Table Of Content

ournal ofOrgano. metallic Chemistry Journal of Organometallic Chemistry 549 (1997) 323-324 Author Index of Volume 549 Abe, M., 117 Gutiérrez, E., 167 Lu, K.-L., 155 Alvarez-Toledano, C., 49 Gutiérrez-Pérez, R., 49 Lukevics, E., 163 Antelmann, B., 139 Luther-Davies, B., 127 Araki, S., 305 Haider, J.J., 319 Arsenyan, P., 163 Haiduc, I., 187 Mack, H., 39 Ashton, P.R., 233 Hakala, K., 177 Maddaluno, J., 81 Aumann, R., 311 Hamor, T.A., 233, 257 Majeed, Z., 257 He, H.-Y., 25 Mak, T.C.W., 239 Baker, P.K., 193 Heard, P.J., 295 Male, J.L., 105 Beck, W., 245 Heath, G.A., 127 Mandal, S.K., 89 Belyakov, S., 163 Hernandez-Ortega, S., 49 McQuillan, F.S., 233 Belyakova, O.A., 55 Herrmann, W.A., 319 McWhinnie, W.R., 257 Bendikov, M., 39 Hirashita, T., 305 Merzweiler, K., 263 Bentele, H.-J., 245 Hitchcock, P.B., | Modelli, A., 149 Bernés, S., 49 Hockless, D.C.R., 127 Motoyama, I., 13 Bolm, C., 275 Houbrechts, S., 127 Miiller, J.F.K., 283 Burns, R.M., 89 Humphrey, M.G., 127 Butcher, R.J., 73 Hung, J.-T., 155 Narayan, S., 73 Huttner, G., 139 Neuburger, M., 283 Chui, K., 239 Hwu, J.R., 155 Nicasio, M.C., 167 Cifuentes, M.P., 127 Nishioka, T., 117 Clark, A.I., 193 Iglesias, M., 213 Corruble, A., 81 Ignatyev, I.S., 45 Orchin, M., 89 Inoue, S., 305 Dal Colle, M., 149 Isobe, K., 117 Paneque, M., 167 De los Rios, I., 221 Pascu, S., 187 Derrien, N., 275 Jain, V.K., 73 Pauson, P.L., 199 Ding, H., 319 Jany, G., 177 Persoons, A., 127 Distefano, G., 149 Jiménez Tenorio, M., 221 Polamo, M., 177 Drew, M.G.B., 193 Jones, C.J., 233 Polyakova, L.A., 55 Durrant, M.C., 193 Pomeroy, R.K., 105 Kawai, M., 305 Popelis, J., 163 Edelmann, F.T., 101 Klinga, M., 177 Poremba, P., 101 Einstein, F.W.B., 105 Eisen, M.S., 39 Klyagina, A.P., 55 Powell, D.H., 31 Pritzkow, H., 251 Enders, M., 251 Kochina, T.A., 45 Kong, X.-F., 25 Puerta, M.C., 221 Ferrand, V., 263, 275 Krannich, L.K., 31 Fischer, R.D., 203 Kratzer, R.M., 319 Qi, M., 95 Fischer, R.W., 319 Krause Bauer, J., 89 Frenzen, G., 39 Kiihn, F.E., 319 Repo, T., 177 Fressigné, C., 81 Kumaresan, S., 155 Rheinwald, G., 263 Frohlich, R., 311 Richards, R.L., 193 Lake, C.H., 31 Rieger, B., 177 Galuzina, T.V., 55 Lappert, M.F., | Rudolph, R., 251 Gambs, C., 275 Lee, F.-Y., 155 Ruiz, C., 167 Garcia-Mellado, O., 49 Leong, W.K., 105 Gibbons, M.N., 187 Leskela, M., 177 Salazar, V., 167 Giessner-Prettre, C., 81 Li, G.Q., 89 Samoc, M., 127 Golovaneva, I.F., 55 Lin, Y., 95 Santos, A., 213 Guan, J., 203 Liu, S., 283 Sato, M., 13 Gubin, S.P., 55 Liu, Z., 239 Scagnolari, F., 149 * Elsevier Science S.A. 324 Author Index of Volume 549 Schaffner, S., 283 Tian, S., | Whittall, I.R., 127 Schauer, S.J., 31 Tocher, D.A., 295 Winterhalter, U., 139 Shen, Q., 95, 203 Tolley, M.S., 233 Silaghi-Dumitrescu, L., 187 Tyler, D.R., 105 Xi, R., 117 Silaghi-Dumitrescu, L., 187 Xie, Z., 239 Slovokhotov, Yu.L., 55 Xu, Y.-M., 25 Song, S., 95 Valerga, P., 221 Xue, F., 239 Sowerby, D.B., 187 Valnot, J.-Y., 81 Spicer, M.D., 199 Vogelgesang, J., 139 Stoeckli-Evans, H., 263, 275 Vrazhnov, D.V., 45 Yamamura, H., 305 Sun, J., 25, 239 Yu, Z., 311 Siinkel, K., 245 Siiss-Fink, G., 263, 275 Walter, O., 139 Suzuki, T., 117 Wang, J.-T., 25 Zehnder, M., 283 Watanabe, M., 13 Zhang, L., 95 Takayama, T., 13 Watkins, C.L., 31 Zhang, Z., 239 Tanna, R., 233 Wen, Y.-S., 155 Zubavichus, Ya.V., 55 7 ed ELSEVIER Journal of Organometallic Chemistry 549 (1997) 325-331 Subject Index of Volume 549 Acetylacetonate complexes (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. Synthesis and crystal structures of the distorted pentagonal bipyrami- Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 dal seven-coordinate acetylacetonate complexes [MI(acac)- Allylic alcohol (CO),(PEt,),] (M = Mo or W) (P.K. Baker, A.J. Clark, M.G.B. High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Drew, M.C. Durrant and R.L. Richards), 193 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. Acetylide Yamamura, M. Kawai and S. Araki), 305 Organometallic complexes for nonlinear optics. X. Molecular Allyl propargylic ethers quadratic and cubic hyperpolarizabilities of systematically varied The action of lithium perchlorate in ether on (allyl propargyl ether) (cyclopentadienyl)bis(phosphine)ruthenium o-arylacetylides: X- hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), ray crystal structure of Ru((E)-4,4’-C = CC,H,CH=CHC, 199 H,NO, XPPh,),(7-C;H,;) (I.R. Whittall, M.P. Cifuentes, M.G. Aminogallane Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Synthesis and characterization of a series of aminogallanes, soons, G.A. Heath and D.C.R. Hockless), 127 [Me,GaR],. The crystal structures of [Me,GaN(CH,Ph),], and Alkyne complexes [Me,GaN(CH,CH,),NMe], (S.J. Schauer, C.H. Lake, C.L. The action of lithium perchlorate in ether on (allyl propargy! ether) Watkins, L.K. Krannich and D.H. Powell), 31 hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), a@-pyrone 199 Synthesis of a new iron tricarbonyl (n*)-a-pyrone complex by reac- Alkynes tion of iron vinyldiketone complexes with methyllithium under a Carbon—carbon coupling reactions on triruthenium clusters: synthesis CO atmosphere (C. Alvarez-Toledano, S. Hernandez-Ortega, S. and structure of Ru,(CO),[ ~,-—7*-PhCCCC(H)PhI][ u,-NS Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 (O)MePh] and Ru,( 4,-COXCO),[ «,—n*-PhCCCC(H)PhIl 2 5- NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Bolm, H. | 3-Bis(trimethylsilyl)- 1-aza-allyls Stoeckli-Evans and G. Siiss-Fink), 275 Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1- Triruthenium clusters containing vinyl ligands: synthesis and structure aza-allyl-lanthanide complexes; X-ray structures of [Sm(LU), of Ru,(,-CO),(CO),.[ w3-NS(O)MePh]( 1 »,-n',n’- I(thf)], [Yb(LL’),] and [RN=C(Bu')CH(R)], (thf = PhCH,C=CH,), Ru,(.-COXCO),[ w;-NS(O)MePh\( p,- tetrahydrofuran, LL’ = n°-N(R)C(Bu')CHR, R=SiMe,) (P.B. n',n?-Pr®°C=CHPr"), Ru,( y2,-COMXCO),[ ~,-NS(O)MePh\ p5- Hitchcock, M.F. Lappert and S. Tian), | n',n?-PhC=CHBu"), and (p,-H)Ru,(CO),( u5-n',n?- Bond length PhC=CHPh)( yu 3-n',n?-PhC=CPh) [yp,-7',n?- |-Fluorogermatrane—germatrane with the shortest intramolecular N NS(O)Me(C,.H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. — Ge bond (E. Lukevics, S. Belyakov, P. Arsenyan and J. Stoeckli-Evans and G. Siiss-Fink), 263 Popelis), 163 Alkynol The interaction of [Cp* RuCl(dippe)] and [CpRuCl(dippe)] with Carbene complexes alkynols: hydroxyvinylidene, allenylidene and related derivatives Organic syntheses via transition metal complexes, XCI'. Dihydropy- (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 aryl imines to (l-alkynyl)carbene complexes of chromium and (1-Alkynylcarbene complexes tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 Organic syntheses via transition metal complexes, XCI'. Dihydropy- Carbon—carbon coupling ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Carbon-—carbon coupling reactions on triruthenium clusters: synthesis aryl imines to (l-alkynyl)carbene complexes of chromium and and structure of Ru,(CO),[ 4;-7°*-PhCCCC(H)PhI[ ,-NS tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 (O)MePh] and Ru,(u,-CO\CO),[ w,-7n*-PhCCCC(H) Alkynyl Ph][ 43-NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Organometallic complexes for nonlinear optics. X. Molecular Bolm, H. Stoeckli-Evans and G. Siiss-Fink), 275 quadratic and cubic hyperpolarizabilities of systematically varied Carbon nucleophile (cyclopentadieny])bis(phosphine)ruthenium o-arylacetylides: X- Proton sponge as a carbon nucleophile, addition to a putative carboca- ray crystal structure of Ru((E£)-4,4’-C = CC,H,CH=CHC, tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. H,NO,\PPh;),(7-C;H,;) (IR. Whittall, M.P. Cifuentes, M.G. Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Carbonyl chromium complexes soons, G.A. Heath and D.C.R. Hockless), 127 Hydrocarbon bridged metal complexes: XLII. Addition of aniline Allenylidene complex tricarbonyl chromium complexes to the dienyl ligands of [(n°- The interaction of [Cp* RuCl(dippe)] and [CpRuCl(dippe)] with H,CC,H,CH,)Fe(CO),]* and [(m°-C;H,CH,)Fe(CO),]* (H.-J. alkynols: hydroxyvinylidene, allenylidene and related derivatives Bentele, K. Siinkel and W. Beck), 245 @ Elsevier Science S.A. 326 Subject Index of Volume 549 Carbonyl! iron complexes K(thf)], [Yb(LL’),] and [RN=C(Bu')CH(R)], (thf = Hydrocarbon bridged metal complexes: XLII. Addition of aniline tetrahydrofuran, LL’ = y°-N(R)C(Bu')CHR, R=SiMe,) (P.B. tricarbony! chromium complexes to the dienyl ligands of [(»- Hitchcock, M.F. Lappert and S. Tian), | H ,CC,H,CH,)Fe(CO),]* and [(m°-C,H,CH,)Fe(CO),]* (H.-J. Systematic studies on the reactions of lanthanide trichlorides with Bentele, K. Siinkel and W. Beck), 245 Naf1 ,3-bis(trimethylsilycyclopentadienyl]. Crystal structures of Catalysis [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Metallocene dichlorides bearing acenaphthy] substituted cyclopentadi- Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 enyl rings: preparation and polymerization behavior (T. Repo, G. Crystal structures Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskelaé and B. Carbon—carbon coupling reactions on triruthenium clusters: synthesis Rieger), 177 and structure of Ru,(CO),[ w,—n*-PhCCCC(H)Ph][ 1>5-NS (O)MePh] and Ru,(,-COXCO),[ w,-n*-PhCCCC(H) Chloride Systematic studies on the reactions of lanthanide trichlorides with Ph][ 4,-NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Na[{1,3-bis(trimethylsilyDcyclopentadienyl]. Crystal structures of Bolm, H. Stoeckli-Evans and G. Siiss-Fink), 275 [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Synthesis and crystal structures of the distorted pentagonal bipyrami- Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 dal seven-coordinate acetylacetonate complexes [MI(acac) Chromium and tungsten complexes (CO),(PEt,),] (M = Mo or W) (P.K. Baker, A.I. Clark, M.G.B. Organic syntheses via transition metal complexes, XCI'. Dihydropy- Drew, M.C. Durrant and R.L. Richards), 193 ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Triruthenium clusters containing vinyl ligands: synthesis and structure aryl imines to (l-alkynyDcarbene complexes of chromium and of Ru,(w,-CO),(CO),[ w,-NS(O)MePh|( n5-7',n?- tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 PhCH,C=CH,), Ru,(m,-COMCO),[ w,-NS(O)MePh\( p ,- Clusters n'.n?-Pr°C=CHPr"), Ru,( ,-COXCO),[ ,-NS(O)MePh\ .;- Carbon—carbon coupling reactions on triruthenium clusters: synthesis n',n?-PhC=CHBu"), and (mw -H)Ru,(CO),.( u,-7',n?- and structure of Ru (CO) [4 ,—n*-PhCCCC(H)Ph][ 1,-NS PhC=CHPh)(u,;-n!',n°*-PhC=CPh) [y,-n',7?- (O)MePh] and Ru,( «,-COXCO),[ w,—n*-PhCCCC(H)PhI 4.; - NS(O)Me(C,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Bolm, H. Stoeckli-Evans and G. Siiss-Fink), 263 Stoeckli-Evans and G. Siiss-Fink), 275 Cyclooctatetraeny! ligands Triruthenium clusters containing vinyl ligands: synthesis and structure Cyclooctatetraenyl complexes of the early transition metals and lan- of Ru,(m,-CO),(CO),[ w,-NS(O)MePh]( n5-7',n?- thanides. IX. (Cyclooctatetraenyl lanthanide diazadiene complexes PhCH,C=CH,), Ru,(,-COKCO),[ w,-NS(O)MePh\( w,- (P. Poremba and F.T. Edelmann), 101 n'.n?-Pr"C=CHPr"), Ru,( p2>-COXCO),[ 2;-NS(O)MePh\ 1.3 - Cyclopentadienyl n',n?-PhC=CHBu"), and (y,-H)Ru,(CO),( w,-n!',n’- Systematic studies on the reactions of lanthanide trichlorides with PhC=CHPh)( yu ,-n!'.n?-PhC=CPh) [yw, -7!',n°?- Nal1 ,3-bis(trimethylsilycyclopentadienyl]. Crystal structures of NS(O)Me(C,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. [1,3-(Me,Si),C,H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Stoeckli-Evans and G. Siiss-Fink), 263 Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 Cobalt The synthesis of novel bridging cyclopentadienyl W-—Sn(IV) bonded Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- bimetallic complexes. Crystal structure of Cl,SnMo(CO),C, ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, H,(CH ,)C=N-NHC,H,(NO,), and pw-(C;H,(CH,)C=N- L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. N(CO)Ph]W(CO),SnCl, - (EtOH), (J.-T. Wang, H.-Y. He, Y.-M. Slovokhotov), 55 Xu, J. Sun and X.-F. Kong), 25 The action of lithium perchlorate in ether on (allyl propargy! ether) hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), 199 Crystals DFT The synthesis of novel bridging cyclopentadienyl W—Sn(IV) bonded Ab initio theoretical study of 3-aminopyrrolidines lithium amides as bimetallic complexes. Crystal structure of Cl,SnMo(CO),C, chiral ligands for butyllithium (C. Fressigné, A. Corruble, J.-Y. H ,(CH ,)C=N-NHC,H,(NO,), and pw-[C;H,(CH,)C=N- Valnot, J. Maddaluno and C. Giessner-Prettre), 81 N(CO)Ph]W(CO),SnCl1, - (EtOH), (J.-T. Wang, H.-Y. He, Y.-M. Diazadiene ligands Xu, J. Sun and X.-F. Kong), 25 Cyclooctatetraenyl complexes of the early transition metals and lan- Crystal structure thanides. IX. (Cyclooctatetraeny])lanthanide diazadiene complexes Conversion of a manganese—carbon-bonded complex to a man- (P. Poremba and F.T. Edelmann), 101 ganese—oxygen-bonded complex, some reactions of manganese Dibenzoylethylene carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. Synthesis of a new iron tricarbonyl (n*)-a-pyrone complex by reac- Krause Bauer and M. Orchin), 89 tion of iron vinyldiketone complexes with methyllithium under a Crystal structure, conformational diversity and solution NMR spec- CO atmosphere (C. Alvarez-Toledano, S. Hernandez-Ortega, S. troscopy of four tris(indenyl)lanthanoid(IIDtetrahydrofuran Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. Dihydropyridine Shen and R.D. Fischer), 203 Organic syntheses via transition metal complexes, XCI'. Dihydropy- Proton sponge as a carbon nucleophile, addition to a putative carboca- ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. aryl imines to (l-alkynyl)carbene complexes of chromium and Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 Synthesis and characterization of cyclometallated palladium(ID) dithio- Diorganoarsenic(V) compound late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. The first oxygen-bridged diorganoarsenic(V) compound: the crystal Jain and R.J. Butcher), 73 structure of AsMe,(S)OAs(S)Me, (L. Silaghi-Dumitrescu, S. Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1- Pascu, I. Silaghi-Dumitrescu, I. Haiduc, M.N. Gibbons and D.B. aza-allyl-lanthanide complexes; X-ray structures of [Sm(LU), Sowerby), 187 Subject Index of Volume 549 Dithiophosphate Hexamethyldisilazane Synthesis and characterization of cyclometallated palladium(ID) dithio- Radiochemical study of the reactions between the methyl cation and late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. hexamethyldisilazane (T.A. Kochina, D.V. Vrazhnov and LS. Jain and R.J. Butcher), 73 Ignatyev), 45 Donor ligands Hydrazone Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- The synthesis of novel bridging cyclopentadienyl W—Sn(IV) bonded dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und bimetallic complexes. Crystal structure of Cl,SnMo(CO),C<H, H. Pritzkow), 251 (CH ,JC=N-NHC,H,(NO,), and p-[(C,;H,(CH,)C=N- N(CO)Ph]W(CO),SnCl1, - (EtOH), (J.-T. Wang, H.-Y. He, Y.-M. Ethene Xu, J. Sun and X.-F. Kong), 25 Metallocene dichlorides bearing acenaphthy! substituted cyclopentadi- Hydrogen bond enyl rings: preparation and polymerization behavior (T. Repo, G. Proton sponge as a carbon nucleophile, addition to a putative carboca- Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. Rieger), 177 Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Hydrolysis Conversion of a manganese—carbon-bonded complex to a man- | -Fluorogermatrane ganese—oxygen-bonded complex, some reactions of manganese |-Fluorogermatrane—germatrane with the shortest intramolecular N carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. —+ Ge bond (E. Lukevics, S. Belyakov, P. Arsenyan and J. Krause Bauer and M. Orchin), 89 Popelis), 163 Fullerenepolydiphenylphosphite Synthesis of polydiphenylphosphite derivatives of [60]fullerene and Iminium carbonylmetalates their reactions with metal complexes (M. Iglesias and A. Santos), Organic syntheses via transition metal complexes, XCI'. Dihydropy- 213 ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Fullerenol aryl imines to (l-alkynyDcarbene complexes of chromium and Synthesis of polydiphenylphosphite derivatives of [60]fullerene and tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 their reactions with metal complexes (M. Iglesias and A. Santos), Indeny! 213 Syntheses of indeny! lanthanide derivatives and the molecular struc- Functionalized cyclopentadieny] tures of [((C,H;),PrCKTHF)], and [((C,H,),La(THF)] (Q. Shen, Tripod-Liganden mit Cyclopentadienyl-Donorgruppe: Synthese und M. Qi, S. Song, L. Zhang and Y. Lin), 95 Reaktivitét von Komplexen des Typs CH,C(CH,-n°- Indenyl ligand C;H,XCH,CPHR, ,PR ’, FeCl (B. Antelmann, G. Huttner, J. Crystal structure, conformational diversity and solution NMR spec- Vogelgesang, O. Walter und U. Winterhalter), 139 troscopy of four tris(indenyl)lanthanoid(IIDtetrahydrofuran adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. Shen and R.D. Fischer), 203 Germatrane Indium |-Fluorogermatrane—germatrane with the shortest intramolecular N — Ge bond (E. Lukevics, S. Belyakov, P. Arsenyan and J. High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Popelis), 163 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. Gold Yamamura, M. Kawai and S. Araki), 305 Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Iron Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. ters (S.P. Gubin, T.V. Galuzina, LF. Golovaneva, A.P. Klyagina, L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Slovokhotov), 55 Slovokhotov), 55 Synthesis of a new iron tricarbony! (7*)-a-pyrone complex by reac- Halgenotrimethylplatinum(UV) metal moiety tion of iron vinyldiketone complexes with methyllithium under a Synthesis and detailed NMR study of tricarbonylrhenium() and CO atmosphere (C. Alvarez-Toledano, S. Hernandez-Ortega, S. trimethylplatinum(IV) halide complexes of 2-methylthiomethyl-4- Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 (S)-methyl-1,3-oxazoline (L). X-ray crystal structure of fac- Iron complexes [ReBr(CO),L] (P.J. Heard and D.A. Tocher), 295 Tripod-Liganden mit Cyclopentadienyl-Donorgruppe: Synthese und Halides Reaktivitéat von Komplexen des Typs CH ,C(CH,-n°-CH,) Observations on the synthesis and chemistry of a complete series of (CH,PR,\CH,PR’,)FeCl (B. Antelmann, G. Huttner, J. Vo- phenylazophNe’ n)tyelKlur(iuCm(,II ) halides (fluoride, chloride, gelgesang, O. Walter und U. Winterhalter), 139 bromide and iodide) (Z. Majeed, W.R. McWhinnie and T.A. Isomerization Hamor), 257 Products from the photoreaction of (Me,;P4(OC),OsW(CO), with Halogenopentacarbonylrhenium metal moiety CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (JL. Synthesis and detailed NMR study of tricarbonylrhenium(I) and Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. trimethylplatinum(IV) halide complexes of 2-methylthiomethyl-4- Tyler), 105 (S)-methyl-1,3-oxazoline (L). X-ray crystal structure of fac- [ReBr(CO),L] (P.J. Heard and D.A. Tocher), 295 n°-1,3-dimethylally] Lanthanides Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1- phosphino)phenylJoxazoline-P,N} palladium(II) hexafluorophos- aza-allyl-lanthanide complexes; X-ray structures of [Sm(LL’), phates complexes complemented by 'H NMR investigations (S. I(thf)], [Yb(LL’),] and [RN=C(Bu')CH(R)], (thf = Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), tetrahydrofuran, LL’ = y*-N(R)C(Bu')CHR, R=SiMe,) (P.B. 283 Hitchcock, M.F. Lappert and S. Tian), | 328 Subject Index of Volume 549 Lanthanoid complexes Methyltrioxorhenium Crystal structure, conformational diversity and solution NMR spec- Multiple bonds between transition metals and main-group elements. troscopy of four tris(indenyl)lanthanoid(III tetrahydrofuran Part 168. Methyltrioxorhenium/Lewisbase catalysts in olefin adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. epoxidation (W.A. Herrmann, H. Ding, R.M. Kratzer, F.E. Kiihn, Shen and R.D. Fischer), 203 J.J. Haider and R.W. Fischer), 319 Lanthanum Mixed-valence Syntheses of indenyl lanthanide derivatives and the molecular struc- A molecular structure of mixed valence biruthenocenium (Ru"'Ru’Y) tures of [(C,H,),PrCl(THF)], and [((C,H,);La(THF)] (Q. Shen, salts [Ru''Cp(C,H,C,H,)CpRu'YL}(’BF*; ), (L = NCCH,, M. Qi, S. Song, L. Zhang and Y. Lin), 95 N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. Ligands Sato), 13 Synthesis and reactivity of new palladium alkyl complexes containing Mo complex PMe, ligands: Insertion reactions and formation of Synthesis of polydiphenylphosphite derivatives of [60]fullerene and bis(pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. their reactions with metal complexes (M. Iglesias and A. Santos), Paneque, C. Ruiz and V. Salazar), 167 213 Lithium amide Thermal decomposition of [Me,SiNCH,CH, NSiMe,] - Li,(THF), to N-(E)-1-Methyl-2,4-pentadiaennilyi)ne [LiN(SiMe3), - THF], via a 1,4-trimethylsilyl shift (H. Mack, G. Hydrocarbon bridged metal complexes: XLII. Addition of aniline Frenzen, M. Bendikov and M.S. Eisen), 39 tricarbonyl chromium complexes to the dienyl ligands of [(n°- Lithium amide—alkyllithium complexes H,CC,H,CH,)Fe(CO),]* and [(m°-C;H,CH,)Fe(CO),]* (H.-J. Ab initio theoretical study of 3-aminopyrrolidines lithium amides as Bentele, K. Siinkel and W. Beck), 245 chiral ligands for butyllithium (C. Fressigné, A. Corruble, J.-Y. N-Methyl-N-~(2 E,4 E)-1-methyl-2,4-hexadiaeninlyi]ne Valnot, J. Maddaluno and C. Giessner-Prettre), 81 Hydrocarbon bridged metal complexes: XLII. Addition of aniline Lithium amides conformation tricarbonyl chromium complexes to the dienyl ligands of [(»°- Ab initio theoretical study of 3-aminopyrrolidines lithium amides as H,CC,H,CH,)Fe(CO),]* and [(m°-C;H,CH,)Fe(CO),]* (H.-J. chiral ligands for butyllithium (C. Fressigné, A. Corruble, J.-Y. Bentele, K. Siinkel and W. Beck), 245 Valnot, J. Maddaluno and C. Giessner-Prettre), 81 N-fuctionalized cyclopentadienyl Lithium perchlorate Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- The action of lithium perchlorate in ether on (allyl propargyl ether) dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), H. Pritzkow), 251 199 NMR spectroscopy Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- phosphino)phenylJoxazoline-P,N} palladium(II) hexafluorophos- Manganese—carbon metallocarboxylate complex phates complexes complemented by 'H NMR investigations (S. Conversion of a manganese—carbon-bonded complex to a man- Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), ganese—oxygen-bonded complex, some reactions of manganese 283 carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. NMR studies Krause Bauer and M. Orchin), 89 Synthesis and detailed NMR study of tricarbonylrhenium(I) and Manganese—oxygen bridging carbonato complex trimethylplatinum(IV) halide complexes of 2-methylthiomethyl-4- Conversion of a manganese—carbon-bonded complex to a man- (S)-methyl-1,3-oxazoline (L). X-ray crystal structure of fac- ganese—oxygen-bonded complex, some reactions of manganese [ReBr(CO),L] (P.J. Heard and D.A. Tocher), 295 carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. Nonlinear optics Krause Bauer and M. Orchin), 89 Organometallic complexes for nonlinear optics. X. Molecular Manganese phosphine complexes quadratic and cubic hyperpolarizabilities of systematically varied Conversion of a manganese—carbon-bonded complex to a man- (cyclopentadienyl)bis(phosphine)ruthenium o-arylacetylides: X- ganese—oxygen-bonded complex, some reactions of manganese ray crystal structure of Ru((£)-4,4’-C = CC,H,CH=CHC,- carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. H,NO, XPPh,),(7-C;H,) (IR. Whittall, M.P. Cifuentes, M.G. Krause Bauer and M. Orchin), 89 Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Mer-cis- to fac-isomerization soons, G.A. Heath and D.C.R. Hockless), 127 Products from the photoreaction of (Me,PXOC),OsW(CO), with CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (U.L. Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. Olefins Tyler), 105 Multiple bonds between transition metals and main-group elements. Metallocarbaborane Part 168. Methyltrioxorhenium/Lewisbase catalysts in olefin Proton sponge as a carbon nucleophile, addition to a putative carboca- epoxidation (W.A. Herrmann, H. Ding, R.M. Kratzer, F.E. Kiihn, tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. J.J. Haider and R.W. Fischer), 319 Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Optically active clusters Metallocene Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- A molecular structure of mixed valence biruthenocenium (Ru''Ru'Y ) ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, salts [Ru'Cp(C,;H,C;H,)CpRu'YL(?BF*; ), (L = NCCH,, L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. Slovokhotov), 55 Sato), 13 Organolanthanide Metallocene dichlorides bearing acenaphthy] substituted cyclopentadi- Systematic studies on the reactions of lanthanide trichlorides with enyl rings: preparation and polymerization behavior (T. Repo, G. Na[1,3-bis(trimethylsilyl)cyclopentadienyl]. Crystal structures of Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskelaé and B. [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Rieger), 177 Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 Subject Index of Volume 549 Organolanthanide complexes Phosphine Cyclooctatetraenyl complexes of the early transition metals and lan- The interaction of [Cp* RuC\K(dippe)] and [CpRuCK(dippe)] with thanides. IX. (Cyclooctatetraeny])lanthanide diazadiene complexes alkynols: hydroxyvinylidene, allenylidene and related derivatives (P. Poremba and F.T. Edelmann), 101 (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. Organometallic chemistry Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 Synthesis and reactivity of new palladium alkyl complexes containing Phosphinooxazolines PMe, ligands: Insertion reactions and formation of bis Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- (pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. phosphino)phenylJoxazoline-P,N} palladium(II) hexafluorophos- Paneque, C. Ruiz and V. Salazar), 167 phates complexes complemented by 'H NMR investigations (S. Orthometallated Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), Synthesis and characterization of cyclometallated palladium(I) dithio- 283 late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. Photochemistry Jain and R.J. Butcher), 73 Products from the photoreaction of (Me,PKOC),OsW(CO), with Oxidation CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (JL. The first oxygen-bridged diorganoarsenic(V) compound: the crystal Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. structure of AsMe,(S)OAs(S)Me, (L. Silaghi-Dumitrescu, S. Tyler), 105 Pascu, I. Silaghi-Dumitrescu, 1. Haiduc, M.N. Gibbons and D.B. Polyethyleneimine Sowerby), 187 Thermal decomposition of [Me,SiNCH,CH, NSiMe,] - Li,(THF), to Oxidative-addition of CCl, [LiN(SiMe3), - THF], via a 1,4-trimethylsilyl shift (H. Mack, G. Products from the photoreaction of (Me,PKOC),OsW(CO), with Frenzen, M. Bendikov and M.S. Eisen), 39 CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (G.L. Polymerization Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. Metallocene dichlorides bearing acenaphthy] substituted cyclopentadi- Tyler), 105 enyl rings: preparation and polymerization behavior (T. Repo, G. Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. Palladium Rieger), 177 Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2’-(diphenyl- Praseodymium phosphino)pheny!Joxazoline-P,N} palladium(II) hexafluorophos- Syntheses of indenyl lanthanide derivatives and the molecular struc- phates complexes complemented by 'H NMR investigations (S. tures of [(C,H,),PrCK(THF)], and [(C,H,),La(THF)] (Q. Shen, Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), M. Qi, S. Song, L. Zhang and Y. Lin), 95 283 Propene Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Metallocene dichlorides bearing acenaphthy! substituted cyclopentadi- ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, enyl rings: preparation and polymerization behavior (T. Repo, G. L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. Slovokhotov), 55 Rieger), 177 Synthesis and characterization of cyclometallated palladium(II) dithio- Proton sponge late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. Proton sponge as a carbon nucleophile, addition to a putative carboca- Jain and R.J. Butcher), 73 tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. Palladium alkyl complexes Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Synthesis and reactivity of new palladium alkyl complexes containing Pyridine PMe, ligands: Insertion reactions and formation of bis Multiple bonds between transition metals and main-group elements. (pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. Part 168. Methyltrioxorhenium/Lewisbase catalysts in olefin Paneque, C. Ruiz and V. Salazar), 167 epoxidation (W.A. Herrmann, H. Ding, R.M. Kratzer, F.E. Kiihn, Pd—C oa bonds J.J. Haider and R.W. Fischer), 319 Synthesis and reactivity of new palladium alkyl complexes containing PMe, ligands: Insertion