Journal of Organometallic Chemistry 1998: Vol 550 Index

9 Pages·1998·2.1 MB·English

ELSEVIER Journal of Organometallic Chemistry 550 (1998) 485-486
Author Index of Volume 550
Adams, H., 7 Donaghy, K.J., 77 Jerzykiewicz, L., 111
Adams, KJ., 315 Donkervoort, J.G., 463 Johnson, B.F.G., 431
Akhter, Z., 131 Dérfler, U., 441
Allan, R.E., 71 Dorn, H., | Kee, T.P., 29
Armspach, D., 193 Dyson, PJ. 431 Kennedy, A.R., 355
Armstrong, D.R., 233, 355 Kennedy, J.D., 151, 341, 441
Edelman, M.A., 397 Kitees, 84. 59
Bailey, N.A., 7 : 4 Kim, Y.-h., 341
Errington, R.J., 47: Kitchen. SJ. 7
Ball, S.C., 457 .
. — Ezhova, M.B., 409
Banister, A.J., 241 Knobler, C.B., 423
Barker, J., 301 Kooijman, H., 463
Batsanov, A.S., 59, 445 Fehiner, T.P., 21 Krause Bauer, J., 309
Beddows, CJ., 267 Fenton, D.E., 7 Kursawe, M., 267
Beswick. M.A.. 71 Ferguson, G., 477
Bickethaupt, F., 347 Finn, M.G., 469 Lamb, S., 481
Boche. G.. 359. 381 Fleischer, R., 173 Lappert, M.F., 397
Bolton, P.D., 445 Fornies-Camer, J., 347 Lawlor, FJ., 183
Bowmaker, G.A., 89 Fox, M.A. 207, 331 Lehmann, C.W., 59, 449
Box, M.R., 267 Fusek, J., 125 Lesley, G., 183
Brown, M.A., 165 Lewis, J., 131
Butters, C., 267 Gallagher, J.F., 477 Liu, D.-S., 397
Gibson. V.C.. 453 Liu, J., 309
Cain, C.P., 29 Gindl. J.. | Lustig, C., 445
Callaghan, K.L.F., 441 Goeta, A.E., 449 Lynn, M.A., 141
Cardin, C., 347 Greatrex, R., 207, 331, 341
Maguire, J.A., 409
Carr, N., 267 Green, M., 267
Mahon, M.F., 267
Carroll, PJ., 77 Green, M.L.H., 63
Marder, T.B., 183
Chisholm, M.H., 141 Greenwood, N.N., 207
Martin, C.M., 431
Chivers, T., 213 Grimes, R.N., 469
May, I., 241
Churakov, A.V., 89
CCldegige, enW. . 6~h. 72 33, 473 Haggitt, J.. 63 nMcGarrve y, aBd.eR-.o,a ge1n6d5
Constable. E.C. 193 Harris, R.K., 89 McGrath, T.D., 315, 441
apa Harwell, D-E., 423 McIntyre, G.M., 449
Cooke, P.A.. 341 Hawley, J.C., 7 Mehnert, C.P., 63
; ; } lehnert, C.P., 6:
Ceny BEB. 48 Hawthorne, M.F., 423 Mitchell, M.C., 29
Cowey, C., 151 Heath, S.L., 473 Mulvey, R.E., 355
Conall. R.A.. 473 Heaton, B.T., 221 Murphy, MP, 151
Cotuse, SP. 39 Hitchcock, P.B., 397 ;
Craig, FJ. 355 Hodgson, S.M., 233 Nabakka, J.M., 423
Cranson, SJ., 207 Hofmann. M.. 331 Neuburger, M., 193
Curtis, M.A., 469 Holub. J.. 151 Noltemeyer, M., |
Hong, F.-E., 309 Norman, N.C., 183
Dam, M.A., 347 Hosmane, N.S., 409
Davidson, MG., 445, 449, 481 Housecroft, C.E., 193 Oh. J.R., 309
Davies, J.E., 431 Howard, J.A.K., 59, 445, 449, 481 Oh, S.-W., 89
Davies, M.K., 71 Olah, G.A., 119
DDaavviieess,, SR..RP..,, 42597 'e so. J.A., 2a2s 1 OOrnpaekn,, T.A,. G.1,0 1 183, 255
De Kanter, F.JJ., 347 ingham, SL. 131 Ozarowski, A. 165
Deng, H., 309
Devitt, P.G., 29 Jaballas, J., 101 Parvez, M., 213
Dillon, K.B., 481 Jastrzebski, J.T.B.H., 463 Pasynkiewicz, S., 111
Elsevier Science S.A.
486 Author Index of Volume 550
Pearson, R.H.H., 431 Schatte, G., 213 Tian, S., 397
Phillips, P.R., 301 Schleyer, P.R., 331 Trojanowska, L., 111
Pietrzykowski, A., 111 Schmidt, H.-G., | Tuck, D.G., 165
Podkorytov, 1.S., 221 Scott, A.J., 183 Tunik, S.P., 221
Prakash, G.K.S., 119 Shah, S.A.A., |
Price, R.D., 445, 449 Sheehan, J.P., 477 Van den Ancker, T.R., 283
Pringle, P.G., 255 Shields, G.P., 457 Van Koten, G., 463
Shore, $.G., 309 Vicario, J.L., 463
Quayle, M.J., 183 Smeets, W.J.J., 347 Vifhas, C., 125
Smith, J.N.B., 241
Raithby, P.R., 71, 131, 457 Smith, M.B., 255 Wallbridge, M.G.H., 301
Raston, C.L., 283 Snaith, R., 233, 457 Wang, Q., 119
Rasul, G., 119 Sneddon, L.G., 77 Welch, A.J., 315
Rawson, J.M., 241 Sobota, P., 111 Weller, A.S., 315
Redshaw, C., 453 Souza, F.E.S., 183 Wheatley, A.E.H., 233
Rice, C.R., 183 Spalding, T.R., 151, 477 White, A.J.P., 453
Ridland, J., 473 Spek, A.L., 347, 463 Willett, K.J., 473
Rijnberg, E., 463 Stalke, D., 173 Williams, D.J., 453
Roden, M.D., 481 Steiner, A., 71 Williams, R.E., 331
Roesky, H.W., | Stibr, B., 125 Worboys, K., 255
Rosair, G.M., 315 Wright, D.S., 71
Taylor, RJ., 29
Sampanthar, J., 221 Teixidor, F., 125 Zehnder, M., 193
Schade, S., 359, 381 Thornton-Pett, M., 151, 341, 441 Zhang, H., 409
ELSEVIER
Journal of Organometallic Chemistry 550 (1998) 487-493
Subject Index of Volume 550
Ab initio Synthesis and structural characterisation of aluminium imino-amide
Formation of the lith alkylal ium secondary amide and pyridyl-amide complexes: bulky monoanionic N.N chelate
[Me, Al{(PhCH , ), N),L i - THF] by a methane elimination /amide ligands via methyl group transfer (V.C. Gibson, C. Redshaw,
insertion process (D.R. Armstrong, F.J. Craig, A.R. Kennedy and AJ.P. White and DJ. Williams), 453
