IS 13842: m-Ureidoaniline, Technical

10 Pages·1993·1.1 MB·English

by  Bureau of Indian Standards

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timely dissemination of this information in an accurate manner to the public.
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“The Right to Information, The Right to Live” “Step Out From the Old to the New”
IS 13842 (1993): m-Ureidoaniline, Technical [PCD 9: Organic
Chemicals Alcohols and Allied Products and Dye
Intermediates]
“!ान $ एक न’ भारत का +नम-ण”
Satyanarayan Gangaram Pitroda
““IInnvveenntt aa NNeeww IInnddiiaa UUssiinngg KKnnoowwlleeddggee””
“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता हहहहै””ै”
Bhartṛhari—Nītiśatakam
“Knowledge is such a treasure which cannot be stolen”

.
IS IS842 : 1993

m-UREIDOANILINE, TECHNICAL -
SPECIFICATION
UDC 667~281.26

@ BIS 1993
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI 110002
September 1993 Price Group 2
eyD setaidemretnI lanoitceS ,eettimmoC PCD 11
FOREWORD
sihT naidnI dradnatS was detpoda yb eht uaeruB fo naidnI Standards, retfa eht tfard dezilanif yb
eht eyD setaidemretnI lanoitceS eettimmoC had neeb devorppa yb eht ,muelorteP laoC and
detaleR stcudorP noisiviD .licnuoC
m enilinaodierU ( C, ,H N,O ) is desu as an etaidemretni rof evitcaer .seyd tI is detneserper yb
eht gniwollof larutcurts :alumrof
NH:!
I
HZ-UREIDOANILINE +
( MOLECULAR MASS 151)
CAS
REGISTRY No. (25711-72-2)
roF eht esoprup fo gnidiced rehtehw a ralucitrap tnemeriuqer fo this standard is deilpmoc ,htiw
eht lanif ,eulav devresbo ro ,detaluclac gnisserpxe eht tluser fo a tset ro ,sisylana shall eb dednuor
ffo ni ecnadrocca htiw SI 2 : 1960 seluR‘ rof gnidnuor ffo laciremun seulav ( revised )‘. ehT
rebmun fo tnacifingis secalp deniater ni eht dednuor ffo seulav dluohs eb eht emas as that fo eht
deificeps seulav ni this standard.
IS 13842 : 1993
Indian Standard
mUREIDOANILINE,TECHNICAL-
SPECTFICiTlON
1 SCOPE 4 .2 Marking
sihT standard sebircserp eht stnemeriuqer and E hca, reniatnoc shall raeb ylbigel and ylbiledni
eht sdohtem fo sampling and tset rof -odieru-m 1t he gniwollof :noitamrofni
.enilina
)a emaN fo eht ;lairetam
2 REFERENCES
)b noitacidnI fo eht ecruos fo ;erutcafunam
ehT gniwollof naidnI Standards era yrassecen
)c ,eraT ten and ssorg mass;
stcnujda ot this standard:
)d hctaB ;rebmun and
IS No. Title
)e htnoM and raey fo .erutcafunam
1070 : 1992 retaW rof lareneg yrotarobal
esu (
third revision )
4 1.2.1 ehT sreniatnoc yam osla eb dekram htiw
2552 : 1989 leetS drums ( dezinavlag and t eh dradnatS Mark.
dezinavlagnu ) (
third revision )
i SAMPLING
5299 : 1969 sdohteM fo sampling and
stset rof eyd setaidemretni i.1 evitatneserpeR samples fo eht lairetam shall
i e) drawn as debircserp ni fo.3 SI 5299 : .9691
3 REQUIREMENTS
3.1 Description 2.5 Number of Tests
The lairetam shall eb ,tsiom nworb-hsiwolley 5.2.1 tseT rof yassa and noitanimreted fo
ot yerg ro elap elprup ni .ruoloc enimaidenelynehp-n shall eb detcudnoc no
hca: fo eht laudividni samples.
3.2 ehT lairetam shall osla ylpmoc htiw eht
stnemeriuqer nevig ni elbaT 1
5.2.2 stseT rof eht noitanimreted fo gniniamer
,scitsiretcarahc ,yleman noitpircsed and rettam
Table 1 Requirements for m-Ureidoaniline, elbulosni ni retaw shall eb detcudnoc no eht
Technical etisopmoc .elpmas

