Table Of Content

ELSEVIER Journal of Organometallic Chemistry 515 (1996) 261 Author Index of Volume 515 Arabatti, M., 155 Jaouen, G., 103 Santini, C., 213 Jin, H., 233 Sawai, Y., 99 Barba, L., 119 Seco, M., 205 Beck, W., 173 Keppeler, B., 139 Segalés, G., 205 Besace, Y., 103 Klingebiel, U., 43 Shipil’, P.N., 11 Bonnardel, P.-A., 221 Komori, K., 27 Shribman, T., 19 Breunig, H.J., 249 Kumeta, K., 99 Sieler, J., 19 Bruce, M.1., 65, 143 Silvestru, C., 131 Skelton, B.W., 65, 89, 143, 233 Lindenberg, F., 19 Cassetta, A., 119 Sowerby, D.B., 131 Lindner, E., 139 Cavell, K.J., 233 Stanger, A., 183 Low, PJ., 65 Cecchi, P., 213 Struchkov, Yu.T., 11 Cheng, H., | Siinkel, K., 173 Chihara, T., 27 Mach, K., 57 Sutherland, E.E., 259 Cingolani, A., 119 Main, L., 109 Suzuki, E., 51 Cooney, J.M., 109 Manimaran, Bala., 155 Szepes, L., 249 Cox, PJ., 253 Marchetti, F., 119 Sztéray, B., 249 Cuenca, T., 33 Mathur, P., 155 Matsumoto, N., 37 Takata, T., 99 D’ Arata, F., 163 Mayer, H.A., 139 Thewalt, U., 57 Denisov, V.R., 11 Tothurst, V.-A., 89 Depree, C.V., 109 Nagy, A., 249 Toscano, R.A., 131 Desjardins, S.Y., 233 Nakanishi, S., 99 Trivedi, R., 155 Dolgushin, F.M., |! Nicholson, B.K., 109 Tunik, S.P., 11 Niesmann, J., 43 Eisen, M.S., 19 Nikols’kii, A.B., 11 Vaissermann, J., 103 El Amouri, H., 103 Noltemeyer, M., 43 Varga, V., 57 Ferrer, M., 205 Viasov, A.V., 11 Ogawa, H., 27 Vogler, A., 245 Fujino, M., 37 Okamoto, M., 51 Furukawa, K., 37 Oldenburg, K., 245 Wakatsuki, Y., 27 Ono, Y., 51 Galakhov, M., 33 Wang, H.-G., | Geisbauer, A., 173 Wardell, J.L., 253 Gierling, K., 139 Pang, J.Y., 193 Watanabe, N., 51 Gioia Lobbia, G., 213 Parish, R.V., 221 Waterman, S.M., 89 Giordano, F., 213 Pellei, M., 119 Weinrich, V., 173 Pertici, P., 163 Weismann, H., 183 Haiduc, I., 131 Pettinari, C., 119 White, A.H., 65, 89, 143, 233 Herbst-Irmer, R., 43 PolaSek, M., 57 Hey-Hawkins, E., 19 Xi, H.-P., | Hiller, J., 57 Reina, R., 205 Hogarth, G., 193 Robson, R., 259 Hoskins, B.F., 259 Rosini, C., 163 Yanovsky, A.L., 11 Hossain, M., 155 Résler, R., 131 Humphrey, M.G., 89 Rossell, O., 205 Zaitseva, N.N., 143 Royo, E., 33 Zhang, J.-K., | Jain, V.K., 81 Royo, P., 33 Zhang, W.-D., | Jakkal, V.S., 81 Rudolph, S., 43 Zhang, Z.-Z., | Elsevier Science S.A. ELSEVIER Journal of Organometallic Chemistry 515 (1996) 261 Author Index of Volume 515 Arabatti, M., 155 Jaouen, G., 103 Santini, C., 213 Jin, H., 233 Sawai, Y., 99 Barba, L., 119 Seco, M., 205 Beck, W., 173 Keppeler, B., 139 Segalés, G., 205 Besace, Y., 103 Klingebiel, U., 43 Shipil’, P.N., 11 Bonnardel, P.-A., 221 Komori, K., 27 Shribman, T., 19 Breunig, H.J., 249 Kumeta, K., 99 Sieler, J., 19 Bruce, M.1., 65, 143 Silvestru, C., 131 Skelton, B.W., 65, 89, 143, 233 Lindenberg, F., 19 Cassetta, A., 119 Sowerby, D.B., 131 Lindner, E., 139 Cavell, K.J., 233 Stanger, A., 183 Low, PJ., 65 Cecchi, P., 213 Struchkov, Yu.T., 11 Cheng, H., | Siinkel, K., 173 Chihara, T., 27 Mach, K., 57 Sutherland, E.E., 259 Cingolani, A., 119 Main, L., 109 Suzuki, E., 51 Cooney, J.M., 109 Manimaran, Bala., 155 Szepes, L., 249 Cox, PJ., 253 Marchetti, F., 119 Sztéray, B., 249 Cuenca, T., 33 Mathur, P., 155 Matsumoto, N., 37 Takata, T., 99 D’ Arata, F., 163 Mayer, H.A., 139 Thewalt, U., 57 Denisov, V.R., 11 Tothurst, V.-A., 89 Depree, C.V., 109 Nagy, A., 249 Toscano, R.A., 131 Desjardins, S.Y., 233 Nakanishi, S., 99 Trivedi, R., 155 Dolgushin, F.M., |! Nicholson, B.K., 109 Tunik, S.P., 11 Niesmann, J., 43 Eisen, M.S., 19 Nikols’kii, A.B., 11 Vaissermann, J., 103 El Amouri, H., 103 Noltemeyer, M., 43 Varga, V., 57 Ferrer, M., 205 Viasov, A.V., 11 Ogawa, H., 27 Vogler, A., 245 Fujino, M., 37 Okamoto, M., 51 Furukawa, K., 37 Oldenburg, K., 245 Wakatsuki, Y., 27 Ono, Y., 51 Galakhov, M., 33 Wang, H.-G., | Geisbauer, A., 173 Wardell, J.L., 253 Gierling, K., 139 Pang, J.Y., 193 Watanabe, N., 51 Gioia Lobbia, G., 213 Parish, R.V., 221 Waterman, S.M., 89 Giordano, F., 213 Pellei, M., 119 Weinrich, V., 173 Pertici, P., 163 Weismann, H., 183 Haiduc, I., 131 Pettinari, C., 119 White, A.H., 65, 89, 143, 233 Herbst-Irmer, R., 43 PolaSek, M., 57 Hey-Hawkins, E., 19 Xi, H.-P., | Hiller, J., 57 Reina, R., 205 Hogarth, G., 193 Robson, R., 259 Hoskins, B.F., 259 Rosini, C., 163 Yanovsky, A.L., 11 Hossain, M., 155 Résler, R., 131 Humphrey, M.G., 89 Rossell, O., 205 Zaitseva, N.N., 143 Royo, E., 33 Zhang, J.-K., | Jain, V.K., 81 Royo, P., 33 Zhang, W.-D., | Jakkal, V.S., 81 Rudolph, S., 43 Zhang, Z.-Z., | Elsevier Science S.A. Journal of Organometallic Chemistry 515 (1996) 263-269 Subject Index of Volume 515 Ab initio MO calculations SbOSP,N rings: crystal and molecular structures of Ph,SbCl, Rotational isomerism in tetramethylstdudiieds tbyi UbVa pnhoeto - ((OPPh,, XXPPh, JN] (X = O, S)(C. Silvestru, R. Résler, I. Haiduc, electron spectroscopy (B. Sztéray, A. Nagy, L. Szepes and H.J. R.A. Toscano and D.B. Sowerby), 131 Breunig), 249 Rotational isomerism in tetramethyldistibane studied by UV photo- Acyl electron spectroscopy (B. Sztéray, A. Nagy, L. Szepes and HJ. Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure Breunig), 249 and attempted decarbonylation of a trans 11,12-bis(dicarbonyl- Arene complexes cyclopentadienylironacyl) substituted dihydro 9,10-ethanoanthra- Photoredox chemistry of bismuth trichloride in benzene (K. Olden- cene (V. Weinrich, A. Geisbauer, K. Sinkel and W. Beck), 173 burg and A. Vogler), 245 Adducts Arene—ruthenium Carbonylation of iron(II) halide in the presence of chelate diphos- Synthesis and characterization of areneruthenium(II) dialkyldithio- phine ligands. Molecular structure of a novel intermolecular adduct phosphate complexes: single crystal structure of [Ru{SSP(OEt),)} [FeCl ,(dppe), [Fe,(CO),Cl,} (Z.-Z. Zhang, J.-K. Zhang, W.-D. (n°-p-cymene,X) [PBPPhh,] (V.K. Jain and V.S. Jakkal), 81 Zhang, H.-P. Xi, H. Cheng and H.-G. Wang), | Aryl ketones Alkali metals Reactions of orthomanganated aryl ketones with SO,: synthesis and Synthesis and structure of titanium(III) tweezer complexes with em- structural characterisation of a novel six-membered metallocyclic bedded alkali metal ions: [(n°-C,HMe,),Ti(n'-C#=C- ring and a new route to aryl sulfonates (J.M. Cooney, C.V. SiMe,),]"M* (M= Li, Na, K, and Cs) (V. Varga, J. Hiller, M. Depree,L . Maiandn B. K. Nicholson), 109 PolaSek, U. Thewalt and K. Mach), 57 Arylnickel complexes Alkyne Insertion into the nickel—carbon bond of N—O chelated aryinickeKII) Linmektal icenntresg wi th | ,4-bis(diphenylphosphino)but-2-yne (DP- complexes. The development of single component catalysts for the PBu): syntheses and molecular euuctes of [(Mo(CO){ p-DP. oligomeroif setahytlenie o(Sn.Y . Desjardins, KJ. Cavell, H. Jin, PBu)},] and [(Mo(CO),(n?-DPPBu)},(Mo(CO)}] (G. Hogarth and B.W. Skelton and A.H. White), 233 1.Y. Pang), 193 Aryl sulfonates Alkynyl Reactions of orthomanganated aryl ketones with SO,: synthesis and Some chemistry of Re,( u-HX u-C,PhXCO),: X-ray structures of structural charactoef ar niovsel asitx-imemobenre d metallocyclic ring and a new route to aryl sulfonates (J.M. Cooney, C.V. CRe,,P(h XpC-OH)X, , pR-eC,,( Puh-XXCX Ow)-,d(pPpMmeX su)-esC , PRheX,C{O p),- A[uX( P= PhH, JBKr a-ned oo. L. Maia and B.K. Nicholson), 109 Au(PPh I) and Re,( p-Br),( p-dppmXCO), (M.1. Bruce, PJ. Low, A B.W. Skelton and A.H. White), 65 (2+ 2}-Cycloadditionen eines Iminosilans—Synthese viergliedriger Allyl Heterocycle(nJ . Niesmann,U . Klingebiel, S. RudolRp. Hher,bst - A second solid-state isomer of [(PPh ,), NIRu,C(CO),(C,H,)}: shift Irmer und M. Noltemeyer), 43 of the carbonyl and allyl positions on large cluster cores by i lobutane crystalf-orpce a(Tc. kChiihnarag, K.K omHo. Orgawia a,nd Y. [2 + 2}-Cycloadditionen Iminosilans— Synthese viergliedriger Wakatsuki), 27 Heterocyclen (J. Niesmann, U. Klingebiel, S. Rudolph, R. Herbst- Aminoaryl ligands Irmer und M. Noltemeyer), 43 Organomercury(II) and organotin(IV) compounds with nitrogen-containing substituents (P.-A. Bonnardel and R.V. Parish), 221 Aminoesters Bismuth Synthesis, reactivity and X-ray molecular structure of the activated Photoredox chemistry of bismuth trichloride in benzene (K. Olden- ester complex [(n*-C,H ,COONS)Co(CO),] (NS = N-succini- burg and A. Vogler), 245 midyl) (H. El Amouri, Y. Besace, J. Vaissermann and G. Jaouen), Bridging ligand 103 A second solid-state isomer of ((PPh ,), NIRu,C(CO),,(H.C) } shift Ansa-cyclopentadienyl complexes of the carbonyl and allyl positions on large cluster cores by Hydride derivatives of Group 4 metals with the ansa(SiMe,),(°- crystal-packing force (T. Chihara, K. Komori, H. Ogawa and Y. C;H,), ligand (T. Cuenca, M. Galakhov, E. Royo and P. Royo), Wakatsuki), 27 33 Linking metal centres with | ,4-bis(diphenylphosphino)but-2-yne (DP- Antimony PBu): syntheses and molecular structures of [(Mo(CO),( u-DP Dichlorodiphenylantimony(V) derivatives of oxo- and thioimi- PBu)}, }a nd [(Mo(CO),(n?-DPPBu)},(Mo(CO))] (G. Hogarth and dodiphosphinic acids, containing novel inorganic SbO,P,N and 1.Y. Pang), 193 264 Subject Index of Volume 515 Carbon disulfide - Chelation Reactions of the cationic bis(chelate)rhodium complex [Rh(P O),]* Linking metal centres with | ,4-bis(diphenylphosphino)but-2-yne (DP- with SO,, CS, and O,/SO, (E. Lindner, B. Keppeler, H.A. PBu): syntheses and molecular structures of [{Mo(CO),( y-DP- Mayer and K. Gierling), 139 PBu)}, }a nd [(Mo(CO),(n?-DPPBu)},{Mo(CO)}] (G. Hogarth and Carbonyl J.Y. Pang), 193 1,3-Asymmetric induction by planar chiral (7*-diene)Fe(CO), com- Chromium plexes in Diels-Alder reaction (S. Nakanishi, K. Kumeta, Y. Reactions of (7°-diphenylacetylene) chromiumtricarbony! complexes Sawai and T. Takata), 99 with polynuclear carbonyls. Ill. Reactions of M,(CO),, (M = Rh, A second solid-state isomer of [(PPh,), NJ[Ru,C(CO),.