Table Of Content

Inorganica Chimica Acta, 212 (1993) 341 Author Index of Volume 212 Abdenadher, C., 51 Fenton, D.E., 65 Ma, L., 303 Sasaki, Y., 175 Adams, H., 65 Ferraro, F., 87 Manchanda, R., 135 Satgé, J., 51 Aguinaga, S., 225 Fleischhauer, P., 241 Manojlovié-Muir, Lj., 191 Schrier, P.W., 157 Ahbala, M., 51 Flérke, U., 241 Martell, A.E., 15 Schrélkamp, S., 207 Akashi, H., 251 Folting, K., 165 Matsumoto, K., 251 Shang, M., 95 Al-Resayes, S.1., 265 Forniés, J., 105 Matsumoto, N., 183 Shapley, J.R., 303 Ara, I., 105 Fung, E.Y., 149 Maurya, M.R., 337 Shibahara, T., 251 Aratake, Y., 183 Milone, L., 311 Shih, K.-Y., 23 Gatteschi, D., 87 Mingos, D.M.P., 5 Skelton, B.W., 139 Bailey, N.A., 65 Giusti, A., 87 Moreno, J.M., 115 Slangen, P.M., 289 Balch, A.L., 149 Glerup, J., 281 Motekaitis, R.J., 15 Sletten, J., 271 Bond, A.H., 225 Gobetto, R., 311 Muir, K.W., 191 Smeets, W.J.J., 289 Bond, A.M., 233 Goodson, P.A., 281 Mwariri, B.N., 191 Smith, J.M., 1 Bott, S.G., 1 Gorter, S., 289 Spek, A.L., 289 Brennan, J.G., 219 Greaves, B.C., 139 Nagasawa, A., 175 Spencer, J.T., 317 Brudvig, G.W., 135 Gulbrandsen, A., 271 Nakatani, K., 271 Sperber, W., 207 Nelson, L.T.J., 31 Stanghellini, P.L., 69, 75 Casey, C.P., 81 Haase, W., 241 Nervi, C., 311 Steigerwald, M.L., 219 Castel, A., 51 Haasnoot, J.G., 289 Nixon, J.F., 265 Stein, E., 311 CCahualutdohnu,r i,K .G.P.,, 214615 HHaaruvpety,, HJ..-,J .2, 332 41 OOhkbaaw,a , M.H,. , 18138 3 SSutnu,c zyZn.sSk.i,, 95S .M., 219 . CCCCoohollneattncoa,inn o,t, ,Q . R,E. R.,., 1, 9 29134 1315 HHHaooy,da gssYho.i-n,S, . , R.D6.KJ5.. ,, 8218 1 OOOsoleiml,sl tae,Sa. ,d D,2. 5, 1M 3.1M1. , 149 TTTahodokouikvwoearn-ooY,ta , mMa.Rm,.o, t1o481,3 A., 175 Cornia, A., 87 Torralba, R.C., 123 Ito, ‘f., TIS Pe ¥., 271 Traeger, J.C., 233 Costello, M.T., 157 Pignolet, L.H., 31 Cotton, F.A., 95 Crabtree, R.H., 135 Jacobson, R.A., 337 Poli, R., 123 Us6n, I., 105 Craighead, K.L., 31 Jansen, J., 289 Puddephatt, R.J., 191 Uson, R., 105 Jeannin, S., 323 Utley, W.B., 15 Ravera, M., 311 Jeannin, Y., 323 Davis, B.J., 149 Jennings, M.C., 191 Reedijk, J., 289 van Koningsbruggen, P.J., Davis, C.M., 317 Johnson, B.F.G., 69 Reyes, A., 225 289 Della Pergola, R., 75 Richmond, M.G., 1 Vennos, D.A., 219 Desor, D., 51 Ringrose, S.L., 337 Diana, E., 75 Kahn, O., 271 Riviére, P., 51 Walton, R.A., 23, 157 Dickson, R.S., 139 Kettle, S.F.A., 69, 75 Rogers, R.D., 225 Weihe, H., 281 Didiuk, M., 135 Khan, M.I., 199 Rohl, A.L., 5 White, A.H., 139 Dominguez-Vera, J.M., 115 King, R.B., 57 Romerosa, A., 115 Widenhoefer, R.A., 81 Kivekas, R., 115 Rosenberger, C., 323 Winter, M., 241 Fabretti, A.C., 87 Kooijman, H., 289 Rossetti, R., 69 Woo, L.K., 337 Fallon, G.D., 139 Krogstad, D.A., 31 Rothfuss, H., 165 Falvello, L.R., 105 Kuroya, H., 251 Ruiz, J., 115 Yang, K., 1 Fanwick, P.E., 23, 157 Kwon, Y.-U., 219 Fehlhammer, W.P., 207 Sakiyama, H., 183 Zanello, P., 311 Felicissimo, A.M.P., 31 Laschi, F., 311 Sarneski, J.E., 135 Zubieta, J., 199 Elsevier Sequoia a ee <aa x Sas oe Inorganica Chimica Acta, 212 (1993) 343-348 Subject Index of Volume 212 Alkoxide complexes interpretation of the »(CO) vibrational spectra of cluster borane cluster photochemistry. 2. Photochemical alcoholysis compounds: Ru3;(CO)o(j13-77:77:7?-CsH,), 69 of the octahydrotriborate(1—) anion, 317 interpretation of the »(CO) vibrational spectra of cluster Aquo compiexes compounds: tetrahedral anions [Fe,Ir,(CO),,]*~, substitution of methanol-d, for the coordinated water in [HFe,Ir,(CO),2]~ and [FelIr,(CO),2], 75 the trinuclear complexes, [M3(3-O)(u-CH;COO),- binding modes of cyanide at trinuclear clusters. Crystal (H,0)3]* (M3;=Ru3, Rh3 or Ru,Rh) in methanol-d,, structure of [Pt3(43-CO)(CN)(dppm);][PF,], 191 175 selective substitution and oxidative addition reactions at Aryl complexes the iridium vertex in [Re7C(CO),,Ir(CsH,,)(CO)}?