International Journal of Mass Spectrometry 2000: Vol 195-196 Index

11 Pages·2000·1.9 MB·English

International Journal of Mass Spectrometry 195/196 (2000) 699-700
Author index
Adams, N.G., 185 DePuy, C.H., 625 Knighton, W.B., 481, 517
Aeschleman, J.A., 215 Dotan, I., 327 Koster, G., 11
Amunugama, R., 439 Drader, J.J., 591 Koyanagi, G.K., 491
Anders, M.W., 203 Drewello, T., 599
Armentrout, P.B., 149 Dua, S., 45 Langer, J., 507
Arnold, S.T., 327 Laskin, J., 285
Asano, K.G., 419 El-Bahraoui, J., 351 Lavorato, D.J., 71
Aschi, M., | Ervin, K.M., 275 Lebrilla, C.B., 259
Attina, M., | Leopold, D.G., 653
Audier, H.E., 385 Feichtinger, D., 351 Lifshitz, C., 11
Fell, L.M., 71, 85
Luna, A., 545
Babcock, L.M., 185 Feng, W.Y., 251 Luu, N.C., 203
Bache-Andreassen, L., 171 Filippi, A., 21
Barlow, S.E., 625 Fisher, J.J., 491 Margalo, J., 139
Barrow, M.P., 599 Flammang, R., 225, 239 Marchandé, N., 139
Bartmess, J.E., 215 Foley, W.M., 517 Marcy, T.P., 653
Baschky, M.C., 411 Freitas, M.A., 591 Marshall, A.G., 591
Bierbaum, V.M., 625 Futrell, J., 285 McGibbon, G.A., 71
Blanksby, S.J., 45 McLuckey, S.A., 419
Gerbaux, P., 239
Bohme, D.K., 393, 401 McMahon, T.B., 491
Géribaldi, S., 139
Bouchoux, G., 225, 239 McSweeney, S.A., 517
Gevrey, S., 545
Bowers, M.T., 685 Midey, A.J., 327
Gill, A.C., 685
Bowie, J.H., 45 Milburn, R.K., 393
Grandinetti, F., 21
Breton, S., 139 Miller, A.E.S., 341
Grimsrud, E.P., 481
Briining, F., 507 Miller, T.M., 341, 517
Gronert, S., 251, 303
Burgers, P.C., 85 Moder, M., 599
Griitzmacher, H.-F., 533
Byrd, M., 285 Morgon, N.H., 363
Hammerum, S., 459 Morizur, J.-P., 545
Cacace, F., | Hargus, M.D., 517 Morris, R.A., 327, 341, 517
Cancilia, M.T., 259 Harrison, A.G., 33 Mourgues, P., 385
Cao, J., 525
Haynes, C.L., 149
Carretas, J.M., 139 Nibbering, N.M.M., 115
Hendrickson, C.L., 591
Cartoni, A., 1 Nikolaev, E.N., 467
Henriksen, J., 459
Chamot-Rooke, J., 385 Nixdorf, A., 533
Henriksen, T., 459
Chen, P., 377 Niichter, M., 599
Hinderling, C., 377
Chen, Y.-M., 149
Holmes, J.L., 525
Chew, F., 251 Occhiucci, G., 21
Hopkinson, A.C., 393
Choret, N., 225 O’ Hair, R.A.J., 303
Hoppilliard, Y., 565
Cooks, R.G., 667 Ohanessian, G., 565
Czira, G., 599 IHenberger, E., 507 Ondruschka, B., 599
Iyer, R.A., 203
Dang, T.T., 625 Paulson, J.F., 341
Daoust-Maleval, I., 121 Jennings, K.R., 685 Penn, S.G., 259
de Koning, L.J., 115 Pepi, F., |
de Matos, A.P., 139 Kass, S.R., 411 Pittman, J.L., 215
Deakyne, C.A., 215 Kato, S., 625 Plattner, D.A., 351
Dearden, D.V., 639 Kenttéimaa, H.I., 609 PolaSek, M., 101
Decker, B.K., 185 Kerr, D.M., 517 Pope, R.M., 639
700 Author index
Reichert, E.L., 55 Speranza, M., 21 Van Doren, J.M., 517
Ridge, D.P., 203 Steiner, V., 121 Vékey, K., 599
Riveros, J.M., 363 Stephenson, J.L., Jr., 419 Viggiano, A.A., 327, 341, 517
Rodgers, M.T., 439 Stumpf, C.L., 609
Rogalewicz, F., 565 Sun, J., 401 We, W., 251
Ruttink, P.J.A., 85 Weisshaar, J.C., 55
Tabet, J.-C., 121 Wenthold, P.G., 319
Taphanel, M.-H., 545 Wiest, O., 351
Sadilek, M., 101
Tegeder, P., 507 Williams, S., 327
Salpin, J.-Y., 239
Terlouw, J.K., 71, 85 Williamson, D.H., 481
Schaaff, T.G., 419
Tortajada, J., 545 Wysocki, V.H., 467
Schwarz, H., 71
Trikoupis, M.A., 85 Wyttenbach, T., 685
Sen, S., 71
Tsaprailis, G., 467
Shen, N., 639
Ta ¥=P., 33 Xavier, L.A., 363
Shi, S.D.-H., 591
Tureéek, F., 101
Sievers, M.R., 149 Yi, S.S., 55
Sinnige, C.G., 115 Uggerud, E., 171 Yu, Y.-Q., 609
Sglling, T.I., 459
Somogyi, A., 467 van der Rest, G., 385 Zhang, D., 667
International Journal of Mass Spectrometry 195/196 (2000) 701-710
Subject index
Ab initio calculations Alkene radical cations
Ab initio insights into amide bond cleavage reactions of Reaction of radical cations of 1,1-dihaloethenes with
formamide with substituted methyl cations XCH > ammonia: substitution and base catalyzed tautomerization
(X = OH, F, and Cl), 303 in sequence, 533
Dissociation chemistry of the hydrogen-bridged radical Alkoxide reactions
cation [CH,=O - ++ H + + » O=C-OCH,]™: proton Fourier-transform ion cyclotron resonance mass spec-
transport catalysis and charge transfer, 85 trometric studies of elimination reactions of anionic
Fragmentation mechanisms of a-amino acids protonated bases with metabolites of a fluorinated anesthetic
under electrospray ionization: a collisional activation and agent: towards modeling bioactivation in the gas phase,
