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Introduction to Mineralogy and Petrology Introduction to Mineralogy and Petrology Second Edition S.K. Haldar The Mining Geological and Metallurgical Institutes (MGMI) Kolkata, West Bengal, India The Indian Geological Congress (IGC) Elsevier Radarweg29,POBox211,1000AEAmsterdam,Netherlands TheBoulevard,LangfordLane,Kidlington,OxfordOX51GB,UnitedKingdom 50HampshireStreet,5thFloor,Cambridge,MA02139,UnitedStates Copyright©2020ElsevierInc.Allrightsreserved. Nopartofthispublicationmaybereproducedortransmittedinanyformorbyanymeans,electronicormechanical,including photocopying,recording,oranyinformationstorageandretrievalsystem,withoutpermissioninwritingfromthepublisher. Detailsonhowtoseekpermission,furtherinformationaboutthePublisher’spermissionspoliciesandourarrangementswith organizationssuchastheCopyrightClearanceCenterandtheCopyrightLicensingAgency,canbefoundatourwebsite:www. elsevier.com/permissions. ThisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightbythePublisher(otherthanasmaybe notedherein). Notices Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchandexperiencebroadenourunderstanding, changesinresearchmethods,professionalpractices,ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusinganyinformation, methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodstheyshouldbemindfuloftheir ownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessionalresponsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,oreditors,assumeanyliabilityforanyinjury and/ordamagetopersonsorpropertyasamatterofproductsliability,negligenceorotherwise,orfromanyuseoroperationof anymethods,products,instructions,orideascontainedinthematerialherein. BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress ISBN:978-0-12-820585-3 ForInformationonallElsevierpublications visitourwebsiteathttps://www.elsevier.com/books-and-journals Publisher:CandiceJanco AcquisitionsEditor:AmyShapiro EditorialProjectManager:SaraPianavilla ProductionProjectManager:KiruthikaGovindaraju Designer:MarkRogers TypesetbyMPSLimited,Chennai,India Contents Abouttheauthor xi 2.5.1 NationalAeronauticsandSpace Preface xiii Administration,USA 89 Listofacronyms xv 2.5.2 RoscosmosStateCorporationfor SpaceActivities,Russiaand 1. Minerals and rocks 1 SovietSpaceProgram,USSR 89 2.5.3 EuropeanSpaceAgency,Europe 93 1.1 Introduction 1 2.5.4 IndianSpaceResearch 1.2 Importanceofminerals,rocks, Organisation,India 93 andsoilstosociety 1 2.5.5 ChinaNationalSpace 1.3 Minerals 6 Administration,China 94 1.3.1 Nonmetallicminerals 7 2.5.6 JapanAerospaceExploration 1.3.2 Metallicminerals 27 Agency,Japan 94 1.4 Rocks 44 2.5.7 IsraelSpaceAgency,Israel 95 1.5 Mineralresources 50 2.6 Statusofspaceexplorationand References 51 potentialforfuturemineral explorationinspace 95 2. Extraterrestrial systems 53 2.6.1 Mercury 95 2.6.2 Venus 95 2.1 Introduction 53 2.6.3 Earth 96 2.2 Definition 54 2.6.4 Mars 99 2.2.1 Universe 54 2.6.5 Jupiter 100 2.2.2 Galaxy 55 2.6.6 Saturn 101 2.2.3 Stars 55 2.6.7 Uranus 102 2.2.4 Planetsandplanetarysystems 56 2.6.8 Neptune 102 2.2.5 Satellites 56 2.7 Techniquesformineralexplorationin 2.2.6 Comets 56 space 102 2.2.7 Asteroids 57 2.7.1 Spaceexplorationsampling 102 2.2.8 Meteoritesandstardust 58 2.7.2 