~ and synthesis and reactivity of 1,1,2,2-tetraphenyl 1,2-digermyl- related clusters, 303 dilithium, 51 electrochemical behaviour of tropone diiron pentacarbonyl complexes, Fe,(CO),[(RC,R),;CO] (R=Me, Et, n-Pr). Formation of a carbon-carbon bond upon reduction, Bidentate ligand complexes 311 reactions of the electron-rich triply bonded dirhenium(I]) reaction of unsymmetrical thioalkynes R-C=C-SC,H,, coimplexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. R=CH;, C,H, with iron and ruthenium carbonyls. Paii II. The synthesis and structural characterization How to build a polynuclear compound using the C-S of the complexes ReOCl,(dppmO) (dppmO= cleavage, 323 Ph,PCH,P(O)Ph.) and Re2(u-O)CI,(u-dppm),, 23 Carboxylate complexes Bidentate phosphine ligand complexes structure and magnetic properties of a syn-anti carboxylate tetrahedrane cluster and phosphorus ligand activation in bridged linear trinuclear copper(II) complex with ferro- the reaction between PhCCo,(CO), and 2,3-bis- magnetic exchange interaction, 115 (diphenylphosphino)maleic anhydride. Molecular struc- substitution of methanol-d, for the coordinated water in ture of Co;(CO),(12-7?-7'-C(Ph)C=C(PPh,)C(O)OC- the trinuclear complexes, [M3(3-O)(u-CH3;COO),- (O))(#2-PPh;), 1 (H,0)3]* (M3;=Ru3, Rh; or Ru,Rh) in methanol-d,, Bimetallic complexes 175 structures and magnetic properties of Co(II)Cu(II) and Chelate complexes Ni(II)Cu(II) compounds incorporating the obp= reactions of the electron-rich triply bonded dirhenium(II) oxamidobis(N,N’-propionato) ligand, 271 complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. Binuclear complexes Part II. The synthesis and structural characterization formation of a high valent di-u-oxo manganese dimer in of the complexes ReOCl,(dppmO) (dppmO= aqueous solution, 135 Ph,PCH,P(O)Ph,) and Re2(y-O)Cl,(u-dppm),, 23 synthesis and *'P and '°Pt NMR characterisation of the Chromium complexes first binuclear platinum(I) complex [Pt,Cl,(u-dppm),(p- structural and magnetic characterization of an adamantane- Bu'CP)] containing a p-parallel ligated phospha-alkyne, like complex ion of chromium(III) and 1,3,5-triamino- 265 cyclohexane, [Cr,(tach),(OH),], 281 Binucleating ligand complexes Cluster complexes iron(II) and sulfate binding by the binucleating ligands size and shape of molecular ions and their relevance to O-BISDIEN, O-BISTREN and O-BISBAMP, 15 the packing of the ‘soft salts’, 5 Boron complexes halide derivatives of palladium-gold cluster compounds. borane cluster photochemistry 2. Photochemical alcoholysis X-ray crystal and molecular structure of (I1)Pd(AuPPh;),- of the octahydrotriborate(1—) anion, 317 (Aul),, 31 metal cluster topology. 14. Fusion of octahedra in metal carbonyl clusters, 57 Cadmium complexes interpretation of the »(CO) vibrational spectra of cluster polyethylene glycol complexation of Cd**. Structures of compounds: Ru3(CO)o(y3-77:77:n7-CsH,), 69 triethylene glycol complexes of CdCl,, CdBr, and Cdl), 225 interpretation of the »(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe,Ir,(CO),.|’~, new insights into the constitution of solutions containing [HFe,Ir,(CO),2]~ and [FelIr,(CO),2], 75 labile, polynuclear compounds: an electrospray mass spectrometric study of mercury- and cadmium-rich preparation of the new species [W3(u3-O)(u-Cl).(u- dithiocarbamato cations, 233 O,CMe),Cl3]~ and [Mo3(3-O)(u-Cl)4(4-O,CMe),CL- Carbonyl complexes (PMe;),.]~ that bracket, structurally, the very common tetrahedrane cluster and phosphorus ligand activation in M;(3-O)(u-X)3(u-O2CR3)3L, type of cluster compound, the reaction between PhCCo,(CO), and 2,3-bis- 95 (diphenylphosphino)maleic anhydride. Molecular struc- hydrothermal syntheses and structures of reduced and ture of Co;(CO)¢(1.-7?-n'-C(Ph)C=C(PPh,)C(O)OC- mixed valence polyoxovanadium clusters with capped (O))(#2-PPh;), 1 cage cores: K3[H;2(AsO)(AsO,)V¢'”V,”O3.]-12H,O and metal cluster topology. 14. Fusion of octahedra in metal Rb;[(As,O),(VO)2V12'¥03,Cl] -2H,O, 199 carbonyl clusters, 57 clusters in the step-by-step growth of solids, 219 Elsevier Sequoia 344 sele :tive substitution and oxidative addition reactions at structure and magnetic properties of a syn-anti carboxylate the iridium vertex in [Re;C(CO) ,Ir(C3H,,)(CO)}?~ and bridged linear trinuclear copper(II) complex with ferro- related clusters, 303 magnetic exchange interaction, 115 Cluster topology retention of dinitrogen in the reactions of some diazo- metal cluster topology. 14. Fusion of octahedra in metal alkanes with a dirhodium complex. Crystal and molecu- carbonyl clusters, 57 lar structures of (n-C;H;),Rh,{CF,;C,CF;-CO-N,CRR’}, Cobalt complexes RR’=MePh and (t-Bu),, 139 tetrahedrane cluster and phosphorus ligand activation in palladium-thallium interactions in dinuclear complexes with the reaction between PhCCo,(CO), and 2,3-bis- structural components that place the two metal centers (diphenylphosphino)maleic anhydride. Molecular struc- in close proximity, 149 ture of Co;(CO),(u2-7?