ab initio theoretical study, 565 203
A mass spectrometric and computational study of gaseous Amide bond cleavage
peroxynitric acid and (HOONO,)H™~ protomers, 1 Ab initio insights into amide bond cleavage reactions of
Mechanisms of reactions between ammonia and methyl- formamide with substituted methyl cations XCH;
ene Oxonium ions: immonium ion formation versus trans- (X = OH, F, and Cl), 303
fer of the oxygen substituent, 171 Amines
Methyl] loss from conventional and distonic isomers of The proton affinities of amin-alkanes. A test case for the
C,H,N'*', 459 kinetic method, 525
Acetophenone radical cation Amino acids
Two different pathways for unimolecular and for cata- Fragmentation mechanisms of a-amino acids protonated
lyzed keto-enol isomerization of ionized acetophenone, under electrospray ionization: a collisional activation and
385 ab initio theoretical study, 565
Acidity Anionic ion-molecule reactions
The gas phase acid/base properties of |,3-dimethyluracil, Fourier-transform ion cyclotron resonance mass spectro-
1-methyl-2-pyridone, and 1-methyl-4-pyridone: rele- metric studies of elimination reactions of anionic bases
vance to the mechanism of orotidine-5'-monophosphate with metabolites of a fluorinated anesthetic agent: to-
decarboxylase, 251 wards modeling bioactivation in the gas phase, 203
The temperature dependence of absolute gas phase acid- Anions and neutrals
ities, 215 Conversion of neutral C,COC, to C,CO. Potential inter-
Addition-elimination stellar molecules, 45
Formation and structural discrimination of stable halo- Arginine
phenylium ions in the gas phase, 21 Refining the model for selective cleavage at acidic resi-
Mechanisms of reactions between ammonia and methyl- dues in arginine-containing protonated peptides, 467
ene oxonium ions: immonium ion formation versus trans- Arylium ions
fer of the oxygen substituent, 171 Formation and structural discrimination of stable halo-
Alkali metal ions phenylium ions in the gas phase, 21
Absolute alkali metal ion binding affinities of several Aspartic acid
azines determined by threshold collision-induced dissoci- Refining the model for selective cleavage at acidic resi-
ation and ab initio theory, 439 dues in arginine-containing protonated peptides, 467
Alkaline earth Azines
Fundamental factors controlling the exchange of multi- Absolute alkali metal ion binding affinities of several
dentate ligands: displacement of 12-crown-4 and triglyme azines determined by threshold collision-induced dissoci-
from complexes with divalent alkaline earth cations, 639 ation and ab initio theory, 439
702 Subject index
Azulene Coalescence
Effect of buffer gas alterations on the thermal electron Unimolecular ion dissociation and laser-induced coales-
attachment and detachment reactions of azulene by pulsed cence of hydrogenated fullerenes, 599
high pressure mass spectrometry, 481 Collision activation
Thiosulfoxides (X,S=S) and disulfanes (XSSX): first
observation of organic thiosulfoxides, 239
Binding affinities
Collisional mass spectrometry
Absolute alkali metal ion binding affinities of several
Dehydration of ionized propanol in the gas phase, 225
azines determined by threshold collision-induced dissoci-
Collision cross sections
ation and ab initio theory, 439
Conformations of biopolymers in the gas phase: a new
Biopolymers
mass spectrometric method, 685
Conformations of biopolymers in the gas phase: a new
Collision-induced dissociation (CID)
mass spectrometric method, 685
Absolute alkali metal ion binding affinities of several
Bond activation
azines determined by threshold collision-induced dissoci-
Activation of CH,, C,H,, and C,H, by gas-phase Nb°*
ation and ab initio theory, 439
and the thermochemistry of Nb-ligand complexes, 149
An electrospray ionization flow tube study of the proto-
Bond dissociation energy
nated betaine/ammonia complex, 11
Activation of CH,, C,H,, and C,H, by gas-phase Nb~
Refining the model for selective cleavage at acidic resi-
and the thermochemistry of Nb-ligand complexes, 149
dues in arginine-containing protonated peptides, 467
The temperature dependence of absolute gas phase acid-
Combinational screening
ities, 215
Mass spectrometric assay of polymerization catalysts for
Bromobenzene
combinational screening, 377
Internal energy distributions resulting from sustained
Combustion