Spacesample-returnmission 105 2.3 TheSun 59 2.7.3 Spaceresources 105 2.3.1 SolarSystem 60 2.8 Spaceminingandprocessingof 2.3.2 OriginoftheSolarSystem 60 resources 106 2.4 Planetaryformation:physicaland 2.9 Sumup 106 chemicalaspects 61 References 107 2.4.1 Mercury 62 2.4.2 Venus 63 2.4.3 Earth 64 3. Basic mineralogy 109 2.4.4 Mars 72 2.4.5 Jupiter 75 3.1 Introduction 109 2.4.6 Saturn 78 3.2 Internalstructureofcrystalsandtheir 2.4.7 Uranus 82 properties 110 2.4.8 Neptune 85 3.2.1 Crystallizedandamorphoussolid 2.4.9 Dwarfplanet 87 minerals 110 2.5 Spaceexploration(programs 3.2.2 Formationofminerals 111 andagencies) 89 3.2.3 Crystallattice 111 vii viii Contents 3.2.4 Crystallographicaxes,thecrystal 5.3.1 Mineralcompositionofintrusive planes,andelementsofcrystal igneousrocks 169 symmetry 113 5.3.2 Extrusiveigneousrocks 180 3.2.5 Crystalsystems,crystalforms,single 5.3.3 Veinsigneousrocks 185 crystal,andcrystaltwinning 114 References 186 3.3 Chemicalandphysicalpropertiesof minerals 117 6. Sedimentary rocks 187 3.3.1 Chemicalpropertiesofminerals 117 6.1 Function,significance,classification, 3.3.2 Physicalpropertiesofminerals 117 andtransformation 187 3.4 Polymorphismandisomorphism 120 6.2 Sedimentaryrockformation 189 3.5 Overviewofthemainrock-forming 6.2.1 Weathering 189 minerals 121 6.2.2 Sedimenttransport 192 3.5.1 Autochthonouselements 122 6.2.3 Deposition 194 3.5.2 Sulfides 123 6.2.4 Lithification 196 3.5.3 Oxidesandhydroxides 123 6.3 Textureandstructureofsedimentary 3.5.4 Carbonates 125 rocks 196 3.5.5 Halides 126 6.3.1 Bedding 197 3.5.6 Sulfates 126 6.3.2 Packingofgrains 204 3.5.7 Phosphates 127 6.4 Classificationofsedimentsand 3.5.8 Silicates 127 sedimentaryrocks 206 6.5 Clasticsedimentsandsedimentaryrocks 206 References 143 6.5.1 Genesisandclassificationofclastic sedimentaryrocks 206 4. Basic petrology 145 6.5.2 Coarse-grained 4.1 Introduction 145 sediments—rudaceous 207 4.2 InteriorstructureoftheEarth 147 6.5.3 Mediumgranularclastic 4.3 Classificationofrocks 149 sediments—arenaceousrocks 214 4.3.1 Igneousrocks 150 6.5.4 Finegranularclastic 4.3.2 Sedimentaryrocks 150 sediments—pelite 219 4.3.3 Metamorphicrocks 151 6.5.5 Diagenesisofclasticsediments 227 4.4 OriginofEarthandtheoryofplate 6.6 Volcaniclasticrock 236 tectonics 152 6.6.1 Definitionandoriginof 4.4.1 OriginoftheEarth 152 volcaniclasticsedimentsandrocks 236 4.4.2 Platetectonics 154 6.6.2 Compositionofvolcaniclastic References 158 sedimentsandrocks 238 6.6.3 Alterationoftuff 239 5. Igneous rocks 159 6.7 Chemicalandbiochemicalsedimentary rocks 240 5.1 Originofigneousrocks 159 6.7.1 Limestone 240 5.1.1 Propertiesofmagmaandlava 160 6.7.2 Dolomites 257 5.1.2 Bowen’sreactionseries 161 6.7.3 Evaporites 260 5.1.3 Coolingofmagmaafter 6.7.4 Siliceoussedimentsandrocks 264 crystallization 162 6.8 Uses 268 5.2 Classificationofigneousrocks 163 References 268 5.2.1 Formsofappearanceandstructure oftheintrusive(plutonic)igneous 7. Metamorphic rocks 269 rocks 165 5.2.2 Formsofappearanceandstructure 7.1 Originandstructuresofmetamorphic oftheextrusive(volcanic)igneous rocks 269 rocks 167 7.2 Typesofmetamorphismand 5.3 Maingroupofigneousrocksandtheir classificationofmetamorphicrocks 275 composition 169 7.3 Rocksofdynamicmetamorphism 275 7.3.1 Mylonite 275 Contents ix 7.3.2 Flazercataclasite 