Table Of Content

Journal of Organometallic Chemistry, 481 (1994) C15—C16 Author Index of Volume 481 Adams, K.J., C9 Henderson, S$.G.D., C9 Ofele, K., 97 Al-Juaid, S., 89 Herdtweck, E., 253 Ogoshi, S., 19 Antinolo, A., 27 Herrmann, W.A., 97, 227, 253 Olbrich, F., 125 Astakhova, N.M., 247 Higgins, T., 63 Ooi, S., 83 Aubert, P., 217 Hitchcock, P.B., 89 Otero, A., 27 Hiiffer, S., 45 Bacqué, E., 167 Huo, S.Q., 235 Pagel, K., 109 Bauer, W., 259 Huy, H.T., 227 Pampaloni, G., 1 Beck, W., 45 Parish, R.V.D., 37 Begley, M.J., 243 Isenburg, T., 153 Patorra, A., 75 Behrendt, A., 153 Pellinghelli, M.A., 173 Berndt, A., 205 Jiménez, J., 37 Peng, S.-M., 143, 183 Bigoli, F., 173 Jones, P.G., 37 Petiaud, R., 7 Birot, M., 167 Pétraud, M., 167 Bonetti, J., 7 Kakiuchi, K., 19 Petrovskii, P.V., 247 Bourgeois, G., 167 Kanai, G., C4 Pillot, J.-P., 167 BroBmer, C., 97 Kazennova, N.B., Cl Podkorytov, I.S., 83 Knoch, F.A., 259 Pohl, D., 259 Cavinato, G., 173 Koelle, U., 1 Polborn, K., 45 Cetinkaya, E., 89 Kohn, R.D., 275 Pornet, J., 217 Chen, S.-B., 183 Koridze, A.A., 247 Priermeier, T., 97, 253 Chi, Y., 143 Kowall, B., 137 Pritzkow, H., 205 Chollet, H., 27 Krym, V.R., 83 Churakov, A.V., Cl Kicikbay, H., 89 Randrianoélina, B., 217 Cinellu, M.A., 195 Kiihn, F.E., 227 Rehder, D., 125 Corrigan, W., 63 Kurosawa, H., 19 Reid, B.D., 283 Cowie, J., C9, 283 Romao, C.C., 227 Cunningham, D., 63 Laguna, A., 37 Rufanov, K.A., Cl Laguna, M., 37 Deobald, B., 205 Lance, M., 69 Sansoni, M., 195 Dolgushin, F.M., 247 Lanfranchi, M., 173 Schumann, H., 275 Dunogués, J., 167 Lappert, M.F., 89 Shang, N.-C., 179 Lee, G.-H., 143, 183 Shiro, M., 83 Ellermann, J., 259 Lemenovskii, D.A., Cl Shyu, S.-G., 143 Elschenbroich, C., 153 Liou, L.-S., 179 Siebert, W., 205 Ephritikhine, M., 69 Llauro, M.-F., 7 Sobota, P., 57 Eujen, R., 75 Lépez-Mardomingo, C., 27 Sowerby, D.B., 243 Lucas, D., 27 Starova, G.L., 83 Fajardo, M., 27 Liigger, T., 189 Steiner, D., 205 Foley, R., 63 Stoccoro, S., 195 Friedrichsen, W., 109 Manassero, M., 195 Struchkov, Yu.T., 247 Manning, A.R., 63 Sun, C.-H., 179 Galakhov, M., 27 McArdle, P., 63 Siissmilch, F., 125 Gil-Sanz, R., 27 McCormick, G.J., C9 Suzuki, A., C4 Gimeno, M.C., 37 Metz, B., 153 Szafert, S., 57 Glanz, M., 275 Michel, A., 7 Gtowiak, T., 57 Miginiac, L., 217 Thiel, W.R., 253 Gondard, C., 7 Minghetti, G., 195 Toniolo, L., 173 Gradoz, P., 69 Mitchell, T.N., 137 Tu, F.-H., 143 Gridnevy, I., C4 Miyaura, N., C4 Tunik, S.P., 83 Moll, M., 259 Hahn, F.E., 189 Mugnier, Y., 27 Vasapollo, G., 173 Harms, K., 153 Verma, R.D., 243 Hauss, J., 205 Nierlich, M., 69 Vig, A., 243 Hemling, H., 275 Nikol’skii, A.B., 83 Vigner, J., 69 C16 Wang, H.-G., 211 Wieser, M., 45 Yanovsky, A.I., 247 Wang, J.-C., 143, 179 Winterfeld, J., 275 Yeh, W.-Y., 183 Wang, J.-T., 211 Wroblewska, M., 57 Yuan, Y.-F., 211 Wang, R.-J., 211 Wu, Y.J., 235 Watanabe, S., 19 Xu, Y.-M., 211 Watmough, J.M.S., 283 Zhang, Y.-W., 211 Welch, A.J., C9, 283 Yamasaki, M., 83 Zhu, Y., 235 Werner, A., 109 Yang, L., 235 Zucca, A., 195 Journal of Organometallic Chemistry, 481 (1994) C17—C24 Subject Index of Volume 481 Addition compound Azobenzonorbornadiene Structure of the silver imidodi(sulphuryl fluoride)—benzene sol- Novel coupling between tricarbonyl(7-azabenzonorbornadiene)i- vate AgN(SO,F),-C;H, (M.J. Begley, D.B. Sowerby, R.D. ron complexes and cyclohexene to form stereospecifically a Verma and A. Vig), 243 (C-5 substituted 7*-cyclohexadiene)Fe(CO), moiety (C.-H Alkoxycarbonyls Sun, N.-C. Shang, L.-S. Liou and J.-C. Wang), 179 Bis(alkoxycarbonyl) complexes of platinum: preparation, reactivity and their role in carbonylation reactions (G. Vasapollo, L. Benzene Toniolo, G. Cavinato, F. Bigoli, M. Lanfranchi and M.A. Structure of the silver imidodi(sulphuryl fluoride)—benzene sol- Pellinghelli), 173 vate AgN(SO,F),-C,H, (M.J. Begley, D.B. Sowerby, R.D. Alkyl complexes Verma and A. Vig), 243 Reactions of hydridovanadium complexes: The formation of seven-coordinated o-alkylvanadium(I1) complexes by hy- Bifunctional ligands Chemie polyfunktioneller Molekiile. CXIII. Komplexe des Di- drovanadation of alkenes, and the molecular structure of trans-[V(CO),(dppe),]-3C,D, (F. Siissmilch, F. Olbrich and cobaltoctacarbonyls mit den Liganden Bis(diphenylphosphino)amin und -amid (D. Pohl, J. Ellermann, F.A. Knoch, D. Rehder), 125 M. Moll und W. Bauer), 259 Alkyne Bis(arene)metals Dark and photochemical reactions of Co,Rh(CO),, with Metal 7 complexes of benzene derivatives. XLIII. Intramolecular diphenylacetylene. Crystal and molecular structure of the Co;Rh(u. — CO), (CO)(u4,n? — PhC,Ph) cluster (S.P. Tu- interactions between bis(benzene)chromium and cymantrene units in di- and tri-nuclear species containing PMe, spacers, nik, V.R. Krym, G.L. Starova, A.B. Nikol’skii, I.S. Podkory- as studied by CV and EPR (C. Elschenbroich, T. Isenburg, B. tov, S. Ooi, M. Yamasaki and M. Shiro), 83 Metz, A. Behrendt and K. Harms), 153 Alkyne complexes Boron Synthesis, electrosynthesis and structural studies of bis(silylcy- Steric effects in heteroboranes. Part 8. Sterically-induced Exo- clopentadienyl)niobium complexes with acetylene ligands (A. skeletal isomerisation of di-copper carbametallaboranes: syn- Antinolo, A. Otero, M. Fajardo, M. Galakhov, R. Gil-Sanz, C. theses and crystal structures of (Ph,PCu),Ph,C,jBH , and Lépez-Mardomingo, D. Lucas, H. Chollet and Y. Mugnier), {(o-tol);PCu},Ph,C,ByHy (KJ. Adams, J. Cowie, S.G.D. 27 Henderson, G.J. McCormick and A.J. Welch), C9 Allyl Synthese und Strukturen von Benzo-tetracarbahexaboran- und Multiple bonds between main-group elements and transition met- 1,3-Dihydro-1,3-diboranaphthalin-Metallkomplexen (B. De- als. CXXXI. Allyl-, vinyl- and related rhenium(VII) trioxides: obald, J. Hauss, H. Pritzkow, D. Steiner, A. Berndt und W. synthesis and degradation (W.A. Herrmann, F.E. Kiihn, C.C. Siebert), 205 Romao and H.T. Huy), 227 Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the Amide copper(I) mediated coupling reaction of Knochel’s (dial- Chemie polyfunktioneller Molekile. CXIII. Komplexe des Di- koxyboryl)methylzinc reagents with propargylic tosylates (I. cobaltoctacarbonyls mit den Liganden Bis(diphenylphos- Gridnev, G. Kanai, N. Miyaura and A. Suzuki), C4 phino)amin und -amid (D. Pohl, J. Ellermann, F.A. Knoch, Boronic acid M. Moll und W. Bauer), 259 Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the Amine copper(I) mediated coupling reaction of Knochel’s (dial- Chemie polyfunktioneller Molekile. CXIII. Komplexe des Di- koxyboryl)methylzinc reagents with propargylic tosylates (I. cobaltoctacarbonyls mit den Liganden Bis(diphenylphos- Gridnev, G. Kanai, N. Miyaura and A. Suzuki), C4 phino)amin und -amid (D. Pohl, J. Ellermann, F.A. Knoch, M. Moll und W. Bauer), 259 Aminomethylation-desilylation Carbaboranes Synthése et protodésilylation de silanes a-alléniques hétérocy- Steric effects in heteroboranes. Part 7. The synthesis and charac- cliques (J. Pornet, P. Aubert, B. Randrianoélina et L. terisation of arene-ruthenium complexes of C-substituted Miginiac), 217 carbaboranes. Molecular structures of 1-Ph-3-(mes)-3,1,2- Arene complexes closo-RuC,ByHj9 (mes = C,H3-1,3,5) and 1-Ph-2-Me-3-(p - Steric effects in heteroboranes. Part 7. The synthesis and charac- cym)-3,1,2-closo-RuC,ByHy (p-cym = C,H,Me-1-'Pr-4), the terisation of arene-ruthenium complexes of C-substituted latter showing an incipient deformation (J. Cowie, B.D. Reid, carbaboranes. Molecular structures of 1-Ph-3-(mes)-3,1,2- J.M.S. Watmough and A.J. Welch), 283 closo-RuC,ByHi9 (m= eC,H;s-1,3 ,5) and 1-Ph-2-Me-3-(p- Carbene cym)-3,1,2-closo-,RByuHCy (p-cym = C,H,Me-1-'Pr-4), the Carbene complexes. XXIV. Preparation and characterization latter showing an incipient deformation (J. Cowie, B.D. Reid, of two enetetramine-derived carbenerhodium(I) chloride J.M.S. Watmough and A.J. Welch), 283 complexes RhCKL®), and [RhCK(COD)L®] {L® = dCN(Me)Cu(CH),CNMe-o} and the preparation and X-ray diphenylacetylene. Crystal and molecular structure of the structures of the enetetramine L® and its salt [L8[BF,], (E. Co,Rh(u,— CO), (CO)(u4,n? — PhC,Ph) cluster (S.P. Tu- Cetinkaya, P.B. Hitchcock, H. Kugikbay, M.F. Lappert and S. nik, V.R. Krym, G.L. Starova, A.B. Nikol’skii, I.S. Podkory- Al-Juaid), 89 tov, S. Ooi, M. Yamasaki and M. Shiro), 83 Carbon-carbon bond formation Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- Komplexchemie und Mechanismen metallkatalysierter CC-Kup- dition von Carbonylmetallaten an kationische Allyl- und plungsreaktionen. II. Oxidative Addition von Chloraromaten Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, an Pd°-Komplexe: Synthese, Struktur und Stabilitat von Aryl- Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und palladium(II)-chloriden der Phosphanreihe (W.A. Herrmann, vierkernige Komplexe mit o,7-Allyl- und o,a-Alken-Briicken C. BroBmer, T. Priermeier und K. Ofele), 97 (S. Huffer, M. Wieser, K. Polborn und W. Beck), 45 Carbonyl Komplexe des 2-(Trimethylsiloxy)phenylisocyanids als Vorstufen Chemical and electrochemical studies on metal carbonyl/ fur die Darstellung von N,O-Heterocarben-Komplexen (F.E. cobaltocene systems (G. Pampaloni and U. Koelle), 1 Hahn und T. Ligger), 189 Dark and photochemical reactions of Co,Rh(CO),, with Synthese und Strukturen von Benzo-tetracarbahexaboran- und diphenylacetylene. Crystal and molecular structure of the 1,3-Dihydro-1,3-diboranaphthalin-Metallkomplexen (B. De- Co,Rh(u — CO), (CO)s(44,n? — PhC,Ph) cluster (S.P. Tu- obald, J. Hauss, H. Pritzkow, D. Steiner, A. Berndt und W. nik, V.R. Krym, G.L. Starova, A.B. Nikol’skii, 1.8. Podkory- Siebert), 205 tov, S. Ooi, M. Yamasaki and M. Shiro), 83 The structure of [(Co(n*-C,H ;)XCO),},SnCl,] in the solid state Novel coupling between tricarbonyl(7-azabenzonorbornadiene)i- (C,H ,9=2,3-dimethylbuta-1,3-diene) (D. Cunningham, T. Hig- ron complexes and cyclohexene to form stereospecifically a gins, P. McArdle, W. Corrigan, R. Foley and A.R. Manning), (C-5 substituted 7*-cyclohexadiene)Fe(CO), moiety (C.-H. 63 Sun, N.-C. Shang, L.-S. Liou and J.-C. Wang), 179 Cobaltocene The structure of [{Co(n*-C,,H ;yXCO),},SnCl,] in the solid state Chemical and electrochemical studies on metal carbonyl/ (C,H ,9=2,3-dimethylbuta-1,3-diene) (D. Cunningham, T. Hig- cobaltocene systems (G. Pampaloni and U. Koelle), 1 gins, P. McArdle, W. Corrigan, R. Foley and A.R. Manning), Complexes 63 Komplexchemie und Mechanismen metallkatalysierter CC-Kup- Carbonylation plungsreaktionen. JII. Phosphol-Komplexe des nuilwertigen Bis(alkoxycarbonyl) complexes of platinum: preparation, reactiv- Palladiums (W.A. Herrmann, W.R. Thiel, T. Priermeier und ity and their role in carbonylation reactions (G. Vasapollo, L. E. Herdtweck), 253 Toniolo, G. Cavinato, F. Bigoli, M. Lanfranchi and M.A. Conjugated heterocyclic dienes Pellinghelli), 173 Synthése et protodésilylation de silanes a-alléniques hétéro- Carborane cycliques (J. Pornet, P. Aubert, B. Randrianoélina et L. Steric effects in heteroboranes. Part 8. Sterically-induced Exo- Miginiac), 217 skeletal isomerisation of di-copper carbametallaboranes: syn- Copper theses and crystal structures of (Ph,PCu),Ph,C,HBy and Steric effects in heteroboranes. Part 8. Sterically-induced Exo- {(o-tol);PCu},Ph,C,jBH , (KJ. Adams, J. Cowie, S.G.D. skeletal isomerisation