Table Of Content

Journal of Organometallic Chemistry, 470 (1994) C19-C20 Author Index of Volume 470 Akabori, S., 263 Habata, Y., 263 Ohkita, K., 179, 189 Akkurt, M., 59 Haiduc, I., 93 Oro, L.A., 271 Antinolo, A., 127 Head, S.R., 73 Otero, A., 127 Asano, H., 263 Heller, D., 237 Ascenso, J.R., 147 Herbst-Irmer, R., 23 Patzke, B., 191 Hirao, T., 179, 189 Pericas, M.A., C12 Belin, C., 43 Hosokawa, T., 253 Pichon, R., 137 Ben Taleb, A., 257 Huo, S.Q., 17 Pietroni, B.R., 275 Berenguer, J.R., C15 Hwang, I.-S., 161 Pletcher, D., 109, 119 Bernardes, V., C12 Poirier, M., 43 Blaser, D., C8 Ikeda, I., 179, 189 Puff, H., 59 Bock, P.L., 73 Ingham, S.L., 153 Boese, R., C8, 191 Qian, C., 99 Borner, A., 237 Jenner, G., 257 Bovio, B., 275 Jiang, Y., 99 Raithby, P.R., 153 Bradshaw, J.D., 231 Jimeno, M.L., 271 Randaccio, L., 59 Breunig, H.J., 87, 93 Riera, A., C12 Burini, A., 275 Kadyrov, R., 237 Riera, V., 173 Kawata, Y., 263 Romao, C.C., 147 Cabeza, J.A., 173 Kergoat, R., 137 Rose, E., 131 Calhorda, M.J., 147 Khan, M.S., 153 Rose-Munch, F., 131 Calogero, S., 275 Khourzom, R., 131 Royo, G., 43 Capon, J.F., 137 King Jr., J.A., 207 Rihlicke, A., Cl Carmona, D., 271 Klingebiel, U., 35 Carré, F., 43 Koike, M., 199 Sarpal, A.S., 67 Cheng, M.-C., 161 K6k, T.R., 59 Sato, M., 263 Chin, M., 73 Kondru, R.-K., 169 Scherer, G., 271 Churchill, M., 231 Kpoton, A., 43 Schuh, W., 59 Cornen, S., 137 Kratz, T., C8 Schulz, M., 243 Corriu, R.J.P., 43 Kuhn, N., C8 Schulz, R.E., 93 Kurosawa, H., 179, 189 See, R.F., 231 Datta, S.N., 169 Sekino, M., 263 De Deus Carvalho, M., 147 Lalinde, E., C15 Semmelhack, M.F., C4 De Jestis, E., 127 Lamata, M.P., 271 Shapley, J.R., 199 Deng, D., 99 Langlois, B., 131 Sharma, H.K., 67 Denker, M., 87 Le Berre-Cosquer, N., 137 Sheldrick, W.S., 183 Dias, A.R., 147 Lewis, J., 153 Silvestru, C., 93 Dielkus, S., 23 L’Haridon, P., 137 Solooki, D., 231 Djukic, J.-P., 131 Limbach, H.-H., 271 Sonika,, 67 Durst, G.L., 73 Long, N.J., 153 Sporzynski, A., 31 Ebert, K.H., 87, 93 Sugafuji, T., 253 Elguero, J., 271 Majewski, M., 1 Sustmann, R., 191 Maringgele, W., 23 Suzuki, K., 263 Fajardo, M., 127 Martinez, F., C15 Szatytowicz, H., 31 Faleschini, P., 59 Mathur, P., 169 Ferrara, J.D., 231 Meller, A., 23 Tessier, C.A., 231 Ferrer, J., 271 Michaelsen, H., 23 Forniés, J., C15 Michalik, M., 237 Vaisserman, J., 131 Fussing, I.M.M., 109, 119 Mosbo, J.A., 73 Veiros, L.F., 147 Moyano, A., C12 Verdaguer, X., C12 Giannoccaro, P., 249 Mugnier, Y., 127 Vermani, O.P., 67 Gleave, D.M., 1 Mulla, F., 173 Vollhardt, K.P.C., 207 Gleichmann, A., 183 Murahashi, S.-I., 253 Goti, A., C4 Wagner, F.E., 275 Greene, A.E., C12 Narula, A.K., 67 Wang, H.-G., 223 C20 Wang, R.-J., 223 Wu, G., 99 Young, J.C., 43 Wang, Y., 161 Wu, Y.J., 17 Youngs, W.J., 231 Weber, L., Cl Yu, A., 223 Wei, H.-H., 161 Xi, H.-P., 223 Werner, E., 35 Zhang, Z.-Z., 223 Werner, H., 243 Yamanaka, T., 253 Zheng, P., 99 Whitby, R.J., 109, 119 Yang, L., 17 Zhu, Y.; 17 Journal of Organometallic Chemistry, 470 (1994) C21-—C28 Subject Index of Volume 470 Acetyl in the catalyzed palladium—copper oxidative carbonylation of Preparation and Mossbauer spectroscopic studies of 1’,1’’-di- amines (P. Giannoccaro), 249 acetyl- and 1’-acetyl-1’’-(1-naphthylimino-ethyl)biferrocenes Amino acid and their partially oxidized biferrocenium salts (H.-H. Wei, n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- 1.-S. Hwang, M.-C. Cheng and Y. Wang), 161 ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. Alkene Gleichmann), 183 Elimination of B-palladium hydroxide in the Pd!!-catalyzed reac- Aniline tion of methyl (a@-hydroxymethyl)acrylate with alcohols (T. Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, 253 J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 Alkoxide Annulene Synthesis of bimetallic[Sn!Y,Al!"]--oxoisopropoxyacetate and Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, --oxoisopropoxide and their acetylacetone and benzoylace- 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]Jannulene tone derivatives ( Sonika, A.K. Narula, O.P. Vermani, H.K. (HBC), 1,2 : 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Sharma and A.S. Sarpal), 67 dro[16Jannulene (QBC) and a tetracobalt complex of QBC. Alkoxyacetylene The first example of a transition metal complex of QBC (D. A convenient synthesis of hexacarbonyldicobalt complexes of Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, M. Churchill and J.D. Ferrara), 231 X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. Antimony Greene), C12 Strukturen und Reaktionen von Methylantimondihalogeniden Alkylidene und Versuche zur Darstellung von Methylantimon (H.J. Bre- The reaction of (4-H),Os ,(CO),(PPh3) with ethylene affords the unig, M. Denker und K.H. Ebert), 87 ethylidene complex (w-H),0(PsPh, 3( uC-COHC)H, ) (M. Arene Koike and J.R. Shapley), 199 Direct synthesis of (7°-arene)- tricarbonylchromium complexes Alkyne by arene displacement from tricarbonyl(7>-1-methylpyr- Ein Beitrag zur Darstellung und Reaktivitat der °-Allyliridium- role)chromium(0) (A. Goti and M.F. Semmelhack), C4 Komplexe [Ir(?-2-RC,;H,4XP'Pr;),] (M. Schulz und H. Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- Werner), 243 aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, Reaction of sodium amalgam with (y-enyne)bis(dicarbonyl-n>- J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 cyclopentadienylmolybdenum(I)) and (-n?,n>-allenyl)bis(di- Synthesis and derivative chemistry of [Ru,(u-PPh,u-OH),(7°- carbonyl-n>-cyclopentadienylmolybdenum) _ tetrafluoroborate p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 complexes. Crystal structure of [[{Mo(n°-C;H;CO),},{u- Asymmetric synthesis HC=CCH(CH ,CH)}],] (.F. Capon, S. Cornen, N. A convenient synthesis of hexacarbonyldicobalt complexes of Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, 137 X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. Synthesis and characterisation of monomeric, dimeric and poly- Greene), C12 meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. Bismuth Long and P.R. Raithby), 153 Syntheses and structures of dimesitylbismuth(II) bromide, Alkynyl Mes,BiBr, and_ bis(diphenyldithiophosphinato)mesitylbis- Unusual stabilization of cationic “M(n*-allyl)*" (M= Pt, Pd) muth(IID), MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. units by a dianionic cis-{Pt(C,F;).(C=CSiMe,),}?~ fragment Breunig, C. Silvestru and I. Haiduc), 93 (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Bond activation Allyl Thermally and photochemically induced vinyl-hydrogen activation Ein Beitrag zur Darstellung und Reaktivitat der >-Allyliridium- of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(>-cyclopentadienyl) Komplexe [Ir(7?-2-RC,H,XP'Pr;),] (M. Schulz und H. cobalt: regio- and stereospecific hydrogen migrations (J.A. Werner), 243 King Jr. and K.P.C. Vollhardt), 207 Aluminium ar-Bonding Synthesis of bimetallic{Sn!Y,Al"]-~-oxoisopropoxyacetate and n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- --oxoisopropoxide and their acetylacetone and benzoylace- ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. tone derivatives ( Sonika, A.K. Narula, O.P. Vermani, H.K. Gleichmann), 183 Sharma and A:S. Sarpal), 67 Bond nature Amine Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: Reactivity of mono- and di-methoxycarbonyl complexes of Pd!! the first estimation of the nature of the Ru!!—olefin bond (K. towards amines and copper amine complexes: role of copper Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 C22 Boracycloalkene Heterozyklen als Liganden. XX. Spektroskopische und struk- Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- turelle Charakterisierung von Pentacarbonylmetall-Kom- gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. und D. Blaser), C8 Meller), 23 Molecular orbital calculations on Fe,(CO),9(u-CO)4-Se), and Borane Fe;Ru(CO);9(4-COw4-Se), (S.N. Datta, R.-K. Kondru and Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- P. Mathur), 169 gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- Carbonylation ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. Reactivity of mono- and di-methoxycarbonyl complexes of Pd! Meller), 23 towards amines and copper amine complexes: role of copper Boron in the catalyzed palladium—copper oxidative carbonylation of Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- amines (P. Giannoccaro), 249 gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- Synthesis of aromatic acids via catalyzed methyl formate—chloro- ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. arene reactions (G. Jenner and A. Ben Taleb), 257 Meller), 23 Catalysis Boron-nitrogen compounds Elimination of B-palladium hydroxide in the Pd"-catalyzed reac- Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- tion of methyl (a@-hydroxymethyl)acrylate with alcohols (T. gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. 253 Meller), 23 Synthesis of aromatic acids via catalyzed methyl formate—chloro- Boroxin arene reactions (G. Jenner and A. Ben Taleb), 257 Can triorganoboroxins exist in a “monomeric” R-B=O form? Chloroarene MNDO calculations and ebulliometric molecular weight de- Synthesis of aromatic acids via catalyzed methyl formate—chloro- termination (A. Sporzyfski and H. Szatylowicz), 31 arene reactions (G. Jenner and A. Ben Taleb), 257 Bridging ligand Chromium Synthesis and derivative chemistry of [Ru ,(4-PPh,)u-OH),(7°- Direct synthesis of (°-arene)- tricarbonylchromium complexes p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 by arene displacement from tricarbonyl(7>-1-methylpyrrole)- Bromide chromium(0) (A. Goti and M.F. Semmelhack), C4 Syntheses and structures of dimesitylbismuth(III) bromide, Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- Mes,BiBr, and_bis(diphenyldithiophosphinato)mesitylbis- aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, muth(IID, MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 Breunig, C. Silvestru and I. Haiduc), 93 Strukturen und Reaktionen von Methylantimondihalogeniden und Versuche zur Darstellung von Methylantimon (H.J. Breu- nig, M. Denker und K.H. Ebert), 87 Cage compound Cluster Formation and structure of [Co{Ph,PN('Bu)PPh.-PP’,}, - Molecular orbital calculations on Fe,(CO),.(u-COMu4-Se), and (CO)\[Co(CO),] —- a cage molecule-pair or an ion-pair com- Fe,Ru(CO),9(u-CO)4-Se), (S.N. Datta, R.