R.E. Mulvey), 355 Amide
Ab initio calculations Formation of the lithium alkylaluminium secondary amide
A structural and theoretical study of the monolithiation of hydroxyl- (Me, Al{(PhCH , ),N}, Li - THF] by a methane elimination /amide
amines (D.R. Armstrong, W. Clegg, S.M. Hodgson, R. Snaith and insertion process (D.R. Armstrong, F.J. Craig, A.R. Kennedy and
A.E.H. Wheatley), 233 R.E. Mulvey), 355
Six-vertex nido-carborane structures with unusual CHB bridges or (Poly amine ligands
endo-CH hydrogens (M. Hofmann, M.A. Fox, R. Greatrex, R.E. The effect of (polyamine ligands on the solution structure of [°Li}-a-
Williams and P.R. Schleyer), 331 (phenylthio)benzyllithium in tetrahydrofuran: A 'H,°Li-HOESY
Absolute configuration NMR study (S. Schade and G. Boche), 359
Phospho-transfer catalysis. On the asymmetric hydrophosphony lation Amphoteric catalysts
of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt, Phospho-transfer catalysis. On the asymmetric hydrophosphonylation
R.J. Taylor and T.P. Kee), 29 of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt,
Alane RJ. Taylor and T.P. Kee), 29
Polymer and metal oxide supported alkali metal naphthalenides: Aqueous solution
application in the generation of lithium and sodium reagents (T.R. A convenient route to carbon-substituted derivatives of nido-5,6-
Van den Ancker and C.L. Raston), 283 C,B,H,, (B. Stibr, F. Teixidor, C. Viiias and J. Fusek), 125
Alkali metal complexes Arachno
Synthesis and characterization of trimethylsilylmethyl-, bis(trimethy!- Metallaheteroborane chemistry. Part 14. Synthesis of the ({MS,B-}-
sily)methyl-and silyl-substituted cyclopentadienes and their alkali cluster compounds [9,94PX ,),-9,6,8-PtS,B,H,] (where X = Ph
metal complexes (M.A. Edelman, P.B. Hitchcock, M.F. Lappert, or OMe), [9,94PPh,),-9,6,8-RhS,B,H,] and [5,5-(PPh,),-
D.-S. Liu and S. Tian), 397 5,6.10-RhS,B,H,], and the {M,S,B,}-cluster compound
Alkoxide {(PPh ,), HRh(PPh , ICIRHS, B,H,] (M.P. Murphy, T.R. Spalding.
Organophosphonate derivatives of titanium and niobium alkoxoanions C. Cowey, J.D. Kennedy, M. Thornton-Pett and J. Holub), 151
(R.J. Errington, J. Ridland, KJ. Willett. W. Clegg, R.A. Coxall Arachno-B,H, ,L
and S.L. Heath), 473 Polyhedral nonaborane chemistry: an unsuspected new isomeric type
Alkyl in the nine-vertex arachno-B,H,,L system (K.L.F. Callaghan, U.
Preparation and structures of some tetraazamacrocyclic complexes of Dérfler, T.D. McGrath, M. Thornton-Pett and J.D. Kennedy), 441
In(11) (P.R. Phillips, M.G.H. Wallbridge and J. Barker), 301 7 Arene
Alkyne bridge Synthesis and reactions of [Mo(2,6-lutidine Xphosphine)] derivatives
The non-perpendicular and non-parallel alkyne bridge in W,( p- (C.P. Mehnert, J. Haggitt and M.L.H. Green), 63
C,H, ~-OCHS Bu),(OCHS Bu), (M.H. Chisholm and M.A.
Lynn), 141
7 -Allyl 'B chemical shifts
The synthesis, structure and reactivity of aldehyde substituted 7‘-al- Experimental and theoretical studies on group | metallacarboranes:
lylic complexes of molybdenum (CJ. Beddows, M.R. Box, C. Synthesis, structure and ab initio calculations of the NMR chemi-
Butters, N. Carr, M. Green, M. Kursawe and M.F. Mahon), 267 cal shifts of the 1-(THF)-1-4TMEDA)-1-Na-2,4-(,)S,i-M2,e4 -
Alumina C,B,H, and related carboranes (M.B. Ezhova, H. Zhang, J.A.
Polymer and metal oxide supported alkali metal naphthalenides: Maguire and N.S. Hosmane), 409
application in the generation of lithium and sodium reagents (T.R. Bibracchial Schiff base macrocycle
Van den Ancker and C.L. Raston), 283 Dinuclear copper(l) complexes of 24-membered bibracchial te-
Aluminium traimine Schiff base macrocycles derived from 2,5-dif-
Formation of the lithium alkylaluminium secondary amide ormylthiophene (H. Adams, N.A. Bailey, S.R. Collinson, D.E
[Me, Al{(PhCH , ), N},L i - THF] by a methane elimination /amide Fenton, J.C. Hawley and S.J. Kitchen), 7
insertion process (D.R. Armstrong, F.J. Craig, A.R. Kennedy and Borane cluster
R.E. Mulvey), 355 Polyhedral nonaborane chemistry: an unsuspected new isomeric type
Elsevier Science S.A.
Subject Index of Volume 550
in the nine-vertex arachno-B,H,,L system (K.L.F. Callaghan, U. Cluster
Dérfler, T.D. McGrath, M. Thornton-Pett and J.D. Kennedy), 441 A molecular orbital analysis of four chromaboranes. On the curious
Boranes behavior of (n'-C.R, Cr fragments in a borane cluster environ-
Studies on tetraborane(8) carbonyl, B,H, - CO: its isomeric composi- ment (T.P. Fehiner), 2!
