Ionic Polymer Metal Composites for Sensors and Actuators PDF
Preview Ionic Polymer Metal Composites for Sensors and Actuators
Engineering Materials Inamuddin Abdullah M. Asiri Editors Ionic Polymer Metal Composites for Sensors and Actuators Engineering Materials This series provides topical information on innovative, structural and functional materials and composites with applications in optical, electrical, mechanical, civil, aeronautical, medical, bio- and nano-engineering. The individual volumes are complete, comprehensive monographs covering the structure, properties, manufac- turing process and applications of these materials. This multidisciplinary series is devotedtoprofessionals,studentsandallthoseinterestedinthelatestdevelopments in the Materials Science field. More information about this series at http://www.springer.com/series/4288 Inamuddin Abdullah M. Asiri (cid:129) Editors Ionic Polymer Metal Composites for Sensors and Actuators 123 Editors Inamuddin AbdullahM. Asiri Department ofChemistry Department ofChemistry Faculty of Science Faculty of Science KingAbdulaziz University KingAbdulaziz University Jeddah, SaudiArabia Jeddah, SaudiArabia ISSN 1612-1317 ISSN 1868-1212 (electronic) Engineering Materials ISBN978-3-030-13727-4 ISBN978-3-030-13728-1 (eBook) https://doi.org/10.1007/978-3-030-13728-1 LibraryofCongressControlNumber:2019932625 ©SpringerNatureSwitzerlandAG2019 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfrom therelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or the editors give a warranty, expressed or implied, with respect to the material contained hereinorforanyerrorsoromissionsthatmayhavebeenmade.Thepublisherremainsneutralwithregard tojurisdictionalclaimsinpublishedmapsandinstitutionalaffiliations. ThisSpringerimprintispublishedbytheregisteredcompanySpringerNatureSwitzerlandAG Theregisteredcompanyaddressis:Gewerbestrasse11,6330Cham,Switzerland Contents Metal-Organic Framework Composites IPMC Sensors and Actuators. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Bianca Maranescu and Aurelia Visa Polysaccharide-Based Ionic Polymer Metal Composite Actuators . . . . . 19 A. Popa, A. Filimon and L. Lupa Conducting Polymer Based Ionic Polymer Metal Composite Actuators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 David Gendron Role of Metal Ion Implantation on Ionic Polymer Metal Composite Membranes. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 Adina Maria Dobos and A. Filimon Study on Time-Dependent Bending Response of IPMC Actuator. . . . . . 75 Hyung-Man Kim and N. D. Vinh Ionic Polymer-Metal Composite Membranes Methods of Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139 Fatma Aydin Unal, Hakan Burhan, Fatima Elmusa, Shukri Hersi and Fatih Sen Ionic Polymer-Metal Composite Actuators Operable in Dry Conditions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149 FatmaAydinUnal,HakanBurhan, SumeyyeKarakus,GizemKaraelioglu and Fatih Sen Pressure Sensors Based on IPMC Actuator . . . . . . . . . . . . . . . . . . . . . . 161 Gokhan Topcu, Tugrul Guner and Mustafa M. Demir v vi Contents Robotic Assemblies Based on IPMC Actuators . . . . . . . . . . . . . . . . . . . 183 D. Josephine Selvarani Ruth Design and Fabrication of Deformable Soft Gripper Using IPMC as Actuator . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 Srijan Bhattacharya, Bikash Bepari and Subhasis Bhaumik Metal-Organic Framework Composites IPMC Sensors and Actuators BiancaMaranescuandAureliaVisa Abstract Metal-organic frameworks (MOFs), a highly studied class of complex structuredporousmaterials,containingdifferenttypesofcentralmetalionsattached to organic linkers, are used in various applications such as catalysis, separation, absorption,photochemistry,protonconductivity,biotechnology,magnetismandsen- soristicscienceetc.ThearchitecturalstructuresofMOFsprovidespecialproperties as improved thermal and mechanical stabilities, high surface areas and large pore sizes to these materials. The need for new functionalities is to take into account that the fabrication methods must be robust, scalable, friendly to environment and cost-effective. · · · Keywords Metal-organicframeworks Sensors Molecularmachines Volatile · organiccompounds Actuators 1 Introduction Developmentofmetal-organicframeworks(MOFs)orcoordinationpolymers(CPs) is one of the most active research fields among chemistry and materials research groups,duetoahighdiversityofapplications[1–9].MOFsnowcanbedesignedand