34 Topics in Organometallic Chemistry Editorial Board: M. Beller J. M. Brown P. H. Dixneuf l l A. Fu¨rstner L. S. Hegedus P. Hofmann l l T. Ikariya L. A. Oro M. Reetz Q.-L. Zhou l l l Topics in Organometallic Chemistry Recently Published Volumes IronCatalysis–Fundamentalsand RegulatedSystemsforMultiphaseCatalysis Applications VolumeEditors:W.Leitner,M.Ho¨lscher VolumeEditor:B.Plietker Vol.23,2008 Vol.33,2010 OrganometallicOxidationCatalysis VolumeEditors:F.Meyer,C.Limberg MedicinalOrganometallicChemistry Vol.22,2007 VolumeEditors:G.Jaouen,N.Metzler-Nolte Vol.32,2010 N-HeterocyclicCarbenesinTransition MetalCatalysis C-XBondFormation VolumeEditor:F.Glorius VolumeEditor:A.Vigalok Vol.21,2006 Vol.31,2010 DendrimerCatalysis TransitionMetalComplexesofNeutral VolumeEditor:L.H.Gade h1-CarbonLigands Vol.20,2006 VolumeEditors:R.Chauvin,Y.Canac Vol.30,2010 MetalCatalyzedCascadeReactions VolumeEditor:T.J.J.Mu¨ller PhotophysicsofOrganometallics Vol.19,2006 VolumeEditor:A.J.Lees CatalyticCarbonylationReactions Vol.29,2010 VolumeEditor:M.Beller Vol.18,2006 MolecularOrganometallicMaterials forOptics BioorganometallicChemistry VolumeEditors:H.LeBozec,V.Guerchais VolumeEditor:G.Simonneaux Vol.28,2010 Vol.17,2006 ConductingandMagneticOrganometallic SurfaceandInterfacialOrganometallic MolecularMaterials ChemistryandCatalysis VolumeEditors:M.Fourmigue´,L.Ouahab VolumeEditors:C.Cope´ret,B.Chaudret Vol.27,2009 Vol.16,2005 ChiralDiazaligandsforAsymmetric MetalCatalystsinOlefinPolymerization Synthesis VolumeEditor:Z.Guan VolumeEditors:M.Lemaire,P.Mangeney Vol.26,2009 Vol.15,2005 Bio-inspiredCatalysts PalladiuminOrganicSynthesis VolumeEditor:T.R.Ward VolumeEditor:J.Tsuji Vol.25,2009 Vol.14,2005 DirectedMetallation MetalCarbenesinOrganicSynthesis VolumeEditor:N.Chatani VolumeEditor:K.H.Do¨tz Vol.24,2007 Vol.13,2004 Iridium Catalysis Volume Editor: Pher G. Andersson With Contributions by (cid:1) (cid:1) (cid:1) John F. Bower Daniel Carmona Jongwook Choi (cid:1) (cid:1) Carmen Claver Robert H. Crabtree Montserrat Die´guez (cid:1) Alan S. Goldman (cid:1) John F. Hartwig (cid:1) Michael J. Krische (cid:1) Luis A. Oro (cid:1) Oscar Pa`mies (cid:1) (cid:1) (cid:1) (cid:1) Andreas Pfaltz Mark J. Pouy Ourida Saidi (cid:1) Jonathan M. J. Williams David H. Woodmansee Editor Prof.PherG.Andersson UppsalaUniversity DepartmentofBiochemistryandOrganicChemistry Box576,BMC S-75123Uppsala Sweden [email protected] ISSN1436-6002 e-ISSN1616-8534 ISBN978-3-642-15333-4 e-ISBN978-3-642-15334-1 DOI10.1007/978-3-642-15334-1 SpringerHeidelbergDordrechtLondonNewYork #Springer-VerlagBerlinHeidelberg2011 Thisworkissubjecttocopyright.Allrightsarereserved,whetherthewholeorpartofthematerialis concerned,specificallytherightsoftranslation,reprinting,reuseofillustrations,recitation,broadcasting, reproductiononmicrofilmorinanyotherway,andstorageindatabanks.Duplicationofthispublication orpartsthereofispermittedonlyundertheprovisionsoftheGermanCopyrightLawofSeptember9, 1965,initscurrentversion,andpermissionforusemustalwaysbeobtainedfromSpringer.Violations areliabletoprosecutionundertheGermanCopyrightLaw. Theuseofgeneraldescriptivenames,registerednames,trademarks,etc.inthispublicationdoesnot imply, even in the absence of a specific statement, that such names are exempt from the relevant protectivelawsandregulationsandthereforefreeforgeneraluse. Coverdesign:Ku¨nkelLopkaGmbH Printedonacid-freepaper SpringerispartofSpringerScience+BusinessMedia(www.springer.com) Volume Editor Prof.PherG.Andersson UppsalaUniversity DepartmentofBiochemistry andOrganicChemistry Box576,BMC S-75123Uppsala Sweden [email protected] Editorial Board Prof.MatthiasBeller Prof.PeterHofmann Leibniz-Institutfu¨rKatalysee.V. Organisch-ChemischesInstitut anderUniversita¨tRostock Universita¨tHeidelberg Albert-Einstein-Str.29a ImNeuenheimerFeld270 18059Rostock,Germany 69120Heidelberg,Germany [email protected] [email protected] Prof.JohnM.Brown Prof.TakaoIkariya ChemistryResearchLaboratory DepartmentofAppliedChemistry OxfordUniversity GraduateSchoolofScienceandEngineering MansfieldRd., TokyoInstituteofTechnology OxfordOX13TA,UK 2-12-1Ookayama,Meguro-ku, [email protected] Tokyo152-8550,Japan [email protected] Prof.PierreH.Dixneuf Prof.LuisA.Oro CampusdeBeaulieu Universite´deRennes1 InstitutoUniversitariodeCata´lisisHomoge´nea Av.duGlLeclerc DepartmentofInorganicChemistry 35042RennesCedex,France I.C.M.A.