-n'-C(Ph)C=C(PPh,)C(O)OC- dirhenium complexes of the tripodal phosphine CH;C- (O))(H2-PPhz), 1 (CH,PPh,)3 (triphos). The isolation and characterization reaction of NO with Cp*;Co3(u-H), preserves the tricobalt of the confacial bioctahedral species [(triphos)- cluster and produces Cp*3;Co;(13-NO)., 81 Re(u-X)3;Re(triphos)]"* (n=1 or 0), 157 structures and magnetic properties of Co(II)Cu(II) and a chain copolymer from WCI,(PMe-,Ph), and [TIOCH,- Ni(II)Cu(II) compounds incorporating the obp= CF3]4, 165 oxamidobis(N,N'-propionato) ligand, 271 dinuclear nickel(II) complexes of a series of dinucleating Copolymer complexes macrocycies with similar or dissimilar coordination sites: a chain copolymer from WCI1,(PMe,Ph), and [TIOCH,- synthesis, structure and physicochemical property, 183 CF;],, 165 binding modes of cyanide at trinuclear clusters. Crystal Copper complexes structure of [Pt;(43-CO)(CN)(dppm)3][PF,], 191 molecular structure and magnetic properties of copper(II), manganese(II) and iron(II) croconate tri-hydrate, 87 hydrothermal syntheses and structures of reduced and mixed valence polyoxovanadium clusters with capped structure and magnetic properties of a syn—anti carboxylate cage cores: K,[H,,(AsO),(AsO,)V,IYV,"’O36]-12H,O and bridged linear trinuclear copper(II) complex with ferro- Rb,[(As,O),(VO)2V12'¥03,Cl]-2H,O, 199 magnetic exchange interaction, 115 a bis(u-isocyanide diiron) complex as chelating ligand structures and magnetic properties of Co(II)Cu(II) and towards iron(II), palladium(I]), zinc(II) and cadmium- Ni(II)Cu(II) compounds incorporating the obp= oxamidobis(N,N’-propionato) ligand, 271 (II). X-ray structural assessment of a novel isocyanide bridging mode, 207 synthesis, characterization, crystal structures and magnetic properties of di- and polynuclear bis(y-3-pyridin-2-yl- polyethylene glycol complexation of Cd?*. Structures of triethylene glycol complexes of CdCl,, CdBr, and Cdl), 1,2,4-triazolato)copper(II) compounds containing 225 N-methylimidazole, pyrazole or 4,4’-bipyridine as co-ligands, 289 synthesis, structure and magnetism of a tetranuclear Fe(III) complex containing an [Fe,(j3-O),]*®* core, 241 Croconate complexes syntheses and characterization of cubane-type clusters, molecular structure and magnetic properties of copper(II), [Mo,S,(edta)2]"~ (2 =2-4), [Mo,S,(H,0),2]"* (=4-6) manganese(II) and iron(II) croconate tri-hydrate, 87 and [Mo,S,(NH3),2]**. X-ray structures of Na,- Crystal structures [Mo,S,(edta),]-6H,O, Ca, ;[Mo,S,(edta),]-13H,O, tetrahedrane cluster and phosphorus ligand activation in Mg,[Mo,S,(edta),]-20H,O, [Mo,S,(H,0)2}(CH3C.H,- the reaction between PhCCo,(CO), and 2,3-bis- SO;);-14H,O and [Mo,S,(NH3),2]Cl,-7H,O, 251 (diphenylphosphino)maleic anhydride. Molecular struc- ture of Co;(CO)¢(j2-7?-n'-C(Ph)C=C(PPh,)C(O)OC- structures and magnetic properties of Co(II)Cu(II) and (O))(u2-PPhz), 1 Ni(II)Cu(II) compounds incorporating the obp= reactions of the electron-rich triply bonded dirhenium(II) oxamidobis(N,N’-propionato) ligand, 271 structural and magnetic characterization of an adamantane- complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. like complex ion of chromium(III) and 1,3,5-triamino- Part II. The synthesis and structural characterization cyclohexane, [Cr,(tach),(OH),], 281 of the complexes ReOCl,(dppmO) (dppmO= Ph,PCH,P(O)Ph,) and Re,(u-O)CI,(u-dppm),, 23 synthesis, characterization, « ystal structures and magnetic halide derivatives of palladium—gold cluster compounds. properties of di- and polynuclear bis(-3-pyridin-2-yl- 1,2,4-triazolato)copper(II) compounds containing X-ray crystal and molecular structure of (I)Pd(AuPPh;),- (Aul),, 31 N-methylimidazole, pyrazole or 4,4’-bipyridine as a polymeric tetraimine Schiff base macrocyclic complex of co-ligands, 289 reaction of unsymmetrical thioalkynes R-C=C-SC,H,, silver(I), 65 reaction of NO with Cp*;Co3(u-H), preserves the tricobalt R=CH;, C.Hs, with iron and ruthenium carbonyls. cluster and produces Cp*3;Co;(13-NO),, 81 How to build a polynuclear compound using the C-S molecular