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t ana \; iSsy .Pe ournal wy raa re me p ofOrgano. ~ > 4 ; ¥ Ji metallic Ri) «t IA}¥ Chemistry gt BATH 45 LSEVIER Journal of Organometallic Chemistry 492 (1995) C23-—C24 Author Index of Volume 492 Abrahams, I., 99 Grobelny, Z., 111 Mitchell, T.N., 191 Abram, U., 217 Gusel’nikov, L.E., C4 Moraal, M.A., 165 Acum, G.A., 65 Mortl, M., 115 Agarwala, R., 135 Habel, W., 225 Motevalli, M., 99 Alberto, R., 217 Haeusler, W., 225 Alcalde, M.I., 151 Halbritter, G., 87 Nesa, L., 41 Apostolidis, C., 199 Hanké6, K., 235 Nieuwenhuis, H.A., 165 Ariza-Castolo, A., 1 Hardcastle, K.I., 41, 135 Nuber, B., 199 Artus, G., 217 Herberhold, M., 59 Azam, K.A., 135 Herrmann, W.A., 217 Oskam, A., 165 Housecroft, C.E., 211 Ostrander, R.L., 211 Blake, A.J., C17 Hsu, S.C.N., 121 Blau, S., 81 Hursthouse, M.B., 135 Paz-Sandoval, M.A., 1 Bocskei, Zs., 115 Hutton, A.T., C14 Pazos-Mayen, C., 1 Bonifaci, C., 35 Pérez-Martinez, J.A., 23 Buckwalter, B.L., 129 Iglesias, M., 11 Plenio, H., 73 Butler, I.R., 157 Joachim, J.E., 199 Raithby, P.R., 65 Carmona, A., 11 Johnson, B.F.G., C17 Raptis, K., 199 Ceccon, A., 35 Jurkschat, K., 145 Rebizant, J., 199 Cerrada, E., 105 Chang, B.-H., 31 Renouard, C., 179 Chiang, M.Y., 121 Kabir, S.E., 41, 135 Rettig, S.J., 157 Contreras, R., 1 Kaden, T.A., 217 Rheingold, A.L., 211 Kanellakopulos, B., 199 Rheinwald, G., 81 Corma, A., 11 Cullen, W.R., 157 Kisch, H., 87 Riera, V., 23 Knausz, D., 115 Rosenberg, E., 41, 135 Dakternieks, D., 145 Knoch, F., 87 Royo, P., 151 Kolos, Zs., 115 Deeming, A.J., 41 Kowalczuk, M., 111 De Jesiis Rosales-Hoz, M., 1 Sanchez, F., 11, 151 Kwetkat, K., 191 De la Mata, J., 151 San José, A., 11 Dilshad, R., 135 Santi, S., 35 Diodone, R., 73 Laguna, A., 105 Sartori, P., 225 Dominguez-Duran, M.E., 1 Laguna, M., 105 Schaeffer, Jr., C.D., 129 Dorfler, U., 59 Lang, H., 81 Schibli, R., 217 Dyson, P.J., C17 Lappert, M.F., Cll Schmid, G., 185 Lavrukhin, B.D., C4 Schollmeyer, D., 145 Egli, A., 217 Lehman, M.F., 129 Schubiger, P.A., 217 Leigh, G.J., C8 Schutz, M., 185 Fawzi, R., Cl Lewis, A., 229 Scott, F.P.A., Cll Ferguson, G., 229 L6épez, E.M., 23 Shah, S.A.A., 99 Fernandez, E.J., 105 Luker, T., 53 Shahiduzzaman, M., 135 Smith, W.D., 129 Galsworthy, J.R., 211 Malik, K.M.A., 135 Sohar, P., 115 Gambaro, A., 35 Martin, C.M., C17 Solan, G.A., 65 Ganis, P., 35 Mayer, H.A., Cl Steimann, M., Cl Garcia-Granda, S., 23 Mays, M.J., 65 Stoeckli-Evans, H., 179 GieBelmann, F., 191 Meyer, D., 199 Stolarzewicz, A., 111 Gimeno, M.C., 105 Miah, A., 41 StoBel, P., Cl Glidewell, C., 229 Miah, R., 135 Stufkens, D.J., 165 Gomez, M., 151 Miguel, D., 23 Sullivan, A.C., 99 Goubitz, K., 165 Milius, W., 59 Sullivan, K.J., 129 C24 Author Index of Volume 492 Siiss-Fink, G., 179 Valle, G., 35 Whitby, R.J., 53 Szakacs, L., 115 Van Loon, A., 165 White, A.S.C., 157 Szepes, L., 235 Vass, G., 235 Wrackmeyer, B., 59 Szymanska-Buzar, T., 241 Venzo, A., 35 Wu, H., 145 Villacampa, M.D., 105 Yeh, W.-Y., 121 Terroba, R., 105 Volkova, V.V., C4 Yoder, C.H., 129 Uddin, K., 41 Webster, M., 53 Zakaria, C.M., 229 Ujszaszy, K., 115 Wewers, F.P., C14 Ziegler, M.L., 199 ond gar metallic Chemistry Aa Ss Journal of Organometallic Chemistry 492 (1995) C25—C32 Subject Index of Volume 492 Acetal Aryl A facile synthesis of acetals and aldehydes from allylic ethers Intramolecular rearrangements of silenes II. Synthesis of 1- catalyzed by cobalt compounds (B.-H. Chang), 31 methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- Acyl 1-silacyclobutane via [4 > 2 + 2]thermocyclodecomposition — The synthesis, characterisation and crystal structure of [Ru,(y>- transient silene rearrangement sequence. Novel 1,4-hydrogen H\(CO)3o-0( : @: n?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. shift from aryl carbon to sp? silicon of the silicon—carbon Johnson and C.M. Martin), C17 double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Aldehyde Lavrukhin), C4 A facile synthesis of acetals and aldehydes from allylic ethers Asymmetric hydrogenation catalyzed by cobalt compounds (B.-H. Chang), 31 Synthesis and characterization of new chiral Rh(1) complexes Alkenyl with N,N’-, and N,P-ligands. A study of anchoring on the Bridging alkenyl species from the protonation of ditungsten, modified zeolites and catalytic properties of heterogenized tungsten—molybdenum and dimolybdenum transverse alkyne complexes (A. Carmona, A. Corma, M. Iglesias, A. San José complexes with HCl and CF,;COOH. Crystal structure of and F. Sanchez), 11 [WMoCl{u-( E)-HC=CHPh\(CO),(n°-C;H;),] (G.A. Acum, Asymmetric hydroxylilation M.J. Mays, P.R. Raithby and G.A. Solan), 65 Synthesis and characterization of new chiral Rh({I) complexes Alkyne with N,N’-, and N,P-ligands. A study of anchoring on the Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- modified zeolites and catalytic properties of heterogenized stilbenylJazobenzole und 2,3-Dihydrocinnoline durch complexes (A. Carmona, A. Corma, M. Iglesias, A. San José cobaltkatalysierte, zweifache Addition von Tolan an Azoben- and F. Sanchez), 11 zolderivate (G. Halbritter, F. Knoch und H. Kisch), 87 1,2-Azaborolyl complexes Alkynes 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schitz), at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), 185 185 Allyl Bis(diphenylphosphino)methane A facile synthesis of acetals and aldehydes from allylic ethers Organomercuration of the carbanion derived from [M(CO),- catalyzed by cobalt compounds (B.-H. Chang), 31 (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular Allyl—vinyl ether rearrangement structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Rearrangements of silyl- and stannyl-substituted diallyl ethers: and F.P. Wewers), C14 competition between the allyl-vinyl ether rearrangement and Boron the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. 1,3-Dibora-[3]ferrocenophanes; synthesis and characterization (M. GieBelmann and K. Kwetkat), 191 Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 Amide A multinuclear NMR study of N-(chlorodimethylsilylmethyl) amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Carbanions Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Organomercuration of the carbanion derived from [M(CO),- Amine (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular Insertion of phenyl azide and diphenyldiazomethane into structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of and F.P. Wewers), C14 an 18-electron alkyl zirconocene triazenido complex (T. Luker, Carbon-13 R.J. Whitby and M. Webster), 53 A multinuciear NMR study of N-(chlorodimethylsilylmethyl) Aminocarbene fragments amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Dérivés cycliques de l’acide carbonimidodithioique en tant que Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 source de carbéne: fragmentation de ces ligands lors de leur Carbonyl coordination 4 un complexe trinucléaire de ruthénium (C. Methylene chain length and coordination geometry in triosmium Renouard, H. Stoeckli-Evans et G. Siiss-Fink), 179 clusters containing diphosphine ligands. X-Ray crystal struc- Arene tures of [Os,(CO),.{u-Ph,P(CPHP)h ,,},K n =4 or 5) and Arene-transition metal complexes as precursors of hard coatings [Os (CO) .{u-Ph,PCH,PPh,},](S.E. Kabir, A. Miah, L. Nesa, prepared by the chemical vapour deposition technique (K. K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Hank6, G. Vass and L. Szepes), 235 4] C26 Subject Index of Volume 492 Organomercuration of the carbanion derived from [M(CO),- A facile synthesis of acetals and aldehydes from allylic ethers (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular catalyzed by cobalt compounds (B.-H. Chang), 31 structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- and F.P. Wewers), C14 carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. Preparation and characterization of the square-based pyramidal Rheinwald), 81 cluster anion [H,Ru,(CO),4(44-COH)] (J.R. Galsworthy, C.E. Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- Housecroft, R.L. Ostrander and A.L. Rheingold), 211 stilbenyl)azobenzole und 2,3-Dihydrocinnoline durch cobalt- The synthesis, characterisation and crystal structure of [Ru,(u>- katalysierte, zweifache Addition von Tolan an Azobenzol- HXCO),( 3-0: : 1?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. derivate (G. Halbritter, F. Knoch und H. Kisch), 87 Johnson and C.M. Martin), C17 Copper Carbonylation Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- A facile synthesis of acetals and aldehydes from allylic ethers carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. catalyzed by cobalt compounds (B.-H. Chang), 31 Rheinwald), 81 Carbonyls Co-substitution Photochemical reaction of W(CO), with SnCl,. III. Synthesis Metallorganische Chemie des Technetiums XII. Photolytische of some novel seven-coordinate tungsten(II) complexes CO-Substitutionsreaktionen von Technetiumtricarbonylver- [WCKSnCl,XCO),L,] (L=N- and P-donor ligands) (T. Szy- bindungen. Synthesen und R6ntgenstrukturanalysen von manska-Buzar), 241 (C5H;)Tc(CO),(PPh), (C;Me,;)Tc(CO),(PPh,) und [HB(G,5- Synthesis and characterization of tetracarbonyl complexes of Me,Pz);Tc(CO),[P(OMe);] im Vergleich mit seinen Homolo- molybdenum and tungsten with functionalized imines. Crystal gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. structure of cis-Mo(CO),[(CH;(C,H;)C=N(CH,)], (M.A. Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. 199 Ariza-Castolo, M. De Jestis Rosales-Hoz and R. Contreras), 1 Crown ethers Chelates The unusual outcome of the reaction of potassium anions with Methylene chain length and coordination geometry in triosmium phenyl glycidyl ether (A. Stolarzewicz, Z. Grobelny and M. clusters containing diphosphine ligands. X-Ray crystal struc- Kowalczuk), 111 tures of [Os,(CO),.