(C,H,)}: shift Co) clusters with Cr(CO),(°-PhC,,Ph). Crystal and molecular of the carbonyl and ally! positions on large cluster cores by structure of the Rh,(CO),( us,n?:°-PhC,Ph)CKCO), cluster crystal-packing force (T. Chihara, K. Komori, H. Ogawa and Y. (S.P. Tunik, P.N. Shipil’, A.V. Vlasov, V.R. Denisov, A.B. Wakatsuki), 27 Nikols’kii, F.M. Dolgushin, A.I. Yanovsky and Yu.T. Struchkov), Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure ll and attempted decarbonylation of a trans 11,12-bis(dicarbonyl- Circular dichroism cyclopentadienylironacyl) substituted dihydro 9,10-ethanoanthra- Synthesis, chirooptical properties and catalytic activity of diene- cene (V. Weinrich, A. Geisbauer, K. Sinkel and W. Beck), 173 rhodium(1) and —iridium(1) cationic complexes containing bi- Pyrolysis of Ru ,( u-dppmXCO),(PPh,): formation of novel Ru, and naphthyl, C,-symmetric diamine ligands (P. Pertici, F. D’ Arata Ru, clusters (M.I. Bruce, N.N. Zaitseva, B.W. Skelton and A.H. and C. Rosini), 163 White), 143 Cluster Reactions of (°-diphenylacetylene) chromiumtricarbonyl complexes A second solid-state isomer of [(PPh,), NRu,C(CO), (C ,H,)): shift with polynuclear carbonyls. III. Reactions of M (CO),, (M = Rh, of the carbonyl and allyl positions on large cluster cores by Co) clusters with Cr(CO),(n°-PhC,Ph). Crystal and molecular crystal-packing force (T. Chihara, K. Komori, H. Ogawa and Y. structure of the Rh,(CO),( u,.7?:7°-PhC,Ph)CXCO), cluster Wakatsuki), 27 (S.P. Tunik, P.N. Shipil’, A.V. Viasov, V.R. Denisov, A.B. Mixed-metal cluster chemistry II]. P-C activation at tungsten—ti- Nikols’kii, F.M. Dolgushin, A.I. Yanovsky and Yu.T. Struchkov), iridium cores; X-ray crystal structures of [CpWIr,{ 2,-7?-PPh Il (C,H4)M -CO)(CO),] and [CpW1i -7r?-P,Ph{(C ,H,) p- Some chemistry of Re,( u-HX u-C,PhXCO),: X-ray structures of CO),(CO),(PPh,)] (S.M. Waterman, V.-A. Tolhurst, M.G. Re,( u-HX p-C,PhXCO),(PMe,),, Re,{-Au(PPh,)}( p- Humphrey, B.W. Skelton and A.H. White), 89 C,PhXCO),, Re,( u-XX y-dppmX u-C, PhXCO), [X = H, Br and Reactions of (7°-diphenylacetylene) chromiumtricarbony! complexes Au(PPh,)] and Re,( -Br),( -dppmXCO), (M.1. Bruce, P.J. Low, with polynuclear carbonyls. III. Reactions of M,(CO),, (M = Rh, B.W. Skelton and A.H. White), 65 Co) clusters with Cr(CO),(°-PhC,,Ph). Crystal and molecular Synthesis, spectroscopic and structural characterisation of structure of the Rh,(CO),( us,9?:9°-PhC,Ph)CKCO), cluster {(CO), Fe( u-CH,)Se}, and (CO), Fe,{ u-Se(CH ,),,Se} (n = 1, 2) (S.P. Tunik, P.N. Shipil’, A.V. Vlasov, V.R. Denisov, A.B. (P. Mathur, Bala. Manimaran, R. Trivedi, M. Hossain and M. Nikols’kii, F.M. Dolgushin, A.I. Yanovsky and Yu.T. Struchkov), Arabatti), 155 11 Carbonylation Superlattice structure of octa-tert-butylpentacyclol4.2.0.07°.0°*.0*7] Carbonylation of iron(II) halide in the presence of chelate diphos- octasilane found by reinvestigation of X-ray structure analysis (K. phine ligands. Molecular structure of a novel intermolecular adduct Furukawa, M. Fujino and N. Matsumoto), 37 [FeCl ,(dppe), \[Fe,(CO),Cl,] (Z.-Z. Zhang, J.-K. Zhang, W.-D. Clusters Zhang, H.-P. Xi, H. Cheng and H.-G. Wang), | Pyrolysis of Ru ,( u-dppmXCO),(PPh,): formation of novel Ru, and Carbonyl! clusters Ru, clusters (M.I. Bruce, N.N. Zaitseva, B.W. Skelton and A.H. Electrospray mass spectrometric studies of some heterometal anionic White), 143 carbonyl clusters (M. Ferrer, R. Reina, O. Rossell, M. Seco and Co G. Segalés), 205 Synthesis, reactivity and X-ray molecular structure of the activated Catalysis ester complex [(n°-C,H,COONS)Co(CO),] (NS = N-succini- Insertion into the nickel—carbon bond of N—O chelated arylnickel(II) midyl) (H. El Amouri, Y. Besace, J. Vaissermann and G. Jaouen), complexes. The development of single component catalysts for the 103 oligomerisation of ethylene (S.Y. Desjardins, K.J. Cavell, H. Jin, Copper B.W. Skelton and A.H. White), 233 Selective synthesis of triphenoxysilane by the reaction of metallic Catalyst silicon with phenol using copper(I) chloride as the catalyst (M. Selective synthesis of triphenoxysilane by the reaction of metallic Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 silicon with phenol using copper(I) chloride as the catalyst (M. Crystal structure Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 Alkyl- and aryl-sulphinylmethylger compounds Ph,GeCH, Catalytic activity S(O)R: structure of Ph ,GeCH ,S(O)C,H,Bu'- p (J.L. Wardell and Synthesis, chirooptical properties and catalytic activity of diene- PJ. Cox), 253 thodium(1) and -iridium(I) cationic complexes containing bi- Bis(4-pyridylethynyl)mercury (B.F. Hoskins, R. Robson and E.E. naphthyl, C,-symmetric diamine ligands (P. Pertici, F. D’ Arata Sutherland), 259 and C. Rosini), 163 Dichlorodiphenylantimony(V) derivatives of oxo- and thioimi- C-C bond formation dodiphosphinic acids, containing novel inorganic SbO,P,N and Insertion into the nickel—carbon bond of N—O chelated arylnickeK(I]) SbOSP,N rings: crystal and molecular structures of Ph,SbCl, complexes. The development of single component catalysts for the ((OPPh,, XXPPh., )N] (X = O, S)(C. Silvestru, R. Résler, I. Haiduc, oligomerisation of ethylene (S.Y. Desjardins, KJ. Cavell, H. Jin, R.A. Toscano and D.B. Sowerby), 131 B.W. Skelton and A.H. White), 233 Subject Index of Volume 515 Dinuclear phosphido- and arsenido-bridged early /late