structure and magnetic properties of copper(II), cleavage, 323 manganese(II) and iron(II) croconate tri-hydrate, 87 synthesis, characterization, and X-ray crystal structure of a preparation of the new species [W3(3-O)(u-Cl)(u- trimetallic diporphyrin complex, 337 O,CMe),Cl;]~ and [Mo3(j3-O)(-Cl),(4-O,CMe),Cl,- Cubane-type complexes (PMe;)2]~ that bracket, structurally, the very common syntheses and characterization of cubane-type clusters, M;(43-O)(-X)3(4-O2CR;)3L, type of cluster compound, [Mo,S,(edta),}"" (n=2-4), [Mo,S,(H,0),2]"* (n=4-6) 95 and [Mo,S,(NH3),2]**. X-ray structures of Na,- pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear [Mo,S,(edta).]-6H,0, Ca; ;[Mo,S,(edta),]-13H,O, [Pt,Hg.] anionic complexes containing unbridged Pt-Hg Mg,[Mo,S,(edta),]-20H,O, [Mo,S,(H2O),2](CH3C.H,- bonds and OH bridges, 105 SO;)5-14H,O and [Mo,S,(NH3),2]Cl,-7H,O, 251 Cyanide complexes Gold complexes binding modes of cyanide at trinuclear clusters. Crystal halide derivatives of palladium-gold cluster compounds. structure of [Pt3;(43-CO)(CN)(dppm),][PF,], 191 X-ray crystal and molecular structure of (I)Pd(AuPPh;,),- Cyclopentadienyl complexes (Aul),, 31 reaction of NO with Cp*;Co;(y-H), preserves the tricobalt cluster and produces Cp*;Co3(13-NO),, 81 Halide complexes Diazoalkane complexes halide derivatives of palladium-gold cluster compounds. retention of dinitrogen in the reactions of some diazo- X-ray crystal and molecular structure of (I)Pd(AuPPh;),- alkanes with a dirhodium complex. Crystal and molecu- (Aul),, 31 lar structures of (7-C;H;)2Rh.{CF3;C,CF;-CO-N,CRR’}, polyethylene glycol complexation of Cd?*. Structures of RR’=MePh and (t-Bu),, 139 triethylene glycol complexes of CdCl,, CdBr, and Cdl,, Dinuclear complexes 225 reactions of the electron-rich triply bonded dirhenium(I]) Hydroborate complexes complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. borane cluster photochemistry. 2. Photochemical alcoholysis Part II. The synthesis and structural characterization of the octahydrotriborate(1—) anion, 317 of the complexes ReOCl,(dppmO) (dppmO= Hydroxo complexes Ph,PCH,P(O)Ph2) and Re2(u-O)CI,(u-dppm),, 23 pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear further considerations on the structure and bonding in [Pt,Hg2] anionic complexes containing unbridged Pt-Hg edge-sharing bioctahedral complexes, 123 bonds and OH bridges, 105 retention of dinitrogen in the reactions of some diazo- alkanes with a dirhodium complex. Crystal and molecu- lar structures of (7-Cs;H;),Rh2{CF3;C,CF;-CO-N,CRR’}, Infrared spectroscopy RR’=MePh and (t-Bu),, 139 interpretation of the »(CO) vibrational spectra of cluster palladium-thallium interactions in dinuclear complexes with compounds: Ru;(CO)o(413-77:77:n?-C,H,), 69 structural components that place the two metal centers interpretation of the »(CO) vibrational spectra of cluster in close proximity, 149 compounds: tetrahedral anions [Fe,Ir,(CO),.]*~, dinuclear nickel(II) complexes of a series of dinucleating [HFe,Ir,(CO),2]~ and [FelIr,(CO),.], 75 macrocycles with similar or dissimilar coordination sites: Ion complexes synthesis, structure and physicochemical property, 183 size and shape of molecular ions and their relevance to electrochemical behaviour of tropone diiron pentacarbonyl the packing of the ‘soft salts’, 5 complexes, Fe,(CO),;[(RC,R);CO] (R=Me, Et, n-Pr). Iridium complexes Formation of a carbon-carbon bond upon reduction, interpretation of the »(CO) vibrational spectra of cluster 311 compounds: tetrahedral anions [Fe,Ir,(CO),|*~, Dithiocarbamato complexes [HFe,Ir,(CO),2]~ and [FelIr,(CO),.], 75 new insights into the constitution of solutions containing selective substitution and oxidative addition reactions at labile, polynuclear compounds: an electrospray mass the iridium vertex in [Re;C(CO),,Ir(CsH;,)(CO)?~ and spectrometric study of mercury- and cadmium-rich related clusters, 303 dithiocarbamato cations, 233 Iron complexes iron(II) and sulfate binding by the binucleating ligands Electrochemistry O-BISDIEN, O-BISTREN and O-BISBAMP, 15 syntheses and characterization of cubane-type clusters, interpretation of the »(CO) vibrational spectra of cluster [Mo,S,(edta)}"~ (n=2-4), [Mo,S,(H20),2]"* (1 =4-6) compounds: tetrahedral anions [Fe,Ir,(CO),.}~, and [Mo,S,(NH3),.]