Table Of Content

Journal of Organometallic Chemistry, 473 (1994) C3-—C4 Author Index of Volume 473 Abe, M., 187 Kato, A., 313 Ogino, H., 187 Adachi, T., 195, 225 Kato, S., 71 Ogoshi, H., 323 Aida, K.-i., 101 Kato, T., 323 Ohnuki, S., 187 Akita, M., 175 Kawachi, A., 29 Ohshita, J., 15 Akiyama, T., 313 Kobayashi, K., 155 Ohsumi, K., Cl Ando, K., 303 Komatsuzaki, N., 303 Onitsuka, K., 195 Aoki, K., 285 Komiya, S., 139 Osakada, K., 359 Aoyagi, K., 117 Kondo, T., 163 Otera, J., 55 Asai, T., 323 Kotora, M., 117 Otsuji, Y., 35, 215 Kubo, K., 243 Otsuka, Y., 195 Baba, K., 225 Kyushin, S., 19 Ozawa, F., 265 Chatani, N., 335 Ren, J.-G., 149 Chiba, H., 45 Maeda, M., 155 Rousset, C.J., 117 Chiba, T., 205 Mandai, T., 343 Chihara, T., 273 Maruyama, Y., 257 Saburi, M., 117 Chosa, J.-i., 35 Masaoka, S., 15 Sadashima, T., 139 Masaoka, Y., 15 Saida, Y., 353 Fujita, T., 243 Mashima, K., 85 Saitoh, M., 285 Fujiwara, J., 63 Masuda, K., 285 Sakamoto, T., 257 Fujiwara, Y., 329 Matsumoto, H., 19 Sato, M., 19 Fukui, H., 295 Matsumoto, T., 343 Sato, T., 55, 63 Fukuoka, A., 139 Matsuoka, S., 343 Sawada, M., 303 Fukuzawa, S.-i., 205 Matsuzaka, H., 1 Sezaki, T., 257 Minato, M., 149 Goto, F., 225 Mise, T.. 155 Shimizu, I., 155, 257 Goto, M., 19 Miura, K., Cl Shinagawa, I., 187 Singh, J.D., 205 Miyake, M., 19 Hasegawa, M., 117 Miyashita, A., 353 Sone, Y., 163 Hayashi, T., 129, 323 Miyata, T., 329 Sonoda, N., 71 Hidai, M., 1 Miyoshi, K., 243 Sonogashira, K., 195 Hirakawa, H., 175 Mizobe, Y., 1 Sugimori, A., 313 Hisamatsu, N., 313 Mizuho, Y., 139 Sugino, T., 71 Hojo, M., Cl Mizuno, K., 35 Sugiura, T., 139 Hosomi, A., Cl Mochida, K., 45 Sugiyama, T., 313 Hotta, M., 353 Morimoto, T., 335 Suzuki, F., 149 Hou, Z., 101 Moro-oka, Y., 175, 295 Suzuki, H., 295 Suzuki, N., 117 Murai, S., 335 Igarashi, T., 149 Murakami, M., 93 Ikarugi, M., 19 Muto, T., 335 Tachibana, A., 15 Ishibashi, N., Cl Takagi, Y., 101 Ishii, N., 175 Takahashi, S., 303 Ishikawa, M., 15 Nakagawa, Y., 29 Takahashi, T., 117 lto, T., 149 Nakajima, T., 155 Takaki, K., 329 Ito, Y., 29, 93 Nakamura, A., 85, 105 Takaya, H., 85, 253 Itoh, K., 215, 285 Nakanishi, K., 35 Takei, K., 105 Izumi, H., 187 Nakanishi, S., 215 Takizawa, T., 359 Izumi, Y., 19 Nakata, K., 329 Tamao, K., 29 Nakayama, Y., 85, 105 Tanaka, M., 295, 359 Kai, Y., 85, 105 Nakazawa, H., 243 Tanaka, T., 225, 303 Kajitani, M., 313 Ninomiya, K., 313 Taniguchi, Y., 329 Kakigano, T., 295 Nishibayashi, Y., 205 Tao, X.-Q., 195 Kambe, N., 71 Nishimura, H., 129 Tekawa, M., 257 Kanda, T., 71 Nitto, Y., 117 Terada, M., 175 Kanehisa, N., 85, 105 Nozaki, K., 253 Tobita, H., 187 Kaneko, T., 323 Nozawa, S.-h., 313 Tokunaga, T., 149 C4 Tomita, H., 149 Uemura, S., 205 Yamamoto, A., xi, 257, 265 Tono, M., 313 Uno, M., 303 Yamamoto, T., 359 Tsuda, T., 303 Yamamoto, Y., 155 Tsuji, J., 343 Wakatsuki, Y., 101, 155 Yamaoka, Y., 329 Tsuji, Y., 163 Wang, W.-Q., 195 Yamazaki, H., 273 Tsujiguchi, Y., 343 Watanabe, Y., 163 Yano, T., 15 Tsunakawa, S., 19 Wu, X., 139 Yasuda, H., 105 Ueda, T., 225 Yamabe, T., 15 Yoshida, M., 253 Uemura, M., 129 Yamagami, I., 265 Yoshida, T., 195, 225 Journal of Organometallic Chemistry, 473 (1994) C5-C12 Subject Index of Volume 473 Acetal Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), Studies on organosilicon chemistry. CXXII. Reaction of 2- 195 oxiranylallylsilanes with acetals. Direct introduction of a vinyl- Towards novel organic synthesis on multimetallic centres: synthe- oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura ses and reactivities of dinuclear ruthenium thiolate complexes and A. Hosomi), Cl (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 2-Acetoxy-2-phenylacetaldehyde monothioacetal 2-Alkynyl carbonate Mechanistic insight into the cinnamylmetal-thioacetal reaction Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- Sato and J. Otera), 55 plex vs. allenylpalladium complex as intermediates (T. Acetylene Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. Preparation of vinylgermanes and a germole by the Pd-catalyzed Tsuji), 343 reactions of Me;GeCn with acetylenes (N. Chatani, T. Mori- 2-Alkynyl formate moto, T. Muto and S. Murai), 335 Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Alcohol elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- Carbene insertion into oxygen—hydrogen bonds by metallopor- plex vs. allenylpalladium complex as intermediates (T. phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. H. Ogoshi), 323 Tsuji), 343 Aldehyde Allyl Highly regioselective reaction of zirconocene-alkene complexes Conjugate addition of allylic groups to a,B-unsaturated carbonyl with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- compounds via (7-allyl)Fe(CO),NO complexes (K. Itoh, S. yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Nakanishi and Y. Otsuji), 215 Saburi), 117 Generation of allyl- and benzyllithiums from the corresponding Reaction of RuH ,(PMe;), with benzaldehyde. Formation of novel halides by the aid of lithium—tellurium exchange reactions (T. oxametallacycle and metallacycloketone complexes via C-H Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Ruthenium-catalysed reductive cleavage of allylic esters with Yamamoto), 265 formic acid and triethylamine. Application to short-step syn- Alkane activation thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Palladium(II) and/or copper(II)-catalyzed carboxylation of small Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 alkanes such as methane and ethane with carbon monoxide Syntheses and reactivities of ferrocenyl organyl tellurides (Y. (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. and Y. Fujiwara), 329 Fukuzawa), 205 Alkene Allylation Photochemical carbon-silicon bond forming reaction on Studies on organosilicon chemistry. CXXII. Reaction of 2- electron-deficient alkenes by disilanes and polysilanes via oxiranylallylsilanes with acetals. Direct introduction of a vinyl- photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura Chosa and Y. Otsuji), 35 and A. Hosomi), C1 Alkoxide Allylsilane Mono- and dinuclear alkoxide copper complexes with PPh, lig- Studies on organosilicon chemistry. CXXII. Reaction of 2- ands (K. Osakada, T. Takizawa, M. Tanaka and T. Ya- oxiranylallylsilanes with acetals. Direct introduction of a vinyl- mamoto), 359 oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura Preparation and some reactions of bis(7>-cyclopentadienyl)hy- and A. Hosomi), Cl drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. Allyltin Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. Diversity in the reaction modes of anionic and cationic stannyl Ito), 149 reagents: y-chloro allylstannanes as a vinyl carbene equiva- Alkyl iodide lent, and its application for (+)-bakuchiol synthesis (J. Fuji- Photo-, electro-, and thermal carbonylation of alkyl iodides in the wara and T. Sato), 63 presence of Group 7 and 8-10 metal carbonyl catalysts (T. Amino substitution Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 Synthesis by the Arbuzov-like dealkylation reaction, characteriza- Alkyne tion, and reactivity of phosphonate and amino-substituted Preparation and characterization of p-alkyne-hexacarbonyldico- phosphonate ruthenium complexes, [(7°-C;H,;CO),Ru{P- balt complexes derived from 1,1’-dialkynylferrocene. Molecu- (OKOR),(NC,Hg)>_,,}] (n = 0-2), and comparison with the lar structures of {(5-C;H ,C=CPh), Fe}{Co(CO),}, and {(n°- iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. C;H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. Miyoshi), 243 C6 Benzyl Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,C- Generation of allyl- and benzyllithiums from the corresponding (CO),,(CH,)] as catalyst precursor for hydrogenation of halides by the aid of lithium—tellurium exchange reactions (T. olefins. Syntheses and structures of unsaturated and saturated Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and Selective sp* C-H bond activation of alkylaromatics promoted by [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 platinum complexes (A. Miyashita, M. Hotta and Y. Saida), Preparation and characterization of u-alkyne-hexacarbonyldico- 353 balt complexes derived from 1,1’-dialkynylferrocene. Molecu- Syntheses and reactivities of ferrocenyl organyl tellurides (Y. lar structures of {(7°-C;H,C=CPh), Fe}{Co,(CO),}, and {(°- Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. C5H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. Fukuzawa), 205 Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), Bifunctional reagent 195 Diversity in the reaction modes of anionic and cationic stannyl Reactions of sterically congested secondary silanes with iron reagents: y-chloro allylstannanes as a vinyl carbene equiva- carbonyls. Formation of y-silylene complexes Fe,(CO),(u- lent, and its application for (+ )-bakuchiol synthesis (J. Fuji- SiR, )( R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, I. Shi- wara and T. Sato), 63 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Bond activation Synthesis and X-ray structure of the divalent and trivalent ytter- Interconversion between (C;R,)Ru!(aliyl) and (C;R;)Ru"'(di- bium-molybdenum complexes Yb''(HMPA),(u-OCMo(CO),- ene) complexes (K. Masuda, M. Saitoh, K. Aoki and K. Itoh), Cp), and [Yb"'(HMPA).(u-OCMo(CO)>,Cp)I[CpMo(CO);], 285 - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Selective sp*> C-H bond activation of alkylaromatics promoted by Unusual reactivities of (u-n?:n?