{u-Ph,P(CH,),,PPh,}K=n4 or 5) and Cryptands [Os (CO)x{uPC-H P,PhPh,,}, ] (S.E. Kabir, A. Miah, L. Nesa, Metal complexes of ferrocene cryptands (H. Plenio and R. K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Diodone), 73 41 Crystal structure Chirality Bridging alkenyl species from the protonation of ditungsten, The one-step synthesis of chiral amino phosphino ferrocenes tungsten—molybdenum and dimolybdenum transverse alkyne (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 complexes with HCl and CF,COOH. Crystal structure of Chromium [WMoCl{u-( E)-HC=CHPhKCO),(7°-C;H;).] (G.A. Acum, Arene-transition metal complexes as precursors of hard coatings M.J. Mays, P.R. Raithby and G.A. Solan), 65 prepared by the chemical vapour deposition technique (K. Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenyl- Hank6, G. Vass and L. Szepes), 235 methanol) with nitrogenous bases: crystal and molecular Heterobimetallic indenyl complexes. Synthesis and structure of structure of the 2:1 adduct with hexamethylenetetramine (G. syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), Insertion of phenyl azide and diphenyldiazomethane into 35 bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of Organomercuration of the carbanion derived from [M(CO),- an 18-electron alkyl zirconocene triazenido complex (T. Luker, (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular R.J. Whitby and M. Webster), 53 structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation and F.P. Wewers), C14 and thermal reactions (M. MOrtl, D. Knausz, Zs. Bocskei, Zs. Cluster Kolos, K. Ujszaszy, L. Szakacs and P. Sohar), 115 Preparation and characterization of the square-based pyramidal Preparation and characterization of the square-based pyramidal cluster anion [H,Ru,(CO),4(44-COH)] (J.R. Galsworthy, C.E. cluster anion [H,Ru,(CO),4(44-COH)] (J.R. Galsworthy, C.E. Housecroft, R.L. Ostrander and A.L. Rheingold), 211 Housecroft, R.L. Ostrander and A.L. Rheingold), 211 Triosmium and triruthenium clusters containing diazaheterocy- Synthesis and crystal structures of the cyclosiloxytin(IV) com- cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. plexes [Cl,Sn{O(SiPh,O),},]-u-(Li(THF),),] and Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, [THF,Sn{(OSiPh,),O},]- toluene (I. Abrahams, M. Mote- M.B. Hursthouse and K.M.A. Malik), 135 valli, S.A.A. Shah and A.C. Sullivan), 99 Clusters Synthesis and X-ray molecular structure of cis,cis-1,3,5-Tris- Methylene chain length and coordination geometry in triosmium (diphenylphosphino)-1,3,5-tris(methoxycarbonyl)cyclohexane clusters containing diphosphine ligands. X-Ray crystal struc- (H.A. Mayer, P. St6Bel, R. Fawzi and M. Steimann), Cl tures of [Os,(CO),o{u-Ph,P(CH,),,PPh,}Kn =4 or 5) and Synthesis, NMR _ studies and molecular structures of [Os (CO).{u-PCPH h, ,PPh5},] (S.E. Kabir, A. Miah, L. Nesa, ((PhSSn),(,C);H] , and [PhSn(S,CNEt,)],(SMCH,), (D. Dak- K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 41 The one-step synthesis of chiral amino phosphino ferrocenes Cobalt (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes The synthesis, characterisation and crystal structure of [Ru,(y>- at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), HXCO),.3(- 0 : 7 : 7?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. 185 Johnson and C.M. Martin), C17 Subject Index of Volume 492 Cyclodimerization Ferrocene 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenyl- at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), methanol) with nitrogenous bases: crystal and molecular 185 structure of the 2:1 adduct with hexamethylenetetramine (G. Cyclopropanation Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Synthesis and characterization of new chiral Rh(1) complexes Metal complexes of ferrocene cryptands (H. Plenio and R. with N,N’-, and N,P-ligands. A study of anchoring on the Diodone), 73 modified zeolites and catalytic properties of heterogenized The one-step synthesis of chiral amino phosphino ferrocenes complexes (A. Carmona, A. Corma, M. Iglesias, A. San José (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 and F. Sanchez), 11 Cyclotrimerization Gold 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes Synthesis of dithiolate gold(III) complexes by dithiolate transfer at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), reactions. X-ray structure of [Au(C,F;XS,C,H,\PPh,)] (E. 185 Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- guna, R. Terroba and M.D. Villacampa), 105 Diazenes Group 1 Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- Metal complexes of ferrocene cryptands (H. Plenio and R. stilbenyl)azobenzole und 2,3-Dihydrocinnoline durch cobalt- Diodone), 73 katalysierte, zweifache Addition von Tolan an Azoben- Group 2 zolderivate (G. Halbritter, F. Knoch und H. Kisch), 87 Metal complexes of ferrocene cryptands (H. Plenio and R. Diazine Diodone), 73 Triosmium and triruthenium clusters containing diazaheterocy- Group 4 cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. Insertion of phenyl azide and diphenyldiazomethane into Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of M.B. Hursthouse and K.M.A. Malik), 135 an 18-electron alkyl zirconocene triazenido complex (T. Luker, Diboraferrocenophanes R.J. Whitby and M. Webster), 53 1,3-Dibora-(3}ferrocenophanes; synthesis and characterization (M. Group 14 Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 A multinuclear NMR study of N-(chlorodimethylsilylmethyl) Diimines amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Photochemistry of the metal—metal-bonded complexes [(CO),- Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Mn-—Ru(MeXCO),(a-diimine)]. Crystal structure of the pho- toproduct [(CO),Mn-n-(o(N),o(N’),n7(PCr-NP)yC-a')- Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. Hafnium Moraal, D.J. Stufkens, A. Oskam and K. Goubitz), 165 Arene-transition metal complexes as precursors of hard coatings Diorganotin sulphides prepared by the chemical vapour deposition technique (K. Synthesis, NMR _ studies and molecular structures of Hank6o, G. Vass and L. Szepes), 235 [(PhSSn),(CH)3], and [PhSn(S,CNEt,)],(SMC,H) , (D. Dak- Half-sandwich cpds ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 Half-sandwich isocyanide, phosphine, methyl and phosphanido Diphosphines pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- Methylene chain length and coordination geometry in triosmium calde, J. De la Mata, M. Gémez, P. Royo and F. Sanchez), clusters containing diphosphine ligands. X-Ray crystal struc- 151 tures of [Os,(CO),.{u-Ph,P(CH,),,PPh,}K=n4 or 5) and Heterocycles [Os (CO),{u-Ph,PCH ,PPh,},](S.E. Kabir, A. Miah, L. Nesa, Triosmium and triruthenium clusters containing diazaheterocy- K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. 41 Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, Dithiolate complexes M.B. Hursthouse and K.M.A. Malik), 135 Synthesis of dithiolate gold(III) complexes by dithiolate transfer Host—guest adducts reactions. X-ray structure of [Au(C,F;XS,C,H,PPh,)] (E. Hydrogen-bonded adducts of ferrocene-1,1’-diylbis(diphenyl- Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- methanol) with nitrogenous bases: crystal and molecular guna, R. Terroba and M.D. Villacampa), 105 structure of the 2:1 adduct with hexamethylenetetramine (G. Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Early transition metals 1,4-H shift Insertion of phenyl azide and diphenyldiazomethane into Intramolecular rearrangements of silenes II. Synthesis of 1- bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- an 18-electron alkyl zirconocene triazenido complex (T. Luker, l-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — R.J. Whitby and M. Webster), 53 transient silene rearrangement sequence. Novel 1,4-hydrogen ESR spectroscopy shift from aryl carbon to sp? silicon of the silicon-—carbon Photochemistry of the metal—-metal-bonded complexes [(CO),- double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the Lavrukhin), C4 photoproduct [(CO),Mn-u-(o(N),o(N’),n7(PCr-NP)yC-a') - Hydride Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. The synthesis, characterisation and crystal structure of [Ru,(y>- Moraal, D.J. Stufkens, A. Oskam and K. Goubitz), 165 HXCO).3(- 0 : o : n?~COPh)] (A.J. Blake, P.J. Dyson, B.F.G. Ether Johnson and C.M. Martin), C17 A facile synthesis of acetals and aldehydes from allylic ethers Triosmium and triruthenium clusters containing diazaheterocy- catalyzed by cobalt compounds (B.-H. Chang), 31 cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. C28 Subject Index of Volume 492 Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, X-Ray structure of [MnMo(SnPh,\CO),(u-tedip(y- M.B. Hursthouse and K.M.A. Malik), 135 S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. Hydrogen bonding Riera and S. Garcia-Granda), 23 Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenyl- Mass spectrometry methanol) with nitrogenous bases: crystal and molecular Arene-transition metal complexes as precursors of hard coatings structure of the 2:1 adduct with hexamethylenetetramine (G. prepared by the chemical vapour deposition technique (K. Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Hank6, G. Vass and L. Szepes), 235 Hydrosilylation Mass spectroscopy The reaction pathway from Speier’s to Karstedt’s hydrosilylation New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation catalyst (M.F. Lappert and F.P.A. Scott), C11 and thermal reactions (M. MOrtl, D. Knausz, Zs. Bécskei, Zs. Kolos, K. Ujszaszy, L. Szakacs and P. Sohar), 115 Imines Metal Carbonyls Synthesis and characterization of tetracarbonyl complexes of Metal carbonyl syntheses. XXII. Low-pressure carbonylation of molybdenum and tungsten with functionalized imines. Crystal [MOCI,]~ and [MO,]~. The technetium(]) and rhenium(1) structure of cis-Mo(CO),[(CH;4C,H;)C=N(CH,)], (M.A. complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram Ariza-Castolo, M. De Jest Rosales-Hoz and R. Contreras), 1 and T.A. Kaden), 217 Indenyl Metallacycle Heterobimetallic indenyl complexes. Synthesis and structure of Insertion of phenyl azide and diphenyldiazomethane into syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), an 18-electron alkyl zirconocene triazenido complex (T. Luker, 35 R.J. Whitby and M. Webster), 53 Iron Metallasiloxanes 1,3-Dibora-[3 }ferrocenophanes; synthesis and characterization (M. Synthesis and crystal structures of the cyclosiloxytin(IV) com- Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 plexes [Cl,Sn{O(SiPh,O),}, ]-u-(Li(THF),),] and [THF,- Hydrogen-bonded adducts of ferrocene-1,1’-diylbis(diphenyl- Sn{(OSiPh,),O0},] + toluene (I. Abrahams, M. Motevalli, methanol) with nitrogenous bases: crystal and molecular S.A.A. Shah and A.C. Sullivan), 99 structure of the 2:1 adduct with hexamethylenetetramine (G. Metal-—metal bonding Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Photochemistry of the metal—metal-bonded complexes [(CO),- The one-step synthesis of chiral amino phosphino ferrocenes Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 photoproduct [(CO),Mn-yn-(o(N),o(N’),n2(PCr-NP)yC-a')- Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. Moraal, D.J. Stufkens, A.O skam and K. Goubitz), 165 Rheinwald), 81 Methylene Isocyanide Methylene chain length and coordination geometry in triosmium Half-sandwich isocyanide, phosphine, methyl and phosphanido clusters containing diphosphine ligands. X-Ray crystal struc- pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- tures of [Os,(CO),9{u-Ph,P(CPHP)h,,},K n =4 or 5) and calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), [Os (CO) .