Table Of Content

Journal of Organometallic Chemistry, 465 (1994) C4 Author Index of Volume 465 Abrahams, I., 73 Hayashi, H., 101 O’Brien, P., 73 Alberts, E., 241 Herres, M., 283 Occhiucci, G., 109 Amaudrut, J., 187 Hiyama, T., 97 Oldroyd, R.D., 275 Holloway, C.E., 1 Oro, L.A., 267 Baker, P.K., 221 Bencze, L., 211 Imhof, W., 283 Parish, R.V., 161 Birk, U., 167 Pasynkiewicz, S., 93 Bissinger, P., 65 Jahn, N., 153 Pinillos, M.T., 267 Blum, A., 167 Powell, A.V., 251 Bonati, F., 267 Kalbarczyk, E., 93 Boncella, J.M., 297 Kao, H.M., 199 Ramsey, T.M., 175 Bovio, B., 267 Karsch, H.H., 65 Rehder, D., 181 Brisdon, B.J., 145 Kempinger, W., 167 Rybinskaya, M.I., 259 Ketkov, S.Yu., 225 Cameron, M., 161 Kimijima, K., 101 Schofield, P.J., 145 Champness, N.R., 275 Klein, B., 119 Shimizu, K., 187 Cho, C.S., 85 Kooijman, H., 241 Shubina, E.S., 259 Crestoni, M.E., 109 Kreindlin, A.Z., 259 Spek, A.L., 241 Kroll, L.C., 289 Storhoff, B.N., 289 De Lange, P.P.M., 241 Krylov, A.N., 259 Sun, W.-H., 263 Dong, T.-Y., 199 Sunkel, K., 167 Lang, H., 283 Szilagyi, R., 211 Epstein, L.M., 259 Lee, Y.C., 199 Eujen, R., 153 Levason, W., 275 ‘Tegel; :C., 267 Thurmann, UV., 153 Lin, J.T., 199 Flower, K.R., 221 Linti, G., 79 Uemura, S., 85 Fornarini, S., 109 Forward, J.M., 251 Maelger, H., 181 Van Wijnkoop, M., 241 Fredericks, E.J., 289 Mahon, M.F., 145 Vasapollo, G., 161 Frithauf, H.-W., 241 Malik, A., 73 Villanueva, L.A., 297 Melnik, M., 1 Vrieze, K., 241 Gailus, H., 181 Mercier, M.-F., 187 Gindling, M.J., 289 Mikulcik, P., 65 Wakasa, M., 101 Goda, K., 97 Mingos, D.M.P., 251 Wang, H.-Q., 263 Gowenlock, B.G., 161 Miyoshi, K., 193 Weidenbruch, M., 127, 137 Grauvogl, G., 65 Mochida, K., 101 Wen, Y.S., 199 Guennec, N., 233 Moinet, C., 233 Gulliver, D.J., 275 Molloy, K.C., 145 Yamaguchi, Y., 193 Guyon, F., 187 Motevalli, M., 73 Yang, S.-Y., 263 Miller, G., 65 Yu, K.-B., 263 Halterman, R.L., 175 Hassler, K., 127, 137 Nakazawa, H., 193 Zhou, Q.-F., 263 Hatanaka, Y., 97 Neumann, W.P., 119 Ziemkowska, W., 93 Journal of Organometallic Chemistry, 465 (1994) C4 Author Index of Volume 465 Abrahams, I., 73 Hayashi, H., 101 O’Brien, P., 73 Alberts, E., 241 Herres, M., 283 Occhiucci, G., 109 Amaudrut, J., 187 Hiyama, T., 97 Oldroyd, R.D., 275 Holloway, C.E., 1 Oro, L.A., 267 Baker, P.K., 221 Bencze, L., 211 Imhof, W., 283 Parish, R.V., 161 Birk, U., 167 Pasynkiewicz, S., 93 Bissinger, P., 65 Jahn, N., 153 Pinillos, M.T., 267 Blum, A., 167 Powell, A.V., 251 Bonati, F., 267 Kalbarczyk, E., 93 Boncella, J.M., 297 Kao, H.M., 199 Ramsey, T.M., 175 Bovio, B., 267 Karsch, H.H., 65 Rehder, D., 181 Brisdon, B.J., 145 Kempinger, W., 167 Rybinskaya, M.I., 259 Ketkov, S.Yu., 225 Cameron, M., 161 Kimijima, K., 101 Schofield, P.J., 145 Champness, N.R., 275 Klein, B., 119 Shimizu, K., 187 Cho, C.S., 85 Kooijman, H., 241 Shubina, E.S., 259 Crestoni, M.E., 109 Kreindlin, A.Z., 259 Spek, A.L., 241 Kroll, L.C., 289 Storhoff, B.N., 289 De Lange, P.P.M., 241 Krylov, A.N., 259 Sun, W.-H., 263 Dong, T.-Y., 199 Sunkel, K., 167 Lang, H., 283 Szilagyi, R., 211 Epstein, L.M., 259 Lee, Y.C., 199 Eujen, R., 153 Levason, W., 275 ‘Tegel; :C., 267 Thurmann, UV., 153 Lin, J.T., 199 Flower, K.R., 221 Linti, G., 79 Uemura, S., 85 Fornarini, S., 109 Forward, J.M., 251 Maelger, H., 181 Van Wijnkoop, M., 241 Fredericks, E.J., 289 Mahon, M.F., 145 Vasapollo, G., 161 Frithauf, H.-W., 241 Malik, A., 73 Villanueva, L.A., 297 Melnik, M., 1 Vrieze, K., 241 Gailus, H., 181 Mercier, M.-F., 187 Gindling, M.J., 289 Mikulcik, P., 65 Wakasa, M., 101 Goda, K., 97 Mingos, D.M.P., 251 Wang, H.-Q., 263 Gowenlock, B.G., 161 Miyoshi, K., 193 Weidenbruch, M., 127, 137 Grauvogl, G., 65 Mochida, K., 101 Wen, Y.S., 199 Guennec, N., 233 Moinet, C., 233 Gulliver, D.J., 275 Molloy, K.C., 145 Yamaguchi, Y., 193 Guyon, F., 187 Motevalli, M., 73 Yang, S.-Y., 263 Miller, G., 65 Yu, K.-B., 263 Halterman, R.L., 175 Hassler, K., 127, 137 Nakazawa, H., 193 Zhou, Q.