-K. Kondru and plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. P. Mathur), 169 Wang), 223 The reaction of (4O-s ,H(CO)),(P Ph;) with ethylene affords the Carbamate ethylidene complex (u-(CHO) )(PP,h, Ou-CsHCH ;) (M. Reactivity of mono- and di-methoxycarbonyl complexes of Pd! Koike and J.R. Shapley), 199 towards amines and copper amine complexes: role of copper Cobalt in the catalyzed palladium-—copper oxidative carbonylation of A convenient synthesis of hexacarbonyldicobalt complexes of amines (P. Giannoccaro), 249 chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, Carbene X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. Heterozyklen als Liganden. XX. Spektroskopische und struk- Greene), C12 turelle Charakterisierung von Pentacarbonylmetall-Kom- Formation and structure of [Co{Ph,PN(‘Bu)PPh,-P,P’},- plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese (CO)|[Co(CO),] - a cage molecule-pair or an ion-pair com- und D. Blaser), C8 plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. Carbon-13 Wang), 223 The reaction of (4-H),Os,(CO), (PPh) with ethylene affords the Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, ethylidene complex (u-H),O(sPPh,; (uC-COHC)H) (M. 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene Koike and J.R. Shapley), 199 (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Carbonyl dro{16Jannulene (QBC) and a tetracobalt complex of QBC. A convenient synthesis of hexacarbonyldicobalt complexes of The first example of a transition metal complex of QBC (D. chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. M. Churchill and J.D. Ferrara), 231 Greene), C12 Thermally and photochemically induced vinyl-hydrogen activation Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- of [n4-1,2 : 3,4-(trans-1,3,5-hexatriene)|(1>-cyclopentadienyl) aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, cobalt: regio- and stereospecific hydrogen migrations (J.A. J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 King Jr. and K.P.C. Vollhardt), 207 Formation and structure of [(Co{Ph,PN('Bu)PPh,-P,P’},- Conformation (CO)|[Co(CO),] — a cage molecule-pair or an ion-pair com- NMR conformational studies of (1,2-bis(diarylphosphino)eth- plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Wang), 223 Kurosawa, T. Hirao and I. Ikeda), 179 Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Cycloheptatrieny] zur Konformation von Achtringen mit Silicium und Germa- Studies on organolanthanide complexes. LXIII. Synthesis, spec- nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. troscopic and X-ray crystallographic characterization of new Puff und W. Schuh), 59 early organolanthanide, organoyttrium hydride and organo- Copper holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Reactivity of mono- and di-methoxycarbonyl complexes of Pd!! G. Wu and P. Zheng), 99 towards amines and copper amine complexes: role of copper Cyclopentadienyl in the catalyzed palladium—copper oxidative carbonylation of n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- amines (P. Giannoccaro), 249 ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. Crystal structure Gleichmann), 183 A '7Au Mossbauer study of reaction products of trimeric 1-ben- Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: zyl-2-gold(1)-imidazole leading to Au! carbene or Au! imida- the first estimation of the nature of the Ru!'—olefin bond (K. zoline complexes and trinuclear Au!!! jmidazolyl derivatives. Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 X-Ray crystal structure of [{(y-1-benzylimidazolato- The electrochemical reduction of Cp,TiCl, in the presence of N3,C”)Au};15] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini trimethylphosphine (I.M.M. Fussing, D. Pletcher and R.J. and B.R. Pietroni), 275 Whitby), 119 Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 109 Heterozyklen als Liganden. XX. Spektroskopische und struk- Cyclosilazane turelle Charakterisierung von Pentacarbonylmetall-Kom- Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), und D. Blaser), C8 35 Pentacoordinate silicon compounds: stereochemical non-rigidity Cyclyne of chelates formed by intramolecular ring-closure. Crystal Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. (HBC), 1,2: 5,6: 9,10: 13,14-tetrabenzo-3,7,11,15-tetradehy- Young and C. Belin), 43 dro[16Jannulene (QBC) and a tetracobalt complex of OBC. Reaction of sodium amalgam with (y-enyne)bis(dicarbonyl-n>- The first example of a transition metal complex of QBC (D. cyclopentadienylmolybdenum(I)) and (-n?,n?-allenyl)bis(di- Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, carbonyl-7>-cyclopentadienylmolybdenum) _ tetrafluoroborate M. Churchill and J.D. Ferrara), 231 complexes. Crystal structure of [[{Mo(n°-C;H;CO)>}{u- HC=CCH(CH ,CH ;)}],] (J.F. Capon, S. Cornen, N. Dialkylamide Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), Reduction with lithium dialkylamides (M. Majewski and D.M. 137 Gleave), 1 Strukturen und Reaktionen von Methylantimondihalogeniden Diastereoselectivity und Versuche zur Darstellung von Methylantimon (H.J. Breu- Direct synthesis of (°-arene)- tricarbonylchromium complexes nig, M. Denker und K.H. Ebert), 87 by arene displacement from tricarbonyl(7°-1-methylpyr- Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, role)chromium(0) (A. Goti and M.F. Semmelhack), C4 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]Jannulene Dinuclear (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Unusual stabilization of cationic ‘““M(n?-allyl)*” (M= Pt, Pd) dro[16Jannulene (QBC) and a tetracobalt complex of QBC. units by a dianionic cis-{Pt(C,F;),(C=CSiMe,),}*~ fragment The first example of a transition metal complex of QBC (D. (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, Diphosphine M. Churchill and J.D. Ferrara), 231 NMR conformational studies of (1,2-bis(diarylphosphino)- Syntheses and structures of dimesitylbismuth(III) bromide, ethane Xdiorgano sulfide )ruthenium complexes (K. Ohkita, H. Mes,BiBr, and _ bis(diphenyldithiophosphinato)mesitylbis- Kurosawa, T. Hirao and I. Ikeda), 179 muth(IID, MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, HJ. Dithioether Breunig, C. Silvestru and I. Haiduc), 93 Nuclear magnetic resonance studies of sulfur inversion in Synthesis and characterisation of monomeric, dimeric and poly- bis(cyclopentadienyl)-molybdenum and -tungsten complexes meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 Long and P.R. Raithby), 153 Dynamic NMR The reaction of dihydridotetrakis(triphenylphosphane)rutheni- Pentacoordinate silicon compounds: stereochemical non-rigidity um(II) with methyl acrylate. Crystal structure of bis(methyl- of chelates formed by intramolecular ring-closure. Crystal acrylate)bis(triphenylphosphane Xaqua)ruthenium(0) (R. Sust- structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. mann, B. Patzke and R. Boese), 191 Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Young and C. Belin), 43 zur Konformation von Achtringen mit Silicium und Germa- nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Electrochemistry Puff und W. Schuh), 59 Molecular structure and electrochemical properties of the Pt"! Cumulene complex of 1,1'-bis(methylthio)ferrocene and the Pd! com- Delocalization of the unpaired spin density in some niobocene plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- complexes with o-donor, 7r-acceptors (A. Antinolo, M. Fa- cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. jardo, E. De Jesis, Y. Mugnier and A. Otero), 127 Kawata, Y. Habata and S. Akabori), 263 C24 The electrochemical reduction of Cp,TiCl, in the presence of 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene trimethylphosphine (1.M.M. Fussing, D. Pletcher and R.J. (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Whitby), 119 dro[16Jannulene (QBC) and a tetracobalt complex of QBC. The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, The first example of a transition metal complex of QBC (D. aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, 109 M. Churchill and J.D. Ferrara), 231 Electron spin resonance Holmium Delocalization of the unpaired spin density in some niobocene Studies on organolanthanide complexes. LXIII. Synthesis, spec- complexes with o-donor, 7-acceptors (A. Antifolo, M. Fa- troscopic and X-ray crystallographic characterization of new jardo, E. De Jess, Y. Mugnier and A. Otero), 127 early organolanthanide, organoyttrium hydride and organo- Enyne holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Reaction of sodium amalgam with (u-enyne)bis(dicarbonyl-n>- G. Wu and P. Zheng), 99 cyclopentadienylmolybdenum(I)) and (-n?,n?-allenyl)bis(di- Hydride carbonyl-n°-cyclopentadienylmolybdenum) _ tetrafluoroborate Ein Beitrag zur Darstellung und Reaktivitat der 7>-Allyliridium- complexes. Crystal structure of [[{Mo(n°-C;H;XCO),}{u- Komplexe [Ir(n?-2-RC3H,)P'Pr;).] (M. Schulz und H. HC=CCH(CH ,CH)}],] G.F. Capon, S. Cornen, N. Werner), 243 Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), Studies on organolanthanide complexes. LXIII. Synthesis, spec- 137 troscopic and X-ray crystallographic characterization of new Extended Hiickel calculations early organolanthanide, organoyttrium hydride and organo- Delocalization of the unpaired spin density in some niobocene holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, complexes with o-donor, w-acceptors (A. Antinolo, M. Fa- G. Wu and P. Zheng), 99 jardo, E. De Jesiis, Y. Mugnier and A. Otero), 127 The reaction of (4-H)(CO,),O (PsPh ) with ethylene affords the Nuclear magnetic resonance studies of sulfur inversion in ethylidene complex (y-H),Os,(CO) (PPh,)u-CHCH) (M. bis(cyclopentadienyl)-molybdenum and -tungsten complexes Koike and J.R. Shapley), 199 with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. Hydrogen migration Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 Thermally and photochemically induced vinyl-hydrogen activation of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(7>-cyclopentadienyl) Ferrocene cobalt: regio- and stereospecific hydrogen migrations (J.A. Molecular structure and electrochemical properties of the Pt! King Jr. and K.P.C. Vollhardt), 207 complex of 1,1’-bis(methylthio)ferrocene and the Pd! com- Hydroxide plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- Elimination of B-palladium hydroxide in the Pd!!