276 9.3.2 Depthofoccurrence 321 7.3.3 Augengneisses 276 9.3.3 Relationtohostrock 323 7.4 Rocksofcontactmetamorphism 276 9.3.4 Structuralcontrol 325 7.4.1 Hornfels 278 9.3.5 Natureofmineralization 329 7.4.2 Skarnsortactites 278 9.3.6 Morphology 331 7.5 Rocksofregionalmetamorphism 279 9.3.7 Geneticmodel 334 7.5.1 Schistsoflow-grade 9.3.8 Grainsize 341 metamorphism 279 9.3.9 Containedmetal 342 7.5.2 Schistsofhigh-grade 9.3.10 Mono-mineraland metamorphism 282 multiple-mineraldeposits 344 7.6 Rocksofplutonicmetamorphism 288 9.4 Hostrocks 344 7.6.1 Granulites 288 9.5 Industryspecifications 345 7.6.2 Eclogites 288 References 348 7.6.3 Migmatites 289 References 289 10. Mineral resource assessment and economic parameters 349 8. Precipitation systems of major 10.1 Definition 349 sedimentary bodies—collector 10.2 Parameters 350 rocks for oil and gas 291 10.2.1 Cutoff 350 8.1 Introduction 291 10.2.2 Minimumwidth 351 8.2 Mainformsofcollectorsedimentary 10.2.3 Ore 351 bodiesinclastites 292 10.2.4 Oredeposit 351 8.2.1 Alluvialfans 292 10.3 Resourceestimationprocedure 352 8.2.2 Deltas 293 10.3.1 Smallandmediumsize 353 8.2.3 Sandbodiesincoastal 10.3.2 Largeanddeepseated 354 marineenvironments(beaches 10.3.3 Statisticalmethod 357 andoffshore) 295 10.3.4 Geostatisticalmethod 358 8.2.4 Debrites 299 10.3.5 Petroleum(oilandgas) 359 8.2.5 Turbidityfans 301 10.4 Resourceclassification 361 8.3 Mainformsofcollectorsedimentary 10.4.1 Metallic/nonmetallicminerals 361 bodiesincarbonaterocks 302 10.4.2 Mineraloilandgas 364 8.3.1 Carbonateplatforms 302 10.5 Mineraleconomics 365 8.3.2 Carbonatedebritesandturbidites 10.5.1 Stagesofinvestment 366 orallodapiclimestones 310 10.5.2 Investmentanalysis 366 8.3.3 Reefandperi-reefbioclastic 10.5.3 Orderofmagnitude limestonesoutsidethesarbonate study/scopingstudy 366 platforms 311 10.5.4 Prefeasibilitystudy 366 References 312 10.5.5 Feasibilitystudy 369 10.6 Overview—acompletecycle 369 9. Mineral deposits: host rocks and 10.6.1 Mineralexploration 369 genetic model 313 10.6.2 Mining 369 10.6.3 Mineralbeneficiation 370 9.1 Definition 313 10.6.4 Smelting 372 9.1.1 Mineral 313 10.6.5 Refining 372 9.1.2 Rock 314 10.6.6 Finisheduseablegoods 373 9.1.3 Mineraldeposit 314 References 376 9.2 Classificationofminerals 316 FurtherReading 376 9.2.1 Mineralclassificationsystem basedonchemicalcomposition 316 11. Hazards of minerals—rocks and 9.2.2 Mineralclassificationsystem sustainable development 377 basedonuses 317 9.3 Classificationofmineraldeposits 317 11.1 Definition 377 9.3.1 Geographicdistribution 317 11.2 Naturalhazards 378 x Contents 11.2.1 Earthquake 378 11.3.24 Wollastonite 387 11.2.2 Volcanoandvolcanism 379 11.4 Hazardsofrocks 387 11.2.3 Glacierandavalanche 381 11.4.1 Granite 387 11.2.4 Lightning 382 11.4.2 Limestone 387 11.2.5 Forestfire 382 11.4.3 Sandstone 387 11.3 Hazardsofminerals 383 11.4.4 Slate 387 11.3.1 Apatite 383 11.4.5 Rock-fall 387 11.3.2 Arsenic 383 11.4.6 Balancingrocks 388 11.3.3 Asbestos 383 11.4.7 Rockfault 388 11.3.4 Bauxite 384 11.5 Hazardsinthemineralindustry 390 11.3.5 Chalcopyrite 384 11.5.1 Exploration 390 11.3.6 Chromite 384 11.5.2 Mining 390 11.3.7 Cinnabar 384 11.5.3 Mineralbeneficiation 398 11.3.8 Clay 384 11.5.4 Smeltingwaste 399 11.3.9 Coalandlignite 384 11.5.5 Metalrefiningwaste 400 