-F., 263 Hatanaka, Y., 97 Neumann, W.P., 119 Ziemkowska, W., 93 Journal of Organometallic Chemistry, 465 (1994) C5-C10 Subject Index of Volume 465 Ab initio Carbene Molecular mechanical studies on the olefin metathesis reaction. Chemie der schweren Carben-Analogen R,M (M = Si, Ge, Sn). I. Development and evaluation of tungsten carbene parame- XIX. Reaktionen von stabilem Diaminogermylen und -stan- ters: METMOD] (L. Bencze and R. Szilagyi), 211 nylen Me,Si(‘BuN),M (M = Ge, Sn) mit organischen Aziden Alkene (B. Klein and W.P. Neumann), 119 Palladium-catalyzed cross-coupling of aryl and alkenyl boronic Molecular mechanical studies on the olefin metathesis reaction. acids with alkenes via oxidative addition of a carbon—boron I. Development and evaluation of tungsten carbene parame- bond to palladium(0) (C.S. Cho and S. Uemura), 85 ters: METMoDI1 (L. Bencze and R. Szilagyi), 211 Alkenyl Carbonyl Palladium-catalyzed cross-coupling of aryl and alkenyl boronic Dinuclear molybdenum carbonyls bridged by hydride ligands (J.T. acids with alkenes via oxidative addition of a carbon—boron Lin, Y.C. Lee, H.M. Kao, T.-Y. Dong and Y.S. Wen), 199 bond to palladium(0) (C.S. Cho and S. Uemura), 85 Catalysis Alkyne Electronic effects of bis(2-aryl-4,5,6,7-tetrahydroindeny])titano- A route to 7?-alkyne complexes of vanadium(I): crystal structure cene dichlorides on the catalytic epoxidation of trans-3-hexene of trans-[IV(CO),(PMe,Ph),(2-butyne)] (H. Gailus, H. Mael- (R.L. Halterman and T.M. Ramsey), 175 ger and D. Rehder), 181 Charge transfer Aluminium Synthesis and magnetic studies of the metallocarborane sandwich Reactions of trimethylaluminium with cis-2-buten-1,4-diol (W. salts [Fe(C;Me;)>][M(C,B )H,>)3)] (M=Cr, Fe, Ni) (J.M. Ziemkowska, S. Pasynkiewicz and E. Kalbarczyk), 93 Forward, D.M.P. Mingos and A.V. Powell), 251 Amide Cobalt Darstellung und Struktur monomerer N-borylierter Gallium- Heterometallic sulfido clusters by metal exchange: syntheses and amide (G. Linti), 79 X-ray crystal structures of (m°-C,H4CH ,)MoFeCo(CO).(u - Arene S) and (n°-C;),;Mo,H Fe,(COC),(H3- S) (W.-H. Sun, S.-Y. Photoabsorption study of electronic excited states of (>-cyclo- Yang, H.-Q. Wang, Q.-F. Zhou and K.-B. Yu), 263 pentadienyl)(°-arene)manganese (S.Yu. Ketkov), 225 Stabilisierung niederkoordinierter M(CO)-Bausteine: Synthese Aryl und Reaktivitat von {(n°-C;H,SiMe,),Hf(C=CPh),}M(CO) Palladium-catalyzed cross-coupling of aryl and alkenyl boronic (M = Ni, Co) (H. Lang, M. Herres and W. Imhof), 283 acids with alkenes via oxidative addition of a carbon—boron Crystal structure bond to palladium(0) (C.S. Cho and S. Uemura), 85 A route to n?-alkyne complexes of vanadium(I): crystal structure Azides of trans-[IV(CO),(PMe, Ph),(2-butyne)] (H. Gailus, H. Mael- Chemie der schweren Carben-Analogen R,M (M = Si, Ge, Sn). ger and D. Rehder), 181 XIX. Reaktionen von stabilem Diaminogermylen und -stan- Darstellung und Struktur monomerer N-borylierter Gallium- nylen Me,Si('BuN),M (M = Ge, Sn) mit organischen Aziden amide (G. Linti), 79 (B. Klein and W.P. Neumann), 119 Heterometallic sulfido clusters by metal exchange: syntheses and X-ray crystal structures of (°-C;H,CH ,)MoFeCo(CO),(15- S) and (n°-C;),;Mo,H Fe4(COC),(Hw3- S) (W.-H. Sun, S.-Y. Boron Yang, H.-Q. Wang, Q.-F. Zhou and K.-B. Yu), 263 Darstellung und Struktur monomerer N-borylierter Gallium- Magnesium compounds: classification and analysis of crystallo- amide (G. Linti), 79 graphic and structural data (C.E. Holloway and M. Melnik), 1 Boronic acid Organotin-substituted organosiloxanes: synthesis and characteri- Palladium-catalyzed cross-coupling of aryl and alkenyl boronic sation, including the crystal structure of 1,3-bis(triphenylstan- acids with alkenes via oxidative addition of a carbon—boron noxy)-1,1,3,3-tetraphenyl-1,3-disiloxane (B.J. Brisdon, M.F. bond to palladium(0) (C.S. Cho and S. Uemura), 85 Mahon, K.C. Molloy and P.J. Schofield), 145 But-2-yne Some complexes of neopentylcadmium species with dithio- and Reactions of the cationic but-2-yne complex [WI(CO)NCMe)- di-selenocarbamates: the synthesis, characterization and sin- {Ph,P(CH.,)PPh,}(n?