transition metal — complexes. Efficient catalysts for ethylene polymerization (F. [2 + 2}-Cycloadditionen eines Iminosilans—Synthese viergliedriger Lindenberg, T. Shribman, J. Sieier, E. Hey-Hawkins and M.S. Heterocyclen (J. Niesmann, U. Klingebiel, S. Rudolph, R. Herbst- Eisen), 19 Irmer und M. Noltemeyer), 43 Insertion into the nickel—carbon bond of N—O chelated arylnickeK(II) Diels—Alder reaction complexes. The development of single component catalysts for the 1,3-Asymmetric induction by planar chiral (n*-diene)Fe(CO), com- oligomerisation of ethylene (S.Y. Desjardins, KJ. Cavell, H. Jin, plexes in Diels-Alder reaction (S. Nakanishi, K. Kumeta, Y. B.W. Skelton and A.H. White), 233 Sawai and T. Takata), 99 Linking metal centres with | ,4-bis(diphenylphosphino)but-2-yne (DP- Diene PBu): syntheses and molecular structures of [(Mo(CO),( u-DP- 1,3-Asymmetric induction by planar chiral (7*-diene)Fe(CO), com- PBu)}, |a nd [((Mo(CO),(n?-DPPBu)},(Mo(CO)}] (G. Hogarth and plexes in Diels—Alder reaction (S. Nakanishi, K. Kumeta, Y. 1.Y. Pang), 193 Sawai and T. Takata), 99 Mixed-metal cluster chemistry II]. P-—C activation at tungsten—tri- Dihydro-ethanoanthracene iridium cores; X-ray crystal structures of [CpWir,{ u,-7?-PPh Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure (C,H) w-CO),(CO),] and [CpW1, -i7?-rPPH,(C,{H )K u- and anempted decarbonylation of a trans |1,12-bis(dicarbonyl- CO),(CO),(PPh,)] (S.M. Waterman, V.-A. Tolhurst, M.G. cyclop ylironacyl) substituted dihydro 9,10-ethanoanthra- Humphrey, B.W. Skelton and A.H. White), 89 cene (V. Weinrich, A. Geisbauer, K. Siinkanedl W . Beck), 173 Pyrolysis of Ru ,( u-dppmXCO),(PPh,): formation of novel Ru, and Diolefin Ru, clusters (M.I. Bruce, N.N. Zaitseva, B.W. Skelton and A.H. 1,3-Asymmetric induction by planar chiral (n*-diene)Fe(CO), com- White), 143 plexes in Diels-Alder reaction (S. Nakanishi, K. Kumeta, Y. Reactions of (7°-diphenylacetylene) chromiumwicarbonyl complexes Sawai and T. Takata), 99 with polynuclear carbonyls. III. Reactions of M (CO),, (M = Rh, Diphenylacetylene Co) clusters with Cr(CO),(y°-PhCPh,) . Crystal and molecular Reactions of (7°-diphenylacetylene) chromiumtricarbony! complexes structure of the Rh,(CO),( us,n?:7°-PhC, Ph)CHCO), cluster with polynuclear carbonyls. III. Reactions of M (CO),, (M = Rh, (S.P. Tunik, P.N. Shipil’, A.V. Vlasov, V.R. Denisov, A.B. Co) clusters with Cr(CO),(°-PhC,,Ph). Crystal and molecular Nikols’kii, F.M. Dolgushin, A.I. Yanovsky and Yu.T. Struchkov), structure of the Rh,(CO),( us,n?:7°-PhC,Ph)CX(CO), cluster 11 (S.P. Tunik, P.N. Shipil’, A.V. Vlasov, V.R. Denisov, A.B. Reactions of orthomanganated aryl ketones with SO,: synthesis and Nikols’kii, F.M. Dolgushin, A.I. Yanovsky and Yu.T. Struchkov), structural characterisation of a novel six-membered metallocyclic 11 ring and a new route to aryl sulfonates (J.M. Cooney, C.V. Diphosphine Depree, L. Main and B.K. Nicholson), 109 Linmektali cenntresg wi th | ,4-bis(diphenylphosphino)but-2-yne (DP- Some chemistry of Re,( u-HX u-C,PhXCO),: X-ray structures of PBu): syntheses and molecular snus of [{Mo(CO),{ x-DP. Re,( u-HX u-C,PhXCO),(PMe,),, Rep{ u-Au(PPh,) p- PBuan)d [){Mo,(CO}),( ?-DPPBu)},(Mo(CO))}] (G. Hogarth and C,PhXCO),, Re( u-XX y-dppmX yu-C, PhXCO), [X = H, Br and 1.Y. Pang), 193 Au(PPh,) ]a nd Re,( «-Br),( «-dppmXCO), (M.I. Bruce, PJ. Low, Direct synthesis B.W. Skelton and A.H. White), 65 Selective synthesis of triphenoxysilane by the reaction of metallic Superlattice structure of octa-tert-butylpentacyclol 4.2.0.07°.0?*.0*7} silicon with phenol using copper(I) chloride as the catalyst (M. octasilane found by reinvestigation of X-ray structure analysis (K. Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 Furukawa, M. Fujino and N. Matsumoto), 37 Distibane Synthesis and characterization of areneruthenium(II) dialkyldithio- Rotational isomerism in tetramethyldistibane studied by UV photo- phosphate complexes: single crystal structure of [Ru{SSP(OE1),} electron spectroscopy (B. Sztéray, A. Nagy, L. Szepes and HJ. (n°-p-cymeneXPPh ,)[BPh,] (V.K. Jain and V.S. Jakkal), 81 Breunig), 249 Synthesis, spectroscopic and structural characterisation of Dynamic behavior {(CO),Fe( 4-CH,)Se}, and (CO), Fe,{ 4-Se(CH ,),,Se} (n = 1, 2) Inter- vs. intramolecular rearrangement of a (Bu,P),Ni moiety in its (P. Mathur, Bala. Manimaran, R. Trivedi, M. Hossain and M. 9-alkyl and 9,10-dialkyl anthracene complexes. Limiting condi- Arabatti), 155 tions and isomer stabilities (A. Stanger and H. Weismann), 183 Cyclopentadieny! Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure Early /late heterodinuclear phosphido- and arsenido-bridged complexes and attempted decarbonylation of a trans 11,12-bis(dicarbonyl- Dinuclear phosphido- and arsenido-bridged early /late transition metal cyclopentadienylironacyl) substituted dihydro 9,10-ethanoanthra- complexes. Efficient catalysts for ethylene polymerization (F. Lindenberg, T. Shribman, J. Sieler, E. Hey-Hawkins and M.S. cene (V. Weinrich, A. Geisbauer, K. Siinkel and W. Beck), 173 Eisen), 19 Electrospray mass spectroscopy 9,10-Dialkyl anthracene Electrospray mass spectrometric studies of some heterometal anionic Inter- vs. intramolecular rearrangement of a (Bu ,P),Ni moiety in its carbonyl clusters (M. Ferrer, R. Reina, O. Rossell, M. Seco and 9-alkyl and 9,10-dialkyl anthracene complexes. Limiting condi- G. Segalés), 205 tions and isomer stabilities (A. Stanger and H. Weismann), 183 Ester complex Dialkyldithiophophate Synthesis, reactivity and X-ray molecular structure of the activated Synthesis and characterization of areneruthenium(II) dialkyldithio- ester complex [(n°-C,H,COONS)CoACO),] (NS = N-succini- phosphate complexes: single crystal structure of [Ru{SSP(OE1),} midyl) (H. El Amouri, Y. Besace, J. Vaissermann and G. Jaouen), (nf- p-cymeneX(PPh ,)IBPh, ](V.K. Jain and V.S. Jakkal), 81 103 yclob Ether-phosphines 7 (2+ 2}-Cycloadditionen eines Iminosilans—Synthese viergliedriger Reactions of the cationic bis(chelate)rhodium complex [Rh(P O),]}* Heterocyclen (J. Niesmann, U. Klingebiel, S. Rudolph, R. Herbst- with SO,, CS, and O,/SO, (E. Lindner, B. Keppeler, H.A. Irmer und M. Noltemeyer), 43 Mayer and K. Gierling), 139 266 Subject Index of Volume 515 Ethylene polymerization Imidazole adducts Dinuclear phosphido- and arsenido-bridged early /late transition metal Tin(IV) and organotin(IV) complexes containing mono or bidentate complexes. Efficient catalysts for ethylene polymerization (F. N-donor ligands. Il. 4-Phenylimidazole derivatives. Crystal and Lindenberg, T. Shribman, J. Sieler, E. Hey-Hawkins and M.S. molecular structure of [bis(4-phenylimidazole) trimethyltin(IV)] Eisen), 19 chloride (C. Pettinari, F. Marchetti, M. Pellei, A. Cingolani, L. Ethynyl Barba and A. Cassetta), 119 Bis(4-pyridylethynyl)mercury (B.F. Hoskins, R. Robson and E.E. Iminophosphane Sutherland), 259 [2 + 2}-Cycloadditionen eines Iminosilans—Synthese viergliedriger Heterocyclen (J. Niesmann, U. Klingebiel, S. Rudolph, R. Herbst- Fluxionality Irmer und M. Noltemeyer), 43 Inter- vs. intramolecular rearrangement of a (Bu,P),Ni moiety in its Iminosilane 9-alkyl and 9,10-dialkyl anthracene complexes. Limiting condi- [2 + 2}-Cycloadditionen eines Iminosilans—Synthese viergliedriger tions and isomer stabilities (A. Stanger and H. Weismann), 183 Heterocyclen (J. Niesmann, U. Klingebiel, S. Rudolph, R. Herbst- Linking metal centres with | ,4-bis(diphenylphosphino)but-2-yne (DP- Irmer und M. Noltemeyer), 43 PBu): syntheses and molecular structures of [(Mo(CO),( -DP- Ir PBu)}, }a nd [{Mo(CO),(»?-DPPBu)},{Mo(CO)}] (G. Hogarth and Synthesis, chirooptical properties and catalytic activity of diene— J.Y. Pang), 193 thodium(1) and -iridium(I) cationic complexes containing bi- naphthyl, C,-symmetric diamine ligands (P. Pertici, F. D’ Arata Gaussian calculations and C. Rosini), 163 Rotational isomerism in tetramethyldistibane studied by UV photo- Iridium electron spectroscopy (B. Sztéray, A. Nagy, L. Szepes and HJ. Mixed-metal cluster chemistry II]. P—C activation at tungsten—ti- Breunig), 249 iridium cores; X-ray crystal structures of [CpWIr,{ u,-7?-PPh Germanium (C,H, w-CO)(CO),} and [CpWir,{ u,-7?-PPH(C,H,)M u- Alkyl- and aryl-sulphinylmethylger compounds Ph,GeCH, CO),(CO),(PPh,)) (S.M. Waterman, V.-A. Tolhurst, M.G. S(O)R: structure of Ph, GeCH ,S(O)C,H,' Bu-p (J.L. Wardell and Humphrey, B.W. Skelton and A.H. White), 89 PJ. Cox), 253 Iron Gold 1,3-Asymmetric induction by planar chiral (*-diene)Fe(CO), com- Some chemistry of Re,( u-HX u-C,PhXCO),: X-ray structures of plexes in Diels—Alder reaction (S. Nakanishi, K. Kumeta, Y. Re,( u-HX w-C,PhXCO),(PMe,),, Re,{u-Au(PPh,) p- Sawai and T. Takata), 99 C,PhXCO),, Re,( x-XX y-dppmX y-C, PhXCO), [X = H, Br and Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure Au(PPh,)] and Re,( j«-Br),( x-dppmXCO), (M.1. Bruce, PJ. Low, and atempesd decarbonylation of a trans 11,12-bis(dicarbonyl- B.W. Skelton and A.H. White), 65 cyclop ylironacyl) substituted dihydro 9,10-ethanoanthracene (V. Weinrich, A. Geisbaver, K. Sinkel and W. Beck), 173 H-bonding Synthesis, spectroscopic and structural characterisation of Tin(IV) and organotin(IV) complexes containing mono or bidentate ((CO)F,e -CH, )Se), and (CO), Fe,{ u-Se(,C),H S e} (mn = 1, 2) N-donor ligands. Il. 4-Phenylimidazole derivatives. Crystal and (P. Mathur, Bala. Manimaran, R. Trivedi, M. Hossain and M. molecular structure of [bis(4-phenylimidazole) trimethyltin(IV)] Arabatti), 155 chloride (C. Pettinari, F. Marchetti, M. Pellei, A. Cingolani, L. Iron halides Barba and A. Cassetta), 119 Carbonylation of iron(II) halide in the presence of chelate diphos- Hf phine ligands. Molecular structure of a novel intermolecular adduct Hydride derivatives of Group 4 metals with the ansa-(SiMe,),(n°- [FeCl ,(dppe), [Fe,(CO),Cl,) (Z.-Z. Zhang, J.-K. Zhang, W.-D. C;H,), ligand (T. Cuenca, M. Galakhov, E. Royo and P. Royo), Zhang, H.-P. Xi, H. Cheng and H.