of di-copper carbametallaboranes: syn- Henderson, G.J. McCormick and A.J. Welch), C9 theses and crystal structures of (Ph,PCu),Ph,C,BHy and Catalysis {(0-tol);PCu},Ph,C,ByHy (KJ. Adams, J. Cowie, S$.G.D. Komplexchemie und Mechanismen metallkatalysierter CC-Kup- Henderson, G.J. McCormick and A.J. Welch), C9 plungsreaktionen. II. Oxidative Addition von Chloraromaten Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the an Pd’-Komplexe: Synthese, Struktur und Stabilitat von Aryl- copper(1) mediated coupling reaction of Knochel’s (dial- palladium(II)-chloriden der Phosphanreihe (W.A. Herrmann, koxyboryl)methylzinc reagents with propargylic tosylates (I. C. BroBmer, T. Priermeier und K. Ofele), 97 Gridnev, G. Kanai, N. Miyaura and A. Suzuki), C4 Chromium Coupling Metal 7 complexes of benzene derivatives. XLIII. Intramolecular Novel coupling between tricarbonyl(7-azabenzonorbornadiene)i- interactions between bis(benzene)chromium and cymantrene ron complexes and cyclohexene to form stereospecifically a units in di- and tri-nuclear species containing PMe, spacers, (C-5 substituted 1*-cyclohexadiene)Fe(CO), moiety (C.-H. as studied by CV and EPR (C. Elschenbroich, T. Isenburg, B. Sun, N.-C. Shang, L.-S. Liou and J.-C. Wang), 179 Metz, A. Behrendt and K. Harms), 153 Coupling reaction Cluster Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the Dark and photochemical reactions of Co;Rh(CO),. with copper(I) mediated coupling reaction of Knochel’s (dial- diphenylacetylene. Crystal and molecular structure of the koxyboryl)methylzinc reagents with propargylic tosylates (1. Co,Rh(u,— CO), (CO),.(u4,n? — PhC,Ph) cluster (S.P. Tu- Gridnev, G. Kanai, N. Miyaura and A. Suzuki), C4 nik, V.R. Krym, G.L. Starova, A.B. Nikol’skii, I.S. Podkory- Crosslinking tov, S. Ooi, M. Yamasaki and M. Shiro), 83 Formation of dimeric 1-alkoxy-3-acyloxytetrabutyldistannoxanes Cobalt by reaction of dibutyltin oxide with esters. I. Characterization Chemical and electrochemical studies on metal carbonyl/ in solution by multinuclear NMR spectroscopy and applica- cobaltocene systems (G. Pampaloni and U. Koelle), 1 tion to polymer crosslinking (J. Bonetti, C. Gondard, R. Chemie polyfunktioneller Molekule. CXIII. Komplexe des Di- Petiaud, M.-F. Liauro and A. Michel), 7 cobaltoctacarbonyls mit den Liganden Bis(diphenylphos- Crystal structure phino)amin und -amid (D. Pohl, J. Ellermann, F.A. Knoch, Carbene complexes. XXIV. Preparation and characterization M. Moll und W. Bauer), 259 of two enetetramine-derived carbenerhodium(I) chloride Dark and photochemical reactions of Co,Rh(CO),. with complexes RhCIK(L®), and [RhCK(COD)L®] {L® = dCN(Me)Cu(CH),CNMe-o} and the preparation and X-ray Dichiorodisilazanes structures of the enetetramine L® and its salt [L8][BF,], (E. Synthesis and chemical properties of 1,3-dichloro-1,3-dihy- Cetinkaya, P.B. Hitchcock, H. Kiiciikbay, M.F. Lappert and S. dridodisilazanes (E. Bacqué, J.-P. Pillot, M. Birot, J. Al-Juaid), 89 Dunogués, G. Bourgeois and M. Pétraud), 167 Chemie polyfunktioneller Molekiile. CXIII. Komplexe des Di- Dihydridodisilazanes cobaltoctacarbonyls mit den Liganden Bis(diphenylphos- Synthesis and chemical properties of 1,3-dichloro-1,3-dihy- phino)amin und -amid (D. Pohl, J. Ellermann, F.A. Knoch, dridodisilazanes (E. Bacqué, J.-P. Pillot, M. Birot, J. M. Moll und W. Bauer), 259 Dunogués, G. Bourgeois and M. Pétraud), 167 Cyclometallation of ferrocenylimines. Part II. Studies on the Diimine cyclomercuration of [1-(arylimino)ethyl] ferrocenes and re- A useful method in organotin chemistry: diimine hydrogenation lated structure-reactivity relationships (Y.J. Wu, S.Q. Huo, Y. of 1,2-bis(trimethylstannyl)-l-alkenes, 1-trimethylsilyl-2-tri- Zhu and L. Yang), 235 methylstannyl-l-alkenes and some _ distannacyclopentenes Komplexchemie und Mechanismen metallkatalysierter CC-Kup- (T.N. Mitchell and B. Kowall), 137 plungsreaktionen. II. Oxidative Addition von Chloraromaten Dinuclear an Pd°-Komplexe: Synthese, Struktur und Stabilitaét von Aryl- Asymmetric monocationic and dicationic gold(II) complexes: X- palladium(II)-chloriden der Phosphanreihe (W.A. Herrmann, ray structure of [MePh,PAu(CH,PPh,CH,),AuOH,|K(Cl- C. BroBmer, T. Priermeier und K. Ofele), 97 O,)2*2CH,Cl,*H,0 (M.C. Gimeno, J. Jiménez, A. Laguna, Steric effects in heteroboranes. Part 7. The synthesis and charac- M. Laguna, P.G. Jones and R.V.D. Parish), 37 terisation of arene-ruthenium complexes of C-substituted Dimeric uranium complexes with bridging phospholyl ligands. carbaboranes. Molecular structures of 1-Ph-3-(mes)-3,1,2- Crystal structure of [{U(m°-C4Me,P)u-n>,n!-C,Me,P)- closo-RuC,ByHig (mes = C,H3-1,3,5) and 1-Ph-2-Me-3-(p- (BH ,)},] (P. Gradoz, M. Ephritikhine, M. Lance, J. Vigner cym)-3,1,2-closo-RuC,ByHy (p-cym = C,H,Me-1-'Pr-4), the and M. Nierlich), 69 latter showing an incipient deformation (J. Cowie, B.D. Reid, Diolefin J.M.S. Watmough and A.J. Welch), 283 The structure of [(Co(n9* XC-O)>C},,SnCHl, ] in the solid state Structure of the silver imidodi(sulphury! fluoride)—benzene sol- (C,H ,9=2,3-dimethylbuta-1,3-diene) (D. Cunningham, T. Hig- vate AgN(SO,F),-C,H, (M.J. Begley, D.B. Sowerby, R.D. gins, P. McArdle, W. Corrigan, R. Foley and A.R. Manning), Verma and A. Vig), 243 63 The structure of [{Co(n*-C,,H,)CO)>},SnCl,] in the solid state Dysprosium (C,H ,9=2,3-dimethylbuta-1,3-diene) (D. Cunningham, T. Hig- Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- gins, P. McArdle, W. Corrigan, R. Foley and A.R. Manning), these und Strukturaufklarung neuer Cyclooctatetraenyl- 63 cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. Cyclic voltammetry Schumann, J. Winterfeld, M. Glanz, R.D. K6hn und H. Hem- Synthesis, electrosynthesis and structural studies of bis(silyl- ling), 275 cyclopentadienyl)niobium complexes with acetylene ligands (A. Antinolo, A. Otero, M. Fajardo, M. Galakhov, R. Gil-Sanz, C. L6pez-Mardomingo, D. Lucas, H. Chollet and Y. Mugnier), Electrochemistry 27 Chemical and electrochemical studies on metal carbonyl/ Cyclohexane cobaltocene systems (G. Pampaloni and U. Koelle), 1 Novel coupling between tricarbonyl(7-azabenzonorbornadiene)i- Metal 7 complexes of benzene derivatives. XLIII. Intramolecular ron complexes and cyclohexene to form stereospecifically a interactions between bis(benzene)chromium and cymantrene (C-5 substituted 7*-cyclohexadiene)Fe(CO), moiety (C.