-MeC, Me)|[BF, ] with bidentate nitro- gle crystal X-ray structure of a mixed neopentyl/ gen donor ligands (P.K. Baker and K.R. Flower), 221 diethyldiselenocarbamate of cadmium: [(CH,),CCH,Cd- Se,CNEt,], (I. Abrahams, A. Malik, M. Motevalli and P. Cadmium O’Brien), 73 Some complexes of neopentylcadmium species with dithio- and Synthesis and magnetic studies of the metallocarborane sandwich di-selenocarbamates: the synthesis, characterization and sin- salts [Fe(C;Me;),]IM(C,B )H,>)2)] (M=Cr, Fe, Ni) (J.M. gle crystal X-ray structure of a mixed neopentyl/ Forward, D.M.P. Mingos and A.V. Powell), 251 diethyldiselenocarbamate of cadmium: [(CH,),;CCH,Cd- Cycloaddition Se,CNEt,], (I. Abrahams, A. Malik, M. Motevalli and P. 1,3-Dipolar cycloaddition to a Fe—-N=C fragment. XII. Reactivity O’Brien), 73 of Fe(2,6-xylyl-isocyanide),('Pr-a-diimine) towards heteroal- lenic C=S bonds (P.P.M. De Lange, E. Alberts, M. dérivés nitrosés correspondants (N. Guennec and C. Moinet), Van Wijnkoop, H.-W. Friihauf, K. Vrieze, H. Kooijman and 233 A.L. Spek), 241 Syntheses and electrochemical behaviour of novel dithiolatonio- Cyclopentadienyl bium-(IV) and -(V) complexes with two 7>-cyclopentadieny! Etude électrochimique des cations (7°-cyclopentadiényl fer 7°- rings (F. Guyon, J. Amaudrut, M.-F. Mercier and K. Shimizu), nitrobenzéne ou 7°-nitrotoluénes)*. Electrosynthése des 187 dérivés nitrosés correspondants (N. Guennec and C. Moinet), Electronic 233 Photoabsorption study of electronic excited states of (7>-cyclo- Komplexchemie perhalogenierter Cyclopentadiene und Alkine. pentadienyl)(°-arene)manganese (S.Yu. Ketkov), 225 XVI. Darstellung von zr-Cyclopentadienylkomplexen mit zwei Epoxidation und drei Chalkogensubstituenten am Ring, [C;Cl4_,,- Electronic effects of bis(2-aryl-4,5,6,7-tetrahydroindenyl)titano- (ER),,(ER’)JML,, (ML,, = Mn(CO);, Fe(C;H;); m= 1 oder cene dichlorides on the catalytic epoxidation of trans-3-hexene 2; E=S, Se; R, R’=Me, Ph). Struktur von [C.Cl,- (R.L. Halterman and T.M. Ramsey), 175 (SMe), /(C3;H,]Fe (K. Siinkel, U. Birk, A. Blum and W. Kempinger), 167 Ferrocene Photoabsorption study of electronic excited states of (7>-cyclo- Synthesis and magnetic studies of the metallocarborane sandwich pentadienyl)7°-arene)manganese (S.Yu. Ketkov), 225 salts [Fe(C;Me;).][M(H,C,,)B,) ] (M = Cr, Fe, Ni) (J.M. Syntheses and electrochemical behaviour of novel dithiolatonio- Forward, D.M.P. Mingos and A.V. Powell), 251 bium-(IV) and -(V) complexes with two 7°-cyclopentadienyl Ferromagnetism rings (F. Guyon, J. Amaudrut, M.-F. Mercier and K. Shimizu), Synthesis and magnetic studies of the metallocarborane sandwich 187 salts [Fe(C;Me;).][M(HC,,,)B) ] (M=Cr, Fe, Ni) (J.M. Forward, D.M.P. Mingos and A.V. Powell), 251 Difluoromethyl Fluorine Synthesis and properties of trifluoromethylated stannanes. The Synthesis and properties of trifluoromethylated stannanes. The formation and NMR spectra of the difluoromethylstannanes formation and NMR spectra of the difluoromethylstannanes (CF3),,(CF>H),,,Sn(CH 3)4_,-m (R. Eujen, N. Jahn and U. (CF;),,(CF,H),,Sn(CH3)4_,- (R. Eujen, N. Jahn and U. Thurmann), 153 Thurmann), 153 Diimine 1,3-Dipolar cycloaddition to a Fe-N=C fragment. XII. Reactivity of Fe(2,6-xylyl-isocyanide),('Pr-a-diimine) towards heteroal- Gallium lenic C=S bonds (P.P.M. De Lange, E. Alberts, M. Darstellung und Struktur monomerer N-borylierter Gallium- Van Wijnkoop, H.-W. Friihauf, K. Vrieze, H. Kooijman and amide (G. Linti), 79 A.L. Spek), 241 Gas phase Dimethyltin Gas phase reactivity of aromatic silanes. The reaction of Coordination complexes of dimethyltin dichloride with C-nitroso Ph(CH,), SiMe, (x = 0 or 1) with cationic electrophiles (M.E. compounds (M. Cameron, B.G. Gowenlock, R.V. Parish and Crestoni, S. Fornarini and G. Occhiucci), 109 G. Vasapollo), 161 Germanium Diphosphine Chemie der schweren Carben-Analogen RM (M = Si, Ge, Sn). Synthesis of a polymer-supported o-phenylene(diphosphine) and XIX. Reaktionen von stabilem Diaminogermylen und -stan- characterization of some metal complexes (N.R. Champness, nylen Me,Si(‘BuN),M (M = Ge, Sn) mit