Journal of Organometallic Chemistry 1994: Vol 482 Index

10 Pages·1994·3.4 MB·English

C2 Journal of Organometallic Chemistry, 482 (1994) C2—C3
Author Index of Volume 482
Ahlgrén, M., 279 Glass, W.K., 301 Nief, F., 125
Ando, W., 131 Goesmann, H., 85 Nikonov, G.I., 187
Antinolo, A., 93 Goubitz, K., 15 Noltemeyer, M., 285
Gowenlock, B.G., 227
Batsanov, A.S., 187 Ogasawara, M., 7
Baudry, D., 125 Haiduc, I., 253 Oro, L.A., 53
Belyakov, S., 73 Heck, J., 81 Oskam, A., 15
Bissinger, P., 151 Hengge, E., 201 Otero, A., 93
Bode, K., 285 Herrmann, W.A., 169
Boersma, J., 191 Hiller, W., 151 Pakkanen, T.A., 279
Borisova, L., 73 Hogerheide, M.P., 191 Parish, R.V., 227
Bravo, J., 147 Horn, E., 99 Pérez-Torrente, J.J., 53
Breunig, H.J., 253 Petit, F., 31
Brown, D.A., 301 Polam, J.R., 1
Ingham, S.L., 139
Burrell, A.K., 261, 271 PolaSek, M., 231
Popelis, J., 73
Cameron, M., 227 Jager, C., 285 Porter, L.C., 1
Canty, A.J., 191 Janssen, M.D., 191 Postel, M., 119
Carpentier, J.-F., 31 Pritzkow, H., 243
Carrillo, F., 93 Kabe, Y., 131 Pursiainen, J., 279
Putala, M., 187
Casas, J.S., 147 Kakkonen, H.J., 279
Castanet, Y., 31 Kalck, P., 45
Castellano, E.E., 147 Karsch, H.H., 151 Raithby, P.R., 139
Ciriano, M.A., 53 Kazennova, N.B., 187 Reid, B.D., 207
Clark, G.R., 261, 271 Keller, H., 63 Ricard, L., 125
Cordero, M.B., 147 Khan, MLS., 139 Rickard, C.E.F., 261, 271
Roper, W.R., 261, 271
Cox, P.J., 221 Klingebiel, U., 285
Csakvari, B., 183 Knausz, D., 183 Roundhill, D.M., 39
Kolos, Zs., 183
Saburi, M., 7
Daran, J.C., 63 Kooijman, H., 151
Sanchez, A., 147
De Alencar Simoni, J., 111 Kreddan, K., 301
Schier, A., 151
De Graaf, W., 191 Kriebisch, K.-A., 81
Schmid, G., 231
De Lange, P.P.M., 99
Sedmera, P., 231
Dias, A.R., 111 Lahoz, F.J., 53
Shaw, K.F., 207
Dias, P.B., 111 Lang, H., 63
Siebenlist, R., 99
Drost, C., 285
Lassacher, P., 201
Silvestru, A., 253
Dunach, E., 119 Le Boisselier, V., 119
Smeets, W.J.J., 191
Lee, G.-H., 67
Sordo, J., 147
Ebert, K.H., 253 Lemenovskii, D.A., 187
Sowerby, D.B., 253
El-Gamati, I., 301 Lewis, J., 139
Spek, A.L., 99, 191
Elliott, G.P., 243 Liu, L.-K., 67
Stadelmann, B., 201
Ernsting, J.M., 99 Long, N.J., 139
Steigelmann, O., 151
Lu, K.-L., 67
Stewart, S.K., 293
Fajardo, M., 93 Lukevics, E., 73
Stone, F.G.A., 243
Faulkner, C.W., 139
Stor, G.J., 15
Fenske, D., 85
Mach, K., 231 Struchkov, Yu.T., 187
Ferazin, G., 151 Markies, B.A., 191 Stufkens, D.J., 15
Fraanje, J., 15
Martinho Simoes, J.A., 111 Stiger, H., 201
Friihauf, H.-W., 99
Massa, W., 81 Su, C.-J., 67
Michalik, M., 85 Szakacs, L., 183
Garcia-Yuste, S., 93 Monteil, F., 45
Gau, H.-M., 67 Morawietz, M.J.A., 169 Teixeira, C., 111
Georgiev, E.M., 39 Mortl, M., 183 Thewalt, U., 231
Gevorgyan, V., 73 Mortreux, A., 31 Tillack, A., 85
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Troev, K., 39 Wadepohl, H., 243 Xie, S., 39
Tsumuraya, T., 131 Wang, Y., 67
Wardell, J.L., 221
Van der Vis, M., 15 Ware, D.C., 271
Zak, Z., 285
Van Koten, G., 191 Welch, A.J., 207
Van Wijnkoop, M., 99 Whiting, A., 293 Zukerman-Schpector, J., 147
Vasapollo, G., 227 Wocadlo, S., 81
Vjater, A., 73 Wolf, A., 243
Journal of Organometallic Chemistry, 482 (1994) C4—C10
Subject Index of Volume 482
Acetonitrile Bi(IID) catalysis
Crystallographic disorder of carbonyl, propyl isocyanide and ace- Bismuth(III)-catalyzed oxidative cleavage of aryl epoxides: sub-
tonitrile groups in the structures of Os ,(CO),9(CNRMNCMe) stituent effects on the kinetics of the oxidation reaction (V.
(K.-L. Lu, L.-K. Liu, C.-J. Su, H.-M. Gau, Y. Wang and G.-H. Le Boisselier, E. Dufach and M. Postel), 119
Lee), 67 Binuclear complexes
Acetylene Synthesis of diphosphine-linked binuclear metal—ring carbonyl
Ruthenium(II) o-acetylide complexes; monomers, dimers and complexes (D.A. Brown, I. El-Gamati, W.K. Glass and K.