-catalyzed reac- cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. tion of methyl (a@-hydroxymethyl)acrylate with alcohols (T. Kawata, Y. Habata and S. Akabori), 263 Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), ortho-Mercuration of ferrocenylimines (S.Q. Huo, Y.J. Wu, Y. 253 Zhu and L. Yang), 17 Preparation and Mossbauer spectroscopic studies of 1’,1’-di- acetyl- and 1’-acetyl-1”-(1-naphthylimino-ethyl)biferrocenes Imidazole and their partially oxidized biferrocenium salts (H.-H. Wei, A '"Au Mossbauer study of reaction products of trimeric 1-ben- I.-S. Hwang, M.-C. Cheng and Y. Wang), 161 zyl-2-gcid(I)-imidazole leading to Au! carbene or Au! imida- Synthesis and characterisation of monomeric, dimeric and poly- zoline complexes and trinuclear Au!!! jmidazolyl derivatives. meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- X-Ray crystal structure of [{(-1-benzylimidazolato- ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. N3,C”)Au}31,] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini Long and P.R. Raithby), 153 and B.R. Pietroni), 275 Heterozyklen als Liganden. XX. Spektroskopische und struk- Germanium turelle Charakterisierung von Pentacarbonylmetall-Kom- Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese zur Konformation von Achtringen mit Silicium und Germa- und D. Blaser), C8 nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Imine Puff und W. Schuh), 59 ortho-Mercuration of ferrocenylimines (S.Q. Huo, Y.J. Wu, Y. Gold Zhu and L. Yang), 17 A '"Au Mossbauer study of reaction products of trimeric 1-ben- Indole zyl-2-gold(I)-imidazole leading to Au! carbene or Au! imida- Direct synthesis of (7°-arene)- tricarbonylchromium complexes zoline complexes and trinuclear Au!! jimidazolyl derivatives. by arene displacement from tricarbonyl(7>-1-methylpyr- X-Ray crystal structure of [{(y-1-benzylimidazolato- role)chromium(0) (A. Goti and M.F. Semmelhack), C4 N?,C*)Au}31,] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini Intramolecular coordination and B.R. Pietroni), 275 Pentacoordinate silicon compounds: stereochemical non-rigidity Group 6 of chelates formed by intramolecular ring-closure. Crystal Heterozyklen als Liganden. XX. Spektroskopische und struk- structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. turelle Charakterisierung von Pentacarbonylmetall-Kom- Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese Young and C. Belin), 43 und D. Blaser), C8 Iridium Ein Beitrag zur Darstellung und Reaktivitat der »>-Allyliridium- Hexabenzocyclohexyne Komplexe [Ir(?-2-RC3H,)P'Pr;),] (M. Schulz und H. Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, Werner), 243 Iron Molecular orbital calculations Molecular orbital calculations on Fe,(CO),9(4-CO)w4-Se), and Molecular orbital calculations on Fe,(CO),9(u-COMu4-Se), and Fe;Ru(CO),9(u-CO)u4-Se), (S.N. Datta, R.-K. Kondru and Fe,Ru(CO),9(u-COXy4-Se), (S.N. Datta, R.-K. Kondru and P. Mathur), 169 P. Mathur), 169 Ubergangsmetall-substituierte Acylphosphane und _ Phos- Molybdenum phaalkene. XX. Dipolare [3 + 2]-Cycloadditionen eines Nuclear magnetic resonance studies of sulfur inversion in Acetylendicarbonsaureesters an die Metallophosphaalkene bis(cyclopentadienyl)-molybdenum and -tungsten complexes (n°-C;Me;CO), Fe-P=C(R)SiMe, (R = Ph, SiMe;) (L. We- with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. ber und A. Riihlicke), Cl Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 Isomerization Reaction of sodium amalgam with (u-enyne)bis(dicarbonyl-n>- Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und cyclopentadienylmolybdenum(I)) and (u-n7,n?-allenyl)bis(di- Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), carbonyl-n>-cyclopentadienylmolybdenum) _t etrafluoroborate 35 complexes. Crystal structure of [[{Mo(n°-C;H;XCO),},{u- HC=CCH(CH,CH;)}],] (J.F. Capon, S. Cornen, N. Lanthanum Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), 137 Studies on organolanthanide complexes. LXIII. Synthesis, spec- Mossbauer spectroscopy troscopic and X-ray crystallographic characterization of new early organolanthanide, organoyttrium hydride and orga- A Au Mossbauer study of reaction products of trimeric 1-ben- zyl-2-gold(I)-imidazole leading to Au! carbene or Au! imida- noholmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, zoline complexes and trinuclear Au!!! imidazolyl derivatives. G. Wu and P. Zheng), 99 Large ring X-Ray crystal structure of [{(y-1-benzylimidazolato- N?,C?)Au};1,] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und and B.R. Pietroni), 275 zur Konformation von Achtringen mit Silicium und Germa- nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Preparation and Mossbauer spectroscopic studies of 1’,1’"-di- Puff und W. Schuh), 59 acetyl- and 1’-acetyl-1’”-(1-naphthylimino-ethyl)biferrocenes Lithium and their partially oxidized biferrocenium salts (H.-H. Wei, I.-S. Hwang, M.-C. Cheng and Y. Wang), 161 Reduction with lithium dialkylamides (M. Majewski and D.M. Gleave), 1 Niobium Mechanism Delocalization of the unpaired spin density in some niobocene Elimination of B-palladium hydroxide in the Pd'!-catalyzed reac- complexes with o-donor, v-acceptors (A. Antifiolo, M. Fa- tion of methyl (a-hydroxymethyl)acrylate with alcohols (T. jardo, E. De Jesis, Y. Mugnier and A. Otero), 127 Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), Nuclear magnetic resonance 253 Analogues of DIOP. Synthesis, reactivity, and NMR behaviour Mercury (A. Borner, R. Kadyrov, M. Michalik and D. Heller), 237 ortho-Mercuration of ferrocenylimines (S.Q. Huo, Y.J. Wu, Y. Determination of the free activation energy for the breaking of Zhu and L. Yang), 17 the *!p—!07 5 bond in [(n°-p-cymene)Ru(u-pz);Ag(PPh,)] Mesityl (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- Syntheses and structures of dimesitylbismuth(III]) bromide, bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 Mes,BiBr, and _bis(diphenyldithiophosphinato)mesityibis- NMR conformational studies of (1,2-bis(diarylphosphino)eth- muth(IID, MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Breunig, C. Silvestru and I. Haiduc), 93 Kurosawa, T. Hirao and I. Ikeda), 179 Metallocarbene Nuclear magnetic resonance studies of sulfur inversion in Thermally and photochemically induced vinyl-hydrogen activation bis(cyclopentadienyl)-molybdenum and -tungsten complexes of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)(>-cyclopentadienyl) with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. cobalt: regio- and stereospecific hydrogen migrations (J.A. Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 King Jr. and K.P.C. Vollhardt), 207 The reaction of (u-H),Os (CO) (PPh) with ethylene affords the Metallocenes ethylidene complex (u-H),Os,(CO),(PPh;u-CHCH, ) (M. Delocalization of the unpaired spin density in some niobocene Koike and J.R. Shapley), 199 complexes with o-donor, 7-acceptors (A. Antifiolo, M. Fa- jardo, E. De Jesiis, Y. Mugnier and A. Otero), 127 Methyl acrylate Olefin The reaction of dihydridotetrakis(triphenylphosphane)rutheni- Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: um(II) with methyl acrylate. Crystal structure of bis(methyl- the first estimation of the nature of the Ru''—olefin bond (K. acrylate )bis(triphenylphosphane Xaqua)ruthenium(0) (R. Sust- Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 mann, B. Patzke and R. Boese), 191 Osmium MNDO calculations The reaction of (4-H),Os,(CO),(PPh;) with ethylene affords the Can triorganoboroxins exist in a “monomeric” R-B=O form? ethylidene complex (u-H),Os,(CO).(PPh3u-CHCH3 ) (M. MNDO calculations and ebulliometric molecular weight de- Koike and J.R. Shapley), 199 termination (A. Sporzyfski and H. Szatytowicz), 31 Oxide Molecular mechanics Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Molecular mechanics (MM2) calculations and cone angles of zur Konformation von Achtringen mit Silicium und Germa- phosphine ligands (M. Chin, G.L. Durst, S.R. Head, P.L. nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Bock and J.A. Mosbo), 73 Puff und W. Schuh), 59 C26 Palladium (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- Elimination of B-palladium hydroxide in the Pd'!-catalyzed reac- bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 tion of methyl (a-hydroxymethyl)acrylate with alcohols (T. Ein Beitrag zur Darstellung und Reaktivitat der 7>-Allyliridium- Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), Komplexe [Ir(n?-2-RC,H,XP'Pr;),] (M. Schulz und H. 253 Werner), 243 Molecular structure and electrochemical properties of the Pt! Syntheses and structures of dimesitylbismuth(III) bromide, complex of 1,1'-bis(methylthio)ferrocene and the Pd! com- Mes,BiBr, and _ bis(diphenyldithiophosphinato)mesitylbis- plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1')ferro- muth(III), MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. Breunig, C. Silvestru and I. Haiduc), 93 Kawata, Y. Habata and S. Akabori), 263 Photochemistry Reactivity of mono- and di-methoxycarbonyl complexes of Pd! Thermally and photochemically induced vinyl-hydrogen activation towards amines and copper amine complexes: role of copper of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(>-cyclopentadienyl) in the catalyzed palladium—copper oxidative carbonylation of cobalt: regio- and stereospecific hydrogen migrations (J.A. amines (P. Giannoccaro), 249 King Jr. and K.P.C. Vollhardt), 207 Synthesis of aromatic acids via catalyzed methyl formate—chloro- Platinum arene reactions (G. Jenner and A. Ben Taleb), 257 Molecular structure and electrochemical properties of the Pt! Unusual stabilization of cationic “M(n?-allyl)*” (M= P t, Pd) complex of 1,1'-bis(methylthio)ferrocene and the Pd! com- units by a dianionic cis-{Pt(C,F;)(C=CSiMe,),}*~ fragment plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. Paramagnetism Kawata, Y. Habata and S. Akabori), 263 Delocalization of the unpaired spin density in some niobocene Unusual stabilization of cationic ““M(n?-allyl)*” (M= Pt, Pd) complexes with o-donor, v-acceptors (A. Antifolo, M. Fa- units by a dianionic cis-{Pt(C,F;),(C=CSiMe,),}’~ fragment jardo, E. De Jess, Y. Mugnier and A. Otero), 127 (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Pauson—Khand reaction Polymer A convenient synthesis of hexacarbonyldicobalt complexes of Synthesis and characterisation of monomeric, dimeric and poly- chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. Greene), C12 Long and P.R. Raithby), 153 Pentacoordinate silicon Praseodymium Pentacoordinate silicon compounds: stereochemical non-rigidity Studies on organolanthanide complexes. LXIII. Synthesis, spec- of chelates formed by intramolecular ring-closure. Crystal troscopic and X-ray crystallographic characterization of new structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. early organolanthanide, organoyttrium hydride and organo- Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Young and C. Belin), 43 G. Wu and P. Zheng), 99 Pentafluorophenyl Pseudo-rotation Unusual stabilization of cationic “M(n?