organischen Aziden W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 (B. Klein and W.P. Neumann), 119 Diphosphinomethanide Germanyl Substituentenabhangigkeit der Lithiumkoordination von Phosphi- Photochemical reactions of 2-(pentamethyldisilanyl)furan and 2- nomethaniden und Molekiilstrukturen von (TMEDA)Li- (pentamethyldigermanyl)furan. Formation of a radical pair [C(PPh,)(SiMe3)] und {(THF)Li[CH(PMe,),]}, (H.H. (K. Mochida, K. Kimijima, M. Wakasa and H. Hayashi), 101 Karsch, G. Grauvogl, P. Mikulcik, P. Bissinger and G. Miiller), Group 6 65 Formation and fac-mer isomerization of cationic phosphenium Diselenocarbamate transition metal complexes formulated as [M(bpy)- Some complexes of neopentylcadmium species with dithio- and (CO)3{PN(Me)CH,CH,NMe}]*_(M = Cr, Mo, W) and di-selenocarbamates: the synthesis, characterization and sin- [M(dppeXCO),{PN(Me)CH,CH,NMe}]* (M= Mo, W) (H. gle crystal X-ray structure of a mixed neopentyl/ Nakazawa, Y. Yamaguchi and K. Miyoshi), 193 diethyldiselenocarbamate of cadmium: [(CH,),CCH,- Group 8 CdSe,CNEt,], (I. Abrahams, A. Malik, M. Motevalli and P. Hydrogen-bonded complexes involving the metal atom and proto- O’Brien), 73 nation of metallocenes of the iron subgroup (E.S. Shubina, Dithiocarbamate AN. Krylov, A.Z. Kreindlin, M.I. Rybinskaya and L.M. Ep- Some complexes of neopentylcadmium species with dithio- and stein), 259 di-selenocarbamates: the synthesis, characterization and sin- Group 14 gle crystal X-ray structure of a mixed neopentyl/ Chemie der schweren Carben-Analogen R,M (M = Si, Ge, Sn). diethyldiselenocarbamate of cadmium: [(CH,),CCH,- XIX. Reaktionen von stabilem Diaminogermylen und -stan- CdSe,CNEt,], (I. Abrahams, A. Malik, M. Motevalli and P. nylen Me,Si(‘BuN),M (M = Ge, Sn) mit organischen Aziden O’Brien), 73 (B. Klein and W.P. Neumann), 119 Synthesis and properties of trifluoromethylated stannanes. The Electrochemistry formation and NMR spectra of the difluoromethylstannanes Etude électrochimique des cations (7>-cyclopentadiényl fer 7°- (CF;),(CFH),,S3n)(4C_,H- QR. Eujen, N. Jahn and U. nitrobenzéne ou 7°-nitrotoluénes)*. Electrosynthése des Thurmann), 153 C7 Hafnium Komplexchemie perhalogenierter Cyclopentadiene und Alkine. Stabilisierung niederkoordinierter M(CO)-Bausteine: Synthese XVI. Darstellung von 7-Cyclopentadienylkomplexen mit zwei und Reaktivitét von {(n°-C;H,SiMe,),Hf(C=CPh),}M(CO) und drei Chalkogensubstituenten am Ring, [C;Cl,_,,,- (M = Ni, Co) (H. Lang, M. Herres and W. Imhof), 283 (ER),,(ER’)JML,, (ML,, =M n(CO)3, Fe(C;H,;); m=1 oder Heteroallenes 2; E=S, Se; R, R’= Me, Ph). Struktur von 1,3-Dipolar cycloaddition to a Fe-N=C fragment. XII. Reactivity [C;Cl,(SMe),[C;H,]Fe (K. Siinkel, U. Birk, A. Blum and W. of Fe(2,6-xylyl-isocyanide),('Pr-a-diimine) towards heteroal- Kempinger), 167 lenic C=S bonds (P.P.M. De Lange, E. Alberts, M. Stabilisierung niederkoordinierter M(CO)-Bausteine: Synthese Van Wijnkoop, H.-W. Friihauf, K. Vrieze, H. Kooijman and und Reaktivitét von {(n°-C;H,SiMe,),Hf(C=CPh),}M(CO) A.L. Spek), 241 (M = Ni, Co) (H. Lang, M. Herres and W. Imhof), 283 Heterometallics Isocyanide Heterometallic sulfido clusters by metal exchange: syntheses and 1,3-Dipolar cycloaddition to a Fe-N=C fragment. XII. Reactivity X-ray crystal structures of (°-C;H4CH ;)MoFeCo(CO),(u3- of Fe(2,6-xylyl-isocyanide),('Pr-a-diimine) towards heteroal- S) and (n°-C;H CH ;).Mo,Fe(CO)~(15-S) (W.-H. Sun, S.-Y. lenic C=S bonds (P.P.M. De Lange, E. Alberts, M. Yang, H.-Q. Wang, Q.-F. Zhou and K.-B. Yu), 263 Van Wijnkoop, H.-W. Friihauf, K. Vrieze, H. Kooijman and Hindered (bulky) ligands A.L. Spek), 241 Phosphine-nitrile ligands: the molecular structure of cis-2-di- Isomerism phenylphosphino-1-cyanocyclopentane and studies of the Formation and fac-mer isomerization of cationic phosphenium donor /acceptor properties of this and related ligands (EJ. transition metal complexes formulated as [M(bpy)- Fredericks, M.J. Gindling, L.C. Kroll and B.N. Storhoff), 289 (CO)3{PN(Me)CH,CH,NMe}]*_(M = Cr, Mo, W) and Hydride [M(dppeX(CO),{PN(Me)C,HN,MeC}H] * (M = Mo, W) (H. Dinuclear molybdenum carbonyls bridged by hydride ligands (J.T. Nakazawa, Y. Yamaguchi and K. Miyoshi), 193 Lin, Y.C. Lee, H.M. Kao, T.