11.3.10 Corundum 385 11.5.6 Mineralindustryrehabilitation 400 11.3.11 Feldspar 385 11.6 Hazardsofthemineralindustryand 11.3.12 Fluorite 385 humanconsequences 402 11.3.13 Galenaandcerussite 385 11.6.1 Minewastecatastrophe 402 11.3.14 Graphite 385 11.6.2 Mineralprocessplant 11.3.15 Gypsum 385 failure 403 11.3.16 Hematite 385 11.7 Sustainablemineraldevelopment 403 11.3.17 Mica 386 11.7.1 Indicators 405 11.3.18 Pyrite 386 11.7.2 Mineralsandminingas 11.3.19 Redongas 386 meansofachieving 11.3.20 Silica 386 sustainabledevelopment 407 11.3.21 Sphalerite 386 References 410 11.3.22 Talc 386 11.3.23 Uraniumminerals 386 Index 411 Dedication Weapons cannot shred the soul, nor can fire burn it. Water cannot wet it, nor can the wind dry it. Bhagavat Gita 2.23 Dedicated in the memory of never-born, eternal, ever-abide, and primeval soul of my parents: Late Dr. Sachindra Nath Haldar (1897(cid:1)1951), and Late Smt. Durga Rani Haldar (1910(cid:1)1991), who inspired me to serve the creation of Nature (God) with all humility, and selflessly. About the author S. K. Haldar (Swapan Kumar Haldar) has been a practicing veteran in the field of Mineral Exploration and Metal Mining for the past four and a half decades. He received BSc (Hons) and MSc degrees from Calcutta University and PhD from the Indian Institute of Technology, Kharagpur. The major part of his career since 1966 has been focused on base and noble metals exploration/mining with short stopovers at Standard Oil (ESSO) Petroleum, Hindustan Copper Limited, and finally, HindustanZincLimited,wherehehasundertakenvarioustechnicalrolesandmana- gerial responsibilities. Since 2003, he has been Emeritus Professor with the Department of Applied Geology, Presidency University, Kolkata, and has taught mineral exploration to postgraduate students of the Applied Geology Department and often at the University of Calcutta and Indian Institute of Technology, Dhanbad. He has been a consultant with international exploration entities, namely, Goldstream Mining NL/IMX Resources Ltd., Australia, and Binani Industries Limited (BIL) Infratech Ltd., India. His profession has often required visits to mines and exploration camps of Australia(cid:1)Tasmania, Canada, the United States, Germany, Portugal, France, Italy,TheNetherlands,Switzerland,SaudiArabia,Egypt,Bangladesh,Nepal,Bhutan,Jordan,andIsrael. He is a life fellow of The Mining Geological and Metallurgical Institutes (MGMI) of India, and the Indian Geological Congress (IGC). He is the recipient of “Dr. J. Coggin Brown Memorial (Gold Medal) for Geological Sciences”byMGMI.Hehasauthored40technicalpapersandfivebooks: 1. ExplorationModelingofBaseMetalDeposits,2007,Elsevier,p.227. 2. MineralExploration—PrinciplesandApplications,FirstEdition,2013,Elsevier,p.374. 3. IntroductiontoMineralogyandPetrology,2014,Elsevier,p.356. 4. Platinum(cid:1)Nickel(cid:1)ChromiumDeposits:Geology,ExplorationandReserveBase,2016,Elsevier,p.322. 5. MineralExploration—PrinciplesandApplications,SecondEdition,2018,Elsevier,p.378. He has a unique professional blend of mineral exploration, evaluation, and mineral economics with the essence of classroomteachingofpostgraduatestudentsofthreecelebrateduniversitiesoverthepastdecades. xi

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