**. X-ray structures of Nap- [HFe,Ir(CO),2.]~ and [FelIr,(CO),.], 75 [Mo,S,(edta)]-6H,O, Ca, ;[Mo,S,(edta),]-13H,O, molecular structure and magnetic properties of copper(II), Mg.[Mo,S,(edta)2]-20H,O, [Mo,S,(H2O),2](CH3C.H,- manganese(II) and iron(II) croconate tri-hydrate, 87 SO3)5-14H,O and [Mo,S,(NH3),2]C7lH,2-O, 251 a bis(y-isocyanide diiron) complex as chelating ligand electrochemical behaviour of tropone diiron pentacarbonyl complexes, Fe,(CO),[(RC,R)3;CO] (R=Me, Et, n-Pr). towards iron(II), palladium(II), zinc(II) and cadmium- Formation of a carbon-carbon bond upon reduction, (II). X-ray structural assessment of a novel isocyanide bridging mode, 207 311 synthesis, structure and magnetism of a tetranuclear Electronic structures syntheses and characterization of cubane-type clusters, Fe(III) complex containing an [Fe,(y3-O),]** core, 241 [Mo,S,(edta),]"~ (n=2-4), [Mo,S,(H;0),.J"* (n=4-6) electrochemical behaviour of tropone diiron pentacarbonyl and [Mo,S,(NH3),.]**. X-ray structures of Na,- complexes, Fe,(CO),[(RC,R);CO] (R=Me, Et, n-Pr). [Mo,S,(edta)2]-6H,O, Ca, 5[Mo,S,(edta),]-13H,O, Formation of a carbon-carbon bond upon reduction, 311 Mg,[Mo,S,(edta)2]-20H,O, [Mo,S,(H2O);2](CH3C.H,- SO3);:14H,O and [Mo,S,(NH3)j2]Cl7H,2-O, 251 reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, R=CH;, C,H;, with iron and ruthenium carbonyls. Germanium complexes How to build a polynuclear compound using the C-S synthesis and reactivity of 1,1,2,2-tetraphenyl 1,2-digermyl- cleavage, 323 dilithium, 51 Isocyanide complexes Glycol complexes a bis(u-isocyanide diiron) complex as chelating ligand polyethylene glycol complexation of Cd?*. Structures of towards iron(II), palladium(I]), zinc(II) and cadmium- triethylene glycol complexes of CdCl,, CdBr, and Cdl), (II). X-ray structural assessment of a novel isocyanide 225 bridging mode, 207 346 Kinetics and mechanism and [Mo,S,(NH;),.]** X-ray structures of Na,- [Mo,S,(edta),]-6H,O, Ca;< [Mo,S,(edta),]-13H,0, substitution of methanol-d, for the coordinated water in Mg,[Mo,S,(edta)]-20H,O, [Mo,S,(H,0);2](CHsC.H,- the trinuclear complexes, [M3(3-O)(u-CH;COO),- (H,O)3]* (M3;=Ru3, Rh; or Ru,Rh) in methanol-d,, SO3);°14H,O and [Mo,S,(NH3);2]Cl,-7H2O, 251 175 Nickel complexes Macrocyclic ligand complexes dinuclear nickel(II) complexes of a series of dinucleating a polymeric tetraimine Schiff base macrocyclic complex of macrocycles with similar or dissimilar coordination sites: silver(I), 65 synthesis, structure and physicochemical property, 183 dinuclear nickel(II) complexes of a series of dinucleating clusters in the step-by-step growth of solids, 219 macrocycles with similar or dissimilar coordination sites: structures and magnetic properties of Co(II)Cu(II) and synthesis, structure and physicochemical property, 183 Ni(II)Cu(II) compounds incorporating the obp= Magnetism oxamidobis(N,N’-propionato) ligand, 271 molecular structure and magnetic properties of copper(II), synthesis, characterization, and X-ray crystal structure of a manganese(II) and iron(II) croconate tri-hydrate, 87 trimetallic diporphyrin complex, 337 structure and magnetic properties of a syn-anti carboxylate Nitrosyl complexes bridged linear trinuclear copper(II) complex with ferro- reaction of NO with Cp*,;Co3(u-H), preserves the tricobalt magnetic exchange interaction, 115 cluster and produces Cp*;Co3(3-NO),, 81 synthesis, structure and magnetism of a tetranuclear NMR Fe(III) complex containing an [Fe,(3-O),]** core, 241 a reinvestigation of isomerism in the Dawson structure: structures and magnetic properties of Co(II)Cu(II) and syntheses and '*W NMR structural characterization of Ni(II)Cu(II) compounds incorporating the obp= three new polyoxotungstates [X,W,s0,.]° (X=PY, oxamidobis(N,N’-propionato) ligand, 271 As’), 41 structural and magnetic characterization of an adamantane- like complex ion of chromium(III) and 1,3,5-triamino- Oxo complexes cyclohexane, [Cr,(tach),(OH),], 281 reactions of the electron-rich triply bonded dirhenium(II) synthesis, characterization, crystal structures and magnetic complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. properties of di- and polynuclear bis(-3-pyridin-2-yl- Part II. The synthesis and structural characterization 1,2,4-triazolato)copper(II) compounds containing of the complexes ReOCl,(dppmO) (dppmO= N-methylimidazole, pyrazole or 4,4’-bipyridine as Ph,PCH,P(O)Ph,) and Re2(u-O)Cl,(u-dppm),, 23 co-ligands, 289 a reinvestigation of isomerism in the Dawson structure: Manganese complexes syntheses and 'W NMR structural characterization of molecular structure and magnetic properties of copper(II), three new polyoxotungstates [X,W,s0,.]