-allyl)*" (M= P t, Pd) Pentacoordinate silicon compounds: stereochemical non-rigidity units by a dianionic cis-{Pt(C,F;),(C=CSiMe,),}*~ fragment of chelates formed by intramolecular ring-closure. Crystal (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. Phosphaalkene Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. Ubergangsmetall-substituierte Acylphosphane und Phos- Young and C. Belin), 43 phaalkene. XX. Dipolare [3 + 2]-Cycloadditionen eines Pyrrole Acetylendicarbonsaureesters an die Metallophosphaalkene Direct synthesis of (7°-arene)- tricarbonylchromium complexes (n°-C;Me;XCO), Fe-P=C(R)SiMe, (R = Ph, SiMe) (L. We- by arene displacement from tricarbonyl(y>-1-methylpyr- ber und A. Riihlicke), Cl role)chromium(0) (A. Goti and M.F. Semmelhack), C4 Phosphazane Formation and structure of [Co{Ph,PN('Bu)PPh,-P, P’},- Quinoline (CO)[Co(CO),] - a cage molecule-pair or an ion-pair com- Direct synthesis of (7°-arene)- tricarbonylchromium complexes plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. by arene displacement from tricarbonyl(7>-1-methylpyr- Wang), 223 role)chromium(0) (A. Goti and M.F. Semmelhack), C4 Phosphide Synthesis and derivative chemistry of [Ru ,(4-PPh,)4-OH),(°- Reduction p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 Reduction with lithium dialkylamides (M. Majewski and D.M. Phosphine Gleave), 1 Molecular mechanics (MM2) calculations and cone angles of The electrochemical reduction of Cp,TiCl, in the presence of phosphine ligands (M. Chin, G.L. Durst, S.R. Head, P.L. trimethylphosphine (I.M.M. Fussing, D. Pletcher and R.J. Bock and J.A. Mosbo), 73 Whitby), 119 The electrochemical reduction of Cp,TiCl, in the presence of The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, trimethylphosphine (I1.M.M. Fussing, D. Pletcher and R.J. aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), Whitby), 119 109 Phosphorus Rhodium Analogues of DIOP. Synthesis, reactivity, and NMR behaviour Analogues of DIOP. Synthesis, reactivity, and NMR behaviour (A. Borner, R. Kadyrov, M. Michalik and D. Heller), 237 (A. Borner, R. Kadyrov, M. Michalik and D. Heller), 237 Determination of the free activation energy for the breaking of Ruthenium the *!p—'0%1)45 bond in [(n°-p-cymene)Ru(-pz);Ag(PPh3) ] n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- C27 ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. bis(cyclopentadienyl)-molybdenum and -tungsten complexes Gleichmann), 183 with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. Determination of the free activation energy for the breaking of Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 the *!Pp-'°7A0g bond in [(7°-p-cymene)Ru(-pz); Ag(PPh;)] Synthesis (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 aryl) complexes (1.M.M. Fussing, D. Pletcher and R.J. Whitby), Molecular orbital calculations on Fe4(CO),9(u-CO)u4-Se), and 109 Fe,Ru(CO),9(u-pCu4 O-SMe) , (S.N. Datta, R.-K. Kondru and P. Mathur), 169 NMR conformational studies of (1,2-bis(diarylphosphino)eth- Tetrabenzocyclo tetrayne aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, Kurosawa, T. Hirao and I. Ikeda), 179 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- the first estimation of the nature of the Ru!!-olefin bond (K. dro[16Jannulene (QBC) and a tetracobalt complex of QBC. Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 The first example of a transition metal complex of QBC (D. Synthesis and derivative chemistry of [Ru (u-PPh)(u-OH),(7°- Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 M. Churchill and J.D. Ferrara), 231 Synthesis of aromatic acids via catalyzed methyl formate—chloro- Tetrafluoroborate arene reactions (G. Jenner and A. Ben Taleb), 257 Reaction of sodium amalgam with (u-enyne)bis(dicarbonyl-n?- The reaction of dihydridotetrakis(triphenylphosphane)rutheni- cyclopentadienylmolybdenum(I)) and (y-n7,7>-allenyl)bis(di- um(II) with methyl acrylate. Crystal structure of bis(methyl- carbonyl-n>-cyclopentadienylmolybdenum) _ tetrafluoroborate acrylate )bis(triphenylphosphaneaqua)ruthenium(0) (R. Sust- complexes. Crystal structure of [[{Mo(°-C;H;CO),}.{u- mann, B. Patzke and R. Boese), 191 HC=CCH(CH ,CH )}],] (J.F. Capon, S. Cornen, N. Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), 137 Selenium Thermochemistry Molecular orbital calculations on Fe,(CO),9(u-CO)w4-Se), and Thermally and photochemically induced vinyl-hydrogen activation Fe,Ru(CO),9(u-CO)4-Se), (S.N. Datta, R.-K. Kondru and of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(>-cyclopentadienyl) P. Mathur), 169 cobalt: regio- and stereospecific hydrogen migrations (J.A. Silicon King Jr. and K.P.C. Vollhardt), 207 Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und Tin Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), Synthesis and characterisation of monomeric, dimeric and poly- 35 meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- Pentacoordinate silicon compounds: stereochemical non-rigidity ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. of chelates formed by intramolecular ring-closure. Crystal Long and P.R. Raithby), 153 structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. Synthesis of bimetallic{Sn'Y,Al!"]--oxoisopropoxyacetate and Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. -“-oxoisopropoxide and their acetylacetone and benzoylace- Young and C. Belin), 43 tone derivatives ( Sonika, A.K. Narula, O.P. Vermani, H.K. Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Sharma and A.S. Sarpal), 67 zur Konformation von Achtringen mit Silicium und Germa- Titanium nium (M. Akkurt, T.R. Kok, P. Faleschini, L. Randaccio, H. The electrochemical reduction of Cp,TiCl, in the presence of Puff und W. Schuh), 59 trimethylphosphine (1.M.M. Fussing, D. Pletcher and R.J. Silver Whitby), 119 Determination of the free activation energy for the breaking of The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, the *'p-'°70a g bond in [(n°-p-cymene)Ru(u-pz);Ag(PPh;)] aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- 109 bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 Tribenzocyclotriyne Sodium Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, Reaction of sodium amalgam with (,-enyne)bis(dicarbonyl-n?- 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]Jannulene cyclopentadienylmolybdenum(I)) and (yu-n7,n?-allenyl)bis(di- (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- carbonyl-7>-cyclopentadienylmolybdenum) _ tetrafluoroborate dro[16Jannulene (QBC) and a tetracobalt complex of QBC. complexes. Crystal structure of [[{Mo(n°-C;H;XCO),},{u- The first example of a transition metal complex of QBC (D. HC=CCH(CH ,CH ;)}],] (J.F. Capon, §. Cornen, N. Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), M. Churchill and J.D. Ferrara), 231 137 Trimethylsilyl Substitution Ubergangsmetall-substituierte Acylphosphane und Phos- Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und phaalkene. XX. Dipolare [3 + 2]-Cycloadditionen eines Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), Acetylendicarbonsaureesters an die Metallophosphaalkene 35 (n°-C;Me;XCO), Fe-P=C(R)SiMe (R = Ph, SiMe,) (L. We- Sulfide ber und A. Rihlicke), Cl NMR conformational studies of (1,2-bis(diarylphosphino)eth- Tungsten aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Nuclear magnetic resonance studies of sulfur inversion in Kurosawa, T. Hirao and I. Ikeda), 179 bis(cyclopentadienyl)-molybdenum and -tungsten complexes Sulfur inversion with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. Nuclear magnetic resonance studies of sulfur inversion in Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 C28 Urea Studies on organolanthanide complexes. LXIII. Synthesis, spec- Reactivity of mono- and di-methoxycarbonyl complexes of Pd! troscopic and X-ray crystallographic characterization of new towards amines and copper amine complexes: role of copper early organolanthanide, organoyttrium hydride and in the catalyzed palladium—copper oxidative carbonylation of organoholmium hydroxide complexes (D. Deng, Y. Jiang, C. amines (P. Giannoccaro), 249 Qian, G. Wu and P. Zheng), 99 The reaction of dihydridotetrakis(triphenylphosphane)rutheni- Vinyl um(II) with methyl acrylate. Crystal structure of bis(methyl- Ein Beitrag zur Darstellung und Reaktivitat der >-Allyliridium- acrylate )bis(triphenylphosphane (aqua)ruthenium(0) (R. Sust- Komplexe [Ir(?-2-RC,;H,XP'Pr;),] (M. Schulz und H. mann, B. Patzke and R. Boese), 191 Werner), 243 X-ray structure Voltammetry Unusual stabilization of cationic “M(n?-allyl)*” (M= P t, Pd) The electrochemical reduction of Cp,TiCl, in the presence of units by a dianionic cis-{Pt(C,F;).(C=CSiMe,),}?~ fragment trimethylphosphine (I.M.M. Fussing, D. Pletcher and R.J. (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Whitby), 119 X-ray diffraction Yttrium Molecular structure and electrochemical properties of the Pt! Studies on organolanthanide complexes. LXIII. Synthesis, spec- complex of 1,1’-bis(methylthio)ferrocene and the Pd! com- troscopic and X-ray crystallographic characterization of new plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- early organolanthanide, organoyttrium hydride and organo- cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Kawata, Y. Habata and S. Akabori), 263 G. Wu and P. Zheng), 99