-H. units in di- and tri-nuclear species containing PMe, spacers, Sun, N.-C. Shang, L.-S. Liou and J.-C. Wang), 179 as studied by CV and EPR (C. Elschenbroich, T. Isenburg, B. Cyclometallation Metz, A. Behrendt and K. Harms), 153 Cyclometallation of ferrocenylimines. Part II. Studies on the Electron spin resonance cyclomercuration of [1-(arylimino)ethyl] ferrocenes and re- Metal 7 complexes of benzene derivatives. XLIII. Intramolecular lated structure-reactivity relationships (Y.J. Wu, S.Q. Huo, Y. interactions between bis(benzene)chromium and cymantrene Zhu and L. Yang), 235 units in di- and tri-nuclear species containing PMe, spacers, Six-membered cyclometallated derivatives of platinum(II) derived as studied by CV and EPR (C. Elschenbroich, T. Isenburg, B. from 2-benzylpyridines. Crystal and molecular structure of Metz, A. Behrendt and K. Harms), 153 [Pt(L(Ph;P)Cl] (CHL = 2-(1-methylbenzyl)pyridine) (G. Enetetramine Minghetti, A. Zucca, S. Stoccoro, M.A. Cinellu, M. Man- Carbene complexes. XXIV. Preparation and characterization assero and M. Sansoni), 195 of two enetetramine-derived carbenerhodium(1) chloride Cyclopentadienyl complexes RhCKL®), and [RhCKCOD)L®] {L® = Synthesis of the novel bifunctional ligand, dicyclopentadienylsul- dCN(Me)Cu(CH),CNMe-o} and the preparation and X-ray fide (C;H;),S, and its dilithium salt (K.A. Rufanov, A.V. structures of the enetetramine L® and its salt [L8][BF,], (E. Churakov, N.B. Kazennova and D.A. Lemenovskii), C1 Cetinkaya, P.B. Hitchcock, H. Kiciikbay, M.F. Lappert and S. Al-Juaid), 89 Ferrocene Destannylation Ferrocene und Ferrocenophane mit dipolaren Strukturelementen Synthesis of 7%-2-stannylmethylallylpalladium complexes and (K. Pagel, A. Werner und W. Friedrichsen), 109 their destannylation leading to trimethylenemethane-pal- Ferrocenophane ladium species (S. Watanabe, S. Ogoshi, K. Kakiuchi and H. Ferrocene und Ferrocenophane mit dipolaren Strukturelementen Kurosawa), 19 (K. Pagel, A. Werner und W. Friedrichsen), 109 C20 Ferrocenylimine Iridium Cyclometallation of ferrocenylimines. Part II. Studies on the Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- cyclomercuration of [1-(arylimino)ethyl] ferrocenes and re- dition von Carbonylmetallaten an kationische Allyl- und lated structure-reactivity relationships (Y.J. Wu, S.Q. Huo, Y. Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, Zhu and L. Yang), 235 Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und Fluorine vierkernige Komplexe mit o,7-Allyl- und o0,¢-Alken-Briicken Trifluormethyl-substituierte Plumbane—Darstellung, Eigen- (S. Hiiffer, M. Wieser, K. Polborn und W. Beck), 45 schaften und NMR-spektroskopische Charakterisierung von Iron CF,;PbR,H (R = CH;, C,H) sowie von CF; Pb(II)-Derivaten Crystal and molecular structure of N-(ferrocenylcarbonyl)-N’- (R. Eujen und A. Patorra), 75 naphthyl thiourea (J.-T. Wang, Y.-F. Yuan, Y.-M. Xu, Y.-W. Fluxionality Zhang, R.-J. Wang and H.-G. Wang), 211 Steric effects in heteroboranes. Part 8. Sterically-induced Exo- Cyclometallation of ferrocenylimines. Part II. Studies on the skeletal isomerisation of di-copper carbametallaboranes: syn- cyclomercuration of [1-(arylimino)ethyl] ferrocenes and re- theses and crystal structures of (Ph,PCu),Ph,C,)BH y and lated structure-reactivity relationships (Y.J. Wu, S.Q. Huo, Y. {(o-tol),PCu},Ph,C,ByH, (K.J. Adams, J. Cowie, S.G.D. Zhu and L. Yang), 235 Henderson, G.J. McCormick and A.J. Welch), C9 Ferrocene und Ferrocenophane mit dipolaren Strukturelementen (K. Pagel, A.W erner und W. Friedrichsen), 109 Gadolinium Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- dition von Carbonylmetallaten an kationische Allyl- und these und Strukturaufklarung neuer Cyclooctatetraenyl- Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und Schumann, J. Winterfeld, M. Glanz, R.D. Kohn und H. Hem- vierkernige Komplexe mit o,7-Allyl- und o0,o-Alken-Briicken ling), 275 (S. Hiiffer, M. Wieser, K. Polborn und W. Beck), 45 Gold Ligand substitution reaction of (u-H)Os,(CO),9(u-COMe) with Asymmetric monocationic and dicationic gold(II) complexes: X- 1,1’-bis(diphenylphosphino)ferrocene (W.-Y. Yeh, S.-B. Chen, ray structure of [MePh,PAu(CH,PPh,CH,),AuOH,] S.-M. Peng and G.-H. Lee), 183 (ClO,),-2CH,Cl,:H,O (M.C. Gimeno, J. Jiménez, A. La- Novel coupling between tricarbonyl(7-azabenzonorbornadiene)i- guna, M. Laguna, P.G. Jones and R.V.D. Parish), 37 ron complexes and cyclohexene to form stereospecifically a Group 1H (C-5 substituted 7*-cyclohexadiene)Fe(CO), moiety (C.-H. Trifluormethyl-substituierte Plumbane—Darstellung, Eigen- Sun, N.-C. Shang, L.-S. Liou and J.