off-resonance excitation in FTMS. I. Fragmentation of the
Rate constants and branching ratios for the reactions of
bromobenzene radical cation, 285
various positive ions with naphthalene from 300 to 1400
S27
Catalyzed H-transport Computational Ge chemistry
Two different pathways for unimolecular and for cata- Gas-phase nucleophilic reactions of Ge(OCH,),: experi-
lyzed keto-enol isomerization of ionized acetophenone, mental and computational characterization of pentacoor-
385 dinated Ge anions, 363
CBS-RAD Conformation
Methyl loss from conventional and distonic isomers of Refining the model for selective cleavage at acidic resi-
C,H,N’*', 459 dues in arginine-containing protonated peptides, 467
C,H; Crossed-beam technique
The C,H; potential energy surface: a Fourier transform Bimolecular ion-molecule collisions in real time:
ion cyclotron resonance investigation of the reaction of Co*(*F,) + n-butane and isobutane reactions, 55
methyl cation with methane, 491 Crown ether
CooH x, Fundamental factors controlling the exchange of multi-
Unimolecular ion dissociation and laser-induced coales- dentate ligands: displacement of 12-crown-4 and triglyme
cence of hydrogenated fullerenes, 599 from complexes with divalent alkaline earth cations, 639
Chemical ionization of alkylanilines Cysteine S conjugates
Site of protonation of N-alkylanilines, 33 Fourier-transform ion cyclotron resonance mass spectro-
[C,H,.}" metric studies of elimination reactions of anionic bases
Dehydration of ionized propanol in the gas phase, 225 with metabolites of a fluorinated anesthetic agent: to-
CIPCI" wards modeling bioactivation in the gas phase, 203
Gas-phase framentation of di- and tripeptides via ion-
molecule reactions with CIPCI” , 609 Decarbonylation
Clusters Dissociation chemistry of the hydrogen-bridged radical
Doubly charged cluster ions [(NaCl) »(Na),]°*: magic cation [CH,=O - - - H + + - O=C—-OCH,]"*: proton
numbers, dissociation, and structure, 667 transport catalysis and charge transfer, 85
CN substituents Identifying ylide ions and methyl migrations in the gas
Small-ring carbenes carrying a positive charge: the effects phase: the decarbonylation reactions of simple ionized
of substituting by CN in c-C,H; , 393 N-heterocycles, 71
Subject index
Dehydration mechanism Double-well potential model
Dehydration of ionized propanol in the gas phase, 225 Gas-phase association reactions of hydroxide, methoxide,
Density functional calculations ethoxide, and their deuterated analogs, 625
Identifying ylide ions and methyl migrations in the gas Doubly charged clusters
phase: the decarbonylation reactions of simple ionized Doubly charged cluster ions [(NaCl),,(Na),]?*: magic
N-heterocycles, 71 numbers, dissociation, and structure, 667
Density functional theory
A computational study of the hydride affinities of Group
I and Group II metals, 319 Electron attachment
Derivatised C, cations Competition between nondissociative and dissociative
Small-ring carbenes carrying a positive charge: the effects electron attachment to halogenated cyclic alkenes in the
of substituting by CN in c-C,H; , 393 gas phase, 517
Desorption Effect of buffer gas alterations on the thermal electron
Low energy (0—14 eV) electron impact to CHF,Cl at attachment and detachment reactions of azulene by pulsed
different phase conditions: medium enhanced desorption high pressure mass spectrometry, 481
of anions, 507 Electron affinity
Deuterium isotope effects The temperature dependence of absolute gas phase acid-
Gas-phase association reactions of hydroxide, methoxide, ities, 215
ethoxide, and their deuterated analogs, 625 Electron capture
DFT calculations Effect of buffer gas alterations on the thermal electron
A mass spectrometric and computational study of gaseous attachment and detachment reactions of azulene by pulsed
peroxynitric acid and (HOONO,)H™ protomers, | high pressure mass spectrometry, 481
Experimental and theoretical studies of the gas-phase Electron transfer
Gas-phase reactions of fullerene cations CZ, (x = 1-3)
reactivity of the (HO),P=O° phosphonium ions towards
with pyrrolidine and piperidine: sequential reactions with
methanol, 545
Ceo, 401
,2-Dichlorohexafluoropentene
Electrospray ionization (ESI)
Competition between nondissociative and dissociative
An electrospray ionization flow tube study of the proto-
electron attachment to halogenated cyclic alkenes in the