-G. Wang), | 33 lsomer Hg A second solid-state isomer of [(PPh ,), N[Ru,C(CO),( C ,H,)}: shift Metal polypyrazolylborates. X. Thienylmercury{Il) derivatives: the of the carboanndy alll yl positions on large cluster cores by X-ray crystal structure of [(S-Me)Thien-2-ylJHg-( u-Pz), B(Pz), crystal-packing force (T. Chihara, K. Komori, H. Ogawa and Y. (G. Gioia Lobbia, P. Cecchi, F. Giordano and C. Santini), 213 Wakatsuki), 27 ' He-NMR Metal polypyrazolylborates. X. Thienylmercury({II) derivatives: the Ketone X-ray crystal structure of [(5-Me)Thien-2-ylJHg- u-Pz), B(Pz), 1,3-Asymmetric induction by planar chiral (n‘-diene)Fe(CO), com (G. Gioia Lobbia, P. Cecchi, F. Giordano and C. Santini), 213 plexes in Diels-Alder reaction (S. Nakanishi, K. Kumeta, Y. Hydrides Sawai and T. Takata), 99 Hydride derivatives of Group 4 metals with the ansa-(SiMe,),(n°- Kinetics C,H,), ligand (T. Cuenca, M. Galakhov, E. Royo and P. Royo), Inter- vs. intramolecular rearrangement of a (Bu ,P),Ni moiety in its 33 9-alkyl and 9,10-dialky! anthracene complexes. Limiting condi- Hydrocarbon bridged metal complexes tions and isomer stabilities (A. Stanger and H. Weismann), 183 Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure and attempted decarbonylation of a trans 11,12-bis(dicarbony!- Manganese cyclopentadienylironacyl) substituted dihydro 9,10-ethanoanthra- Reactions of orthomanganated aryl ketones with SO,: synthesis and cene (V. Weinrich, A. Geisbauer, K. Siinkel and W. Beck), 173 structural characterisation of a novel six-membered metallocyclic Hydrogenation ring and a new route to aryl sulfonates (J.M. Cooney, C.V. Synthesis, chirooptical properties and catalytic activity of diene— Depree, L. Main and B.K. Nicholson), 109 thodium(I) and -iridium(1) cationic complexes containing bi- Mercury naphthyl, C,-symmetric diamine ligands (P. Pertici, F. D’ Arata Bis(4-pyridylethynyl)mercury (B.F. Hoskins, R. Robson and E.E. and C. Rosini), 163 Sutherland), 259 Subject Index of Volume 515 267 Organomercury(II) and organotin(IV) compounds with nitrogen-con- midy!) (H. El Amouri, Y. Besace, J. Vaissermann and G. Jaouen), taining substituents (P.-A. Bonnardel and R.V. Parish), 221 103 Metallacycie Organosilane Dichlorodiphenylantimony(V) derivatives of oxo- and thioimi- Selective synthesis of triphenoxysilane by the reaction of metallic dodiphosphinic acids, containing novel inorganic SbO,P,N and silicon with phenol using copper(I) chloride as the catalyst (M. SbOSP,N rings: crystal and molecular structures of Ph,SbCl, Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 ((OPPh, XXPPh, JN]( X = O, S)(C. Silvestru, R. Résler, I. Haiduc, Orthometallation R.A. Toscano and D.B. Sowerby), 131 Mixed-metal cluster chemistry II]. P-C activation at tungsten—tri- Metallocycle iridium cores; X-ray crystal structures of [CpWir,{ 45-n° -PPh Reactions of orthomanganated ary! ketones with SO,: synthesis and (C,H JK #-CO),(CO),} and [CpWwir,{ Bs 7 -PPA(C,H MK w- structural characterisation of a novel six-membered metallocyclic CO),(CO),(PPh ,)) (S.M. Waterman, V.-A. Tothurst, MG. ring and a new route to aryl sulfonates (J.M. Cooney, C.V. Humphrey, B.W. Skelton and A.H. White), 89 Depree, L. Main and B.K. Nicholson), 109 Oxidation Metal—metal bonds Reactions of the cationic bis(chelate)rhodium complex [RP O),]* Electrospray mass spectrometric studies of some heterometal anionic with SO,, CS, and O,/SO, (E. Lindner, B. Keppeler, H.A. carbonyl! clusters (M. Ferrer, R. Reina, O. Rossell, M. Seco and Mayer and K. Gierling), 139 idophosphinic acids G. Segalés), 205 Methylene Dichlorodiphenylantimony(V) derivaoft oxio- vande thsioi mi- Synthesis, spectroscopic and structural characterisation of dodiphosphinic acids, containing novel inorganic SbO,P,N and {(CO),Fe( x-CH,, )Se}, and (CO), Fe,{ u-Se(CH,),Se} (n = 1, 2) SbOSP,N rings: crystal and molecular structures of Ph,SbCl, (P. Mathur, Bala. Manimaran, R. Trivedi, M. Hossain and M. ((OPPh, XXPPh, JN] (X = O, S)(C. Silvestru, R. Résler, |. Haiduc, Arabatti), 155 R.A. Toscano and D.B. Sowerby), 131 Molybdenum Linking metal centres with | ,4-bis(diphenylphosphino)but-2-yne (DP- Phenol PBu): syntheses and molecular structures of [(Mo(CO), u-DP- Selective synthesis of triphenoxysilane by the reaction of metallic PBu)}, }a nd [(Mo(CO),(n?-DPPBu)) ,(Mo(CO))}] (G. Hogarth and silicon with phenol using copper(I) chloride as the catalyst (M. J.Y. Pang), 193 Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 Phosphine Nickel Some chemistry of Re,( u-HX u-C,PhXCO),: X-ray structures of Insertion into the nickel—carbon bond of N—O chelated aryinickeK(II) Re,( w-HX p-C,PhXCO),(PMe,),, Re,{ u-Au(PPh,)K p- complexes. The development of single component catalysts for the C,PhXCO),, Re,( u-XX w-dppmX -C, PhXCO), [X = H, Br and oligomerisation of ethylene (S.Y. Desjardins, KJ. Cavell, H. Jin, Au(PPh ,)] and Re,( s-Br),( u-dppmX(CO), (M.1. Bruce, PJ. Low, B.W. Skelton and A.H. White), 233 B.W. Skelton and A.H. White), 65 Inter- vs. intramolecular rearrangement of a (Bu,P),N i moiety in its Photochemistry 9-alkyl and 9,10-dialky! anthracene complexes. Limiting condi- Photoredox chemistry of bismuth trichloride in benzene (K. Olden- tions and isomer stabilities (A. Stanger and H. Weismann), 183 burg and A. Vogler), 245 Nuclear magnetic resonance Photoelectron spectroscopy Inter- vs. intramolecular rearrangement of a (Bu ,P), Ni moiety in its 9-alkyl and 9,10-dialkyl anthracene complexes. Limiting condi- electron spectroscopy (B. Sztéray, A. Nagy, L. Szepes and HJ. tions and isomer stabilities (A. Stanger and H. Weismann), 183 Breunig), 249 Organomercury({II) and organotin(IV) compounds with nitrogen-con- Planar chiral taining substituents (P.