-Y. Dong and Y.S. Wen), 199 Hydrogen bonding Hydrogen-bonded complexes involving the metal atom and proto- Lithium nation of metallocenes of the iron subgroup (E.S. Shubina, Substituentenabhangigkeit der Lithiumkoordination von Phosphi- A.N. Krylov, A.Z. Kreindlin, M.I. Rybinskaya and L.M. Ep- nomethaniden und Molekiilstrukturen von (TMEDA)Li- stein), 259 [C(PPh,),(SiMe3)] und {(THF)Li[CH(PMe,),}}, (H.H. Karsch, G. Grauvogl, P. Mikulcik, P. Bissinger and G. Miiller), 65 Imidazole N-substituted imidazole derivatives of rhodium(]) and iridium(]). Crystal structure of the head-to-head dinuclear compound [Ir,(-N-benzylimidazolato-N *,C?),(CO),] (F. Bonati, L.A. Magnesium Oro, M.T. Pinillos, C. Tejel and B. Bovio), 267 Magnesium compounds: classification and analysis of crystallo- Infrared spectroscopy graphic and structural data (C.E. Holloway and M. Melnik), 1 Schwingungsspektren, Normalkoordinatenanalysen und Synthe- Manganese sen der t-Butylsilane ‘BuSiX,, X =H, D, F, Cl, Br, I (K. Komplexchemie perhalogenierter Cyclopentadiene und Alkine. Hassler and M. Weidenbruch), 127 XVI. Darstellung von z-Cyclopentadienylkomplexen mit zwei Schwingungsspektren und Normalkoordinatenanalysen der Di-t- und drei Chalkogensubstituenten am Ring, [C;Cl,_,,- butylsilane ‘Bu,SiX,, X =H, D, F, Cl, Br, I (K. Hassler and (ER),,(ER’)JML,, (ML,, = Mn(CO),, Fe(C;H;); m=1 oder M. Weidenbruch), 137 2; E=S, Se; R, R’=Me, Ph). Struktur von [CCl - Ion cyclotron resonance (SMe), )[C;H;]Fe (K. Siinkel, U. Birk, A. Blum and W. Gas phase reactivity of aromatic silanes. The reaction of Kempinger), 167 Ph(CH), SiMe, (x = 0 or 1) with cationic electrophiles (M.E. Photoabsorption study of electronic excited states of (n>-cyclo- Crestoni, S. Fornarini and G. Occhiucci), 109 pentadienyl)(°-arene manganese (S.Yu. Ketkov), 225 Iridium Metallocarborane N-substituted imidazole derivatives of rhodium(I) and iridium(I). Synthesis and magnetic studies of the metallocarborane sandwich Crystal structure of the head-to-head dinuclear compound salts [Fe(C;Me;),IM(C,B )H,>),)] (M=Cr, Fe, Ni) (J.M. [Ir(u-N-benzylimidazolato-N *,C”),(CO),] (F. Bonati, L.A. Forward, D.M.P. Mingos and A.V. Powell), 251 Oro, M.T. Pinillos, C. Tejel and B. Bovio), 267 Metallocenes Iron Electronic effects of bis(2-aryl-4,5,6,7-tetrahydroindeny|)titano- 1,3-Dipolar cycloaddition to a Fe-N=C fragment. XII. Reactivity cene dichlorides on the catalytic epoxidation of trans-3-hexene of Fe(2,6-xylyl-isocyanide),(‘Pr-a-diimine) towards heteroal- (R.L. Halterman and T.M. Ramsey), 175 lenic C=S bonds (P.P.M. De Lange, E. Alberts, M. Hydrogen-bonded complexes involving the metal atom and proto- Van Wijnkoop, H.-W. Friihauf, K. Vrieze, H. Kooijman and nation of metallocenes of the iron subgroup (E.S. Shubina, A.L. Spek), 241 A.N. Krylov, A.Z. Kreindlin, M.I. Rybinskaya and L.M. Ep- Etude électrochimique des cations (>-cyclopentadiényl fer °- stein), 259 nitrobenzéne ou 7°-nitrotoluénes)*. Electrosynthése des Komplexchemie perhalogenierter Cyclopentadiene und Alkine. dérivés nitrosés correspondants (N. Guennec and C. Moinet), XVI. Darstellung von 7-Cyclopentadienylkomplexen mit zwei 233 und drei Chalkogensubstituenten am Ring, [C5Cl4_,,,- Heterometallic sulfido clusters by metal exchange: syntheses and (ER),,(ER’)JML,, (ML,, = Mn(CO);, Fe(C;H;); m= 1 oder X-ray crystal structures of (7°-C;H,CH ;)MoFeCo(CO),(y5- 2; E=S, Se; R, R’=Me, Ph). Struktur von [C,;C1,(S- S) and (7°-C;H,CH ;),Mo,Fe(CO),(u3-S) (W.-H. Sun, S.-Y. Me),[C;H;]Fe (K. Siinkel, U. Birk, A. Blum and W. Yang, H.-Q. Wang, Q.-F. Zhou and K.