-FacultyofScience [email protected] UniversityofZaragoza-CSIC Zaragoza-50009,Spain Prof.AloisFu¨rstner [email protected] Max-Planck-Institutfu¨rKohlenforschung Prof.ManfredReetz Kaiser-Wilhelm-Platz1 Max-Planck-Institutfu¨rKohlenforschung 45470Mu¨lheimanderRuhr,Germany Kaiser-Wilhelm-Platz1 [email protected] 45470Mu¨lheimanderRuhr,Germany Prof.LouisS.Hegedus [email protected] DepartmentofChemistry Prof.Qi-LinZhou ColoradoStateUniversity StateKeyLaboratoryofElemento-organic FortCollins,Colorado80523-1872,USA Chemistry [email protected] NankaiUniversity WeijinRd.94,Tianjin300071PRChina [email protected] v . Topics in Organometallic Chemistry Also Available Electronically Topics in Organometallic Chemistry is included in Springer’s eBook package ChemistryandMaterialsScience.Ifalibrarydoesnotoptforthewholepackagethe book series may be bought on a subscription basis. Also, all back volumes are availableelectronically. For all customers who have a standing order to the print version of Topics in Organometallic Chemistry, we offer free access to the electronic volumes of the SeriespublishedinthecurrentyearviaSpringerLink. Ifyoudonothaveaccess,youcanstillviewthetableofcontentsofeachvolume andtheabstractofeacharticlebygoingtotheSpringerLinkhomepage,clickingon “ChemistryandMaterialsScience,”underSubjectCollection,then“BookSeries,” underContentTypeandfinallybyselectingTopicsinOrganometallicChemistry. Youwillfindinformationaboutthe – EditorialBoard – AimsandScope – InstructionsforAuthors – SampleContribution at springer.com using the search function by typing in Topics in Organometallic Chemistry. ColorfiguresarepublishedinfullcolorintheelectronicversiononSpringerLink. Aims and Scope The series Topics in Organometallic Chemistry presents critical overviews of researchresultsinorganometallicchemistry.Asourunderstandingoforganometallic structures,propertiesandmechanismsgrows,newpathsareopenedforthedesign of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being made that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Reviewarticlesaregenerallyinvitedbythevolumeeditors. In references Topics in Organometallic Chemistry is abbreviated Top Organomet Chemandiscitedasajournal. vii . Preface Theuseofiridiumincatalystsfororganicreactionsisarapidlyevolvingfieldthat coversawiderangeofchemicalreactivity.Withthisinmind,ithasbeenapleasure to edit this volume on Iridium Catalysis, which aims to present the reader with a comprehensiveresourcethatcoversthefieldandfocusesonrecentadvancesinthe area.Allchaptershavebeenwrittenbyleadingchemistsinthecorrespondingarea andIamextremelythankfultothemfortheircontributionsandefficientcollabora- tioninthisproject:RobertHCrabtree,CarmenClaver,MontserratDieguez,Oscar Pamies, Andreas Pfaltz, David H. Woodmansee, Jonathan M.J. Williams, Ourida Saidi,MichaelJ.Krische,JohnF.Bower,AlanS.Goldman,JongwookChoi,John F.Hartwig,MarkJ.Pouy,LuisA.Oro,andDanielCarmona.Iamalsogratefulfor allhelpreceivedfromSPRINGER,especiallyfromJuttaLindenborn. Ihopethatthisbookwillbeusefultoresearchers,teachers,andstudentsinvolved inorganicsynthesisandthatitmightalsoattractnewpeopletotheinterestingfield ofcatalysis. Uppsala,Sweden PherG.Andersson 2010 ix .
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