{u-PPCHh ,, PPh,},](S.E. Kabir, A. Miah, L. Nesa, 151 K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Isomerism 41 Synthesis, NMR _ studies and molecular structures of MOCVD ((PhSSn),(CH ,)3], and [PhSn(S,CNEt, )],(SXCH ,), (D. Dak- Arene-transition metal complexes as precursors of hard coatings ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 prepared by the chemical vapour deposition technique (K. Hank6, G. Vass and L. Szepes), 235 Lithium Molybdenum Synthesis and crystal structures of the cyclosiloxytin(IV) com- Bridging alkenyl species from the protonation of ditungsten, plexes [Cl,Sn{O(SiPh,O),},]-u-(Li(THF),),] and [THF,- tungsten—molybdenum and dimolybdenum transverse alkyne Sn{(OSiPh,),O},]- toluene (I. Abrahams, M. Motevalli, complexes with HC] and CF,;COQH. Crystal structure of S.A.A. Shah and A.C. Sullivan), 99 [WMoCK{u-( E)-HC=CHPhK(CO),(7°-C;H5),] (G.A. Acum, Low-pressure Carbonylation M.J. Mays, P.R. Raithby and G.A. Solan), 65 Metal carbonyl syntheses. XXII. Low-pressure carbonylation of Organomercuration of the carbanion derived from [M(CO),- [MOCI,]~ and [MO,]~. The technetium(I) and rhenium(1) (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram and F.P. Wewers), C14 and T.A. Kaden), 217 Reduction reactions of binuclear manganese—molybdenum com- plexes containing S,CPR, and bidentate P-donor bridges. Manganese X-Ray structure of [MnMo(SnPh,\CO),(y-tedip(u- Photochemistry of the metal—metal-bonded complexes [(CO),- S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. Mn-Ru(MeXCO),(a-diimine)]. Crystal structure of the Riera and S. Garcia-Granda), 23 photoproduct [(CO),Mn-u-(o(N),o(N’),77(PCr-NP)yC-a')- Synthesis and characterization of tetracarbonyl complexes of Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. molybdenum and tungsten with functionalized imines. Crystal Moraal, D.J. Stufkens, A.O skam and K. Goubitz), 165 structure of cis-Mo(CO),[(CH;XC,H;)C=N(CH,)], (M.A. Reduction reactions of binuclear manganese—molybdenum com- Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. plexes containing S,CPR, and bidentate P-donor bridges. Ariza-Castolo, M. De Jesis Rosales-Hoz and R. Contreras), 1 Subject Index of Volume 492 Synthesis and X-ray molecular structure of cis,cis-1,3,5-Tris- Photochemistry (diphenylphosphino)-1,3,5-tris(methoxycarbonyl)cyclohexane Photochemistry of the metal—metal-bonded complexes [(CO).- (H.A. Mayer, P. St6Bel, R. Fawzi and M. Steimann), Cl Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the photoproduct [(CO),Mn-p-(a(N),o(N’),72(PCr-NP)yC-a') - Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. Niobium Moraal, D.J. Stufkens, A. Oskam and K. Goubitz), 165 Half-sandwich isocyanide, phosphine, methyl and phosphanido Photochlorination pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 151 Photolysis Nitrene Metallorganische Chemie des Technetiums XII. Photolytische New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation CO-Substitutionsreaktionen von Technetiumtricarbonylver- and thermal reactions (M. MOrtl, D. Knausz, Zs. Bécskei, Zs. bindungen. Synthesen und R6ntgenstrukturanalysen von Kolos, K. Ujszdszy, L. Szakacs and P. Sohar), 115 (C;H;)Tce(CO)(PPh;), (C;Me;)Tc(CO),(PPh;) und [HB(3,5- Nitrogen Me,Pz);Tc(CO),[P(OMe),] im Vergleich mit seinen Homolo- Triosmium and triruthenium clusters containing diazaheterocy- gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, 199 M.B. Hursthouse and K.M.A. Malik), 135 Platinum NMR The reaction pathway from Speier’s to Karstedt’s hydrosilylation A multinuclear NMR study of N-(chlorodimethylsilylmethyl) catalyst (M.F. Lappert and F.P.A. Scott), C11 amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Poly(carbosilanes) Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- NMR, multinuclear kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 1,3-Dibora-[3]ferrocenophanes; synthesis and characterization (M. Poly(dialkylsilylene co-alkylenes) Herberhold, U. Doérfler, W. Milius and B. Wrackmeyer), 59 Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 Osmium Potassium anions Methylene chain length and coordination geometry in triosmium The unusual outcome of the reaction of potassium anions with clusters containing diphosphine ligands. X-Ray crystal struc- phenyl glycidyl ether (A. Stolarzewicz, Z. Grobelny and M. tures of [Os,(CO),o{u-Ph,P(CH),,PPh,}Kn =4 or 5) and Kowalczuk), 111 [Os (CO),{uPC-H P,PhPh,,}, ](S.E. Kabir, A. Miah, L. Nesa, Protonation K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Bridging alkenyl species from the protonation of ditungsten, 41 tungsten—molybdenum and dimolybdenum transverse alkyne Triosmium and triruthenium clusters containing diazaheterocy- complexes with HCl and CF,COOH. Crystal structure of [WMoCl{u-( E)-HC=CHPh\(CO),(?-C;H;),] (G.A. Acum, cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, M.J. Mays, P.R. Raithby and G.A. Solan), 65 M.B. Hursthouse and K.M.A. Malik), 135 Oxiranes The unusual outcome of the reaction of potassium anions with phenyl glycidyl ether (A. Stolarzewicz, Z. Grobelny and M. Rearrangement Kowalczuk), 111 Intramolecular rearrangements of silenes II. Synthesis of 1- methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- Palladium l-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — The one-step synthesis of chiral amino phosphino ferrocenes transient silene rearrangement sequence. Novel 1,4-hydrogen (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 shift from aryl carbon to sp? silicon of the silicon—carbon Pentamethylcyclopentadienyl double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Half-sandwich isocyanide, phosphine, methyl and phosphanido Lavrukhin), C4 pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- Rhenium calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), Metal carbonyl syntheses. XXII. Low-pressure carbonylation of 151 {MOCI,]~ and [MO,]~. The technetium(]) and rhenium(1) Phosphanido complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Half-sandwich isocyanide, phosphine, methyl and phosphanido Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- and T.A. Kaden), 217 calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), Rhodium 151 Heterobimetallic indenyl complexes. Synthesis and structure of Phosphine syn-[Cr(CO).(,:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- Half-sandwich isocyanide, phosphine, methyl and phosphanido con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- 35 calde, J. De la Mata, M. G6mez, P. Royo and F. Sanchez), Synthesis and characterization of new chiral Rh(I) complexes 151 with N,N’-, and N,P-ligands. A study of anchoring on the Phosphorus modified zeolites and catalytic properties of heterogenized The one-step synthesis of chiral amino phosphino ferrocenes complexes (A. Carmona, A. Corma, M. Iglesias, A. San José (1.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 and F. Sanchez), 11 C30 Subject Index of Volume 492 Rotamers Synthesis and crystal structures of the cyclosiloxytin(IV) com- A multinuclear NMR study of N-(chlorodimethylsilylmethyl) plexes [Cl,Sn{O(SiPh,O),}, ]-u-(Li(THF),),] and [THF,- amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Sn{(OSiPh,),0},]- toluene (I. Abrahams, M. Motevalli, Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 S.A.A. Shah and A.C. Sullivan), 99 Ruthenium The reaction pathway from Speier’s to Karstedt’s hydrosilylation Dérivés cycliques de l’acide carbonimidodithioique en tant que catalyst (M.F. Lappert and F.P.A. Scott), C11 source de carbéne: fragmentation de ces ligands lors de leur °Si-NMR spectroscopy coordination 4 un complexe trinucléaire de ruthénium (C. Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- Renouard, H. Stoeckli-Evans et G. Siiss-Fink), 179 kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 Photochemistry of the metal—metal-bonded complexes [(CO),- Stannasiloxane Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the Synthesis and crystal structures of the cyclosiloxytin(IV) com- photoproduct [(CO),Mn-p-(o(N),o(N’),n7(PCr-NP)yC-a')- plexes [Cl,Sn{O(SiPh,O),},]-u-(Li(THF),),] and [THF,- Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. Sn{(OSiPh,),;0},]- toluene (I. Abrahams, M. Motevalli, Moraal, D.J. Stufkens, A.O skam and K. Goubitz), 165 S.A.A. Shah and A.C. Sullivan), 99 Preparation and characterization of the square-based pyramidal Stereochemistry cluster anion [H,Ru,(CO),4(4.4-COH)] (J.R. Galsworthy, C.E. Synthesis and characterization of tetracarbonyl complexes of Housecroft, R.L. Ostrander and A.L. Rheingold), 211 molybdenum and tungsten with functionalized imines. Crystal The synthesis, characterisation and crystal structure of [Ru,(u>- structure of cis-Mo(CO),[(CH;XC;H;)C=N(CH,)], (M.A. HCO) (3-0 : o : n?