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Journal of Organometallic Chemistry, 470 (1994) C19-C20 Author Index of Volume 470 Akabori, S., 263 Habata, Y., 263 Ohkita, K., 179, 189 Akkurt, M., 59 Haiduc, I., 93 Oro, L.A., 271 Antinolo, A., 127 Head, S.R., 73 Otero, A., 127 Asano, H., 263 Heller, D., 237 Ascenso, J.R., 147 Herbst-Irmer, R., 23 Patzke, B., 191 Hirao, T., 179, 189 Pericas, M.A., C12 Belin, C., 43 Hosokawa, T., 253 Pichon, R., 137 Ben Taleb, A., 257 Huo, S.Q., 17 Pietroni, B.R., 275 Berenguer, J.R., C15 Hwang, I.-S., 161 Pletcher, D., 109, 119 Bernardes, V., C12 Poirier, M., 43 Blaser, D., C8 Ikeda, I., 179, 189 Puff, H., 59 Bock, P.L., 73 Ingham, S.L., 153 Boese, R., C8, 191 Qian, C., 99 Borner, A., 237 Jenner, G., 257 Bovio, B., 275 Jiang, Y., 99 Raithby, P.R., 153 Bradshaw, J.D., 231 Jimeno, M.L., 271 Randaccio, L., 59 Breunig, H.J., 87, 93 Riera, A., C12 Burini, A., 275 Kadyrov, R., 237 Riera, V., 173 Kawata, Y., 263 Romao, C.C., 147 Cabeza, J.A., 173 Kergoat, R., 137 Rose, E., 131 Calhorda, M.J., 147 Khan, M.S., 153 Rose-Munch, F., 131 Calogero, S., 275 Khourzom, R., 131 Royo, G., 43 Capon, J.F., 137 King Jr., J.A., 207 Rihlicke, A., Cl Carmona, D., 271 Klingebiel, U., 35 Carré, F., 43 Koike, M., 199 Sarpal, A.S., 67 Cheng, M.-C., 161 K6k, T.R., 59 Sato, M., 263 Chin, M., 73 Kondru, R.-K., 169 Scherer, G., 271 Churchill, M., 231 Kpoton, A., 43 Schuh, W., 59 Cornen, S., 137 Kratz, T., C8 Schulz, M., 243 Corriu, R.J.P., 43 Kuhn, N., C8 Schulz, R.E., 93 Kurosawa, H., 179, 189 See, R.F., 231 Datta, S.N., 169 Sekino, M., 263 De Deus Carvalho, M., 147 Lalinde, E., C15 Semmelhack, M.F., C4 De Jestis, E., 127 Lamata, M.P., 271 Shapley, J.R., 199 Deng, D., 99 Langlois, B., 131 Sharma, H.K., 67 Denker, M., 87 Le Berre-Cosquer, N., 137 Sheldrick, W.S., 183 Dias, A.R., 147 Lewis, J., 153 Silvestru, C., 93 Dielkus, S., 23 L’Haridon, P., 137 Solooki, D., 231 Djukic, J.-P., 131 Limbach, H.-H., 271 Sonika,, 67 Durst, G.L., 73 Long, N.J., 153 Sporzynski, A., 31 Ebert, K.H., 87, 93 Sugafuji, T., 253 Elguero, J., 271 Majewski, M., 1 Sustmann, R., 191 Maringgele, W., 23 Suzuki, K., 263 Fajardo, M., 127 Martinez, F., C15 Szatytowicz, H., 31 Faleschini, P., 59 Mathur, P., 169 Ferrara, J.D., 231 Meller, A., 23 Tessier, C.A., 231 Ferrer, J., 271 Michaelsen, H., 23 Forniés, J., C15 Michalik, M., 237 Vaisserman, J., 131 Fussing, I.M.M., 109, 119 Mosbo, J.A., 73 Veiros, L.F., 147 Moyano, A., C12 Verdaguer, X., C12 Giannoccaro, P., 249 Mugnier, Y., 127 Vermani, O.P., 67 Gleave, D.M., 1 Mulla, F., 173 Vollhardt, K.P.C., 207 Gleichmann, A., 183 Murahashi, S.-I., 253 Goti, A., C4 Wagner, F.E., 275 Greene, A.E., C12 Narula, A.K., 67 Wang, H.-G., 223 C20 Wang, R.-J., 223 Wu, G., 99 Young, J.C., 43 Wang, Y., 161 Wu, Y.J., 17 Youngs, W.J., 231 Weber, L., Cl Yu, A., 223 Wei, H.-H., 161 Xi, H.-P., 223 Werner, E., 35 Zhang, Z.-Z., 223 Werner, H., 243 Yamanaka, T., 253 Zheng, P., 99 Whitby, R.J., 109, 119 Yang, L., 17 Zhu, Y.; 17 Journal of Organometallic Chemistry, 470 (1994) C21-—C28 Subject Index of Volume 470 Acetyl in the catalyzed palladium—copper oxidative carbonylation of Preparation and Mossbauer spectroscopic studies of 1’,1’’-di- amines (P. Giannoccaro), 249 acetyl- and 1’-acetyl-1’’-(1-naphthylimino-ethyl)biferrocenes Amino acid and their partially oxidized biferrocenium salts (H.-H. Wei, n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- 1.-S. Hwang, M.-C. Cheng and Y. Wang), 161 ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. Alkene Gleichmann), 183 Elimination of B-palladium hydroxide in the Pd!!-catalyzed reac- Aniline tion of methyl (a@-hydroxymethyl)acrylate with alcohols (T. Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, 253 J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 Alkoxide Annulene Synthesis of bimetallic[Sn!Y,Al!"]--oxoisopropoxyacetate and Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, --oxoisopropoxide and their acetylacetone and benzoylace- 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]Jannulene tone derivatives ( Sonika, A.K. Narula, O.P. Vermani, H.K. (HBC), 1,2 : 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Sharma and A.S. Sarpal), 67 dro[16Jannulene (QBC) and a tetracobalt complex of QBC. Alkoxyacetylene The first example of a transition metal complex of QBC (D. A convenient synthesis of hexacarbonyldicobalt complexes of Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, M. Churchill and J.D. Ferrara), 231 X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. Antimony Greene), C12 Strukturen und Reaktionen von Methylantimondihalogeniden Alkylidene und Versuche zur Darstellung von Methylantimon (H.J. Bre- The reaction of (4-H),Os ,(CO),(PPh3) with ethylene affords the unig, M. Denker und K.H. Ebert), 87 ethylidene complex (w-H),0(PsPh, 3( uC-COHC)H, ) (M. Arene Koike and J.R. Shapley), 199 Direct synthesis of (7°-arene)- tricarbonylchromium complexes Alkyne by arene displacement from tricarbonyl(7>-1-methylpyr- Ein Beitrag zur Darstellung und Reaktivitat der °-Allyliridium- role)chromium(0) (A. Goti and M.F. Semmelhack), C4 Komplexe [Ir(?-2-RC,;H,4XP'Pr;),] (M. Schulz und H. Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- Werner), 243 aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, Reaction of sodium amalgam with (y-enyne)bis(dicarbonyl-n>- J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 cyclopentadienylmolybdenum(I)) and (-n?,n>-allenyl)bis(di- Synthesis and derivative chemistry of [Ru,(u-PPh,u-OH),(7°- carbonyl-n>-cyclopentadienylmolybdenum) _ tetrafluoroborate p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 complexes. Crystal structure of [[{Mo(n°-C;H;CO),},{u- Asymmetric synthesis HC=CCH(CH ,CH)}],] (.F. Capon, S. Cornen, N. A convenient synthesis of hexacarbonyldicobalt complexes of Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, 137 X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. Synthesis and characterisation of monomeric, dimeric and poly- Greene), C12 meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. Bismuth Long and P.R. Raithby), 153 Syntheses and structures of dimesitylbismuth(II) bromide, Alkynyl Mes,BiBr, and_ bis(diphenyldithiophosphinato)mesitylbis- Unusual stabilization of cationic “M(n*-allyl)*" (M= Pt, Pd) muth(IID), MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. units by a dianionic cis-{Pt(C,F;).(C=CSiMe,),}?~ fragment Breunig, C. Silvestru and I. Haiduc), 93 (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Bond activation Allyl Thermally and photochemically induced vinyl-hydrogen activation Ein Beitrag zur Darstellung und Reaktivitat der >-Allyliridium- of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(>-cyclopentadienyl) Komplexe [Ir(7?-2-RC,H,XP'Pr;),] (M. Schulz und H. cobalt: regio- and stereospecific hydrogen migrations (J.A. Werner), 243 King Jr. and K.P.C. Vollhardt), 207 Aluminium ar-Bonding Synthesis of bimetallic{Sn!Y,Al"]-~-oxoisopropoxyacetate and n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- --oxoisopropoxide and their acetylacetone and benzoylace- ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. tone derivatives ( Sonika, A.K. Narula, O.P. Vermani, H.K. Gleichmann), 183 Sharma and A:S. Sarpal), 67 Bond nature Amine Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: Reactivity of mono- and di-methoxycarbonyl complexes of Pd!! the first estimation of the nature of the Ru!!—olefin bond (K. towards amines and copper amine complexes: role of copper Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 C22 Boracycloalkene Heterozyklen als Liganden. XX. Spektroskopische und struk- Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- turelle Charakterisierung von Pentacarbonylmetall-Kom- gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. und D. Blaser), C8 Meller), 23 Molecular orbital calculations on Fe,(CO),9(u-CO)4-Se), and Borane Fe;Ru(CO);9(4-COw4-Se), (S.N. Datta, R.-K. Kondru and Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- P. Mathur), 169 gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- Carbonylation ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. Reactivity of mono- and di-methoxycarbonyl complexes of Pd! Meller), 23 towards amines and copper amine complexes: role of copper Boron in the catalyzed palladium—copper oxidative carbonylation of Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- amines (P. Giannoccaro), 249 gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- Synthesis of aromatic acids via catalyzed methyl formate—chloro- ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. arene reactions (G. Jenner and A. Ben Taleb), 257 Meller), 23 Catalysis Boron-nitrogen compounds Elimination of B-palladium hydroxide in the Pd"-catalyzed reac- Reaktion von konjugierten Doppelbindungsystemen mit Dihalo- tion of methyl (a@-hydroxymethyl)acrylate with alcohols (T. gen(diorganylamino)boranen und Na/K-Legierung (W. Ma- Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), ringgele, S. Dielkus, R. Herbst-Irmer, H. Michaelsen und A. 253 Meller), 23 Synthesis of aromatic acids via catalyzed methyl formate—chloro- Boroxin arene reactions (G. Jenner and A. Ben Taleb), 257 Can triorganoboroxins exist in a “monomeric” R-B=O form? Chloroarene MNDO calculations and ebulliometric molecular weight de- Synthesis of aromatic acids via catalyzed methyl formate—chloro- termination (A. Sporzyfski and H. Szatylowicz), 31 arene reactions (G. Jenner and A. Ben Taleb), 257 Bridging ligand Chromium Synthesis and derivative chemistry of [Ru ,(4-PPh,)u-OH),(7°- Direct synthesis of (°-arene)- tricarbonylchromium complexes p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 by arene displacement from tricarbonyl(7>-1-methylpyrrole)- Bromide chromium(0) (A. Goti and M.F. Semmelhack), C4 Syntheses and structures of dimesitylbismuth(III) bromide, Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- Mes,BiBr, and_bis(diphenyldithiophosphinato)mesitylbis- aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, muth(IID, MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 Breunig, C. Silvestru and I. Haiduc), 93 Strukturen und Reaktionen von Methylantimondihalogeniden und Versuche zur Darstellung von Methylantimon (H.J. Breu- nig, M. Denker und K.H. Ebert), 87 Cage compound Cluster Formation and structure of [Co{Ph,PN('Bu)PPh.-PP’,}, - Molecular orbital calculations on Fe,(CO),.(u-COMu4-Se), and (CO)\[Co(CO),] —- a cage molecule-pair or an ion-pair com- Fe,Ru(CO),9(u-CO)4-Se), (S.N. Datta, R.