polymers (C.W. Faulkner, S.L. Ingham, M.S. Khan, J. Lewis, Kreddan), 301
N.J. Long and P.R. Raithby), 139 Biphatic medium Phosphines
Alkynes Carbonylation of bromobenzene in a biphasic medium catalysed
1,3-Dipolar cycloaddition to the C=X-—M fragment. 13. Regiose- by water-soluble palladium complexes derived from tris(3-
lectivity in the reactions of mononuclear iminoketone com- sulphophenyl)phosphine (F. Monteil and P. Kalck), 45
plexes Fe(CO),('Bu-N=C(H)—C(R)=O) (R = Ph, Me) with the Bipyridine
asymmetric alkyne methyl propynoate (M. Van Wijnkoop, R. Synthesis and structural studies of phenyl(iodo)- and methyl-
Siebenlist, J.M. Ernsting, P.P.M. De Lange, H.-W. Frihauf, (phenyl)palladium(II) complexes of bidentate nitrogen donor
E. Horn and A.L. Spek), 99 ligands (B.A. Markies, A.J. Canty, W. De Graaf, J. Boersma,
Synthesis and coordination chemistry of tellurium alkynes (H. M.D. Janssen, M.P. Hogerheide, W.J.J. Smeets, A.L. Spek
Keller, J.C. Daran and H. Lang), 63 and G. Van Koten), 191
Ambidentate ligands Bismuth
Phosphinomethanid-Komplexe der Lanthanoide (H.H. Karsch, Bismuth(III)-catalyzed oxidative cleavage of aryl epoxides: sub-
G. Ferazin, H. Kooijman, O. Steigelmann, A. Schier, P. stituent effects on the kinetics of the oxidation reaction (V.
Bissinger und W. Hiller), 151 Le Boisselier, E.D unach and M. Postel), 119
Amides Bond enthalpies
Synthesis and characterization of bridged half-sandwich amides Photomicrocalorimetry: photosubstitution of carbonyl by phos-
of titanium and zirconium (W.A. Herrmann and M.J.A. phites in [Mn(°-C;H,CH;CO),] (P.B. Dias, C. Teixeira,
Morawietz), 169 A.R. Dias, J. De Alencar Simoni and J.A. Martinho Simoes),
Amine 111
Asymmetrische Katalyse. IV. Hydrosilylierung von Acetophenon Boronate
mit Pyrrolin-2,5-dion/-modifizierten [Rh(COD)CI],-Kataly- Synthesis of trans-arylvinylboronates via a palladium catalysed
satoren (A. Tillack, M. Michalik, D. Fenske und H. Goes- cross-coupling of a vinylboronate ester with aryl halides (S.K.
mann), 85 Stewart and A. Whiting), 293
Synthesis and structural studies of phenyl(iodo)- and methyl- Bridging ligands
(phenyl)palladium(II) complexes of bidentate nitrogen donor Bimetallic reactivity: unusual change in the coordination mode of
ligands (B.A. Markies, A.J. Canty, W. De Graaf, J. Boersma, the bridging ligands arising from an oxidative addition process
M.D. Janssen, M.P. Hogerheide, W.J.J. Smeets, A.L. Spek (M.A. Ciriano, J.J. Pérez-Torrente, F.J. Lahoz and L.A. Oro),
and G. Van Koten), 191 53
q-aromatic ligands
n>-Pentabenzylcyclopentadieny] derivatives of titanium (IV), (IID),
Carbene
and (II). The crystal structures of (n°-C;H;°-C,Bz,)TiCl,
(Bz = benzyl), (n°-C;H5°-CBz;)TiCl, and (n°-C;H;n- Kooperative Wirkung in 7z-Ligand-verbrickten Zweikernkom-
plexen. XIV. [{(CpM(CO,}, u-(n""!-Et, NC=CNEt ,)] (M = Mo,
C;Bz;)Tiln?-(CSiMe;),] (G. Schmid, U. Thewalt, M. PolaSek,
W), ein zweikerniger Bis(Fischer-Carben)-Komplex mit einem
K. Mach and P. Sedmera), 231
1,2-Dimetallavierring als zentralem Baustein (J. Heck, K.-A.
Aryl epeoxide cleavage
Kriebisch, W. Massa und S. Wocadlo), 81
Bismuth(III)-catalyzed oxidative cleavage of aryl epoxides: sub-
Carbon-chlorine bonds
stituent effects on the kinetics of the oxidation reaction (V.
Hydrogenolysis of carbon—chlorine bonds in carbon tetrachloride
Le Boisselier, E. Dunach and M. Postel), 119
and trichlorofluoromethane in the presence of catalytic quan-
Aryl Halides
tities of tris(triphenylphosphine) ruthenium(II) dichloride (S.
Synthesis of trans-arylvinylboronates via a palladium catalysed
Xie, E.M. Georgiev, D.M. Roundhill and K. Troev), 39
cross-coupling of a vinylboronate ester with aryl halides (S.K.
Carbonyl
Stewart and A. Whiting), 293
1,3-Dipolar cycloaddition to the C=X-—M fragment. 13. Regiose-
Benzothiazole-2-thiolato lectivity in the reactions of mononuclear iminoketone com-
Bimetallic reactivity: unusual change in the coordination mode of plexes Fe(CO),(‘Bu-N=C(H)—C(R)=O) (R = Ph, Me) with the
the bridging ligands arising from an oxidative addition process asymmetric alkyne methyl propynoate (M. Van Wijnkoop, R.
(M.A. Ciriano, J.J. Pérez-Torrente, F.J. Lahoz and L.A. Oro), Siebenlist, J.M. Ernsting, P.P.M. De Lange, H.-W. Fruhauf,
53 E. Horn and A.L. Spek), 99
CS
Crystallographic disorder of carbonyl, propyl isocyanide and ace- cross-coupling of a vinylboronate ester with aryl halides (S.K.
tonitrile groups in the structures of Os ,(CO),)((CNRMXNCMe) Stewart and A. Whiting), 293
(K.-L. Lu, L.-K. Liu, C.-J. Su, H.-M. Gau, Y. Wang and G.-H. Crystallography
Lee), 67 Crystallographic disorder of carbonyl, propyl isocyanide and ace-
Solid state studies of some nitrosoaromatic iron carbonyls (M. tonitrile groups in the structures of Os,(CO),.(CNR\XNCMe)
Cameron, B.G. Gowenlock, R.V. Parish and G. Vasapollo), (K.-L. Lu, L.-K. Liu, C.-J. Su, H.-M. Gau, Y. Wang and G.-H.
227 Lee), 67
Synthesis and coordination chemistry of tellurium alkynes (H. Crystal structure
Keller, J.C. Daran and H. Lang), 63 1,3-Dipolar cycloaddition to the C=X-M fragment. 13. Regiose-
Synthesis and structural characterization of [N(PPh;),][H,Ru;- lectivity in the reactions of mononuclear iminoketone com-
Rh(CO),,>] (H.J. Kakkonen, M. Ahlgrén, T.A. Pakkanen and plexes Fe(CO),(*Bu-N=C(H)-C(R)=O) (R = Ph, Me) with the
J. Pursiainen), 279 asymmetric alkyne methyl propynoate (M. Van Wijnkoop, R.
Synthesis of diphosphine-linked binuclear metal—-ring carbonyl Siebenlist, J.M. Ernsting, P.P.M. De Lange, H.-W. Frihauf,
complexes (D.A. Brown, I. El-Gamati, W.K. Glass and K. E. Horn and A.L. Spek), 99
Kreddan), 301 Coordination of the potentially tridentate ligands 2,6-diacetyl-
Carbonylation pyridine-bis(anil) (dapa) and 2-(2-(2'-methylidenepyridyl)-
Carbonylation of bromobenzene in a biphasic medium catalysed aminoethyl)pyridine (map) in the complexes fac-BrMn-
by water-soluble palladium complexes derived from tris(3- (CO)3L, fac-(CO);MM’(CO),L (M, M’ = Mn, Re; L = dapa,
sulphophenyl)phosphine (F. Monteil and P. Kalck), 45 map) and their photoproducts. The crystal structure of
Mechanistic investigations of palladium-catalysed single and dou- BrMn(CO),(N,N,N-dapa) (G.J. Stor, M. Van der Vis, D.J.