tion in the gas phase and in solution, and its reactions with alkenes Cluster carbonyls
(S.J. Cranson, M.A. Fox, R. Greatrex and N.N. Greenwood), 207 Metal core rearrangements in hetero-bimetallic nona-osmium car-
Boron bony! clusters; the crystal and molecular structures of [Os,(CO),,
A molecular orbital analysis of four chromaboranes. On the curious {Au(PCy,)},] and [Os,(CO),,(Au, DPPE)] (Z. Akhter, S.L. Ing-
behavior of (*°-C.R,)Cr fragments in a borane cluster environ- ham, J. Lewis and P.R. Raithby), 131
ment (T.P. Fehlner), 21 Cluster compound
B-frame supported bimetallics. [(PMe, ph), PtB,H,,Ru(m°- Metallaheteroborane chemistry. Part 14. Synthesis of the (MS,B,)}-
‘¢PrC,H,Me)] and [(PMe, ph), PtB,H,Ru(P7rC°,,-H ',M ’e) }: cluster compounds [9,9-(PX ,),-9.6,8-PtS,B,H,] (where X = Ph
an interesting pair of electron-deficient nido and closo geometries or OMe), [9,94PPh,),-9.6.8-RhS,B,H,] and [5.5-(PPh,),-
(Y.-h. Kim, P.A. Cooke, R. Greatrex, J.D. Kennedy and M. 5,6,10-RhS,B,H,], and the {M,S,B,}-cluster compound
Thornton-Pett), 341 [(PPh ,), HRh(,I PCIRPHS,h B,H,] (M.P. Murphy, T.R. Spalding,
Six-vertex nido-carborane structures with unusual CHB bridges or C. Cowey, J.D. Kennedy, M. Thornton-Pett and J. Holub), 151
endo-CH hydrogens (M. Hofmann, M.A. Fox, R. Greatrex, R.E. C-N-Li cluster
Williams and P.R. Schleyer), 331 Preparation and structures of (Li[C(N'Bu),(HN'Bu)]}, -(THF) and
Boron hydride {Li,[C(N'Bu),]},, containing the novel anions [C(N'Bu),
Stability and NMR correlations, experimental vs. calculational, among (HN'Bu)]~ and [C(N'Bu),P~ (7. Chivers, M. Parvez and G.
isoelectronic closo-hexaborane /carborane compounds (J. Jaballas Schatte), 213
and T. Onak), 101 Contigurational stability
Phospho-transfer catalysis. On the asymmetric hydrophosphony lation
Cage boron atom of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt,
Synthesis and structural characterisation of the carbene-containing R.J. Taylor and T.P. Kee), 29
metallaheteroborane compound [2-I-2-(Bu' NC)-3-(Bu' NHCH)- Conformation
closo-2,\-Pd,T,e,H By ] (G. Ferguson, J.F. Gallagher, J.P. Sheehan Synthesis and properties of new tris(cyanoethyl phosphine complexes
and T.R. Spalding), 477 of platinum (01D, palladium (0.11), iridium (1) and rhodium (1).
Carbodiimides Conformational analysis of tris(cyanoethyl)phosphine ligands
Preparation and structures of {Li[{C(N'Bu),(HN'Bu)]}, -(THF) and (A.G, Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255
{Li,[C(N'Bu),]},, containing the novel anions [C(N'Bu),(HN' Copper(1)
Bu)]~ and [C(N'Bu),}~ (T. Chivers, M. Parvez and G. Schatte), Dinuclear copper(l) complexes of 24-membered bibracchial te-
213 traimine Schiff base macrocycles derived from 2,5-dif-
Carbon-substituted derivatives ormylthiophene (H. Adams, N.A. Bailey, S.R. Collinson, D.E.
A convenient route to carbon-substituted derivatives of nido-5,6- Fenton, J.C. Hawley and S.J. Kitchen), 7
C,B,H,, (B. Stibr, F. Teixidor, C. Vilas and J. Fusek), 125 Crystal structure
Carborane n'- and n°-benzene coordination in [Ag(C,,D,),BF,] (A.S. Batsanov,
Experimental and theoretical studies on group | metallacarboranes: S.P. Crabtree, J.A.K. Howard, C.W. Lehmann and M. Kilner), 59
Synthesis, structure and ab initio calculations of the NMR chemi- Experimental and theoretical studies on group | metallacarboranes:
cal shifts of the 1-(THF)-1-~TMEDA)-1-Na-2,4-(,S),i-M2.e4 - Synthesis, structure and ab initio calculations of the NMR chemi-
C,B,H, and related carboranes (M.B. Ezhova, H. Zhang, J.A. cal shifts of the 1-(THF)-1-CTMEDA)-1-Na-2,4-(,S),i-M2.e4 -
Maguire and N.S. Hosmane), 409 C,B,H, and related carboranes (M.B. Ezhova, H. Zhang, J.A.
Six-vertex nido-carborane structures with unusual CHB bridges or Maguire and N.S. Hosmane), 409
endo-CH hydrogens (M. Hofmann, M.A. Fox, R. Greatrex, R.E. Organophosphonate derivatives of titanium and niobium alkoxoanions
Williams and P.R. Schleyer), 331 (RJ. Errington, J. Ridland, K.J. Willett, W. Clegg, R.A. Coxall
Stability and NMR correlations, experimental vs. calculational, among and S.L. Heath), 473
isoelectronic closo-hexaborane /carborane compounds (J. Jaballas Synthesis and reactions of [Mo(2,6-luXtp ihodspihninee] derivatives
and T. Onak), 101 (C.P. Mehnert, J. Haggitt and M.L.H. Green), 63
Carboranes Vibrational spectroscopy and solid-state MAS NMR studies of mer-
A hydridotantalum(V )-carborane analogue of Schwartz's reagent: syn- cury(II) acetate complexes [Hg(X)OAc]. Crystal structure of
thesis and reactivity (M.A. Curtis, M.G. Finn and R.N. Grimes), [Hg(CN)OAc] (G.A. Bowmaker, A.V. Churakov, R.K. Harris and
469 S.-W. Oh), 89
Chelate Cyclopentadiene
Dithiadiazolyls as heterocyclic chelators: a radical approach to coordi- Synthesis and characterization of trimethylsilylmethy!-, bis(trimethyl-
nation chemistry? (A.J. Banister, I. May, J.M. Rawson and J.N.B. silyl) methyl-and silyl-substituted cyclopentadienes and their alkali
Smith), 241 metal complexes (M.A. Edelman, P.B. Hitchcock, M.F. Lappert,
Chiral derivatising agent D.-S. Liu and S. Tian), 397
Phospho-transfer catalysis. On the asymmetric hydrophosphonylation Cyclopentadieny!
of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt, Preparation and structures of some tetraazamacrocyclic complexes of
R.J. Taylor and T.P. Kee), 29 In(1) (P.R. Phillips, M.G.H. Wallbridge and J. Barker), 301
Chromium CyclopentadienyInickel clusters
A molecular orbital analysis of four chromaboranes. On the curious Reactions of nickelocene with lithium and magnesium alkyls contain-
behavior of (1°-C.R,)Cr fragments in a borane cluster environ- ing B-hydrogen atoms (S. Pasynkiewicz, A. Pietrzykowski, L.
ment (T.P. Fehiner), 21 Trojanowska, P. Sobota and L. Jerzykiewicz), 111
Subject Index of Volume 550 489
Deuterobenzene 7-coordination cal shifts of the 1-(THF)-14(TMEDA)-1-Na-2,4-(,S),i-M2.e4 -
7'- and 7*-benzene coordination in [Ag(C, D,),BF,] (A.S. Batsanov, C,B,H, and related carboranes (M.B. Ezhova, H. Zhang, J.A.