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. Johnson and C.M. Martin), C17 Ariza-Castolo, M. De Jesis Rosales-Hoz and R. Contreras), 1 Structure Metal carbonyl syntheses. XXII. Low-pressure carbonylation of [MOCI,]~ and [MO,]~. The technetium(]) and rhenium(I) Seven-coordinate complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Photochemical reaction of W(CO), with SnCl,. III. Synthesis Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram of some novel seven-coordinate tungsten(II) complexes and T.A. Kaden), 217 [WCKSnCl,4CO),L,] (L=N- and P-donor ligands) (T. Szy- Supported catalysts manska-Buzar), 241 Synthesis and characterization of new chiral Rh(I) complexes Silaacenaphthene with N,N’-, and N,P-ligands. A study of anchoring on the Intramolecular rearrangements of silenes II. Synthesis of 1- modified zeolites and catalytic properties of heterogenized methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- complexes (A. Carmona, A. Corma, M. Iglesias, A. San José 1-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — and F. Sanchez), 11 transient silene rearrangement sequence. Novel 1,4-hydrogen Syn and anti structures shift from aryl carbon to sp? silicon of the silicon—carbon Heterobimetallic indenyl complexes. Synthesis and structure of double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- Lavrukhin), C4 con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), Silacyclobutane 35 Intramolecular rearrangements of silenes II. Synthesis of 1- Synthesis methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- Half-sandwich isocyanide, phosphine, methyl and phosphanido 1-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- transient silene rearrangement sequence. Novel 1,4-hydrogen calde, J. De la Mata, M. Gémez, P. Royo and F. Sanchez), shift from aryl carbon to sp? silicon of the silicon—carbon 151 double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Synthesis of dithiolate gold(III) complexes by dithiolate transfer Lavrukhin), C4 reactions. X-ray structure of [Au(C,F;XS,C,;H,\PPh,)] (E. Silenes Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- Intramolecular rearrangements of silenes II. Synthesis of 1- guna, R. Terroba and M.D. Villacampa), 105 methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- 1-silacyclobutane via [4 —- 2 + 2]thermocyclodecomposition — transient silene rearrangement sequence. Novel 1,4-hydrogen shift from aryl carbon to sp? silicon of the silicon—carbon double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Technecium Lavrukhin), C4 Metallorganische Chemie des Technetiums XII. Photolytische Silicon CO-Substitutionsreaktionen von Technetiumtricarbonylver- A multinuclear NMR study of N-(chlorodimethylsilylmethyl) bindungen. Synthesen und Ro6ontgenstrukturanalysen von amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. (C5H;)Tc(CO)(PPh), (C;Me;)Tc(CO),(PPh,) und [HB(3,5- Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Me,Pz),;Tc(CO),[P(OMe),] im Vergleich mit seinen Homolo- New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. and thermal reactions (M. M6rtl, D. Knausz, Zs. Boécskei, Zs. Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), Kolos, K. Ujszdszy, L. Szakdcs and P. Soh4r), 115 199 Rearrangements of silyl- and stannyl-substituted diallyl ethers: Technetium competition between the allyl-vinyl ether rearrangement and Metal carbonyl syntheses. XXII. Low-pressure carbonylation of the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. [MOCI,]~ and [MO,]~. The technetium(]) and rhenium(I) GieBelmann and K. Kwetkat), 191 complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 and T.A. Kaden), 217 Subject Index of Volume 492 C31 Thermolysis Syntheses and characterization of tricarbonyl tungsten complexes Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- containing 1,1'-bis(diphenylphosphino)ferrocene ligand (S.C.N. carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. Hsu, W.-Y. Yeh and M.Y. Chiang), 121 Rheinwald), 81 Synthesis and characterization of tetracarbonyl complexes of Thiolate fragments molybdenum and tungsten with functionalized imines. Crystal Dérivés cycliques de l’acide carbonimidodithioique en tant que structure of cis-Mo(CO),[(CH;XC,H;)C=N(CH,)], (M.A. source de carbéne: fragmentation de ces ligands lors de leur Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. coordination 4 un complexe trinucléaire de ruthénium (C. Ariza-Castolo, M. De Jestis Rosales-Hoz and R. Contreras), 1 Renouard, H. Stoeckli-Evans et G. Siiss-Fink), 179 Tin Wittig rearrangement Photochemical reaction of W(CO), with SnCl,. III. Synthesis of Rearrangements of silyl- and stannyl-substituted diallyl ethers: some novel seven-coordinate tungsten(II) complexes competition between the allyl-vinyl ether rearrangement and [WCK(SnCl,4CO),L,] (L=N- and P-donor ligands) (T. Szy- the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. manska-Buzar), 241 GieBelmann and K. Kwetkat), 191 Rearrangements of silyl- and stannyl-substituted diallyl ethers: competition between the allyl-vinyl ether rearrangement and X-ray diffraction the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. 1,3-Dibora-(3]ferrocenophanes; synthesis and characterization (M. GieBelmann and K. Kwetkat), 191 Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 Synthesis and crystal structures of the cyclosiloxytin(IV) com- X-ray structure plexes [Cl,Sn{O(SiPh,O),}, ]-u-(Li(THF),),] and [THF,- Heterobimetallic indenyl complexes. Synthesis and structure of Sn{(OSiPh,),O},]- toluene (I. Abrahams, M. Motevalli, syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- S.A.A. Shah and A.C. Sullivan), 99 con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), Synthesis, NMR _ studies and molecular structures of 35 ((PhSSn),(C)3H] , and [PhSn(S,CNEt ,)],(SMCH,), (D. Dak- Metal complexes of ferrocene cryptands (H. Plenio and R. ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 Diodone), 73 Synthesis of dithiolate gold(III) complexes by dithiolate transfer Metallorganische Chemie des Technetiums XII. Photolytische reactions. X-ray structure of [Au(C,F;4S,C,H,\PPh,)] (E. CO-Substitutionsreaktionen von Technetiumtricarbonylver- Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- bindungen. Synthesen und Ro6ntgenstrukturanalysen von guna, R. Terroba and M.D. Villacampa), 105 (C3;H,)Tc(CO),(PPh), (C;Me;)Tc(CO),(PPh,) und [HB(3,5- Transition metal complexes Me,Pz);Tc(CO),[P(OMe),;] im Vergleich mit seinen Homolo- Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. stilbenyl)azobenzole und 2,3-Dihydrocinnoline durch cobalt- Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), katalysierte, zweifache Addition von Tolan an Azobenzol- 199 derivate (G. Halbritter, F. Knoch und H. Kisch), 87 Reduction reactions of binuclear manganese—molybdenum com- Trialkylphosphoniodithioformate bridges plexes containing S,CPR, and bidentate P-donor bridges. Reduction reactions of binuclear manganese—molybdenum com- X-Ray structure of [MnMo(SnPh,)CO),(y-tedipp- plexes containing S,CPR, and bidentate P-donor bridges. S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. X-Ray structure of [MnMo(SnPh,)CO),(y-tedipy- Riera and S. Garcia-Granda), 23 S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. Synthesis of dithiolate gold(III) complexes by dithiolate transfer Riera and S. Garcia-Granda), 23 reactions. X-ray structure of [Au(C,F;XS,C,H,PPh,)] (E. Trimethylsilyl Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation guna, R. Terroba and M.D. Villacampa), 105 and thermal reactions (M. M6rtl, D. Knausz, Zs. Bocskei, Zs. Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- Kolos, K. Ujsz4szy, L. Szakacs and P. Sohar), 115 stilbenylJazobenzole und 2,3-Dihydrocinnoline durch cobalt- Tripodal phosphine katalysierte, zweifache Addition von Tolan an Azobenzol- Synthesis and X-ray molecular structure of cis,cis-1,3,5-Tris- derivate (G. Halbritter, F. Knoch und H. Kisch), 87 (diphenylphosphino)-1,3,5-tris(methoxycarbonyl)cyclohexane (H.A. Mayer, P. St6Bel, R. Fawzi and M. Steimann), Cl Zeolites Tungsten Synthesis and characterization of new chiral Rh(1I) complexes Bridging alkenyl species from the protonation of ditungsten, with N,N’-, and N,P-ligands. A study of anchoring on the tungsten—molybdenum and dimolybdenum transverse alkyne modified zeolites and catalytic properties of heterogenized complexes with HCl and CF;COQOH. Crystal structure of complexes (A. Carmona, A. Corma, M. Iglesias, A. San José [WMoCK{u-( E)-HC=CHPh\(CO),(7°-C;H5),] (G.A. Acum, and F. Sanchez), 11 M.J. Mays, P.R. Raithby and G.A. Solan), 65 Zinc Organomercuration of the carbanion derived from [M(CO),- Synthesis of dithiolate gold(III) complexes by dithiolate transfer (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular reactions. X-ray structure of [Au(C,F;XS,C,H,PPh,)] (E. structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- and F.P. Wewers), C14 guna, R. Terroba and M.D. Villacampa), 105 Photochemical reaction of W(CO), with SnCl,. III. Synthesis Zirconium of some novel seven-coordinate tungsten(II) complexes Arene-transition metal complexes as precursors of hard coatings [WCK(SnCl,4CO),L,] (L=N- and P-donor ligands) (T. Szy- prepared by the chemical vapour deposition technique (K. manska-Buzar), 241 Hank6o, G. Vass and L. Szepes), 235 C32 Subject Index of Volume 492 Insertion of phenyl azide and diphenyldiazomethane into Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of edition, Rare Earth Elements, Volume 12b, Sc, Y, La-—Lu, an 18-electron alkyl zirconocene triazenido complex (T. Luker, Compounds with Carbon (G.J. Leigh), C20 R.J. Whitby and M. Webster), 53 Inorganic Chemistry, 2nd edition, D.F. Shriver, P.W. Atkins and C.H. Langford (G.J. Leigh), C21 Book reviews Progress in Inorganic Chemistry, Volume 42, K.D. Karlin (Ed.) Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th (G.J. Leigh), C21 edition, Molybdenum, Supplement Volume B9, Compounds with Se, Te, Po (G.J. Leigh), C20

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Journal of Organometallic Chemistry 1995: Vol 492 Index PDF