ble carbonylation of aryl and vinyl halides by methyl formate Stufkens, A. Oskam, J. Fraanje and K. Goubitz), 15
(J.-F. Carpentier, Y. Castanet, A. Mortreux and F. Petit), 31 Is electrophilic substitution possible in the coordinated cyclopen-
Carbonyls tadienyl ligand of early transition metal metallocene com-
Coordination of the potentially tridentate ligands 2,6-diacetyl- plexes? Molecular structure of binuclear nitrene niobocene
pyridine-bis(anil) (dapa) and 2-(2-(2’-methylidenepyridyl)- complex [(C;H,C(COOEt)=N-yp-N)(C5H5)Nb], (G.I.
aminoethyl)pyridine (map) in the complexes fac-BrMn- Nikonov, M. Putala, N.B. Kazennova, D.A. Lemenovskii, A.S.
(CO)3L, fac-(CO);MM’(CO),L (M, M’ = Mn, Re; L = dapa, Batsanov and Yu.T. Struchkov), 187
map) and their photoproducts. The crystal structure of New aryltellurium(II) diorganophosphinodithioates. Crystal struc-
BrMn(CO),(N,N,N-dapa) (G.J. Stor, M. Van der Vis, D.J. ture of red (294 K) and yellow (173 K) ‘JPhTeS(S)PPh, ], a
Stufkens, A. Oskam, J. Fraanje and K. Goubitz), 15 supramolecular polymer displaying an unusual coordination
Carboranes pattern of the phosphinodithioato ligand (A. Silvestru, I.
Synthesis and characterisation of metal complexes of ether Haiduc, K.H. Ebert, H.J. Breunig and D.B. Sowerby), 253
carbaboranes. Molecular structures of d® ML3, d® ML, and Reactions of coordinated tetrafluoroethylene with halogens. Syn-
d'° ML complexes of mono- and di-ether C,B, carbaborane thesis of o-bonded halotetrafluoroethyl complexes of ruthe-
ligands, showing the progressive importance of secondary nium(II) and osmium(II) and the structure of OsI(C,F,D-
M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207 (CO),(PPh,), (A.K. Burrell, G.R. Clark, C.E.F. Rickard, W.R.
Carbyne Roper and D.C. Ware), 271
Hydroboration of carbon-tungsten triple bonds: crystal structures Structures of 4-tolyl 2-(triphenylstannyl)ethyl sulphone and 4-tolyl
of the >-benzyl complexes (n-C;H;)CO),W{n?-CH- 4-(triphenylstannyl)butyl sulphone (P.J. Cox and J.L. Wardell),
221
[B(C,H;)2]C,H,Me-4} and (n-C;Me,CO),W{n?-CH-
[B(C,H5),]C,;,H,Me-4} (H. Wadepohl, G.P. Elliott, H. Synthesis and characterisation of metal complexes of ether
Pritzkow, F.G.A. Stone and A. Wolf), 243 carbaboranes. Molecular structures of d° ML;, d® ML, and
Catalysis d'° ML complexes of mono- and di-ether C,By carbaborane
Asymmetrische Katalyse. IV. Hydrosilylierung von Acetophenon ligands, showing the progressive importance of secondary
mit Pyrrolin-2,5-dion/-modifizierten [Rh(COD)CI],-Kataly- M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207
satoren (A. Tillack, M. Michalik, D. Fenske und H. Goes- Synthesis and coordination chemistry of tellurium alkynes (H.
mann), 85 Keller, J.C. Daran and H. Lang), 63
Mechanistic investigations of palladium-catalysed single and dou- Synthesis and structural characterization of [N(PPh;),][H,Ru,;-
ble carbonylation of aryl and vinyl halides by methyl formate Rh(CO),,] (H.J. Kakkonen, M. Ahlgrén, T.A. Pakkanen and
(J.-F. Carpentier, Y. Castanet, A. Mortreux and F. Petit), 31 J. Pursiainen), 279
Chromium Synthesis and structural studies of phenyl(iodo)- and methyl-
Synthesis of diphosphine-linked binuclear metal-ring carbonyl (phenyl)palladium(II) complexes of bidentate nitrogen donor
complexes (D.A. Brown, I. El-Gamati, W.K. Glass and K. ligands (B.A. Markies, A.J. Canty, W. De Graaf, J. Boersma,
Kreddan), 301 M.D. Janssen, M.P. Hogerheide, W.J.J. Smeets, A.L. Spek
Cluster and G. Van Koten), 191
Synthesis and structural characterization of [N(PPh;),][H,Ru,- Synthesis and structure of silylmethylsilatranes RR’R’SiCH,-
Rh(CO),,] (H.J. Kakkonen, M. Ahlgrén, T.A. Pakkanen and Si(OCH ,CH,),N (V. Gevorgyan, L. Borisova, A. Vjater, J.
J. Pursiainen), 279
Popelis, S. Belyakov and E. Lukevics), 73
Cobalt
Tetrafluoroethyl complexes of iridium(III) derived from a te-
Synthesis and coordination chemistry of tellurium alkynes (H.
trafluoroethylene complex of iridium(1). A study of a-fluoride
Keller, J.C. Daran and H. Lang), 63
abstraction and determination of the structure of IrCl,-
Coupling
(CF,CF,CIMCOXPPh;), (A.K. Burrell, G.R. Clark, C.E.F.
Synthesis of trans-arylvinylboronates via a palladium catalysed
Rickard and W.R. Roper), 261
C6
CS, complexes Fluorine
Studies of the reactivity towards insertion and electrophilic pro- Tetrafluoroethyl complexes of iridium(III) derived from a te-
cesses of Nb-H and Nb(n?-CS,) moieties of bis(trimethyl- trafluoroethylene complex of iridium(1). A study of a-fluoride
silylcyclopentadienyl)niobium complexes (A. Antinolo, F. Car- abstraction and determination of the structure of IrCl,-
rillo, M. Fajardo, S. Garcia-Yuste and A. Otero), 93 (CF,CF,CIMCOXPPh;), (A.K. Burrell, G.R. Clark, C.E.F.