nated betaine/ammonia complex, ||
gas phase, 517
Coordination chemistry of manganese-salen complexes
,2-Dichlorooctafluorocyclohexene
studied by electrospray tandem mass spectrometry: the
Competition between nondissociative and dissociative
significance of axial ligands, 351
electron attachment to halogenated cyclic alkenes in the
Doubly charged cluster ions [(NaCl),,(Na),]°*: magic
gas phase, 517
numbers, dissociation, and structure, 667
Diethyl! ether
Fragmentation mechanisms of a-amino acids protonated
Temperature and pressure effects on the elimination
under electrospray ionization: a collisional activation and
reactions of diethyl ether with hydroxide and amide ions,
ab initio theoretical study, 565
411
Elimination reactions
Dimethyloxalate Fourier-transform ion cyclotron resonance mass spectro-
Dissociation chemistry of the hydrogen-bridged radical metric studies of elimination reactions of anionic bases
cation [CH,=O «+ - H «+ - O=C-OCH,]™: proton with metabolites of a fluorinated anesthetic agent: to-
transport catalysis and charge transfer, 85 wards modeling bioactivation in the gas phase, 203
Dipeptide Temperature and pressure effects on the elimination
Gas-phase framentation of di- and tripeptides via ion- reactions of diethyl ether with hydroxide and amide ions,
molecule reactions with CIPCI” , 609 411
Dissociative attachment Energy deposition function
Low energy (0—14 eV) electron impact to CHF,Cl at Internal energy distributions resulting from sustained
different phase conditions: medium enhanced desorption off-resonance excitation in FTMS. I. Fragmentation of the
of anions, 507 bromobenzene radical cation, 285
Disulfane Enhanced cleavages
Thiosulfoxides (X,S=S) and disulfanes (XSSX): first Refining the model for selective cleavage at acidic resi-
observation of organic thiosulfoxides, 239 dues in arginine-containing protonated peptides, 467
704 Subject index
Epoxidation catalysts Fragmentation
Coordination chemistry of manganese-salen complexes Fragmentation mechanisms of a-amino acids protonated
studied by electrospray tandem mass spectrometry: the under electrospray ionization: a collisional activation and
significance of axial ligands, 351 ab initio theoretical study, 565
Gas-phase framentation of di- and tripeptides via ion-
Flowing afterglow molecule reactions with CIPCI™, 609
Temperature and pressure effects on the elimination Refining the model for selective cleavage at acidic resi-
reactions of diethyl ether with hydroxide and amide ions, dues in arginine-containing protonated peptides, 467
411 Fullerene ions
Flowing afterglow Langmuir probe Gas-phase reactions of fullerene cations Cé, (x = 1-3)
Competition between nondissociative and dissociative with pyrrolidine and piperidine: sequential reactions with
electron attachment to halogenated cyclic alkenes in the Céo, 401
gas phase, 517
Flow tube Gas-phase
An electrospray ionization flow tube study of the proto- Conformations of biopolymers in the gas phase: a new
nated betaine/ammonia complex, 11 mass spectrometric method, 685
Fluoride affinity Gas-phase framentation of di- and tripeptides via ion-
Gas-phase nucleophilic reactions of Ge(OCH;),: experi- molecule reactions with CIPCI~, 609
mental and computational characterization of pentacoor- Gas phase reactivity of rare earth metal cations with
dinated Ge anions, 363 trialkylorthoformates: synthesis of neutral rare earth
Formamide alkoxides, 139
Ab initio insights into amide bond cleavage reactions of Gas-phase chemistry
formamide with substituted methyl cations XCH; Formation and structural discrimination of stable halo-
(X = OH, F, and Cl), 303 phenylium ions in the gas phase, 21
Fourier transform ion cyclotron resonance (FTICR) A mass spectrometric and computational study of gaseous
The C,H; potential energy surface: a Fourier transform peroxynitric acid and (HOONO,)H™ protomers, 1
ion cyclotron resonance investigation of the reaction of Gas-phase enthalpy
methyl cation with methane, 491 The temperature dependence of absolute gas phase acid-
Fundamental factors controlling the exchange of multi- ities, 215
dentate ligands: displacement of 12-crown-4 and triglyme Gas-phase ion chemistry
from complexes with divalent alkaline earth cations, 639 Bimolecular ion-molecule collisions in real time:
Gas-phase fragmentation of di- and tripeptides via ion— Co*(?F,) + n-butane and isobutane reactions, 55
molecule reactions with CIPCI” , 609 Gas phase isomerization
Mechanisms of reactions between ammonia and methyl- Two different pathways for unimolecular and for cata-
ene Oxonium ions: immonium ion formation versus trans- lyzed keto-enol isomerization of ionized acetophenone, 385
fer of the oxygen substituent, 171 Gas-phase nucleophilic reactions
Reaction of radical cations of 1,1-dihaloethenes with Gas-phase nucleophilic reactions of Ge(OCH;),: experi-
ammonia: substitution and base catalyzed tautomerization mental and computational characterization of pentacoor-
in sequence, 533 dinated Ge anions, 363
Water molecule assisted proton mobility in gaseous pro- Germanium methoxide
tonated GlyPro and ProGly, 115 Gas-phase nucleophilic reactions of Ge(OCH,),: experi-
Fourier transform ion cyclotron resonance mass spectro- mental and computational characterization of pentacoor-
metry (FTICR/MS) dinated Ge anions, 363
Comparison and interconversion of the two most common Germy] anions
frequency-to-mass calibration functions for Fourier trans- Gas-phase nucleophilic reactions of Ge(OCH;),: experi-
form ion cyclotron resonance mass spectrometry, 591 mental and computational characterization of pentacoor-
Fourier-transform ion cyclotron resonance mass spectro- dinated Ge anions, 363
metric studies of elimination reactions of anionic bases GlyPro
with metabolites of a fluorinated anesthetic agent: to- Water molecule assisted proton mobility in gaseous pro-
wards modeling bioactivation in the gas phase, 203 tonated GlyPro and ProGly, 115
Gas phase reactivity of rare earth metal cations with G2(MP2)
trialkylorthoformates: synthesis of neutral rare earth Methyl loss from conventional and distonic isomers of
alkoxides, 139 C,H,N~*', 459
Subject index
G2(MP2,SVP) calculations Interstellar chemistry
Dehydration of ionized propanol in the gas phase, 225 Gas-phase reactivity of SO™: a selected ion flow tube
Guided ion beams study, 185
Absolute alkali metal ion binding affinities of several Jon-association reactions
azines determined by threshold collision-induced dissoci- Gas-phase association reactions of hydroxide, methoxide,
ation and ab initio theory, 439 ethoxide, and their deuterated analogs, 625
Ion chemistry
Rate constants and branching ratios for the reactions of
H/D exchange various positive ions with naphthalene from 300 to 1400
An electrospray ionization flow tube study of the proto- K, 327
nated betaine/ammonia complex, 11 Ion cyclotron resonance
Water molecule assisted proton mobility in gaseous pro- Comparison and interconversion of the two most common
tonated GlyPro and ProGly, 115 frequency-to-mass calibration functions for Fourier trans-
Heats of formation form ion cyclotron resonance mass spectrometry, 591
Methyl! loss from conventional and distonic isomers of Ion/ion proton transfer
C;,H,N*', 459 Ion trap collisional activation of protonated poly(pro-
High temperature pylene imine) dendrimers: generations 1-5, 419
Rate constants and branching ratios for the reactions of Ion-molecule reaction
various positive ions with naphthalene from 300 to 1400 Bimolecular ion-molecule collisions in real time:
K, 327 Co* CF 4) + n-butane and isobutane reactions, 55
Homoaromaticity Dehydration of ionized propanol in the gas phase, 225
Small-ring carbenes carrying a positive charge: the effects Experimental and theoretical studies of the gas-phase
of substituting by CN in c-C,H; , 393 reactivity of the (HO),P=O~ phosphonium ions towards
HOSO radical methanol, 545
Gas-phase reactivity of SO”: a selected ion flow tube Formation and structural discrimination of stable halo-
study, 185 phenylium ions in the gas phase, 21
HSO radical Gas-phase framentation of di- and tripeptides via ion-
Gas-phase reactivity of SO™’: a selected ion flow tube molecule reactions with CIPCI” ,6 09
study, 185 Gas-phase reactivity of SO: a selected ion flow tube
Hydride affinities study, 185
A computational study of the hydride affinities of Group Mechanisms of reactions between ammonia and methyl-
I and Group II metals, 319 ene oxonium ions: immonium ion formation versus trans-
Hydride ion transfer fer of the oxygen substituent, 171
Gas-phase reactivity of SO™’: a selected ion flow tube Rate constants and branching ratios for the reactions of