-B. Yu), 263 Kempinger), 167 C8 Molecular mechanics Oxidative addition Molecular mechanical studies on the olefin metathesis reaction. Palladium-catalyzed cross-coupling of aryl and alkenyl boronic I. Development and evaluation of tungsten carbene parame- acids with alkenes via oxidative addition of a carbon—boron ters: METMODI (L. Bencze and R. Szilagyi), 211 bond to palladium(0) (C.S. Cho and S. Uemura), 85 Phosphine-nitrile ligands: the molecular structure of cis-2-di- phenylphosphino-1l-cyanocyclopentane and studies of the Palladium donor /acceptor properties of this and related ligands (E.J. On the regioselectivity of palladium catalyzed cross-coupling re- Fredericks, M.J. Gindling, L.C. Kroll and B.N. Storhoff), 289 actions of alkenylsilanes: participation of B-cationic organosil- Molybdenum icate-palladium species during the transmetallation (Y. Dinuclear molybdenum carbonyls bridged by hydride ligands (J.T. Hatanaka, K. Goda and T. Hiyama), 97 Lin, Y.C. Lee, H.M. Kao, T.-Y. Dong and Y.S. Wen), 199 Palladium-catalyzed cross-coupling of aryl and alkenyl boronic Heterometallic sulfido clusters by metal exchange: syntheses and acids with alkenes via oxidative addition of a carbon—boron X-ray crystal structures of (7°-C;H4CH ;)MoFeCo(CO),(u3- bond to palladium(0) (C.S. Cho and S. Uemura), 85 S) and (n°-C;),;Mo,H Fe,(COC),(Hw3- S) (W.-H. Sun, S.-Y. Phosphine-nitrile ligands: the molecular structure of cis-2-di- Yang, H.-Q. Wang, Q.-F. Zhou and K.-B. Yu), 263 phenylphosphino-1-cyanocyclopentane and studies of the Mossbauer spectroscopy donor/acceptor properties of this and related ligands (E.J. Coordination complexes of dimethyltin dichloride with C-nitroso Fredericks, M.J. Gindling, L.C. Kroll and B.N. Storhoff), 289 compounds (M. Cameron, B.G. Gowenlock, R.V. Parish and Reactions of unsaturated electrophiles with trans-(PMe;),- G. Vasapollo), 161 Pd(PhXNHPh) (J.M. Boncella and L.A. Villanueva), 297 Organotin-substituted organosiloxanes: synthesis and characteri- Phosphenium sation, including the crystal structure of 1,3-bis(triphenylstan- Formation and fac-mer isomerization of cationic phosphenium noxy)-1,1,3,3-tetraphenyl-1,3-disiloxane (B.J. Brisdon, M.F. transition metal complexes formulated as [M(bpy)- Mahon, K.C. Molloy and P.J. Schofield), 145 (CO)3{PN(Me)CH,CH,NMe}]* _(M = Cr, Mo, W) and Neopentyl [M(dppeXCO),{PN,(;CMHe ,)NMCe}H] * (M = Mo, W) (H. Some complexes of neopentylcadmium species with dithio- and Nakazawa, Y. Yamaguchi and K. Miyoshi), 193 di-selenocarbamates: the synthesis, characterization and sin- Phosphine-nitrile ligands gle crystal X-ray structure of a mixed neopentyl/ Phosphine-nitrile ligands: the molecular structure of cis-2-di- diethyldiselenocarbamate of cadmium: [(CH,),CCH,Cd- phenylphosphino-1-cyanocyclopentane and studies of the Se,CNEt,], (I. Abrahams, A. Malik, M. Motevalli and P. donor/acceptor properties of this and related ligands (E.J. O’Brien), 73 Fredericks, M.J. Gindling, L.C. Kroll and B.N. Storhoff), 289 Nickel Phosphite Phosphine-nitrile ligands: the molecular structure of cis-2-di- Formation and fac-mer isomerization of cationic phosphenium phenylphosphino-1-cyanocyclopentane and studies of the transition metal complexes formulated as [M(bpy)- donor/acceptor properties of this and related ligands (E.J. (CO)3{PN(Me)CH ,;CH,NMe}]* (M = Cr, Mo, W) and Fredericks, M.J. Gindling, L.C. Kroll and B.N. Storhoff), 289 [M(dppeXCO),{PN,(CMH e,)NMCeH}] * (M = Mo, W) (H. Stabilisierung niederkoordinierter M(CO)-Bausteine: Synthese Nakazawa, Y. Yamaguchi and K. Miyoshi), 193 und Reaktivitat von {(m°-C;H,SiMe;),Hf(C=CPh),}M(CO) Photoabsorption (M = Ni, Co) (H. Lang, M. Herres and W. Imhof), 283 Photoabsorption study of electronic excited states of (7>-cyclo- Synthesis of a polymer-supported o-phenylene(diphosphine) and pentadienyl)n°-arene manganese (S.Yu. Ketkov), 225 characterization of some metal complexes (N.R. Champness, Photochemistry W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 Photochemical reactions of 2-(pentamethyldisilanyl)furan and 2- Niobium (pentamethyldigermanyl)furan. Formation of a radical pair Syntheses and electrochemical behaviour of novel dithiolatonio- (K. Mochida, K. Kimijima, M. Wakasa and H. Hayashi), 101 bium-(IV) and -(V) complexes with two 7°-cyclopentadienyl Platinum rings (F. Guyon, J. Amaudrut, M.