-C. Wang), 179 schaften und NMR-spektroskopische Charakterisierung von Synthese und Strukturen von Benzo-tetracarbahexaboran- und CF,PbR,H (R = CH;, C,H) sowie von CF;Pb(II)-Derivaten 1,3-Dihydro-1,3-diboranaphthalin-Metallkomplexen (B. De- (R. Eujen und A. Patorra), 75 obald, J. Hauss, H. Pritzkow, D. Steiner, A. Berndt und W. Siebert), 205 Heteroboranes Synthesis of the novel bifunctional ligand, dicyclopentadienylsul- fide (C5;H;),S, and its dilithium salt (K.A. Rufanov, A.V. Steric effects in heteroboranes. Part 7. The synthesis and charac- terisation of arene-ruthenium complexes of C-substituted Churakov, N.B. Kazennova and D.A. Lemenovskii), C1 carbaboranes. Molecular structures of 1-Ph-3-(mes)-3,1,2- Isocyanide closo-RuC ,ByH,9 (mes = C,H3-1,3,5) and 1-Ph-2-Me-3-( p- Komplexe des 2-(Trimethylsiloxy)phenylisocyanids als Vorstufen cym)-3,1,2-closo-RuC,B Hy (p-cym = C,H4Me-1-'Pr-4), the fiir die Darstellung von N,O-Heterocarben-Komplexen (F.E. latter showing an incipient deformation (J. Cowie, B.D. Reid, Hahn und T. Liigger), 189 J.M.S. Watmough and A.J. Welch), 283 Lanthanum Heterocycles Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- Ferrocene und Ferrocenophane mit dipolaren Strukturelementen these und Strukturaufklarung neuer Cyclooctatetraenyl- (K. Pagel, A. Werner and W. Friedrichsen), 109 cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. Heterocyclic a-allenylsilanes Schumann, J. Winterfeld, M. Glanz, R.D. Kohn und H. Hem- Synthése et protodésilylation de silanes a-alléniques hétéro- ling), 275 cycliques (J. Pornet, P. Aubert, B. Randrianoélina et L. Lead Miginiac), 217 Trifluormethyl-substituierte Plumbane—Darstellung, Eigen- Hydrogenation schaften und NMR-spektroskopische Charakterisierung von A useful method in organotin chemistry: diimine hydrogenation CF,PbR,H (R = CH;, C,H) sowie von CF;Pb(II)-Derivaten of 1,2-bis(trimethylstannyl)-l-alkenes, 1-trimethylsilyl-2-tri- (R. Eujen und A. Patorra), 75 methylstannyl-l-alkenes and some _ distannacyclopentenes Lilium (T.N. Mitchell and B. Kowall), 137 Ferrocene und Ferrocenophane mit dipolaren Strukturelementen Hydrovanadation (K. Pagel, A. Werner und W. Friedrichsen), 109 Reactions of hydridovanadium complexes: The formation of Lithium seven-coordinated o-alkylvanadium(I) complexes by _hy- Synthesis of the novel bifunctional ligand, dicyclopentadienylsul- drovanadation of alkenes, and the molecular structure of fide (C;H5;),S, and its dilithium salt (K.A. Rufanov, A.V. trans-[V(CO),(dnpe)>]-3C,D, (F. Siissmilch, F. Olbrich and Churakov, N.B. Kazennova and D.A. Lemenovskii), C1 D. Rehder), 125 Lutetium Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- Imidodi(sulphury! fluoride) these und Strukturaufklarung neuer Cyclooctatetraenyl- Structure of the silver imidodi(sulphuryl fluoride)—benzene sol- cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. vate AgN(SO,F),:C,H, (M.J. Begley, D.B. Sowerby, R.D. Schumann, J. Winterfeld, M. Glanz, R.D. Kohn und H. Hem- Verma and A. Vig), 243 ling), 275 Magnesium Osmium The synthesis of olefin polymerization precatalysts: [TiCl (C,H 7- Dimerization of trimethylsilylpropyne on a triosmium cluster. OCH,CO,CH,)} and [(C,H;,O0CH,CO,Et), Mg(p- Formation, crystal structure and rearrangement of Os,H[;- Cl)TiCl,]- 2CH,Cl,. Crystal structures and properties (P. C(SiMe ,)C(Me)CC(SiMe,)C(CHO,) , complex (A.A. Ko- Sobota, M. Wroblewska, S. Szafert and T. Glowiak), 57 ridze, N.M. Astakhova, P.V. Petrovskii, F.M. Dolgushin, A.I. Manganese Yanovsky and Yu.T. Struchkov), 247 Chemical and electrochemical studies on metal carbonyl/ Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- cobaltocene systems (G. Pampaloni and U. Koelle), 1 dition von Carbonylmetallaten an kationische Allyl- und Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, dition von Carbonylmetallaten an kationische Allyl- und Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, vierkernige Komplexe mit o,7-Allyl- und o,a-Alken-Briicken Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und (S. Huffer, M. Wieser, K. Polborn und W. Beck), 45 vierkernige Komplexe mit o,7-Allyl- und o,o-Alken-Briicken Ligand substitution reaction of (u-H)Os,(CO),9(u-COMe) with (S. Hiiffer, M. Wieser, K. Polborn und W. Beck), 45 1,1'-bis(diphenylphosphino)ferrocene (W.-Y. Yeh, S.-B. Chen, Metal 7 complexes of benzene derivatives. XLIII. Intramolecular S.-M. Peng and G.-H. Lee), 183 interactions between bis(benzene)chromium and cymantrene Oxidative addition units in di- and tri-nuclear species containing PMe, spacers, Komplexchemie und Mechanismen metallkatalysierter CC-Kup- as studied by CV and EPR (C. Elschenbroich, T. Isenburg, B. plungsreaktionen. III. Phosphol-Komplexe des nullwertigen Metz, A. Behrendt and K. Harms), 153 Palladiums (W.A. Herrmann, W.R. Thiel, T. Priermeier und Mercury E. Herdtweck), 253 Cyclometallation of ferrocenylimines. Part II. Studies on the cyclomercuration of [1-(arylimino)ethyl] ferrocenes and related structure-reactivity relationships (Y.J. Wu, S.Q. Huo, Y. Zhu and L. Yang), 235 Palladium Metallacarborane Komplexchemie und Mechanismen metallkatalysierter CC-Kup- Steric effects in heteroboranes. Part 8. Sterically-induced Exo- plungsreaktionen. III. Phosphol-Komplexe des nullwertigen skeletal isomerisation of di-copper carbametallaboranes: syn- Palladiums (W.A. Herrmann, W.R. Thiel, T. Priermeier und theses and crystal structures of (Ph,PCu),Ph,C,B,Hy and E. Herdtweck), 253 {(0-tol),;PCu},Ph,C,ByH, (K.J. Adams, J. Cowie, S.G.D. Komplexchemie und Mechanismen metallkatalysierter CC-Kup- Henderson, G.J. McCormick and A.J. Welch), C9 plungsreaktionen. II. Oxidative Addition von Chloraromaten Molybdenum an Pd°-Komplexe: Synthese, Struktur und Stabilitat von Aryl- Synthesis and properties of mixed-metal phosphido and phos- palladium(II)-chloriden der Phosphanreihe (W.A. Herrmann, phinidene clusters derived from reaction between Ru,(CO),o- C. BroBmer, T. Priermeier und K. Ofele), 97 (4-H u-PPh,) and Cp*Mo(CO),;H (J.