-A. Bonnardel and R.V. Parish), 221 1,3-Asymmetric induction by planar chiral (n‘-diene)Fe(CO), complexes in Diels-Alder reaction (S. Nakanishi, K. Kumeta, Y. Sawai and T. Takata), 99 Octamethyltitanocene Polypyrazoly Iborates Synthesis and structure of titanium(III) tweezer with em- bedded alkali metal ions: [(n°-C,HMe,),Ti(n'-C#C- Metal polypyrazolylborates. X. Thienylmercury(II) derivatives: the X-ray crystal structure of [(5-Me)Thien-2-yiJHg4 -Pz), B(Pz), SiMe,),}" M* (M = Li, Na, K, and Cs) (V. Varga, J. Hiller, M. PolaSek, U. Thewalt and K. Mach), 57 (G. Gioia Lobbia, P. Cecchi, F. Giordano and C. Santini), 213 Octasilacubane Superiattice structure of octa-fert-butylpentacycla 4.2.0.07°.0°*.0*"} Pyrolysis of Ru,( 4-dppmXCO),{(PPh,): formaoft niovoeln R u, and Ru, clusters (M.1. Bruce, N.N. Zaitseva, B.W. Skelton and A.H. octasilane found by reinvestigation of X-ray structure analysis (K. Furukawa, M. Fujino and N. Matsumoto), 37 White), 143 Olefin insertion Insertion into the nickel—carbon bond of N-Oc helated arylnickeIKI ) Rh Synthesis, and catalytic activity of diene- complexes. The development of single component catalysts for the oligomerisation of ethylene (S.Y. Desjardins, KJ. Cavell, H. Jin, thodium(I) and -iridium(I) cationic complexes containing bi- B.W. Skelton and A.H. White), 233 naphthyl, C,-symmetric diamine ligands (P. Pertici, F. D’ Arata Organomercury(I1) compounds and C. Rosini), 163 Metal polypyrazolylborates. X. Thienylmercury({II) derivatives: the Rhenium X-ray crystal structure of [(5-Me)Thien-2-ylJHg u-Pz), B(Pz), Some chemistry of Re,( u-HX ~-C,PhXCO),: X-ray structures of Re,( z-HX u-C,PhXCO),(PMe,),, Re,{u-Au(PPh,)K p- (G. Gioia Lobbia, P. Cecchi, F. Giordano and C. Santini), 213 Organometallic carboxylic acid C,PhXCO),, Re,( pXX w-dppm p-C,PhXCO), [x = H, Br and Synthesis, reactivity and X-ray molecular structure of the activated Au(PPh ,)] and Re,( -Br),( u-dppmX(CO), (M.1. Bruce, PJ. Low, ester complex [(n°-C,H,COONS)Co(CO),] (NS = N-succini- B.W. Skelton and A.H. White), 65 268 Subject Index of Volume 515 '*Rh NMR a Superlattice structure Superlattice structure of octa-tert-butylpentacycla[4.2.0.07*.0°*.0*’] Reactions of the cationic bis(chelate)rhodium complex [Rh(P_ O),]* with SO,, CS, and O,/SO, (E. Lindner, B. Keppeler, H.A. octasilane found by reinvestigation of X-ray structure analysis (K. Mayer and K. Gierling), 139 Furukawa, M. Fujino and N. Matsumoto), 37 Rhodium Synthesis Reactions of (7°-diphenylacetylene) chromiumtricarbonyl complexes Insertion into the nickel—carbon bond of N—O chelated aryinickeKII) with polynuclear carbonyls. III. Reactions of M (CO),, (M = Rh, complexes. The development of single component catalysts for the Co) clusters with Cr(CO),(n°-PhCP,h) . Crystal and molecular oligomerisation of ethylene (S.Y. Desjardins, KJ. Cavell, H. Jin, structure of the Rh,(CO),( us,9?:7°-PhC,Ph)CKCO), cluster B.W. Skelton and A.H. White), 233 (S.P. Tunik, P.N. Shipil’, A.V. Vlasov, V.R. Denisov, A.B. Synthesis, reactivity and X-ray molecular structure of the activated Nikols’kii, F.M. Dolgushin, A.I. Yanovsky and Yu.T. Struchkov), ester complex [(n°-C,H,COONS)CoCO),] (NS = N-succini- 11 midyl) (H. El Amouri, Y. Besace, J. Vaissermann and G. Jaouen), Reactions of the cationic bis(chelate)rhodium complex [RP 0), ]* 103 with SO,, CS, and O,/SO, (E. Lindner, B. Keppeler, H.A. Mayer and K. Gierling), 139 Thienylmercury(II) derivatives Ruthenium Metal polypyrazolylborates. X. Thienylmercury({II) derivatives: the A second solid-state isomer of [((PPh ,), NJ[Ru,C(CO), (C,H,)}: shift X-ray crystal structure of [(S-Me)Thien-2-ylJHg-( u-Pz), B(Pz), of the carbonyl and ally! positions on large cluster cores by (G. Gioia Lobbia, P. Cecchi, F. Giordano and C. Santini), 213 crystal-packing force (T. Chihara, K. Komori, H. Ogawa and Y. Thioimidophosphinic acids Wakatsuki), 27 Dichlorodiphenylantimony(V) derivatives of oxo- and thioimi- Pyrolysis of Ru ,( 4-dppmXCO),(PPh,): formation of novel Ru, and dodiphosphinic acids, containing novel inorganic SbO,P,N and Ru, clusters (M.I. Bruce, N.N. Zaitseva, B.W. Skelton and A.H. SbOSP,N rings: crystal and molecular structures of Ph,SbCI, White), 143 ((OPPh, XXPPh, )N](X = O, S)(C. Silvestru, R. Résler, I. Haiduc, Synthesis and characterization of areneruthenium(II) dialkyldithio- R.A. Toscano and D.B. Sowerby), 131 phosphate complexes: single crystal structure of [Ru{SSP(OEt),} Tin (n°-p-cymene,X) |P[PBPhh ,]( V.K. Jain and V.S. Jakkal), 81 Organomercury({II) and organotin(IV) compounds with nitrogen-con- Selenium taining substituents (P.