study, 185 various positive ions with naphthalene from 300 to 1400
Hydride reductions K, 327
A computational study of the hydride affinities of Group Reaction of radical cations of 1,1-dihaloethenes with
I and Group II metals, 319 ammonia: substitution and base catalyzed tautomerization
Hydrogenated fullerenes in sequence, 533
Unimolecular ion dissociation and laser-induced coales- Study of gas-phase reactivity of positive and negative
cence of hydrogenated fullerenes, 599 even-electron ions prepared from diethylmethylphospho-
Hydroxide and alkoxide nate ester in an external chemical ionization source of
Gas-phase association reactions of hydroxide, methoxide, orthogonal tandem quadrupole/ion trap instrument, 121
ethoxide, and their deuterated analogs, 625 Thiosulfoxides (X,S=S) and disulfanes (XSSX): first
Hydroxide ion transfer observation of organic thiosulfoxides, 239
Gas-phase reactivity of SO~’: a selected ion flow tube Water molecule assisted proton mobility in gaseous pro-
study, 185 tonated GlyPro and ProGly, 115
Ion-neutral complexes
Dissociation chemistry of the hydrogen-bridged radical
Imines cation [CH,=O - + - H - - » O=C-OCH,]™: proton
Mechanisms of reactions between ammonia and methyl- transport catalysis and charge transfer, 85
ene Oxonium ions: immonium ion formation versus trans- A mass spectrometric and computational study of gaseous
fer of the oxygen substituent, 171 peroxynitric acid and (HOONO,)H™ protomers, 1
706 Subject index
Ion trap collisional activation Low energy CID
Ion trap collisional activation of protonated poly(pro- Site of protonation of N-alkylanilines, 33
pylene imine) dendrimers: generations 1-5, 419
Ion trap mass spectrometer
Study of gas-phase reactivity of positive and negative Magic numbers
even-electron ions prepared from diethylmethylphospho-
Doubly charged cluster ions [(NaCl),,(Na),]°*: magic
nate ester in an external chemical ionization source of
numbers, dissociation, and structure, 667
orthogonal tandem quadrupole/ion trap instrument, 121
Mass spectrometric assay
Iron carbony!
Mass spectrometric assay of polymerization catalysts for
Methyl bonding to Fe and Fe(CO),,: reactions of Fe and
combinational screening, 377
Fe(CO),, with methyl halides, 341
Mass spectrometry
Iron-methyl bond energies
Conformations of biopolymers in the gas phase: a new
Methyl bonding to Fe and Fe(CO),,: reactions of Fe and
mass spectrometric method, 685
Fe(CO),, with methyl halides, 341
A mass spectrometric and computational study of gaseous
Isomers at C5O
peroxynitric acid and (HOONO,)H™ protomers, 1
Conversion of neutral C,COC, to C,CO. Potential inter-
Metal cluster
stellar molecules, 45
A vibrationally resolved negative ion photoelectron spec-
Isonitrosomethane
trum of Nbx, 653
High-energy [C,H,,N,O] cation radicals and molecules,
Metal ions
101
A computational study of the hydride affinities of Group
Isotope effects
I and Group II metals, 319
Temperature and pressure effects on the elimination
A vibrationally resolved negative ion photoelectron spec-
reactions of diethyl! ether with hydroxide and amide ions,
trum of Nb,, 653
411
Metals
Fragmentation behavior of multiple-metal-coordinated
Keto-enol tautomerism acidic oligosaccharides studied by matrix-assisted laser
Two different pathways for unimolecular and for cata- desorption ionization Fourier transform mass spectrome-
lyzed keto-enol isomerization of ionized acetophenone, try, 259
385 Metastable ions
Kinetic method Methyl loss from conventional and distonic isomers of
Microcanonical analysis of the kinetic method. The mean- C,H,N*', 459
ing of the ‘‘effective temperature,’ 271 Methylation of methane
The proton affinities of amin-alkanes. A test case for the The C,H; potential energy surface: a Fourier transform
kinetic method, 525 ion cyclotron resonance investigation of the reaction of
Kinetics methyl cation with methane, 491
Competition between nondissociative and dissociative Methyl halides
electron attachment to halogenated cyclic alkenes in the
Formation and structural discrimination of stable halo-
gas phase, 517
phenylium ions in the gas phase, 21
Rate constants and branching ratios for the reactions of
Microcanonical kinetic rate theory
various positive ions with naphthalene from 300 to 1400
Microcanonical analysis of the kinetic method. The mean-
K, 327