reactions and formation of bis Radiochromatographic method (pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. Radiochemical study of the reactions between the methyl cation and Paneque, C. Ruiz and V. Salazar), 167 hexamethyldisilazane (T.A. Kochina, D.V. Vrazhnov and LS. Penta-2,4-dienyl system Ignatyev), 45 High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Rearrangements 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. The action of lithium perchlorate in ether on (allyl propargyl ether) Yamamura, M. Kawai and S. Araki), 305 hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), Pentanuclear heterotrimetallic clusters 199 Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Regioselectivity ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. Slovokhotov), 55 Yamamura, M. Kawai and S. Araki), 305 Pent-2-en-4-ynyl system Rh complexes High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Synthesis of polydiphenylphosphite derivatives of [60]fullerene and 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. their reactions with metal complexes (M. Iglesias and A. Santos), Yamamura, M. Kawai and S. Araki), 305 213 Phenylazophenyl Rhodium Observations on the synthesis and chemistry of a complete series of Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- phenylazophenyK(C,N ’) tellurium(II) halides (fluoride, chloride, ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, bromide and iodide) (Z. Majeed, W.R. McWhinnie and T.A. L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Hamor), 257 Slovokhotov), 55 330 Subject Index of Volume 549 Ru complexes Synthesis and crystal structures of the distorted pentagonal bipyrami- Synthesis of polydiphenylphosphite derivatives of [60]fullerene and dal seven-coordinate acetylacetonate complexes [MI(acac) their reactions with metal complexes (M. Iglesias and A. Santos), (CO),(PEt,),] (M = Mo or W) (P.K. Baker, A.I. Clark, M.G.B. 213 Drew, M.C. Durrant and R.L. Richards), 193 Ruthenium Carbon—carbon coupling reactions on triruthenium clusters: synthesis and structure of Ru,(CO),[ w,-7*-PhCCCC(H)Ph][ w,-NS Tellurium (O)MePh] and Ru,( w,-COXCO),[ w,—n*-PhCCCC(H)PhI]l w,- Observations on the synthesis and chemistry of a complete series of NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Bolm, H. phenylazophNe’ nteyllKur(iuCm(,II ) halides (fluoride, chloride, Stoeckli-Evans and G. Siiss-Fink), 275 bromide and iodide) (Z. Majeed, W.R. McWhinnie and T.A. Organometallic complexes for nonlinear optics. X. Molecular Hamor), 257 quadratic and cubic hyperpolarizabilities of systematically varied Tetramethyldiarsinedisulfide (cyclopentadienyl)bis(phorsutphheinniuem o-arylacetylides: X- The first oxygen-bridged diorganoarsenic(V) compound: the crystal ray crystal structure of Ru((E)-4,4’-C = CC,H,CH=CHC, structure of AsMe,(S)OAs(S)Me, (L. Silaghi-Dumitrescu, S. H,NO, XPPh,),(7-C;H;) (LR. Whittall, M.P. Cifuentes, M.G. Pascu, I. Silaghi-Dumitrescu, I. Haiduc, M.N. Gibbons and D.B. Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Sowerby), 187 soons, G.A. Heath and D.C.R. Hockless), 127 Thermolysis The interaction of [Cp* RuCK(dippe)] and [CpRuClK(dippe)] with Synthesis and characterization of a series of aminogallanes, alkynols: hydroxyvinylidene, allenylidene and related derivatives [Me,GaR],. The crystal structures of [Me,GaN(CH,Ph),], and (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. [Me,GaN(CH,CH,),NMe], (S.J. Schauer, C.H. Lake, C.L. Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 Watkins, L.K. Krannich and D.H. Powell), 31 Triruthenium clusters containing vinyl ligands: synthesis and structure THF adducts of Ru,(y,-CO),(CO),.[ w,-NS(O)MePh|( nw, -',n?- Crystal structure, conformational diversity and solution NMR spec- PhCH,C=CH,), Ru,(,-COXCO),[ w,-NS(O)MePh\( w,- troscopy of four tris(indenyl)lanthanoid( [tetrahydrofuran n'.n?-Pr"C=CHPr"), Ru,( »-COXCO),[ ;-NS(O)MePh\ .;- adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. n'.n°?-PhC=CHBu"), and (y,-H)Ru,(CO),( u,-n',n’- Shen and R.D. Fischer), 203 PhC=CHPh)( uw ,-n',n°-PhC=CPh) [yp,-n!',.n?- Titanium NS(O)Me(C,,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- Stoeckli-Evans and G. Siiss-Fink), 263 dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und Ruthenocene H. Pritzkow), 251 A molecular structure of mixed valence biruthenocenium (Ru Ru'Y ) TMS-shift salts [Ru''Cp(C,;H,C;H,)CpRu'YL?(’BF*; ), (L = NCCH,, Thermal decomposition of [Me ,Si,CNH,C NSHiMe ,]- Li,(THF), to N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. [LiN(SiMe3), - THF], via a 1,4-trimethylsilyl shift (H. Mack, G. Sato), 13 Frenzen, M. Bendikov and M.S. Eisen), 39 Trimethylsily| Systematic studies on the reactions of lanthanide trichlorides with Samarium Na{1,3-bis(trimethylsily)cyclopentadienyl]. Crystal structures of Cyclooctatetraenyl complexes of the early transition metals and lan- [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, thanides. IX. (Cyclooctatetraeny!)lanthanide diazadiene complexes Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 (P. Poremba and F.T. Edelmann), 101 Tripodal ligands Silylium groups Tripod-Liganden mit Cyclopentadienyl-Donorgruppe: Synthese und Radiochemical study of the reactions between the methyl cation and Reaktivitiét von Komplexen des Typs CH,C(CH,-n°- hexamethyldisilazane (T.A. Kochina, D.V. Vrazhnov and LS. C;H,CH,PR,CH, PR’, )FeCl (B. Antelmann, G. Huttner, J. Ignatyev), 45 Vogelgesang, O. Walter und U. Winterhalter), 139 Solution NMR ('H, "13~9~ La) Crystal structure, conformational diversity and solution NMR spec- troscopy of four tris(indeny!)lanthanoid(II])tetrahydrofuran Vinylidene complex adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. The interaction of [Cp* RuCl(dippe)] and [CpRuCl(dippe)] with Shen and R.D. Fischer), 203 alkynols: hydroxyvinylidene, allenylidene and related derivatives Susceptibility (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. Organometallic complexes for nonlinear optics. X. Molecular Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 quadratic and cubic hyperpolarizabilities of systematically varied Vinylketene complexes (cyclopentadienyl)bis(phosphine)ruthenium o-arylacetylides: X- Synthesis of a new iron tricarbonyl (7*)-a-pyrone complex by reac- ray crystal structure of Ru((£)-4,4'-C = CC,H,CH=CHC,- tion of iron vinyldiketone complexes with methyllithium under a H,NO, XPPh,),(m-C;H,) (I.R. Whittall, M.P. Cifuentes, M.G. CO atmosphere (C. Alvarez-Toledano, S$. Hernandez-Ortega, S. Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 soons, G.A. Heath and D.C.R. Hockless), 127 Vinyl ligands Synthesis Triruthenium clusters containing vinyl ligands: synthesis and structure Syntheses of indenyl lanthanide derivatives and the molecular struc- of Ru,(m,-CO),(CO),[ w3-NS(O)MePh]( »,-7',n?- tures of [(CyH;),PrCK(THF)], and [(C,H,),La(THF)] (Q. Shen, PhCH,C=CH,), Ru,(y,-COMCO),[ w,-NS(O)MePh\( »;- M. Qi, S. Song, L. Zhang and Y. Lin), 95 n',n?-Pr"C=CHPr"), Ru,( ,-COXCO),[ ;-NS(O)MePh]( 2;- Synthesis and characterization of a series of aminogallanes, n',n?-PhC=CHBu"), and (w,-H)Ru,(CO),( u>-7',n?- [Me,GaR],. The crystal structures of [Me,GaN(CH,Ph),], and PhC=CHPh)(y,-n!',n?-PhC=CPh) [p,;-7',.n?- [Me,GaN(CH,CH,),NMe], (S.J. Schauer, C.H. Lake, C.L. NS(O)Me(C,,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. Watkins, L.K. Krannich and D.H. Powell), 31 Stoeckli-Evans and G. Siiss-Fink), 263 Subject Index of Volume 549 331 ‘Wing-tip’ butterfly structure phates complexes complemented by 'H NMR investigations (S. Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Liu, J.F.K. Miller, M. Neuburger, S. Schaffner and M. Zehnder), ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, 283 L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Organometallic complexes for nonlinear optics. X. Molecular Slovokhotov), 55 quadratic and cubic hyperpolarizabilities of systematically varied (cyclopentadieny|)bis(phosphine)ruthenium o-arylacetylides: X- X-ray crystal structure ray crystal structure of Ru((£)-4,4’-C = CC,H,CH=CHC, Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- H,NO, XPPh,),(7-C;H,) (1.R. Whittall, M.P. Cifuentes, M.G. ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. soons, G.A. Heath and D.C.R. Hockless), 127 Slovokhotov), 55 Thermal decomposition of [Me,SiNCH,CH, NSiMe,] - Li,(THF), to Ytterbium [LiN(SiMe3), - THF], via a 1,4-trimethylsily! shift (H. Mack, G. Cyclooctatetraenyl complexes of the early transition metals and lan- Frenzen, M. Bendikov and M.S. Eisen), 39 thanides. IX. (Cyclooctatetraeny])lanthanide diazadiene complexes X-ray diffraction (P. Poremba and F.T. Edelmann), 101 A molecular structure of mixed valence biruthenocenium (Ru' Ru! ) salts [Ru''Cp(C,H,C,H,)CpRu'YL}?’*(BF, ), (L = NCCH,, N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. Zirconium Sato), 13 Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- Syntheses of indenyl lanthanide derivatives and the molecular struc- dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und tures of [((C,H,),PrCKTHF)], and [(C,H,),La(THF)] (Q. Shen, H. Pritzkow), 251 M. Qi, S. Song, L. Zhang and Y. Lin), 95 Metallocene dichlorides bearing acenaphthy! substituted cyclopentadi- X-ray structure enyl rings: preparation and polymerization behavior (T. Repo, G. Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. phosphino)pheny!Joxazoline-P,N} palladium(II) hexafluorophos- Rieger), 177

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Preview Journal of Organometallic Chemistry 1997: Vol 549 Index