constructedstartingfromawidediversityofmetalionsormetal-containingclusters, andorganicligands(Fig.1). Thevarietyofmetalions,organiclinkersandstructuralstylescomeupwithan endlessnumberofpotentialcombinations. InternationalRoadmapforDevicesandSystems(IRDS),adescendantofInterna- tionalTechnologyRoadmapforSemiconductors(ITRS)providespredictionsabout likelysemiconductorsanddevices,withthemainaimtoalignacademicandresearch lab efforts with electronic devices manufacturers and equipment suppliers. The 2017 edition reports, under emerging research materials, identify opportunities as B B.Maranescu·A.Visa( ) InstituteofChemistryTimis¸oaraoftheRomanianAcademy,300223Timis¸oara,Romania e-mail:[email protected] ©SpringerNatureSwitzerlandAG2019 1 InamuddinandA.M.Asiri(eds.),IonicPolymerMetalCompositesforSensors andActuators,EngineeringMaterials,https://doi.org/10.1007/978-3-030-13728-1_1 2 B.MaranescuandA.Visa Fig.1 Generalstructureof MOF multifunctional materials/sensors, generation and energy storage, medical, as well asflexibleelectronics[10]. Relyontheapplicationsetting,thesyntheticrouteisfollowedbothtobenefitfrom the complexity of organics moiety, to decrease the production costs and to reduce thesizetomoleculardimensions. 2 DesignandSynthesis Since 1995, when the first synthesis was reported in the literature [11], most of the syntheses have been performed by solvothermal methods using conventional heating[12–16].Usually,thereactiontimesneeded werelong,several days inthe caseofsolvothermalsynthesistosomeweeksfordiffusionmethods.Therefore,itis importanttofindmoreefficientandtechno-economicallyviablealternativesynthetic techniques,thatcanbeusedsuccessfullytoscaleuptheproductionofMOFs. Thenewlydevelopedapproaches,suchasultrasounds[17–21],mechanochemical [22–26],microwave(MW)[27–31]andelectrochemicalsynthesis[32–36],providea promisingalternativeoftime-consumingsynthesisbyshorteningthesynthesistimes andincreasingtheproductionyield. By comparing with traditionally used zeolites and carbon materials, MOFs are unique with reference to their extraordinarily high porosities, tunable pores, and variousfunctionalsites.Diversemethodshavebeenappliedtodetect/sensedifferent levels of gases, anions, cations, and various pollutants in addition of developing materialsforsensing,drugdelivery,andheterogeneous catalysisinmanycontexts (Fig.2). Metal-OrganicFrameworkCompositesIPMCSensorsandActuators 3 Fig.2 MOFasactuators andsensor 3 PropertiesandApplications 3.1 Nano/MolecularMachinesBasedActuators Veryimportantandpromisingresearchdirectionisthedesignandbuildingofmolec- ularmachines.In2016NobelprizeinchemistrywasgiventoJean-PierreSauvage, SirJamesFraserStoddartandBenL.Feringaforthisfascinatingdomain[37,38]. Inordertoconstructnanomaterialswithmachine-likefunctions,sometechnolo- gies were proposed by M. Venturi and co-workers [39]. Light-powered dynamic nanomachineswhichimplylightenergystimulationofmaterialsareofgreatinterest. Furthermore,lightstimuliareappliedtonanomachinesfromsmalldistanceswith- outphysicalinteraction,andtheenergyquantaaremeasuredbytuningtheintensity, wavelengthorpolarizationofthelight. C. Barrett and co-workers [40] highlighted in their review article the most encouraging models of the organization of switches and rotors into linear, two- dimensional assembly, and strong three-dimensional crystals. These dynamic sys- temsweredesignedandconstructedtoanswertoahighdiversityofactuationstimuli. ActuatorsworkingonthisprincipleofMOFscanalsobeusedasartificialmolecular machines[41,42]. M. Garcia Garibay and his co-workers [42, 43] performed researches in the domain of pillared paddlewheel MOFs constructed by a modular approach using 9,10-bis-(pyridylethynyl)triptycene as a column and molecular rotator and dicar- boxylatelinkersofvaryinglengthsandstericbulk.Using1,4-bicyclo[2.2.2]octane dicarboxylicacid(BODCA)-MOF,amaterialwithahigh-symmetryBODCAlinker inaZn Ocubiclattice,anultrafastrotationinanamphidynamiccrystallinemetal- 4 organicframeworkwasperformed(Fig.3a,b). Fourkeyarchitecturalelementsweretakingintoaccount:(1)rotorsizeandshape, (2)theaccessibilityoffreevolumehigherthanthevolumeofrotator,(3)thechemical natureofligandaswellasofmetalandthedegreeoffreedomforrotatortothestator and (4) the axial symmetries of rotator and stator. These kinds of molecules open newperspectivesintheareasasgasstorage,catalysis,andphotochemistry.
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