ing of the ‘‘effective temperature,’’ 271
Temperature and pressure effects on the elimination
Molecular dynamics
reactions of diethyl ether with hydroxide and amide ions,
Fundamental factors controlling the exchange of multi-
411
dentate ligands: displacement of 12-crown-4 and triglyme
from complexes with divalent alkaline earth cations, 639
Laser desorption/ionization MS/MS
Unimolecular ion dissociation and laser-induced coales- Doubly charged cluster ions [(NaCl),,(Na),]°*: magic
cence of hydrogenated fullerenes, 599 numbers, dissociation, and structure, 667
Ligand exchange Multiple collisions
Fundamental factors controlling the exchange of multi- Internal energy distributions resulting from sustained
dentate ligands: displacement of 12-crown-4 and triglyme off-resonance excitation in FTMS. I. Fragmentation of the
from complexes with divalent alkaline earth cations, 639 bromobenzene radical cation, 285
Subject index
N-alkylanilines Penning trap
Site of protonation of N-alkylanilines, 33 Comparison and interconversion of the two most common
Naphthalene frequency-to-mass calibration functions for Fourier trans-
Rate constants and branching ratios for the reactions of form ion cyclotron resonance mass spectrometry, 591
various positive ions with naphthalene from 300 to 1400 Pentacoordinated Ge anions
E32) Gas-phase nucleophilic reactions of Ge(OCH,),: experi-
Negative ion-molecule reactions mental and computational characterization of pentacoor-
Methyl bonding to Fe and Fe(CO),,: reactions of Fe and dinated Ge anions, 363
Fe(CO),, with methyl halides, 341 Peptides
Negative ions Gas-phase fragmentation of di- and tripeptides via ion—
Low energy (0-14 eV) electron impact to CHF,Cl at molecule reactions with CIPCI” , 609
different phase conditions: medium enhanced desorption Refining the model for selective cleavage at acidic resi-
of anions, 507 dues in arginine-containing protonated peptides, 467
Neutralization reionization Peroxides
High-energy [C,H,,N,O] cation radicals and molecules, A mass spectrometric and computational study of gaseous
101 peroxynitric acid and (HOONO,)H~ protomers, |
Identifying ylide ions and methyl migrations in the gas Phosphenium ions
phase: the decarbonylation reactions of simple ionized Gas-phase fragmentation of di- and tripeptides via ion—
N-heterocycles, 71 molecule reactions with CIPCI” , 609
Phosphorus ions
Thiosulfoxides (X,S=S) and disulfanes (XSSX): first
observation of organic thiosulfoxides, 239 Experimental and theoretical studies of the gas-phase
reactivity of the (HO),P=O° phosphonium ions towards
Niobium
methanol, 545
Activation of CH,, C,H,, and C,H, by gas-phase Nb*
Photoelectron spectroscopy
and the thermochemistry of Nb-ligand complexes, 149
A vibrationally resolved negative ion photoelectron spec-
Niobium clusters
trum of Nb,, 653
A vibrationally resolved negative ion photoelectron spec-
Piperidine
trum of Nb,, 653
Gas-phase reactions of fullerene cations Ci, (x = 1-3)
Nitrosomethane
with pyrrolidine and piperidine: sequential reactions with
High-energy [C,H,,N,O] cation radicals and molecules,
Ceo, 401
101
Polymerization catalysts
Nucleophilic addition
Mass spectrometric assay of polymerization catalysts for
Gas-phase reactions of fullerene cations Cf, (x = 1-3)
combinational screening, 377
with pyrrolidine and piperidine: sequential reactions with
Poly(propylene imine) dendrimer
Coo, 401
Ion trap collisional activation of protonated poly(pro-
Nucleophilic substitution
pylene imine) dendrimers: generations 1-5, 419
Mechanisms of reactions between ammonia and methyl-
ProGly
ene Oxonium ions: immonium ion formation versus trans-
Water molecule assisted proton mobility in gaseous pro-
fer of the oxygen substituent, 171
tonated GlyPro and ProGly, 115
Reaction of radical cations of 1,1-dihaloethenes with
Propanol *
ammonia: substitution and base catalyzed tautomerization
Dehydration of ionized propanol in the gas phase, 225
in sequence, 533
Proton affinity (PA)
The gas phase acid/base properties of 1,3-dimethyluracil,
1-methyl-2-pyridone, and 1-methyl-4-pyridone: _ rele-
Oligosaccharide vance to the mechanism of orotidine-5’-monophosphate
Fragmentation behavior of multiple-metal-coordinated decarboxylase, 251
acidic oligosaccharides studied by matrix-assisted laser Experimental and theoretical studies of the gas-phase