( Clause 3. 2 )
5.3 Criteria for Conformity

IS No. Characteristic Require- Methods
ments of Test, 5.3.1 For Individual Samples
Ref to
Annex ehT tol shall eb deralced as gnimrofnoc ot eht
)1( (2) (3) (4) tnemeriuqer fo yassa and enimaidenelynehp
9 rettaM elbulosni ni retaw 10.0 A tnetnoc fi hcae fo eht laudividni tset tluser
( no 100 tnecrep sisab ,) seifsitas eht tnaveler tnemeriuqer nevig ni
tnecrep yb ,ssam XUM
elbaT 1.
ii) ,yassA tnecrep yb ,ssam Min 45.0 B
. . . enimaidenelynehP-m ( no 100 0.50 C 5.3.2
111) For Composite Sample
tnecrep sisab ,) tnecrep yb
,ssam xaM roF gniralced eht ytimrofnoc fo eht tol ot eht
stnemeriuqer fo all rehto scitsiretcarahc ( ees
4 PACKING AND MARKING 5.2.2 ) detset no eht etisopmoc ,elpmas eht tset
stluser rof hcae fo eht citsiretcarahc shall
4.1 Packing yfsitas eht tnaveler stnemeriuqer nevig ni 3.1
ehT lairetam shall eb dekcap ni leets drums and elba’l 1.
( ees S1 2552 : 1989 ) ro EPDH bags denil htiw
elbatius enelyhteylop mlif ro as deerga ot -teb 6 TEST METHODS
neew eht resahcrup and eht .reilppus hcaE 6.1 stseT shall eb deirrac tuo gnidrocca ot eht
reniatnoc shall eb yleruces .desolc sdohtem derrefer ni 1oc 4 fo elbaT 1.
1
.
SI 13842 : 1993
6.2 ytilauQ of stnegaeR NOTE - eruP‘ ’slacimehc llahs naem slacimehc taht
do ton niatnoc seitirupmi hcihw tceffa eht stlcser fo
sselnU deificeps esiwrehto erup slacimehc dna
.’sisylana
dellitsid water ( see SI 1070 : 1992 ) llahs eb
deyolpme ni tests.
ANNEX A
1, IS .oN )i( dna l-A 2-A ]
[ Table Clauses and
NOITANIIv!RETED FO RETTAM ELBULOSNI NI RETAW
A-l PROCEDI JRE 2-A NOITALUCLAC
Matter elbulosni
hgieWI yletarucca tuoba 30 g of the elpmas dna
ni water, ( 100 tnecrep M, x
refsnart ti ot a. ertil-1 .rekaeb ddA 500 lm of 10 000
,)sisab tnecrep yb =ssam M x A
water rits yllacinahcem dna mraw pu ot .C°53 2
ritS for 15 setunim dna retlif hguorht -retnuoc where
desiop papers dna wash the eudiser htiw 300 lm M, = ssam ni g of ;eudiser
dloc water. yrD the eudiser at 90 ot 100 C“
llit tnatsnoc .ssam evreserP the etartlif dna M, = ssam ni g of elpmas ;nekat dna
sgnihsaw for yassa ( see xennA B ). A =E ,yassa tnecrep yb ssam (see xennA B)
+
ANNEX B
1, ZS .oN )ii( ]
[ Table
YASSA
B-l REAGENTS cirolhcordyh dica dna 5.0 g of muissatop -orb
.edim ,etartiT elihw gnirrits ,yllacinahcem htiw
B-l.1 Hydrochloric Acid - detartnecnoC
dradnats muidos ,etirtin noitulos at C°02-51
gnisu muissatop starch edidoi paper ot a
B-l.2 Potassium Bromide