ournal ofOrgano. metallic Chemistry Journal of Organometallic Chemistry 549 (1997) 323-324 Author Index of Volume 549 Abe, M., 117 Gutiérrez, E., 167 Lu, K.-L., 155 Alvarez-Toledano, C., 49 Gutiérrez-Pérez, R., 49 Lukevics, E., 163 Antelmann, B., 139 Luther-Davies, B., 127 Araki, S., 305 Haider, J.J., 319 Arsenyan, P., 163 Haiduc, I., 187 Mack, H., 39 Ashton, P.R., 233 Hakala, K., 177 Maddaluno, J., 81 Aumann, R., 311 Hamor, T.A., 233, 257 Majeed, Z., 257 He, H.-Y., 25 Mak, T.C.W., 239 Baker, P.K., 193 Heard, P.J., 295 Male, J.L., 105 Beck, W., 245 Heath, G.A., 127 Mandal, S.K., 89 Belyakov, S., 163 Hernandez-Ortega, S., 49 McQuillan, F.S., 233 Belyakova, O.A., 55 Herrmann, W.A., 319 McWhinnie, W.R., 257 Bendikov, M., 39 Hirashita, T., 305 Merzweiler, K., 263 Bentele, H.-J., 245 Hitchcock, P.B., | Modelli, A., 149 Bernés, S., 49 Hockless, D.C.R., 127 Motoyama, I., 13 Bolm, C., 275 Houbrechts, S., 127 Miiller, J.F.K., 283 Burns, R.M., 89 Humphrey, M.G., 127 Butcher, R.J., 73 Hung, J.-T., 155 Narayan, S., 73 Huttner, G., 139 Neuburger, M., 283 Chui, K., 239 Hwu, J.R., 155 Nicasio, M.C., 167 Cifuentes, M.P., 127 Nishioka, T., 117 Clark, A.I., 193 Iglesias, M., 213 Corruble, A., 81 Ignatyev, I.S., 45 Orchin, M., 89 Inoue, S., 305 Dal Colle, M., 149 Isobe, K., 117 Paneque, M., 167 De los Rios, I., 221 Pascu, S., 187 Derrien, N., 275 Jain, V.K., 73 Pauson, P.L., 199 Ding, H., 319 Jany, G., 177 Persoons, A., 127 Distefano, G., 149 Jiménez Tenorio, M., 221 Polamo, M., 177 Drew, M.G.B., 193 Jones, C.J., 233 Polyakova, L.A., 55 Durrant, M.C., 193 Pomeroy, R.K., 105 Kawai, M., 305 Popelis, J., 163 Edelmann, F.T., 101 Klinga, M., 177 Poremba, P., 101 Einstein, F.W.B., 105 Eisen, M.S., 39 Klyagina, A.P., 55 Powell, D.H., 31 Pritzkow, H., 251 Enders, M., 251 Kochina, T.A., 45 Kong, X.-F., 25 Puerta, M.C., 221 Ferrand, V., 263, 275 Krannich, L.K., 31 Fischer, R.D., 203 Kratzer, R.M., 319 Qi, M., 95 Fischer, R.W., 319 Krause Bauer, J., 89 Frenzen, G., 39 Kiihn, F.E., 319 Repo, T., 177 Fressigné, C., 81 Kumaresan, S., 155 Rheinwald, G., 263 Frohlich, R., 311 Richards, R.L., 193 Lake, C.H., 31 Rieger, B., 177 Galuzina, T.V., 55 Lappert, M.F., | Rudolph, R., 251 Gambs, C., 275 Lee, F.-Y., 155 Ruiz, C., 167 Garcia-Mellado, O., 49 Leong, W.K., 105 Gibbons, M.N., 187 Leskela, M., 177 Salazar, V., 167 Giessner-Prettre, C., 81 Li, G.Q., 89 Samoc, M., 127 Golovaneva, I.F., 55 Lin, Y., 95 Santos, A., 213 Guan, J., 203 Liu, S., 283 Sato, M., 13 Gubin, S.P., 55 Liu, Z., 239 Scagnolari, F., 149 * Elsevier Science S.A. 324 Author Index of Volume 549 Schaffner, S., 283 Tian, S., | Whittall, I.R., 127 Schauer, S.J., 31 Tocher, D.A., 295 Winterhalter, U., 139 Shen, Q., 95, 203 Tolley, M.S., 233 Silaghi-Dumitrescu, L., 187 Tyler, D.R., 105 Xi, R., 117 Silaghi-Dumitrescu, L., 187 Xie, Z., 239 Slovokhotov, Yu.L., 55 Xu, Y.-M., 25 Song, S., 95 Valerga, P., 221 Xue, F., 239 Sowerby, D.B., 187 Valnot, J.-Y., 81 Spicer, M.D., 199 Vogelgesang, J., 139 Stoeckli-Evans, H., 263, 275 Vrazhnov, D.V., 45 Yamamura, H., 305 Sun, J., 25, 239 Yu, Z., 311 Siinkel, K., 245 Siiss-Fink, G., 263, 275 Walter, O., 139 Suzuki, T., 117 Wang, J.-T., 25 Zehnder, M., 283 Watanabe, M., 13 Zhang, L., 95 Takayama, T., 13 Watkins, C.L., 31 Zhang, Z., 239 Tanna, R., 233 Wen, Y.-S., 155 Zubavichus, Ya.V., 55 7 ed ELSEVIER Journal of Organometallic Chemistry 549 (1997) 325-331 Subject Index of Volume 549 Acetylacetonate complexes (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. Synthesis and crystal structures of the distorted pentagonal bipyrami- Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 dal seven-coordinate acetylacetonate complexes [MI(acac)- Allylic alcohol (CO),(PEt,),] (M = Mo or W) (P.K. Baker, A.J. Clark, M.G.B. High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Drew, M.C. Durrant and R.L. Richards), 193 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. Acetylide Yamamura, M. Kawai and S. Araki), 305 Organometallic complexes for nonlinear optics. X. Molecular Allyl propargylic ethers quadratic and cubic hyperpolarizabilities of systematically varied The action of lithium perchlorate in ether on (allyl propargyl ether) (cyclopentadienyl)bis(phosphine)ruthenium o-arylacetylides: X- hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), ray crystal structure of Ru((E)-4,4’-C = CC,H,CH=CHC, 199 H,NO, XPPh,),(7-C;H,;) (I.R. Whittall, M.P. Cifuentes, M.G. Aminogallane Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Synthesis and characterization of a series of aminogallanes, soons, G.A. Heath and D.C.R. Hockless), 127 [Me,GaR],. The crystal structures of [Me,GaN(CH,Ph),], and Alkyne complexes [Me,GaN(CH,CH,),NMe], (S.J. Schauer, C.H. Lake, C.L. The action of lithium perchlorate in ether on (allyl propargy! ether) Watkins, L.K. Krannich and D.H. Powell), 31 hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), a@-pyrone 199 Synthesis of a new iron tricarbonyl (n*)-a-pyrone complex by reac- Alkynes tion of iron vinyldiketone complexes with methyllithium under a Carbon—carbon coupling reactions on triruthenium clusters: synthesis CO atmosphere (C. Alvarez-Toledano, S. Hernandez-Ortega, S. and structure of Ru,(CO),[ ~,-—7*-PhCCCC(H)PhI][ u,-NS Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 (O)MePh] and Ru,( 4,-COXCO),[ «,—n*-PhCCCC(H)PhIl 2 5- NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Bolm, H. | 3-Bis(trimethylsilyl)- 1-aza-allyls Stoeckli-Evans and G. Siiss-Fink), 275 Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1- Triruthenium clusters containing vinyl ligands: synthesis and structure aza-allyl-lanthanide complexes; X-ray structures of [Sm(LU), of Ru,(,-CO),(CO),.[ w3-NS(O)MePh]( 1 »,-n',n’- I(thf)], [Yb(LL’),] and [RN=C(Bu')CH(R)], (thf = PhCH,C=CH,), Ru,(.-COXCO),[ w;-NS(O)MePh\( p,- tetrahydrofuran, LL’ = n°-N(R)C(Bu')CHR, R=SiMe,) (P.B. n',n?-Pr®°C=CHPr"), Ru,( y2,-COMXCO),[ ~,-NS(O)MePh\ p5- Hitchcock, M.F. Lappert and S. Tian), | n',n?-PhC=CHBu"), and (p,-H)Ru,(CO),( u5-n',n?- Bond length PhC=CHPh)( yu 3-n',n?-PhC=CPh) [yp,-7',n?- |-Fluorogermatrane—germatrane with the shortest intramolecular N NS(O)Me(C,.H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. — Ge bond (E. Lukevics, S. Belyakov, P. Arsenyan and J. Stoeckli-Evans and G. Siiss-Fink), 263 Popelis), 163 Alkynol The interaction of [Cp* RuCl(dippe)] and [CpRuCl(dippe)] with Carbene complexes alkynols: hydroxyvinylidene, allenylidene and related derivatives Organic syntheses via transition metal complexes, XCI'. Dihydropy- (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 aryl imines to (l-alkynyl)carbene complexes of chromium and (1-Alkynylcarbene complexes tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 Organic syntheses via transition metal complexes, XCI'. Dihydropy- Carbon—carbon coupling ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Carbon-—carbon coupling reactions on triruthenium clusters: synthesis aryl imines to (l-alkynyl)carbene complexes of chromium and and structure of Ru,(CO),[ 4;-7°*-PhCCCC(H)PhI[ ,-NS tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 (O)MePh] and Ru,(u,-CO\CO),[ w,-7n*-PhCCCC(H) Alkynyl Ph][ 43-NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Organometallic complexes for nonlinear optics. X. Molecular Bolm, H. Stoeckli-Evans and G. Siiss-Fink), 275 quadratic and cubic hyperpolarizabilities of systematically varied Carbon nucleophile (cyclopentadieny])bis(phosphine)ruthenium o-arylacetylides: X- Proton sponge as a carbon nucleophile, addition to a putative carboca- ray crystal structure of Ru((E£)-4,4’-C = CC,H,CH=CHC, tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. H,NO,\PPh;),(7-C;H,;) (IR. Whittall, M.P. Cifuentes, M.G. Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Carbonyl chromium complexes soons, G.A. Heath and D.C.R. Hockless), 127 Hydrocarbon bridged metal complexes: XLII. Addition of aniline Allenylidene complex tricarbonyl chromium complexes to the dienyl ligands of [(n°- The interaction of [Cp* RuCl(dippe)] and [CpRuCl(dippe)] with H,CC,H,CH,)Fe(CO),]* and [(m°-C;H,CH,)Fe(CO),]* (H.-J. alkynols: hydroxyvinylidene, allenylidene and related derivatives Bentele, K. Siinkel and W. Beck), 245 @ Elsevier Science S.A. 326 Subject Index of Volume 549 Carbonyl! iron complexes K(thf)], [Yb(LL’),] and [RN=C(Bu')CH(R)], (thf = Hydrocarbon bridged metal complexes: XLII. Addition of aniline tetrahydrofuran, LL’ = y°-N(R)C(Bu')CHR, R=SiMe,) (P.B. tricarbony! chromium complexes to the dienyl ligands of [(»- Hitchcock, M.F. Lappert and S. Tian), | H ,CC,H,CH,)Fe(CO),]* and [(m°-C,H,CH,)Fe(CO),]* (H.-J. Systematic studies on the reactions of lanthanide trichlorides with Bentele, K. Siinkel and W. Beck), 245 Naf1 ,3-bis(trimethylsilycyclopentadienyl]. Crystal structures of Catalysis [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Metallocene dichlorides bearing acenaphthy] substituted cyclopentadi- Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 enyl rings: preparation and polymerization behavior (T. Repo, G. Crystal structures Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskelaé and B. Carbon—carbon coupling reactions on triruthenium clusters: synthesis Rieger), 177 and structure of Ru,(CO),[ w,—n*-PhCCCC(H)Ph][ 1>5-NS (O)MePh] and Ru,(,-COXCO),[ w,-n*-PhCCCC(H) Chloride Systematic studies on the reactions of lanthanide trichlorides with Ph][ 4,-NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Na[{1,3-bis(trimethylsilyDcyclopentadienyl]. Crystal structures of Bolm, H. Stoeckli-Evans and G. Siiss-Fink), 275 [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Synthesis and crystal structures of the distorted pentagonal bipyrami- Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 dal seven-coordinate acetylacetonate complexes [MI(acac) Chromium and tungsten complexes (CO),(PEt,),] (M = Mo or W) (P.K. Baker, A.I. Clark, M.G.B. Organic syntheses via transition metal complexes, XCI'. Dihydropy- Drew, M.C. Durrant and R.L. Richards), 193 ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Triruthenium clusters containing vinyl ligands: synthesis and structure aryl imines to (l-alkynyDcarbene complexes of chromium and of Ru,(w,-CO),(CO),[ w,-NS(O)MePh|( n5-7',n?- tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 PhCH,C=CH,), Ru,(m,-COMCO),[ w,-NS(O)MePh\( p ,- Clusters n'.n?-Pr°C=CHPr"), Ru,( ,-COXCO),[ ,-NS(O)MePh\ .;- Carbon—carbon coupling reactions on triruthenium clusters: synthesis n',n?-PhC=CHBu"), and (mw -H)Ru,(CO),.( u,-7',n?- and structure of Ru (CO) [4 ,—n*-PhCCCC(H)Ph][ 1,-NS PhC=CHPh)(u,;-n!',n°*-PhC=CPh) [y,-n',7?- (O)MePh] and Ru,( «,-COXCO),[ w,—n*-PhCCCC(H)PhI 4.; - NS(O)Me(C,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Bolm, H. Stoeckli-Evans and G. Siiss-Fink), 263 Stoeckli-Evans and G. Siiss-Fink), 275 Cyclooctatetraeny! ligands Triruthenium clusters containing vinyl ligands: synthesis and structure Cyclooctatetraenyl complexes of the early transition metals and lan- of Ru,(m,-CO),(CO),[ w,-NS(O)MePh]( n5-7',n?- thanides. IX. (Cyclooctatetraenyl lanthanide diazadiene complexes PhCH,C=CH,), Ru,(,-COKCO),[ w,-NS(O)MePh\( w,- (P. Poremba and F.T. Edelmann), 101 n'.n?-Pr"C=CHPr"), Ru,( p2>-COXCO),[ 2;-NS(O)MePh\ 1.3 - Cyclopentadienyl n',n?-PhC=CHBu"), and (y,-H)Ru,(CO),( w,-n!',n’- Systematic studies on the reactions of lanthanide trichlorides with PhC=CHPh)( yu ,-n!'.n?-PhC=CPh) [yw, -7!',n°?- Nal1 ,3-bis(trimethylsilycyclopentadienyl]. Crystal structures of NS(O)Me(C,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. [1,3-(Me,Si),C,H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Stoeckli-Evans and G. Siiss-Fink), 263 Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 Cobalt The synthesis of novel bridging cyclopentadienyl W-—Sn(IV) bonded Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- bimetallic complexes. Crystal structure of Cl,SnMo(CO),C, ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, H,(CH ,)C=N-NHC,H,(NO,), and pw-(C;H,(CH,)C=N- L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. N(CO)Ph]W(CO),SnCl, - (EtOH), (J.-T. Wang, H.-Y. He, Y.-M. Slovokhotov), 55 Xu, J. Sun and X.-F. Kong), 25 The action of lithium perchlorate in ether on (allyl propargy! ether) hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), 199 Crystals DFT The synthesis of novel bridging cyclopentadienyl W—Sn(IV) bonded Ab initio theoretical study of 3-aminopyrrolidines lithium amides as bimetallic complexes. Crystal structure of Cl,SnMo(CO),C, chiral ligands for butyllithium (C. Fressigné, A. Corruble, J.-Y. H ,(CH ,)C=N-NHC,H,(NO,), and pw-[C;H,(CH,)C=N- Valnot, J. Maddaluno and C. Giessner-Prettre), 81 N(CO)Ph]W(CO),SnCl1, - (EtOH), (J.-T. Wang, H.-Y. He, Y.-M. Diazadiene ligands Xu, J. Sun and X.-F. Kong), 25 Cyclooctatetraenyl complexes of the early transition metals and lan- Crystal structure thanides. IX. (Cyclooctatetraeny])lanthanide diazadiene complexes Conversion of a manganese—carbon-bonded complex to a man- (P. Poremba and F.T. Edelmann), 101 ganese—oxygen-bonded complex, some reactions of manganese Dibenzoylethylene carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. Synthesis of a new iron tricarbonyl (n*)-a-pyrone complex by reac- Krause Bauer and M. Orchin), 89 tion of iron vinyldiketone complexes with methyllithium under a Crystal structure, conformational diversity and solution NMR spec- CO atmosphere (C. Alvarez-Toledano, S. Hernandez-Ortega, S. troscopy of four tris(indenyl)lanthanoid(IIDtetrahydrofuran Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. Dihydropyridine Shen and R.D. Fischer), 203 Organic syntheses via transition metal complexes, XCI'. Dihydropy- Proton sponge as a carbon nucleophile, addition to a putative carboca- ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. aryl imines to (l-alkynyl)carbene complexes of chromium and Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 Synthesis and characterization of cyclometallated palladium(ID) dithio- Diorganoarsenic(V) compound late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. The first oxygen-bridged diorganoarsenic(V) compound: the crystal Jain and R.J. Butcher), 73 structure of AsMe,(S)OAs(S)Me, (L. Silaghi-Dumitrescu, S. Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1- Pascu, I. Silaghi-Dumitrescu, I. Haiduc, M.N. Gibbons and D.B. aza-allyl-lanthanide complexes; X-ray structures of [Sm(LU), Sowerby), 187 Subject Index of Volume 549 Dithiophosphate Hexamethyldisilazane Synthesis and characterization of cyclometallated palladium(ID) dithio- Radiochemical study of the reactions between the methyl cation and late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. hexamethyldisilazane (T.A. Kochina, D.V. Vrazhnov and LS. Jain and R.J. Butcher), 73 Ignatyev), 45 Donor ligands Hydrazone Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- The synthesis of novel bridging cyclopentadienyl W—Sn(IV) bonded dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und bimetallic complexes. Crystal structure of Cl,SnMo(CO),C<H, H. Pritzkow), 251 (CH ,JC=N-NHC,H,(NO,), and p-[(C,;H,(CH,)C=N- N(CO)Ph]W(CO),SnCl1, - (EtOH), (J.-T. Wang, H.-Y. He, Y.-M. Ethene Xu, J. Sun and X.-F. Kong), 25 Metallocene dichlorides bearing acenaphthy! substituted cyclopentadi- Hydrogen bond enyl rings: preparation and polymerization behavior (T. Repo, G. Proton sponge as a carbon nucleophile, addition to a putative carboca- Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. Rieger), 177 Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Hydrolysis Conversion of a manganese—carbon-bonded complex to a man- | -Fluorogermatrane ganese—oxygen-bonded complex, some reactions of manganese |-Fluorogermatrane—germatrane with the shortest intramolecular N carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. —+ Ge bond (E. Lukevics, S. Belyakov, P. Arsenyan and J. Krause Bauer and M. Orchin), 89 Popelis), 163 Fullerenepolydiphenylphosphite Synthesis of polydiphenylphosphite derivatives of [60]fullerene and Iminium carbonylmetalates their reactions with metal complexes (M. Iglesias and A. Santos), Organic syntheses via transition metal complexes, XCI'. Dihydropy- 213 ridinyl carbene complexes by [4 + 2] annulation of alkenyl- or Fullerenol aryl imines to (l-alkynyDcarbene complexes of chromium and Synthesis of polydiphenylphosphite derivatives of [60]fullerene and tungsten (R. Aumann, Z. Yu and R. Frohlich), 311 their reactions with metal complexes (M. Iglesias and A. Santos), Indeny! 213 Syntheses of indeny! lanthanide derivatives and the molecular struc- Functionalized cyclopentadieny] tures of [((C,H;),PrCKTHF)], and [((C,H,),La(THF)] (Q. Shen, Tripod-Liganden mit Cyclopentadienyl-Donorgruppe: Synthese und M. Qi, S. Song, L. Zhang and Y. Lin), 95 Reaktivitét von Komplexen des Typs CH,C(CH,-n°- Indenyl ligand C;H,XCH,CPHR, ,PR ’, FeCl (B. Antelmann, G. Huttner, J. Crystal structure, conformational diversity and solution NMR spec- Vogelgesang, O. Walter und U. Winterhalter), 139 troscopy of four tris(indenyl)lanthanoid(IIDtetrahydrofuran adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. Shen and R.D. Fischer), 203 Germatrane Indium |-Fluorogermatrane—germatrane with the shortest intramolecular N — Ge bond (E. Lukevics, S. Belyakov, P. Arsenyan and J. High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Popelis), 163 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. Gold Yamamura, M. Kawai and S. Araki), 305 Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Iron Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. ters (S.P. Gubin, T.V. Galuzina, LF. Golovaneva, A.P. Klyagina, L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Slovokhotov), 55 Slovokhotov), 55 Synthesis of a new iron tricarbony! (7*)-a-pyrone complex by reac- Halgenotrimethylplatinum(UV) metal moiety tion of iron vinyldiketone complexes with methyllithium under a Synthesis and detailed NMR study of tricarbonylrhenium() and CO atmosphere (C. Alvarez-Toledano, S. Hernandez-Ortega, S. trimethylplatinum(IV) halide complexes of 2-methylthiomethyl-4- Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 (S)-methyl-1,3-oxazoline (L). X-ray crystal structure of fac- Iron complexes [ReBr(CO),L] (P.J. Heard and D.A. Tocher), 295 Tripod-Liganden mit Cyclopentadienyl-Donorgruppe: Synthese und Halides Reaktivitéat von Komplexen des Typs CH ,C(CH,-n°-CH,) Observations on the synthesis and chemistry of a complete series of (CH,PR,\CH,PR’,)FeCl (B. Antelmann, G. Huttner, J. Vo- phenylazophNe’ n)tyelKlur(iuCm(,II ) halides (fluoride, chloride, gelgesang, O. Walter und U. Winterhalter), 139 bromide and iodide) (Z. Majeed, W.R. McWhinnie and T.A. Isomerization Hamor), 257 Products from the photoreaction of (Me,;P4(OC),OsW(CO), with Halogenopentacarbonylrhenium metal moiety CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (JL. Synthesis and detailed NMR study of tricarbonylrhenium(I) and Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. trimethylplatinum(IV) halide complexes of 2-methylthiomethyl-4- Tyler), 105 (S)-methyl-1,3-oxazoline (L). X-ray crystal structure of fac- [ReBr(CO),L] (P.J. Heard and D.A. Tocher), 295 n°-1,3-dimethylally] Lanthanides Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- Synthesis, characterisation and reactions of 1,3-bis(trimethylsilyl)-1- phosphino)phenylJoxazoline-P,N} palladium(II) hexafluorophos- aza-allyl-lanthanide complexes; X-ray structures of [Sm(LL’), phates complexes complemented by 'H NMR investigations (S. I(thf)], [Yb(LL’),] and [RN=C(Bu')CH(R)], (thf = Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), tetrahydrofuran, LL’ = y*-N(R)C(Bu')CHR, R=SiMe,) (P.B. 283 Hitchcock, M.F. Lappert and S. Tian), | 328 Subject Index of Volume 549 