-FP—C=C-H)Co(CO),, the platinum complexes (A. Miyashita, M. Hotta and Y. Saida), adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis 353 and reduction with hydrosilanes giving polynuclear complexes, Bond cleavage (CP), Fe,Co3(ws5-C=CH\CO)i9, (u-CH=CH)[(— p3 - Carbon-carbon bond cleavage and skeletal rearrangement of C)Co(CO),], and CpFeCo,(u-C=CCOH), (M. Akita, M. coordinated norbornadiene. Preparation of a 7°-6-methyl- Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 fulvene complex [(C;Me,;)Ru(C;H,CH)]CBHF, (H. Suzuki, Carbonylation T. Kakigano, H. Fukui, M. Tanaka and Y. Moro-oka), 295 Photo-, electro-, and thermal carbonylation of alkyl iodides in the Bridging ligand presence of Group 7 and 8-10 metal carbonyl catalysts (T. Preparation and structure of the first ansa-molybdenocene and Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 tungstenocene derivatives. Reaction of [O(SiMe,C;H,),]JMo- Catalysis H, with methyl methacrylate to probe the olefin attacking site Carbene insertion into oxygen—hydrogen bonds by metallopor- (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. Shimizu, phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Y. Yamamoto and Y. Wakatsuki), 155 H. Ogoshi), 323 Bulky ligands Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Carbene insertion into oxygen—hydrogen bonds by metallopor- elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and plex vs. allenylpalladium complex as intermediates (T. H. Ogoshi), 323 Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. Tsuji), 343 Carbene Photo-, electro-, and thermal carbonylation of alkyl iodides in the Carbene insertion into oxygen—hydrogen bonds by metallopor- presence of Group 7 and 8-10 metal carbonyl catalysts (T. phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 H. Ogoshi), 323 Carbide Preparation of vinylgermanes and a germole by the Pd-catalyzed reactions of Me,;GeCn with acetylenes (N. Chatani, T. Mori- Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,C- moto, T. Muto and S. Murai), 335 (CO),,(CH,)] as catalyst precursor for hydrogenation of Reaction rate enhancement by addition of anionic surfactant olefins. Syntheses and structures of unsaturated and saturated hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and SDS in the ruthenium catalyzed hydrogen transfer from a [PPN][Ru,C(CO),,,H] (T. Chihara and H. Yamazaki), 273 1,4-diol to 4-phenyl-3-buten-2-one (K. Nozaki, M. Yoshida and H. Takaya), 253 Carbon-carbon bond formation Ruthenium-catalysed reductive cleavage of allylic esters with Carbon-carbon bond forming reactions via new organosamar- formic acid and triethylamine. Application to short-step syn- ium(II]) intermediates (M. Murakami and Y. Ito), 93 thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Highly regioselective reaction of zirconocene-alkene complexes Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- Catalyst precursor yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,- Saburi), 117 C(CO),.(CH3)] as catalyst precursor for hydrogenation of Carbon monoxide Palladium(ID and/or copper(I1)-catalyzed carboxylation of small olefins. Syntheses and structures of unsaturated and saturated hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and alkanes such as methane and ethane with carbon monoxide [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki and Y. Fujiwara), 329 Catalytic asymmetric cross-coupling Carbonyl Catalytic asymmetric induction of planar chirality: Palladium- catalyzed asymmetric cross-coupling of meso tricarbonyl(a- Conjugate addition of allylic groups to a,B-unsaturated carbonyl rene)chromium complexes with alkenyl- and arylboronic acids compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. Nakanishi and Y. Otsuji), 215 (M. Uemura, H. Nishimura and T. Hayashi), 129 Charge transfer Conjugated enyne Molecular structures and charge-transfer complexes of cis-di- Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and benzo[c,h]-1,6-disilabicyclo[4.4.0]deca-3,8-dienes and bi(ben- elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- zo[c |silacyclopent-3-ene-1-yl)s (S. Kyushin, M. Ikarugi, S. plex vs. allenylpalladium complex as intermediates (T. Tsunakawa, Y. Izumi, M. Miyake, M. Sato, H. Matsumoto Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. and M. Goto), 19 Tsuji), 343 Chiral ligand Copper Catalytic asymmetric induction of planar chirality: Palladium- Mono- and dinuclear alkoxide copper complexes with PPh, lig- catalyzed asymmetric cross-coupling of meso tricarbo- ands (K. Osakada, T. Takizawa, M. Tanaka and T. Ya- nyl(arene)chromium complexes with alkenyl- and arylboronic mamoto), 359 acids (M. Uemura, H. Nishimura and T. Hayashi), 129 Palladium(II) and/or copper(II)-catalyzed carboxylation of small (Arene)chromium alkanes such as methane and ethane with carbon monoxide Catalytic asymmetric induction of planar chirality: Palladium- (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki catalyzed asymmetric cross-coupling of meso tricarbo- and Y. Fujiwara), 329 nyl(arene)chromium complexes with alkenyl- and arylboronic Crown thioethers acids (M. Uemura, H. Nishimura and T. Hayashi), 129 Ruthenium(II) hydrido complexes of quadridentate crown Cinnamylmetal-thioacetal reaction thioethers, trans-RuH(ClXsyn-L) (L = Me,{14]JaneS,, Me,- Mechanistic insight into the cinnamylmetal-thioacetal reaction [15]aneS,, Me,{16]aneS,) and {Ru,H(u-H)CIK(syn-Me,{14]- employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. aneS,).}Cl containing a linear Ru-H-Ru bond. Novel char- Sato and J. Otera), 55 acteristics of syn-crown thioethers affecting discrimination of Cluster axial ligands and geometry of the unsupported Ru-H-Ru Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,- linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba C(CO),,(CH;3)] as catalyst precursor for hydrogenation of and T. Tanaka), 225 olefins. Syntheses and structures of unsaturated and saturated Crystal structure hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 Kawachi, Y. Nakagawa and Y. Ito), 29 Towards novel organic synthesis on multimetallic centres: synthe- Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- ses and reactivities of dinuclear ruthenium thiolate complexes clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 taining three different chiralities in one molecule (M. Uno, K. Cobalt Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- S. Takahashi), 303 ture, and properties of (n>-cyclopentadienyl or 7>pen- Synthesis and X-ray structure of the divalent and trivalent ytter- tamethylcyclopentadieny! 1-phenylmethanimine-N, 1-dithiol- bium-molybdenum complexes Yb!'(HMPA),(u-OCMo- ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. (CO),Cp), and [Yb"(HMPA)<(4-OCMo(CO),Cp)][CpMo- Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama (CO)3],- THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakat- and A. Sugimori), 313 suki), 101 Preparation and characterization of p-alkyne-hexacarbonyldico- Cyanide balt complexes derived from 1,1'-dialkynylferrocene. Molecu- Preparation of vinylgermanes and a germole by the Pd-catalyzed lar structures of {(n°-C;H ,C=CPh), Fe}{Co,(CO),}, and {(n°- reactions of Me,GeCn with acetylenes (N. Chatani, T. Mori- C;H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. moto, T. Muto and S. Murai), 335 Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), Cyclobutadiene 195 Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- Synthesis and reactivity of platinum-containing heterodinuclear clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- complexes with methyl and 1,2-bis(diphenylphosphino)ethane taining three different chiralities in one molecule (M. Uno, K. ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. S. Takahashi), 303 Mizuho and S. Komiya), 139 Cyclooctatetraenyl Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- A new convenient preparation of monocyclooctatetraenyl- clopentadieny!)cobalt(tetraarylcyclobutadiene) complexes con- lanthanide complexes from metallic lanthanides and oxidants taining three different chiralities in one molecule (M. Uno, K. (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and Kai and H. Takaya), 85 S. Takahashi), 303 Cyclopentadienyl Unusual reactivities of (y-n?:n?-FP—C=C-H)Co,(CO),, the Preparation and some reactions of bis(7>-cyclopentadienyl)hy- adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. and reduction with hydrosilanes giving polynuclear complexes, Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. (CP), Fe ,Co3(45-C=CH\CO),9, (u-CH=CH)[(- p3- Ito), 149 C)Co,(CO),], and CpFeCo,(-C=CH ,{CO), (M. Akita, M. Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 Dimerization 1,2,5,3-Cobaltadithiazole Reaction of RuH,(PMe,), with benzaldehyde. Formation of novel A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- oxametallacycle and metallacycloketone complexes via C-H ture, and properties of (n°-cyclopentadienyl or 1°pen- bond activation of aldehyde (F. Ozawa, I. Yamagami and A. tamethylcyclopentadienyl1-phenylmethanimi|-ndeit-hNio,l - Yamamoto), 265 ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. (Amino)disilane Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. and A. Sugimori), 313 Kawachi, Y. Nakagawa and Y. Ito), 29 C8 Disubstituted alkyne Group 9 Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Photo-, electro-, and thermal carbonylation of alkyl iodides in the elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- presence of Group 7 and 8-10 metal carbonyl catalysts (T. plex vs. allenylpalladium complex as intermediates (T. Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 Mandai, T. Matsumoto, Y. Tsujiguchi, S$. Matsuoka and J. Group 10 Tsuji), 343 Photo-, electro-, and thermal carbonylation of alkyl iodides in the Dithiolate presence of Group 7 and 8-10 metal carbonyl catalysts (T. A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 ture, and properties of (n>-cyclopentadienyl or n> pen- Group 14 tamethylcyclopentadienyl 1-phenylmethanimine-N, |-dithiol- Photochemical carbon-silicon bond forming reaction on ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. electron-deficient alkenes by disilanes and polysilanes via Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. and A. Sugimori), 313 Chosa and Y. Otsuji), 35 Electronic spectra Halide Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. Generation of allyl- and benzyllithiums from the corresponding Kawachi, Y. Nakagawa and Y. Ito), 29 halides by the aid of lithium—tellurium exchange reactions (T. Electron transfer Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 Photochemical carbon-silicon bond forming reaction on Heterobimetallics electron-deficient alkenes by disilanes and polysilanes via Synthesis and reactivity of platinum-containing heterodinuclear photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. complexes with methyl and 1,2-bis(diphenylphosphino)ethane Chosa and Y. Otsuji), 35 ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - Ethane THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Palladium(II) and/or copper(II)-catalyzed carboxylation of small Mizuho and S. Komiya), 139 alkanes such as methane and ethane with carbon monoxide Hydride (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki Preparation and some reactions of bis(7°-cyclopentadienyl)hy- and Y. Fujiwara), 329 drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. Extended Hiickel calculations Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. Ruthenium(II) hydrido complexes of quadridentate crown Ito), 149 thioethers, trans-RuH(ClXsyn-L) (L = Me,{14JaneS,, Me,- Reaction of RuH ,(PMe,), with benzaldehyde. Formation of novel [1SJaneS,, Me,{16JaneS,) and {Ru,H(y-H)CK(syn-Me,[14]- oxametallacycle and metallacycloketone complexes via C-H aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- bond activation of aldehyde (F. Ozawa, I. Yamagami and A. acteristics of syn-crown thioethers affecting discrimination of Yamamoto), 265 axial ligands and geometry of the unsupported Ru-H-Ru Hydrogen bonding linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba Reaction of RuH ,(PMe,), with benzaldehyde. Formation of novel and T. Tanaka), 225 oxametallacycle and metallacycloketone complexes via C-—H bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Ferrocene Yamamoto), 265 Preparation and characterization of y-alkyne-hexacarbonyldico- Hydrogen transfer balt complexes derived from 1,1’-dialkynylferrocene. Molecu- Reaction rate enhancement by addition of anionic surfactant lar structures of {(n°-C;H 4C=CPh), Fe}{Co,(CO),}, and {(n°- C5H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. SDS in the ruthenium catalyzed hydrogen transfer from a 1,4-diol to 4-phenyl-3-buten-2-one (K. Nozaki, M. Yoshida Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), and H. Takaya), 253 195 Syntheses and reactivities of ferrocenyl organyl tellurides (Y. Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. Interconversion Fukuzawa), 205 Interconversion between (C;R5)Ru'(allyl) and (C;R,)Ru'(di- Formic acid ene) complexes (K. Masuda, M. Saitoh, K. Aoki and K. Itoh), Ruthenium-catalysed reductive cleavage of allylic esters with 285 formic acid and triethylamine. Application to short-step syn- Iron thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Conjugate addition of allylic groups to a,B-unsaturated carbonyl Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. Nakanishi and Y. Otsuji), 215 Germanium Reactions of sterically congested secondary silanes with iron Preparation of vinylgermanes and a germole by the Pd-catalyzed carbonyls. Formation of y-silylene complexes Fe,(CO),(y- reactions of Me,GeCn with acetylenes (N. Chatani, T. Mori- SiR) (R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, 1. Shi- moto, T. Muto and S. Murai), 335 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Group 7 Synthesis and reactivity of platinum-containing heterodinuclear Photo-, electro-, and thermal carbonylation of alkyl iodides in the complexes with methyl and 1,2-bis(diphenylphosphino)ethane presence of Group 7 and 8-10 metal carbonyl catalysts (T. ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Group 8 Mizuho and S. Komiya), 139 Photo-, electro-, and thermal carbonylation of alkyl iodides in the Unusual reactivities of (u-n?:n?-FP-C=C-H)Co,(CO),, the presence of Group 7 and 8-10 metal carbonyl catalysts (T. adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 and reduction with hydrosilanes giving polynuclear complexes, C9 (CP), Fe,Co3("5-C=CH\(CO)i9, (u-CH=CH)[(p-3 - Reaction of RuH ,(PMe3), with benzaldehyde. Formation of novel C)Co(CO)o], and CpFeCo ;(-C=CH 5 (CO), (M. Akita, M. oxametallacycle and metallacycloketone complexes via C-H Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Yamamoto), 265 Ketone Towards novel organic synthesis on multimetallic centres: synthe- Conjugate addition of allylic groups to a,B-unsaturated carbonyl ses and reactivities of dinuclear ruthenium thiolate complexes compounds via (7°-allyl)Fe(CO),NO complexes (K. Itoh, S. (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 Nakanishi and Y. Otsuji), 215 Metallocenes Highly regioselective reaction of zirconocene-alkene complexes Highly regioselective reaction of zirconocene-alkene complexes with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Saburi), 117 Saburi), 117 Ketone dianion Preparation and structure of the first ansa-molybdenocene and Synthesis and X-ray structure of the divalent and trivalent ytter- tungstenocene derivatives. Reaction of [O(SiMe,C;H,)>}- bium-molybdenum complexes Yb'(HMPA),(u-OCMo(CO),- MoH, with methyl methacrylate to probe the olefin attacking Cp), and [Yb"(HMPA).(4.-OCMo(CO),Cp)I[CpMo(CO),], site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 Methane Palladium(I]) and/or copper(II)-catalyzed carboxylation of small Lanthanide alkanes such as methane and ethane with carbon monoxide A new convenient preparation of monocyclooctatetraenyl- (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki lanthanide complexes from metallic lanthanides and oxidants and Y. Fujiwara), 329 (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Methyl methacrylate Kai and H. Takaya), 85 Preparation and structure of the first ansa-molybdenocene and Lewis acid tungstenocene derivatives. Reaction of [O(SiMe,C;H,),]- Diversity in the reaction modes of anionic and cationic stannyl MoH, with methyl methacrylate to probe the olefin attacking reagents: y-chloro allylstannanes as a vinyl carbene equiva- site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. lent, and its application for (+ )-bakuchiol synthesis (J. Fuji- Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 wara and T. Sato), 63 Molybdenum Linear Ru-H-Ru bond Preparation and some reactions of bis(n>-cyclopentadienyl)hy- Ruthenium(II]) hydrido complexes of quadridentate crown drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. thioethers, trans-RuH(ClXsyn-L) (L = Me,[14JaneS,, Me,- Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. [15JaneS,, Me,{l6JaneS,) and {Ru jH(u-H)CiK(syn-Me,[14]- Ito), 149 aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- Preparation and structure of the first ansa-molybdenocene and acteristics of syn-crown thioethers affecting discrimination of tungstenocene derivatives. Reaction of [O(SiMe,C;H,)>]- axial ligands and geometry of the unsupported Ru-H-Ru MoH, with methyl methacrylate to probe the olefin attacking linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. and T. Tanaka), 225 Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 Lithium Synthesis and reactivity of platinum-containing heterodinuclear Generation of allyl- and benzyllithiums from the corresponding complexes with methyl and 1,2-bis(diphenylphosphino)ethane halides by the aid of lithium—tellurium exchange reactions (T. ligands. X-Ray crystal structure of (dpe)MePt—FeCp(CO), - Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Silicon—carbon unsaturated compounds.. XLVIII. Synthesis and Mizuho and S. Komiya), 139 reactions of silicon analogs of lithium enolates (J. Ohshita, Y. Synthesis and X-ray structure of the divalent and trivalent ytter- Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano bium-molybdenum complexes Yb"!(HMPA),( 1-OCMo(CO),- and T. Yamabe), 15 Cp), and [Yb""'(HMPA).(4-OCMo(CO)>Cp)I[CpMo(CO),]}, Lithium enolates - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Silicon—carbon unsaturated compounds.. XLVIII. Synthesis and Monoterpene reactions of silicon analogs of lithium enolates (J. Ohshita, Y. Diversity in the reaction modes of anionic and cationic stannyl Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano reagents: y-chloro allylstannanes as a vinyl carbene equiva- and T. Yamabe), 15 lent, and its application for (+)-bakuchiol synthesis (J. Fuji- wara and T. Sato), 63 Manganese Synthesis and reactivity of platinum-containing heterodinuclear complexes with methyl and 1,2-bis(diphenylphosphino)ethane Niobium ligands. X-Ray crystal structure of (dpe)MePt—FeCp(CO), - Reaction courses for formation of early transition metal phenox- THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. Mizuho and S. Komiya), 139 Kai and N. Kanehisa), 105 Metallacycle Nitrosyl A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- Conjugate addition of allylic groups to a,B-unsaturated carbonyl ture, and properties of (m°-cyclopentadienyl or 7°pen- compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. tamethylcyclopentadienyl)(1-phenylmethanim|i-ndiet-hNio,l - Nakanishi and Y. Otsuji), 215 ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. Norbornadiene Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama Carbon-—carbon bond cleavage and skeletal rearrangement of and A. Sugimori), 313 coordinated norbornadiene. Preparation of a 7°-6-methyl- fulvene complex [(C;Me,)Ru(C;H,CHCH )]BF, (H. Suzuki, Platinum T. Kakigano, H. Fukui, M. Tanaka and Y. Moro-oka), 295 Selective sp> C-H bond activation of alkylaromatics promoted by platinum complexes (A. Miyashita, M. Hotta and Y. Saida), 353 Optical resolution Synthesis and reactivity of platinum-containing heterodinuclear Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- complexes with methyl and 1,2-bis(diphenylphosphino)ethane clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- ligands. X-Ray crystal structure of (dpe)MePt—FeCp(CO), - taining three different chiralities in one molecule (M. Uno, K. THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and Mizuho and S. Komiya), 139 S. Takahashi), 303 Polynuclear Organic synthesis Unusual reactivities of (u-n*:n?-FP-C=C-H)Co,(CO),, the Diversity in the reaction modes of anionic and cationic stannyl adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis reagents: y-chloro allylstannanes as a vinyl carbene equiva- and reduction with hydrosilanes giving polynuclear complexes, lent, and its application for (+)-bakuchiol synthesis (J. Fuji- (CP), Fe,Co3(u5-C=CH\CO),), (u-CH=CH)[(- p3- wara and T. Sato), 63 C)Co,(CO).], and CpFeCo(u-C=CCOH), (M. Akita, M. Oxidation Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 Syntheses and reactivities of ferrocenyl organyl tellurides (Y. Porphyrin Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. Carbene insertion into oxygen—hydrogen bonds by metallopor- Fukuzawa), 205 phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Oxidative addition H. Ogoshi), 323 Towards novel organic synthesis on multimetallic centres: synthe- ses and reactivities of dinuclear ruthenium thiolate complexes (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 Radical Selective sp> C-H bond activation of alkylaromatics promoted by platinum complexes (A. Miyashita, M. Hotta and Y. Saida), Palladium 353 Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Reductive cleavage elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- Ruthenium-catalysed reductive cleavage of allylic esters with plex vs. allenylpalladium complex as intermediates (T. formic acid and triethylamine. Application to short-step syn- Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Tsuji), 343 Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 Palladium(II) and/or copper(II)-catalyzed carboxylation of small Rhodium alkanes such as methane and ethane with carbon monoxide Carbene insertion into oxygen—hydrogen bonds by metallopor- (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and and Y. Fujiwara), 329 H. Ogoshi), 323 Preparation of vinylgermanes and a germole by the Pd-catalyzed Ruthenium reactions of Me,GeCn with acetylenes (N. Chatani, T. Mori- Carbon-carbon bond cleavage and skeletal rearrangement of moto, T. Muto and S. Murai), 335 coordinated norbornadiene. Preparation of a 7°-6-methyl- Phosphite fulvene complex [((C;Me;)Ru(C;H,C,H)C]BHF , (H. Suzuki, Synthesis by the Arbuzov-like dealkylation