Table Of Content

EVIER Volume 544, Number 2, 20 September 1997 295-297 Volume Contents Regular Papers Cyclooctatetraenyl complexes of the early transition metals and lanthanides VIII. Anionic sandwich complexes of the lanthanides containing silylated cyclooctatetraenyl ligands P. Poremba, U. Rei®mann, M. Noltemeyer, H.-G. Schmidt, W. Briiser and F.T. Edelmann. ..................0020.020 0ee e l DF-studies on a ‘stop and go’ rotor: steric and electronic factors determining the regio- and stereochemical position of a 7°-Cr(CO); metal fragment on a helically distorted biaryl ligand i, Sen, es Ce Ce, I ea SS hide ee OR Ele bles 6 Oe weR G ee tia he oe ee ew bee te ee ak 7 Redox investigation and X-ray diffraction structure of the dimeric rhodium maleonitriledithiolate complex [Cp* Rh(mnt)],. Confirmation of bridging and chelating mnt ligands in the solid-state structure Sy a Os COE DE NE 6 Nw ES NR ee ew 8 8 ee ee Be oe ele ae ee See 15 A dinuclear manganese carbonyl complex of tetramethylthiourea: X-ray crystal structure of eg-[Mn (CO) {n'-SC(NMe),,} ] K.A. Azam, Md.M. Hossain, M.B. Hursthouse, S.E. Kabir, M.M. Karim and K.M.A. Malik... ......00.2.0.00 .eeu2 ee.eee as 23 The behaviour of polydentate hydrazonic ligands derived from 2-acetylpyridine towards organotin compounds. Part I: the diorganotin(IV) complexes M. Carcelli, D. Delledonne, A. Fochi, G. Pelizzi, M.C. Rodriguez-Argiielles and U. Russo ....2..2.2..0 0 0. ee .eee .eee. enc es 29 First functionalized diorganotin (IV) derivative containing the imidobis(diphenylselenophosphinate-SSee,’ ) ligand. The synthesis and X-ray crystal structures of Bu, Sn[{N(SePPh, )5-Se,Se’}, ] and Ph, ClSn[N(SePPh, )5-Se,Se’]- H,O L. Flores-Santos, R. Cea-Olivares, S. Hernandez-Ortega, R.A. Toscano, V. Garcia-Montalvo, J. Novosad and J.D. Woollins ........... 37 Insertion of SnCl, into the metal-metal bonds in bridged binuclear complexes (Me, E)[(n°-C;H,)M(CO)],( u-CO), (E = Si, Ge; M = Fe, Ru). The molecular structure of (Me,Ge)[(n°-C,H, )Fe(CO), ],SnCl, rs es es CI ka ke ay Wk Bie ee 6 OR ew ee Le ale Oe we pew wee kk ee ew Reactions of tris(trimethylsilyl)silanecarboxylates with organolithium reagents ns ge 6 ee GS oe ee A ee ee Oe ea eo OE ee ewe we eles Redox responsive bi/tri-nuclear complexes incorporating ferrocenyl unit: Synthesis, characterization, physicochemical studies and X-ray structure of [C;H;FeC;H,CH = CHC;H,N-CH,]PR, with a mirror creating disorder a ee i a or Sg ae Be a ee we le adie a ee 0 ee ee ee Bee ew eww eo wee Wap Synthesis and molecular structure of Na{[1,3-(Me,Si),C,;H,]Yb"},( u-D A.Z. Voskoboynikov, A.Yu. Agarkov, A.K. Shestakova, I.P. Beletskaya, L.O. Kuz’mina and J.A.K. Howard ..............02208- Bimetallic complexes III. Synthesis and reactions of C;H,PPh,-bridged zirconium—molybdenum and zirconium—tungsten complexes ee eg is sag Oe ak a ee ACN eS = GN eA OA CNRS Ae OS ee ee ee Syntheses and structures of cyclopentadienyl arsenic compounds. II. Pentamethyl- and tetraisopropylcyclopentadienyl arsenic amido derivatives E.V. Avtomonov, K. Megges, X. Li, J. Lorberth, S. Wocadlo, W. Massa, K. Harms, A.V. Churakov and J.A.K. Howard ............. Oxidative addition of mono and bis(carbene) complexes derived from imidazoly] and thiazolyl gold(I) compounds H.G. Raubenheimer, PJ. Olivier, L. Lindeque, M. Desmet, J. HruSak and G.J. Kruger... 2.0... cece cece eee eee rece reece Optical metal-to-metal charge transfer in [Fe"'(CH, PPh, ),Re'(CO),Cl]* nS lS ig ete gee Me te ROS at1 a 49 BPO A hake we” Ak eee le RNR ee Oea k Oe ae ores OR Reactivity of 1-alkynylplatinum(II) complexes towards trialkylboranes i, es a as gg a a ke WO Se Oe & Re 6 8s ca 0 Se eee ON Ree OO COE bee ee Rage a eee 4 Elsevier Science S.A. 296 Volume Contents Synthese und Charakterisierung von C,- und C,-verbriickten Bis(fluorenyl)komplexen des Zirconiums und Hafniums und deren Anwendung bei der katalytischen Olefinpolymerisation B. Peifer, M.B. Welch and H.G. Alt Investigations on the synthesis and stability of n*-bonded cycloheptadienyl complexes of molybdenum Z.I. Hussain, A.