° (X=PY, manganese(II) and iron(II) croconate tri-hydrate, 87 As’), 41 formation of a high valent di-~-oxo manganese dimer in preparation of the new species [W3(13-O)(u-Cl)2(p- aqueous solution, 135 O,CMe),Cl3]~ and [Mo3(13-O)(-Cl)4(u-O,CMe),Cl,- Mass spectrometry (PMe;)2]~ that bracket, structurally, the very common new insights into the constitution of solutions containing M3(3-O)(-X)3(4-O2CR3)3L, type of cluster compound, labile, polynuclear compounds: an electrospray mass 95 spectrometric study of mercury- and cadmium-rich formation of a high valent di-~-oxo manganese dimer in dithiocarbamato cations, 233 aqueous solution, 135 Mercury complexes hydrothermal syntheses and structures of reduced and pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear mixed valence polyoxovanadium clusters with capped [Pt,Hg.] anionic complexes containing unbridged Pt-Hg cage cores: K3[H,,(AsO).(AsO,)V¢'YV,”O3.]-12H,O and bonds and OH bridges, 105 Rb.[(As,0),(VO),V;2'¥O3¢Cl]-2H,O, 199 new insights into the constitution of solutions containing synthesis, structure and magnetism of a tetranuclear labile, polynuclear compounds: an electrospray mass Fe(III) complex containing an [Fe,(j3-O),]** core, 241 spectrometric study of mercury- and cadmium-rich dithiocarbamato cations, 233 Palladium complexes Metal complexes halide derivatives of palladium-gold cluster compounds. size and shape of molecular ions and their relevance to X-ray crystal and molecular structure of (I)Pd(AuPPh;),- the packing of the ‘soft salts’, 5 (Aul),, 31 metal cluster topology. 14. Fusion of octahedra in metal palladium-thallium interactions in dinuclear complexes with carbonyl clusters, 57 structural components that place the two metal centers a bis(y-isocyanide diiron) complex as chelating ligand in close proximity, 149 towards iron(II), palladium(II), zinc(II) and cadmium- clusters in the step-by-step growth of solids, 219 (II). X-ray structural assessment of a novel isocyanide synthesis, characterization, and X-ray crystal structure of a bridging mode, 207 trimetallic diporphyrin complex, 337 Molybdenum complexes Phospha-alkyne complexes preparation of the new species [W3(3-O)(u-Cl)2(u- synthesis and *‘P and Pt NMR characterisation of the O,CMe),Cl]~ and [Mo3(s13-O)(u-Cl)4(4-O2CMe),Cl.- first binuclear platinum(I) complex [Pt,Cl,(u-dppm),(u- (PMe;).]” that bracket, structurally, the very common Bu'CP)] containing a p-parallel ligated phospha-alkyne, M(43-O)(u-X)3(4-O2CR;)3L, type of cluster compound, 265 95 Phosphine complexes syntheses and characterization of cubane-type clusters, dirhenium complexes of the tripodal phosphine CH;C- [Mo,S,(edta),]"~ (n=2-4), [Mo,S,(H2O),2]"* (n=4-6) (CH,PPh,2); (triphos). The isolation and characterization of the confacial bioctahedral species [(triphos)- Rhenium complexes Re(yu-X)3Re(triphos)]"* (m=1 or 0), 157 reactions of the electron-rich triply bonded dirhenium(II) Photochemistry complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. borane cluster photochemistry. 2. Photochemical alcoholysis Part II. The synthesis and structural characterization of the octahydrotriborate(1—) anion, 317 of the complexes ReOCl,(dppmO) (dppmO = Platinum complexes Ph,PCH,P(O)Ph,) and Re2(u-O)Cl,(u-dppm),, 23 synthesis and reactivity of 1,1,2,2-tetraphenyl 1,2-digermyl- dirhenium complexes of the tripodal phosphine CH,C- dilithium, 51 (CH,PPh,); (triphos). The isolation and characterization pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear of the confacial bioctahedral species [(triphos)- [Pt,Hg,] anionic complexes containing unbridged Pt-Hg Re(u-X)3Re(triphos)}"* (n=1 or 0), 157 bonds and OH bridges, 105 selective substitution and oxidative addition reactions at binding modes of cyanide at trinuclear clusters. Crystal the iridium vertex in [Re;C(CO),,Ir(CsH,,)(CO)}*~ and structure of [Pt;(43;-CO)(CN)(dppm)3][PF,], 191 related clusters, 303 synthesis and *'P and '*Pt NMR characterisation of the Rhodium complexes first binuclear platinum(I) complex [Pt,Cl,(u-dppm).