reaction, characteriza- T. Kakigano, H. Fukui, M. Tanaka and Y. Moro-oka), 295 tion, and reactivity of phosphonate and amino-substituted Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,- phosphonate ruthenium complexes, [(n°-C;H;)CO),- C(CO),,(CH;)] as catalyst precursor for hydrogenation of Ru{P(OKOR),(NC,Hg)>_,,}] (n = 0-2), and comparison with olefins. Syntheses and structures of unsaturated and saturated the iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and Miyoshi), 243 [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 Phosphonate Interconversion between (C;R;)Ru'Y(allyl) and (C;R;)Ru"(di- Synthesis by the Arbuzov-like dealkylation reaction, characteriza- ene) complexes (K. Masuda, M. Saitoh, K. Aoki and K. Itoh), tion, and reactivity of phosphonate and amino-substituted 285 phosphonate ruthenium complexes, [(n°-C;H;)CO),- Reaction of RuH,(PMe;), with benzaldehyde. Formation of novel Ru{P(OKOR),(NC,4Hg)>_,,}] (2 = 0-2), and comparison with oxametallacycle and metallacycloketone complexes via C-H the iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Miyoshi), 243 Yamamoto), 265 Photochemistry Reaction rate enhancement by addition of anionic surfactant Photochemical carbon-silicon bond forming reaction on SDS in the ruthenium catalyzed hydrogen transfer from a electron-deficient alkenes by disilanes and polysilanes via 1,4-diol to 4-phenyl-3-buten-2-one (K. Nozaki, M. Yoshida photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. and H. Takaya), 253 Chosa and Y. Otsuji), 35 Ruthenium-catalysed reductive cleavage of allylic esters with Selective sp> C-H bond activation of alkylaromatics promoted by formic acid and triethylamine. Application to short-step syn- platinum complexes (A. Miyashita, M. Hotta and Y. Saida), thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. 353 Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 Planar chirality Ruthenium(I]) hydrido complexes of quadridentate crown Catalytic asymmetric induction of planar chirality: Palladium- thioethers, trans-RuH(ClXsyn-L) (L= Me,[14]aneS,, Me,- catalyzed asymmetric cross-coupling of meso tricarbon- [1S]aneS,, Me,{16JaneS,) and {Ru jH(y-H)CI(syn-Me,[14]- yl(arene)chromium complexes with alkenyl- and arylboronic aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- acids (M. Uemura, H. Nishimura and T. Hayashi), 129 acteristics of syn-crown thioethers affecting discrimination of Cll axial ligands and geometry of the unsupported Ru-H-Ru Molecular structures and charge-transfer complexes of cis-di- linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba benzo[c,h]-1,6-disilabicyclo[4.4.0]deca-3,8-dienes and bi(ben- and T. Tanaka), 225 zo[c]silacyclopent-3-ene-1-yl)s (S. Kyushin, M. Ikarugi, S. Synthesis by the Arbuzov-like dealkylation reaction, characteriza- Tsunakawa, Y. Izumi, M. Miyake, M. Sato, H. Matsumoto tion, and reactivity of phosphonate and amino-substituted and M. Goto), 19 phosphonate ruthenium complexes, [(n°-C;H;)(CO),- Reactions of sterically congested secondary silanes with iron Ru{P(OKOR),(NC,Hg)>_,,}] (2 = 0-2), and comparison with carbonyls. Formation of p-silylene complexes Fe ,(CO),(u- the iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. SiR) (R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, I. Shi- Miyoshi), 243 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Towards novel organic synthesis on multimetallic centres: synthe- Silicon-carbon unsaturated compounds.. XLVIII. Synthesis and ses and reactivities of dinuclear ruthenium thiolate complexes reactions of silicon analogs of lithium enolates (J. Ohshita, Y. (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano Ruthenium(II) hydrides and T. Yamabe), 15 Ruthenium(II) hydrido complexes of quadridentate crown Silyl thioethers, trans-RuH(ClXsyn-L) (L = Me,{14JaneS,, Me,- Photochemical carbon-silicon bond forming reaction on [1S5JaneS,, Meg{16]aneS,) and {Ru,H(u-H)CK(syn-Me,[14]- electron-deficient alkenes by disilanes and polysilanes via aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. acteristics of syn-crown thioethers affecting discrimination of Chosa and Y. Otsuji), 35 axial ligands and geometry of the unsupported Ru-H-Ru u-Silylene linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba Reactions of sterically congested secondary silanes with iron and T. Tanaka), 225 carbonyls. Formation of p-silylene complexes Fe,(CO),(y- SiR) (R = mesityl and O(2,6-'Pr,C,H,)) (H. Tobita, I. Shi- nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Silyllithium Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. Kawachi, Y. Nakagawa and Y. Ito), 29 Samarium o-7 conjugation A new convenient preparation of monocyclooctatetraenyl- Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. lanthanide complexes from metallic lanthanides and oxidants Kawachi, Y. Nakagawa and Y. Ito), 29 (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Kai and H. Takaya), 85 Carbon-carbon bond forming reactions via new organosamar- ium(III) intermediates (M. Murakami and Y. Ito), 93 Secondary silanes Tantalum Reactions of sterically congested secondary silanes with iron Reaction courses for formation of early transition metal phenox- carbonyls. Formation of y-silylene complexes Fe ,(CO),(y- ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. SiR) (R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, I. Shi- Kai and N. Kanehisa), 105 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Tellurium Selenolate Generation of allyl- and benzyllithiums from the corresponding A new convenient preparation of monocyclooctatetraenyl- halides by the aid of lithium—tellurium exchange reactions (T. lanthanide complexes from metallic lanthanides and oxidants Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Syntheses and reactivities of ferrocenyl organyl tellurides (Y. Kai and H. Takaya), 85 Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. Silane Fukuzawa), 205 Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. Thiolate Kawachi, Y. Nakagawa and Y. Ito), 29 A new convenient preparation of monocyclooctatetraenyl- Photochemical carbon-silicon bond forming reaction on lanthanide complexes from metallic lanthanides and oxidants electron-deficient alkenes by disilanes and polysilanes via (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. Kai and H. Takaya), 85 Chosa and Y. Otsuji), 35 Towards novel organic synthesis on multimetallic centres: synthe- Studies on organosilicon chemistry. CXXII. Reaction of 2- ses and reactivities of dinuclear ruthenium thiolate complexes oxiranylallylsilanes with acetals. Direct introduction of a vinyl- (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura Tin and A. Hosomi), Cl Mechanistic insight into the cinnamylmetal-thioacetal reaction Silicon employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. Conjugate addition of allylic groups to a,B-unsaturated carbonyl Sato and J. Otera), 55 compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. Titanium Nakanishi and Y. Otsuji), 215 Reaction courses for formation of early transition metal phenox- Highly regioselective reaction of zirconocene-alkene complexes ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- Kai and N. Kanehisa), 105 yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Tosylato Saburi), 117 Preparation and some reactions of bis(7>-cyclopentadienyl)hy- Mechanistic insight into the cinnamylmetal-thioacetal reaction drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. Sato and J. Otera), 55 Ito), 149 C12 Tungsten X-ray diffraction Preparation and some reactions of bis(7>-cyclopentadienyl)hy- Preparation and characterization of j-alkyne-hexacarbonyldico- drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. balt complexes derived from 1,1'-dialkynylferrocene. Molecu- Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. lar structures of {(°-C;H ,C=CPh), Fe}{Co(CO),}, and {(n°- Ito), 149 C;H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. Preparation and structure of the first ansa-molybdenocene and Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), tungstenocene derivatives. Reaction of [O(SiMe,C;H,4)>]- 195 MoH, with methyl methacrylate to probe the olefin attacking Reactions of sterically congested secondary silanes with iron site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. carbonyls. Formation of y-silylene complexes Fe (CO),.(u- Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 SiR) (R = mesityl and O(2,6-'Pr,C,H,)) (H. Tobita, I. Shi- Reaction courses for formation of early transition metal phenox- nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- Kai and N. Kanehisa), 105 clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- Synthesis and reactivity of platinum-containing heterodinuclear taining three different chiralities in one molecule (M. Uno, K. complexes with methyl and 1,2-bis(diphenylphosphino)ethane Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - S. Takahashi), 303 THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Synthesis and X-ray structure of the divalent and trivalent ytter- Mizuho and S. Komiya), 139 bium-molybdenum complexes Yb''(HMPA),(4-OCMo(CO),- Cp), and [Yb"(HMPA),(4-OCMo(CO),Cp)\[CpMo(CO),] Unsaturated compounds - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Silicon—carbon unsaturated compounds... XLVIII. Synthesis and reactions of silicon analogs of lithium enolates (J. Ohshita, Y. Ytterbium Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano Synthesis and X-ray structure of the divalent and trivalent ytter- and T. Yamabe), 15 bium-molybdenum complexes Yb!" (HMPA),(u-OCMo(CO),- Cp), and [Yb"'(HMPA).(u-OCMo(CO),Cp)I[CpMo(CO);], Vinyl carbene - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Diversity in the reaction modes of anionic and cationic stannyl reagents: y-chloro allylstannanes as a vinyl carbene equiva- Zirconium lent, and its application for (+)-bakuchiol synthesis (J. Fuji- Highly regioselective reaction of zirconocene-alkene complexes wara and T. Sato), 63 with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- Vinyloxirane yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Studies on organosilicon chemistry. CXXII. Reaction of 2- Saburi), 117 oxiranylallylsilanes with acetals. Direct introduction of a vinyl- Reaction courses for formation of early transition metal phenox- oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. and A. Hosomi), Cl Kai and N. Kanehisa), 105

ebook img

Journal of Organometallic Chemistry 1994: Vol 473 Index PDF

11 Pages·1994·2.5 MB·English
by  
#periodicals #sim_microfilm #pub_journal-of-organometallic-chemistry
Save to my drive
Quick download
Download
Upgrade Premium
Most books are stored in the elastic cloud where traffic is expensive. For this reason, we have a limit on daily download.