-A. Bonnardel and R.V. Parish), 221 Titanium(II1) Synthesis, spectroscopic and structural characterisation of {(CO),Fe( u-CH,)Se}, and (CO), Fe,{ u-Se(CH,),Se} (n = 1, 2) Synthesis and structure of titanium(III) tweezer complexes with em- (P. Mathur, Bala. Manimaran, R. Trivedi, M. Hossain and M. bedded alkali metal ions: [(m°-C,HMe,),Ti(m'-C=C- Arabatti), 155 SiMe,),]” M* (M = Li, Na, K, and Cs) (V. Varga, J. Hiller, M. Si PolaSek, U. Thewalt and K. Mach), 57 Hydride derivatives of Group 4 metals with the ansa-(SiMe,),(n°- Titanium tweezer C,H), ligand (T. Cuenca, M. Galakhov, E. Royo and P. Royo), Synthesis and structure of titanium(III) tweezer complexes with em- bedded alkali metal ions: [(m°-C,HMe,),Ti(n'-C#C- 33 Silicon SiMe,),]” M* (M = Li, Na, K, and Cs) (V. Varga, J. Hiller, M. PoléSek, U. Thewalt and K. Mach), 57 Selective synthesis of triphenoxysilane by the reaction of metallic silicon with phenol using copper(I) chloride as the catalyst (M. Trimethylsilylethynyl arms Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 Synthesis and structure of titanium(III) tweezer complexes with em- Superlattice structure of octa-tert-butylpentacyclol4.2.0.07°.0°*.0*’] bedded alkali metal ions: [(m°-C,HMe,),Ti(n'-C=C- SiMe,),]” M* (M = Li, Na, K, and Cs) (V. Varga, J. Hiller, M. octasilane found by reinvestigation of X-ray structure analysis (K. PolaSek, U. Thewalt and K. Mach), 57 Furukawa, M. Fujino and N. Matsumoto), 37 Silylcyclopentadienyls Trimethyltin chloride Hydride derivatives of Group 4 metals with the ansa-(SiMe,),(n°- Tin(IV) and organotin(IV) complexes containing mono or bidentate C.H,), ligand (T. Cuenca, M. Galakhov, E. Royo and P. Royo), N-donor ligands. II. 4-Phenylimidazole derivatives. Crystal and 33 molecular structure of [bis(4-phenylimidazole) trimethyltin(IV)] chloride (C. Pettinari, F. Marchetti, M. Pellei, A. Cingolani, L. Sn Tin(IV) and organotin(IV) complexes containing mono or bidentate Barba and A. Cassetta), 119 N-donor ligands. II. 4-Phenylimidazole derivatives. Crystal and Triphenoxysilane molecular structure of [bis(4-phenylimidazole) trimethyltin(IV)] Selective synthesis of triphenoxysilane by the reaction of metallic chloride (C. Pettinari, F. Marchetti, M. Pellei, A. Cingolani, L. silicon with phenol using copper(I) chloride as the catalyst (M. Barba and A. Cassetta), 119 Okamoto, N. Watanabe, E. Suzuki and Y. Ono), 51 Sulfoxide Tungsten Alkyl- and aryl-sulphinylmethylger compounds Ph,GeCH, Mixed-metal cluster chemistry III. P—C activation at tungsten—ti- S(O)R: structure of Ph, GeCH ,S(O)C,,'B Hu- p (J.L. Wardell and iridium cores; X-ray crystal structures of [CpWir,{ u,-7?-PPh (C,H4)K u-CO),(CO),}] and [CpWir,{ w,-7?-PPh(C,H,) u- PJ. Cox), 253 CO),(CO),(PPh,)] (S.M. Waterman, V.-A. Tolhurst, M.G. Sulfur dioxide ™ Humphrey, B.W. Skelton and A.H. White), 89 Reactions of the cationic bis(chelate)rhodium complex [Rh(P O),]* with SO,, CS, and O,/SO, (E. Lindner, B. Keppeler, H.A. Mayer and K. Gierling), 139 X-ray diffraction Sulphinylmethyl derivatives Synthesis, spectroscopic and structural characterisation of Alkyl- and aryl-sulphinylmethylgermanium compounds Ph,GeCH, {(CO),Fe( x-CH,)Se}, and (CO), Fe,{ u-Se(C)H,,,S e} (nm = 1, 2) S(O)R: structure of Ph,GeCH,S(O)C,HB,u'- p (J.L. Wardell and (P. Mathur, Bala. Manimaran, R. Trivedi, M. Hossain and M. PJ. Cox), 253 Arabatti), 155 Subject Index of Volume 515 269 X-ray structure Tin{IV) and organotin(IV) complexes containing mono or bidentate Hydrocarbon bridged metal complexes. XXXIV. Synthesis, structure N-donor ligands. Il. 4-Phenylimidazole derivatives. Crystal and and attempted decarbonylation of a trans 11,12-bis(dicarbonyl- molecular structure of [bis(4-phenylimidazole) trimethyitin(IV)] cyclopentadienylironacyl) substituted dihydro 9,10-ethanoanthra- chloride (C. Pettinari, F. Marchetti, M. Pellei, A. Cingolani, L. cene (V. Weinrich, A. Geisbaver, K. Sinkel and W. Beck), 173 Barba and A. Cassetta), 119 Metal polypyrazolylborates. X. Thienylmercury(II) derivatives: the X-ray crystal structure of [(5-Me)Thien-2-yiJHg-( u-Pz), B(Pz), (G. Gioia Lobbia, P. Cecchi, F. Giordano and C. Santini), 213 Zirconocene Synthesis and structure of titanium(III) tweezer complexes with em- Dinuclear phosphido- and arsenido-bridged early /late transition metal bedded alkali metal ions: [(m°-C,HMe,),Ti(n'-C=C- complexes. Efficient catalysts for ethylene polymerization (F. SiMe,),}” M* (M = Li, Na, K, and Cs) (V. Varga, J. Hiller, M. Lindenberg, T. Shribman, J. Sieler, E. Hey-Hawkins and M.S. PoléSek, U. Thewalt and K. Mach), 57 Eisen), 19 Synthesis, reactivity and X-ray molecular structure of the activated Zr ester complex [(n°-C,H,COONS)CoACO),] (NS = N-succini- Hydride derivatives of Group 4 metals with the ansa(SiMe,),(°- midy!) (H. El Amouri, Y. Besace, J. Vaissermann and G. Jaouen), C.H,), ligand (T. Cuenca, M. Galakhov, E. Royo and P. Royo), 103 33