Joining Technology of -TiAl Alloys Joining Technology of -TiAl Alloys Sónia Simões Filomena Viana Manuel F. Vieira CEMUC Faculdade de Engenharia da Universidade do Porto (FEUP) Universidade do Porto Porto Portugal p, p, A SCIENCE PUBLISHERS BOOK A SCIENCE PUBLISHERS BOOK Cover illustrations reproduced with kind permission of the fi rst author of the book, Sónia Simões CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2017 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Printed on acid-free paper Version Date: 2200117700141096 International Standard Book Number-13: 997788--11--44998877--43183794--23 (Hardback) This book contains information obtained from authentic and highly regarded sources. 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Other titles: Joining technology of gamma titanium-aluminum alloys Description: Boca Raton, FL : CRC Press, 2017. | “A Science Publishers book.” | Includes bibliographical references and index. Identifi ers: LCCN 2017008753| ISBN 9781498738743 (hardback : alk. paper) | ISBN 9781498738750 (e-book : alk. paper) Subjects: LCSH: Titanium-aluminum alloys. | Joints (Engineering) Classifi cation: LCC TN693.T5 S537 2017 | DDC 669/.7322--dc23 LC record available at https://lccn.loc.gov/2017008753 Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Preface γ-TiAl alloys are a novel class of advanced structural materials which enlarge the possible choices of materials for high temperature applications, especially when the weight reduction of the components is critical for structural applications. The development and processing of high temperature materials is crucial to technological advances in engineering areas where materials have to meet extreme demands. γ-TiAl alloys have a series of properties that make them attractive to the aerospace and automotive industries and are being used to produce components for the new generation of aircraft engines and automotive turbochargers. The joining of components is an essential part of a man-made product manufacturing. The joining processes often contribute significantly to the cost of the final product and to the production difficulties. γ-TiAl alloys can be successfully joined by processes such as friction welding, brazing, diffusion bonding and transient liquid phase bonding. These processes do not require the melting of the base material and therefore the joints do not present high residual stress, so that the formation of some deleterious intermetallics can be prevented. However, very demanding bonding conditions are needed to produce a sound interface with the desired mechanical properties. Even when the bulk materials remain at temperatures significantly below their melting point (such as in soldering, brazing and diffusion bonding), the required processing temperatures often induce phase transformations, structural modifications and localised stresses that impair the properties of the joints. The joining of γ-TiAl alloys, either to themselves or to dissimilar materials, requires the application of new strategies in order to obtain good quality joints in appropriate processing conditions. This book describes the current state of knowledge regarding the bonding of these advanced materials, with emphasis on the techniques used by the authors, who for more than a decade, have undertaken research into the joining of these materials by solid-state diffusion bonding and brazing, together with teams from the Universities of Coimbra and Minho. This book has been organised into eight chapters—three introductory chapters covering the applications, structure and conventional processes for joining γ-TiAl alloys, followed by five chapters focusing on the use vi Joining Technology of -TiAl Alloys of reactive multilayers to bond γ-TiAl alloys to themselves and to other materials. This book is intended for students, materials scientists, engineers, and technicians who desire to familiarise themselves with the joining of γ-TiAl alloys and with the new developments in this field. Sónia Simões Filomena Viana Manuel F. Vieira Acknowledgements This book is the result of a collaborative research work and fruitful discussions with many colleagues working in the field of joining of advanced materials. Though it would be impossible to thank all those who have directly or indirectly contributed to this project, a few specific references will be made to the following contributors. We would like to acknowledge the invaluable cooperation of the team from the University of Coimbra (CEMUC), Prof. Dr. Maria Teresa Vieira and Dr. Ana Sofia Ramos, in all aspects related to the reactive multilayer systems and to the team from the University of Minho, Dr. Ana Maria Pinto and Dr. Aníbal Guedes, in the brazing of γ-TiAl alloys. The authors are also very grateful to Dr. Mustafa Koçak for his scientific and technical support and to the facilities provided at the Helmholtz-Zentrum Geesthacht. We would like to acknowledge the financial support of the Fundação para a Ciência e Tecnologia-FCT and the Faculty of Engineering, University of Porto-FEUP. Finally, we would like to thank our colleagues, co-workers and students at the Department of Metallurgical and Materials Engineering, University of Porto, for their encouragement and suggestions. Contents Preface v Acknowledgements vii List of Abbreviations xiii List of Figures xv List of Tables xxiii 1. γ-TiAl Alloys 1 1.1 Introduction 1 1.2 Structure of γ-TiAl Alloys 2 1.3 Properties of γ-TiAl Alloys 6 1.4 Processing of γ-TiAl Alloys 8 1.5 Concluding Remarks 11 1.6 References 12 2. Joining of γ-TiAl Alloys 15 2.1 Introduction 15 2.2 Fusion Welding 16 2.3 Friction Welding 20 2.4 Brazing 23 2.5 Concluding Remarks 27 2.6 References 28 3. Diffusion Bonding of γ-TiAl Alloys 30 3.1 Introduction 30 3.2 Diffusion Bonding 31 3.2.1 Diffusion Bonding Parameters 32 3.2.2 Interdiffusion in γ-TiAl Intermetallics 34 3.3 Diffusion Bonding of γ-TiAl Alloys 35 3.3.1 Diffusion Bonding of γ-TiAl Alloys using Interlayers 44 3.4 Concluding Remarks 48 3.5 References 49
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