Cycloaddition Rickard and W.R. Roper), 261
1,3-Dipolar cycloaddition to the C=X-—M fragment. 13. Regiose- Fluoroalkyl
lectivity in the reactions of mononuclear iminoketone com- Tetrafluoroethyl complexes of iridium(III) derived from a te-
plexes Fe(CO),(‘Bu-N=C(H)-—C(R)=O) (R = Ph, Me) with the trafluoroethylene complex of iridium(I). A study of a-fluoride
asymmetric alkyne methyl propynoate (M. Van Wijnkoop, R. abstraction and determination of the structure of IrCl,-
Siebenlist, J.M. Ernsting, P.P.M. De Lange, H.-W. Fruhauf, (CF,CF,CIMCOPPh,), (A.K. Burrell, G.R. Clark, C.E.F.
E. Horn and A.L. Spek), 99 Rickard and W.R. Roper), 261
Cyclopentadienyl
Germanium
n>-Pentabenzylcyclopentadienyl derivatives of titanium (IV), (IID),
Cyclotrigermanes. Synthesis and thermal decomposition (T.
and (II). The crystal structures of (n°-C;H;X7°-C;Bz,)TiCl,
(Bz = benzyl), (n°-C;H;X7°-C;Bz,)TiCl, and (n°-C;H;X>- Tsumuraya, Y. Kabe and W. Ando), 131
Synthesis _and structure of silylmethylsilatranes RR’R’SiCH,-
C;Bz;)Tiln?-(CSiMe;)>] (G. Schmid, U. Thewalt, M. PolaSek,
K. Mach and P. Sedmera), 231 Si(OCH ;CH »)4N (V. Gevorgyan, L. Borisova, A. Vjater, J.
Is electrophilic substitution possible in the coordinated cyclopen- Popelis, S. Belyakov and E. Lukevics), 73
tadienyl ligand of early transition metal metallocene com- Group 5
plexes? Molecular structure of binuclear nitrene niobocene Is electrophilic substitution possible in the coordinated cyclopen-
complex [(C;H,C(COOEt)}=N-u-N)(C5H;)Nb], (G.I. tadienyl ligand of early transition metal metallocene com-
Nikonov, M. Putala, N.B. Kazennova, D.A. Lemenovskii, A.S. plexes? Molecular structure of binuclear nitrene niobocene
Batsanov and Yu.T. Struchkov), 187 complex [(C;H,C(COOEt)=N-u-N )-(C5H5)Nb], (G.I.
Cyclopentadienyl complexes Nikonov, M. Putala, N.B. Kazennova, D.A. Lemenovskii, A.S.
Studies of the reactivity towards insertion and electrophilic pro- Batsanov and Yu.T. Struchkov), 187
cesses of Nb-H and Nb(7?-CS,) moieties of bis(trimethyl-
Hammet correlation
silylcyclopentadienyl)niobium complexes (A. Antifolo, F. Car-
Bismuth(III)-catalyzed oxidative cleavage of aryl epoxides: sub-
rillo, M. Fajardo, S. Garcia-Yuste and A. Otero), 93
stituent effects on the kinetics of the oxidation reaction (V.
Cyclotadiene
Le Boisselier, E.D unach and M. Postel), 119
Formation of stable cationic (cyclooctadiene)Rhodium(I) com-
Homogeneous catalysis
plexes containing thiophene ligands (J.R. Polam and L.C.
Hydrogenolysis of carbon—chlorine bonds in carbon tetrachloride
Porter), 1
and trichlorofluoromethane in the presence of catalytic quan-
tities of tris(triphenylphosphine) ruthenium(II) dichloride (S.
Diacetyl complex
Xie, E.M. Georgiev, D.M. Roundhill and K. Troev), 39
Bimetallic reactivity: unusual change in the coordination mode of
Hydrazine
the bridging ligands arising from an oxidative addition process
Lithium-bis(silyl)hydrazide, Tris(sily)Jhydrazine und 1,2-Diaza-
(M.A. Ciriano, J.J. Pérez-Torrente, F.J. Lahoz and L.A. Oro),
53 3,5-disilacyclopentane (K. Bode, C. Drost, C. Jager, U.
Klingebiel, M. Noltemeyer und Z. Zak), 285
Dihydrogen
Hydride
Effects of chelate ring rigidity on intramolecular hydrogen ex-
change in hydrido(dihydrogen)bis(diphosphine)ruthenium(II) Effects of chelate ring rigidity on intramolecular hydrogen ex-
change in hydrido(dihydrogen)bis(diphosphine)ruthenium(II)
ions [RuH, (Xdip?hos-phinHe), ]* (diphosphine = binap and
ions [RuH(n?-H ,diphosphine),]* (diphosphine = binap and
dpbp) (M. Ogasawara and M. Saburi), 7
dpbp) (M. Ogasawara and M. Saburi), 7
Diimine
Hydrides
Coordination of the potentially tridentate ligands 2,6-diacetyl-
pyridine-bis(anil) (dapa) and 2-(2-(2’-methylidenepyridyl)- Studies of the reactivity towards insertion and electrophilic pro-
cesses of Nb-H and Nb(n?-CS,) moieties of bis(trimethyl-
aminoethyl)pyridine (map) in the complexes fac-BrMn-
(CO),L, fac-(CO);MM’(CO),L (M, M’ = Mn, Re; L = dapa, silylcyclopentadienyl)niobium complexes (A. Antifolo, F. Car-
rillo, M. Fajardo, S. Garcia-Yuste and A. Otero), 93
map) and their photoproducts. The crystal structure of
BrMn(CO),(N,N,N-dapa) (G.J. Stor, M. Van der Vis, D.J. Hydroboration
Hydroboration of carbon-—tungsten triple bonds: crystal structures
Stufkens, A. Oskam, J. Fraanje and K. Goubitz), 15
of the 1°-benzyl complexes (y-C;H;)CO),W{n?-CH-
Diphosphine
[B(C,H5).]C,H4Me-4} and (n-C;Me;CO),W{n?-CH-
Effects of chelate ring rigidity on intramolecular hydrogen ex-
[B(C,H5).]C,H,Me-4} (H. Wadepohl, G.P. Elliott, H.
change in hydrido(dihydrogen)bis(diphosphine)ruthenium(II)
Pritzkow, F.G.A. Stone and A. Wolf), 243
ions [RuH(n?-H, Xdiphosphine),]* (diphosphine = binap and
dpbp) (M. Ogasawara and M. Saburi), 7 Hydrogen bonding
Synthesis and structure of silylmethylsilatranes RR’R’SiCH,-
Synthesis of diphosphine-linked binuclear metal—ring carbonyl
complexes (D.A. Brown, I. El-Gamati, W.K. Glass and K. §i(OCH ;CH,)3N (V. Gevorgyan, L. Borisova, A. Vjater, J.
