G. Davies and C.A.P. Smethurst), Wenseleers, A.W. Gerbrandij and E. Goovaerts), 115 463 NMR Oxidative coupling reaction X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- Synthesis of ruthenium vinylidene complexes with dppe ligand and silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. their cyclopropenation reaction (C.-W. Chang, P.-C. Ting, Y.-C. Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Lin, G.-H. Lee and Y. Wang), 417 NMR spectroscopy Oxo complexes Synthesis and __ characterization of TiC 5H; X2,4-C,H,,) Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von [POCH,CH(O)C,H,O] and Ti(2,4-C,H,,), [POCH,CH(O) Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fiir C,H,O] chiral phosphite adducts of an open and a half open die ring6ffnende metathetische Polymerisation von Cycloolefinen titanocene (D. Vos, A.M. Arif and R.D. Ernst), 277 (W. Klaui und T. Hardt), 241 Nuclear magnetic resonance Studies on the formation of uniform 7*-coordinated triphos-Mo(0)- complexes (A. Kless, J. Holz, H. Reinke and A. Borner), 99 Palladium Olefin Thioethercarboxylates in palladium chemistry: First proof of hemil- Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius abile properties of S—O ligands (W.H. Meyer, R. Briill, H.G. and H.G. Alt), 205 Raubenheimer, C. Thompson and G.J. Kruger), 83 O,-oxidation Palladium-catalysis Electrochemical reduction of some [(°-Cyclopentadieny]) (7°-arene) Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- iron(ID][PF, ]c omplexes bearing an imine or a nitrone function in manes with allylic chlorides at room temperature (T. Nakano, T. benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 Moinet, S. Sinbandhit and L. Toupet), 253 Pentamethylcyclopentadienide Organic halides Synthesis and structure of alkali metal ‘ate’ complexes in the yt- Synthesis of ruthenium vinylidene complexes with dppe ligand and trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, their cyclopropenation reaction (C.-W. Chang, P.-C. Ting, Y.-C. J.W. Ziller and S.I. Khan), 141 Lin, G.-H. Lee and Y. Wang), 417 Pentamethylcyclopentadieny] iridium Organo copper(I) 7n*-quinone, 7°-semiquinone and n°-hydroquinone complexes of pen- Synthese und Reaktionsverhalten monomerer Bis(?-Alkin)- tamethylcyclopentadienyl iridium. X-ray molecular structure of Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. Kohler, [Cp * Ir(n*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. H. Pritzkow und H. Lang), 31 Vaissermann), 483 Subject Index of Volume 553 533 Peralkylcyclopentadieny| [Cp * Ir(m*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. Utility of hydridotributyltin as both reductant and hydride transfer Vaissermann), 483 reagent in organotransition metal chemistry I. A convenient syn- thesis of the organoditantalum(IV) hydrides (n-C;Me,R),Ta,( u- Raman spectra H),Cl, (R = Me, Et) from (7-C,Me,R)TaCl,, and probes of the Vibrational spectra and structure of dicyclopentadienylzinc (O.G. possible reaction pathways (T.-Y. Lee and L. Messerle), 397 Garkusha, B.V. Lokshin and G.K. Borisov), 59 Periphery- and Template reactions X-Ray analysis of E- and Z-(ethylene)isomers Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- Templatreaktionen PH-funktioneller Bis(phosphinoethyl)amine (A. silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Phenyl ring orientation Rearrangement Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- An unusual rearrangement of 1|-trimethylsiloxy-3-bromomagnesium- phenylphosphany)ethane transition metal chelates (H. Brunner, A. 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina Winter and J. Breu), 285 and M.G. Voronkov), 481 Phosphido-bridged Reduction Synthesis of triruthenium clusters containing mixed bridging phos- A thermodynamic study of the electron transfer chain catalyzed phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. PBXu u‘-PC,y,) ,] and the electron-deficient complex [Ru,( p- Liu and S.L. Gipson), 269 COXCO),( u-H),( u-PBu ),(Bu PH)] (M. Graf, K. Merzweiler, Rhenium C. Bruhn and H.-C. Béttcher), 371 Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- Phosphinidene complexes gangsmetallen. CLXVI. Molekulare Organorhenium-Vorstufen fiir Different reaction modes of supermesitylphosphaalkyne with CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and [W(CO),thf]-unusual C-H-activation forming an indanyl sub- R.W. Fischer), 443 stituent (P. Kramkowski, M. Scheer and G. Baum), 511 Rhodium complexes n°-Phosphinocarbene complex Modelling intermediates in the catalytic carbonylation of CH,I, to Conversion of 77?-phosphinocarbene complexes into tungstaphos- malonate esters; Evidence for a ketene pathway (W.S. Weston, P. phabicyclof[1.1.0]butanone units (Th. Lehotkay, K. Wurst, P. Jait- Lightfoot and D.J. Cole-Hamilton), 473 ner and F.R. KreiBl), 103 ROMP Photochemistry Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von Electronic spectrum and photoreactivity of dimethyl(1,5-cyclo- Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fur octadiene)-platinum(ID (H. Kunkely and A. Vogler), 517 die ring6ffnende metathetische Polymerisation von Cycloolefinen Photolysis (W. Kliaui und T. Hardt), 241 Photochemical reactions of digermanyl-substituted naphthalenes: The Ruthenium germyl! migration to the aromatic ring (K. Mochida, H. Ginyama, Fixation of triruthenium clusters on melamine: synthesis and structure M. Takahashi and M. Kira), 163 of [Ru,( 4,-HXCO),{ ~3,n?-NHC,N,(NH,),}], cis-[{Ru,( 25- Piperidine- and piperazine alcohols HXCO)o}5{ 43.797: 43.9°-NHC,N,(NH,)}] and trans-[{Ru,( 5- Study of cyclic borinates obtained from piperidine- and piperazine HCO) }.{ 3,77: 43,.n°-NHC,N,(NH,)}] (R. Dorta, H. alcohols by spectroscopic methods and X-ray crystallography (H. Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 H6pfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. Heteroligand substitution in clusters of ruthenium and cobalt (T.M. Daran), 221 Risiinen, S. Jiaiiskeléinen and T.A. Pakkanen), 453 Planar chirality Synthesis of triruthenium clusters containing mixed bridging phos- Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-1,3- phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- oxazolidin-5-ones (F. Alonso, S.G. Davies and C.A.P. Smethurst), PBu’,X u4-PCy,),] and the electron-deficient complex [Ru, ( p- 463 COXCO),( u-H),( u-PBu', ),(Bu', PH)] (M. Graf, K. Merzweiler, Platinum complexes C. Bruhn and H.-C. Béttcher), 371 Electronic spectrum and photoreactivity of dimethyl(1,5-cyclo- Ruthenium-hydride complexes octadiene)-platinum(II) (H. Kunkely and A. Vogler), 517 Ruthenium-mediated selective head-to-tail dimerization of acrylic and Polymerization a, B-unsaturated carbonyl compounds: generation of an acrylate- A facile access to CpCr (acac)Cl and related systems (O. Heinemann, hydride complex C;Me,R(uCH(, P=CCHCOy, ,E H (C.S. Yi P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 and N. Liu), 157 para-Fluoro benzyl! substituted bis(indenyl) metallocenes as catalyst precursors in ethene polymerization (G. Jany, M. Gustafsson, T. Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskeli), 173 Sakurai reaction Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of and H.G. Alt), 205 allylic stannanes and silanes with methyl propiolate (H.