-F. Mercier and K. Shimizu), Phosphine-nitrile ligands: the molecular structure of cis-2-di- 187 phenylphosphino-1-cyanocyclopentane and studies of the Nitrobenzene donor/acceptor properties of this and related ligands (E.J. Etude électrochimique des cations (n>-cyclopentadiényl fer 7°- Fredericks, M.J. Gindling, L.C. Kroll and B.N. Storhoff), 289 nitrobenzéne ou 7°-nitrotoluénes)*. Electrosynthése des Synthesis of a polymer-supported o-phenylene(diphosphine) and dérivés nitrosés correspondants (N. Guennec and C. Moinet), characterization of some metal complexes (N.R. Champness, 233 W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 Nitrosobenzene Polymer Etude électrochimique des cations (>-cyclopentadiényl fer 7°- Synthesis of a polymer-supported o-phenylene(diphosphine) and nitrobenzéne ou 7°-nitrotoluénes)*. Electrosynthése des characterization of some metal complexes (N.R. Champness, dérivés nitrosés correspondants (N. Guennec and C. Moinet), W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 233 Polymerization Nuclear magnetic resonance Molecular mechanical studies on the olefin metathesis reaction. Coordination complexes of dimethyltin dichloride with C-nitroso I. Development and evaluation of tungsten carbene parame- compounds (M. Cameron, B.G. Gowenlock, R.V. Parish and ters: METMODI (L. Bencze and R. Szilagyi), 211 G. Vasapollo), 161 Olefin metathesis Radical Molecular mechanical studies on the olefin metathesis reaction. Photochemical reactions of 2-(pentamethyldisilanyl)furan and 2- I. Development and evaluation of tungsten carbene parame- (pentamethyldigermanyl)furan. Formation of a radical pair ters: METMOD! (L. Bencze and R. Szilagyi), 211 (K. Mochida, K. Kimijima, M. Wakasa and H. Hayashi), 101 Radiolysis Silyl Gas phase reactivity of aromatic silanes. The reaction of Substituentenabhangigkeit der Lithiumkoordination von Phosphi- Ph(CH), SiMe, (x = 0 or 1) with cationic electrophiles (M.E. nomethaniden und Molekiilstrukturen von (TMEDA)Li- Crestoni, S. Fornarini and G. Occhiucci), 109 [C(PPh,),(SiMe;)] und {(THF)Li[CH(PMe,),]}, (H.H. Raman spectrocopy Karsch, G. Grauvogl, P. Mikulcik, P. Bissinger and G. Miller), Schwingungsspektren, Normalkoordinatenanalysen und Synthe- 65 sen der t-Butylsilane ‘BuSiX,, X =H, D, F, Cl, Br, I (K. Stannoxy Hassler and M. Weidenbruch), 127 Organotin-substituted organosiloxanes: synthesis and characteri- Raman spectroscopy sation, including the crystal structure of 1,3-bis(triphenylstan- Schwingungsspektren und Normalkoordinatenanalysen der Di-t- noxy)-1,1,3,3-tetraphenyl-1,3-disiloxane (B.J. Brisdon, M.F. butylsilane ‘Bu,SiX,, X = H, D, F, Cl, Br, I (K. Hassler and Mahon, K.C. Molloy and P.J. Schofield), 145 M. Weidenbruch), 137 Sulfido Regioselectivity Heterometallic sulfido clusters by metal exchange: syntheses and On the regioselectivity of palladium catalyzed cross-coupling re- X-ray crystal structures of (n°-C5H4CH ,)MoFeCo(CO).(.3- actions of alkenylsilanes: participation of B-cationic organosil- S) and (m°-C5H,CH),Mo,Fe(CO),(3-S) (W.-H. Sun, S.-Y. icate-palladium species during the transmetallation (Y. Yang, H.-Q. Wang, Q.-F. Zhou and K.-B. Yu), 263 Hatanaka, K. Goda and T. Hiyama), 97 Sulfur Rhodium Komplexchemie perhalogenierter Cyclopentadiene und Alkine. N-substituted imidazole derivatives of rhodium(I) and iridium(I). XVI. Darstellung von 7-Cyclopentadienylkomplexen mit zwei Crystal structure of the head-to-head dinuclear compound und drei Chalkogensubstituenten am Ring, [C,;Cl,_,,- [Ir,(u-N-benzylimidazolato-N *,C?),(CO),] (F. Bonati, L.A. (ER),,(ER’)JML,, (ML,, = Mn(CO);, Fe(C;H;); m=1 oder Oro, M.T. Pinillos, C. Tejel and B. Bovio), 267 2; E=S, Se; R, R’=Me, Ph). Struktur von [C,Cl,- Synthesis of a polymer-supported o-phenylene(diphosphine) and (SMe), [C;H;]Fe (K. Siinkel, U. Birk, A. Blum and W. characterization of some metal complexes (N.R. Champness, Kempinger), 167 W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 Supported catalyst Ruthenium Synthesis of a polymer-supported o-phenylene(diphosphine) and