-C. Wang, Y. Chi, S.-M. Komplexe des 2-(Trimethylsiloxy)phenylisocyanids als Vorstufen Peng, G.-H. Lee, S.-G. Shyu and F.-H. Tu), 143 fiir die Darstellung von N,O-Heterocarben-Komplexen (F.E. Mossbauer Hahn und T. Liigger), 189 Asymmetric monocationic and dicationic gold(I]) complexes: X- Synthesis of 7°-2-stannylmethylallylpalladium complexes and ray structure of [MePh,PAu(CH,PPh,CH,),AuO,Hj ]- their destannylation leading to trimethylenemethane-pal- (ClO,)2-2CH,Cl,:H,0 (M.C. Gimeno, J. Jiménez, A. La- ladium species (S. Watanabe, S. Ogoshi, K. Kakiuchi and H. guna, M. Laguna, P.G. Jones and R.V.D. Parish), 37 Kurosawa), 19 Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the copper(I) mediated coupling reaction of Knochel’s (dial- koxyboryl)methylzinc reagents with propargylic tosylates (I. Naphthyl Gridnev, G. Kanai, N. Miyaura and A. Suzuki), C4 Crystal and molecular structure of N-(ferrocenylcarbonyl)-N’- Phosphane naphthyl thiourea (J.-T. Wang, Y.-F. Yuan, Y.-M. Xu, Y.-W. Chemie polyfunktioneller Molekiile. CXIII. Komplexe des Di- Zhang, R.-J. Wang and H.-G. Wang), 211 cobaltoctacarbonyls mit den Liganden Bis(diphenylphos- Neodymium phino)amin und -amid (D. Pohl, J. Ellermann, F.A. Knoch, Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- M. Moll und W. Bauer), 259 these und Strukturaufklarung neuer Cyclooctatetraenyl- Phosphane ligands cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. Reactions of hydridovanadium complexes: The formation of Schumann, J. Winterfeld, M. Glanz, R.D. Kohn und H. Hem- seven-coordinated o-alkylvanadium(1) complexes by hy- ling), 275 drovanadation of alkenes, and the molecular structure of Niobium trans-[V(CO).(dppe)>]-3C,D, (F. Siissmilch, F. Olbrich and Synthesis, electrosynthesis and structural studies of bis(silyl- D. Rehder), 125 cyclopentadienyl)niobium complexes with acetylene ligands Phosphido (A. Antinolo, A. Otero, M. Fajardo, M. Galakhov, R. Gil-Sanz, Synthesis and properties of mixed-metal phosphido and phos- C. Lépez-Mardomingo, D. Lucas, H. Chollet and Y. Mugnier), phinidene clusters derived from reaction between Ru ,(CO),o- 27 (u-H)\(u-PPh,) and Cp* Mo(CO),H (J.-C. Wang, Y. Chi, S.-M. NMR Peng, G.-H. Lee, S.-G. Shyu and F.-H. Tu), 143 Formation of dimeric 1-alkoxy-3-acyloxytetrabutyldistannoxanes Phosphines by reaction of dibutyltin oxide with esters. I. Characterization Bis(alkoxycarbonyl) complexes of platinum: preparation, reactiv- in solution by multinuclear NMR spectroscopy and applica- ity and their role in carbonylation reactions (G. Vasapollo, L. tion to polymer crosslinking (J. Bonetti, C. Gondard, R. Toniolo, G. Cavinato, F. Bigoli, M. Lanfranchi and M.A. Petiaud, M.-F. Llauro and A. Michel), 7 Pellinghelli), 173 C22 Phosphinidene Propargylic-bis-trimethylsilanes Synthesis and properties of mixed-metal phosphido and phos- Synthése et protodésilylation de silanes a-alléniques hétéro- phinidene clusters derived from reaction between Ru ,(CO),9- cycliques (J. Pornet, P. Aubert, B. Randrianoélina et L. (u-HXu-PPh,) and Cp*Mo(CO),H (J.-C. Wang, Y. Chi, S.-M. Miginiac), 217 Peng, G.-H. Lee, S.-G. Shyu and F.-H. Tu), 143 Pyrazolo[1,2-a]pyrazoolates Phosphole Ferrocene und Ferrocenophane mit dipolaren Strukturelementen Komplexchemie und Mechanismen metallkatalysierter CC-Kup- (K. Pagel, A. Werner und W. Friedrichsen), 109 plungsreaktionen. III. Phosphol-Komplexe des nullwertigen Rhenium Palladiums (W.A. Herrmann, W.R. Thiel, T. Priermeier und Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- E. Herdtweck), 253 dition von Carbonylmetallaten an kationische Allyl- und Phospholyl complexes Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, Dimeric uranium complexes with bridging phospholyl ligands. Crystal structure of [{U(°-C,Me,P\u-n>,n'-C,Me,P)- Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und vierkernige Komplexe mit o,7r-Allyl- und o,a-Alken-Briicken (BH ,)},] (P. Gradoz, M. Ephritikhine, M. Lance, J. Vigner (S. Huffer, M. Wieser, K. Polborn und W. Beck), 45 and M. Nierlich), 69 Multiple bonds between main-group elements and transition met- Phosphorus als. CXXXI. Allyl-, vinyl- and related rhenium(VII) trioxides: Komplexchemie und Mechanismen metallkatalysierter CC-Kup- synthesis and degradation (W.A. Herrmann, F.E. Kiihn, C.C. plungsreaktionen. III. Phosphol-Komplexe des nullwertigen Romao and H.T. Huy), 227 Palladiums (W.A. Herrmann, W.R. Thiel, T. Priermeier und Rhodium E. Herdtweck), 253 Carbene complexes. XXIV. Preparation and characterization Photochemistry Dark and photochemical reactions of Co,;Rh(CO),, with of two enetetramine-derived carbenerhodium(I) chloride complexes RhCKL®), and [RhCKCOD)L®] {L® = diphenylacetylene. Crystal and molecular structure of the Co,Rh(u— CO), (CO)(u4,n? — PhC,Ph) cluster (S.P. Tu- dCN(Me)Cu(CH),CNMe-o} and the preparation and X-ray structures of the enetetramine L® and its salt [L8][BF,], (E. nik, V.R. Krym, G.L. Starova, A.B. Nikol’skii, I.S. Podkory- Cetinkaya, P.B. Hitchcock, H. Kiigiikbay, M.F. Lappert and S. tov, S. Ooi, M. Yamasaki and M. Shiro), 83 Al-Juaid), 89 Platinum Dark and photochemical reactions of Co,Rh(CO),, with Bis(alkoxycarbonyl) complexes of platinum: preparation, reactiv- diphenylacetylene. Crystal and molecular structure of the ity and their role in carbonylation reactions (G. Vasapollo, L. Co,Rh(u>— CO), (CO),(u4,n? — PhCPh) cluster (S.P. Tu- Toniolo, G. Cavinato, F. Bigoli, M. Lanfranchi and M.A. nik, V.R. Krym, G.L. Starova, A.B. Nikol’skii, 1.8. Podkory- Pellinghelli), 173 tov, S. Ooi, M. Yamasaki and M. Shiro), 83 Six-membered cyclometallated