-S. Dang PRAZEPAM and A.G. Davies), 67 C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- Samarium tion. Crystal structure of (L)Au[P(C,,H,CH ,-4),] (HL = 7-chloro- Cyclooctatetraenyl complexes of the early transition metals and lan- 1 ,3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- thanides. X. The first organometallic triple decker sandwich com- AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 M. Manassero and M. Sansoni), 405 Synthesis, structural characterisation and dynamic behaviour of penta- fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 Quinone Schiff base 7 y"a-q uinone, 7°D-eseimtieqlui none and 7°6- hydroquinone complexes :, of pen- Synthesis of the first mono(cyclopentadieny|)lanthanide Schiff base tamethylcyclopentadienyl iridium. X-ray molecular structure of complex bearing C,-symmetric tetradentate ligand: crystal struc- Subject Index of Volume 553 ture of [(m°-CH.)Yb( -OC 5) H 5) N,O)],( u-THFX THF) (Q. Liu sembly of three fused Na,O, cubane units and a 2 ,-water molecule and M. Ding), 179 (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. Secondary amine Sullivan), 23 Electrochemical reduction of some [(°-Cyclopentadieny]) (°-arene) Steric protection iron(ID][PF, ]c omplexes bearing an imine or a nitrone function in A convenient synthesis of a sterically protected 1|,4-diphosphabu- benzylic position of the arene ligand (F. Pierre, A. Stricker, C. tatriene and its pentacarbonyltungsten complexes (S. Ito, K. Toy- Moinet, S. Sinbandhit and L. Toupet), 253 ota and M. Yoshifuji), 135 Selective attack of nucleophile Structural analyses First examples of acylgold(1) complexes RCOAuPPh, (R = Me, n-Bu, Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- t-Bu, Ph) trapped as oxygen coordinated ligands L at one of phenylphosphanyDethane transition metal chelates (H. Brunner, A. rhenium atoms in Re,( u-PPh,),(CO),(ax-L) (H.-J. Haupt, D. Winter and J. Breu), 285 Petters and U. Flérke), 497 Structures Semiquinone Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und 7n*-quinone, 7°-semiquinone and 7°-hydroquinone complexes of pen- Templatreaktionen PH-funktioneller Bis(phosphinoethy|)amine (A. tamethylcyclopentadieny! iridium. X-ray molecular structure of HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 [Cp * Ir(m*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. Substitution Vaissermann), 483 A thermodynamic study of the electron transfer chain catalyzed Sila-bridged substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. Synthesis and characterization of a series of sila-bridged diiron com- Liu and S.L. Gipson), 269 plexes (E)[(°-,tH ,-)FBe(uCO)C], ( u-CO), (E = Me,Si, Sulfonamido Me,SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- Synthesis and structure of sulfonamido cyclopentadiene titanium com- and trans-(Me, Si)[n°-t-BuC ,H , )Fe(CO)},( u-CO), (Y. Zhang, plexes: X-ray structure of Ti(n*:o-C;H,CH,CH,NSO,C, S. Xu, G. Tian, X. Zhou and J. Sun), 149 H,CH,)CI, (C. Lensink), 387 Silicon Sulphur—oxygen ligands X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- Thioethercarboxylates in palladium chemistry: First proof of hemil- silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. abile properties of S—O ligands (W.H. Meyer, R. Brill, H.G. Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Raubenheimer, C. Thompson and G.J. Kruger), 83 Silole Supermesitylphosphaalkyne Synthesis and properties of dithienosiloles (J. Ohshita, M. Nodono, T. Different reaction modes of supermesitylphosphaalkyne with Watanabe, Y. Ueno, A. Kunai, Y. Harima, K. Yamashita and M. [W(CO).thf]-unusual C-H-activation forming an indanyl sub- Ishikawa), 487 stituent (P. Kramkowski, M. Scheer and G. Baum), 511 Silyl Silyl-Komplexe des Molybdans und Wolframs. Synthese, Reaktivitat und Struktur (S.H.A. Petri, B. Neumann, H.-G. Stammler und P. Tantalum Jutzi), 317 Utility of hydridotributyltin as both reductant and hydride transfer Silylacetylenic alcohols reagent in organotransition metal chemistry I. A convenient syn- An unusual rearrangement of 1|-trimethylsiloxy-3-bromomagnesium- thesis of the organoditantalum(IV) hydrides (7-C;Me,R),Ta,( p- H),Cl, (R = Me, Et) from (7-C;Me,R)TaCl,, and probes of the 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina and M.G. Voronkov), 481 possible reaction pathways (T.-Y. Lee and L. Messerle), 397 Silylene complex Thermogravimetry Thermal reactions of alkyl(hydridoXhydrosily)iridium(UIl) com- Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- plexes: generation of a hydrido(silylene)iridium(1) species via the gangsmetallen. CLX VI. Molekulare Organorhenium-Vorstufen fiir reductive elimination of alkane and 1,2-H-shift from the silicon CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and R.W. Fischer), 443 atom to the Ir(1) metal center (M. Okazaki, H. Tobita, Y. Kawano, S. Inomata and H. Ogino), | Through-space coupling Silyl ethers X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- An unusual rearrangement of 1|-trimethylsiloxy-3-bromomagnesium- silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 and M.G. Voronkov), 481 Tin(IV) complex Silyliridium Tin([V) and organotin(V) complexes containing mono or bidentate Thermal reactions of alkyl(hydridoXhydrosily)iridium(ID com- N-donor ligands. III. 1-methylimidazole derivatives: synthesis, plexes: generation of a hydrido(silylene)iridium(1) species via the spectroscopic and structural characterization (C. Pettinari, M. reductive elimination of alkane and 1,2-H-shift from the silicon Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi atom to the Ir(I) metal center (M. Okazaki, H. Tobita, Y. Kawano, and E. Rivarola), 345 S. Inomata and H. Ogino), | Titanium Silyl migration Synthesis and structure of sulfonamido cyclopentadiene titanium com- An unusual rearrangement of 1-trimethylsiloxy-3-bromomagnesium- plexes: X-ray structure of Ti(n*:o-C;H,CH,CH,NSO,C, H,CH,)CI, (C. Lensink), 387 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina and M.G. Voronkov), 481 Titanocene Single-source precursor Synthese und Reaktionsverhalten monomerer Bis(7?-Alkin)- Silyl-Komplexe des Molybdins und Wolframs. Synthese, Reaktivitat Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. Kohler, H. Pritzkow und H. Lang), 31 und Struktur (S.H.A. Petri, B. Neumann, H.-G. Stammler und P. Jutzi), 317 Synthesis and charracdt erization of TiC 5H; X2,4-C,H,,) Sodium [POCH,CH(O)C,H,O] and Ti(2,4-C,H,,), [POCH,CH(O) Formation and X-ray structure of [{O(Ph,SiONa),}, - (NaOH) - (HO) C,H,O] chiral phosphite adducts of an open and a half open -(7 pyridine)]- (tolu-e( pnyreidi)ne ) incorporating a unique as- titanocene (D. Vos, A.M. Arif and R.D. Ernst), 277

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Oe metallic Chemistry LSEVIE Journal of Organometallic Chemistry 553 (1998) 525-526 Author Index of Volume 553 A-ihara, N.-a., 493 Farfan, N., 221 Kreibl, F.R., 103 Abrahams, I., 23 Fischer, A., 111 Kriiger, C., 477 Aitola, E., 173 Fischer, R.W., 443 Kruger, G.J., 83 Alonso, F., 463 Flérke, U., 497 Kucken, S., 39 Alt, H.G., 205 Kiihn, F.E., 443 Amouri, H., 483 Garcia, M.H., 115 Kunai, A., 487 Ansari, M.A., 141 Garkusha, O.G., 59 Kunkely, H., 517 Antelmann, B., 433 Gerbrandij, A.W., 115 Arif, A.M., 277 Geyer, A., 331 Lang, H., 31 Ginyama, H., 163 Larina, L., 129 Barba, L., 345 Gipson, S.L., 269 Lazell, M., 23 Baum, G., 511 Goovaerts, E., 115 Le Bras, J., 483 Bayon, J.C., 199 Graf, M., 371 Lee, G.-H., 417 Beckhaus, R., 427 Gustafsson, ‘M.,:173 Lee, T.-Y., 397 Bildstein, B., 73 Gutierrez; A,, 221 Lehotkay, Th., 103 Bishop, L.A., 53 Lensink, C., 387 Bodensieck, U., 307 Hardt, T., 241 Leskela, M., 173 Borisov, G.K., 59 Harima, Y., 487 Lightfoot, P., 473 Borner, A., 99 Hart, S.L., 507 Lin, Y.-C., 417 Bottcher, H.-C., 371 Haupt, H.-J., 497 Liu, N., 157 Breu, J., 285 Heinemann, O., 477 Liu, Q., 179 Bricout, H., 469 Herrmann, W.A., 443 Liu, Z., 269 Brintzinger, H.-H., 331 HeBler, A., 39 Lokshin, B.V., 59 Bruhn, C., 371 Hiller, J., 15 Brill, R., 83 Holz, J., 99 Mach, K., 15 Brunner, H., 285 Hopfl, H., 221 Manassero, M., 405 Brusilovets, A.I., 379 Huttner, G., 433 McCamley, A., 507 McCormack, P.J., 507 Calhorda, M.J., 115 Iglesias, M., 193 Mealli, C., 115 Cassetta, A., 345 Inomata, S., | Medvedeva, A., 129 Castillo, D., 221 Ishikawa, M., 487 Medvedeva, A.S., 481 Chang, C.