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t ana \; iSsy .Pe ournal wy raa re me p ofOrgano. ~ > 4 ; ¥ Ji metallic Ri) «t IA}¥ Chemistry gt BATH 45 LSEVIER Journal of Organometallic Chemistry 492 (1995) C23-—C24 Author Index of Volume 492 Abrahams, I., 99 Grobelny, Z., 111 Mitchell, T.N., 191 Abram, U., 217 Gusel’nikov, L.E., C4 Moraal, M.A., 165 Acum, G.A., 65 Mortl, M., 115 Agarwala, R., 135 Habel, W., 225 Motevalli, M., 99 Alberto, R., 217 Haeusler, W., 225 Alcalde, M.I., 151 Halbritter, G., 87 Nesa, L., 41 Apostolidis, C., 199 Hanké6, K., 235 Nieuwenhuis, H.A., 165 Ariza-Castolo, A., 1 Hardcastle, K.I., 41, 135 Nuber, B., 199 Artus, G., 217 Herberhold, M., 59 Azam, K.A., 135 Herrmann, W.A., 217 Oskam, A., 165 Housecroft, C.E., 211 Ostrander, R.L., 211 Blake, A.J., C17 Hsu, S.C.N., 121 Blau, S., 81 Hursthouse, M.B., 135 Paz-Sandoval, M.A., 1 Bocskei, Zs., 115 Hutton, A.T., C14 Pazos-Mayen, C., 1 Bonifaci, C., 35 Pérez-Martinez, J.A., 23 Buckwalter, B.L., 129 Iglesias, M., 11 Plenio, H., 73 Butler, I.R., 157 Joachim, J.E., 199 Raithby, P.R., 65 Carmona, A., 11 Johnson, B.F.G., C17 Raptis, K., 199 Ceccon, A., 35 Jurkschat, K., 145 Rebizant, J., 199 Cerrada, E., 105 Chang, B.-H., 31 Renouard, C., 179 Chiang, M.Y., 121 Kabir, S.E., 41, 135 Rettig, S.J., 157 Contreras, R., 1 Kaden, T.A., 217 Rheingold, A.L., 211 Kanellakopulos, B., 199 Rheinwald, G., 81 Corma, A., 11 Cullen, W.R., 157 Kisch, H., 87 Riera, V., 23 Knausz, D., 115 Rosenberg, E., 41, 135 Dakternieks, D., 145 Knoch, F., 87 Royo, P., 151 Kolos, Zs., 115 Deeming, A.J., 41 Kowalczuk, M., 111 De Jesiis Rosales-Hoz, M., 1 Sanchez, F., 11, 151 Kwetkat, K., 191 De la Mata, J., 151 San José, A., 11 Dilshad, R., 135 Santi, S., 35 Diodone, R., 73 Laguna, A., 105 Sartori, P., 225 Dominguez-Duran, M.E., 1 Laguna, M., 105 Schaeffer, Jr., C.D., 129 Dorfler, U., 59 Lang, H., 81 Schibli, R., 217 Dyson, P.J., C17 Lappert, M.F., Cll Schmid, G., 185 Lavrukhin, B.D., C4 Schollmeyer, D., 145 Egli, A., 217 Lehman, M.F., 129 Schubiger, P.A., 217 Leigh, G.J., C8 Schutz, M., 185 Fawzi, R., Cl Lewis, A., 229 Scott, F.P.A., Cll Ferguson, G., 229 L6épez, E.M., 23 Shah, S.A.A., 99 Fernandez, E.J., 105 Luker, T., 53 Shahiduzzaman, M., 135 Smith, W.D., 129 Galsworthy, J.R., 211 Malik, K.M.A., 135 Sohar, P., 115 Gambaro, A., 35 Martin, C.M., C17 Solan, G.A., 65 Ganis, P., 35 Mayer, H.A., Cl Steimann, M., Cl Garcia-Granda, S., 23 Mays, M.J., 65 Stoeckli-Evans, H., 179 GieBelmann, F., 191 Meyer, D., 199 Stolarzewicz, A., 111 Gimeno, M.C., 105 Miah, A., 41 StoBel, P., Cl Glidewell, C., 229 Miah, R., 135 Stufkens, D.J., 165 Gomez, M., 151 Miguel, D., 23 Sullivan, A.C., 99 Goubitz, K., 165 Milius, W., 59 Sullivan, K.J., 129 C24 Author Index of Volume 492 Siiss-Fink, G., 179 Valle, G., 35 Whitby, R.J., 53 Szakacs, L., 115 Van Loon, A., 165 White, A.S.C., 157 Szepes, L., 235 Vass, G., 235 Wrackmeyer, B., 59 Szymanska-Buzar, T., 241 Venzo, A., 35 Wu, H., 145 Villacampa, M.D., 105 Yeh, W.-Y., 121 Terroba, R., 105 Volkova, V.V., C4 Yoder, C.H., 129 Uddin, K., 41 Webster, M., 53 Zakaria, C.M., 229 Ujszaszy, K., 115 Wewers, F.P., C14 Ziegler, M.L., 199 ond gar metallic Chemistry Aa Ss Journal of Organometallic Chemistry 492 (1995) C25—C32 Subject Index of Volume 492 Acetal Aryl A facile synthesis of acetals and aldehydes from allylic ethers Intramolecular rearrangements of silenes II. Synthesis of 1- catalyzed by cobalt compounds (B.-H. Chang), 31 methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- Acyl 1-silacyclobutane via [4 > 2 + 2]thermocyclodecomposition — The synthesis, characterisation and crystal structure of [Ru,(y>- transient silene rearrangement sequence. Novel 1,4-hydrogen H\(CO)3o-0( : @: n?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. shift from aryl carbon to sp? silicon of the silicon—carbon Johnson and C.M. Martin), C17 double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Aldehyde Lavrukhin), C4 A facile synthesis of acetals and aldehydes from allylic ethers Asymmetric hydrogenation catalyzed by cobalt compounds (B.-H. Chang), 31 Synthesis and characterization of new chiral Rh(1) complexes Alkenyl with N,N’-, and N,P-ligands. A study of anchoring on the Bridging alkenyl species from the protonation of ditungsten, modified zeolites and catalytic properties of heterogenized tungsten—molybdenum and dimolybdenum transverse alkyne complexes (A. Carmona, A. Corma, M. Iglesias, A. San José complexes with HCl and CF,;COOH. Crystal structure of and F. Sanchez), 11 [WMoCl{u-( E)-HC=CHPh\(CO),(n°-C;H;),] (G.A. Acum, Asymmetric hydroxylilation M.J. Mays, P.R. Raithby and G.A. Solan), 65 Synthesis and characterization of new chiral Rh({I) complexes Alkyne with N,N’-, and N,P-ligands. A study of anchoring on the Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- modified zeolites and catalytic properties of heterogenized stilbenylJazobenzole und 2,3-Dihydrocinnoline durch complexes (A. Carmona, A. Corma, M. Iglesias, A. San José cobaltkatalysierte, zweifache Addition von Tolan an Azoben- and F. Sanchez), 11 zolderivate (G. Halbritter, F. Knoch und H. Kisch), 87 1,2-Azaborolyl complexes Alkynes 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schitz), at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), 185 185 Allyl Bis(diphenylphosphino)methane A facile synthesis of acetals and aldehydes from allylic ethers Organomercuration of the carbanion derived from [M(CO),- catalyzed by cobalt compounds (B.-H. Chang), 31 (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular Allyl—vinyl ether rearrangement structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Rearrangements of silyl- and stannyl-substituted diallyl ethers: and F.P. Wewers), C14 competition between the allyl-vinyl ether rearrangement and Boron the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. 1,3-Dibora-[3]ferrocenophanes; synthesis and characterization (M. GieBelmann and K. Kwetkat), 191 Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 Amide A multinuclear NMR study of N-(chlorodimethylsilylmethyl) amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Carbanions Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Organomercuration of the carbanion derived from [M(CO),- Amine (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular Insertion of phenyl azide and diphenyldiazomethane into structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of and F.P. Wewers), C14 an 18-electron alkyl zirconocene triazenido complex (T. Luker, Carbon-13 R.J. Whitby and M. Webster), 53 A multinuciear NMR study of N-(chlorodimethylsilylmethyl) Aminocarbene fragments amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Dérivés cycliques de l’acide carbonimidodithioique en tant que Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 source de carbéne: fragmentation de ces ligands lors de leur Carbonyl coordination 4 un complexe trinucléaire de ruthénium (C. Methylene chain length and coordination geometry in triosmium Renouard, H. Stoeckli-Evans et G. Siiss-Fink), 179 clusters containing diphosphine ligands. X-Ray crystal struc- Arene tures of [Os,(CO),.{u-Ph,P(CPHP)h ,,},K n =4 or 5) and Arene-transition metal complexes as precursors of hard coatings [Os (CO) .{u-Ph,PCH,PPh,},](S.E. Kabir, A. Miah, L. Nesa, prepared by the chemical vapour deposition technique (K. K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Hank6, G. Vass and L. Szepes), 235 4] C26 Subject Index of Volume 492 Organomercuration of the carbanion derived from [M(CO),- A facile synthesis of acetals and aldehydes from allylic ethers (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular catalyzed by cobalt compounds (B.-H. Chang), 31 structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- and F.P. Wewers), C14 carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. Preparation and characterization of the square-based pyramidal Rheinwald), 81 cluster anion [H,Ru,(CO),4(44-COH)] (J.R. Galsworthy, C.E. Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- Housecroft, R.L. Ostrander and A.L. Rheingold), 211 stilbenyl)azobenzole und 2,3-Dihydrocinnoline durch cobalt- The synthesis, characterisation and crystal structure of [Ru,(u>- katalysierte, zweifache Addition von Tolan an Azobenzol- HXCO),( 3-0: : 1?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. derivate (G. Halbritter, F. Knoch und H. Kisch), 87 Johnson and C.M. Martin), C17 Copper Carbonylation Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- A facile synthesis of acetals and aldehydes from allylic ethers carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. catalyzed by cobalt compounds (B.-H. Chang), 31 Rheinwald), 81 Carbonyls Co-substitution Photochemical reaction of W(CO), with SnCl,. III. Synthesis Metallorganische Chemie des Technetiums XII. Photolytische of some novel seven-coordinate tungsten(II) complexes CO-Substitutionsreaktionen von Technetiumtricarbonylver- [WCKSnCl,XCO),L,] (L=N- and P-donor ligands) (T. Szy- bindungen. Synthesen und R6ntgenstrukturanalysen von manska-Buzar), 241 (C5H;)Tc(CO),(PPh), (C;Me,;)Tc(CO),(PPh,) und [HB(G,5- Synthesis and characterization of tetracarbonyl complexes of Me,Pz);Tc(CO),[P(OMe);] im Vergleich mit seinen Homolo- molybdenum and tungsten with functionalized imines. Crystal gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. structure of cis-Mo(CO),[(CH;(C,H;)C=N(CH,)], (M.A. Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. 199 Ariza-Castolo, M. De Jestis Rosales-Hoz and R. Contreras), 1 Crown ethers Chelates The unusual outcome of the reaction of potassium anions with Methylene chain length and coordination geometry in triosmium phenyl glycidyl ether (A. Stolarzewicz, Z. Grobelny and M. clusters containing diphosphine ligands. X-Ray crystal struc- Kowalczuk), 111 tures of [Os,(CO),.{u-Ph,P(CH,),,PPh,}K=n4 or 5) and Cryptands [Os (CO)x{uPC-H P,PhPh,,}, ] (S.E. Kabir, A. Miah, L. Nesa, Metal complexes of ferrocene cryptands (H. Plenio and R. K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Diodone), 73 41 Crystal structure Chirality Bridging alkenyl species from the protonation of ditungsten, The one-step synthesis of chiral amino phosphino ferrocenes tungsten—molybdenum and dimolybdenum transverse alkyne (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 complexes with HCl and CF,COOH. Crystal structure of Chromium [WMoCl{u-( E)-HC=CHPhKCO),(7°-C;H;).] (G.A. Acum, Arene-transition metal complexes as precursors of hard coatings M.J. Mays, P.R. Raithby and G.A. Solan), 65 prepared by the chemical vapour deposition technique (K. Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenyl- Hank6, G. Vass and L. Szepes), 235 methanol) with nitrogenous bases: crystal and molecular Heterobimetallic indenyl complexes. Synthesis and structure of structure of the 2:1 adduct with hexamethylenetetramine (G. syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), Insertion of phenyl azide and diphenyldiazomethane into 35 bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of Organomercuration of the carbanion derived from [M(CO),- an 18-electron alkyl zirconocene triazenido complex (T. Luker, (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular R.J. Whitby and M. Webster), 53 structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation and F.P. Wewers), C14 and thermal reactions (M. MOrtl, D. Knausz, Zs. Bocskei, Zs. Cluster Kolos, K. Ujszaszy, L. Szakacs and P. Sohar), 115 Preparation and characterization of the square-based pyramidal Preparation and characterization of the square-based pyramidal cluster anion [H,Ru,(CO),4(44-COH)] (J.R. Galsworthy, C.E. cluster anion [H,Ru,(CO),4(44-COH)] (J.R. Galsworthy, C.E. Housecroft, R.L. Ostrander and A.L. Rheingold), 211 Housecroft, R.L. Ostrander and A.L. Rheingold), 211 Triosmium and triruthenium clusters containing diazaheterocy- Synthesis and crystal structures of the cyclosiloxytin(IV) com- cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. plexes [Cl,Sn{O(SiPh,O),},]-u-(Li(THF),),] and Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, [THF,Sn{(OSiPh,),O},]- toluene (I. Abrahams, M. Mote- M.B. Hursthouse and K.M.A. Malik), 135 valli, S.A.A. Shah and A.C. Sullivan), 99 Clusters Synthesis and X-ray molecular structure of cis,cis-1,3,5-Tris- Methylene chain length and coordination geometry in triosmium (diphenylphosphino)-1,3,5-tris(methoxycarbonyl)cyclohexane clusters containing diphosphine ligands. X-Ray crystal struc- (H.A. Mayer, P. St6Bel, R. Fawzi and M. Steimann), Cl tures of [Os,(CO),o{u-Ph,P(CH,),,PPh,}Kn =4 or 5) and Synthesis, NMR _ studies and molecular structures of [Os (CO).{u-PCPH h, ,PPh5},] (S.E. Kabir, A. Miah, L. Nesa, ((PhSSn),(,C);H] , and [PhSn(S,CNEt,)],(SMCH,), (D. Dak- K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 41 The one-step synthesis of chiral amino phosphino ferrocenes Cobalt (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes The synthesis, characterisation and crystal structure of [Ru,(y>- at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), HXCO),.3(- 0 : 7 : 7?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. 185 Johnson and C.M. Martin), C17 Subject Index of Volume 492 Cyclodimerization Ferrocene 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenyl- at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), methanol) with nitrogenous bases: crystal and molecular 185 structure of the 2:1 adduct with hexamethylenetetramine (G. Cyclopropanation Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Synthesis and characterization of new chiral Rh(1) complexes Metal complexes of ferrocene cryptands (H. Plenio and R. with N,N’-, and N,P-ligands. A study of anchoring on the Diodone), 73 modified zeolites and catalytic properties of heterogenized The one-step synthesis of chiral amino phosphino ferrocenes complexes (A. Carmona, A. Corma, M. Iglesias, A. San José (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 and F. Sanchez), 11 Cyclotrimerization Gold 1,2-Azaborolyl complexes. XX XI. Cyclooligomerization of alkynes Synthesis of dithiolate gold(III) complexes by dithiolate transfer at the 1,2-azaborolylcobalt moiety (G. Schmid and M. Schiitz), reactions. X-ray structure of [Au(C,F;XS,C,H,\PPh,)] (E. 185 Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- guna, R. Terroba and M.D. Villacampa), 105 Diazenes Group 1 Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- Metal complexes of ferrocene cryptands (H. Plenio and R. stilbenyl)azobenzole und 2,3-Dihydrocinnoline durch cobalt- Diodone), 73 katalysierte, zweifache Addition von Tolan an Azoben- Group 2 zolderivate (G. Halbritter, F. Knoch und H. Kisch), 87 Metal complexes of ferrocene cryptands (H. Plenio and R. Diazine Diodone), 73 Triosmium and triruthenium clusters containing diazaheterocy- Group 4 cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. Insertion of phenyl azide and diphenyldiazomethane into Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of M.B. Hursthouse and K.M.A. Malik), 135 an 18-electron alkyl zirconocene triazenido complex (T. Luker, Diboraferrocenophanes R.J. Whitby and M. Webster), 53 1,3-Dibora-(3}ferrocenophanes; synthesis and characterization (M. Group 14 Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 A multinuclear NMR study of N-(chlorodimethylsilylmethyl) Diimines amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Photochemistry of the metal—metal-bonded complexes [(CO),- Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Mn-—Ru(MeXCO),(a-diimine)]. Crystal structure of the pho- toproduct [(CO),Mn-n-(o(N),o(N’),n7(PCr-NP)yC-a')- Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. Hafnium Moraal, D.J. Stufkens, A. Oskam and K. Goubitz), 165 Arene-transition metal complexes as precursors of hard coatings Diorganotin sulphides prepared by the chemical vapour deposition technique (K. Synthesis, NMR _ studies and molecular structures of Hank6o, G. Vass and L. Szepes), 235 [(PhSSn),(CH)3], and [PhSn(S,CNEt,)],(SMC,H) , (D. Dak- Half-sandwich cpds ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 Half-sandwich isocyanide, phosphine, methyl and phosphanido Diphosphines pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- Methylene chain length and coordination geometry in triosmium calde, J. De la Mata, M. Gémez, P. Royo and F. Sanchez), clusters containing diphosphine ligands. X-Ray crystal struc- 151 tures of [Os,(CO),.{u-Ph,P(CH,),,PPh,}K=n4 or 5) and Heterocycles [Os (CO),{u-Ph,PCH ,PPh,},](S.E. Kabir, A. Miah, L. Nesa, Triosmium and triruthenium clusters containing diazaheterocy- K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. 41 Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, Dithiolate complexes M.B. Hursthouse and K.M.A. Malik), 135 Synthesis of dithiolate gold(III) complexes by dithiolate transfer Host—guest adducts reactions. X-ray structure of [Au(C,F;XS,C,H,PPh,)] (E. Hydrogen-bonded adducts of ferrocene-1,1’-diylbis(diphenyl- Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- methanol) with nitrogenous bases: crystal and molecular guna, R. Terroba and M.D. Villacampa), 105 structure of the 2:1 adduct with hexamethylenetetramine (G. Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Early transition metals 1,4-H shift Insertion of phenyl azide and diphenyldiazomethane into Intramolecular rearrangements of silenes II. Synthesis of 1- bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- an 18-electron alkyl zirconocene triazenido complex (T. Luker, l-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — R.J. Whitby and M. Webster), 53 transient silene rearrangement sequence. Novel 1,4-hydrogen ESR spectroscopy shift from aryl carbon to sp? silicon of the silicon-—carbon Photochemistry of the metal—-metal-bonded complexes [(CO),- double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the Lavrukhin), C4 photoproduct [(CO),Mn-u-(o(N),o(N’),n7(PCr-NP)yC-a') - Hydride Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. The synthesis, characterisation and crystal structure of [Ru,(y>- Moraal, D.J. Stufkens, A. Oskam and K. Goubitz), 165 HXCO).3(- 0 : o : n?~COPh)] (A.J. Blake, P.J. Dyson, B.F.G. Ether Johnson and C.M. Martin), C17 A facile synthesis of acetals and aldehydes from allylic ethers Triosmium and triruthenium clusters containing diazaheterocy- catalyzed by cobalt compounds (B.-H. Chang), 31 cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. C28 Subject Index of Volume 492 Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, X-Ray structure of [MnMo(SnPh,\CO),(u-tedip(y- M.B. Hursthouse and K.M.A. Malik), 135 S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. Hydrogen bonding Riera and S. Garcia-Granda), 23 Hydrogen-bonded adducts of ferrocene-1,1'-diylbis(diphenyl- Mass spectrometry methanol) with nitrogenous bases: crystal and molecular Arene-transition metal complexes as precursors of hard coatings structure of the 2:1 adduct with hexamethylenetetramine (G. prepared by the chemical vapour deposition technique (K. Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Hank6, G. Vass and L. Szepes), 235 Hydrosilylation Mass spectroscopy The reaction pathway from Speier’s to Karstedt’s hydrosilylation New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation catalyst (M.F. Lappert and F.P.A. Scott), C11 and thermal reactions (M. MOrtl, D. Knausz, Zs. Bécskei, Zs. Kolos, K. Ujszaszy, L. Szakacs and P. Sohar), 115 Imines Metal Carbonyls Synthesis and characterization of tetracarbonyl complexes of Metal carbonyl syntheses. XXII. Low-pressure carbonylation of molybdenum and tungsten with functionalized imines. Crystal [MOCI,]~ and [MO,]~. The technetium(]) and rhenium(1) structure of cis-Mo(CO),[(CH;4C,H;)C=N(CH,)], (M.A. complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram Ariza-Castolo, M. De Jest Rosales-Hoz and R. Contreras), 1 and T.A. Kaden), 217 Indenyl Metallacycle Heterobimetallic indenyl complexes. Synthesis and structure of Insertion of phenyl azide and diphenyldiazomethane into syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), an 18-electron alkyl zirconocene triazenido complex (T. Luker, 35 R.J. Whitby and M. Webster), 53 Iron Metallasiloxanes 1,3-Dibora-[3 }ferrocenophanes; synthesis and characterization (M. Synthesis and crystal structures of the cyclosiloxytin(IV) com- Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 plexes [Cl,Sn{O(SiPh,O),}, ]-u-(Li(THF),),] and [THF,- Hydrogen-bonded adducts of ferrocene-1,1’-diylbis(diphenyl- Sn{(OSiPh,),O0},] + toluene (I. Abrahams, M. Motevalli, methanol) with nitrogenous bases: crystal and molecular S.A.A. Shah and A.C. Sullivan), 99 structure of the 2:1 adduct with hexamethylenetetramine (G. Metal-—metal bonding Ferguson, C. Glidewell, A. Lewis and C.M. Zakaria), 229 Photochemistry of the metal—metal-bonded complexes [(CO),- The one-step synthesis of chiral amino phosphino ferrocenes Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 photoproduct [(CO),Mn-yn-(o(N),o(N’),n2(PCr-NP)yC-a')- Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. Moraal, D.J. Stufkens, A.O skam and K. Goubitz), 165 Rheinwald), 81 Methylene Isocyanide Methylene chain length and coordination geometry in triosmium Half-sandwich isocyanide, phosphine, methyl and phosphanido clusters containing diphosphine ligands. X-Ray crystal struc- pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- tures of [Os,(CO),9{u-Ph,P(CPHP)h,,},K n =4 or 5) and calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), [Os (CO) .