(u- retention of dinitrogen in the reactions of some diazo- Bu'CP)] containing a p-parallel ligated phospha-alkyne, alkanes with a dirhodium complex. Crystal and molecu- 265 lar structures of (7-C;H;),Rh,{CF;C,CF,-CO-N,CRR’}, Polyaza macrocyclic complexes RR’=MePh and (t-Bu), 139 iron(II) and sulfate binding by the binucleating ligands substitution of methanol-d, for the coordinated water in O-BISDIEN, O-BISTREN and O-BISBAMP, 15 the trinuclear complexes, [M3(3-O)(u-CH;COO),- Polydentate ligand complexes (H,O)3]* (M3;=Ru;, Rh; or Ru,Rh) in methanol-d,, dirhenium complexes of the tripodal phosphine CH,C- 175 (CH,PPh,); (triphos). The isolation and characterization Ruthenium complexes of the confacial bioctahedral species [(triphos)- interpretation of the v(CO) vibrational spectra of cluster Re(u-X)3Re(triphos)]"* (n=1 or 0), 157 compounds: Ru3(CO)>(13-77:77:?-C,H,), 69 electrochemical behaviour of tropone diiron pentacarbonyl substitution of methanol-d, for the coordinated water in complexes, Fe,(CO);[(RC,R);CO] (R=Me, Et, n-Pr). the trinuclear complexes, [M3(3-O)(u-CH;COO),- Formation of a carbon-carbon bond upon reduction, (H,0)3]* (M3;=Ru;, Rh; or Ru,Rh) in methanol-d,, 311 175 Polynuclear complexes reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, a reinvestigation of isomerism in the Dawson structure: R=CH;, C;H;, with iron and ruthenium carbonyls. syntheses and '°W NMR structural characterization of How to build a polynuclear compound using the C-S three new polyoxotungstates [X2W1s0,.]° (X=PY, cleavage, 323 As’), 41 pentafluoropheny] trinuclear [Pt,Hg] and hexanuclear Schiff base complexes [Pt,Hg.] anionic complexes containing unbridged Pt-Hg a polymeric tetraimine Schiff base macrocyclic complex of bonds and OH bridges, 105 silver(I), 65 structure and magnetic properties of a syn-anti carboxylate Silver complexes bridged linear trinuclear copper(II) complex with ferro- a polymeric tetraimine Schiff base macrocyclic complex of magnetic exchange interaction, 115 silver(I), 65 new insights into the constitution of solutions containing Solid state labile, polynuclear compounds: an electrospray mass size and shape of molecular ions and their relevance to spectrometric study of mercury- and cadmium-rich the packing of the ‘soft salts’, 5 dithiocarbamato cations, 233 Stability constants synthesis, structure and magnetism of a tetranuclear iron(II) and sulfate binding by the binucleating ligands Fe(III) complex containing an [Fe,(j13-O),]** core, 241 O-BISDIEN, O-BISTREN and O-BISBAMP, 15 structural and magnetic characterization of an adamantane- Structure and bonding like complex ion of chromium(III) and 1,3,5-triamino- further considerations on the structure and bonding in cyclohexane, [Cr,(tach),(OH),], 281 edge-sharing bioctahedral complexes, 123 reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, Sulfur complexes R=CH;, C,Hs, with iron and ruthenium carbonyls. syntheses and characterization of cubane-type clusters, How to build a polynuclear compound using the C-S cleavage, 323 [Mo,S,(edta),]"" (”=2-4), [Mo,S,(H20),2]"* (n=4-6) and [Mo,S,(NH3),.]**. X-ray structures of Na,- Porphyrin complexes [Mo,S,(edta)2]-6H,0, Ca, ;[Mo,S,(edta),]-13H,O, synthesis, characterization, and X-ray crystal structure of a Mg,[Mo,S,(edta),] -20H,0, [Mo,S,(H20);2](CH3CsH,- trimetallic diporphyrin complex, 337 SO;);-14H,O and [Mo,S,(NH3);2]Cl,-7H,O, 251 Potentiometry iron(II) and sulfate binding by the binucleating ligands O-BISDIEN, O-BISTREN and O-BISBAMP, 15 Tellurium complexes clusters in the step-by-step growth of solids, 219 Raman spectroscopy Thallium complexes interpretation of the (CO) vibrational spectra of cluster palladium-thallium interactions in dinuclear complexes with compounds: Ru3(CO)o(3-7:77:7?-CgH,), 69 structural components that place the two metal centers interpretation of the (CO) vibrational spectra of cluster in close proximity, 149 compounds: tetrahedral anions [Fe,Ir,(CO),2]”~, a chain copolymer from WCI,(PMe,Ph), and [TIOCH,- [HFe,Ir,(CO),.]