-W., 417 Ito, S., 135 Mendes, P., 115 Cinellu, M.A., 405 Merlic, C.A., 183 Cingolani, A., 345 Jaaskelainen, S., 453 Merzweiler, K., 371 Cole-Hamilton, D.J., 473 Jaitner, P., 103 Messerle, L., 397 Jany, G., 173 Meyer, W.H., 83 Damrau, H.-R.H., 331 Dang, H.-S., 67 Jerzykiewicz, L.B., 379 Migita, T., 493 Jolly, P.W., 477 Miliani, M., 345 Daran, J.-C., 221 Davies, A.G., 67 Jones, P.G., 111 Milius, W., 205 Jutzi, P., 317 Minghetti, G., 405 Davies, S.G., 463 Mochida, K., 163 Demina, M., 129 Demina, M.M., 481 Kawano, Y., | Moinet, C., 253 Khan, S.I., 141 Monflier, E., 469 Dias, A.R., 115 Ding, M., 179 Kira, M., 163 Mortreux, A., 469 Dobado, J.A., 173 Klaui, W., 241 Motevalli, M., 23 Dorta, R., 307 Kless, A., 99 Duarte, M.T., 115 Klinga, M., 173 Nakano, T., 493 Kohler, K., 31 Neumann, B., 317 Edelmann, F.T., 393 Kool, L.B., 53 Nief, F., 503 Enokido, T., 493 Kopacka, H., 73 Noda, S., 493 Ernst, R.D., 277 Kosugi, M., 493 Nodono, M., 487 Evans, W.J., 141 Kramkowski, P., 511 Novokshonov, V.V., 481 Elsevier Science S.A. 526 Author Index of Volume 553 Ogino, H., | Santillan, R., 221 Ueno, Y., 487 Ohshita, J., 487 Santos, A., 193 Utko, J., 379 Okazaki, M., | Schaper, F., 331 Oster, J., 427 Scheer, M., 511 Vaissermann, J., 483 Schmutzler, R., 111 Varga, V., 15 Pakkanen, T.A., 453 Schweiger, M., 73 Velikanov, A., 129 Peifer, B., 205 Serra, M.E.S., 199 Verhovnik, G.P.J., 477 Pellei, M., 345 Shah, S.A.A., 23 Vogler, A., 517 Pereira, J.P.R., 199 Sheldrick, W.S., 39 Voronkov, M., 129 Pereira, M.M., 199 Sinbandhit, S., 253 Voronkov, M.G., 481 Periasamy, M., 91 Smethurst, C.A.P., 463 Vos, D., 277 Petri, S.H.A., 317 Sobota, P., 379 Petters, D., 497 Stammler, H.-G., 317 Wachter, W.M., 443 Pettinari, C., 345 Stelzer, O., 39 Wang, Y., 417 Piedade, M.F.M., 115 Stoccoro, S., 405 Watanabe, T., 487 Pierre, F., 253 Stoeckli-Evans, H., 307 Weeber, A., 331 Pifferi, A., 345 Stricker, A., 253 Wenseleers, W., 115 Plack, V., 111 Sullivan, A.C., 23 Weston, W.S., 473 PolaSek, M., 15 Sun, G.-R., 111 Winter, A., 285 Poremba, P., 393 Sun, J., 149 Winterhalter, U., 433 Pritzkow, H.,.31 Siiss-Fink, G., 307 Wu, F., 183 Y Prosenc."M.<Pt} 3st? : * ** Wurst, K., 73, 103 Rao, MIEN. 9.rgd9 EP ~,o deo r : +"O P“sas k& a&Us 4%h ashi, Me Poe ?2) 163. - “Rising BMS Xu, S., 149 “Stamaik Is * sRaubenhéaner, H.G:.8 3° Taylor, .P.C..,S 07 ie at >R¥inke, r -99 s- “3. Thewalt, i a -+* Yamashita, K., 487 Yi, C.S., 157 Repo, T.; 173 Thompson, C., 83 Ricard, L., 503 Tian, G., 149 Yoshifuji, M., 135 Rivarola, E., 345 Ting, P.-C., 417 Rocha Gonsalves, A.M.d’A.., 19 Tobita, H., | Zhang, Y., 149 Toupet, L., 253 Zhou, X., 149 Sakhaii, P., 111 Toyota, K., 13 Ziller, J.W., 141 Sansoni, M., 405 Turner, ig : Zucca, A., 405 ournal ofOrgano. metallic ee! Chemistry ELSEVIER Journal of Organometallic Chemistry 553 (1998) 527-535 Subject Index of Volume 553 Absorption spectra Allyl iodide Electronic spectrum and photoreactivity of dimethyl(1,5-cyclo- Synthesis of ruthenium vinylidene complexes with dppe ligand and octadiene)-platinum(1) (H. Kunkely and A. Vogler), 517 their cyclopropenation reaction (C.-W. Chang, P.-C. Ting, Y.-C. Acetylenic alcohols Lin, G.-H. Lee and Y. Wang), 417 Universal method for trimethylsilylation of acetylenic alcohols and Allylsilanes . glycols (M. Demina, A. Velikanov, A. Medvedeva, L. Larina and Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of M. Voronkov), 129 allylic stannanes and silanes with methyl propiolate (H.-S. Dang Acetylenic glycols and A.G. Davies), 67 Universal method for trimethylsilylation of acetylenic alcohols and Allylstannanes glycols (M. Demina, A. Velikanov, A. Medvedeva, L. Larina and Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of M. Voronkov), 129 allylic stannanes and silanes with methyl propiolate (H.-S. Dang Acrylic acids and A.G. Davies), 67 Asymmetric transfer hydrogenation of acrylic acids catalyzed by Aluminium(ID) rhodium(I1) complexes of diphosphine ligands (A.M.d’A. Synthesies, properties and crystal structures of ionic [Al,( ,?- Rocha Gonsalves, J.C. Bayon, M.M. Pereira, M.E.S. Serra and thffo),(EtOH),CJlCI,, , [Al,(4,7?-thffo),Cl, AIEtCl,] and te- J.P.R. Pereira), 199 tranuclear [AlI,( u.7?-thffo),( u-OEv),Cl,] (thffo = OCH ,CH Acylation (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. L.B. Jerzykiewicz), 379 Wu), 183 Alumoxanes Acylgold(1) organyls as ligands Synthesies, properties and crystal structures of ionic [Al,( .?- First examples of acylgold(1) complexes RCOAuPPh, (R = Me, n-Bu, thffo),(EtOH),CJlCI,, , [Al ,(4,7?-thffo),Cl, JAIEtCl,] and te- t-Bu, Ph) trapped as oxygen coordinated ligands L at one of tranuclear [AlI,( u.7?-thffo),( u-OEU,Cl,] (thffo’=-OCH,CH rhenium atoms in Re,( u-PPh,),(CO),(ax-L) (H.-J. Haupt, D. (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets. and Petters and U. Flérke), 497 L.B. Jerzykiewicz), 379 Alkali metal Arene Synthesis and structure of alkali metal ‘ate’ complexes in the yt- Electrochemical reduction of some [(7°-Cyclopentadieny!) (7°-arene) trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, iron(ID][PR, ]c omplexes bearing an imine or a nitrone function in J.W. Ziller and S.I. Khan), 141 benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Alkene Moinet, S. Sinbandhit and L. Toupet), 253 The CoCl, /Ph(Et), N:BH , /CO system: Reactions of the borane and Aryl cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- Alkoxide gangsmetallen. CLXVI. Molekulare Organorhenium-Vorstufen fiir Synthesis and structure of alkali metal ‘ate’ complexes in the yt- CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, R.W. Fischer), 443 J.W. Ziller and S.I. Khan), 141 Arylpalladium complexes Alkoxides Thioethercarboxylates in palladium chemistry: First proof of hemil- Synthesies, properties and crystal structures of ionic [AI,( b.n?- abile properties of S—O ligands (W.H. Meyer, R. Brill, H.G. thffo),(EtOH),CJlCI,, , [Al,(2.n°-thffo),Cl, [AIEtCl,] and te- Raubenheimer, C. Thompson and G.J. Kruger), 83 tranuclear [Al,( .77-thffo),( u-OEt),Cl,] (thffo = OCH,CH Asymmetric (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and Asymmetric transfer hydrogenation of acrylic acids catalyzed by L.B. Jerzykiewicz), 379 rhodium(1) complexes of diphosphine ligands (A.M.d’A. Alkyl Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- J.P.R. Pereira), 199 gangsmetallen. CLXVI- Molekulare Organorhenium-Vorstufen fiir ‘Ate’ complex CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and Synthesis and structure of alkali metal ‘ate’ complexes in the yt- R.W. Fischer), 443 trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, Allylgermanes J.W. Ziller and S.I. Khan), 141 Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- | .4-benzodiazepin-2-ones manes with allylic chlorides at room temperature (T. Nakano, T. C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 tion. Crystal structure of (L)Au[P(C,,HCH ,-4),] (HL = 7-chloro- Elsevier Science S.A. Subject Index of Volume 553 | ,3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- Carbonylative cyclisations AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, The CoCl, /Ph(Et), N:BH ,/CO system: Reactions of the borane and M. Manassero and M. Sansoni), 405 cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 Carbonyls Heteroligand substitution in clusters of ruthenium and cobalt (T.M. Bis(diphenylphosphany|ethane type ligands Risinen, S. Jaiskeléinen and T.A. Pakkanen), 453 Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- Carbyne phenylphosphany|)ethane transition metal chelates (H. Brunner, A. Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von Winter and J. Breu), 285 Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fir Bis(phosphinoethy| amines die ring6ffnende metathetische Polymerisation von Cycloolefinen Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und (W. Klaui und T. Hardt), 241 Templatreaktionen PH-funktioneller Bis(phosphinoetahmyinle (A. Catalysis HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 A thermodynamic study of the electron transfer chain catalyzed Borinates substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. Study of cyclic borinates obtained from piperidine- and piperazine Liu and S.L. Gipson), 269 alcohols by spectroscopic methods and X-ray crystallography (H. Asymmetric transfer hydrogenation of acrylic acids catalyzed by H6épfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. rhodium(I1) complexes of diphosphine ligands (A.M.d’A. Daran), 221 Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and Boron complexes J.P.R. Pereira), 199 Study of cyclic borinates obtained from piperidine- and piperazine para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst alcohols by spectroscopic methods and X-ray crystallography (H. precursors in ethene polymerization (G. Jany, M. Gustafsson, T. H6pfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskelia), 173 Darah); 221 Catalytic carbonylation _ Bridging water . Modelling intermediates in the catalytic carbonylation of CH,I, to Formation and X-ray structure of [{O(Ph, SiONa), }, - (NaOH) - (HO) malonate esters; Evidence for a ketene pathway (W.S. Weston, P. -(7 pyridine)]- (tolu-e( pnyriedi)ne ) incorporating a unique as- Lightfoot and D.J. Cole-Hamilton), 473 sembly of three fused Na,O, cubane units and a jz, -water molecule _ Cerium (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. Cyclooctatetraenyl complexes of the early transition metals and lan- Sullivan), 23 thanides. X. The first organometallic triple decker sandwich com- Butadiene plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 Tetraferrocenyl-[3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka C—H-Activation and K. Wurst), 73 Different reaction modes of supermesitylphosphaalkyne with Butatriene [W(CO),thf]-unusual C-H-activation forming an indanyl sub- Tetraferrocenyl-(3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka stituent (P. Kramkowski, M. Scheer and G. Baum), 511 and K. Wurst), 73 Chelate Synthesies, properties and crystal structures of ionic [Al,( ,n?- thffo),(EtOH),CJlCl,, , [Al,(4,?-thffo),Cl, [AIEtCl,] and te- Coo tranuclear [AI,( ,7?-thffo),( u-OEt),Cl,] (thffo = OCH,CH Reactions of fullerenols C,)(OH), (x = 12, 18) with trialkoxysilanes (CH,),0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and (RO),Si(CH,),X (R = Me, X = Cl; R = Et, X = NH,) (M. Igle- L.B. Jerzykiewicz), 379 sias and A. Santos), 193 Chiral Carbene ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von plexes—syntheses, crystal structures and structural dynamics in Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fiir solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, die ring6ffnende metathetische Polymerisation von Cycloolefinen F. Schaper and H.-H. Brintzinger), 331 (W. Klaui und T. Hardt), 241 Synthesis of racemic chiral-at-metal complexes of the group 4 metals Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. by a lithium chloride catalysed ligand redistribution reaction (S.L. Wu), 183 Hart, A. McCamley, P.J. McCormack and P.C. Taylor), 507 Carbon—hydrogen bond activation Chiral diphosphine Thermal reactions of alkyl(hydridohydrosily)iridium(ID com- Asymmetric transfer hydrogenation of acrylic acids catalyzed by plexes: generation of a hydrido(silylene)iridium(1) species via the rhodium(I) complexes of diphosphine ligands (A.M.d’A. reductive elimination of alkane and 1,2-H-shift from the silicon Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and atom to the Ir(I) metal center (M. Okazaki, H. Tobita, Y. Kawano, J.P.R. Pereira), 199 S. Inomata and H. Ogino), | Chirality transfer Carbonyl Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. phenylphosphanyiethane transition metal chelates (H. Brunner, A. Wu), 183 Winter and J. Breu), 285 Synthesis of triruthenium clusters containing mixed bridging phos- Chiral phosphite phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- Synthesis and __ characterization of Ti(C 5H; 2,4-C,H,,) PBu{ 4‘-PC,y,) ,] and the electron-deficient complex [Ru,( y- [POCH,CH(O)C,H,O] and Ti(2,4-C,H,,), [POCH,CH(O) COXCO),( u-H),( u-PBu} ),(Bu, PH)] (M. Graf, K. Merzweiler, C,H,O] chiral phosphite adducts of an open and a half open C. Bruhn and H.-C. Béttcher), 371 titanocene (D. Vos, A.M. Arif and R.D. Ernst), 277 Carbonylation Chromium The CoCl, /Ph(Et), N:BH ,/CO system: Reactions of the borane and A facile access to CpCr (acac)Cl and related systems (O. Heinemann, cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 Subject Index of Volume 553 529 Synthesis of B-keto Fischer carbene complexes (C.A. Merlic and F. Synthesis and structure of sulfonamido cyclopentadiene titanium com- Wu), 183 plexes: X-ray structure of Ti(n°:0-C;H,CH,CH,NSO,C, Cluster H,CH,)CI, (C. Lensink), 387 Fixation of triruthenium clusters on melamine: synthesis and structure Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base of [Ru,( ,-H{ 4X,,7?C-NHC,ON,(N)H,), }], cis-[{Ru,(2,- complex bearing C,-symmetric tetradentate ligand: crystal struc- HXC3O.77:) 43,,9°-}NHC,,N,({NH,) }] and trans-{{Ru,( y- ture of [(m°-C 5H.) Yb 4-OC 5) H 59 N,O)],( u-THFX THF) (Q. Liu HCO) },{ 43.77: 43.n°-NHC,N,(NH,)}] (R. Dorta, H. and M. Ding), 179 Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 Synthesis of triruthenium clusters containing mixed bridging phos- Synthesis of triruthenium clusters containing mixed bridging phos- phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- phido ligands: X-ray crystal structures of [Ru,(CO),( u-H) p- PBXu u-P'Cy,) ,] and the electron-deficient complex [Ru, ( y- PBXu u-‘PCy,,) ,] and the electron-deficient complex [Ru,( y- COXCO),( -H),( u-PBu5 ),(Bu, PH)] (M. Graf, K. Merzweiler, COXCO),( u-H),( u-PBu’, ),(Bu PH)] (M. Graf, K. Merzweiler, C. Bruhn and H.-C. Bottcher), 371 C. Bruhn and H.-C. Béttcher), 371 C,-symmetry Cobalt carbonyl reagents Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base The CoCl, /Ph(Et), N:BH ,/CO system: Reactions of the borane and complex bearing C,-symmetric tetradentate ligand: crystal struc- cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 ture of [(m°-C 5H.) Yb( 4-OC 5) H 5) NO)],( u-THFX THF) (Q. Liu 7-Complex and M. Ding), 179 Synthesis, structural characterisation and dynamic behaviour of penta- Cumulene fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 Tetraferrocenyl-(3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka Complexes and K. Wurst), 73 Wasserlisliche Phosphane VII. Synthese, Koordinationschemie und CVD Templatreaktionen PH-funktioneller Bis(phosphinoethylamine (A. Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 gangsmetallen. CLXVI. Molekulare Organorhenium-Vorstufen fiir Conducting polymer CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and Synthesis and properties of dithienosiloles (J. Ohshita, M. Nodono, T. R.W. Fischer), 443 Watanabe, Y. Ueno, A. Kunai, Y. Harima, K. Yamashita and M. Cyclooctatetraenyl complexes Ishikawa), 487 Cyclooctatetraenyl complexes of the early transition metals and lan- Configuration thanides. X. The first organometallic triple decker sandwich com- ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 plexes—syntheses, crystal structures and structural dynamics in Cyclopentadiene solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, Synthesis and structure of sulfonamido cyclopentadiene titanium com- F. Schaper and H.