Synthesis of a polymer-supported o-phenylene(diphosphine) and characterization of some metal complexes (N.R. Champness, characterization of some metal complexes (N.R. Champness, W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 W. Levason, R.D. Oldroyd and D.J. Gulliver), 275 Selenium Komplexchemie perhalogenierter Cyclopentadiene und Alkine. XVI. Darstellung von z-Cyclopentadienylkomplexen mit zwei Thiolate und drei Chalkogensubstituenten am Ring, [C ;Cl4_,,- Syntheses and electrochemical behaviour of novel dithiolatonio- (ER),,(ER’))ML,, (ML,, = Mn(CO)3, Fe(C;H5;); m= 1 oder bium-(IV) and -(V) complexes with two 7°-cyclopentadienyl 2; E=S, Se; R, R’=Me, Ph). Struktur von [C,Cl,- rings (F. Guyon, J. Amaudrut, M.-F. Mercier and K. Shimizu), (SMe), ]|C5;H;]Fe (K. Siinkel, U. Birk, A. Blum and W. 187 Kempinger), 167 Tin Silane Chemie der schweren Carben-Analogen R,M (M = Si, Ge, Sn). Gas phase reactivity of aromatic silanes. The reaction of XIX. Reaktionen von stabilem Diaminogermylen und -stan- Ph(,)C, SHiMe , (x = 0 or 1) with cationic electrophiles (M.E. nylen Me,Si(‘BuN),M (M = Ge, Sn) mit organischen Aziden Crestoni, S. Fornarini and G. Occhiucci), 109 (B. Klein and W.P. Neumann), 119 On the regioselectivity of palladium catalyzed cross-coupling re- Synthesis and properties of trifluoromethylated stannanes. The actions of alkenylsilanes: participation of B-cationic organosil- formation and NMR spectra of the difluoromethy!stannanes icate-palladium species during the transmetallation (Y. (CF;),(CF,H),,Sn(CH 3)4_,,-, (R. Eujen, N. Jahn and U. Hatanaka, K. Goda and T. Hiyama), 97 Thurmann), 153 Schwingungsspektren, Normalkoordinatenanalysen und Synthe- Titanium sen der t-Butylsilane ‘BuSiX,, X =H, D, F, Cl, Br, I (K. Electronic effects of bis(2-aryl-4,5,6,7-tetrahydroindeny])titano- Hassler and M. Weidenbruch), 127 cene dichlorides on the catalytic epoxidation of trans-3-hexene Schwingungsspektren und Normalkoordinatenanalysen der Di-t- (R.L. Halterman and T.M. Ramsey), 175 butylsilane ‘Bu,SiX,, X = H, D, F, Cl, Br, I (K. Hassler and Stabilisierung niederkoordinierter M(CO)-Bausteine: Synthese M. Weidenbruch), 137 und Reaktivitat von {(m°-C;H,SiMe,),Hf(C=CPh),}M(CO) Silanyl (M = Ni, Co) (H. Lang, M. Herres and W. Imhof), 283 Photochemical reactions of 2-(pentamethyldisilanyl)furan and 2- Transmetallation (pentamethyldigermanyl)furan. Formation of a radical pair On the regioselectivity of palladium catalyzed cross-coupling re- (K. Mochida, K. Kimijima, M. Wakasa and H. Hayashi), 101 actions of alkenylsilanes: participation of B-cationic organosil- Silicon icate-palladium species during the transmetallation (Y. Stabilisierung niederkoordinierter M(CO)-Bausteine: Synthese Hatanaka, K. Goda and T. Hiyama), 97 und Reaktivitét von {(n°-C;H,SiMe,)>Hf(C=CPh),}M(CO) Tungsten (M = Ni, Co) (H. Lang, M. Herres and W. Imhof), 283 Molecular mechanical studies on the olefin metathesis reaction. Siloxanes I. Development and evaluation of tungsten carbene parame- Organotin-substituted organosiloxanes: synthesis and characteri- ters: METMODI (L. Bencze and R. Szilagyi), 211 sation, including the crystal structure of 1,3-bis(triphenylstan- Reactions of the cationic but-2-yne complex [WI(COXNCMe)- noxy)-1,1,3,3-tetraphenyl-1,3-disiloxane (B.J. Brisdon, M.F. {Ph,P(CH,)PPhj}(n?-MeCMe)|[BF,] with bidentate nitro- Mahon, K.C. Molloy and P.J. Schofield), 145 gen donor ligands (P.K. Baker and K.R. Flower), 221 C10 Unsaturated electrophiles X-ray diffraction Reactions of unsaturated electrophiles with trans-(PMe;),- Magnesium compounds: classification and analysis of crystallo- Pd(PhXNHPh) (J.M. Boncella and L.A. Villanueva), 297 graphic and structural data (C.E. Holloway and M. Melnik), 1 Synthesis and magnetic studies of the metallocarborane sandwich Vanadium salts [Fe(C;Mes;),]IM(C,B)H,,).)] (M=Cr, Fe, Ni) (J.M. A route to 7?-alkyne complexes of vanadium(I): crystal structure Forward, D.M.P. Mingos and A.V. Powell), 251 of trans-[[V(CO),(PMe,Ph),(2-butyne)] (H. Gailus, H. Mael- ger and D. Rehder), 181