Preview Journal of Organometallic Chemistry 1994: Vol 473 Index

Journal of Organometallic Chemistry, 473 (1994) C3-—C4 Author Index of Volume 473 Abe, M., 187 Kato, A., 313 Ogino, H., 187 Adachi, T., 195, 225 Kato, S., 71 Ogoshi, H., 323 Aida, K.-i., 101 Kato, T., 323 Ohnuki, S., 187 Akita, M., 175 Kawachi, A., 29 Ohshita, J., 15 Akiyama, T., 313 Kobayashi, K., 155 Ohsumi, K., Cl Ando, K., 303 Komatsuzaki, N., 303 Onitsuka, K., 195 Aoki, K., 285 Komiya, S., 139 Osakada, K., 359 Aoyagi, K., 117 Kondo, T., 163 Otera, J., 55 Asai, T., 323 Kotora, M., 117 Otsuji, Y., 35, 215 Kubo, K., 243 Otsuka, Y., 195 Baba, K., 225 Kyushin, S., 19 Ozawa, F., 265 Chatani, N., 335 Ren, J.-G., 149 Chiba, H., 45 Maeda, M., 155 Rousset, C.J., 117 Chiba, T., 205 Mandai, T., 343 Chihara, T., 273 Maruyama, Y., 257 Saburi, M., 117 Chosa, J.-i., 35 Masaoka, S., 15 Sadashima, T., 139 Masaoka, Y., 15 Saida, Y., 353 Fujita, T., 243 Mashima, K., 85 Saitoh, M., 285 Fujiwara, J., 63 Masuda, K., 285 Sakamoto, T., 257 Fujiwara, Y., 329 Matsumoto, H., 19 Sato, M., 19 Fukui, H., 295 Matsumoto, T., 343 Sato, T., 55, 63 Fukuoka, A., 139 Matsuoka, S., 343 Sawada, M., 303 Fukuzawa, S.-i., 205 Matsuzaka, H., 1 Sezaki, T., 257 Minato, M., 149 Goto, F., 225 Mise, T.. 155 Shimizu, I., 155, 257 Goto, M., 19 Miura, K., Cl Shinagawa, I., 187 Singh, J.D., 205 Miyake, M., 19 Hasegawa, M., 117 Miyashita, A., 353 Sone, Y., 163 Hayashi, T., 129, 323 Miyata, T., 329 Sonoda, N., 71 Hidai, M., 1 Miyoshi, K., 243 Sonogashira, K., 195 Hirakawa, H., 175 Mizobe, Y., 1 Sugimori, A., 313 Hisamatsu, N., 313 Mizuho, Y., 139 Sugino, T., 71 Hojo, M., Cl Mizuno, K., 35 Sugiura, T., 139 Hosomi, A., Cl Mochida, K., 45 Sugiyama, T., 313 Hotta, M., 353 Morimoto, T., 335 Suzuki, F., 149 Hou, Z., 101 Moro-oka, Y., 175, 295 Suzuki, H., 295 Suzuki, N., 117 Murai, S., 335 Igarashi, T., 149 Murakami, M., 93 Ikarugi, M., 19 Muto, T., 335 Tachibana, A., 15 Ishibashi, N., Cl Takagi, Y., 101 Ishii, N., 175 Takahashi, S., 303 Ishikawa, M., 15 Nakagawa, Y., 29 Takahashi, T., 117 lto, T., 149 Nakajima, T., 155 Takaki, K., 329 Ito, Y., 29, 93 Nakamura, A., 85, 105 Takaya, H., 85, 253 Itoh, K., 215, 285 Nakanishi, K., 35 Takei, K., 105 Izumi, H., 187 Nakanishi, S., 215 Takizawa, T., 359 Izumi, Y., 19 Nakata, K., 329 Tamao, K., 29 Nakayama, Y., 85, 105 Tanaka, M., 295, 359 Kai, Y., 85, 105 Nakazawa, H., 243 Tanaka, T., 225, 303 Kajitani, M., 313 Ninomiya, K., 313 Taniguchi, Y., 329 Kakigano, T., 295 Nishibayashi, Y., 205 Tao, X.-Q., 195 Kambe, N., 71 Nishimura, H., 129 Tekawa, M., 257 Kanda, T., 71 Nitto, Y., 117 Terada, M., 175 Kanehisa, N., 85, 105 Nozaki, K., 253 Tobita, H., 187 Kaneko, T., 323 Nozawa, S.-h., 313 Tokunaga, T., 149 C4 Tomita, H., 149 Uemura, S., 205 Yamamoto, A., xi, 257, 265 Tono, M., 313 Uno, M., 303 Yamamoto, T., 359 Tsuda, T., 303 Yamamoto, Y., 155 Tsuji, J., 343 Wakatsuki, Y., 101, 155 Yamaoka, Y., 329 Tsuji, Y., 163 Wang, W.-Q., 195 Yamazaki, H., 273 Tsujiguchi, Y., 343 Watanabe, Y., 163 Yano, T., 15 Tsunakawa, S., 19 Wu, X., 139 Yasuda, H., 105 Ueda, T., 225 Yamabe, T., 15 Yoshida, M., 253 Uemura, M., 129 Yamagami, I., 265 Yoshida, T., 195, 225 Journal of Organometallic Chemistry, 473 (1994) C5-C12 Subject Index of Volume 473 Acetal Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), Studies on organosilicon chemistry. CXXII. Reaction of 2- 195 oxiranylallylsilanes with acetals. Direct introduction of a vinyl- Towards novel organic synthesis on multimetallic centres: synthe- oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura ses and reactivities of dinuclear ruthenium thiolate complexes and A. Hosomi), Cl (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 2-Acetoxy-2-phenylacetaldehyde monothioacetal 2-Alkynyl carbonate Mechanistic insight into the cinnamylmetal-thioacetal reaction Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- Sato and J. Otera), 55 plex vs. allenylpalladium complex as intermediates (T. Acetylene Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. Preparation of vinylgermanes and a germole by the Pd-catalyzed Tsuji), 343 reactions of Me;GeCn with acetylenes (N. Chatani, T. Mori- 2-Alkynyl formate moto, T. Muto and S. Murai), 335 Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Alcohol elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- Carbene insertion into oxygen—hydrogen bonds by metallopor- plex vs. allenylpalladium complex as intermediates (T. phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. H. Ogoshi), 323 Tsuji), 343 Aldehyde Allyl Highly regioselective reaction of zirconocene-alkene complexes Conjugate addition of allylic groups to a,B-unsaturated carbonyl with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- compounds via (7-allyl)Fe(CO),NO complexes (K. Itoh, S. yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Nakanishi and Y. Otsuji), 215 Saburi), 117 Generation of allyl- and benzyllithiums from the corresponding Reaction of RuH ,(PMe;), with benzaldehyde. Formation of novel halides by the aid of lithium—tellurium exchange reactions (T. oxametallacycle and metallacycloketone complexes via C-H Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Ruthenium-catalysed reductive cleavage of allylic esters with Yamamoto), 265 formic acid and triethylamine. Application to short-step syn- Alkane activation thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Palladium(II) and/or copper(II)-catalyzed carboxylation of small Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 alkanes such as methane and ethane with carbon monoxide Syntheses and reactivities of ferrocenyl organyl tellurides (Y. (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. and Y. Fujiwara), 329 Fukuzawa), 205 Alkene Allylation Photochemical carbon-silicon bond forming reaction on Studies on organosilicon chemistry. CXXII. Reaction of 2- electron-deficient alkenes by disilanes and polysilanes via oxiranylallylsilanes with acetals. Direct introduction of a vinyl- photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura Chosa and Y. Otsuji), 35 and A. Hosomi), C1 Alkoxide Allylsilane Mono- and dinuclear alkoxide copper complexes with PPh, lig- Studies on organosilicon chemistry. CXXII. Reaction of 2- ands (K. Osakada, T. Takizawa, M. Tanaka and T. Ya- oxiranylallylsilanes with acetals. Direct introduction of a vinyl- mamoto), 359 oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura Preparation and some reactions of bis(7>-cyclopentadienyl)hy- and A. Hosomi), Cl drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. Allyltin Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. Diversity in the reaction modes of anionic and cationic stannyl Ito), 149 reagents: y-chloro allylstannanes as a vinyl carbene equiva- Alkyl iodide lent, and its application for (+)-bakuchiol synthesis (J. Fuji- Photo-, electro-, and thermal carbonylation of alkyl iodides in the wara and T. Sato), 63 presence of Group 7 and 8-10 metal carbonyl catalysts (T. Amino substitution Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 Synthesis by the Arbuzov-like dealkylation reaction, characteriza- Alkyne tion, and reactivity of phosphonate and amino-substituted Preparation and characterization of p-alkyne-hexacarbonyldico- phosphonate ruthenium complexes, [(7°-C;H,;CO),Ru{P- balt complexes derived from 1,1’-dialkynylferrocene. Molecu- (OKOR),(NC,Hg)>_,,}] (n = 0-2), and comparison with the lar structures of {(5-C;H ,C=CPh), Fe}{Co(CO),}, and {(n°- iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. C;H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. Miyoshi), 243 C6 Benzyl Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,C- Generation of allyl- and benzyllithiums from the corresponding (CO),,(CH,)] as catalyst precursor for hydrogenation of halides by the aid of lithium—tellurium exchange reactions (T. olefins. Syntheses and structures of unsaturated and saturated Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and Selective sp* C-H bond activation of alkylaromatics promoted by [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 platinum complexes (A. Miyashita, M. Hotta and Y. Saida), Preparation and characterization of u-alkyne-hexacarbonyldico- 353 balt complexes derived from 1,1’-dialkynylferrocene. Molecu- Syntheses and reactivities of ferrocenyl organyl tellurides (Y. lar structures of {(7°-C;H,C=CPh), Fe}{Co,(CO),}, and {(°- Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. C5H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. Fukuzawa), 205 Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), Bifunctional reagent 195 Diversity in the reaction modes of anionic and cationic stannyl Reactions of sterically congested secondary silanes with iron reagents: y-chloro allylstannanes as a vinyl carbene equiva- carbonyls. Formation of y-silylene complexes Fe,(CO),(u- lent, and its application for (+ )-bakuchiol synthesis (J. Fuji- SiR, )( R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, I. Shi- wara and T. Sato), 63 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Bond activation Synthesis and X-ray structure of the divalent and trivalent ytter- Interconversion between (C;R,)Ru!(aliyl) and (C;R;)Ru"'(di- bium-molybdenum complexes Yb''(HMPA),(u-OCMo(CO),- ene) complexes (K. Masuda, M. Saitoh, K. Aoki and K. Itoh), Cp), and [Yb"'(HMPA).(u-OCMo(CO)>,Cp)I[CpMo(CO);], 285 - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Selective sp*> C-H bond activation of alkylaromatics promoted by Unusual reactivities of (u-n?:n?-FP—C=C-H)Co(CO),, the platinum complexes (A. Miyashita, M. Hotta and Y. Saida), adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis 353 and reduction with hydrosilanes giving polynuclear complexes, Bond cleavage (CP), Fe,Co3(ws5-C=CH\CO)i9, (u-CH=CH)[(— p3 - Carbon-carbon bond cleavage and skeletal rearrangement of C)Co(CO),], and CpFeCo,(u-C=CCOH), (M. Akita, M. coordinated norbornadiene. Preparation of a 7°-6-methyl- Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 fulvene complex [(C;Me,;)Ru(C;H,CH)]CBHF, (H. Suzuki, Carbonylation T. Kakigano, H. Fukui, M. Tanaka and Y. Moro-oka), 295 Photo-, electro-, and thermal carbonylation of alkyl iodides in the Bridging ligand presence of Group 7 and 8-10 metal carbonyl catalysts (T. Preparation and structure of the first ansa-molybdenocene and Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 tungstenocene derivatives. Reaction of [O(SiMe,C;H,),]JMo- Catalysis H, with methyl methacrylate to probe the olefin attacking site Carbene insertion into oxygen—hydrogen bonds by metallopor- (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. Shimizu, phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Y. Yamamoto and Y. Wakatsuki), 155 H. Ogoshi), 323 Bulky ligands Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Carbene insertion into oxygen—hydrogen bonds by metallopor- elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and plex vs. allenylpalladium complex as intermediates (T. H. Ogoshi), 323 Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. Tsuji), 343 Carbene Photo-, electro-, and thermal carbonylation of alkyl iodides in the Carbene insertion into oxygen—hydrogen bonds by metallopor- presence of Group 7 and 8-10 metal carbonyl catalysts (T. phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 H. Ogoshi), 323 Carbide Preparation of vinylgermanes and a germole by the Pd-catalyzed reactions of Me,;GeCn with acetylenes (N. Chatani, T. Mori- Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,C- moto, T. Muto and S. Murai), 335 (CO),,(CH,)] as catalyst precursor for hydrogenation of Reaction rate enhancement by addition of anionic surfactant olefins. Syntheses and structures of unsaturated and saturated hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and SDS in the ruthenium catalyzed hydrogen transfer from a [PPN][Ru,C(CO),,,H] (T. Chihara and H. Yamazaki), 273 1,4-diol to 4-phenyl-3-buten-2-one (K. Nozaki, M. Yoshida and H. Takaya), 253 Carbon-carbon bond formation Ruthenium-catalysed reductive cleavage of allylic esters with Carbon-carbon bond forming reactions via new organosamar- formic acid and triethylamine. Application to short-step syn- ium(II]) intermediates (M. Murakami and Y. Ito), 93 thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Highly regioselective reaction of zirconocene-alkene complexes Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- Catalyst precursor yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,- Saburi), 117 C(CO),.