-H. Brintzinger), 331 plexes: X-ray structure of Ti(n*:o-C;H,CH,CH,NSO,C, Conformational analysis H,CH,)CI, (C. Lensink), 387 Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- Cyclopentadieny| phenylphosphany)ethane transition metal chelates (H. Brunner, A. A facile access to CpCr (acac)Cl and related systems (O. Heinemann, Winter and J. Breu), 285 P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 Coordinative N — B bond Electrochemical reduction of some [(7°-Cyclopentadieny!) (°-arene) Study of cyclic borinates obtained from piperidine- and piperazine iron(II) |[PF, ] complexes bearing an imine or a nitrone function in alcohols by spectroscopic methods and X-ray crystallography (H. benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Ho6pfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. Moinet, S. Sinbandhit and L. Toupet), 253 Daran), 221 Synthesis and characterization of a series of sila-bridged diiron com- Copper(I) fluoride plexes (E)[(m°-t-BuC,H ,) Fe(CO)],( u-CO), (E = Me,Si, Synthese und Reaktionsverhalten monomerer Bis(?-Alkin)- Me,SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. Kohler, and trans-(Me,Si)[n°-t-BuC,H ,)Fe(CO)],( u-CO), (Y. Zhang, H. Pritzkow und H. Lang), 31 S. Xu, G. Tian, X. Zhou and J. Sun), 149 Copper(I) hydride Synthese und Reaktionsverhalten monomerer Bis(7?-Alkin)- Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. K@hler, H. Pritzkow und H. Lang), 31 Copper-mediated coupling reaction A convenient synthesis of a sterically protected 1,4-diphosphabu- Delocalization tatriene and its pentacarbonyltungsten complexes (S. Ito, K. Toy- Organometallic nickel(II) complexes with substituted benzonitrile lig- ota and M. Yoshifuji), 135 ands. Synthesis, electrochemical studies and non-linear optical Crystal structure properties. The X-ray crystal structure of [Ni(m°-C,H,) Formation and X-ray structure of [(O(Ph,SiONa),}, - (NaOH) - (HO) {P(C,.H;),;(NCC,H,N[HPR,] (A.R. Dias, M.H. Garcia, P. -(7 pyridine)]- (tolu-e( pnyreidi)ne ) incorporating a unique as- Mendes, M.F.M. Piedade, M.T. Duarte, M.J. Calhorda, C. Mealli, sembly of three fused Na,O, cubane units and a . ,-water molecule W. Wenseleers, A.W. Gerbrandij and E. Goovaerts), 115 (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. Dialkylketone Sullivan), 23 The CoCl, /Ph(EN:tBH) ,,/C O system: Reactions of the borane and Synthesies, properties and crystal structures of ionic [Al,( ,n?- cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 thffo),(EtOH),CJlCI,, , [Al,(4,?-thffo),Cl, [AIEtC],] and te- DIAZEPAM tranuclear [Al,( ,7?-thffo),( 4-OEt),Cl,] (thffo = OCH,CH C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- (CH ,),;0) compounds (P. Sobota, J. Utko, A.I. Brusilovets and tion. Crystal structure of (L)Au[P(C,,H,CH ,-4),] (HL = 7-chloro- L.B. Jerzykiewicz), 379 1 ,3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- Subject Index of Volume 553 AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and M. Manassero and M. Sansoni), 405 J.P.R. Pereira), 199 Dicyclopentadienylzinc (Cp, Zn) Fullerenol Vibrational spectra and structure of dicyclopentadienylzine (O.G. Reactions of fullerenols C,,(OH), (x = 12, 18) with trialkoxysilanes Garkusha, B.V. Lokshin and G.K. Borisov), 59 (RO),Si(CH,),X (R = Me, X = Cl; R = Et, X = NH,) (M. Igle- Digermane sias and A. Santos), 193 Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- Fulvalene manes with allylic chlorides at room temperature (T. Nakano, T. Synthesis, structural characterisation and dynamic behaviour of penta- Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 Dimerisation Functionalised cyclopentadieny| Different reaction modes of supermesitylphosphaalkyne with Funktionalisierte cyclopentadienylliganden fiir den aufbau von [W(CO).thf]-unusual C-H-activation forming an indanyl sub- tripod-komplexen: synthese und komplexchemie (B. Antelmann, stituent (P. Kramkowski, M. Scheer and G. Baum), 511 G. Huttner und U. Winterhalter), 433 | .4-Diphosphabutatriene A convenient synthesis of a sterically protected 1,4-diphosphabu- Germanium tatriene and its pentacarbonyltungsten complexes (S. Ito, K. Toy- Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- ota and M. Yoshifuji), 135 manes with allylic chlorides at room temperature (T. Nakano, T. Dirhenium complexes Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 First examples of acylgold(1) complexes RCOAuPPh, (R = Me, n-Bu, Germy| radical t-Bu, Ph) trapped as oxygen coordinated ligands L at one of Photochemical reactions of digermanyl-substituted naphthalenes: The rhenium atoms in Re,( u-PPh,),(CO),(ax-L) (H.-J. Haupt, D. germyl! migration to the aromatic ring (K. Mochida, H. Ginyama, Petters and U. Flérke), 497 M. Takahashi and M. Kira), 163 Dithiacylohexane Gold Heteroligand substitution in clusters of ruthenium and cobalt (T.M. C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- Riisinen, S. Jéiskeliinen and T.A. Pakkanen), 453 tion. Crystal structure of (L)Au[P(C,,HCH ,-4),] (HL = 7-chloro- | 3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- Electrochemical reduction AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, Electrochemical reduction of some [(7°-Cyclopentadieny!) (7°-arene) M. Manassero and M. Sansoni), 405 iron(II) |[PF, ]c omplexes bearing an imine or a nitrone function in Group metal benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Synthesis of racemic chiral-at-metal complexes of the group 4 metals Moinet, S. Sinbandhit and L. Toupet), 253 by a lithium chloride catalysed ligand redistribution reaction (S.L. Electrochemistry Hart, A. McCamley, P.J. McCormack and P.C. Taylor), 507 Tetraferrocenyl-[3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka and K. Wurst), 73 Electron-transfer Hafnium A thermodynamic study of the electron transfer chain catalyzed para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. precursors in ethene polymerization (G. Jany, M. Gustafsson, T. Liu and S.L. Gipson), 269 Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskela), 173 Ene reaction Hapticity Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- allylic stannanes and silanes with methyl propiolate (H.-S. Dang plexes—syntheses, crystal structures and structural dynamics in and A.G. Davies), 67 solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, Ethylene F. Schaper and H.-H. Brintzinger), 331 A facile access to CpCr (acac)CI and related systems (O. Heinemann, Head-to-tail dimerization of acrylic compounds P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 Ruthenium-mediated selective head-to-tail dimerization of acrylic and a, B-unsaturated carbonyl compounds: generation of an acrylate- Ferrocene hydride complex C;Me;Ru(PCy,;(CH,=CHCO,EvH (C.S. Yi Tetraferrocenyl-{3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka and N. Liu), 157 and K. Wurst), 73 Hemilability Ferrocenecarboxaldehyde Thioethercarboxylates in palladium chemistry: First proof of hemil- Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-|,3- abile properties of S—O ligands (W.H. Meyer, R. Brill, H.G. oxazolidin-5-ones (F. Alonso, $.G. Davies and C.A.P. Smethurst), Raubenheimer, C. Thompson and G.J. Kruger), 83 463 Heterogeneous catalysis Fluorine Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- and H.G. Alt), 205 silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. Hydride Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Utility of hydridotributyltin as both reductant and hydride transfer Formates reagent in organotransition metal chemistry I. A convenient syn- Asymmetric transfer hydrogenation of acrylic acids catalyzed by thesis of the organoditantalum(IV) hydrides (7-C ;Me,R),Ta,( p- rhodium(I1) complexes of diphosphine ligands (A.M.d’A. H),Cl, (R = Me, Et) from (m-C;Me,R)TaCl,, and probes of the Rocha Gonsalves, J.C. Bayén, M.M. Pereira, M.E.S. Serra and possible reaction pathways (T.-Y. Lee and L. Messerle), 397 J.P.R. Pereira), 199 Hydridotri(buty)tin Formic acid Utility of hydridotributyltin as both reductant and hydride transfer Asymmetric transfer hydrogenation of acrylic acids catalyzed by reagent in organotransition metal chemistry I. A convenient syn- rhodium(1) complexes of diphosphine ligands (A.M.d’A. thesis of the organoditantalum(IV) hydrides (n-C;Me,R),Ta>( p- Subject Index of Volume 553 531 H),Cl, (R = Me, Et) from (7-C,Me,R)TaCl,, and probes of the Synthese und Reaktionsverhalten monomerer Bis(?