Kreddan), 301 Popelis, S. Belyakov and E. Lukevics), 73
Disorder Hydrogen exchange
Crystallographic disorder of carbonyl, propyl isocyanide and ace- Effects of chelate ring rigidity on intramolecular hydrogen ex-
tonitrile groups in the structures of Os ,(CO),)(CNRMNCMe) change in hydrido(dihydrogen)bis(diphosphine)ruthenium(D
(K.-L. Lu, L.-K. Liu, C.-J. Su, H.-M. Gau, Y. Wang and G.-H. ions [RuH(?-H ,(diphosphine),]* (diphosphine = binap and
Lee), 67 dpbp) (M. Ogasawara and M. Saburi), 7
Hydrogenolysis Lithium
Hydrogenolysis of carbon-chlorine bonds in carbon tetrachloride Lithium-bis(silyDhydrazide, Tris(silyl)hydrazine und 1,2-Diaza-
and trichlorofluoromethane in the presence of catalytic quan- 3,5-disilacyclopentane (K. Bode, C. Drost, C. Jager, U.
tities of tris(triphenylphosphine) ruthenium(II) dichloride (S. Klingebiel, M. Noltemeyer und Z. Zak), 285
Xie, E.M. Georgiev, D.M. Roundhill and K. Troev), 39
Insertion Manganese
Studies of the reactivity towards insertion and electrophilic pro- Coordination of the potentially tridentate ligands 2,6-diacetyl-
cesses of Nb-H and Nb(n?-CS,) moieties of bis(trimethyl- pyridine-bis(anil) (dapa) and 2-(2(2’-methylidenepyridy))-
silylcyclopentadienyl)niobium complexes (A. Antifolo, F. Car- aminoethyl)pyridine (map) in the complexes fac-BrMn-
rillo, M. Fajardo, §. Garcia-Yuste and A. Otero), 93 (CO);,L, fac-(CO);MM'(CO),L (M, M’ =Mn, Re; L =dapa,
Iridium map) and their photoproducts. The crystal structure of
Tetrafluoroethyl complexes of iridium(III) derived from a te- BrMn(CO),(N,N,N-dapa) (G.J. Stor, M. Van der Vis, D.J.
trafluoroethylene complex of iridium(I). A study of a-fluoride Stufkens, A. Oskam, J. Fraanje and K. Goubitz), 15
abstraction and determination of the structure of IrCl,- Photomicrocalorimetry: photosubstitution of carbonyl by phos-
(CF,CF,CIMCOMPPh;), (A.K. Burrell, G.R. Clark, C.E.F. phites in [Mn(n>-C;H,CH,(CO)3 ] (P.B. Dias, C. Teixeira,
Rickard and W.R. Roper), 261 A.R. Dias, J. De Alencar Simoni and J.A. Martinho SimGes),
Iron 111
1,3-Dipolar cycloaddition to the C=X-—M fragment. 13. Regiose- Synthesis of diphosphine-linked binuclear metal-ring carbonyl
lectivity in the reactions of mononuclear iminoketone com- complexes (D.A. Brown, I. El-Gamati, W.K. Glass and K.
plexes Fe(CO),(' Bu-N=C(H)—C(R)=O) (R = Ph, Me) with the Kreddan), 301
asymmetric alkyne methyl propynoate (M. Van Wijnkoop, R. Mechanism
Siebenlist, J.M. Ernsting, P.P.M. De Lange, H.-W. Friihauf, Carbonylation of bromobenzene in a biphasic medium catalysed
E. Horn and A.L. Spek), 99 by water-soluble palladium complexes derived from tris(G-
Oligosilane mit Fe- oder Mo-Komplexsubstituenten (B. Stadel- sulphophenyl)phosphine (F. Monteil and P. Kalck), 45
mann, P. Lassacher, H. Stiger und E. Hengge), 201 Molybdenum
Solid state studies of some nitrosoaromatic iron carbonyls (M. Kooperative Wirkung in 7-Ligand-verbrickten Zweikernkom-
Cameron, B.G. Gowenlock, R.V. Parish and G. Vasapollo), plexen. XIV. [{(CpM(CO,}, w-(77""-Et, NCSCNEt, )] (M = Mo,
227 W), ein zweikerniger Bis(Fischer-Carben)-Komplex mit einem
Synthesis of diphosphine-linked binuclear metal—ring carbonyl 1,2-Dimetallavierring als zentralem Baustein (J. Heck, K.-A.
complexes (D.A. Brown, I. El-Gamati, W.K. Glass and K. Kriebisch, W. Massa und S. Wocadlo), 81
Kreddan), 301 Oligosilane mit Fe- oder Mo-Komplexsubstituenten (B. Stadel-
Isocyanide mann, P. Lassacher, H. Stiiger und E. Hengge), 201
Crystallographic disorder of carbonyl, propyl isocyanide and ace- Mossbauer spectra
tonitrile groups in the structures of Os 3(CO),,(CNR XNCMe) Solid state studies of some nitrosoaromatic iron carbonyls (M.
(K.-L. Lu, L.-K. Liu, C.-J. Su, H.-M. Gau, Y. Wang and G.-H. Cameron, B.G. Gowenlock, R.V. Parish and G. Vasapollo),
Lee), 67 227
Isomerism
Lithium-bis(silyDhydrazide, Tris(sily)hydrazine und 1,2-Diaza-
3,5-disilacyclopentane (K. Bode, C. Drost, C. Jager, U. Neodymium
Klingebiel, M. Noltemeyer und Z. Zak), 285 2,4-Dimethylpentadienyl complexes of neodymium, samarium and
ytterbium (D. Baudry, F. Nief and L. Ricard), 125
Ketone Niobium
Asymmetrische Katalyse. IV. Hydrosilylierung von Acetophenon Is electrophilic substitution possible in the coordinated cyclopen-
mit Pyrrolin-2,5-dion /-modifizierten [Rh(COD)CI],-Kataly- tadienyl ligand of early transition metal metallocene com-
satoren (A. Tillack, M. Michalik, D. Fenske und H. Goes- plexes? Molecular structure of binuclear nitrene niobocene
mann), 85 complex [(C;H ,C(COOED=N-w-N)-(C5H;)Nb], (G.I.
Nikonov, M. Putala, N.B. Kazennova, D.A. Lemenovskii, A.S.
Lanthanides Batsanov and Yu.T. Struchkov), 187
2,4-Dimethylpentadienyl complexes of neodymium, samarium and Studies of the reactivity towards insertion and electrophilic pro-
ytterbium (D. Baudry, F. Nief and L. Ricard), 125 cesses of Nb-H and Nb(1777-CS,) moieties of bis(trimethyl-
Lanthanoids silylcyclopentadienyl)niobium complexes (A. Antinolo, F. Car-
Phosphinomethanid-Komplexe der Lanthanoide (H.H. Karsch, rillo, M. Fajardo, S. Garcia-Yuste and A. Otero), 93
G. Ferazin, H. Kooijman, O. Steigelmann, A. Schier, P. Nitroso compound
Bissinger und W. Hiller), 151 Solid state studies of some nitrosoaromatic iron carbonyls (M.