derivatives of platinum(II) derived Synthese und Strukturen von Benzo-tetracarbahexaboran- und from 2-benzylpyridines. Crystal and molecular structure of 1,3-Dihydro-1,3-diboranaphthalin-Metallkomplexen (B. De- [Pt(LXPh,P)Cl] (HL = 2-(1-methylbenzyl)pyridine) (G. obald, J. Hauss, H. Pritzkow, D. Steiner, A. Berndt und W. Minghetti, A. Zucca, S. Stoccoro, M.A. Cinellu, M. Man- Siebert), 205 assero and M. Sansoni), 195 Ruthenium Polarography Dimerization of trimethylsilylpropyne on a triosmium cluster. Synthesis, electrosynthesis and structural studies of bis(silyl- Formation, crystal structure and rearrangement of Os,H[3- cyclopentadienyl)niobium complexes with acetylene ligands C(SiMe,)C(Me)CC(SiMe,)C(CHO,) , complex (A.A. Ko- (A. Antifolo, A. Otero, M. Fajardo, M. Galakhov, R. Gil-Sanz, ridze, N.M. Astakhova, P.V. Petrovskii, F.M. Dolgushin, A.1. C. Lépez-Mardomingo, D. Lucas, H. Chollet and Y. Mugnier), Yanovsky and Yu.T. Struchkov), 247 a f Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- Polymer dition von Carbonylmetallaten an kationische Allyl- und Formation of dimeric 1-alkoxy-3-acyloxytetrabutyldistannoxanes Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, by reaction of dibutyltin oxide with esters. I. Characterization Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und in solution by multinuclear NMR spectroscopy and applica- vierkernige Komplexe mit o,7r-Allyl- und o,a-Alken-Briicken tion to polymer crosslinking (J. Bonetti, C. Gondard, R. (S. Hiiffer, M. Wieser, K. Polborn und W. Beck), 45 Petiaud, M.-F. Llauro and A. Michel), 7 Steric effects in heteroboranes. Part 7. The synthesis and charac- Polymerization terisation of arene-ruthenium complexes of C-substituted Formation of dimeric 1-alkoxy-3-acyloxytetrabutyldistannoxanes carbaboranes. Molecular structures of 1-Ph-3-(mes)-3,1,2- by reaction of dibutyltin oxide with esters. I. Characterization closo-RuC,ByHj9 (m= eC,H,s-1,3 ,5) and 1-Ph-2-Me-3-(p - in solution by multinuclear NMR spectroscopy and applica- cym)-3,1,2-closo-,RByuHCy (p-cym = C,H,Me-1-'Pr-4), the tion to polymer crosslinking (J. Bonetti, C.. Gondard, R. latter showing an incipient deformation (J. Cowie, B.D. Reid, Petiaud, M.-F. Llauro and A. Michel), 7 J.M.S. Watmough and A.J. Welch), 283 The synthesis of olefin polymerization precatalysts: [TiCl,(C,- Rutherium H,0CH,CO,CH;)} and [(C,H;OCH,CO,Et), Meg(p- Cl),TiCl,]-2CH,Cl,. Crystal structures and properties (P. Synthesis and properties of mixed-metal phosphido and phosphinidene clusters derived from reaction between Ru,(CO),,- Sobota, M. Wroblewska, S. Szafert and T. Gtowiak), 57 Praseodymium (4-H) u-PPh,) and Cp*Mo(CO)H (J.-C. Wang, Y. Chi, S.-M. Peng, G.-H. Lee, S.-G. Shyu and F.-H. Tu), 143 Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- these und Strukturaufklarung neuer Cyclooctatetraenyl- Samarium cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- Schumann, J. Winterfeld, M. Glanz, R.D. K6hn und H. Hem- these und Strukturaufklarung neuer Cyclooctatetraenyl- ling), 275 cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. C23 Schumann, J. Winterfeld, M. Glanz, R.D. K6hn und H. Hem- cyclopentadienyl-Sandwich-Komplexe der seltenen Erden (H. ling), 275 Schumann, J. Winterfeld, M. Glanz, R.D. Kéhn und H. Hem- Silazanes ling), 275 Synthesis and chemical properties of 1,3-dichloro-1,3-dihy- Tin dridodisilazanes (E. Bacqué, J.-P. Pillot, M. Birot, J. A useful method in organotin chemistry: diimine hydrogenation Dunogués, G. Bourgeois and M. Pétraud), 167 of 1,2-bis(trimethylstannyl)-1-alkenes, 1-trimethylsilyl-2-tri- Silicon methylstannyl-l-alkenes and some distannacyclopentenes A useful method in organotin chemistry: diimine hydrogenation (T.N. Mitchell and B. Kowall), 137 of 1,2-bis(trimethylstannyl)-l-alkenes, 1-trimethylsilyl-2-tri- Formation of dimeric 1-alkoxy-3-acyloxytetrabutyldistannoxanes methylstannyl-l-alkenes and some _ distannacyclopentenes by reaction of dibutyltin oxide with esters. I. Characterization (T.N. Mitchell and B. Kowall), 137 in solution by multinuclear NMR spectroscopy and applica- Synthesis and chemical properties of 1,3-dichloro-1,3-dihy- tion to polymer crosslinking (J. Bonetti, C. Gondard, R. dridodisilazanes (E. Bacqué, J.-P. Pillot, M. Birot, J. Petiaud, M.-F. Llauro and A. Michel), 7 Dunogués, G. Bourgeois and M. Pétraud), 167 The structure of [{Co(n*-C;H ,)XCO),},SnCl,] in the solid state Silver (C,H j9=2,3-dimethylbuta-1,3-diene) (D. Cunningham, T. Hig- Structure of the silver imidodi(sulphuryl fluoride)—benzene sol- gins, P. McArdle, W. Corrigan, R. Foley and A.R. Manning), vate AgN(SO,F),:C,H, (M.J. Begley, D.B. Sowerby, R.D. 63 Verma and A. Vig), 243 Titanium Stannanes The synthesis of olefin polymerization precatalysts: [TiCl,(C,- Formation of dimeric 1-alkoxy-3-acyloxytetrabutyldistannoxanes H,OCH ,CO,CH;)] and [(C,H;OCH,CO,Et), Meg(p- by reaction of dibutyltin oxide with esters. I. Characterization Cl),TiCl,]:2CH,Cl,. Crystal structures and properties (P. in solution by multinuclear NMR spectroscopy and applica- Sobota, M. Wroblewska, S. Szafert and T. Glowiak), 57 tion to polymer crosslinking (J. Bonetti, C. Gondard, R. Trifluoromethyl Petiaud, M.-F. Llauro and A. Michel), 7 Trifluormethyl-substituierte Plumbane—Darstellung, Eigen- Stannyl schaften und NMR-spektroskopische Charakterisierung von Synthesis of 7°-2-stannylmethylallylpalladium complexes and CF;PbR,H (R = CH;, C,H) sowie von CF,Pb(II)-Derivaten their destannylation leading to trimethylenemethane-pal- (R. Eujen and A. Patorra), 75 ladium species (S. Watanabe, S. Ogoshi, K. Kakiuchi and H. Trimethylenemethane Kurosawa), 19 Synthesis of 7°-2-stannylmethylallylpalladium complexes and Stereospecific their destannylation leading to trimethylenemethane-pal- Novel coupling between tricarbonyl(7-azabenzonorbornadiene)i- ladium species (S. Watanabe, S. Ogoshi, K. Kakiuchi and H. ron complexes and cyclohexene to form stereospecifically a Kurosawa), 19 (C-5 substituted n*-cyclohexadiene)Fe(CO), moiety (C.