{u-PPCHh ,, PPh,},](S.E. Kabir, A. Miah, L. Nesa, 151 K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Isomerism 41 Synthesis, NMR _ studies and molecular structures of MOCVD ((PhSSn),(CH ,)3], and [PhSn(S,CNEt, )],(SXCH ,), (D. Dak- Arene-transition metal complexes as precursors of hard coatings ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 prepared by the chemical vapour deposition technique (K. Hank6, G. Vass and L. Szepes), 235 Lithium Molybdenum Synthesis and crystal structures of the cyclosiloxytin(IV) com- Bridging alkenyl species from the protonation of ditungsten, plexes [Cl,Sn{O(SiPh,O),},]-u-(Li(THF),),] and [THF,- tungsten—molybdenum and dimolybdenum transverse alkyne Sn{(OSiPh,),O},]- toluene (I. Abrahams, M. Motevalli, complexes with HC] and CF,;COQH. Crystal structure of S.A.A. Shah and A.C. Sullivan), 99 [WMoCK{u-( E)-HC=CHPhK(CO),(7°-C;H5),] (G.A. Acum, Low-pressure Carbonylation M.J. Mays, P.R. Raithby and G.A. Solan), 65 Metal carbonyl syntheses. XXII. Low-pressure carbonylation of Organomercuration of the carbanion derived from [M(CO),- [MOCI,]~ and [MO,]~. The technetium(I) and rhenium(1) (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram and F.P. Wewers), C14 and T.A. Kaden), 217 Reduction reactions of binuclear manganese—molybdenum com- plexes containing S,CPR, and bidentate P-donor bridges. Manganese X-Ray structure of [MnMo(SnPh,\CO),(y-tedip(u- Photochemistry of the metal—metal-bonded complexes [(CO),- S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. Mn-Ru(MeXCO),(a-diimine)]. Crystal structure of the Riera and S. Garcia-Granda), 23 photoproduct [(CO),Mn-u-(o(N),o(N’),77(PCr-NP)yC-a')- Synthesis and characterization of tetracarbonyl complexes of Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. molybdenum and tungsten with functionalized imines. Crystal Moraal, D.J. Stufkens, A.O skam and K. Goubitz), 165 structure of cis-Mo(CO),[(CH;XC,H;)C=N(CH,)], (M.A. Reduction reactions of binuclear manganese—molybdenum com- Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. plexes containing S,CPR, and bidentate P-donor bridges. Ariza-Castolo, M. De Jesis Rosales-Hoz and R. Contreras), 1 Subject Index of Volume 492 Synthesis and X-ray molecular structure of cis,cis-1,3,5-Tris- Photochemistry (diphenylphosphino)-1,3,5-tris(methoxycarbonyl)cyclohexane Photochemistry of the metal—metal-bonded complexes [(CO).- (H.A. Mayer, P. St6Bel, R. Fawzi and M. Steimann), Cl Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the photoproduct [(CO),Mn-p-(a(N),o(N’),72(PCr-NP)yC-a') - Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. Niobium Moraal, D.J. Stufkens, A. Oskam and K. Goubitz), 165 Half-sandwich isocyanide, phosphine, methyl and phosphanido Photochlorination pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 151 Photolysis Nitrene Metallorganische Chemie des Technetiums XII. Photolytische New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation CO-Substitutionsreaktionen von Technetiumtricarbonylver- and thermal reactions (M. MOrtl, D. Knausz, Zs. Bécskei, Zs. bindungen. Synthesen und R6ntgenstrukturanalysen von Kolos, K. Ujszdszy, L. Szakacs and P. Sohar), 115 (C;H;)Tce(CO)(PPh;), (C;Me;)Tc(CO),(PPh;) und [HB(3,5- Nitrogen Me,Pz);Tc(CO),[P(OMe),] im Vergleich mit seinen Homolo- Triosmium and triruthenium clusters containing diazaheterocy- gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, 199 M.B. Hursthouse and K.M.A. Malik), 135 Platinum NMR The reaction pathway from Speier’s to Karstedt’s hydrosilylation A multinuclear NMR study of N-(chlorodimethylsilylmethyl) catalyst (M.F. Lappert and F.P.A. Scott), C11 amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Poly(carbosilanes) Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- NMR, multinuclear kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 1,3-Dibora-[3]ferrocenophanes; synthesis and characterization (M. Poly(dialkylsilylene co-alkylenes) Herberhold, U. Doérfler, W. Milius and B. Wrackmeyer), 59 Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 Osmium Potassium anions Methylene chain length and coordination geometry in triosmium The unusual outcome of the reaction of potassium anions with clusters containing diphosphine ligands. X-Ray crystal struc- phenyl glycidyl ether (A. Stolarzewicz, Z. Grobelny and M. tures of [Os,(CO),o{u-Ph,P(CH),,PPh,}Kn =4 or 5) and Kowalczuk), 111 [Os (CO),{uPC-H P,PhPh,,}, ](S.E. Kabir, A. Miah, L. Nesa, Protonation K. Uddin, K.I. Hardcastle, E. Rosenberg and A.J. Deeming), Bridging alkenyl species from the protonation of ditungsten, 41 tungsten—molybdenum and dimolybdenum transverse alkyne Triosmium and triruthenium clusters containing diazaheterocy- complexes with HCl and CF,COOH. Crystal structure of [WMoCl{u-( E)-HC=CHPh\(CO),(?-C;H;),] (G.A. Acum, cles (R. Agarwala, K.A. Azam, R. Dilshad, S.E. Kabir, R. Miah, M. Shahiduzzaman, K.I. Hardcastle, E. Rosenberg, M.J. Mays, P.R. Raithby and G.A. Solan), 65 M.B. Hursthouse and K.M.A. Malik), 135 Oxiranes The unusual outcome of the reaction of potassium anions with phenyl glycidyl ether (A. Stolarzewicz, Z. Grobelny and M. Rearrangement Kowalczuk), 111 Intramolecular rearrangements of silenes II. Synthesis of 1- methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- Palladium l-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — The one-step synthesis of chiral amino phosphino ferrocenes transient silene rearrangement sequence. Novel 1,4-hydrogen (I.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 shift from aryl carbon to sp? silicon of the silicon—carbon Pentamethylcyclopentadienyl double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Half-sandwich isocyanide, phosphine, methyl and phosphanido Lavrukhin), C4 pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- Rhenium calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), Metal carbonyl syntheses. XXII. Low-pressure carbonylation of 151 {MOCI,]~ and [MO,]~. The technetium(]) and rhenium(1) Phosphanido complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Half-sandwich isocyanide, phosphine, methyl and phosphanido Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- and T.A. Kaden), 217 calde, J. De la Mata, M. Gomez, P. Royo and F. Sanchez), Rhodium 151 Heterobimetallic indenyl complexes. Synthesis and structure of Phosphine syn-[Cr(CO).(,:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- Half-sandwich isocyanide, phosphine, methyl and phosphanido con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- 35 calde, J. De la Mata, M. G6mez, P. Royo and F. Sanchez), Synthesis and characterization of new chiral Rh(I) complexes 151 with N,N’-, and N,P-ligands. A study of anchoring on the Phosphorus modified zeolites and catalytic properties of heterogenized The one-step synthesis of chiral amino phosphino ferrocenes complexes (A. Carmona, A. Corma, M. Iglesias, A. San José (1.R. Butler, W.R. Cullen, S.J. Rettig and A.S.C. White), 157 and F. Sanchez), 11 C30 Subject Index of Volume 492 Rotamers Synthesis and crystal structures of the cyclosiloxytin(IV) com- A multinuclear NMR study of N-(chlorodimethylsilylmethyl) plexes [Cl,Sn{O(SiPh,O),}, ]-u-(Li(THF),),] and [THF,- amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. Sn{(OSiPh,),0},]- toluene (I. Abrahams, M. Motevalli, Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 S.A.A. Shah and A.C. Sullivan), 99 Ruthenium The reaction pathway from Speier’s to Karstedt’s hydrosilylation Dérivés cycliques de l’acide carbonimidodithioique en tant que catalyst (M.F. Lappert and F.P.A. Scott), C11 source de carbéne: fragmentation de ces ligands lors de leur °Si-NMR spectroscopy coordination 4 un complexe trinucléaire de ruthénium (C. Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- Renouard, H. Stoeckli-Evans et G. Siiss-Fink), 179 kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 Photochemistry of the metal—metal-bonded complexes [(CO),- Stannasiloxane Mn-Ru(MeXCO),(a@-diimine)]. Crystal structure of the Synthesis and crystal structures of the cyclosiloxytin(IV) com- photoproduct [(CO),Mn-p-(o(N),o(N’),n7(PCr-NP)yC-a')- plexes [Cl,Sn{O(SiPh,O),},]-u-(Li(THF),),] and [THF,- Ru(MeXCO),] (H.A. Nieuwenhuis, A. Van Loon, M.A. Sn{(OSiPh,),;0},]- toluene (I. Abrahams, M. Motevalli, Moraal, D.J. Stufkens, A.O skam and K. Goubitz), 165 S.A.A. Shah and A.C. Sullivan), 99 Preparation and characterization of the square-based pyramidal Stereochemistry cluster anion [H,Ru,(CO),4(4.4-COH)] (J.R. Galsworthy, C.E. Synthesis and characterization of tetracarbonyl complexes of Housecroft, R.L. Ostrander and A.L. Rheingold), 211 molybdenum and tungsten with functionalized imines. Crystal The synthesis, characterisation and crystal structure of [Ru,(u>- structure of cis-Mo(CO),[(CH;XC;H;)C=N(CH,)], (M.A. HCO) (3-0 : o : n?-COPh)] (A.J. Blake, P.J. Dyson, B.F.G. Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. Johnson and C.M. Martin), C17 Ariza-Castolo, M. De Jesis Rosales-Hoz and R. Contreras), 1 Structure Metal carbonyl syntheses. XXII. Low-pressure carbonylation of [MOCI,]~ and [MO,]~. The technetium(]) and rhenium(I) Seven-coordinate complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Photochemical reaction of W(CO), with SnCl,. III. Synthesis Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram of some novel seven-coordinate tungsten(II) complexes and T.A. Kaden), 217 [WCKSnCl,4CO),L,] (L=N- and P-donor ligands) (T. Szy- Supported catalysts manska-Buzar), 241 Synthesis and characterization of new chiral Rh(I) complexes Silaacenaphthene with N,N’-, and N,P-ligands. A study of anchoring on the Intramolecular rearrangements of silenes II. Synthesis of 1- modified zeolites and catalytic properties of heterogenized methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- complexes (A. Carmona, A. Corma, M. Iglesias, A. San José 1-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — and F. Sanchez), 11 transient silene rearrangement sequence. Novel 1,4-hydrogen Syn and anti structures shift from aryl carbon to sp? silicon of the silicon—carbon Heterobimetallic indenyl complexes. Synthesis and structure of double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- Lavrukhin), C4 con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), Silacyclobutane 35 Intramolecular rearrangements of silenes II. Synthesis of 1- Synthesis methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- Half-sandwich isocyanide, phosphine, methyl and phosphanido 1-silacyclobutane via [4 — 2 + 2]thermocyclodecomposition — pentamethylcyclopentadienylniobium(V) complexes (M.I. Al- transient silene rearrangement sequence. Novel 1,4-hydrogen calde, J. De la Mata, M. Gémez, P. Royo and F. Sanchez), shift from aryl carbon to sp? silicon of the silicon—carbon 151 double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Synthesis of dithiolate gold(III) complexes by dithiolate transfer Lavrukhin), C4 reactions. X-ray structure of [Au(C,F;XS,C,;H,\PPh,)] (E. Silenes Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- Intramolecular rearrangements of silenes II. Synthesis of 1- guna, R. Terroba and M.D. Villacampa), 105 methyl-1-hydro-1-silaacenaphthene from 1-methyl-1-naphthyl- 1-silacyclobutane via [4 —- 2 + 2]thermocyclodecomposition — transient silene rearrangement sequence. Novel 1,4-hydrogen shift from aryl carbon to sp? silicon of the silicon—carbon double bond (L.E. Gusel’nikov, V.V. Volkova and B.D. Technecium Lavrukhin), C4 Metallorganische Chemie des Technetiums XII. Photolytische Silicon CO-Substitutionsreaktionen von Technetiumtricarbonylver- A multinuclear NMR study of N-(chlorodimethylsilylmethyl) bindungen. Synthesen und Ro6ontgenstrukturanalysen von amides (C.H. Yoder, W.D. Smith, B.L. Buckwalter, C.D. (C5H;)Tc(CO)(PPh), (C;Me;)Tc(CO),(PPh,) und [HB(3,5- Schaeffer, Jr., K.J. Sullivan and M.F. Lehman), 129 Me,Pz),;Tc(CO),[P(OMe),] im Vergleich mit seinen Homolo- New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. and thermal reactions (M. M6rtl, D. Knausz, Zs. Boécskei, Zs. Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), Kolos, K. Ujszdszy, L. Szakdcs and P. Soh4r), 115 199 Rearrangements of silyl- and stannyl-substituted diallyl ethers: Technetium competition between the allyl-vinyl ether rearrangement and Metal carbonyl syntheses. XXII. Low-pressure carbonylation of the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. [MOCI,]~ and [MO,]~. The technetium(]) and rhenium(I) GieBelmann and K. Kwetkat), 191 complexes [NEt,],[MCI,(CO),] (R. Alberto, R. Schibli, A. Synthese und Charakterisierung von Poly(dialkylsilylen-co-al- Egli, P.A. Schubiger, W.A. Herrmann, G. Artus, U. Abram kylenen) (W. Habel, W. Haeusler und P. Sartori), 225 and T.A. Kaden), 217 Subject Index of Volume 492 C31 Thermolysis Syntheses and characterization of tricarbonyl tungsten complexes Thermolyseverhalten alkinylsubstituierter Cyclopentadienyl-Di- containing 1,1'-bis(diphenylphosphino)ferrocene ligand (S.C.N. carbonyl-Eisen-Verbindungen (H. Lang, S. Blau und G. Hsu, W.-Y. Yeh and M.Y. Chiang), 121 Rheinwald), 81 Synthesis and characterization of tetracarbonyl complexes of Thiolate fragments molybdenum and tungsten with functionalized imines. Crystal Dérivés cycliques de l’acide carbonimidodithioique en tant que structure of cis-Mo(CO),[(CH;XC,H;)C=N(CH,)], (M.A. source de carbéne: fragmentation de ces ligands lors de leur Paz-Sandoval, M.E. Dominguez-Duran, C. Pazos-Mayen, A. coordination 4 un complexe trinucléaire de ruthénium (C. Ariza-Castolo, M. De Jestis Rosales-Hoz and R. Contreras), 1 Renouard, H. Stoeckli-Evans et G. Siiss-Fink), 179 Tin Wittig rearrangement Photochemical reaction of W(CO), with SnCl,. III. Synthesis of Rearrangements of silyl- and stannyl-substituted diallyl ethers: some novel seven-coordinate tungsten(II) complexes competition between the allyl-vinyl ether rearrangement and [WCK(SnCl,4CO),L,] (L=N- and P-donor ligands) (T. Szy- the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. manska-Buzar), 241 GieBelmann and K. Kwetkat), 191 Rearrangements of silyl- and stannyl-substituted diallyl ethers: competition between the allyl-vinyl ether rearrangement and X-ray diffraction the [2,3] Wittig sigmatropic rearrangement (T.N. Mitchell, F. 1,3-Dibora-(3]ferrocenophanes; synthesis and characterization (M. GieBelmann and K. Kwetkat), 191 Herberhold, U. Dorfler, W. Milius and B. Wrackmeyer), 59 Synthesis and crystal structures of the cyclosiloxytin(IV) com- X-ray structure plexes [Cl,Sn{O(SiPh,O),}, ]-u-(Li(THF),),] and [THF,- Heterobimetallic indenyl complexes. Synthesis and structure of Sn{(OSiPh,),O},]- toluene (I. Abrahams, M. Motevalli, syn-[Cr(CO),(u,n:n-indenyl)Rh(COD)] (C. Bonifaci, A. Cec- S.A.A. Shah and A.C. Sullivan), 99 con, A. Gambaro, P. Ganis, S. Santi, G. Valle and A. Venzo), Synthesis, NMR _ studies and molecular structures of 35 ((PhSSn),(C)3H] , and [PhSn(S,CNEt ,)],(SMCH,), (D. Dak- Metal complexes of ferrocene cryptands (H. Plenio and R. ternieks, K. Jurkschat, D. Schollmeyer and H. Wu), 145 Diodone), 73 Synthesis of dithiolate gold(III) complexes by dithiolate transfer Metallorganische Chemie des Technetiums XII. Photolytische reactions. X-ray structure of [Au(C,F;4S,C,H,\PPh,)] (E. CO-Substitutionsreaktionen von Technetiumtricarbonylver- Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- bindungen. Synthesen und Ro6ntgenstrukturanalysen von guna, R. Terroba and M.D. Villacampa), 105 (C3;H,)Tc(CO),(PPh), (C;Me;)Tc(CO),(PPh,) und [HB(3,5- Transition metal complexes Me,Pz);Tc(CO),[P(OMe),;] im Vergleich mit seinen Homolo- Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- gen (J.E. Joachim, C. Apostolidis, B. Kanellakopulos, D. stilbenyl)azobenzole und 2,3-Dihydrocinnoline durch cobalt- Meyer, B. Nuber, K. Raptis, J. Rebizant und M.L. Ziegler), katalysierte, zweifache Addition von Tolan an Azobenzol- 199 derivate (G. Halbritter, F. Knoch und H. Kisch), 87 Reduction reactions of binuclear manganese—molybdenum com- Trialkylphosphoniodithioformate bridges plexes containing S,CPR, and bidentate P-donor bridges. Reduction reactions of binuclear manganese—molybdenum com- X-Ray structure of [MnMo(SnPh,)CO),(y-tedipp- plexes containing S,CPR, and bidentate P-donor bridges. S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. X-Ray structure of [MnMo(SnPh,)CO),(y-tedipy- Riera and S. Garcia-Granda), 23 S,CPCy,)] (E.M. Lépez, D. Miguel, J.A. Pérez-Martinez, V. Synthesis of dithiolate gold(III) complexes by dithiolate transfer Riera and S. Garcia-Granda), 23 reactions. X-ray structure of [Au(C,F;XS,C,H,PPh,)] (E. Trimethylsilyl Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- New N-hydroxy carbamic acid trialkylsilyl derivatives: preparation guna, R. Terroba and M.D. Villacampa), 105 and thermal reactions (M. M6rtl, D. Knausz, Zs. Bocskei, Zs. Ubergangsmetallkomplexe von Diazenen. XXXIV. 2,6-Di(trans- Kolos, K. Ujsz4szy, L. Szakacs and P. Sohar), 115 stilbenylJazobenzole und 2,3-Dihydrocinnoline durch cobalt- Tripodal phosphine katalysierte, zweifache Addition von Tolan an Azobenzol- Synthesis and X-ray molecular structure of cis,cis-1,3,5-Tris- derivate (G. Halbritter, F. Knoch und H. Kisch), 87 (diphenylphosphino)-1,3,5-tris(methoxycarbonyl)cyclohexane (H.A. Mayer, P. St6Bel, R. Fawzi and M. Steimann), Cl Zeolites Tungsten Synthesis and characterization of new chiral Rh(1I) complexes Bridging alkenyl species from the protonation of ditungsten, with N,N’-, and N,P-ligands. A study of anchoring on the tungsten—molybdenum and dimolybdenum transverse alkyne modified zeolites and catalytic properties of heterogenized complexes with HCl and CF;COQOH. Crystal structure of complexes (A. Carmona, A. Corma, M. Iglesias, A. San José [WMoCK{u-( E)-HC=CHPh\(CO),(7°-C;H5),] (G.A. Acum, and F. Sanchez), 11 M.J. Mays, P.R. Raithby and G.A. Solan), 65 Zinc Organomercuration of the carbanion derived from [M(CO),- Synthesis of dithiolate gold(III) complexes by dithiolate transfer (Ph,PCH,PPh,)] (M = Cr, Mo or W). Crystal and molecular reactions. X-ray structure of [Au(C,F;XS,C,H,PPh,)] (E. structure of [Cr(CO),{Ph,PCH(HgMe)PPh,}] (A.T. Hutton Cerrada, E.J. Fernandez, M.C. Gimeno, A. Laguna, M. La- and F.P. Wewers), C14 guna, R. Terroba and M.D. Villacampa), 105 Photochemical reaction of W(CO), with SnCl,. III. Synthesis Zirconium of some novel seven-coordinate tungsten(II) complexes Arene-transition metal complexes as precursors of hard coatings [WCK(SnCl,4CO),L,] (L=N- and P-donor ligands) (T. Szy- prepared by the chemical vapour deposition technique (K. manska-Buzar), 241 Hank6o, G. Vass and L. Szepes), 235 C32 Subject Index of Volume 492 Insertion of phenyl azide and diphenyldiazomethane into Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th bis(cyclopentadienyl)zirconacyclopentanes. Crystal structure of edition, Rare Earth Elements, Volume 12b, Sc, Y, La-—Lu, an 18-electron alkyl zirconocene triazenido complex (T. Luker, Compounds with Carbon (G.J. Leigh), C20 R.J. Whitby and M. Webster), 53 Inorganic Chemistry, 2nd edition, D.F. Shriver, P.W. Atkins and C.H. Langford (G.J. Leigh), C21 Book reviews Progress in Inorganic Chemistry, Volume 42, K.D. Karlin (Ed.) Gmelin Handbook of Inorganic and Organometallic Chemistry, 8th (G.J. Leigh), C21 edition, Molybdenum, Supplement Volume B9, Compounds with Se, Te, Po (G.J. Leigh), C20

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