S.P. Crabtree, J.A.K. Howard, C.W. Lehmann and M. Kilner), 59 Maguire and N.S. Hosmane), 409
DFT /IGLO method GIAO /NMR
Preparation, *’Si and '‘C NMR and DFT /IGLO studies of silylear- Stability and NMR correlations, experimental vs. calculational, among
boxonium ions (G.K.S. Prakash, Q. Wang, G. Rasul and G.A. isoelectronic closo-hexaborane /carborane compounds (J. Jaballas
Olah), 119 and T. Onak), 101
Dicarbaborane Gold
A convenient route to carbon-substituted derivatives of nido-5,6- Metal core rearrangements in hetero-bimetallic nona-osmium car-
C,B,H,, (B. Stibr, F. Teixidor, C. Vitias and J. Fusek), 125 bony! clusters; the crystal and molecular structures of [Os,(CO),,
9,10-Dimetallatriptycenes {Au(PCy ,)},] and [Os,(CO),,(Au, DPPE)] (Z. Akhter, S.L. Ing-
9,10-Dimetallatriptycenes of group 14: a structural study (M.A. Dam, ham, J. Lewis and P.R. Raithby), 131
F.JJ. De Kanter, F. Bickelhaupt, W.JJ. Smeets, A.L. Spek, J. Grignard reagent
Fornies-Camer and C. Cardin), 347 The metallation of imino(triphenyl)phosphorane by ethylmagnesium
Dipropargy! thioether chloride: The synthesis, isolation and X-ray structure of
Synthesis and structural characterization of a thioether-bridged [Ph ,P=NMgCl -O=P(NMe,),], (A.S. Batsanov, P.D. Bolton,
commo-metallabis(dicarbollide) species: a model system for Venus R.C.B. Copley, M.G. Davidson, J.A.K. Howard, C. Lustig and
flytrap cluster reagents (J.M. Nabakka, D.E. Harwell, C.B. Kno- R.D. Price), 445
bler and M.F. Hawthorne), 423 Group 4
Dithiadiazoly! Synthesis and structural characterization of sulfonates, phosphinates
Dithiadiazolyls as heterocyclic chelators: a radical approach to coordi- and carboxylates of organometallic Group 4 metal fluorides
nation chemistry? (AJ. Banister, |. May, J.M. Rawson and J.N.B. (S.A.A. Shah, H. Dorn, J. Gindl, M. Noltemeyer, H.-G. Schmidt
Smith), 241 and H.W. Roesky), |
Halides
Electron count
B-frame supported bimetallics. [(PMe, ph), PtB,H,,Ru(n°- Synthesis and structural characterization of sulfonates, phosphinates
‘““PrC,H,Me)] and [(PMe, ph), PtB,H,Ru(n®-"’’HP,r MCe,)) : and carboxylates of organometallic Group 4 metal fluorides
(S.A.A. Shah, H. Dorn, J. Gindl, M. Noltemeyer, H.-G. Schmidt
an interesting pair of electron-deficient nido and closo geometries
and H.W. Roesky), |
(Y.-h. Kim, P.A. Cooke, R. Greatrex, J.D. Kennedy and M.
B-H elimination
Thornton-Pett), 341
Reactions of nickelocene with lithium and magnesium alkyls contain-
Enantiopurity assay
ing B-hydrogen atoms (S. Pasynkiewicz, A. Pietrzykowski, L.
Phospho-transfer catalysis. On the asymmetric hydrophosphonylation
Trojanowska, P. Sobota and L. Jerzykiewicz), 111
of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt,
Heteroatom assisted lithiation
RJ. Taylor and T.P. Kee), 29
Formation of mixed aryl—, alkyl—lithium aggregates in the heteroatom
Enantioselective
assisted lithiation of a,a’-dialkyl substituted | ,3-bis{(dimethyl-
Phospho-transfer catalysis. On the asymmetric hydrophosphony lation
amino)methyl}benzene (J.G. Donkervoort, J.L. Vicario, E. Rijn-
of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt,
berg. J.T.B.H. Jastrzebski, H. Kooijman, A.L. Spek and G.
R.J. Taylor and T.P. Kee), 29
Van Koten), 463
Ether-bridged commo-metallabisdicarbollide complex
Heterobimetallics
Synthesis and structural characterization of a thioether-bridged
Formation of the lithium alkylaluminium secondary amide
commo-metallabis(dicarbollide) species: a model system for Venus
[Me Al{(PhCH , ), N}, Li - THF] by a methane elimination /amide
flytrap cluster reagents (J.M. Nabakka, D.E. Harwell, C.B. Kno-
insertion process (D.R. Armstrong, FJ. Craig, A.R. Kennedy and
bler and M.F. Hawthorne), 423
R.E. Mulvey), 355
Hetero-trimethylenemethane ligands
Fluxionality Preparation and structures of {Li[C(N'Bu),(HN'Bu)}}, -(THF) and
Studies on tetraborane(8) carbonyl, B,H, - CO: its isomeric composi- {Li,[C(N'Bu),}},, containing the novel anions [C
tion in the gas phase and in solution, and its reactions with alkenes (N'Bu),(HNBu') ” and [C(N' Bu), ~ (1. Chivers, M. Parvez and
(S.J. Cranson, M.A. Fox, R. Greatrex and N.N. Greenwood), 207 G. Schatte), 213
Hexanuclear and pentanuclear ruthenaborides
Gallane Formation of H,Ru,(CO),, from H,Ru,(CO),, an improved synthe-
Polymer and metal oxide supported alkali metal naphthalenides: sis of HRu,(CO),, B (D.A. McCarthy, J. Krause Bauer, F.-E.
application in the generation of lithium and sodium reagents (T.R. Hong, J.R. Oh, H. Deng, J. Liu and S.G. Shore), 309
Van den Ancker and C.L. Raston), 283 Hexaphenylditin
Geometrical isomerism Studies of organotin(IV)-orthoquinone systems (M.A. Brown, B.R.