Lanthanum Cameron, B.G. Gowenlock, R.V. Parish and G. Vasapollo),
Synthesis and characterisation of metal complexes of ether 227
carbaboranes. Molecular structures of d° ML,, d® ML, and Nuclear magnetic resonance
d'° ML complexes of mono- and di-ether CB, carbaborane Effects of chelate ring rigidity on intramolecular hydrogen ex-
ligands, showing the progressive importance of secondary change in hydrido(dihydrogen)bis(diphosphine)ruthenium(ID)
M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207 ions [RuH(n?-H, Xdiphosphine),]* (diphosphine = binap and
Linked cyclopentadienyl dpbp) (M. Ogasawara and M. Saburi), 7
Synthesis and characterization of bridged half-sandwich amides Solid state studies of some nitrosoaromatic iron carbonyls (M.
of titanium and zirconium (W.A. Herrmann and M.J.A. Cameron, B.G. Gowenlock, R.V. Parish and G. Vasapollo),
Morawietz), 169 227
C8
Oligosilanes Phosphinodithioates
Oligosilane mit Fe- oder Mo-Komplexsubstituenten (B. Stadel- New aryltellurium(I]) diorganophosphinodithioates. Crystal struc-
mann, P. Lassacher, H. Stiiger und E. Hengge), 201 ture of red (294 K) and yellow (173 K) }[PhTeS(S)PPh,], a
Optical resolution supramolecular polymer displaying an unusual coordination
Asymmetrische Katalyse. IV. Hydrosilylierung von Acetophenon pattern of the phosphinodithioato ligand (A. Silvestru, I.
mit Pyrrolin-2,5-dion/-modifizierten [Rh(COD)CI],-Kataly- Haiduc, K.H. Ebert, H.J. Breunig and D.B. Sowerby), 253
satoren (A. Tillack, M. Michalik, D. Fenske und H. Goes- Phosphinomethanides
mann), 85 Phosphinomethanid-Komplexe der Lanthanoide (H.H. Karsch,
Organotin G. Ferazin, H. Kooijman, O. Steigelmann, A. Schier, P.
Structures of 4-tolyl 2-(triphenylstannyl)ethyl sulphone and 4-tolyl Bissinger und W. Hiller), 151
4-(triphenylstannyl)butyl sulphone (P.J. Cox and J.L. Wardell), Phosphite
221 Photomicrocalorimetry: photosubstitution of carbonyl by phos-
Osmium phites in [Mn(n°-C;H,CH,\CO),] (P.B. Dias, C. Teixeira,
Crystallographic disorder of carbonyl, propyl isocyanide and ace- A.R. Dias, J. De Alencar Simoni and J.A. Martinho SimGes),
tonitrile groups in the structures of Os ,(CO),)((CNRNCMe) 111
(K.-L. Lu, L.-K. Liu, C.-J. Su, H.-M. Gau, Y. Wang and G.-H. Photochemistry
Lee), 67 Coordination of the potentially tridentate ligands 2,6-diacetyl-
Reactions of coordinated tetrafluoroethylene with halogens. Syn- pyridine-bis(anil) (dapa) and 2-(2-(2’-methylidenepyridyl)-
thesis of o-bonded halotetrafluoroethyl complexes of ruthe- aminoethyl)pyridine (map) in the complexes fac-BrMn-
nium(II) and osmium(II) and the structure of OsI(C,F,D- (CO),L, fac-(CO);MM’(CO),L (M, M’ = Mn, Re; L = dapa,
(CO),(PPh), (A.K. Burrell, G.R. Clark, C.E.F. Rickard, W.R. map) and their photoproducts. The crystal structure of
Roper and D.C. Ware), 271 BrMn(CO),(N,N,N-dapa) (G.J. Stor, M. Van der Vis, D.J.
Oxidation Stufkens, A. Oskam, J. Fraanje and K. Goubitz), 15
Bismuth(III)-catalyzed oxidative cleavage of aryl epoxides: sub- Cyclotrigermanes. Synthesis and thermal decomposition (T.
stituent effects on the kinetics of the oxidation reaction (V. Tsumuraya, Y. Kabe and W. Ando), 131
Le Boisselier, E.D unach and M. Postel), 119 Photomicrocalorimetry
Oxidative addition Photomicrocalorimetry: photosubstitution of carbonyl by phos-
Bimetallic reactivity: unusual change in the coordination mode of phites in [Mn(n°-C;H,CH,\CO),] (P.B. Dias, C. Teixeira,
the bridging ligands arising from an oxidative addition process A.R. Dias, J. De Alencar Simoni and J.A. Martinho SimGes),
(M.A. Ciriano, J.J. Pérez-Torrente, F.J. Lahoz and L.A. Oro), 111
53 Photosubstitution
Synthesis and structural studies of phenyl(iodo)- and methyl- Photomicrocalorimetry: photosubstitution of carbonyl by phos-
phites in [Mn(n°-C5H,CH;\(CO),] (P.B. Dias, C. Teixeira,
(phenyl)palladium(II) complexes of bidentate nitrogen donor
ligands (B.A. Markies, A.J. Canty, W. De Graaf, J. Boersma, A.R. Dias, J. De Alencar Simoni and J.A. Martinho Simoes),
M.D. Janssen, M.P. Hogerheide, W.J.J. Smeets, A.L. Spek 111
and G. Van Koten), 191 Polymer
New aryltellurium(II) diorganophosphinodithioates. Crystal struc-
Palladium ture of red (294 K) and yellow (173 K) {[PhTeS(S)PPh,], a
Carbonylation of bromobenzene in a biphasic medium catalysed supramolecular polymer displaying an unusual coordination
by water-soluble palladium complexes derived from tris(3- pattern of the phosphinodithioato ligand (A. Silvestru, I.
sulphophenyl)phosphine (F. Monteil and P. Kalck), 45
Haiduc, K.H. Ebert, H.J. Breunig and D.B. Sowerby), 253
Mechanistic investigations of palladium-catalysed single and dou-
ble carbonylation of aryl and vinyl halides by methyl formate Rhenium
(J.-F. Carpentier, Y. Castanet, A. Mortreux and F. Petit), 31 Coordination of the potentially tridentate ligands 2,6-diacetyl-
Synthesis and structural studies of phenyl(iodo)- and methyl- pyridine-bis(anil) (dapa) and 2-(2-(2’-methylidenepyridyl)-
(phenyl)palladium(II) complexes of bidentate nitrogen donor aminoethyl)pyridine (map) in the complexes fac-BrMn-
ligands (B.A. Markies, A.J. Canty, W. De Graaf, J. Boersma, (CO)3L, fac-(CO);MM’(CO),L (M, M’ = Mn, Re; L = dapa,
M.D. Janssen, M.P. Hogerheide, W.J.J. Smeets, A.L. Spek map) and their photoproducts. The crystal structure of
and G. Van Koten), 191 BrMn(CO),(N,N,N-dapa) (G.J. Stor, M. Van der Vis, D.J.