desorption ionization Fourier transform mass spectrome- reactivity of the (HO),P=O~ phosphonium ions towards
try, 259 methanol, 545
Oxonium ions The proton affinities of amin-alkanes. A test case for the
Mechanisms of reactions between ammonia and methyl- kinetic method, 525
ene oxonium ions: immonium ion formation versus trans- Protonation site
fer of the oxygen substituent, 171 Site of protonation of N-alkylanilines, 33
708 Subject index
Proton-bound dimers desorption ionization Fourier transform mass spectrome-
Microcanonical analysis of the kinetic method. The mean- try, 259
ing of the ‘‘effective temperature,’ 271 Singlet/triplet splitting
Pyridone Small-ring carbenes carrying a positive charge: the effects
The gas phase acid/base properties of 1,3-dimethyluracil, of substituting by CN in c-C,H;, 393
1-methyl-2-pyridone, and 1-methyl-4-pyridone: _rele- Sodium chloride
vance to the mechanism of orotidine-5’-monophosphate Doubly charged cluster ions [(NaCl),,(Na),]?*: magic
decarboxylase, 251 numbers, dissociation, and structure, 667
Pyrrolidine SO* ion
Gas-phase reactions of fullerene cations Ci (x = 1-3) Gas-phase reactivity of SO™’: a selected ion flow tube
with pyrrolidine and piperidine: sequential reactions with study, 185
Co, 401 Substituted methyl cations
Ab initio insights into amide bond cleavage reactions of
Quadrupole ion trap formamide with substituted methyl cations XCH>
(X = OH, F, and Cl), 303
Ion trap collisional activation of protonated poly(pro-
pylene imine) dendrimers: generations 1-5, 419 Surface-induced dissociation (SID)
Refining the model for selective cleavage at acidic resi-
dues in arginine-containing protonated peptides, 467
Rare earth alkoxides Sustained off-resonance irradiation-collision-induced disso-
Gas phase reactivity of rare earth metal cations with
ciation (SORI-CID)
trialkylorthoformates: synthesis of neutral rare earth
Internal energy distributions resulting from sustained
alkoxides, 139
off-resonance excitation in FTMS. I. Fragmentation of the
Rare earth metal ions bromobenzene radical cation, 285
Gas phase reactivity of rare earth metal cations with
trialkylorthoformates: synthesis of neutral rare earth
alkoxides, 139
Tandem mass spectrometry
Rate constants
Doubly charged cluster ions [(NaCl),,(Na),]°~: magic
Rate constants and branching ratios for the reactions of
numbers, dissociation, and structure, 667
various positive ions with naphthalene from 300 to 1400
Thiosulfoxides (X,S=S) and disulfanes (XSSX): first
Ky o27
observation of organic thiosulfoxides, 239
Reaction mechanism
Unimolecular ion dissociation and laser-induced coales-
Reaction of radical cations of 1,1l-dihaloethenes with
cence of hydrogenated fullerenes, 599
ammonia: substitution and base catalyzed tautomerization
Thermal electron detachment
in sequence, 533
Effect of buffer gas alterations on the thermal electron
attachment and detachment reactions of azulene by pulsed
Salen complexes high pressure mass spectrometry, 481
Coordination chemistry of manganese-salen complexes Thermochemistry
studied by electrospray tandem mass spectrometry: the Activation of CH,, C,H,, and C,H, by gas-phase Nb~
significance of axial ligands, 351 and the thermochemistry of Nb-ligand complexes, 149
Salt-bridge complex The temperature dependence of absolute gas phase acid-
An electrospray ionization flow tube study of the proto- ities, 215
nated betaine/ammonia complex, 11 Thiosulfide
Selected-ion flow tube (SIFT) Thiosulfoxides (X,S=S) and disulfanes (XSSX): first
Gas-phase association reactions of hydroxide, methoxide, observation of organic thiosulfoxides, 239
ethoxide, and their deuterated analogs, 625 Time-of-flight mass spectrometry
Gas-phase reactions of fullerene cations Ci (x = 1-3) Bimolecular ion-molecule collisions in real time:
with pyrrolidine and piperidine: sequential reactions with Co*(*F,) + n-butane and isobutane reactions, 55
Co, 401 Time-resolved bimolecular collisions
Gas-phase reactivity of SO~’: a selected ion flow tube Bimolecular ion-molecule collisions in real time:
study, 185 Co*(*F,) + n-butane and isobutane reactions, 55
Sialic acid Transition metal chemistry
Fragmentation behavior of multiple-metal-coordinated Bimolecular ion-molecule collisions in real time:
acidic oligosaccharides studied by matrix-assisted laser Co*(7F,) + n-butane and isobutane reactions, 55