Studies on tetraborane(8) carbonyl, B,H, - CO: its isomeric composi- McGarvey, A. Ozarowski and D.G. Tuck), 165
tion in the gas phase and in solution, and its reactions with alkenes Hg(X)OAc
(S.J. Cranson, M.A. Fox, R. Greatrex and N.N, Greenwood), 207 Vibrational spectroscopy and solid-state MAS NMR studies of mer-
Germanium cury(I]) acetate complexes [Hg(X)OAc]. Crystal structure of
9,10-Dimetallatriptycenes of group 14: a structural study (M.A. Dam, [Hg(CN)OAc] (G.A. Bowmaker, A.V. Churakov, R.K. Harris and
F.JJ. De Kanter, F. Bickelhaupt, WJJ. Smeets, A.L. Spek, J. S.-W. Oh), 89
‘H.°Li-HOESY
Fornies-Camer and C. Cardin), 347
GIAO computed '*C The effect of (polyamine ligands on the solution structure of [°Li}-a-
Experimental and theoretical studies on group | metallacarboranes: (phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY
Synthesis, structure and ab initio calculations of the NMR chemi- NMR study (S. Schade and G. Boche), 359
490 Subject Index of Volume 550
The effect of polyether ligands on the solution structure of [°Li}a- closo-2,1-Pd,Tye HB, ] (G. Ferguson, J.F. Gallagher, J.P. Sheehan
(phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY and T.R. Spalding), 477
NMR study (S. Schade and G. Boche), 381 Lithium
Hydridometallacarboranes A structural and theoretical study of the monolithiation of hydroxyl-
A hydridotantalum(V )-carborane analogue of Schwartz's reagent: syn- amines (D.R. Armstrong, W. Clegg, S.M. Hodgson, R. Snaith and
thesis and reactivity (M.A. Curtis, M.G. Finn and R.N. Grimes), A.E.H. Wheatley), 233
469 Formation of the lithium alkylaluminium secondary amide
Hydroboration [Me, Al{(PhCH , ),N },L i: THF] by a methane elimination /amide
Studies on tetraborane(8) carbonyl, B,H, - CO: its isomeric composi- insertion process (D.R. Armstrong, FJ. Craig, A.R. Kennedy and
tion in the gas phase and in solution, and its reactions with alkenes R.E. Mulvey), 355
(S.J. Cranson, M.A. Fox, R. Greatrex and N.N. Greenwood), 207 The mechanism of lithiation and nitrile insertion reactions of B-meth-
Hydroxylamine ylazines: evidence from the structure of 3-C,H,NCH=C
A structural and theoretical study of the monolithiation of hydroxyl- (Ph)NCHIC(Ph)=NLi - PMDETA (S.C. Ball, R.P. Davies, P.R.
amines (D.R. Armstrong, W. Clegg, S.M. Hodgson, R. Snaith and Raithby, G.P. Shields and R. Snaith), 457
A.E.H. Wheatley), 233 Lithium reagent
Polymer and metal oxide supported alkali metal naphthalenides:
IGLO/NMR
application in the generation of lithium and sodium reagents (T.R.
Stability and NMR correlations, experimental vs. calculational, among
Van den Ancker and C.L. Raston), 283
isoelectronic closo-hexaborane /carborane compounds (J. Jaballas
and T. Onak), 101
MAS NMR
Imino-amide ligands
Vibrational spectroscopy and solid-state MAS NMR studies of mer-
Synthesis and structural characterisation of aluminium imino-amide
cury(II) acetate complexes [Hg(X)OAc]. Crystal structure of
and pyridyl-amide complexes: bulky monoanionic N,N chelate
[Hg(CN)OAc] (G.A. Bowmaker, A.V. Churakov, R.K. Harris and
ligands via methyl group transfer (V.C. Gibson, C. Redshaw,
S.-W. Oh), 89
A.J.P. White and D.J. Williams), 453
Metal complexes
Iminophosphorane
Phospho-transfer catalysis. On the asymmetric hydrophosphonylation
Low temperature neutron and X-ray diffraction study of imino(tri-
of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt,
phenyl )phosphorane (M.G. Davidson, A.E. Goeta, J.A.K. Howard,
RJ. Taylor and T.P. Kee), 29
C.W. Lehmann, G.M. Mcintyre and R.D. Price), 449
Metallaborane
The metallation of imino(tripheny))phosphorane by ethylmagnesium
A molecular orbital analysis of four chromaboranes. On the curious
chloride: The synthesis, isolation and X-ray structure of
behavior of (7°-C,R, Cr fragments in a borane cluster environ-
[Ph ,P=NMgCl-O=P(NMe,),], (A.S. Batsanov, P.D. Bolton,
ment (T.P. Fehiner), 21
R.C.B. Copley, M.G. Davidson, J.A.K. Howard, C. Lustig and
Metallacarboranes
R.D. Price), 445
A hydridotantalum(V )-carborane analogue of Schwartz's reagent: syn-
Indium
thesis and reactivity (M.A. Curtis, M.G. Finn and R.N. Grimes),
Preparation and structures of some tetraazamacrocyclic complexes of
469
In(II}) (P.R. Phillips, M.G.H. Wallbridge and J. Barker), 301
Metallaheteroborane cluster compound
Intramolecular electron transfer reactions
Synthesis and structural characterisation of the carbene-containing
Studies of organotin(IV)-orthoquinone systems (M.A. Brown, B.R.
metallaheteroborane compound [2-I-2-(Bu' NC)-3-(Bu' NHCH)-
McGarvey, A. Ozarowski and D.G. Tuck), 165
closo-2,1-PdTHeyB] (G. Ferguson, J.F. Gallagher, J.P. Sheehan
lon pair equilibria
and T.R. Spalding), 477
The effect of (polyamine ligands on the solution structure of [°Li]-a-
Metal vapour synthesis
(phenylthio)benzyllithium in tetrahydrofuran: A 'H,°Li-HOESY
Synthesis and reactions of [Mo(2,6-lutidineXphosphine)] derivatives
NMR study (S. Schade and G. Boche), 359
(C.P. Mehnert, J. Haggitt and M.L.H. Green), 63
The effect of polyether ligands on the solution structure of [°Li]-a-
Methyl! group transfer
(phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY
Synthesis and structural characterisation of aluminium imino-amide
NMR study (S. Schade and G. Boche), 381
and pyridyl-amide complexes: bulky monoanionic N,N chelate
Iridium
ligands via methyl group transfer (V.C. Gibson, C. Redshaw,
Synthesis and properties of new tris(cyanoethyl phosphine complexes
A.J.P. White and DJ. Williams), 453
of platinum (0,11), palladium (OID, iridium (1) and rhodium (1).
Mixed organolithium aggregate
Conformational analysis of tris(cyanoethyl)phosphine ligands
Formation of mixed aryl-, alkyl—lithium aggregates in the heteroatom
(A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255
assisted lithiation of a,a’-dialkyl substituted 1,3-bis{(dimethyl-
[°Li}-a-(phenylthio)benzyllithium amino)methyl]benzene (J.G. Donkervoort, J.L. Vicario, E. Rijn-
The effect of (poly)amine ligands on the solution structure of [°Li]}-a- berg, J.T.B.H. Jastrzebski, H. Kooijman, A.L. Spek and G.
(phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY Van Koten), 463
NMR study (S. Schade and G. Boche), 359 Molybdenum
The effect of polyether ligands on the solution structure of [°Li}a- Synthesis and reactions of [Mo(2,6-lutidineXphosphine)] derivatives
(phenylthio)benzyllithium in tetrahydrofuran: A 'H,°Li-HOESY (C.P. Mehnert, J. Haggitt and M.L.H. Green), 63
NMR study (S. Schade and G. Boche), 381 The synthesis, structure and reactivity of aldehyde substituted 7°-al-
Ligand redistribution lylic complexes of molybdenum (CJ. Beddows, M.R. Box, C.