Synthesis of trans-arylvinylboronates via a palladium catalysed Stufkens, A. Oskam, J. Fraanje and K. Goubitz), 15
cross-coupling of a vinylboronate ester with aryl halides (S.K. Rhodium
Stewart and A. Whiting), 293 Asymmetrische Katalyse. IV. Hydrosilylierung von Acetophenon
Palladum mit Pyrrolin-2,5-dion/-modifizierten [Rh(COD)CI],-Kataly-
Synthesis and characterisation of metal complexes of ether satoren (A. Tillack, M. Michalik, D. Fenske und H. Goes-
carbaboranes. Molecular structures of d° ML, d® ML, and mann), 85
d'° ML complexes of mono- and di-ether C,By carbaborane Bimetallic reactivity: unusual change in the coordination mode of
ligands, showing the progressive importance of secondary the bridging ligands arising from an oxidative addition process
M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207 (M.A. Ciriano, J.J. Pérez-Torrente, F.J. Lahoz and L.A. Oro),
Pentadienyl 53
2,4-Dimethylpentadienyl complexes of neodymium, samarium and Formation of stable cationic (cyclooctadiene)Rhodium(I) com-
ytterbium (D. Baudry, F. Nief and L. Ricard), 125 plexes containing thiophene ligands (J.R. Polam and L.C.
Phosphine Porter), 1
Solid state studies of some nitrosoaromatic iron carbonyls (M. Synthesis and characterisation of metal complexes of ether
Cameron, B.G. Gowenlock, R.V. Parish and G. Vasapollo), carbaboranes. Molecular structures of d® ML;, d® ML, and
227 d'° ML complexes of mono- and di-ether C,By carbaborane
C9
ligands, showing the progressive importance of secondary C;Bz;)Tiln?-(CSiMe3)>] (G. Schmid, U. Thewalt, M. PolaSek,
M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207 K. Mach and P. Sedmera), 231
Synthesis and structural characterization of [N(PPh,),][H,Ru;- Hydroboration of carbon-tungsten triple bonds: crystal structures
Rh(CO),>] (H.J. Kakkonen, M. Ahlgrén, T.A. Pakkanen and of the 1°-benzyl complexes (n-C;H;CO),W{n>-CH-
J. Pursiainen), 279 [B(C,H;),]C,H,Me-4} and (n-C,;Me;CO),W{n?-CH-
Ruthenium [B(C,;H;),]C,H,Me-4} (H. Wadepohl, G.P. Elliott, H.
Effects of chelate ring rigidity on intramolecular hydrogen ex- Pritzkow, F.G.A. Stone and A. Wolf), 243
change in hydrido(dihydrogen)bis(diphosphine)ruthenium(I]) Phosphinomethanid-Komplexe der Lanthanoide (H.H. Karsch,
ions [RuH,(X dniph?osp-hinHe),] * (diphosphine = binap and G. Ferazin, H. Kooijman, O. Steigelmann, A. Schier, P.
dpbp) (M. Ogasawara and M. Saburi), 7 Bissinger und W. Hiller), 151
Hydrogenolysis of carbon—chlorine bonds in carbon tetrachloride Substituent effects
and trichlorofluoromethane in the presence of catalytic quan- Bismuth(III])-catalyzed oxidative cleavage of aryl epoxides: sub-
tities of tris(triphenylphosphine) ruthenium(II) dichloride (S. stituent effects on the kinetics of the oxidation reaction (V.
Xie, E.M. Georgiev, D.M. Roundhill and K. Troev), 39 Le Boisselier, E. Dunach and M. Postel), 119
Reactions of coordinated tetrafluoroethylene with halogens. Syn- Supramolecular association
thesis of o-bonded halotetrafluoroethyl complexes of ruthe- New aryltellurium(I]) diorganophosphinodithioates. Crystal struc-
nium(II) and osmium(II) and the structure of OsI(C,F,D- ture of red (294 K) and yellow (173 K) {[PhTeS(S)PPh,], a
(CO),(PPh,), (A.K. Burrell, G.R. Clark, C.E.F. Rickard, W.R. supramolecular polymer displaying an unusual coordination
Roper and D.C. Ware), 271 pattern of the phosphinodithioato ligand (A. Silvestru, I.
Ruthenium(II) o-acetylide complexes; monomers, dimers and Haiduc, K.H. Ebert, H.J. Breunig and D.B. Sowerby), 253
polymers (C.W. Faulkner, S.L. Ingham, M.S. Khan, J. Lewis, Synthesis
N.J. Long and P.R. Raithby), 139 Synthesis and characterization of bridged half-sandwich amides
Synthesis and characterisation of metal complexes of ether of titanium and zirconium (W.A. Herrmann and M.J.A.
carbaboranes. Molecular structures of d®° ML,, d® ML, and Morawietz), 169
d'° ML complexes of mono- and di-ether C,By carbaborane
ligands, showing the progressive importance of secondary Tellurium
M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207 New aryltellurium(I]) diorganophosphinodithioates. Crystal struc-
Synthesis and structural characterization of [N(PPh,),][H,Ru,- ture of red (294 K) and yellow (173 K) '[PhTeS(S)PPh 5], a
Rh(CO),,] (H.J. Kakkonen, M. Ahlgrén, T.A. Pakkanen and supramolecular polymer displaying an unusual coordination
J. Pursiainen), 279 pattern of the phosphinodithioato ligand (A. Silvestru, I.
Haiduc, K.H. Ebert, H.J. Breunig and D.B. Sowerby), 253
Synthesis and coordination chemistry of tellurium alkynes (H.
Samarium
Keller, J.C. Daran and H. Lang), 63
2,4-Dimethylpentadienyl complexes of neodymium, samarium and
Tetrafluorethylene
ytterbium (D. Baudry, F. Nief and L. Ricard), 125
Reactions of coordinated tetrafluoroethylene with halogens. Syn-
Silacylic compounds
thesis of o-bonded halotetrafluoroethyl complexes of ruthe-
Lithium-bis(sily)Jhydrazide, Tris(sily)hydrazine und _ 1,2-Diaza-
nium(II) and osmium(II) and the structure of OsI(C,F,D-
3,5-disilacyclopentane (K. Bode, C. Drost, C. Jager, U.
(CO).(PPh;), (A.K. Burrell, G.R. Clark, C.E.F. Rickard, W.R.