-L.A.B. De Souza and M.W. Whiteley Synthesis of manganese and ruthenium complexes of phenyltrimethylsilane, diphenyltetramethyldisilane and poly(methylphenylsilane) A.J. Wiseman, R.G. Jones and M.J. Went n°-Complexes of cyclopentadienylsilylethers (C;H,OSiR, ) and hydroxycyclopentadiene (C;H,OH) with titanium and zirconium chlorides H. Plenio and A. Warnecke Sterisch tiberladene Indenylkomplexe des Zirconiums und Hafniums ee Od as oe oe Se ee we wR a ee Sl ES ee ee eee oe es Preliminary Communication Tetrahydrofuran as an one-electron donor: Highly diastereoselective coupling of cobalt-complexed propargyl aicohol G.G. Melikyan and A. Deravakian Regular Papers Heterogenised catalysts on zeolites. Synthesis of new chiral Rh(I) complexes with (2S,4R)-trans-4-RCOO-2-(t-butylaminocarbony])pyrrolidines and (2S,4S)-cis-4-RCONH-2-(t-butylaminocarbony])pyrrolidines. Heterogenisation on silica and a USY-zeolite and study of the role of support on their catalytic profile in hydrogenation of olefins A. Corma, M. Iglesias, F. Mohino and F. Sanchez In situ formation of alkenyl- and alkynylboranes for Diels—Alder reactions by boron—silicon exchange with alkenyl- and alkynylsilanes D.A. Singleton and S.-W. Leung Single component N-O chelated arylnickel(II) complexes as ethene polymerisation and CO /ethene copolymerisation catalysts. Examples of ligand induced changes to the reaction pathway S.Y. Desjardins, K.J. Cavell, J.L. Hoare, B.W. Skelton, A.N. Sobolev, A.H. White and W. Keim Dynamic NMR and X-ray diffraction study of (N-B)-diphenyl(2-aminoethoxy)borane derivatives of ephedrines and pseudoephedrines H. Hopfl, N. Farfan, D. Castillo, R. Santillan, R. Contreras, F.J. Martinez-Martinez, M. Galvan, R. Alvarez, L. Fernandez, S. Halut and J.-C. Organometallic complexes for non-linear optics XII. Syntheses and second-order susceptibilities of (neomenthyldiphenylphosphine)gold o- arylacetylides: X-ray crystal structures of Au(C=CPh\(nmdpp) and Au(( £)-4,4’-C=CC,H,CH=CHC,HN,O, (nmdpp) I.R. Whittall, M.G. Humphrey, M. Samoc, B. Luther-Davies and D.C.R. Hockless.2.... .ee .ee .eee. ee. e.ee .ee. e.ee es Synthesis, stereochemistry and decomplexation of (7-arene)(n-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids R.M.G. Roberts and E. Johnsen Preparation and characterization of (C;Me,Ph)TiCI,, the oxochloride complexes [(C;Me,Ph)TiClI,], ( 4-O) and [((C;Me, Ph)TiCI( 4-O)], and the oxo-complex [(C; Me, Ph)Ti],( u-O),. The X-ray crystal structures of [((C;Me,Ph)TiClI],, ( u-O) and [((C,Me, Ph)Til],( u-O), M. Bjorgvinsson, S. Halldorsson, I. Arnason, J. Magull and D. Fenske Preparation of oligosilanes containing perhalogenated silyl groups (—SiX,, -SiX,—, >SiX-, X =Cl, Br) and their hydrogenation by stannanes U. Herzog and G. Roewer Insertion of GeCl, into molybdenum—hydrogen bonds: a convenient route to dichlorogermyl complexes A.C. Filippou, J.G. Winter, G. Kociok-Kohn and I. Hinz Syntheses, characterization and study of the properties of heterobimetallic compounds containing ferrocenyl units. X-ray crystal structure of: [Zn{(m°-C 5H; )Fe[(m°-C 5H ,)—CH=N,—-CH— ,C—NH(CH ,), JCI, ] re. a or, OO el Ss 5 5 oy) Wk a0 65d Woe ee 406 9080 Boa. oes wp be 68 doe ee ee eee oes Rhodium(I) fluorothiolate complexes as hydroformylation catalyst precursors. Crystal structure of two polymorphs of trans- [Rh(SC,F ;( COXPPh,), ] J.L.G. Fierro, M. Martinez-Ripoll, M.D. Merchan, A. Rodriguez, P. Terreros, H. Torrens and M.A. Vivar-Cerrato Volume Contents Nucleophilic and electrophilic reactions of C; cyclo-polyenes coordinated to the [CpMoL]," * fragment (nm = 1,2; L = 1/2dppe, PMe;, P(OMe),, CO) C.G. De Azevedo, M.J. Calhorda, M.A.A.F. De C.T. Carrondo, A.R. Dias, M.T. Duarte, A.M. Galvao, C.A. Gamelas, I.S. Gongalves, F.M. Da Piedade and C.C. Romao Organometallic complexes for nonlinear optics. 14. Syntheses and second-order nonlinear optical properties of ruthenium, nickel and gold g-acetylides of 1,3,5-triethynylbenzene: X-ray crystal structures of 1-(HC = C)-3,5-C,H,(trans-C = CRuCK(dppm),), and 1,3,5-C,H,(C = CAu(PPh;)), ate : I.R. Whittall, M.G. Humphrey, S. Houbrechts, J. Maes, A. Persoons, S. Schmid and D.C.R. Hockless Author Index of volume 544 Subject Index of volume 544 Volume Contents