Studies of organotin(IV)-orthoquinone systems (M.A. Brown, B.R. Butters, N. Carr, M. Green, M. Kursawe and M.F. Mahon), 267
McGarvey, A. Ozarowski and D.G. Tuck), 165 Multinuclear NMR
Ligand transfer Multinuclear NMR studies on substituted derivatives of Rh,(CO),,, in
Synthesis and structural characterisation of the carbene-containing solution (S.P. Tunik, LS. Podkorytov, B.T. Heaton, J.A. Iggo and
metallaheteroborane compound [2-I-2-(Bu' NC)-3-(Bu' NHCH)- J. Sampanthar), 221
Subject Index of Volume 550 491
Nickel Conformational analysis of tris(cyanoethy))phosphine ligands
Reactions of nickelocene with lithium and magnesium alkyls contain- (A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255
ing B-hydrogen atoms (S. Pasynkiewicz, A. Pietrzykowski, L. ortho-Phenylenemagnesium
Trojanowska, P. Sobota and L. Jerzykiewicz), 111 9,10-Dimetallatriptycenes of group 14: a structural study (M.A. Dam,
Nido and closo geometries FJJ. De Kanter, F. Bickelhaupt, W.JJ. Smeets, A.L. Spek, J.
B-frame supported bimetallics. [(PMe, ph), PtB,H,,Ru(n°- Fornies-Camer and C. Cardin), 347
‘“°PrC,,H,Me)} and [(PMe, ph), PtB,H,Ru(’-'*’PrC,,MHe,)} : Phosphide
an interesting pair of electron-deficient nido and closo geometries The first synthesis, isolation and X-ray structure of a phosphonium
(Y.-h. Kim, P.A. Cooke, R. Greatrex, J.D. Kennedy and M. phosphide, (Ph ,PMe)* {(C,H (CF, ),-2.4.6],P}~ (M.G. David-
Thornton-Pett), 341 son, K.B. Dillon, J.A.K. Howard, S. Lamb and M.D. Roden), 481!
Niobium Phosphine
Organophosphonate derivatives of titanium and niobium alkoxoanions Synthesis and reactions of [Mo(2,6-lutidine Xphosphine)] derivatives
(R.J. Errington, J. Ridland, KJ. Willeu, W. Clegg, R.A. Coxall (C.P. Mehnert, J. Haggitt and M.L.H. Green), 63
and S.L. Heath), 473 Phosphines
Nitriles Metal core rearrangements in hetero-bimetallic nona-osmium car-
The mechanism of lithiation and nitrile insertion reactions of B-meth- bony! clusters; the crystal and molecular structures of [Os,(CO),,
ylazines: evidence from the structure of 3-C,H,NCH=C(Ph) {Au(PCy ,)},] and [Os,(CO),,(Au, DPPE)] (Z. Akhter, S.L. Ing-
N(H)C(Ph)=NLi - PMDETA (S.C. Ball, R.P. Davies, PR. ham, J. Lewis and P.R. Raithby), 131
Raithby, G.P. Shields and R. Snaith), 457 Phosphonium
Nitrogen The first synthesis, isolation and X-ray structure of a phosphonium
Dithiadiazolyls as heterocyclic chelators: a radical approach to coordi- phosphide, (Ph ,PMe)* {[C,H,(CF,),-2,4.6],P}” (M.G. David-
nation chemistry? (A.J. Banister, 1. May, J.M. Rawson and J.N.B. son, K.B. Dillon, J.A.K. Howard, S$. Lamb and M.D. Roden), 481
Smith), 241 Phosphorus
NMR spectroscopy Low temperature neutron and X-ray diffraction study of iminoltri-
Polyhedral nonaborane chemistry: an unsuspected new isomeric type pheny!)phosphorane (M.G. Davidson, A.E. Goeta, J.A.K. Howard,
in the nine-vertex arachno-B,H,,L system (K.L.F. Callaghan, U. C.W. Lehmann, G.M. McIntyre and R.D. Price), 449
Dérfler, T.D. McGrath, M. Thornton-Pett and J.D. Kennedy), 441 Platinum
Rhodathiaboranes with ‘anomalous’ electron counts: synthesis, struc- Synthesis and properties of new tris(cyanoethyl phosphine complexes
ture and reactivity (K.J. Adams, T.D. McGrath, G.M. Rosair, A.S. of platinum (0,11), palladium (0,11), iridium (1) and rhodium (1).
Weller and A.J. Welch), 315 Conformational analysis of tris(cyanoethyl)phosphine ligands
Synthesis and characterization of trimethylsilylmethyl-, bis(trimethyl- (A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255
silymethyl-and silyl-substituted cyclopentadienes and their alkali Polyether ligands
metal complexes (M.A. Edelman, P.B. Hitchcock, M.F. Lappert, The effect of polyether ligands on the solution structure of [°Li}a-
D.-S. Liu and S. Tian), 397 (phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY
NMR study (S. Schade and G. Boche), 381
Organoboranes Polystyrene
Studies on tetraborane(8) carbonyl, B,H, - CO: its isomeric composi- Polymer and metal oxide supported alkali metal naphthalenides:
tion in the gas phase and in solution, and its reactions with alkenes application in the generation of lithium and sodium reagents (T.R.
(S.J. Cranson, M.A. Fox, R. Greatrex and N.N, Greenwood), 207 Van den Ancker and C.L. Raston), 283
Organomagnesium Pudovik reaction
The metallation of imino(triphenyl)phosphorane by ethylmagnesium Phospho-transfer catalysis. On the asymmetric hydrophosphonylation
chloride: The synthesis, isolation and X-ray structure of of aldehydes (S.R. Davies, M.C. Mitchell, C.P. Cain, P.G. Devitt,
[Ph ,P=NMgCl -O=P(NMe,),], (A.S. Batsanov, P.D. Bolton, R.J. Taylor and T.P. Kee), 29
R.C.B. Copley, M.G. Davidson, J.A.K. Howard, C. Lustig and Pyridyl-amide complexes
R.D. Price), 445 Synthesis and structural characterisation of aluminium imino-amide
Organometallic clusters and pyridyl-amide complexes: bulky monoanionic N.N chelate
The synthesis and characterisation of some closed polyhedral metallo- ligands via methyl group transfer (V.C. Gibson, C. Redshaw,
carbon clusters (J.E. Davies, B.F.G. Johnson, C.M. Martin, R.H.H. A.J.P. White and D.J. Williams), 453
Pearson and P.J. Dyson), 431
Organophosphonate
Organophosphonate derivatives of titanium and niobium alkoxoanions
(R.J. Errington, J. Ridland, KJ. Willet. W. Clegg, R.A. Coxall Radiotransition
and S.L. Heath), 473 Synthesis and structural characterization of a thioether-bridged
Orthoquinones llabis(dicarbollide) species: a model system for Venus
Studies of organotin(IV)-orthoquinone systems (M.A. Brown, B.R. flytrap cluster reagents (J.M. Nabakka, D.E. Harwell, C.B. Kno-
McGarvey, A. Ozarowski and D.G. Tuck), 165 bler and M.F. Hawthorne), 423
Osmium Reaction mechanisms
Metal core rearrangements in hetero-bimetallic nona-osmium car- The mechanism of lithiation and nitrile insertion reactions of B-meth-
bony! clusters; the crystal and molecular structures of [Os,(CO),, ylazines: evidence from the structure of 3-C,H,NCH=C
{Au(PCy,)},] and [Os,(CO),,(Au, DPPE)] (Z. Akhter, S.L. Ing- (Ph)NCHIC(Ph)=NLi - PMDETA (S.C. Ball, R.P. Davies, P.R.