-Alkin)- possible reaction pathways (T.-Y. Lee and L. Messerle), 397 Kupfer(1)-Fluorid- und-Kupfer(1)-Hydrid-Komplexe (K. K6hler, Hydroboration H. Pritzkow und H. Lang), 31 The CoCl, /Ph(Et), N:BH,/CO system: Reactions of the borane and Melamine cobalt carbonyl species (M.L.N. Rao and M. Periasamy), 91 Fixation of triruthenium clusters on melamine: synthesis and structure Hydroquinone of [Ru,( 2>-HXCO)o{ ~3,n?-NHC,N,(NH,),}], cis-[{Ru,( p,- n*-quinone, 7°-semiquinone and 7°-hydroquinone complexes of pen- HXC4O3.77): 43,.9°-}NHC,.N,({NH,) }] and trans-[{Ru,( >- tamethylcyclopentadieny! iridium. X-ray molecular structure of H\CO),}{ 43,.77?:43.n’°-NHC,N,(NH,)}] (R. Dorta, H. [Cp * Ir(y*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 Vaissermann), 483 Metal carbony! Synthesis and characterization of a series of sila-bridged diiron com- Indenyl plexes (E)[(m°-t-Bu,CH ,)Fe(CO)],( u-CO), (E = Me,Si, para-Fluoro benzyl substituted bis(indenyl) metallocenes as catalyst Me,SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- precursors in ethene polymerization (G. Jany, M. Gustafsson, T. and trans-(Me, Si)[n°-t-BuC ,H ,)Fe(CO)],( u-CO), (Y. Zhang, Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskela), 173 S. Xu, G. Tian, X. Zhou and J. Sun), 149 Iron Metalla—phospha—carbon ring system A thermodynamic study of the electron transfer chain catalyzed Conversion of 1?-phosphinocarbene complexes into tungstaphos- substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. phabicyclo[1.1.0]butanone units (Th. Lehotkay, K. Wurst, P. Jait- Liu and S.L. Gipson), 269 ner and F.R. Kreibl), 103 Electrochemical reduction of some [(°-Cyclopentadieny]) (7°-arene) Metallasiloxane iron(II) |[PF, ]c omplexes bearing an imine or a nitrone function in Formation and X-ray structure of [{O(Ph, SiONa),}, - (NaOH) - (HO) benzylic position of the arene ligand (F. Pierre, A. Stricker, C. -(7 pyridine)]- (tolu-e( pnyriedi)ne ) incorporating a unique as- Moinet, S. Sinbandhit and L. Toupet), 253 sembly of three fused Na,O, cubane units and a . ,-water molecule Synthesis and characterization of a series of sila-bridged diiron com- (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. plexes (E)[(m°-t-Bu;CH ,)Fe(CO)],( u-CO), (E = Me,Si, Sullivan), 23 Me, SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- Metallocene and trans-(Me, Si)[n°-t-BuC ;H ,)Fe(CO)],( u-CO), (Y. Zhang, Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius S. Xu, G. Tian, X. Zhou and J. Sun), 149 and H.G. Alt), 205 Tetraferroceny|-{(3]-cumulene (B. Bildstein, M. Schweiger, H. Kopacka ansa-Metallocene and K. Wurst), 73 ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- Iron complexes plexes—syntheses, crystal structures and structural dynamics in Funktionalisierte cyclopentadienylliganden fiir den aufbau von solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, tripod-komplexen: synthese und komplexchemie (B. Antelmann, F. Schaper and H.-H. Brintzinger), 331 G. Huttner und U. Winterhalter), 433 Metallocenes Isomerization Synthesis of racemic chiral-at-metal complexes of the group 4 metals Isomerization of olefins in a two-phase system by homogeneous by a lithium chloride catalysed ligand redistribution reaction (S.L. water-soluble nickel complexes (H. Bricout, A. Mortreux and E. Hart, A. McCamley, P.J. McCormack and P.C. Taylor), 507 Monflier), 469 Metalloene reaction Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of Labelling studies allylic stannanes and silanes with methyl propiolate (H.-S. Dang Modelling intermediates in the catalytic carbonylation of CH,I, to and A.G. Davies), 67 malonate esters; Evidence for a ketene pathway (W.S. Weston, P. Metathesis Lightfoot and D.J. Cole-Hamilton), 473 Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- Lanthanide manes with allylic chlorides at room temperature (T. Nakano, T. Synthesis, structural characterisation and dynamic behaviour of penta- Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 1-methylimidazole derivative Laser photolysis Tin(IV) and organotin(IV) complexes containing mono or bidentate Photochemical reactions of digermanyl-substituted naphthalenes: The N-donor ligands. III. 1l-methylimidazole derivatives: synthesis, germyl migration to the aromatic ring (K. Mochida, H. Ginyama, spectroscopic and structural characterization (C. Pettinari, M. M. Takahashi and M. Kira), 163 Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi and E. Rivarola), 345 Macrocycles | ,2-migration Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und Thermal reactions of alkyl(hydridoXhydrosily)iridium(UILD) com- Templatreaktionen PH-funktioneller Bis(phosphinoethy])amine (A. plexes: generation of a hydrido(silylene)iridium(1) species via the HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 reductive elimination of alkane and 1,2-H-shift from the silicon Magnesium atom to the Ir(I) metal center (M. Okazaki, H. Tobita, Y. Kawano, ansa-Metallocene derivatives. XLI. Chiral ansa-Magnesocene com- S. Inomata and H. Ogino), |! plexes—syntheses, crystal structures and structural dynamics in Migration solution (H.-R.H. Damrau, A. Geyer, M.-H. Prosenc, A. Weeber, Photochemical reactions of digermanyl-substituted naphthalenes: The F. Schaper and H.-H. Brintzinger), 331 germyl migration to the aromatic ring (K. Mochida, H. Ginyama, Mechanism M. Takahashi and M. Kira), 163 Modelling intermediates in the catalytic carbonylation of CH,1I, to Molybdenum(0) malonate esters; Evidence for a ketene pathway (W.S. Weston, P. Studies on the formation of uniform 7*-coordinated triphos-Mo(0)- Lightfoot and D.J. Cole-Hamilton), 473 complexes (A. Kless, J. Holz, H. Reinke and A. Borner), 99 532 Subject Index of Volume 553 Molybdenum Organodimetallics Silyl-Komplexe des Molybdins und Wolframs. Synthese, Reaktivitat Utility of hydridotributyltin as both reductant and hydride transfer und Struktur (S.H.A. Petri, B. Neumann, H.-G. Stammler und P. reagent in organotransition metal chemistry I. A convenient syn- Jutzi), 317 thesis of the organoditantalum(IV) hydrides (7-C;Me,R),Ta,( p- Multi-cluster H),Cl, (R = Me, Et) from (7-C;Me,R)TaCl,, and probes of the Fixation of triruthenium clusters on melamine: synthesis and structure possible reaction pathways (T.-Y. Lee and L. Messerle), 397 of [Ru,( 4,-HXCO).{ u3.7?-NHC,N,(NH,),}], cis-[{Ru,( »- Organolanthanides HXCO) }.{ 43.77: 3.9?-NHC,N,(NH,)}] and trans-[{Ru,( p>- Cyclooctatetraeny! complexes of the early transition metals and lan- HCO) },{ 43.7: 43.n°-NHC,N,(NH,)}] (R. Dorta, H. thanides. X. The first organometallic triple decker sandwich com- Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 Organometallic Ni Naphthylgermane Organometallic nickel(I]) complexes with substituted benzonitrile lig- Photochemical reactions of digermanyl-substituted naphthalenes: The ands. Synthesis, electrochemical studies and non-linear optical germyl! migration to the aromatic ring (K. Mochida, H. Ginyama, properties. The X-ray crystal structure of [Ni(m°-C;H,{P(C, M. Takahashi and M. Kira), 163 H,;),4NCC,H,N[HP,R] (A.R. Dias, M.H. Garcia, P. Mendes, N-donor ligand M.F.M. Piedade, M.T. Duarte, M.J. Calhorda, C. Mealli, W. Tin(IV) and organotin(IV) complexes containing mono or bidentate Wenseleers, A.W. Gerbrandij and E. Goovaerts), 115 N-donor ligands. III. 1l-methylimidazole derivatives: synthesis, Organosilicon polymer spectroscopic and structural characterization (C. Pettinari, M. Synthesis and properties of dithienosiloles (J. Ohshita, M. Nodono, T. Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi Watanabe, Y. Ueno, A. Kunai, Y. Harima, K. Yamashita and M. and E. Rivarola), 345 Ishikawa), 487 Neodymium Organotin(IV) complex Cyclooctatetraenyl complexes of the early transition metals and lan- Tin(V) and organotin(IV) complexes containing mono or bidentate thanides. X. The first organometallic triple decker sandwich com- N-donor ligands. III. 1-methylimidazole derivatives: synthesis, plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 spectroscopic and structural characterization (C. Pettinari, M. Nickel Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi Isomerization of olefins in a two-phase system by homogeneous and E. Rivarola), 345 water-soluble nickel complexes (H. Bricout, A. Mortreux and E. Organoytterbium complex Monflier), 469 Synthesis of the first mono(cyclopentadienyl)lanthanide Schiff base Nitrile orbitals complex bearing C,-symmetric tetradentate ligand: crystal struc- Organometallic nickel(II) complexes with substituted benzonitrile lig- ture of [(7°-C;H.)Yb( 4-OC 5) H49N,O)],( u-THFXTHF) (Q. Liu ands. Synthesis, electrochemical studies and non-linear optical and M. Ding), 179 properties. The X-ray crystal structure of [Ni(m°-C;H,XP(C, Oxazolidinone H,),4NCC,H,N)JH[P,R, ] (A.R. Dias, M.H. Garcia, P. Mendes, Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-1,3- M.F.M. Piedade, M.T. Duarte, M.J. Calhorda, C. Mealli, W. oxazolidin-5-ones (F. Alonso, $.G. Davies and C.A.P. Smethurst), Wenseleers, A.W. Gerbrandij and E. Goovaerts), 115 463 NMR Oxidative coupling reaction X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- Synthesis of ruthenium vinylidene complexes with dppe ligand and silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. their cyclopropenation reaction (C.-W. Chang, P.-C. Ting, Y.-C. Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Lin, G.-H. Lee and Y. Wang), 417 NMR spectroscopy Oxo complexes Synthesis and __ characterization of TiC 5H; X2,4-C,H,,) Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von [POCH,CH(O)C,H,O] and Ti(2,4-C,H,,), [POCH,CH(O) Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fiir C,H,O] chiral phosphite adducts of an open and a half open die ring6ffnende metathetische Polymerisation von Cycloolefinen titanocene (D. Vos, A.M. Arif and R.D. Ernst), 277 (W. Klaui und T. Hardt), 241 Nuclear magnetic resonance Studies on the formation of uniform 7*-coordinated triphos-Mo(0)- complexes (A. Kless, J. Holz, H. Reinke and A. Borner), 99 Palladium Olefin Thioethercarboxylates in palladium chemistry: First proof of hemil- Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius abile properties of S—O ligands (W.H. Meyer, R. Briill, H.G. and H.G. Alt), 205 Raubenheimer, C. Thompson and G.J. Kruger), 83 O,-oxidation Palladium-catalysis Electrochemical reduction of some [(°-Cyclopentadieny]) (7°-arene) Palladium-catalyzed metathesis of phenylalkyl- or chloroalkyldiger- iron(ID][PF, ]c omplexes bearing an imine or a nitrone function in manes with allylic chlorides at room temperature (T. Nakano, T. benzylic position of the arene ligand (F. Pierre, A. Stricker, C. Enokido, S. Noda, N.-a. A-ihara, M. Kosugi and T. Migita), 493 Moinet, S. Sinbandhit and L. Toupet), 253 Pentamethylcyclopentadienide Organic halides Synthesis and structure of alkali metal ‘ate’ complexes in the yt- Synthesis of ruthenium vinylidene complexes with dppe ligand and trium /2,6-dimethylphenoxide system (W.J. Evans, M.A. Ansari, their cyclopropenation reaction (C.-W. Chang, P.-C. Ting, Y.-C. J.W. Ziller and S.I. Khan), 141 Lin, G.-H. Lee and Y. Wang), 417 Pentamethylcyclopentadieny] iridium Organo copper(I) 7n*-quinone, 7°-semiquinone and n°-hydroquinone complexes of pen- Synthese und Reaktionsverhalten monomerer Bis(?-Alkin)- tamethylcyclopentadienyl iridium. X-ray molecular structure of Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. Kohler, [Cp * Ir(n*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. H. Pritzkow und H. Lang), 31 Vaissermann), 483 Subject Index of Volume 553 533 Peralkylcyclopentadieny| [Cp * Ir(m*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. Utility of hydridotributyltin as both reductant and hydride transfer Vaissermann), 483 reagent in organotransition metal chemistry I. A convenient syn- thesis of the organoditantalum(IV) hydrides (n-C;Me,R),Ta,( u- Raman spectra H),Cl, (R = Me, Et) from (7-C,Me,R)TaCl,, and probes of the Vibrational spectra and structure of dicyclopentadienylzinc (O.G. possible reaction pathways (T.-Y. Lee and L. Messerle), 397 Garkusha, B.V. Lokshin and G.K. Borisov), 59 Periphery- and Template reactions X-Ray analysis of E- and Z-(ethylene)isomers Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- Templatreaktionen PH-funktioneller Bis(phosphinoethyl)amine (A. silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Phenyl ring orientation Rearrangement Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- An unusual rearrangement of 1|-trimethylsiloxy-3-bromomagnesium- phenylphosphany)ethane transition metal chelates (H. Brunner, A. 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina Winter and J. Breu), 285 and M.G. Voronkov), 481 Phosphido-bridged Reduction Synthesis of triruthenium clusters containing mixed bridging phos- A thermodynamic study of the electron transfer chain catalyzed phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. PBXu u‘-PC,y,) ,] and the electron-deficient complex [Ru,( p- Liu and S.L. Gipson), 269 COXCO),( u-H),( u-PBu ),(Bu PH)] (M. Graf, K. Merzweiler, Rhenium C. Bruhn and H.-C. Béttcher), 371 Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- Phosphinidene complexes gangsmetallen. CLXVI. Molekulare Organorhenium-Vorstufen fiir Different reaction modes of supermesitylphosphaalkyne with CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and [W(CO),thf]-unusual C-H-activation forming an indanyl sub- R.W. Fischer), 443 stituent (P. Kramkowski, M. Scheer and G. Baum), 511 Rhodium complexes n°-Phosphinocarbene complex Modelling intermediates in the catalytic carbonylation of CH,I, to Conversion of 77?-phosphinocarbene complexes into tungstaphos- malonate esters; Evidence for a ketene pathway (W.S. Weston, P. phabicyclof[1.1.0]butanone units (Th. Lehotkay, K. Wurst, P. Jait- Lightfoot and D.J. Cole-Hamilton), 473 ner and F.R. KreiBl), 103 ROMP Photochemistry Neue Wolfram(VI) carbin- und Carbenkomplexe durch Reaktion von Electronic spectrum and photoreactivity of dimethyl(1,5-cyclo- Chlorocarbinkomplexen mit Nukleophilen. Neue Katalysatoren fur octadiene)-platinum(ID (H. Kunkely and A. Vogler), 517 die ring6ffnende metathetische Polymerisation von Cycloolefinen Photolysis (W. Kliaui und T. Hardt), 241 Photochemical reactions of digermanyl-substituted naphthalenes: The Ruthenium germyl! migration to the aromatic ring (K. Mochida, H. Ginyama, Fixation of triruthenium clusters on melamine: synthesis and structure M. Takahashi and M. Kira), 163 of [Ru,( 4,-HXCO),{ ~3,n?-NHC,N,(NH,),}], cis-[{Ru,( 25- Piperidine- and piperazine alcohols HXCO)o}5{ 43.797: 43.9°-NHC,N,(NH,)}] and trans-[{Ru,( 5- Study of cyclic borinates obtained from piperidine- and piperazine HCO) }.{ 3,77: 43,.n°-NHC,N,(NH,)}] (R. Dorta, H. alcohols by spectroscopic methods and X-ray crystallography (H. Stoeckli-Evans, U. Bodensieck and G. Siiss-Fink), 307 H6pfl, N. Farfan, D. Castillo, R. Santillan, A. Gutierrez and J.-C. Heteroligand substitution in clusters of ruthenium and cobalt (T.M. Daran), 221 Risiinen, S. Jiaiiskeléinen and T.A. Pakkanen), 453 Planar chirality Synthesis of triruthenium clusters containing mixed bridging phos- Synthesis and reactivity of a range of 2-ferrocenyl-3-pivaloyl-1,3- phido ligands: X-ray crystal structures of [Ru,(CO),( u-HX p- oxazolidin-5-ones (F. Alonso, S.G. Davies and C.A.P. Smethurst), PBu’,X u4-PCy,),] and the electron-deficient complex [Ru, ( p- 463 COXCO),( u-H),( u-PBu', ),(Bu', PH)] (M. Graf, K. Merzweiler, Platinum complexes C. Bruhn and H.