Lanthanoid complexes Methyltrioxorhenium Crystal structure, conformational diversity and solution NMR spec- Multiple bonds between transition metals and main-group elements. troscopy of four tris(indenyl)lanthanoid(III tetrahydrofuran Part 168. Methyltrioxorhenium/Lewisbase catalysts in olefin adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. epoxidation (W.A. Herrmann, H. Ding, R.M. Kratzer, F.E. Kiihn, Shen and R.D. Fischer), 203 J.J. Haider and R.W. Fischer), 319 Lanthanum Mixed-valence Syntheses of indenyl lanthanide derivatives and the molecular struc- A molecular structure of mixed valence biruthenocenium (Ru"'Ru’Y) tures of [(C,H,),PrCl(THF)], and [((C,H,);La(THF)] (Q. Shen, salts [Ru''Cp(C,H,C,H,)CpRu'YL}(’BF*; ), (L = NCCH,, M. Qi, S. Song, L. Zhang and Y. Lin), 95 N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. Ligands Sato), 13 Synthesis and reactivity of new palladium alkyl complexes containing Mo complex PMe, ligands: Insertion reactions and formation of Synthesis of polydiphenylphosphite derivatives of [60]fullerene and bis(pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. their reactions with metal complexes (M. Iglesias and A. Santos), Paneque, C. Ruiz and V. Salazar), 167 213 Lithium amide Thermal decomposition of [Me,SiNCH,CH, NSiMe,] - Li,(THF), to N-(E)-1-Methyl-2,4-pentadiaennilyi)ne [LiN(SiMe3), - THF], via a 1,4-trimethylsilyl shift (H. Mack, G. Hydrocarbon bridged metal complexes: XLII. Addition of aniline Frenzen, M. Bendikov and M.S. Eisen), 39 tricarbonyl chromium complexes to the dienyl ligands of [(n°- Lithium amide—alkyllithium complexes H,CC,H,CH,)Fe(CO),]* and [(m°-C;H,CH,)Fe(CO),]* (H.-J. Ab initio theoretical study of 3-aminopyrrolidines lithium amides as Bentele, K. Siinkel and W. Beck), 245 chiral ligands for butyllithium (C. Fressigné, A. Corruble, J.-Y. N-Methyl-N-~(2 E,4 E)-1-methyl-2,4-hexadiaeninlyi]ne Valnot, J. Maddaluno and C. Giessner-Prettre), 81 Hydrocarbon bridged metal complexes: XLII. Addition of aniline Lithium amides conformation tricarbonyl chromium complexes to the dienyl ligands of [(»°- Ab initio theoretical study of 3-aminopyrrolidines lithium amides as H,CC,H,CH,)Fe(CO),]* and [(m°-C;H,CH,)Fe(CO),]* (H.-J. chiral ligands for butyllithium (C. Fressigné, A. Corruble, J.-Y. Bentele, K. Siinkel and W. Beck), 245 Valnot, J. Maddaluno and C. Giessner-Prettre), 81 N-fuctionalized cyclopentadienyl Lithium perchlorate Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- The action of lithium perchlorate in ether on (allyl propargyl ether) dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), H. Pritzkow), 251 199 NMR spectroscopy Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- phosphino)phenylJoxazoline-P,N} palladium(II) hexafluorophos- Manganese—carbon metallocarboxylate complex phates complexes complemented by 'H NMR investigations (S. Conversion of a manganese—carbon-bonded complex to a man- Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), ganese—oxygen-bonded complex, some reactions of manganese 283 carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. NMR studies Krause Bauer and M. Orchin), 89 Synthesis and detailed NMR study of tricarbonylrhenium(I) and Manganese—oxygen bridging carbonato complex trimethylplatinum(IV) halide complexes of 2-methylthiomethyl-4- Conversion of a manganese—carbon-bonded complex to a man- (S)-methyl-1,3-oxazoline (L). X-ray crystal structure of fac- ganese—oxygen-bonded complex, some reactions of manganese [ReBr(CO),L] (P.J. Heard and D.A. Tocher), 295 carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. Nonlinear optics Krause Bauer and M. Orchin), 89 Organometallic complexes for nonlinear optics. X. Molecular Manganese phosphine complexes quadratic and cubic hyperpolarizabilities of systematically varied Conversion of a manganese—carbon-bonded complex to a man- (cyclopentadienyl)bis(phosphine)ruthenium o-arylacetylides: X- ganese—oxygen-bonded complex, some reactions of manganese ray crystal structure of Ru((£)-4,4’-C = CC,H,CH=CHC,- carbonato complexes (G.Q. Li, R.M. Burns, S.K. Mandal, J. H,NO, XPPh,),(7-C;H,) (IR. Whittall, M.P. Cifuentes, M.G. Krause Bauer and M. Orchin), 89 Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Mer-cis- to fac-isomerization soons, G.A. Heath and D.C.R. Hockless), 127 Products from the photoreaction of (Me,PXOC),OsW(CO), with CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (U.L. Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. Olefins Tyler), 105 Multiple bonds between transition metals and main-group elements. Metallocarbaborane Part 168. Methyltrioxorhenium/Lewisbase catalysts in olefin Proton sponge as a carbon nucleophile, addition to a putative carboca- epoxidation (W.A. Herrmann, H. Ding, R.M. Kratzer, F.E. Kiihn, tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. J.J. Haider and R.W. Fischer), 319 Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Optically active clusters Metallocene Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- A molecular structure of mixed valence biruthenocenium (Ru''Ru'Y ) ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, salts [Ru'Cp(C,;H,C;H,)CpRu'YL(?BF*; ), (L = NCCH,, L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. Slovokhotov), 55 Sato), 13 Organolanthanide Metallocene dichlorides bearing acenaphthy] substituted cyclopentadi- Systematic studies on the reactions of lanthanide trichlorides with enyl rings: preparation and polymerization behavior (T. Repo, G. Na[1,3-bis(trimethylsilyl)cyclopentadienyl]. Crystal structures of Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskelaé and B. [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, Rieger), 177 Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 Subject Index of Volume 549 Organolanthanide complexes Phosphine Cyclooctatetraenyl complexes of the early transition metals and lan- The interaction of [Cp* RuC\K(dippe)] and [CpRuCK(dippe)] with thanides. IX. (Cyclooctatetraeny])lanthanide diazadiene complexes alkynols: hydroxyvinylidene, allenylidene and related derivatives (P. Poremba and F.T. Edelmann), 101 (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. Organometallic chemistry Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 Synthesis and reactivity of new palladium alkyl complexes containing Phosphinooxazolines PMe, ligands: Insertion reactions and formation of bis Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- (pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. phosphino)phenylJoxazoline-P,N} palladium(II) hexafluorophos- Paneque, C. Ruiz and V. Salazar), 167 phates complexes complemented by 'H NMR investigations (S. Orthometallated Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), Synthesis and characterization of cyclometallated palladium(I) dithio- 283 late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. Photochemistry Jain and R.J. Butcher), 73 Products from the photoreaction of (Me,PKOC),OsW(CO), with Oxidation CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (JL. The first oxygen-bridged diorganoarsenic(V) compound: the crystal Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. structure of AsMe,(S)OAs(S)Me, (L. Silaghi-Dumitrescu, S. Tyler), 105 Pascu, I. Silaghi-Dumitrescu, 1. Haiduc, M.N. Gibbons and D.B. Polyethyleneimine Sowerby), 187 Thermal decomposition of [Me,SiNCH,CH, NSiMe,] - Li,(THF), to Oxidative-addition of CCl, [LiN(SiMe3), - THF], via a 1,4-trimethylsilyl shift (H. Mack, G. Products from the photoreaction of (Me,PKOC),OsW(CO), with Frenzen, M. Bendikov and M.S. Eisen), 39 CCl,; synthesis and isomerization of Os(CO),(PMe,)CI, (G.L. Polymerization Male, F.W.B. Einstein, W.K. Leong, R.K. Pomeroy and D.R. Metallocene dichlorides bearing acenaphthy] substituted cyclopentadi- Tyler), 105 enyl rings: preparation and polymerization behavior (T. Repo, G. Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. Palladium Rieger), 177 Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2’-(diphenyl- Praseodymium phosphino)pheny!Joxazoline-P,N} palladium(II) hexafluorophos- Syntheses of indenyl lanthanide derivatives and the molecular struc- phates complexes complemented by 'H NMR investigations (S. tures of [(C,H,),PrCK(THF)], and [(C,H,),La(THF)] (Q. Shen, Liu, J.F.K. Miiller, M. Neuburger, S. Schaffner and M. Zehnder), M. Qi, S. Song, L. Zhang and Y. Lin), 95 283 Propene Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Metallocene dichlorides bearing acenaphthy! substituted cyclopentadi- ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, enyl rings: preparation and polymerization behavior (T. Repo, G. L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. Slovokhotov), 55 Rieger), 177 Synthesis and characterization of cyclometallated palladium(II) dithio- Proton sponge late complexes of the type [Pd(E~ CXS~ S)] (S. Narayan, V.K. Proton sponge as a carbon nucleophile, addition to a putative carboca- Jain and R.J. Butcher), 73 tion linked to a dicarbacobaltaborane cage (F.S. McQuillan, T.A. Palladium alkyl complexes Hamor, R. Tanna, P.R. Ashton, M.S. Tolley and C.J. Jones), 233 Synthesis and reactivity of new palladium alkyl complexes containing Pyridine PMe, ligands: Insertion reactions and formation of bis Multiple bonds between transition metals and main-group elements. (pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. Part 168. Methyltrioxorhenium/Lewisbase catalysts in olefin Paneque, C. Ruiz and V. Salazar), 167 epoxidation (W.A. Herrmann, H. Ding, R.M. Kratzer, F.E. Kiihn, Pd—C oa bonds J.J. Haider and R.W. Fischer), 319 Synthesis and reactivity of new palladium alkyl complexes containing PMe, ligands: Insertion reactions and formation of bis Radiochromatographic method (pyrazolyl)borate derivatives (E. Gutiérrez, M.C. Nicasio, M. Radiochemical study of the reactions between the methyl cation and Paneque, C. Ruiz and V. Salazar), 167 hexamethyldisilazane (T.A. Kochina, D.V. Vrazhnov and LS. Penta-2,4-dienyl system Ignatyev), 45 High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Rearrangements 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. The action of lithium perchlorate in ether on (allyl propargyl ether) Yamamura, M. Kawai and S. Araki), 305 hexacarbonyldicobalt complexes (P.L. Pauson and M.D. Spicer), Pentanuclear heterotrimetallic clusters 199 Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Regioselectivity ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. Slovokhotov), 55 Yamamura, M. Kawai and S. Araki), 305 Pent-2-en-4-ynyl system Rh complexes High y-selectivity in the coupling of penta-2,4-dienyl- and pent-2-en- Synthesis of polydiphenylphosphite derivatives of [60]fullerene and 4-ynylindium reagents with aldehydes (T. Hirashita, S. Inoue, H. their reactions with metal complexes (M. Iglesias and A. Santos), Yamamura, M. Kawai and S. Araki), 305 213 Phenylazophenyl Rhodium Observations on the synthesis and chemistry of a complete series of Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- phenylazophenyK(C,N ’) tellurium(II) halides (fluoride, chloride, ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, bromide and iodide) (Z. Majeed, W.R. McWhinnie and T.A. L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Hamor), 257 Slovokhotov), 55 330 Subject Index of Volume 549 Ru complexes Synthesis and crystal structures of the distorted pentagonal bipyrami- Synthesis of polydiphenylphosphite derivatives of [60]fullerene and dal seven-coordinate acetylacetonate complexes [MI(acac) their reactions with metal complexes (M. Iglesias and A. Santos), (CO),(PEt,),] (M = Mo or W) (P.K. Baker, A.I. Clark, M.G.B. 213 Drew, M.C. Durrant and R.L. Richards), 193 Ruthenium Carbon—carbon coupling reactions on triruthenium clusters: synthesis and structure of Ru,(CO),[ w,-7*-PhCCCC(H)Ph][ w,-NS Tellurium (O)MePh] and Ru,( w,-COXCO),[ w,—n*-PhCCCC(H)PhI]l w,- Observations on the synthesis and chemistry of a complete series of NS(O)MePh] (V. Ferrand, C. Gambs, N. Derrien, C. Bolm, H. phenylazophNe’ nteyllKur(iuCm(,II ) halides (fluoride, chloride, Stoeckli-Evans and G. Siiss-Fink), 275 bromide and iodide) (Z. Majeed, W.R. McWhinnie and T.A. Organometallic complexes for nonlinear optics. X. Molecular Hamor), 257 quadratic and cubic hyperpolarizabilities of systematically varied Tetramethyldiarsinedisulfide (cyclopentadienyl)bis(phorsutphheinniuem o-arylacetylides: X- The first oxygen-bridged diorganoarsenic(V) compound: the crystal ray crystal structure of Ru((E)-4,4’-C = CC,H,CH=CHC, structure of AsMe,(S)OAs(S)Me, (L. Silaghi-Dumitrescu, S. H,NO, XPPh,),(7-C;H;) (LR. Whittall, M.P. Cifuentes, M.G. Pascu, I. Silaghi-Dumitrescu, I. Haiduc, M.N. Gibbons and D.B. Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Sowerby), 187 soons, G.A. Heath and D.C.R. Hockless), 127 Thermolysis The interaction of [Cp* RuCK(dippe)] and [CpRuClK(dippe)] with Synthesis and characterization of a series of aminogallanes, alkynols: hydroxyvinylidene, allenylidene and related derivatives [Me,GaR],. The crystal structures of [Me,GaN(CH,Ph),], and (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. [Me,GaN(CH,CH,),NMe], (S.J. Schauer, C.H. Lake, C.L. Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 Watkins, L.K. Krannich and D.H. Powell), 31 Triruthenium clusters containing vinyl ligands: synthesis and structure THF adducts of Ru,(y,-CO),(CO),.[ w,-NS(O)MePh|( nw, -',n?- Crystal structure, conformational diversity and solution NMR spec- PhCH,C=CH,), Ru,(,-COXCO),[ w,-NS(O)MePh\( w,- troscopy of four tris(indenyl)lanthanoid( [tetrahydrofuran n'.n?-Pr"C=CHPr"), Ru,( »-COXCO),[ ;-NS(O)MePh\ .;- adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. n'.n°?-PhC=CHBu"), and (y,-H)Ru,(CO),( u,-n',n’- Shen and R.D. Fischer), 203 PhC=CHPh)( uw ,-n',n°-PhC=CPh) [yp,-n!',.n?- Titanium NS(O)Me(C,,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- Stoeckli-Evans and G. Siiss-Fink), 263 dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und Ruthenocene H. Pritzkow), 251 A molecular structure of mixed valence biruthenocenium (Ru Ru'Y ) TMS-shift salts [Ru''Cp(C,;H,C;H,)CpRu'YL?(’BF*; ), (L = NCCH,, Thermal decomposition of [Me ,Si,CNH,C NSHiMe ,]- Li,(THF), to N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. [LiN(SiMe3), - THF], via a 1,4-trimethylsilyl shift (H. Mack, G. Sato), 13 Frenzen, M. Bendikov and M.S. Eisen), 39 Trimethylsily| Systematic studies on the reactions of lanthanide trichlorides with Samarium Na{1,3-bis(trimethylsily)cyclopentadienyl]. Crystal structures of Cyclooctatetraenyl complexes of the early transition metals and lan- [1,3-(Me,Si),C;H,],Ln (Ln = La, Nd, Gd, Dy) (Z. Xie, K. Chui, thanides. IX. (Cyclooctatetraeny!)lanthanide diazadiene complexes Z. Liu, F. Xue, Z. Zhang, T.C.W. Mak and J. Sun), 239 (P. Poremba and F.T. Edelmann), 101 Tripodal ligands Silylium groups Tripod-Liganden mit Cyclopentadienyl-Donorgruppe: Synthese und Radiochemical study of the reactions between the methyl cation and Reaktivitiét von Komplexen des Typs CH,C(CH,-n°- hexamethyldisilazane (T.A. Kochina, D.V. Vrazhnov and LS. C;H,CH,PR,CH, PR’, )FeCl (B. Antelmann, G. Huttner, J. Ignatyev), 45 Vogelgesang, O. Walter und U. Winterhalter), 139 Solution NMR ('H, "13~9~ La) Crystal structure, conformational diversity and solution NMR spec- troscopy of four tris(indeny!)lanthanoid(II])tetrahydrofuran Vinylidene complex adducts: [Ln(C,H,), - THF] (Ln = La, Pr, Nd, Sm) (J. Guan, Q. The interaction of [Cp* RuCl(dippe)] and [CpRuCl(dippe)] with Shen and R.D. Fischer), 203 alkynols: hydroxyvinylidene, allenylidene and related derivatives Susceptibility (dippe = 1,2-bis(diisopropylphosphino)ethane) (I. De los Rios, M. Organometallic complexes for nonlinear optics. X. Molecular Jiménez Tenorio, M.C. Puerta and P. Valerga), 221 quadratic and cubic hyperpolarizabilities of systematically varied Vinylketene complexes (cyclopentadienyl)bis(phosphine)ruthenium o-arylacetylides: X- Synthesis of a new iron tricarbonyl (7*)-a-pyrone complex by reac- ray crystal structure of Ru((£)-4,4'-C = CC,H,CH=CHC,- tion of iron vinyldiketone complexes with methyllithium under a H,NO, XPPh,),(m-C;H,) (I.R. Whittall, M.P. Cifuentes, M.G. CO atmosphere (C. Alvarez-Toledano, S$. Hernandez-Ortega, S. Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- Bernés, R. Gutiérrez-Pérez and O. Garcia-Mellado), 49 soons, G.A. Heath and D.C.R. Hockless), 127 Vinyl ligands Synthesis Triruthenium clusters containing vinyl ligands: synthesis and structure Syntheses of indenyl lanthanide derivatives and the molecular struc- of Ru,(m,-CO),(CO),[ w3-NS(O)MePh]( »,-7',n?- tures of [(CyH;),PrCK(THF)], and [(C,H,),La(THF)] (Q. Shen, PhCH,C=CH,), Ru,(y,-COMCO),[ w,-NS(O)MePh\( »;- M. Qi, S. Song, L. Zhang and Y. Lin), 95 n',n?-Pr"C=CHPr"), Ru,( ,-COXCO),[ ;-NS(O)MePh]( 2;- Synthesis and characterization of a series of aminogallanes, n',n?-PhC=CHBu"), and (w,-H)Ru,(CO),( u>-7',n?- [Me,GaR],. The crystal structures of [Me,GaN(CH,Ph),], and PhC=CHPh)(y,-n!',n?-PhC=CPh) [p,;-7',.n?- [Me,GaN(CH,CH,),NMe], (S.J. Schauer, C.H. Lake, C.L. NS(O)Me(C,,H,)] (V. Ferrand, K. Merzweiler, G. Rheinwald, H. Watkins, L.K. Krannich and D.H. Powell), 31 Stoeckli-Evans and G. Siiss-Fink), 263 Subject Index of Volume 549 331 ‘Wing-tip’ butterfly structure phates complexes complemented by 'H NMR investigations (S. Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- Liu, J.F.K. Miller, M. Neuburger, S. Schaffner and M. Zehnder), ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, 283 L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. Organometallic complexes for nonlinear optics. X. Molecular Slovokhotov), 55 quadratic and cubic hyperpolarizabilities of systematically varied (cyclopentadieny|)bis(phosphine)ruthenium o-arylacetylides: X- X-ray crystal structure ray crystal structure of Ru((£)-4,4’-C = CC,H,CH=CHC, Optically active pentanuclear wing-tip butterfly heterotrimetallic clus- H,NO, XPPh,),(7-C;H,) (1.R. Whittall, M.P. Cifuentes, M.G. ters (S.P. Gubin, T.V. Galuzina, I.F. Golovaneva, A.P. Klyagina, Humphrey, B. Luther-Davies, M. Samoc, S. Houbrechts, A. Per- L.A. Polyakova, O.A. Belyakova, Ya.V. Zubavichus and Yu.L. soons, G.A. Heath and D.C.R. Hockless), 127 Slovokhotov), 55 Thermal decomposition of [Me,SiNCH,CH, NSiMe,] - Li,(THF), to Ytterbium [LiN(SiMe3), - THF], via a 1,4-trimethylsily! shift (H. Mack, G. Cyclooctatetraenyl complexes of the early transition metals and lan- Frenzen, M. Bendikov and M.S. Eisen), 39 thanides. IX. (Cyclooctatetraeny])lanthanide diazadiene complexes X-ray diffraction (P. Poremba and F.T. Edelmann), 101 A molecular structure of mixed valence biruthenocenium (Ru' Ru! ) salts [Ru''Cp(C,H,C,H,)CpRu'YL}?’*(BF, ), (L = NCCH,, N(CH),N) (M. Watanabe, I. Motoyama, T. Takayama and M. Zirconium Sato), 13 Chirale Titan- und Zirkoniumkomplexe mit dem 1-(8-Chinolyl)-2,3- Syntheses of indenyl lanthanide derivatives and the molecular struc- dimethylcyclopentadienyl-Liganden (M. Enders, R. Rudolph und tures of [((C,H,),PrCKTHF)], and [(C,H,),La(THF)] (Q. Shen, H. Pritzkow), 251 M. Qi, S. Song, L. Zhang and Y. Lin), 95 Metallocene dichlorides bearing acenaphthy! substituted cyclopentadi- X-ray structure enyl rings: preparation and polymerization behavior (T. Repo, G. Crystallographic studies of {n*-1,3-dimethylallyl}{2-[2'-(diphenyl- Jany, K. Hakala, M. Klinga, M. Polamo, M. Leskela and B. phosphino)pheny!Joxazoline-P,N} palladium(II) hexafluorophos- Rieger), 177

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