-K. Kondru and plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. P. Mathur), 169 Wang), 223 The reaction of (4O-s ,H(CO)),(P Ph;) with ethylene affords the Carbamate ethylidene complex (u-(CHO) )(PP,h, Ou-CsHCH ;) (M. Reactivity of mono- and di-methoxycarbonyl complexes of Pd! Koike and J.R. Shapley), 199 towards amines and copper amine complexes: role of copper Cobalt in the catalyzed palladium-—copper oxidative carbonylation of A convenient synthesis of hexacarbonyldicobalt complexes of amines (P. Giannoccaro), 249 chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, Carbene X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. Heterozyklen als Liganden. XX. Spektroskopische und struk- Greene), C12 turelle Charakterisierung von Pentacarbonylmetall-Kom- Formation and structure of [Co{Ph,PN(‘Bu)PPh,-P,P’},- plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese (CO)|[Co(CO),] - a cage molecule-pair or an ion-pair com- und D. Blaser), C8 plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. Carbon-13 Wang), 223 The reaction of (4-H),Os,(CO), (PPh) with ethylene affords the Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, ethylidene complex (u-H),O(sPPh,; (uC-COHC)H) (M. 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene Koike and J.R. Shapley), 199 (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Carbonyl dro{16Jannulene (QBC) and a tetracobalt complex of QBC. A convenient synthesis of hexacarbonyldicobalt complexes of The first example of a transition metal complex of QBC (D. chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. M. Churchill and J.D. Ferrara), 231 Greene), C12 Thermally and photochemically induced vinyl-hydrogen activation Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- of [n4-1,2 : 3,4-(trans-1,3,5-hexatriene)|(1>-cyclopentadienyl) aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, cobalt: regio- and stereospecific hydrogen migrations (J.A. J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 King Jr. and K.P.C. Vollhardt), 207 Formation and structure of [(Co{Ph,PN('Bu)PPh,-P,P’},- Conformation (CO)|[Co(CO),] — a cage molecule-pair or an ion-pair com- NMR conformational studies of (1,2-bis(diarylphosphino)eth- plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Wang), 223 Kurosawa, T. Hirao and I. Ikeda), 179 Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Cycloheptatrieny] zur Konformation von Achtringen mit Silicium und Germa- Studies on organolanthanide complexes. LXIII. Synthesis, spec- nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. troscopic and X-ray crystallographic characterization of new Puff und W. Schuh), 59 early organolanthanide, organoyttrium hydride and organo- Copper holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Reactivity of mono- and di-methoxycarbonyl complexes of Pd!! G. Wu and P. Zheng), 99 towards amines and copper amine complexes: role of copper Cyclopentadienyl in the catalyzed palladium—copper oxidative carbonylation of n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- amines (P. Giannoccaro), 249 ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. Crystal structure Gleichmann), 183 A '7Au Mossbauer study of reaction products of trimeric 1-ben- Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: zyl-2-gold(1)-imidazole leading to Au! carbene or Au! imida- the first estimation of the nature of the Ru!'—olefin bond (K. zoline complexes and trinuclear Au!!! jmidazolyl derivatives. Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 X-Ray crystal structure of [{(y-1-benzylimidazolato- The electrochemical reduction of Cp,TiCl, in the presence of N3,C”)Au};15] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini trimethylphosphine (I.M.M. Fussing, D. Pletcher and R.J. and B.R. Pietroni), 275 Whitby), 119 Etude conformationnelle du complexe 7°-(4-(trifluorométhoxy)- The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, aniline)tricarbonylchrome (F. Rose-Munch, R. Khourzom, aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), J.-P. Djukic, E. Rose, B. Langlois et J. Vaisserman), 131 109 Heterozyklen als Liganden. XX. Spektroskopische und struk- Cyclosilazane turelle Charakterisierung von Pentacarbonylmetall-Kom- Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), und D. Blaser), C8 35 Pentacoordinate silicon compounds: stereochemical non-rigidity Cyclyne of chelates formed by intramolecular ring-closure. Crystal Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. (HBC), 1,2: 5,6: 9,10: 13,14-tetrabenzo-3,7,11,15-tetradehy- Young and C. Belin), 43 dro[16Jannulene (QBC) and a tetracobalt complex of OBC. Reaction of sodium amalgam with (y-enyne)bis(dicarbonyl-n>- The first example of a transition metal complex of QBC (D. cyclopentadienylmolybdenum(I)) and (-n?,n?-allenyl)bis(di- Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, carbonyl-7>-cyclopentadienylmolybdenum) _ tetrafluoroborate M. Churchill and J.D. Ferrara), 231 complexes. Crystal structure of [[{Mo(n°-C;H;CO)>}{u- HC=CCH(CH ,CH ;)}],] (J.F. Capon, S. Cornen, N. Dialkylamide Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), Reduction with lithium dialkylamides (M. Majewski and D.M. 137 Gleave), 1 Strukturen und Reaktionen von Methylantimondihalogeniden Diastereoselectivity und Versuche zur Darstellung von Methylantimon (H.J. Breu- Direct synthesis of (°-arene)- tricarbonylchromium complexes nig, M. Denker und K.H. Ebert), 87 by arene displacement from tricarbonyl(7°-1-methylpyr- Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, role)chromium(0) (A. Goti and M.F. Semmelhack), C4 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]Jannulene Dinuclear (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Unusual stabilization of cationic ‘““M(n?-allyl)*” (M= Pt, Pd) dro[16Jannulene (QBC) and a tetracobalt complex of QBC. units by a dianionic cis-{Pt(C,F;),(C=CSiMe,),}*~ fragment The first example of a transition metal complex of QBC (D. (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, Diphosphine M. Churchill and J.D. Ferrara), 231 NMR conformational studies of (1,2-bis(diarylphosphino)- Syntheses and structures of dimesitylbismuth(III) bromide, ethane Xdiorgano sulfide )ruthenium complexes (K. Ohkita, H. Mes,BiBr, and _ bis(diphenyldithiophosphinato)mesitylbis- Kurosawa, T. Hirao and I. Ikeda), 179 muth(IID, MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, HJ. Dithioether Breunig, C. Silvestru and I. Haiduc), 93 Nuclear magnetic resonance studies of sulfur inversion in Synthesis and characterisation of monomeric, dimeric and poly- bis(cyclopentadienyl)-molybdenum and -tungsten complexes meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 Long and P.R. Raithby), 153 Dynamic NMR The reaction of dihydridotetrakis(triphenylphosphane)rutheni- Pentacoordinate silicon compounds: stereochemical non-rigidity um(II) with methyl acrylate. Crystal structure of bis(methyl- of chelates formed by intramolecular ring-closure. Crystal acrylate)bis(triphenylphosphane Xaqua)ruthenium(0) (R. Sust- structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. mann, B. Patzke and R. Boese), 191 Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Young and C. Belin), 43 zur Konformation von Achtringen mit Silicium und Germa- nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Electrochemistry Puff und W. Schuh), 59 Molecular structure and electrochemical properties of the Pt"! Cumulene complex of 1,1'-bis(methylthio)ferrocene and the Pd! com- Delocalization of the unpaired spin density in some niobocene plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- complexes with o-donor, 7r-acceptors (A. Antinolo, M. Fa- cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. jardo, E. De Jesis, Y. Mugnier and A. Otero), 127 Kawata, Y. Habata and S. Akabori), 263 C24 The electrochemical reduction of Cp,TiCl, in the presence of 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene trimethylphosphine (1.M.M. Fussing, D. Pletcher and R.J. (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- Whitby), 119 dro[16Jannulene (QBC) and a tetracobalt complex of QBC. The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, The first example of a transition metal complex of QBC (D. aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, 109 M. Churchill and J.D. Ferrara), 231 Electron spin resonance Holmium Delocalization of the unpaired spin density in some niobocene Studies on organolanthanide complexes. LXIII. Synthesis, spec- complexes with o-donor, 7-acceptors (A. Antifolo, M. Fa- troscopic and X-ray crystallographic characterization of new jardo, E. De Jess, Y. Mugnier and A. Otero), 127 early organolanthanide, organoyttrium hydride and organo- Enyne holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Reaction of sodium amalgam with (u-enyne)bis(dicarbonyl-n>- G. Wu and P. Zheng), 99 cyclopentadienylmolybdenum(I)) and (-n?,n?-allenyl)bis(di- Hydride carbonyl-n°-cyclopentadienylmolybdenum) _ tetrafluoroborate Ein Beitrag zur Darstellung und Reaktivitat der 7>-Allyliridium- complexes. Crystal structure of [[{Mo(n°-C;H;XCO),}{u- Komplexe [Ir(n?-2-RC3H,)P'Pr;).] (M. Schulz und H. HC=CCH(CH ,CH)}],] G.F. Capon, S. Cornen, N. Werner), 243 Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), Studies on organolanthanide complexes. LXIII. Synthesis, spec- 137 troscopic and X-ray crystallographic characterization of new Extended Hiickel calculations early organolanthanide, organoyttrium hydride and organo- Delocalization of the unpaired spin density in some niobocene holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, complexes with o-donor, w-acceptors (A. Antinolo, M. Fa- G. Wu and P. Zheng), 99 jardo, E. De Jesiis, Y. Mugnier and A. Otero), 127 The reaction of (4-H)(CO,),O (PsPh ) with ethylene affords the Nuclear magnetic resonance studies of sulfur inversion in ethylidene complex (y-H),Os,(CO) (PPh,)u-CHCH) (M. bis(cyclopentadienyl)-molybdenum and -tungsten complexes Koike and J.R. Shapley), 199 with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. Hydrogen migration Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 Thermally and photochemically induced vinyl-hydrogen activation of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(7>-cyclopentadienyl) Ferrocene cobalt: regio- and stereospecific hydrogen migrations (J.A. Molecular structure and electrochemical properties of the Pt! King Jr. and K.P.C. Vollhardt), 207 complex of 1,1’-bis(methylthio)ferrocene and the Pd! com- Hydroxide plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- Elimination of B-palladium hydroxide in the Pd!!-catalyzed reac- cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. tion of methyl (a@-hydroxymethyl)acrylate with alcohols (T. Kawata, Y. Habata and S. Akabori), 263 Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), ortho-Mercuration of ferrocenylimines (S.Q. Huo, Y.J. Wu, Y. 253 Zhu and L. Yang), 17 Preparation and Mossbauer spectroscopic studies of 1’,1’-di- acetyl- and 1’-acetyl-1”-(1-naphthylimino-ethyl)biferrocenes Imidazole and their partially oxidized biferrocenium salts (H.