ham, J. Lewis and P.R. Raithby), 131 Raithby, G.P. Shields and R. Snaith), 457
Rh,(CO),,,
Palladium Multinuclear NMR studies on substituted derivatives of Rh,(CO),,, in
Synthesis and properties of new tris(cyanoethyl phosphine complexes solution (S.P. Tunik, 1S. Podkorytov, B.T. Heaton, J.A. Iggo and
of platinum (0,11, palladium (01D, iridium (1) and rhodium (1). J. Sampanthar), 221
492 Subject Index of Volume 550
Rhodathiaboranes Sulfur
Rhodathiaboranes with ‘anomalous’ electron counts: synthesis, struc- Dithiadiazolyls as heterocyclic chelators: a radical approach to coordi-
ture and reactivity (K.J. Adams, T.D. McGrath, G.M. Rosair, A.S. nation chemistry? (A.J. Banister, 1. May, J.M. Rawson and J.N.B.
Weller and A.J. Welch), 315 Smith), 241
Rhodium Synthesis
Multinuclear NMR studies on substituted derivatives of Rh,(CO),, in A convenient route to carbon-substituted derivatives of nido-5,6-
solution (S.P. Tunik, LS. Podkorytov, B.T. Heaton, J.A. Iggo and C,B,H,, (B. Stibr, F. Teixidor, C. Viiias and J. Fusek), 125
J. Sampanthar), 221 Synthesis and properties of new tris(cyanoethyl phosphine complexes
Synthesis and properties of new tris(cyanoethy| phosphine complexes of platinum (0.11), palladium (01D, iridium (1) and rhodium (1).
of platinum (01D, palladium (0,1), iridium (D and rhodium (1. Conformational analysis of tis(cyanoethyl)phosphine ligands
Conformational analysis of tris(cyanoethyl)phosphine ligands (A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255
(A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255 Tantalacarboranes
closo-Ru ,C , polyhedral frameworks A hydridotantalum(V )-carborane analogue of Schwartz's reagent: syn-
The synthesis and characterisation of some closed polyhedral metallo- thesis and reactivity (M.A. Curtis, M.G. Finn and R.N. Grimes),
carbon clusters (J.E. Davies, B.F.G. Johnson, C.M. Martin, R.H.H. 469
Pearson and P.J. Dyson), 431
Ruthenium clusters
Formation of H,Ru,(CO),, from H,Ru,(CO),, an improved synthe- Tantalum
sis of HRu,(CO),, B (D.A. McCarthy, J. Krause Bauer, F.-E. A hydridotantalum(V )-carborane analogue of Schwartz's reagent: syn-
Hong, J.R. Oh, H. Deng, J. Liu and S.G. Shore), 309 thesis and reactivity (M.A. Curtis, M.G. Finn and R.N. Grimes),
469
Tetraazamacrocycle
Preparation and structures of some tetraazamacrocyclic complexes of
Si and '“C NMR spectroscopy In(III) (P.R. Phillips, M.G.H. Wallbridge and J. Barker), 301
Preparation, ~’Si and '‘C NMR and DFT /IGLO studies of silylear- Tetraborane(8) carbony!
boxonium ions (G.K.S. Prakash, Q. Wang, G. Rasul and G.A. Studies on tetraborane(8) carbonyl, B,H, - CO: its isomeric composi-
Olah), 119 tion in the gas phase and in solution, and its reactions with alkenes
Silica (S.J. Cranson, M.A. Fox, R. Greatrex and N.N. Greenwood), 207
Polymer and metal oxide supported alkali metal naphthalenides: Thiophene
application in the generation of lithium and sodium reagents (T.R. Dinuclear copper(1) complexes of 24-membered bibracchial te-
Van den Ancker and C.L. Raston), 283 traimine Schiff base macrocycles derived from 2,5-di-
Silicon formylthiophene (H. Adams, N.A. Bailey, S.R. Collinson, D.E.
9,10-Dimetallatriptycenes of group 14: a structural study (M.A. Dam, Fenton, J.C. Hawley and S.J. Kitchen), 7
FJ.J. De Kanter, F. Bickelhaupt, W.J.J. Smeets, A.L. Spek, J. Tin
Fornies-Camer and C. Cardin), 347 9,10-Dimetallatriptycenes of group 14; a structural study (M.A. Dam,
Silver FJ3.J. De Kanter, F. Bickelhaupt, W.J.J. Smeets, A.L. Spek, J.
n'- and 7*-benzene coordination in [Ag(C, D,),BF,] (A.S. Batsanov, Fornies-Camer and C. Cardin), 347
S.P. Crabtree, J.A.K. Howard, C.W. Lehmann and M. Kilner), 59 Titania
Silylearboxonium ions Polymer and metal oxide supported alkali metal naphthalenides:
Preparation, *’Si and '"C NMR and DFT /IGLO studies of silylear- application in the generation of lithium and sodium reagents (T.R.
boxonium ions (G.K.S. Prakash, Q. Wang, G. Rasul and G.A. Van den Ancker and C.L. Raston), 283
Olah), 119 Titanium
Sodium reagent Organophosphonate derivatives of titanium and niobium alkoxoanions
Polymer and metal oxide supported alkali metal naphthalenides: (R.J. Errington, J. Ridland, K.J. Willett, W. Clegg. R.A. Coxall
application in the generation of lithium and sodium reagents (T.R. and S.L. Heath), 473
Van den Ancker and C.L. Raston), 283 Synthesis and structural characterization of sulfonates, phosphinates
Solution structures and carboxylates of organometallic Group 4 metal fluorides
The effect of (polyamine ligands on the solution structure of [° Li}-a- (S.A.A. Shah, H. Dorn, J. Gindl, M. Noltemeyer, H.-G. Schmidt
(phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY and H.W. Roesky), |
NMR study (S. Schade and G. Boche), 359 Total orbital energy
Solution structures in THF /(D, JTHF 1:1 The non-perpendicular and non-parallel alkyne bridge in W,( p-
The effect of polyether ligands on the solution structure of [°Li}-a- C,H, w-OCHS Bu),(OCHS Bu), (M.H. Chisholm and M.A.