-C. Béttcher), 371 Electronic spectrum and photoreactivity of dimethyl(1,5-cyclo- Ruthenium-hydride complexes octadiene)-platinum(II) (H. Kunkely and A. Vogler), 517 Ruthenium-mediated selective head-to-tail dimerization of acrylic and Polymerization a, B-unsaturated carbonyl compounds: generation of an acrylate- A facile access to CpCr (acac)Cl and related systems (O. Heinemann, hydride complex C;Me,R(uCH(, P=CCHCOy, ,E H (C.S. Yi P.W. Jolly, C. Kriiger and G.P.J. Verhovnik), 477 and N. Liu), 157 para-Fluoro benzyl! substituted bis(indenyl) metallocenes as catalyst precursors in ethene polymerization (G. Jany, M. Gustafsson, T. Repo, E. Aitola, J.A. Dobado, M. Klinga and M. Leskeli), 173 Sakurai reaction Selbstimmobilisierende Metallocenkatalysatoren (B. Peifer, W. Milius Lewis acid catalysed M-ene, H-ene, and cycloaddition reactions of and H.G. Alt), 205 allylic stannanes and silanes with methyl propiolate (H.-S. Dang PRAZEPAM and A.G. Davies), 67 C(3) aurated 1,4-benzodiazepin-2-ones. Synthesis and characteriza- Samarium tion. Crystal structure of (L)Au[P(C,,H,CH ,-4),] (HL = 7-chloro- Cyclooctatetraenyl complexes of the early transition metals and lan- 1 ,3-dihydro-1- methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DI- thanides. X. The first organometallic triple decker sandwich com- AZEPAM) (G. Minghetti, A. Zucca, M.A. Cinellu, S. Stoccoro, plexes of the lanthanides (P. Poremba and F.T. Edelmann), 393 M. Manassero and M. Sansoni), 405 Synthesis, structural characterisation and dynamic behaviour of penta- fulvalenyldilanthanide(II) complexes (F. Nief and L. Ricard), 503 Quinone Schiff base 7 y"a-q uinone, 7°D-eseimtieqlui none and 7°6- hydroquinone complexes :, of pen- Synthesis of the first mono(cyclopentadieny|)lanthanide Schiff base tamethylcyclopentadienyl iridium. X-ray molecular structure of complex bearing C,-symmetric tetradentate ligand: crystal struc- Subject Index of Volume 553 ture of [(m°-CH.)Yb( -OC 5) H 5) N,O)],( u-THFX THF) (Q. Liu sembly of three fused Na,O, cubane units and a 2 ,-water molecule and M. Ding), 179 (I. Abrahams, M. Lazell, M. Motevalli, S.A.A. Shah and A.C. Secondary amine Sullivan), 23 Electrochemical reduction of some [(°-Cyclopentadieny]) (°-arene) Steric protection iron(ID][PF, ]c omplexes bearing an imine or a nitrone function in A convenient synthesis of a sterically protected 1|,4-diphosphabu- benzylic position of the arene ligand (F. Pierre, A. Stricker, C. tatriene and its pentacarbonyltungsten complexes (S. Ito, K. Toy- Moinet, S. Sinbandhit and L. Toupet), 253 ota and M. Yoshifuji), 135 Selective attack of nucleophile Structural analyses First examples of acylgold(1) complexes RCOAuPPh, (R = Me, n-Bu, Enantioselective catalysis. Part 114. Chirostructural analysis of bis(di- t-Bu, Ph) trapped as oxygen coordinated ligands L at one of phenylphosphanyDethane transition metal chelates (H. Brunner, A. rhenium atoms in Re,( u-PPh,),(CO),(ax-L) (H.-J. Haupt, D. Winter and J. Breu), 285 Petters and U. Flérke), 497 Structures Semiquinone Wasserlésliche Phosphane VII. Synthese, Koordinationschemie und 7n*-quinone, 7°-semiquinone and 7°-hydroquinone complexes of pen- Templatreaktionen PH-funktioneller Bis(phosphinoethy|)amine (A. tamethylcyclopentadieny! iridium. X-ray molecular structure of HeBler, S. Kucken, O. Stelzer und W.S. Sheldrick), 39 [Cp * Ir(m*-1,4 benzoquinone)] (J. Le Bras, H. Amouri and J. Substitution Vaissermann), 483 A thermodynamic study of the electron transfer chain catalyzed Sila-bridged substitution of triphenylphosphine for iodide on CpFe(CO),I (Z. Synthesis and characterization of a series of sila-bridged diiron com- Liu and S.L. Gipson), 269 plexes (E)[(°-,tH ,-)FBe(uCO)C], ( u-CO), (E = Me,Si, Sulfonamido Me,SiSiMe,, Me,SiOSiMe,). The molecular structures of cis- Synthesis and structure of sulfonamido cyclopentadiene titanium com- and trans-(Me, Si)[n°-t-BuC ,H , )Fe(CO)},( u-CO), (Y. Zhang, plexes: X-ray structure of Ti(n*:o-C;H,CH,CH,NSO,C, S. Xu, G. Tian, X. Zhou and J. Sun), 149 H,CH,)CI, (C. Lensink), 387 Silicon Sulphur—oxygen ligands X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- Thioethercarboxylates in palladium chemistry: First proof of hemil- silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. abile properties of S—O ligands (W.H. Meyer, R. Brill, H.G. Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 Raubenheimer, C. Thompson and G.J. Kruger), 83 Silole Supermesitylphosphaalkyne Synthesis and properties of dithienosiloles (J. Ohshita, M. Nodono, T. Different reaction modes of supermesitylphosphaalkyne with Watanabe, Y. Ueno, A. Kunai, Y. Harima, K. Yamashita and M. [W(CO).thf]-unusual C-H-activation forming an indanyl sub- Ishikawa), 487 stituent (P. Kramkowski, M. Scheer and G. Baum), 511 Silyl Silyl-Komplexe des Molybdans und Wolframs. Synthese, Reaktivitat und Struktur (S.H.A. Petri, B. Neumann, H.-G. Stammler und P. Tantalum Jutzi), 317 Utility of hydridotributyltin as both reductant and hydride transfer Silylacetylenic alcohols reagent in organotransition metal chemistry I. A convenient syn- An unusual rearrangement of 1|-trimethylsiloxy-3-bromomagnesium- thesis of the organoditantalum(IV) hydrides (7-C;Me,R),Ta,( p- H),Cl, (R = Me, Et) from (7-C;Me,R)TaCl,, and probes of the 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina and M.G. Voronkov), 481 possible reaction pathways (T.-Y. Lee and L. Messerle), 397 Silylene complex Thermogravimetry Thermal reactions of alkyl(hydridoXhydrosily)iridium(UIl) com- Mehrfachbindungen zwischen Hauptgruppenelementen und Uber- plexes: generation of a hydrido(silylene)iridium(1) species via the gangsmetallen. CLX VI. Molekulare Organorhenium-Vorstufen fiir reductive elimination of alkane and 1,2-H-shift from the silicon CVD-prozesse (W.A. Herrmann, W.M. Wachter, F.E. Kiihn and R.W. Fischer), 443 atom to the Ir(1) metal center (M. Okazaki, H. Tobita, Y. Kawano, S. Inomata and H. Ogino), | Through-space coupling Silyl ethers X-ray analysis and NMR-studies of E- and Z-1,2-bis(fluorodimethyl- An unusual rearrangement of 1|-trimethylsiloxy-3-bromomagnesium- silyl)-1,2-diphenylethenes (V. Plack, P. Sakhaii, A. Fischer, P.G. 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina Jones, R. Schmutzler, K. Tamao and G.-R. Sun), 111 and M.G. Voronkov), 481 Tin(IV) complex Silyliridium Tin([V) and organotin(V) complexes containing mono or bidentate Thermal reactions of alkyl(hydridoXhydrosily)iridium(ID com- N-donor ligands. III. 1-methylimidazole derivatives: synthesis, plexes: generation of a hydrido(silylene)iridium(1) species via the spectroscopic and structural characterization (C. Pettinari, M. reductive elimination of alkane and 1,2-H-shift from the silicon Pellei, M. Miliani, A. Cingolani, A. Cassetta, L. Barba, A. Pifferi atom to the Ir(I) metal center (M. Okazaki, H. Tobita, Y. Kawano, and E. Rivarola), 345 S. Inomata and H. Ogino), | Titanium Silyl migration Synthesis and structure of sulfonamido cyclopentadiene titanium com- An unusual rearrangement of 1-trimethylsiloxy-3-bromomagnesium- plexes: X-ray structure of Ti(n*:o-C;H,CH,CH,NSO,C, H,CH,)CI, (C. Lensink), 387 2-propyne (A.S. Medvedeva, V.V. Novokshonov, M.M. Demina and M.G. Voronkov), 481 Titanocene Single-source precursor Synthese und Reaktionsverhalten monomerer Bis(7?-Alkin)- Silyl-Komplexe des Molybdins und Wolframs. Synthese, Reaktivitat Kupfer(I)-Fluorid- und-Kupfer(I)-Hydrid-Komplexe (K. Kohler, H. Pritzkow und H. Lang), 31 und Struktur (S.H.A. Petri, B. Neumann, H.-G. Stammler und P. Jutzi), 317 Synthesis and charracdt erization of TiC 5H; X2,4-C,H,,) Sodium [POCH,CH(O)C,H,O] and Ti(2,4-C,H,,), [POCH,CH(O) Formation and X-ray structure of [{O(Ph,SiONa),}, - (NaOH) - (HO) C,H,O] chiral phosphite adducts of an open and a half open -(7 pyridine)]- (tolu-e( pnyreidi)ne ) incorporating a unique as- titanocene (D. Vos, A.M. Arif and R.D. Ernst), 277

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