Klingebiel, M. Noltemeyer und Z. Zak), 285
Roper and D.C. Ware), 271
Silane
Tetrazole
Asymmetrische Katalyse. IV. Hydrosilylierung von Acetophenon
Crystal structure of triphenyl(S5-mercapto-1-phenyl-1,2,3,4-tetra-
mit Pyrrolin-2,5-dion/-modifizierten [Rh(COD)CI],-Kataly-
zolato)tin(IV) (J. Bravo, M.B. Cordero, J.S. Casas, A. Sanchez,
satoren (A. Tillack, M. Michalik, D. Fenske und H. Goes-
J. Sordo, E.E. Castellano and J. Zukerman-Schpector), 147
mann), 85
Thermochemistry
Silatrane
Photomicrocalorimetry: photosubstitution of carbonyl by phos-
Synthesis and structure of silylmethylsilatranes RR’R”SiCH,-
phites in [Mn(n°-C;H,CH,CO);] (P.B. Dias, C. Teixeira,
Si(OCH»CH)3N (V. Gevorgyan, L. Borisova, A. Vjater, J.
A.R. Dias, J. De Alencar Simoni and J.A. Martinho Sim6es),
Popelis, S. Belyakov and E. Lukevics), 73
111
Silicon
Thiopenes
Lithium-bis(silyl)hydrazide, Tris(sily)hydrazine und 1,2-Diaza- Formation of stable cationic (cyclooctadiene)Rhodium(I) com-
3,5-disilacyclopentane (K. Bode, C. Drost, C. Jager, U.
plexes containing thiophene ligands (J.R. Polam and L.C.
Klingebiel, M. Noltemeyer und Z. Zak), 285
Porter), 1
Synthesis and reactions of silylcarbamates with bulky substituents
Tin
(M. Mortl, D. Knausz, Zs. Kolos, L. Szakacs and B. Csakvari),
Crystal structure of triphenyl(S5-mercapto-1-phenyl-1,2,3,4-tetra-
183
zolato)tin(IV) (J. Bravo, M.B. Cordero, J.S. Casas, A. Sanchez,
Synthesis and structure of silylmethylsilatranes RR’ R’SiCH,-
J. Sordo, E.E. Castellano and J. Zukerman-Schpector), 147
Si(OCH »CH)3N (V. Gevorgyan, L. Borisova, A. Vjater, J. Ruthenium(II) o-acetylide complexes; monomers, dimers and
Popelis, S. Belyakov and E. Lukevics), 73 polymers (C.W. Faulkner, S.L. Ingham, M.S. Khan, J. Lewis,
Spectroscopy N.J. Long and P.R. Raithby), 139
Oligosilane mit Fe- oder Mo-Komplexsubstituenten (B. Stadel- Structures of 4-tolyl 2-(triphenylstannyl)ethyl sulphone and 4-tolyl
mann, P. Lassacher, H. Stiiger und E. Hengge), 201 4-(triphenylstannyl)butyl sulphone (P.J. Cox and J.L. Wardell),
Structure 221
n>-Pentabenzylcyclopentadienyl derivatives of titanium (IV), (IID, Titanium
and (II). The crystal structures of (7°-C;H;°-C;Bz;)TiCl, n°-Pentabenzylcyclopentadieny! derivatives of titanium (IV), (IID,
(Bz = benzyl), (n°-C;H;°-C;Bzs)TiCl, and (n°-C5;H5X7°- and (II). The crystal structures of (n°-C;H;°-C,Bz;)TiCl,
(Bz = benzyl), (n°-C;H;°-C;Bz;)TiCl, and (n°-C;H;\>-
X-ray crystal structure
C;Bz;)Tiln?-(CSiMe;),] (G. Schmid, U. Thewalt, M. PolaSek, Ruthenium(II) o-acetylide complexes; monomers, dimers and
K. Mach and P. Sedmera), 231 polymers (C.W. Faulkner, S.L. Ingham, M.S. Khan, J. Lewis,
Synthesis and characterization of bridged half-sandwich amides N.J. Long and P.R. Raithby), 139
of titanium and zirconium (W.A. Herrmann and M.J.A. X-ray diffraction
Morawietz), 169 Kooperative Wirkung in 7-Ligand-verbruckten Zweikernkom-
Tungsten plexen. XIV. [(CpM(CO,},4-(y"N'C'=C-NEEtt ,, )] (M = Mo,
Hydroboration of carbon—tungsten triple bonds: crystal structures W), ein zweikerniger Bis(Fischer-Carben)-Komplex mit einem
of the °-benzyl complexes (n-C;H;CO);W{n?-CH- 1,2-Dimetallavierring als zentralem Baustein (J. Heck, K.-A.
[B(C,H,;),]C,H,Me-4} and (n-C;Me,CO),W{n>-CH- Kriebisch, W. Massa und S. Wocadlo), 81
[B(C,H5),]C,;,H,Me-4} (H. Wadepohl, G.P. Elliott, H. Structures of 4-tolyl 2-(triphenylstannyl)ethyl sulphone and 4-tolyl
Pritzkow, F.G.A. Stone and A. Wolf), 243 4-(triphenylstannyl)butyl sulphone (P.J. Cox and J.L. Wardell),
Kooperative Wirkung in 7-Ligand-verbruckten Zweikernkom- 221
plexen. XIV. [{CpM(CO,}, u-(n""'-Et, NC=CNEt,)] (M = Mo, X-ray structure
W), ein zweikerniger Bis(Fischer-Carben)-Komplex mit einem 2,4-Dimethylpentadienyl complexes of neodymium, samarium and
1,2-Dimetallavierring als zentralem Baustein (J. Heck, K.-A. ytterbium (D. Baudry, F. Nief and L. Ricard), 125
Kriebisch, W. Massa und S. Wocadlo), 81 Bimetallic reactivity: unusual change in the coordination mode of
the bridging ligands arising from an oxidative addition process
(M.A. Ciriano, J.J. Pérez-Torrente, F.J. Lahoz and L.A. Oro),
Uranium 53
Synthesis and characterisation of metal complexes of ether Crystal structure of triphenyl(5-mercapto-1-phenyl-1,2,3,4-tetra-
carbaboranes. Molecular structures of d® ML3, d® ML, and zolato)tin(IV) (J. Bravo, M.B. Cordero, J.S. Casas, A. Sanchez,
d'° ML complexes of mono- and di-ether C,B, carbaborane J. Sordo, E.E. Castellano and J. Zukerman-Schpector), 147
ligands, showing the progressive importance of secondary
Ytterbium
M...O bonding (K.F. Shaw, B.D. Reid and A.J. Welch), 207
2,4-Dimethylpentadienyl complexes of neodymium, samarium and
ytterbium (D. Baudry, F. Nief and L. Ricard), 125
Vinyl Zirconium
Synthesis of trans-arylvinylboronates via a palladium catalysed Synthesis and characterization of bridged half-sandwich amides
cross-coupling of a vinylboronate ester with aryl halides (S.K. of titanium and zirconium (W.A. Herrmann and M.J.A.
Stewart and A. Whiting), 293 Morawietz), 169