(CH3)] as catalyst precursor for hydrogenation of Carbon monoxide Palladium(ID and/or copper(I1)-catalyzed carboxylation of small olefins. Syntheses and structures of unsaturated and saturated hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and alkanes such as methane and ethane with carbon monoxide [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki and Y. Fujiwara), 329 Catalytic asymmetric cross-coupling Carbonyl Catalytic asymmetric induction of planar chirality: Palladium- catalyzed asymmetric cross-coupling of meso tricarbonyl(a- Conjugate addition of allylic groups to a,B-unsaturated carbonyl rene)chromium complexes with alkenyl- and arylboronic acids compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. Nakanishi and Y. Otsuji), 215 (M. Uemura, H. Nishimura and T. Hayashi), 129 Charge transfer Conjugated enyne Molecular structures and charge-transfer complexes of cis-di- Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and benzo[c,h]-1,6-disilabicyclo[4.4.0]deca-3,8-dienes and bi(ben- elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- zo[c |silacyclopent-3-ene-1-yl)s (S. Kyushin, M. Ikarugi, S. plex vs. allenylpalladium complex as intermediates (T. Tsunakawa, Y. Izumi, M. Miyake, M. Sato, H. Matsumoto Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. and M. Goto), 19 Tsuji), 343 Chiral ligand Copper Catalytic asymmetric induction of planar chirality: Palladium- Mono- and dinuclear alkoxide copper complexes with PPh, lig- catalyzed asymmetric cross-coupling of meso tricarbo- ands (K. Osakada, T. Takizawa, M. Tanaka and T. Ya- nyl(arene)chromium complexes with alkenyl- and arylboronic mamoto), 359 acids (M. Uemura, H. Nishimura and T. Hayashi), 129 Palladium(II) and/or copper(II)-catalyzed carboxylation of small (Arene)chromium alkanes such as methane and ethane with carbon monoxide Catalytic asymmetric induction of planar chirality: Palladium- (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki catalyzed asymmetric cross-coupling of meso tricarbo- and Y. Fujiwara), 329 nyl(arene)chromium complexes with alkenyl- and arylboronic Crown thioethers acids (M. Uemura, H. Nishimura and T. Hayashi), 129 Ruthenium(II) hydrido complexes of quadridentate crown Cinnamylmetal-thioacetal reaction thioethers, trans-RuH(ClXsyn-L) (L = Me,{14]JaneS,, Me,- Mechanistic insight into the cinnamylmetal-thioacetal reaction [15]aneS,, Me,{16]aneS,) and {Ru,H(u-H)CIK(syn-Me,{14]- employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. aneS,).}Cl containing a linear Ru-H-Ru bond. Novel char- Sato and J. Otera), 55 acteristics of syn-crown thioethers affecting discrimination of Cluster axial ligands and geometry of the unsupported Ru-H-Ru Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,- linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba C(CO),,(CH;3)] as catalyst precursor for hydrogenation of and T. Tanaka), 225 olefins. Syntheses and structures of unsaturated and saturated Crystal structure hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 Kawachi, Y. Nakagawa and Y. Ito), 29 Towards novel organic synthesis on multimetallic centres: synthe- Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- ses and reactivities of dinuclear ruthenium thiolate complexes clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 taining three different chiralities in one molecule (M. Uno, K. Cobalt Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- S. Takahashi), 303 ture, and properties of (n>-cyclopentadienyl or 7>pen- Synthesis and X-ray structure of the divalent and trivalent ytter- tamethylcyclopentadieny! 1-phenylmethanimine-N, 1-dithiol- bium-molybdenum complexes Yb!'(HMPA),(u-OCMo- ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. (CO),Cp), and [Yb"(HMPA)<(4-OCMo(CO),Cp)][CpMo- Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama (CO)3],- THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakat- and A. Sugimori), 313 suki), 101 Preparation and characterization of p-alkyne-hexacarbonyldico- Cyanide balt complexes derived from 1,1'-dialkynylferrocene. Molecu- Preparation of vinylgermanes and a germole by the Pd-catalyzed lar structures of {(n°-C;H ,C=CPh), Fe}{Co,(CO),}, and {(n°- reactions of Me,GeCn with acetylenes (N. Chatani, T. Mori- C;H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. moto, T. Muto and S. Murai), 335 Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), Cyclobutadiene 195 Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- Synthesis and reactivity of platinum-containing heterodinuclear clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- complexes with methyl and 1,2-bis(diphenylphosphino)ethane taining three different chiralities in one molecule (M. Uno, K. ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. S. Takahashi), 303 Mizuho and S. Komiya), 139 Cyclooctatetraenyl Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- A new convenient preparation of monocyclooctatetraenyl- clopentadieny!)cobalt(tetraarylcyclobutadiene) complexes con- lanthanide complexes from metallic lanthanides and oxidants taining three different chiralities in one molecule (M. Uno, K. (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and Kai and H. Takaya), 85 S. Takahashi), 303 Cyclopentadienyl Unusual reactivities of (y-n?:n?-FP—C=C-H)Co,(CO),, the Preparation and some reactions of bis(7>-cyclopentadienyl)hy- adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. and reduction with hydrosilanes giving polynuclear complexes, Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. (CP), Fe ,Co3(45-C=CH\CO),9, (u-CH=CH)[(- p3- Ito), 149 C)Co,(CO),], and CpFeCo,(-C=CH ,{CO), (M. Akita, M. Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 Dimerization 1,2,5,3-Cobaltadithiazole Reaction of RuH,(PMe,), with benzaldehyde. Formation of novel A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- oxametallacycle and metallacycloketone complexes via C-H ture, and properties of (n°-cyclopentadienyl or 1°pen- bond activation of aldehyde (F. Ozawa, I. Yamagami and A. tamethylcyclopentadienyl1-phenylmethanimi|-ndeit-hNio,l - Yamamoto), 265 ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. (Amino)disilane Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. and A. Sugimori), 313 Kawachi, Y. Nakagawa and Y. Ito), 29 C8 Disubstituted alkyne Group 9 Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Photo-, electro-, and thermal carbonylation of alkyl iodides in the elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- presence of Group 7 and 8-10 metal carbonyl catalysts (T. plex vs. allenylpalladium complex as intermediates (T. Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 Mandai, T. Matsumoto, Y. Tsujiguchi, S$. Matsuoka and J. Group 10 Tsuji), 343 Photo-, electro-, and thermal carbonylation of alkyl iodides in the Dithiolate presence of Group 7 and 8-10 metal carbonyl catalysts (T. A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 ture, and properties of (n>-cyclopentadienyl or n> pen- Group 14 tamethylcyclopentadienyl 1-phenylmethanimine-N, |-dithiol- Photochemical carbon-silicon bond forming reaction on ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. electron-deficient alkenes by disilanes and polysilanes via Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. and A. Sugimori), 313 Chosa and Y. Otsuji), 35 Electronic spectra Halide Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. Generation of allyl- and benzyllithiums from the corresponding Kawachi, Y. Nakagawa and Y. Ito), 29 halides by the aid of lithium—tellurium exchange reactions (T. Electron transfer Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 Photochemical carbon-silicon bond forming reaction on Heterobimetallics electron-deficient alkenes by disilanes and polysilanes via Synthesis and reactivity of platinum-containing heterodinuclear photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. complexes with methyl and 1,2-bis(diphenylphosphino)ethane Chosa and Y. Otsuji), 35 ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - Ethane THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Palladium(II) and/or copper(II)-catalyzed carboxylation of small Mizuho and S. Komiya), 139 alkanes such as methane and ethane with carbon monoxide Hydride (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki Preparation and some reactions of bis(7°-cyclopentadienyl)hy- and Y. Fujiwara), 329 drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. Extended Hiickel calculations Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. Ruthenium(II) hydrido complexes of quadridentate crown Ito), 149 thioethers, trans-RuH(ClXsyn-L) (L = Me,{14JaneS,, Me,- Reaction of RuH ,(PMe,), with benzaldehyde. Formation of novel [1SJaneS,, Me,{16JaneS,) and {Ru,H(y-H)CK(syn-Me,[14]- oxametallacycle and metallacycloketone complexes via C-H aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- bond activation of aldehyde (F. Ozawa, I. Yamagami and A. acteristics of syn-crown thioethers affecting discrimination of Yamamoto), 265 axial ligands and geometry of the unsupported Ru-H-Ru Hydrogen bonding linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba Reaction of RuH ,(PMe,), with benzaldehyde. Formation of novel and T. Tanaka), 225 oxametallacycle and metallacycloketone complexes via C-—H bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Ferrocene Yamamoto), 265 Preparation and characterization of y-alkyne-hexacarbonyldico- Hydrogen transfer balt complexes derived from 1,1’-dialkynylferrocene. Molecu- Reaction rate enhancement by addition of anionic surfactant lar structures of {(n°-C;H 4C=CPh), Fe}{Co,(CO),}, and {(n°- C5H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. SDS in the ruthenium catalyzed hydrogen transfer from a 1,4-diol to 4-phenyl-3-buten-2-one (K. Nozaki, M. Yoshida Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), and H. Takaya), 253 195 Syntheses and reactivities of ferrocenyl organyl tellurides (Y. Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. Interconversion Fukuzawa), 205 Interconversion between (C;R5)Ru'(allyl) and (C;R,)Ru'(di- Formic acid ene) complexes (K. Masuda, M. Saitoh, K. Aoki and K. Itoh), Ruthenium-catalysed reductive cleavage of allylic esters with 285 formic acid and triethylamine. Application to short-step syn- Iron thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Conjugate addition of allylic groups to a,B-unsaturated carbonyl Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. Nakanishi and Y. Otsuji), 215 Germanium Reactions of sterically congested secondary silanes with iron Preparation of vinylgermanes and a germole by the Pd-catalyzed carbonyls. Formation of y-silylene complexes Fe,(CO),(y- reactions of Me,GeCn with acetylenes (N. Chatani, T. Mori- SiR) (R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, 1. Shi- moto, T. Muto and S. Murai), 335 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Group 7 Synthesis and reactivity of platinum-containing heterodinuclear Photo-, electro-, and thermal carbonylation of alkyl iodides in the complexes with methyl and 1,2-bis(diphenylphosphino)ethane presence of Group 7 and 8-10 metal carbonyl catalysts (T. ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Group 8 Mizuho and S. Komiya), 139 Photo-, electro-, and thermal carbonylation of alkyl iodides in the Unusual reactivities of (u-n?:n?-FP-C=C-H)Co,(CO),, the presence of Group 7 and 8-10 metal carbonyl catalysts (T. adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis Kondo, Y. Sone, Y. Tsuji and Y. Watanabe), 163 and reduction with hydrosilanes giving polynuclear complexes, C9 (CP), Fe,Co3("5-C=CH\(CO)i9, (u-CH=CH)[(p-3 - Reaction of RuH ,(PMe3), with benzaldehyde. Formation of novel C)Co(CO)o], and CpFeCo ;(-C=CH 5 (CO), (M. Akita, M. oxametallacycle and metallacycloketone complexes via C-H Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Yamamoto), 265 Ketone Towards novel organic synthesis on multimetallic centres: synthe- Conjugate addition of allylic groups to a,B-unsaturated carbonyl ses and reactivities of dinuclear ruthenium thiolate complexes compounds via (7°-allyl)Fe(CO),NO complexes (K. Itoh, S. (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 Nakanishi and Y. Otsuji), 215 Metallocenes Highly regioselective reaction of zirconocene-alkene complexes Highly regioselective reaction of zirconocene-alkene complexes with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Saburi), 117 Saburi), 117 Ketone dianion Preparation and structure of the first ansa-molybdenocene and Synthesis and X-ray structure of the divalent and trivalent ytter- tungstenocene derivatives. Reaction of [O(SiMe,C;H,)>}- bium-molybdenum complexes Yb'(HMPA),(u-OCMo(CO),- MoH, with methyl methacrylate to probe the olefin attacking Cp), and [Yb"(HMPA).(4.-OCMo(CO),Cp)I[CpMo(CO),], site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 Methane Palladium(I]) and/or copper(II)-catalyzed carboxylation of small Lanthanide alkanes such as methane and ethane with carbon monoxide A new convenient preparation of monocyclooctatetraenyl- (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki lanthanide complexes from metallic lanthanides and oxidants and Y. Fujiwara), 329 (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Methyl methacrylate Kai and H. Takaya), 85 Preparation and structure of the first ansa-molybdenocene and Lewis acid tungstenocene derivatives. Reaction of [O(SiMe,C;H,),]- Diversity in the reaction modes of anionic and cationic stannyl MoH, with methyl methacrylate to probe the olefin attacking reagents: y-chloro allylstannanes as a vinyl carbene equiva- site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. lent, and its application for (+ )-bakuchiol synthesis (J. Fuji- Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 wara and T. Sato), 63 Molybdenum Linear Ru-H-Ru bond Preparation and some reactions of bis(n>-cyclopentadienyl)hy- Ruthenium(II]) hydrido complexes of quadridentate crown drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. thioethers, trans-RuH(ClXsyn-L) (L = Me,[14JaneS,, Me,- Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. [15JaneS,, Me,{l6JaneS,) and {Ru jH(u-H)CiK(syn-Me,[14]- Ito), 149 aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- Preparation and structure of the first ansa-molybdenocene and acteristics of syn-crown thioethers affecting discrimination of tungstenocene derivatives. Reaction of [O(SiMe,C;H,)>]- axial ligands and geometry of the unsupported Ru-H-Ru MoH, with methyl methacrylate to probe the olefin attacking linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. and T. Tanaka), 225 Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 Lithium Synthesis and reactivity of platinum-containing heterodinuclear Generation of allyl- and benzyllithiums from the corresponding complexes with methyl and 1,2-bis(diphenylphosphino)ethane halides by the aid of lithium—tellurium exchange reactions (T. ligands. X-Ray crystal structure of (dpe)MePt—FeCp(CO), - Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Silicon—carbon unsaturated compounds.. XLVIII. Synthesis and Mizuho and S. Komiya), 139 reactions of silicon analogs of lithium enolates (J. Ohshita, Y. Synthesis and X-ray structure of the divalent and trivalent ytter- Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano bium-molybdenum complexes Yb"!(HMPA),( 1-OCMo(CO),- and T. Yamabe), 15 Cp), and [Yb""'(HMPA).(4-OCMo(CO)>Cp)I[CpMo(CO),]}, Lithium enolates - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Silicon—carbon unsaturated compounds.. XLVIII. Synthesis and Monoterpene reactions of silicon analogs of lithium enolates (J. Ohshita, Y. Diversity in the reaction modes of anionic and cationic stannyl Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano reagents: y-chloro allylstannanes as a vinyl carbene equiva- and T. Yamabe), 15 lent, and its application for (+)-bakuchiol synthesis (J. Fuji- wara and T. Sato), 63 Manganese Synthesis and reactivity of platinum-containing heterodinuclear complexes with methyl and 1,2-bis(diphenylphosphino)ethane Niobium ligands. X-Ray crystal structure of (dpe)MePt—FeCp(CO), - Reaction courses for formation of early transition metal phenox- THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. Mizuho and S. Komiya), 139 Kai and N. Kanehisa), 105 Metallacycle Nitrosyl A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, struc- Conjugate addition of allylic groups to a,B-unsaturated carbonyl ture, and properties of (m°-cyclopentadienyl or 7°pen- compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. tamethylcyclopentadienyl)(1-phenylmethanim|i-ndiet-hNio,l - Nakanishi and Y. Otsuji), 215 ato)cobalt(III) (A. Kato, M. Tono, N. Hisamatsu, S.-h. Norbornadiene Nozawa, K. Ninomiya, T. Sugiyama, M. Kajitani, T. Akiyama Carbon-—carbon bond cleavage and skeletal rearrangement of and A. Sugimori), 313 coordinated norbornadiene. Preparation of a 7°-6-methyl- fulvene complex [(C;Me,)Ru(C;H,CHCH )]BF, (H. Suzuki, Platinum T. Kakigano, H. Fukui, M. Tanaka and Y. Moro-oka), 295 Selective sp> C-H bond activation of alkylaromatics promoted by platinum complexes (A. Miyashita, M. Hotta and Y. Saida), 353 Optical resolution Synthesis and reactivity of platinum-containing heterodinuclear Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- complexes with methyl and 1,2-bis(diphenylphosphino)ethane clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- ligands. X-Ray crystal structure of (dpe)MePt—FeCp(CO), - taining three different chiralities in one molecule (M. Uno, K. THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and Mizuho and S. Komiya), 139 S. Takahashi), 303 Polynuclear Organic synthesis Unusual reactivities of (u-n*:n?-FP-C=C-H)Co,(CO),, the Diversity in the reaction modes of anionic and cationic stannyl adducts of FP—C=C-H to Co,(CO),: photolysis, thermolysis reagents: y-chloro allylstannanes as a vinyl carbene equiva- and reduction with hydrosilanes giving polynuclear complexes, lent, and its application for (+)-bakuchiol synthesis (J. Fuji- (CP), Fe,Co3(u5-C=CH\CO),), (u-CH=CH)[(- p3- wara and T. Sato), 63 C)Co,(CO).], and CpFeCo(u-C=CCOH), (M. Akita, M. Oxidation Terada, N. Ishii, H. Hirakawa and Y. Moro-oka), 175 Syntheses and reactivities of ferrocenyl organyl tellurides (Y. Porphyrin Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. Carbene insertion into oxygen—hydrogen bonds by metallopor- Fukuzawa), 205 phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and Oxidative addition H. Ogoshi), 323 Towards novel organic synthesis on multimetallic centres: synthe- ses and reactivities of dinuclear ruthenium thiolate complexes (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 Radical Selective sp> C-H bond activation of alkylaromatics promoted by platinum complexes (A. Miyashita, M. Hotta and Y. Saida), Palladium 353 Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and Reductive cleavage elimination of 2-alkynyl carbonates. 2-Alkynylpalladium com- Ruthenium-catalysed reductive cleavage of allylic esters with plex vs. allenylpalladium complex as intermediates (T. formic acid and triethylamine. Application to short-step syn- Mandai, T. Matsumoto, Y. Tsujiguchi, S. Matsuoka and J. thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. Tsuji), 343 Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 Palladium(II) and/or copper(II)-catalyzed carboxylation of small Rhodium alkanes such as methane and ethane with carbon monoxide Carbene insertion into oxygen—hydrogen bonds by metallopor- (K. Nakata, Y. Yamaoka, T. Miyata, Y. Taniguchi, K. Takaki phyrin catalysts (T. Hayashi, T. Kato, T. Kaneko, T. Asai and and Y. Fujiwara), 329 H. Ogoshi), 323 Preparation of vinylgermanes and a germole by the Pd-catalyzed Ruthenium reactions of Me,GeCn with acetylenes (N. Chatani, T. Mori- Carbon-carbon bond cleavage and skeletal rearrangement of moto, T. Muto and S. Murai), 335 coordinated norbornadiene. Preparation of a 7°-6-methyl- Phosphite fulvene complex [((C;Me;)Ru(C;H,C,H)C]BHF , (H. Suzuki, Synthesis by the Arbuzov-like dealkylation reaction, characteriza- T. Kakigano, H. Fukui, M. Tanaka and Y. Moro-oka), 295 tion, and reactivity of phosphonate and amino-substituted Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru,- phosphonate ruthenium complexes, [(n°-C;H;)CO),- C(CO),,(CH;)] as catalyst precursor for hydrogenation of Ru{P(OKOR),(NC,Hg)>_,,}] (n = 0-2), and comparison with olefins. Syntheses and structures of unsaturated and saturated the iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. hexaruthenium hydrido clusters [PPN][Ru,C(CO),;H] and Miyoshi), 243 [PPN][Ru,C(CO),,H] (T. Chihara