(phenylthio)benzyllithium in tetrahydrofuran: A 'H.°Li-HOESY Lynn), 141
NMR study (S. Schade and G. Boche), 381 Transition metals
Stereoselective crystallization Synthesis and structural characterization of sulfonates, phosphinates
Formation of mixed aryl—, alkyl—lithium aggregates in the heteroatom and carboxylates of organometallic Group 4 metal fluorides
assisted lithiation of a,a'-dialkyl substituted |, 3-bis[{(dimethyl- (S.A.A. Shah, H. Dorn, J. Gindl, M. Noltemeyer, H.-G. Schmidt
amino)methylJbenzene (J.G. Donkervoort, J.L. Vicario, E. Rijn- and H.W. Roesky), |
berg, J.T.B.H. Jastrzebski, H. Kooijman, A.L. Spek and G. Triruthenium dodecacarbony|
Van Koten), 463 The synthesis and characterisation of some closed polyhedral metallo-
Structure carbon clusters (J.E. Davies, B.F.G. Johnson, C.M. Martin, R.H.H.
Synthesis and properties of new tris(cyanoethyl phosphine complexes Pearson and PJ. Dyson), 431
of platinum (0,11), palladium (0,11), iridium (1) and rhodium (1). Tris(cyanoethy|! phosphine
Conformational analysis of tris(cyanoethyl)phosphine ligands Synthesis and properties of new tris(cyanoethy! phosphine complexes
(A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255 of platinum (0,11), palladium (0,11), iridium (1) and rhodium (1).
Subject Index of Volume 550 493
Conformational analysis of tris(cyanoethyl)phosphine ligands The metallation of imino(triphenyl)phosphorane by ethylmagnesium
(A.G. Orpen, P.G. Pringle, M.B. Smith and K. Worboys), 255 chloride: The synthesis, isolation and X-ray structure of
Tungsten [Ph ,P=N-M O=gP(NCMe,l),] , (A.S. Batsanov, P.D. Bolton,
The non-perpendicular and non-parallel alkyne bridge in W,( p- R.C.B. Copley, M.G. Davidson, J.A.K. Howard, C. Lustig and
C,H, w-OBuC), (HOCHS B u), (M.H. Chisholm and M.A. R.D. Price), 445
Lynn), 141 The synthesis, structure and reactivity of aldehyde substituted 7 ‘-al-
lylic complexes of molybdenum (CJ. Beddows, M.R. Box, C
Wade's rules Butters, N. Carr, M. Green, M. Kursawe and M.F. Mahon), 267
Rhodathiaboranes with ‘anomalous’ electron counts: synthesis, struc- X-ray diffraction analysis
ture and reactivity (K.J. Adams, T.D. McGrath, G.M. Rosair, A.S. Metallaheteroborane chemistry. Part 14. Synthesis of the {MS,B,}-
Weller and A.J. Welch), 315 cluster compounds [9,9-(PX ,),-9.6.8-PtS,B,H,] (where X = Ph
or OMe), [9,94(PPh,),-9,.6.8-RhS,B,H,] and [5.5-(PPh,),-
X-ray 5,6,10-RhS,B,H,], and the (M,S,B,}-cluster compound
Preparation and structures of some tetraazamacrocyclic complexes of ((PPh ,), HRA(PPh , ICIRHS, B,H,] (M.P. Murphy, T.R. Spalding.
In(I11) (PLR. Phillips, M.G.H. Wallbridge and J. Barker), 301 C. Cowey, J.D. Kennedy, M. Thornton-Pett and J. Holub), 151
X-ray and neutron diffraction X-ray structure
Low temperature neutron and X-ray diffraction study of imino(tri- A structural and theoretical study of the monolithiation of hydroxy|-
pheny! )phosphorane (M.G. Davidson, A.E. Goeta, J.A.K. Howard. amines (D.R. Armstrong. W. Clegg. S.M. Hodgson. R. Snaith and
C.W. Lehmann, G.M. Mcintyre and R.D. Price), 449 A.E.H. Wheatley), 233
X-ray crystal structure Metal core rearrangements in hetero-bimetallic nona-osmium car-
Dinuclear copper(]) complexes of 24-membered bibracchial te- bony! clusters: the crystal and molecular structures of [Os,(CO),,
traimine Schiff base macrocycles derived from 2,5-dif- {Au(PCy ,)},] and [Os,(CO),,(Au, DPPE)] (Z. Akhter, S.L. Ing-
ormylthiophene (H. Adams, N.A. Bailey, S.R. Collinson, D.E. ham, J. Lewis and P.R. Raithby), 131
Fenton, J.C. Hawley and S.J. Kitchen), 7 Preparation and structures of {Li[C(N' Bu),(HN'Bu)]}, -(THF) and
X-ray diffraction {Li,[C(N'Bu),]},. containing the novel anions [C(N'Bu),
Experimental and theoretical studies on group | metallacarboranes: (HN'Bu)]” and [C(N'Bu),}~ (T. Chivers, M. Parvez and G.
Synthesis, structure and ab initio calculations of the NMR chemi- Schatte), 213
cal shifts of the 1|4(THF)-1-TMEDA)-1-Na-2,44,S),i-M2.e4 - The mechanism of lithiation and nitrile insertion reactions of B-meth-
C,B,H, and related carboranes (M.B. Ezhova, H. Zhang, J.A. ylazines: evidence from the structure of 3-C,.H,NCH=C
Maguire and N.S. Hosmane), 409 (Ph)NCHIC(Ph)- =PMNDLETiA (S.C. Ball, R.P. Davies, PR.
Formation of the lithium alkylaluminium secondary amide Raithby, G.P. Shields and R. Snaith), 457
[Me, Al{(PhCH , ),N},L i - THF] by a methane elimination /amide
insertion process (D.R. Armstrong, FJ. Craig, A.R. Kennedy and
Ylide
R.E. Mulvey), 355
The first synthesis, isolation and X-ray structure of a phosphonium
Polyhedral nonaborane chemistry: an unsuspected new isomeric type
phosphide, (Ph ,PMe)* [C,H (CF, ),-2.4.6],P}> (M.G. David-
in the nine-vertex arachno-B,H,,L system (K.L.F. Callaghan, U.
son, K.B. Dillon, J.A.K. Howard, S. Lamb and M.D. Roden), 481
Dérfler, T.D. McGrath, M. Thornton-Pett and J.D. Kennedy), 441
Rhodathiaboranes with ‘anomalous’ electron counts: synthesis, struc-
ture and reactivity (K.J. Adams, T.D. McGrath, G.M. Rosair, A.S. Zirconium
Weller and AJ. Welch), 315 Synthesis and structural characterization of sulfonates, phosphinates
The first synthesis, isolation and X-ray structure of a phosphonium and carboxylates of organometallic Group 4 metal fluorides
phosphide, (Ph ,PMe)* {([C,,H,(CF,),-2.4.6],P}” (M.G. David- (S.A.A. Shah, H. Dorn, J. Gindl, M. Noltemeyer, H.-G. Schmidt
son, K.B. Dillon, J.A.K. Howard, S. Lamb and M.D. Roden), 481 and H.W. Roesky), |