-H. Wei, A '"Au Mossbauer study of reaction products of trimeric 1-ben- I.-S. Hwang, M.-C. Cheng and Y. Wang), 161 zyl-2-gcid(I)-imidazole leading to Au! carbene or Au! imida- Synthesis and characterisation of monomeric, dimeric and poly- zoline complexes and trinuclear Au!!! jmidazolyl derivatives. meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- X-Ray crystal structure of [{(-1-benzylimidazolato- ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. N3,C”)Au}31,] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini Long and P.R. Raithby), 153 and B.R. Pietroni), 275 Heterozyklen als Liganden. XX. Spektroskopische und struk- Germanium turelle Charakterisierung von Pentacarbonylmetall-Kom- Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese zur Konformation von Achtringen mit Silicium und Germa- und D. Blaser), C8 nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Imine Puff und W. Schuh), 59 ortho-Mercuration of ferrocenylimines (S.Q. Huo, Y.J. Wu, Y. Gold Zhu and L. Yang), 17 A '"Au Mossbauer study of reaction products of trimeric 1-ben- Indole zyl-2-gold(I)-imidazole leading to Au! carbene or Au! imida- Direct synthesis of (7°-arene)- tricarbonylchromium complexes zoline complexes and trinuclear Au!! jimidazolyl derivatives. by arene displacement from tricarbonyl(7>-1-methylpyr- X-Ray crystal structure of [{(y-1-benzylimidazolato- role)chromium(0) (A. Goti and M.F. Semmelhack), C4 N?,C*)Au}31,] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini Intramolecular coordination and B.R. Pietroni), 275 Pentacoordinate silicon compounds: stereochemical non-rigidity Group 6 of chelates formed by intramolecular ring-closure. Crystal Heterozyklen als Liganden. XX. Spektroskopische und struk- structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. turelle Charakterisierung von Pentacarbonylmetall-Kom- Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. plexen der Imidazol-2-ylidene (N. Kuhn, T. Kratz, R. Boese Young and C. Belin), 43 und D. Blaser), C8 Iridium Ein Beitrag zur Darstellung und Reaktivitat der »>-Allyliridium- Hexabenzocyclohexyne Komplexe [Ir(?-2-RC3H,)P'Pr;),] (M. Schulz und H. Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, Werner), 243 Iron Molecular orbital calculations Molecular orbital calculations on Fe,(CO),9(4-CO)w4-Se), and Molecular orbital calculations on Fe,(CO),9(u-COMu4-Se), and Fe;Ru(CO),9(u-CO)u4-Se), (S.N. Datta, R.-K. Kondru and Fe,Ru(CO),9(u-COXy4-Se), (S.N. Datta, R.-K. Kondru and P. Mathur), 169 P. Mathur), 169 Ubergangsmetall-substituierte Acylphosphane und _ Phos- Molybdenum phaalkene. XX. Dipolare [3 + 2]-Cycloadditionen eines Nuclear magnetic resonance studies of sulfur inversion in Acetylendicarbonsaureesters an die Metallophosphaalkene bis(cyclopentadienyl)-molybdenum and -tungsten complexes (n°-C;Me;CO), Fe-P=C(R)SiMe, (R = Ph, SiMe;) (L. We- with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. ber und A. Riihlicke), Cl Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 Isomerization Reaction of sodium amalgam with (u-enyne)bis(dicarbonyl-n>- Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und cyclopentadienylmolybdenum(I)) and (u-n7,n?-allenyl)bis(di- Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), carbonyl-n>-cyclopentadienylmolybdenum) _t etrafluoroborate 35 complexes. Crystal structure of [[{Mo(n°-C;H;XCO),},{u- HC=CCH(CH,CH;)}],] (J.F. Capon, S. Cornen, N. Lanthanum Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), 137 Studies on organolanthanide complexes. LXIII. Synthesis, spec- Mossbauer spectroscopy troscopic and X-ray crystallographic characterization of new early organolanthanide, organoyttrium hydride and orga- A Au Mossbauer study of reaction products of trimeric 1-ben- zyl-2-gold(I)-imidazole leading to Au! carbene or Au! imida- noholmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, zoline complexes and trinuclear Au!!! imidazolyl derivatives. G. Wu and P. Zheng), 99 Large ring X-Ray crystal structure of [{(y-1-benzylimidazolato- N?,C?)Au};1,] (B. Bovio, S. Calogero, F.E. Wagner, A. Burini Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und and B.R. Pietroni), 275 zur Konformation von Achtringen mit Silicium und Germa- nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Preparation and Mossbauer spectroscopic studies of 1’,1’"-di- Puff und W. Schuh), 59 acetyl- and 1’-acetyl-1’”-(1-naphthylimino-ethyl)biferrocenes Lithium and their partially oxidized biferrocenium salts (H.-H. Wei, I.-S. Hwang, M.-C. Cheng and Y. Wang), 161 Reduction with lithium dialkylamides (M. Majewski and D.M. Gleave), 1 Niobium Mechanism Delocalization of the unpaired spin density in some niobocene Elimination of B-palladium hydroxide in the Pd'!-catalyzed reac- complexes with o-donor, v-acceptors (A. Antifiolo, M. Fa- tion of methyl (a-hydroxymethyl)acrylate with alcohols (T. jardo, E. De Jesis, Y. Mugnier and A. Otero), 127 Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), Nuclear magnetic resonance 253 Analogues of DIOP. Synthesis, reactivity, and NMR behaviour Mercury (A. Borner, R. Kadyrov, M. Michalik and D. Heller), 237 ortho-Mercuration of ferrocenylimines (S.Q. Huo, Y.J. Wu, Y. Determination of the free activation energy for the breaking of Zhu and L. Yang), 17 the *!p—!07 5 bond in [(n°-p-cymene)Ru(u-pz);Ag(PPh,)] Mesityl (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- Syntheses and structures of dimesitylbismuth(III]) bromide, bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 Mes,BiBr, and _bis(diphenyldithiophosphinato)mesityibis- NMR conformational studies of (1,2-bis(diarylphosphino)eth- muth(IID, MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Breunig, C. Silvestru and I. Haiduc), 93 Kurosawa, T. Hirao and I. Ikeda), 179 Metallocarbene Nuclear magnetic resonance studies of sulfur inversion in Thermally and photochemically induced vinyl-hydrogen activation bis(cyclopentadienyl)-molybdenum and -tungsten complexes of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)(>-cyclopentadienyl) with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. cobalt: regio- and stereospecific hydrogen migrations (J.A. Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 King Jr. and K.P.C. Vollhardt), 207 The reaction of (u-H),Os (CO) (PPh) with ethylene affords the Metallocenes ethylidene complex (u-H),Os,(CO),(PPh;u-CHCH, ) (M. Delocalization of the unpaired spin density in some niobocene Koike and J.R. Shapley), 199 complexes with o-donor, 7-acceptors (A. Antifiolo, M. Fa- jardo, E. De Jesiis, Y. Mugnier and A. Otero), 127 Methyl acrylate Olefin The reaction of dihydridotetrakis(triphenylphosphane)rutheni- Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: um(II) with methyl acrylate. Crystal structure of bis(methyl- the first estimation of the nature of the Ru''—olefin bond (K. acrylate )bis(triphenylphosphane Xaqua)ruthenium(0) (R. Sust- Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 mann, B. Patzke and R. Boese), 191 Osmium MNDO calculations The reaction of (4-H),Os,(CO),(PPh;) with ethylene affords the Can triorganoboroxins exist in a “monomeric” R-B=O form? ethylidene complex (u-H),Os,(CO).(PPh3u-CHCH3 ) (M. MNDO calculations and ebulliometric molecular weight de- Koike and J.R. Shapley), 199 termination (A. Sporzyfski and H. Szatytowicz), 31 Oxide Molecular mechanics Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Molecular mechanics (MM2) calculations and cone angles of zur Konformation von Achtringen mit Silicium und Germa- phosphine ligands (M. Chin, G.L. Durst, S.R. Head, P.L. nium (M. Akkurt, T.R. K6k, P. Faleschini, L. Randaccio, H. Bock and J.A. Mosbo), 73 Puff und W. Schuh), 59 C26 Palladium (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- Elimination of B-palladium hydroxide in the Pd'!-catalyzed reac- bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 tion of methyl (a-hydroxymethyl)acrylate with alcohols (T. Ein Beitrag zur Darstellung und Reaktivitat der 7>-Allyliridium- Hosokawa, T. Sugafuji, T. Yamanaka and S.-I. Murahashi), Komplexe [Ir(n?-2-RC,H,XP'Pr;),] (M. Schulz und H. 253 Werner), 243 Molecular structure and electrochemical properties of the Pt! Syntheses and structures of dimesitylbismuth(III) bromide, complex of 1,1'-bis(methylthio)ferrocene and the Pd! com- Mes,BiBr, and _ bis(diphenyldithiophosphinato)mesitylbis- plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1')ferro- muth(III), MesBi(S,PPh,), (K.H. Ebert, R.E. Schulz, H.J. cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. Breunig, C. Silvestru and I. Haiduc), 93 Kawata, Y. Habata and S. Akabori), 263 Photochemistry Reactivity of mono- and di-methoxycarbonyl complexes of Pd! Thermally and photochemically induced vinyl-hydrogen activation towards amines and copper amine complexes: role of copper of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(>-cyclopentadienyl) in the catalyzed palladium—copper oxidative carbonylation of cobalt: regio- and stereospecific hydrogen migrations (J.A. amines (P. Giannoccaro), 249 King Jr. and K.P.C. Vollhardt), 207 Synthesis of aromatic acids via catalyzed methyl formate—chloro- Platinum arene reactions (G. Jenner and A. Ben Taleb), 257 Molecular structure and electrochemical properties of the Pt! Unusual stabilization of cationic “M(n?-allyl)*” (M= P t, Pd) complex of 1,1'-bis(methylthio)ferrocene and the Pd! com- units by a dianionic cis-{Pt(C,F;)(C=CSiMe,),}*~ fragment plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. Paramagnetism Kawata, Y. Habata and S. Akabori), 263 Delocalization of the unpaired spin density in some niobocene Unusual stabilization of cationic ““M(n?-allyl)*” (M= Pt, Pd) complexes with o-donor, v-acceptors (A. Antifolo, M. Fa- units by a dianionic cis-{Pt(C,F;),(C=CSiMe,),}’~ fragment jardo, E. De Jess, Y. Mugnier and A. Otero), 127 (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Pauson—Khand reaction Polymer A convenient synthesis of hexacarbonyldicobalt complexes of Synthesis and characterisation of monomeric, dimeric and poly- chiral (non-racemic) terminal alkoxyacetylenes (V. Bernardes, meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- X. Verdaguer, A. Moyano, M.A. Pericas, A. Riera and A.E. ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. Greene), C12 Long and P.R. Raithby), 153 Pentacoordinate silicon Praseodymium Pentacoordinate silicon compounds: stereochemical non-rigidity Studies on organolanthanide complexes. LXIII. Synthesis, spec- of chelates formed by intramolecular ring-closure. Crystal troscopic and X-ray crystallographic characterization of new structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. early organolanthanide, organoyttrium hydride and organo- Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Young and C. Belin), 43 G. Wu and P. Zheng), 99 Pentafluorophenyl Pseudo-rotation Unusual stabilization of cationic “M(n?-allyl)*" (M= P t, Pd) Pentacoordinate silicon compounds: stereochemical non-rigidity units by a dianionic cis-{Pt(C,F;),(C=CSiMe,),}*~ fragment of chelates formed by intramolecular ring-closure. Crystal (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. Phosphaalkene Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. Ubergangsmetall-substituierte Acylphosphane und Phos- Young and C. Belin), 43 phaalkene. XX. Dipolare [3 + 2]-Cycloadditionen eines Pyrrole Acetylendicarbonsaureesters an die Metallophosphaalkene Direct synthesis of (7°-arene)- tricarbonylchromium complexes (n°-C;Me;XCO), Fe-P=C(R)SiMe, (R = Ph, SiMe) (L. We- by arene displacement from tricarbonyl(y>-1-methylpyr- ber und A. Riihlicke), Cl role)chromium(0) (A. Goti and M.F. Semmelhack), C4 Phosphazane Formation and structure of [Co{Ph,PN('Bu)PPh,-P, P’},- Quinoline (CO)[Co(CO),] - a cage molecule-pair or an ion-pair com- Direct synthesis of (7°-arene)- tricarbonylchromium complexes plex? (Z.-Z. Zhang, A. Yu, H.-P. Xi, R.-J. Wang and H.-G. by arene displacement from tricarbonyl(7>-1-methylpyr- Wang), 223 role)chromium(0) (A. Goti and M.F. Semmelhack), C4 Phosphide Synthesis and derivative chemistry of [Ru ,(4-PPh,)4-OH),(°- Reduction p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 Reduction with lithium dialkylamides (M. Majewski and D.M. Phosphine Gleave), 1 Molecular mechanics (MM2) calculations and cone angles of The electrochemical reduction of Cp,TiCl, in the presence of phosphine ligands (M. Chin, G.L. Durst, S.R. Head, P.L. trimethylphosphine (I.M.M. Fussing, D. Pletcher and R.J. Bock and J.A. Mosbo), 73 Whitby), 119 The electrochemical reduction of Cp,TiCl, in the presence of The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, trimethylphosphine (I1.M.M. Fussing, D. Pletcher and R.J. aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), Whitby), 119 109 Phosphorus Rhodium Analogues of DIOP. Synthesis, reactivity, and NMR behaviour Analogues of DIOP. Synthesis, reactivity, and NMR behaviour (A. Borner, R. Kadyrov, M. Michalik and D. Heller), 237 (A. Borner, R. Kadyrov, M. Michalik and D. Heller), 237 Determination of the free activation energy for the breaking of Ruthenium the *!p—'0%1)45 bond in [(n°-p-cymene)Ru(-pz);Ag(PPh3) ] n>-Pentamethylcyclopentadienylruthenium(II) complexes contain- C27 ing 7°-coordinated a-amino acids (W.S. Sheldrick and A. bis(cyclopentadienyl)-molybdenum and -tungsten complexes Gleichmann), 183 with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. Determination of the free activation energy for the breaking of Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 the *!Pp-'°7A0g bond in [(7°-p-cymene)Ru(-pz); Ag(PPh;)] Synthesis (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 aryl) complexes (1.M.M. Fussing, D. Pletcher and R.J. Whitby), Molecular orbital calculations on Fe4(CO),9(u-CO)u4-Se), and 109 Fe,Ru(CO),9(u-pCu4 O-SMe) , (S.N. Datta, R.-K. Kondru and P. Mathur), 169 NMR conformational studies of (1,2-bis(diarylphosphino)eth- Tetrabenzocyclo tetrayne aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, Kurosawa, T. Hirao and I. Ikeda), 179 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]annulene Relative stability of 7>-cyclopentadienyl(olefin)ruthenium cations: (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- the first estimation of the nature of the Ru!!-olefin bond (K. dro[16Jannulene (QBC) and a tetracobalt complex of QBC. Ohkita, H. Kurosawa, T. Hirao and I. Ikeda), 189 The first example of a transition metal complex of QBC (D. Synthesis and derivative chemistry of [Ru (u-PPh)(u-OH),(7°- Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, p-cymene),]* (J.A. Cabeza, F. Mulla and V. Riera), 173 M. Churchill and J.D. Ferrara), 231 Synthesis of aromatic acids via catalyzed methyl formate—chloro- Tetrafluoroborate arene reactions (G. Jenner and A. Ben Taleb), 257 Reaction of sodium amalgam with (u-enyne)bis(dicarbonyl-n?- The reaction of dihydridotetrakis(triphenylphosphane)rutheni- cyclopentadienylmolybdenum(I)) and (y-n7,7>-allenyl)bis(di- um(II) with methyl acrylate. Crystal structure of bis(methyl- carbonyl-n>-cyclopentadienylmolybdenum) _ tetrafluoroborate acrylate )bis(triphenylphosphaneaqua)ruthenium(0) (R. Sust- complexes. Crystal structure of [[{Mo(°-C;H;CO),}.{u- mann, B. Patzke and R. Boese), 191 HC=CCH(CH ,CH )}],] (J.F. Capon, S. Cornen, N. Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), 137 Selenium Thermochemistry Molecular orbital calculations on Fe,(CO),9(u-CO)w4-Se), and Thermally and photochemically induced vinyl-hydrogen activation Fe,Ru(CO),9(u-CO)4-Se), (S.N. Datta, R.-K. Kondru and of [n*-1,2 : 3,4-(trans-1,3,5-hexatriene)|(>-cyclopentadienyl) P. Mathur), 169 cobalt: regio- and stereospecific hydrogen migrations (J.A. Silicon King Jr. and K.P.C. Vollhardt), 207 Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und Tin Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), Synthesis and characterisation of monomeric, dimeric and poly- 35 meric ferrocenylacetylides. Crystal structure of 1,1’-bis(phenyl- Pentacoordinate silicon compounds: stereochemical non-rigidity ethynyl)ferrocene (S.L. Ingham, M.S. Khan, J. Lewis, N.J. of chelates formed by intramolecular ring-closure. Crystal Long and P.R. Raithby), 153 structure of 8-dimethylamino-1-trifluorosilylnaphthalene (F. Synthesis of bimetallic{Sn'Y,Al!"]--oxoisopropoxyacetate and Carré, R.J.P. Corriu, A. Kpoton, M. Poirier, G. Royo, J.C. -“-oxoisopropoxide and their acetylacetone and benzoylace- Young and C. Belin), 43 tone derivatives ( Sonika, A.K. Narula, O.P. Vermani, H.K. Zur Struktur des Diethylgermanium-diphenylsiliciumoxids und Sharma and A.S. Sarpal), 67 zur Konformation von Achtringen mit Silicium und Germa- Titanium nium (M. Akkurt, T.R. Kok, P. Faleschini, L. Randaccio, H. The electrochemical reduction of Cp,TiCl, in the presence of Puff und W. Schuh), 59 trimethylphosphine (1.M.M. Fussing, D. Pletcher and R.J. Silver Whitby), 119 Determination of the free activation energy for the breaking of The synthesis and electrochemistry of CpTiCl,(OR) (R = alkyl, the *'p-'°70a g bond in [(n°-p-cymene)Ru(u-pz);Ag(PPh;)] aryl) complexes (I.M.M. Fussing, D. Pletcher and R.J. Whitby), (D. Carmona, J. Ferrer, M.P. Lamata, L.A. Oro, H.-H. Lim- 109 bach, G. Scherer, J. Elguero and M.L. Jimeno), 271 Tribenzocyclotriyne Sodium Syntheses and crystal structures of 1,2:5,6:9,10: 13,14: 17, Reaction of sodium amalgam with (,-enyne)bis(dicarbonyl-n?- 18 : 21,22-hexabenzo-3,7,11,15,19,23-hexadehydro[24]Jannulene cyclopentadienylmolybdenum(I)) and (yu-n7,n?-allenyl)bis(di- (HBC), 1,2: 5,6: 9,10 : 13,14-tetrabenzo-3,7,11,15-tetradehy- carbonyl-7>-cyclopentadienylmolybdenum) _ tetrafluoroborate dro[16Jannulene (QBC) and a tetracobalt complex of QBC. complexes. Crystal structure of [[{Mo(n°-C;H;XCO),},{u- The first example of a transition metal complex of QBC (D. HC=CCH(CH ,CH ;)}],] (J.F. Capon, §. Cornen, N. Solooki, J.D. Bradshaw, C.A. Tessier, W.J. Youngs, R.F. See, Le Berre-Cosquer, R. Pichon, R. Kergoat and P. L’Haridon), M. Churchill and J.D. Ferrara), 231 137 Trimethylsilyl Substitution Ubergangsmetall-substituierte Acylphosphane und Phos- Cyclotetrasilazane als Precursor fiir Cyclotrisilazane und phaalkene. XX. Dipolare [3 + 2]-Cycloadditionen eines Bis(cyclodisilazan-1-yl)silane (E. Werner und U. Klingebiel), Acetylendicarbonsaureesters an die Metallophosphaalkene 35 (n°-C;Me;XCO), Fe-P=C(R)SiMe (R = Ph, SiMe,) (L. We- Sulfide ber und A. Rihlicke), Cl NMR conformational studies of (1,2-bis(diarylphosphino)eth- Tungsten aneXdiorgano sulfide)ruthenium complexes (K. Ohkita, H. Nuclear magnetic resonance studies of sulfur inversion in Kurosawa, T. Hirao and I. Ikeda), 179 bis(cyclopentadienyl)-molybdenum and -tungsten complexes Sulfur inversion with dithioethers (J.R. Ascenso, M. De Deus Carvalho, A.R. Nuclear magnetic resonance studies of sulfur inversion in Dias, C.C. Romao, M.J. Calhorda and L.F. Veiros), 147 C28 Urea Studies on organolanthanide complexes. LXIII. Synthesis, spec- Reactivity of mono- and di-methoxycarbonyl complexes of Pd! troscopic and X-ray crystallographic characterization of new towards amines and copper amine complexes: role of copper early organolanthanide, organoyttrium hydride and in the catalyzed palladium—copper oxidative carbonylation of organoholmium hydroxide complexes (D. Deng, Y. Jiang, C. amines (P. Giannoccaro), 249 Qian, G. Wu and P. Zheng), 99 The reaction of dihydridotetrakis(triphenylphosphane)rutheni- Vinyl um(II) with methyl acrylate. Crystal structure of bis(methyl- Ein Beitrag zur Darstellung und Reaktivitat der >-Allyliridium- acrylate )bis(triphenylphosphane (aqua)ruthenium(0) (R. Sust- Komplexe [Ir(?-2-RC,;H,XP'Pr;),] (M. Schulz und H. mann, B. Patzke and R. Boese), 191 Werner), 243 X-ray structure Voltammetry Unusual stabilization of cationic “M(n?-allyl)*” (M= P t, Pd) The electrochemical reduction of Cp,TiCl, in the presence of units by a dianionic cis-{Pt(C,F;).(C=CSiMe,),}?~ fragment trimethylphosphine (I.M.M. Fussing, D. Pletcher and R.J. (J.R. Berenguer, J. Forniés, E. Lalinde and F. Martinez), C15 Whitby), 119 X-ray diffraction Yttrium Molecular structure and electrochemical properties of the Pt! Studies on organolanthanide complexes. LXIII. Synthesis, spec- complex of 1,1’-bis(methylthio)ferrocene and the Pd! com- troscopic and X-ray crystallographic characterization of new plexes of 1,4,7-trithia[7]- and 1,5,9-trithia[9] (1,1’)ferro- early organolanthanide, organoyttrium hydride and organo- cenophanes (M. Sato, K. Suzuki, H. Asano, M. Sekino, Y. holmium hydroxide complexes (D. Deng, Y. Jiang, C. Qian, Kawata, Y. Habata and S. Akabori), 263 G. Wu and P. Zheng), 99

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