and H. Yamazaki), 273 Phosphonate Interconversion between (C;R;)Ru'Y(allyl) and (C;R;)Ru"(di- Synthesis by the Arbuzov-like dealkylation reaction, characteriza- ene) complexes (K. Masuda, M. Saitoh, K. Aoki and K. Itoh), tion, and reactivity of phosphonate and amino-substituted 285 phosphonate ruthenium complexes, [(n°-C;H;)CO),- Reaction of RuH,(PMe;), with benzaldehyde. Formation of novel Ru{P(OKOR),(NC,4Hg)>_,,}] (2 = 0-2), and comparison with oxametallacycle and metallacycloketone complexes via C-H the iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. bond activation of aldehyde (F. Ozawa, I. Yamagami and A. Miyoshi), 243 Yamamoto), 265 Photochemistry Reaction rate enhancement by addition of anionic surfactant Photochemical carbon-silicon bond forming reaction on SDS in the ruthenium catalyzed hydrogen transfer from a electron-deficient alkenes by disilanes and polysilanes via 1,4-diol to 4-phenyl-3-buten-2-one (K. Nozaki, M. Yoshida photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. and H. Takaya), 253 Chosa and Y. Otsuji), 35 Ruthenium-catalysed reductive cleavage of allylic esters with Selective sp> C-H bond activation of alkylaromatics promoted by formic acid and triethylamine. Application to short-step syn- platinum complexes (A. Miyashita, M. Hotta and Y. Saida), thesis of a-hydroxy acids (Y. Maruyama, T. Sezaki, M. 353 Tekawa, T. Sakamoto, I. Shimizu and A. Yamamoto), 257 Planar chirality Ruthenium(I]) hydrido complexes of quadridentate crown Catalytic asymmetric induction of planar chirality: Palladium- thioethers, trans-RuH(ClXsyn-L) (L= Me,[14]aneS,, Me,- catalyzed asymmetric cross-coupling of meso tricarbon- [1S]aneS,, Me,{16JaneS,) and {Ru jH(y-H)CI(syn-Me,[14]- yl(arene)chromium complexes with alkenyl- and arylboronic aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- acids (M. Uemura, H. Nishimura and T. Hayashi), 129 acteristics of syn-crown thioethers affecting discrimination of Cll axial ligands and geometry of the unsupported Ru-H-Ru Molecular structures and charge-transfer complexes of cis-di- linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba benzo[c,h]-1,6-disilabicyclo[4.4.0]deca-3,8-dienes and bi(ben- and T. Tanaka), 225 zo[c]silacyclopent-3-ene-1-yl)s (S. Kyushin, M. Ikarugi, S. Synthesis by the Arbuzov-like dealkylation reaction, characteriza- Tsunakawa, Y. Izumi, M. Miyake, M. Sato, H. Matsumoto tion, and reactivity of phosphonate and amino-substituted and M. Goto), 19 phosphonate ruthenium complexes, [(n°-C;H;)(CO),- Reactions of sterically congested secondary silanes with iron Ru{P(OKOR),(NC,Hg)>_,,}] (2 = 0-2), and comparison with carbonyls. Formation of p-silylene complexes Fe ,(CO),(u- the iron analogues (H. Nakazawa, T. Fujita, K. Kubo and K. SiR) (R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, I. Shi- Miyoshi), 243 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Towards novel organic synthesis on multimetallic centres: synthe- Silicon-carbon unsaturated compounds.. XLVIII. Synthesis and ses and reactivities of dinuclear ruthenium thiolate complexes reactions of silicon analogs of lithium enolates (J. Ohshita, Y. (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano Ruthenium(II) hydrides and T. Yamabe), 15 Ruthenium(II) hydrido complexes of quadridentate crown Silyl thioethers, trans-RuH(ClXsyn-L) (L = Me,{14JaneS,, Me,- Photochemical carbon-silicon bond forming reaction on [1S5JaneS,, Meg{16]aneS,) and {Ru,H(u-H)CK(syn-Me,[14]- electron-deficient alkenes by disilanes and polysilanes via aneS,),}Cl containing a linear Ru-H-Ru bond. Novel char- photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. acteristics of syn-crown thioethers affecting discrimination of Chosa and Y. Otsuji), 35 axial ligands and geometry of the unsupported Ru-H-Ru u-Silylene linkage (T. Yoshida, T. Adachi, T. Ueda, F. Goto, K. Baba Reactions of sterically congested secondary silanes with iron and T. Tanaka), 225 carbonyls. Formation of p-silylene complexes Fe,(CO),(y- SiR) (R = mesityl and O(2,6-'Pr,C,H,)) (H. Tobita, I. Shi- nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Silyllithium Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. Kawachi, Y. Nakagawa and Y. Ito), 29 Samarium o-7 conjugation A new convenient preparation of monocyclooctatetraenyl- Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. lanthanide complexes from metallic lanthanides and oxidants Kawachi, Y. Nakagawa and Y. Ito), 29 (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Kai and H. Takaya), 85 Carbon-carbon bond forming reactions via new organosamar- ium(III) intermediates (M. Murakami and Y. Ito), 93 Secondary silanes Tantalum Reactions of sterically congested secondary silanes with iron Reaction courses for formation of early transition metal phenox- carbonyls. Formation of y-silylene complexes Fe ,(CO),(y- ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. SiR) (R = mesityl and O(2,6-'Pr,C,H)) (H. Tobita, I. Shi- Kai and N. Kanehisa), 105 nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 Tellurium Selenolate Generation of allyl- and benzyllithiums from the corresponding A new convenient preparation of monocyclooctatetraenyl- halides by the aid of lithium—tellurium exchange reactions (T. lanthanide complexes from metallic lanthanides and oxidants Kanda, S. Kato, T. Sugino, N. Kambe and N. Sonoda), 71 (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. Syntheses and reactivities of ferrocenyl organyl tellurides (Y. Kai and H. Takaya), 85 Nishibayashi, T. Chiba, J.D. Singh, S. Uemura and S.-i. Silane Fukuzawa), 205 Electronic spectra of (aminoXphenyl)disilanes (K. Tamao, A. Thiolate Kawachi, Y. Nakagawa and Y. Ito), 29 A new convenient preparation of monocyclooctatetraenyl- Photochemical carbon-silicon bond forming reaction on lanthanide complexes from metallic lanthanides and oxidants electron-deficient alkenes by disilanes and polysilanes via (K. Mashima, Y. Nakayama, A. Nakamura, N. Kanehisa, Y. photoinduced electron transfer (K. Mizuno, K. Nakanishi, J.-i. Kai and H. Takaya), 85 Chosa and Y. Otsuji), 35 Towards novel organic synthesis on multimetallic centres: synthe- Studies on organosilicon chemistry. CXXII. Reaction of 2- ses and reactivities of dinuclear ruthenium thiolate complexes oxiranylallylsilanes with acetals. Direct introduction of a vinyl- (M. Hidai, Y. Mizobe and H. Matsuzaka), 1 oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura Tin and A. Hosomi), Cl Mechanistic insight into the cinnamylmetal-thioacetal reaction Silicon employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. Conjugate addition of allylic groups to a,B-unsaturated carbonyl Sato and J. Otera), 55 compounds via (7?-allyl)Fe(CO),NO complexes (K. Itoh, S. Titanium Nakanishi and Y. Otsuji), 215 Reaction courses for formation of early transition metal phenox- Highly regioselective reaction of zirconocene-alkene complexes ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- Kai and N. Kanehisa), 105 yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Tosylato Saburi), 117 Preparation and some reactions of bis(7>-cyclopentadienyl)hy- Mechanistic insight into the cinnamylmetal-thioacetal reaction drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. employing 2-acetoxy-2-phenylacetaldehyde monothioacetal (T. Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. Sato and J. Otera), 55 Ito), 149 C12 Tungsten X-ray diffraction Preparation and some reactions of bis(7>-cyclopentadienyl)hy- Preparation and characterization of j-alkyne-hexacarbonyldico- drido(tosylato)-molybdenum and -tungsten (M. Minato, J.-G. balt complexes derived from 1,1'-dialkynylferrocene. Molecu- Ren, H. Tomita, T. Tokunaga, F. Suzuki, T. Igarashi and T. lar structures of {(°-C;H ,C=CPh), Fe}{Co(CO),}, and {(n°- Ito), 149 C;H,C=CPh), Fe}Co,(CO), (K. Onitsuka, X.-Q. Tao, W.-Q. Preparation and structure of the first ansa-molybdenocene and Wang, Y. Otsuka, K. Sonogashira, T. Adachi and T. Yoshida), tungstenocene derivatives. Reaction of [O(SiMe,C;H,4)>]- 195 MoH, with methyl methacrylate to probe the olefin attacking Reactions of sterically congested secondary silanes with iron site (T. Mise, M. Maeda, T. Nakajima, K. Kobayashi, I. carbonyls. Formation of y-silylene complexes Fe (CO),.(u- Shimizu, Y. Yamamoto and Y. Wakatsuki), 155 SiR) (R = mesityl and O(2,6-'Pr,C,H,)) (H. Tobita, I. Shi- Reaction courses for formation of early transition metal phenox- nagawa, S. Ohnuki, M. Abe, H. Izumi and H. Ogino), 187 ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. Synthesis and structure of planar-chiral (1,2,4-trisubstituted cy- Kai and N. Kanehisa), 105 clopentadienyl)cobalt(tetraarylcyclobutadiene) complexes con- Synthesis and reactivity of platinum-containing heterodinuclear taining three different chiralities in one molecule (M. Uno, K. complexes with methyl and 1,2-bis(diphenylphosphino)ethane Ando, N. Komatsuzaki, T. Tsuda, T. Tanaka, M. Sawada and ligands. X-Ray crystal structure of (dpe)MePt-FeCp(CO), - S. Takahashi), 303 THF (A. Fukuoka, T. Sadashima, T. Sugiura, X. Wu, Y. Synthesis and X-ray structure of the divalent and trivalent ytter- Mizuho and S. Komiya), 139 bium-molybdenum complexes Yb''(HMPA),(4-OCMo(CO),- Cp), and [Yb"(HMPA),(4-OCMo(CO),Cp)\[CpMo(CO),] Unsaturated compounds - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Silicon—carbon unsaturated compounds... XLVIII. Synthesis and reactions of silicon analogs of lithium enolates (J. Ohshita, Y. Ytterbium Masaoka, S. Masaoka, M. Ishikawa, A. Tachibana, T. Yano Synthesis and X-ray structure of the divalent and trivalent ytter- and T. Yamabe), 15 bium-molybdenum complexes Yb!" (HMPA),(u-OCMo(CO),- Cp), and [Yb"'(HMPA).(u-OCMo(CO),Cp)I[CpMo(CO);], Vinyl carbene - THF (Z. Hou, K.-i. Aida, Y. Takagi and Y. Wakatsuki), 101 Diversity in the reaction modes of anionic and cationic stannyl reagents: y-chloro allylstannanes as a vinyl carbene equiva- Zirconium lent, and its application for (+)-bakuchiol synthesis (J. Fuji- Highly regioselective reaction of zirconocene-alkene complexes wara and T. Sato), 63 with aldehydes or ketones (N. Suzuki, C.J. Rousset, K. Ao- Vinyloxirane yagi, M. Kotora, T. Takahashi, M. Hasegawa, Y. Nitto and M. Studies on organosilicon chemistry. CXXII. Reaction of 2- Saburi), 117 oxiranylallylsilanes with acetals. Direct introduction of a vinyl- Reaction courses for formation of early transition metal phenox- oxirane moiety (M. Hojo, N. Ishibashi, K. Ohsumi, K. Miura ides (H. Yasuda, Y. Nakayama, K. Takei, A. Nakamura, Y. and A. Hosomi), Cl Kai and N. Kanehisa), 105

See more

The list of books you might like

Upgrade Premium
Most books are stored in the elastic cloud where traffic is expensive. For this reason, we have a limit on daily download.
DMCA & Copyright: Dear all, most of the website is community built, users are uploading hundred of books everyday, which makes really hard for us to identify copyrighted material, please contact us if you want any material removed.
Copyright @ PDFdrive.to, 2022 | We love our users