3 etunim dne .tniop
B-l.3 Sodium Nitrite Solution - - 0.1 N.
3-B NOITALUCLAC
B-l.4 Potassium Starch Iodide Paper V x Nx 302
,yassA tnecrep yb ssam =
B-2 PROCEDURE M
where
refsnarT the etartlif dna sgnihsaw deniatbo ni
V = emulov ni lm of muidos etirtin noitulos
gninimreted rettam elbulosni ni water (see A-l) ,desu
otni ertil-eno cirtemulov ksalf dna etulid ot
kram htiw water at C°02 dna shake .llew N E ytilamron of dradnats muidos etirtin
noitulos ( 3.l-B ), dna
ettepiP tuo 50 lm touqila ni ertil-enota .rekaeb
ddA 400 lm eci dloc water, 25 lm detartnecnoc M = ssam ni g of elpmas nekat for the test.
2
.
SI 13842 : 1993
ANNEX C
[ Table 1, SlNo. )iii( ]
NOITANIMRETED FO ENIMAIDENELYNEHP-m
l-C ENILTUO FO EHT DOHTEM 90 lm fo retaw rof eerht .setunim ,nehT yb
snaem fo eht ,rotacilppa taoc eht etalp htiw
enimaidenelynehp-m ni enilinaodieru-m is -reted
acilis leg reyal fo ssenkciht ton gnideecxe 0.5 mm
denim yb niht reyal .yhpargotamorhc
and ecalp ti ni eht nevo deniatniam at 110°C rof
C-2 SUTARAPPA 90 .setunim yB snaem fo a ,eldeen kram a niht
enil esiwhtdiw no all setalp at tuoba 3 mc morf
C-2.1 cihpargotamorhC rebmahC - 220 mm x
eht reppu .egde 41~0 evomer a band fo tuoba
100 mm x 220 mm
5 mm htdiw acilis leg morf rehtie fo eht laretal
sides fo hcae .etalp
C-2.2 ettepiporciM - fo 1,-ol and 5~1 yticapac
C-2.3 Thin Layer Chromatographic Glass C-4.2 Preparation of Sample Solution
Plates - 200 mm x 200 mm ezinegomoH eht elpmas rof a wef setunim and
hgiew yb snaem fo a gnihgiew elttob 2.0 g 100
C-2.4 nihT etalP rotacilppA - elbatsujdA
tnecrep basis fo eht lairetam and refsnart ot a
C-2.5 cihpargotamorhC yarpS elttoB lm-OOl cirtemulov .ksalf evlossiD ni lonahtem
and ekam up eht noitulos ot eht kram yb -dda
C-2.6 nevO
gni .ainomma
C-2.7 gnihgieW elttoB
C-4.3 topS 1p-ol fo eht elpmas noitulos )2.4-C(
C-3 STNEGAER and 5-~1 fo eht ecnerefer noitulos ( C-3.2 ) on
eht niht reyal .etalp ecalP eht repoleved ni eht
C-3.1 aciliS leG G - lartuen
.rebmahc esolC eht rebmahc htiw its dil and
wolla ot eveihca .muirbiliuqe woN ecalp eht
C-3.2 enimaidenelynehp-m noituloS .- 0.02 -rep
tnec ni .lonahtem eta!p ylluferac ni eht rebmahc and wo!la eht
tneule ot nur ni gnidnecsa rennam rof tuoba
C-3.3 tneulE - mroforolhc : lonahte ( 80 : 20 .) 100 .setunim evomeR eht etalp morf eht
rebmahc and yrd ffo eht tnevlos .yletelpmoc
C-3.4 yarpS noituloS - 0.5 tnecrep ni 2N ICH
yarpS eht deird etalp htiw yarps noitulos
and lonahtem ni lauqe .noitroporp
( C-3.4 ) and taeh ti ot 100°C.
C-4 PROCEDURE C-4.3.1 yB lausiv ,nosirapmoc eht tops -serroc
gnidnop ot enimaidenelynehp-m ni eht elpmas
C-4.1 Preparation of the Chromatographic Plates
shall evah ytisne.tni lauqe ot ro less than that
xiM 50 g fo lartuen acilis leg G htiw 85 ot fo ecnerefer .elpmas
.

dradnatS Mark
ehT esu fo eht dradnatS Mark is denrevog yb eht snoisivorp fo eht Bureau of Indian
Standards Act, 1986 and eht seluR and snoitalugeR edam .rednuereht ehT dradnatS Mark
no stcudorp derevoc yb an naidnI dradnatS syevnoc eht ecnarussa that yeht evah neeb
decudorp ot ylpmoc htiw eht stnemeriuqer fo that standard rednu a llew denifed metsys
fo ,noitcepsni gnitset and ytilauq lortnoc hcihw is desived and desivrepus yb SIB and
detarepo yb eht .recudorp dradnatS dekram stcudorp era osla ylsuounitnoc dekcehc yb
rofSIB ytimrofnoc ot that standard as a rehtruf .draugefas sliateD fo snoitidnoc rednu
hcihw a ecnecil rof eht esu fo eht dradnatS Mark yam eb detnarg ot srerutcafunam 0,
srecudorp yam eb deniatbo morf eht uaeruB fo naidnI Standards.
.
Bureau of Indian Standards
SIB si a yrotutats noitutitsni dehsilbatse rednu the uaeruB of Indian Standards Act, 1986 to
etomorp suoinomrah tnempoleved of the seitivitca of ,noitazidradnats gnikram dna ytilauq
noitacifitrec of goods dna gnidnetta ot detcennoc srettam ni the .yrtnuoc
Copyright
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ni yna mrof tuohtiw the roirp noissimrep ni gnitirw of .SIB sihT does ton edulcerp the free ,esu
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or grade .snoitangised seiriuqnE gnitaler ot thgirypoc eb addressed ot the rotceriD
( snoitacilbuP ), .SIB
noisiveR of naidnI sdradnatS
stnemdnemA deussi~era ot sdradnats as the deen sesira no the sisab of .stnemmoc sdradnatS
are osla deweiver ;yllacidoirep a dradnats gnola htiw stnemdnema si demriffaer nehw hcus weiver
setacidni that on segnahc are ;dedeen fi the weiver setacidni that segnahc are ,dedeen ti si nekat
pu for .noisiver sresU of naidnI sdradnatS dluohs niatrecsa that yeht are ni noissessop of the
tsetal stnemdnema or noitide yb gnirrefer ot the tsetal eussi of SIB‘ .koobdnaH dna sdradnatS‘
ylhtnoM .’snoitiddA stnemmoC no siht naidnI dradnatS yam eb tnes ot SIB gnivig the gniwollof
:ecnerefer
:toD No. )828(llCP
Amendments Issued Since Publication
dnemA No. Date of eussI txeT detceffA
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