-H. 4-trimethylsilyl-3-vinylidenepiperidines Sun, N.-C. Shang, L.-S. Liou and J.-C. Wang), 179 Synthése et protodésilylation de silanes a-alléniques hétéro- Structure cycliques (J. Pornet, P. Aubert, B. Randrianoélina et L. Komplexchemie und Mechanismen metallkatalysierter CC-Kup- Miginiac), 217 plungsreaktionen. III. Phosphol-Komplexe des nullwertigen 4-trimethylsilyl-3-vinylidenetetrahydropyranes Palladiums (W.A. Herrmann, W.R. Thiel, T. Priermeier und Synthése et protodésilylation de silanes a-alléniques hétéro- E. Herdtweck), 253 cycliques (J. Pornet, P. Aubert, B. Randrianoélina et L. Sulfur Miginiac), 217 Synthesis of the novel bifunctional ligand, dicyclopentadienylsul- Tungsten fide (C;H;),S, and its dilithium salt (K.A. Rufanov, A.V. Kohlenwasserstoffverbriickte Komplexe. XXIX. Nucleophile Ad- Churakov, N.B. Kazennova and D.A. Lemenovskii), C1 dition von Carbonylmetallaten an kationische Allyl- und Synthesis Alken-Komplexe von Wolfram, Mangan, Rhenium, Eisen, Multiple bonds between main-group elements and transition met- Ruthenium, Osmium, Cobalt und Iridium: Zwei-, drei- und als. CXXXI. Allyl-, vinyl- and related rhenium(VII) trioxides: vierkernige Komplexe mit o,7r-Allyl- und o,a-Alken-Briicken synthesis and degradation (W.A. Herrmann, F.E. Kiihn, C.C. (S. Hiiffer, M. Wieser, K. Polborn und W. Beck), 45 Roméo and H.T. Huy), 227 Synthesis and chemical properties of 1,3-dichloro-1,3-dihy- Uranium dridodisilazanes (E. Bacqué, J.-P. Pillot, M. Birot, J. Dimeric uranium complexes with bridging phospholyl ligands. Dunogués, G. Bourgeois and M. Pétraud), 167 Crystal structure of [{U(n>°-C,Me,PXu-n°,n'-C,Me,P)- (BH ,)},] (P. Gradoz, M. Ephritikhine, M. Lance, J. Vigner and M. Nierlich), 69 Thermochemistry Multiple bonds between main-group elements and transition metals. CXXXI. Allyl-, vinyl- and related rhenium(VID trioxides: Vanadium synthesis and degradation (W.A. Herrmann, F.E. Kiihn, C.C. Chemical and electrochemical studies on metal carbonyl/ Romao and H.T. Huy), 227 cobaltocene systems (G. Pampaloni and U. Koelle), 1 Thiourea Metal 7 complexes of benzene derivatives. XLIII. Intramolecular Crystal and molecular structure of N-(ferrocenylcarbonyl)-N’- interactions between bis(benzene)chromium and cymantrene naphthyl thiourea (J.-T. Wang, Y.-F. Yuan, Y.-M. Xu, Y.-W. units in di- and tri-nuclear species containing PMe, spacers, Zhang, R.-J. Wang and H.-G. Wang), 211 as studied by CV and EPR (C. Elschenbroich, T. Isenburg, B. Thulium Metz, A. Behrendt and K. Harms), 153 Metallorganische Verbindungen der Lanthanoide. LXXXV. Syn- Reactions of hydridovanadium complexes: The formation of these und Strukturaufklarung neuer Cyclooctatetraenyl- seven-coordinated o-alkylvanadium(I) complexes by hydrovanadation of alkenes, and the molecular structure of (C104), -2CH,Cl,-H,0 (M.C. Gimeno, J. Jiménez, A. La- trans-[V(CO),(dppe)>]-3C,D¢, (F. Siissmilch, F. Olbrich and guna, M. Laguna, P.G. Jones and R.V.D. Parish), 37 D. Rehder), 125 Bis(alkoxycarbonyl) complexes of platinum: preparation, reactiv- Vinyl ity and their role in carbonylation reactions (G. Vasapollo, L. Multiple bonds between main-group elements and transition met- Toniolo, G. Cavinato, F. Bigoli, M. Lanfranchi and M.A. als. CXXXI. Allyl-, vinyl- and related rhenium(VID) trioxides: Pellinghelli), 173 synthesis and degradation (W.A. Herrmann, F.E. Kihn, C.C. Dimeric uranium complexes with bridging phospholyl ligands. Romao and H.T. Huy), 227 Crystal structure of [{U(n*°-C,Me,PXu-n°,n'-C,Me,P)- *'vV NMR (BH,)},] (P. Gradoz, M. Ephritikhine, M. Lance, J. Vigner Reactions of hydridovanadium complexes: The formation of and M. Nierlich), 69 seven-coordinated o-alkylvanadium(I) complexes by _hy- Six-membered cyclometallated derivatives of platinum(II) derived drovanadation of alkenes, and the molecular structure of from 2-benzylpyridines. Crystal and molecular structure of trans-[V(CO),(dppe)>]-3C,D, (F. Siissmilch, F. Olbrich and [Pt(L(Ph,P)Cl] (HL = 2-(1-methylbenzyl)pyridine) (G. D. Rehder), 125 Minghetti, A. Zucca, S. Stoccoro, M.A. Cinellu, M. Man- assero and M. Sansoni), 195 X-ray diffraction Komplexchemie und Mechanismen metallkatalysierter CC-Kup- plungsreaktionen. II. Oxidative Addition von Chloraromaten Ylide an Pd°-Komplexe: Synthese, Struktur und Stabilitat von Aryl- Asymmetric monocationic and dicationic gold(II) complexes: X- palladium(I])-chloriden der Phosphanreihe (W.A. Herrmann, ray structure of [MePh,PAu(CH ,PPh,CH ,),AuOH,]- C. Bro®mer, T. Priermeier und K. Ofele), 97 (C1O,),*2CH,Cl,-H,O (M.C. Gimeno, J. Jiménez, A. La- Steric effects in heteroboranes. Part 8. Sterically-induced Exo- guna, M. Laguna, P.G. Jones and R.V.D. Parish), 37 skeletal isomerisation of di-copper carbametallaboranes: syn- theses and crystal structures of (Ph;PCu),Ph,C,B,H, and {(o-tol),;PCu},Ph,C,ByH, (KJ. Adams, J. Cowie, S.G.D. Zinc Henderson, G.J. McCormick and A.J. Welch), C9 Synthesis of pinacol esters of 2,3-alkadienylboronic acid via the X-ray structure copper(I) mediated coupling reaction of Knochel’s (dial- Asymmetric monocationic and dicationic gold(II) complexes: X- koxyboryl)methylzinc reagents with propargylic tosylates (I. ray structure of [MePh,PAu(CH,PPh,CH,),AuOH,]- Gridnev, G. Kanai, N. Miyaura and A. Suzuki), C4