Introduction to Steels This page intentionally left blank Introduction to Steels Processing, Properties, and Applications P. C. Angelo B. Ravisankar CRCPress Taylor&FrancisGroup 52VanderbiltAvenue, NewYork,NY10017 ©2019byTaylor&FrancisGroup,LLC CRCPressisanimprintofTaylor&FrancisGroup,anInformabusiness NoclaimtooriginalU.S.Governmentworks Printedonacid-freepaper InternationalStandardBookNumber-13:978-1-138-38999-1(Hardback) Thisbookcontainsinformationobtainedfromauthenticandhighlyregardedsources. Reasonableeffortshavebeenmadetopublishreliabledataandinformation,buttheauthor andpublishercannotassumeresponsibilityforthevalidityofallmaterialsorthe consequencesoftheiruse.Theauthorsandpublishershaveattemptedtotracethecopyright holdersofallmaterialreproducedinthispublicationandapologizetocopyrightholdersif permissiontopublishinthisformhasnotbeenobtained.Ifanycopyrightmaterialhasnot beenacknowledgedpleasewriteandletusknowsowemayrectifyinanyfuturereprint. 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Title:Introductiontosteels:processing,properties,andapplications/P.C.Angeloand B.Ravisankar. Description:NewYork,NY:CRCPress/Taylor&FrancisGroup,2019.|Includes bibliographicalreferencesandindex. Identifiers:LCCN2018052858|ISBN9781138389991(hardback:acid-freepaper)|ISBN 9780429423598(ebook) Subjects:LCSH:Steel–Metallurgy. Classification:LCCTN730.A582019|DDC669/.142–dc23 LCrecordavailableathttps://lccn.loc.gov/2018052858 VisittheTaylor&FrancisWebsiteat http://www.taylorandfrancis.com andtheCRCPressWebsiteat http://www.crcpress.com Contents Preface ......................................................... ix AuthorBios..................................................... xi 1 Iron-CarbonDiagram......................................... 1 1.1 Iron-CarbonDiagram ...................................3 1.2 SlowCoolingofEutectoidComposition....................7 1.3 SlowCoolingofHypoeutectoidComposition...............8 1.4 SlowCoolingofHypereutectoidComposition ..............9 2 HeatTreatmentofSteels..................................... 11 2.1 Annealing............................................12 2.2 Normalizing..........................................13 2.3 Hardening............................................14 2.4 Hardenability.........................................18 2.5 Tempering............................................20 2.6 Martempering.........................................21 2.7 Austempering.........................................21 2.8 Ausforming...........................................22 2.9 Isoforming............................................23 2.10 PrecipitationHeatTreatment............................23 3 SurfaceHardening .......................................... 27 3.1 CaseHardening.......................................27 3.2 ChemicalSurfaceHardening............................28 4 PlainCarbonSteels.......................................... 31 4.1 LowCarbon(or)MildSteels ............................31 4.2 MediumCarbonSteels .................................32 4.3 HighCarbonSteels ....................................32 4.4 ApplicationsasEngineeringMaterial.....................33 5 EffectofAlloyingElementsinSteel........................... 35 5.1 EffectofAlloyingElementsonIronCarbonDiagram .......35 5.2 FerriteStabilizers......................................36 5.3 AusteniteStabilizers ...................................37 5.4 NeutralStabilizer......................................39 5.5 EffectofVariousElementsasDissolvedinFerrite Matrix ...............................................40 v vi Contents 5.6 EffectofVariousElementsasCarbidesinFerrite/ AusteniteMatrix ......................................40 5.7 SummaryofCarbides ..................................43 5.8 DispersedMetallicParticles.............................44 5.9 NonmetallicInclusions.................................45 5.10 IntermetallicCompounds...............................46 5.11 AlloyDistributioninAustenite ..........................46 5.12 EffectofAlloyingElementsonHardening.................46 5.13 EffectofAlloyingElementsonHardenability..............48 5.14 EffectofAlloyingElementsonTempering.................49 6 LowAlloySteels............................................ 51 6.1 PlainCarbonSteels(1XXXSeries)........................52 6.2 NickelSteels(2XXX) ...................................53 6.3 Nickel-ChromiumSteels(3XXX) .........................54 6.4 MolybdenumSteels(4XXX) .............................54 6.5 ChromiumSteels(5XXX) ...............................55 6.6 VanadiumSteels(6XXX)................................55 6.7 TungstenSteels(7XXX).................................55 6.8 TripleAlloySteels(8XXXand9XXX) .....................55 6.9 SiliconSteels..........................................56 6.10 BoronSteels ..........................................56 6.11 InterstitialFreeSteels ..................................57 6.12 ApplicationsasEngineeringMaterial.....................62 7 HighStrengthSteels......................................... 65 7.1 DefinitionandNeedofHighStrengthSteels...............65 7.2 TypesandProblemsinDevelopingHighStrength Steels ................................................67 7.3 MetallurgyofHighStrengthSteels.......................78 7.4 ApplicationsParticularlyforAutomotives.................80 8 HighAlloySteels ........................................... 83 8.1 MaragingSteels .......................................83 8.2 StainlessSteels ........................................92 8.3 ToolSteels...........................................116 9 SelectionofMaterials....................................... 125 9.1 ToolsUsedforSelectionofMaterials ....................125 9.2 SystemizedSelectionofMaterials.......................126 9.3 CaseStudies .........................................127 Contents vii SubjectiveQuestions ...........................................133 Objectivequestions.............................................139 Bibliography...................................................145 Index .........................................................149 This page intentionally left blank Preface Steel is adapting itself to emerging structural standards and conditions. From 1778, when the first iron bridge was built, to the present, steel is the mostcommonlyusedmaterialforvariousapplications.Steelisappropriate to most critical requirements by the addition of alloying elements and by suitable heat treatment. Steels are also most suitable for manufacturing by forming, welding, casting, and machining. There are several standard books that deal with the metallurgy of steel but they are meant for metallurgical engineers and are not suitable for engineers from other disciplines including mechanical, production, electrical, electronics, and aeronautical engineering students. It is to fulfill this requirement that Introduction to Steel: Processing, Properties, and Applications has been written. It will also be useful for practicing engineers. We also expect the book to satisfy the needs of students preparing for competitive exams. This book consistsof nine chapterscovering most of the important types of steels and their physical metallurgy, microstructure, and engineering applications. Chapter 1 introduces the iron-carbon diagram and discusses the importance and interpretation of it as well as the resultant microstruc- ture under equilibrium conditions with respect to carbon content. The effect of nonequilibrium cooling (heat treatment) on properties and meth- odology of heat treatment are discussed in Chapter 2. The most important surface hardening methods and methodology are described in Chapter 3. Chapter 4 deals with the various plain carbon steels and their heat treat- ment as well as important applications as engineering material. The effect of alloying elements on phase stability, microstructure, and properties are discussed in Chapter 5. The properties and applications of steel with low amounts of alloying elements are described in Chapter 6. High-strength steels are discussed in Chapter 7, in particular their applications for specialized uses in automobiles and aerospace. Chapter 8 covers high alloy steels – in particular maraging steels, stainless steels, and tool steels – describing their special uses in various applications. The basic techniques of the selection of material illustrated through case studies are included in Chapter 9. In addition, the book contains both subjective and objective questions as an aid to students preparing for semester-end and competitive exams. This book is based on our many years of teaching undergraduate and postgraduate students of various engineering disciplines. It is our fond hopethatthepresentbookwillserveasatextbookforcoursesinengineer- ing and also as a useful reference book for practicing engineers. We look forward to receiving your valuable response and suggestions. ix