~ and [FelIr,(CO),2], 75 CF3],, 165 348 Thiazole complexes (H,O)3]* (M3;=Ru;, Rh; or Ru,Rh) in methanol-d,, synthesis, characterization, crystal structures and magnetic 175 properties of di- and polynuclear bis(u-3-pyridin-2-yl- binding modes of cyanide at trinuclear clusters. Crystal 1,2,4-triazolato)copper(II) compounds containing structure of [Pt3(43-CO)(CN)(dppm)3][PF.], 191 N-methylimidazole, pyrazole or 4,4’-bipyridine as Tungsten complexes co-ligands, 289 a reinvestigation of isomerism in the Dawson structure: Thioalkyne complexes syntheses and '*W NMR structural characterization of reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, three new polyoxotungstates [X;W sO0,2]° (X=PY, R=CH;, C,Hs, with iron and ruthenium carbonyls. As’), 41 How to build a polynuclear compound using the C-S preparation of the new species [W3(13-O)(u-Cl)2(y- cleavage, 323 O,CMe),4Cl3]~ and [Mo3(43-O)(-Cl),(u-O,CMe),Cl,- Transition metal complexes (PMe;)2]” that bracket, structurally, the very common further considerations on the structure and bonding in M;(413-O)(u-X)3(u4-O2CR3)3L, type of cluster compound, edge-sharing bioctahedral complexes, 123 Tridentate ligand complexes a chain copolymer from WCI,(PMe,Ph), and [TIOCH,- structural and magnetic characterization of an adamantane- CF3],, 165 like complex ion of chromium(III) and 1,3,5-triamino- cyclohexane, [Cr,(tach),(OH)<,], 281 Trinuclear complexes Vanadium complexes reaction of NO with Cp*;Co3(u-H), preserves the tricobalt hydrothermal syntheses and structures of reduced and cluster and produces Cp*3;Co3(u3-NO)., 81 mixed valence polyoxovanadium clusters with capped substitution of methanol-d, for the coordinated water in cage cores: K,[H;.(AsO),(AsO,)V6'YV,”O3,]-12H,O and the trinuclear complexes, [M3(3-O)(u-CH;COO),- Rb;[(As2O),(VO)2V12'¥O3¢Cl] -2H2O, 199

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Inorganica Chimica Acta 1993: Vol 212 Index PDF

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Inorganica Chimica Acta, 212 (1993) 341 Author Index of Volume 212 Abdenadher, C., 51 Fenton, D.E., 65 Ma, L., 303 Sasaki, Y., 175 Adams, H., 65 Ferraro, F., 87 Manchanda, R., 135 Satgé, J., 51 Aguinaga, S., 225 Fleischhauer, P., 241 Manojlovié-Muir, Lj., 191 Schrier, P.W., 157 Ahbala, M., 51 Flérke, U., 241 Martell, A.E., 15 Schrélkamp, S., 207 Akashi, H., 251 Folting, K., 165 Matsumoto, K., 251 Shang, M., 95 Al-Resayes, S.1., 265 Forniés, J., 105 Matsumoto, N., 183 Shapley, J.R., 303 Ara, I., 105 Fung, E.Y., 149 Maurya, M.R., 337 Shibahara, T., 251 Aratake, Y., 183 Milone, L., 311 Shih, K.-Y., 23 Gatteschi, D., 87 Mingos, D.M.P., 5 Skelton, B.W., 139 Bailey, N.A., 65 Giusti, A., 87 Moreno, J.M., 115 Slangen, P.M., 289 Balch, A.L., 149 Glerup, J., 281 Motekaitis, R.J., 15 Sletten, J., 271 Bond, A.H., 225 Gobetto, R., 311 Muir, K.W., 191 Smeets, W.J.J., 289 Bond, A.M., 233 Goodson, P.A., 281 Mwariri, B.N., 191 Smith, J.M., 1 Bott, S.G., 1 Gorter, S., 289 Spek, A.L., 289 Brennan, J.G., 219 Greaves, B.C., 139 Nagasawa, A., 175 Spencer, J.T., 317 Brudvig, G.W., 135 Gulbrandsen, A., 271 Nakatani, K., 271 Sperber, W., 207 Nelson, L.T.J., 31 Stanghellini, P.L., 69, 75 Casey, C.P., 81 Haase, W., 241 Nervi, C., 311 Steigerwald, M.L., 219 Castel, A., 51 Haasnoot, J.G., 289 Nixon, J.F., 265 Stein, E., 311 CCahualutdohnu,r i,K .G.P.,, 214615 HHaaruvpety,, HJ..-,J .2, 332 41 OOhkbaaw,a , M.H,. , 18138 3 SSutnu,c zyZn.sSk.i,, 95S .M., 219 . CCCCoohollneattncoa,inn o,t, ,Q . R,E. R.,., 1, 9 29134 1315 HHHaooy,da gssYho.i-n,S, . , R.D6.KJ5.. ,, 8218 1 OOOsoleiml,sl tae,Sa. ,d D,2. 5, 1M 3.1M1. , 149 TTTahodokouikvwoearn-ooY,ta , mMa.Rm,.o, t1o481,3 A., 175 Cornia, A., 87 Torralba, R.C., 123 Ito, ‘f., TIS Pe ¥., 271 Traeger, J.C., 233 Costello, M.T., 157 Pignolet, L.H., 31 Cotton, F.A., 95 Crabtree, R.H., 135 Jacobson, R.A., 337 Poli, R., 123 Us6n, I., 105 Craighead, K.L., 31 Jansen, J., 289 Puddephatt, R.J., 191 Uson, R., 105 Jeannin, S., 323 Utley, W.B., 15 Ravera, M., 311 Jeannin, Y., 323 Davis, B.J., 149 Jennings, M.C., 191 Reedijk, J., 289 van Koningsbruggen, P.J., Davis, C.M., 317 Johnson, B.F.G., 69 Reyes, A., 225 289 Della Pergola, R., 75 Richmond, M.G., 1 Vennos, D.A., 219 Desor, D., 51 Ringrose, S.L., 337 Diana, E., 75 Kahn, O., 271 Riviére, P., 51 Walton, R.A., 23, 157 Dickson, R.S., 139 Kettle, S.F.A., 69, 75 Rogers, R.D., 225 Weihe, H., 281 Didiuk, M., 135 Khan, M.I., 199 Rohl, A.L., 5 White, A.H., 139 Dominguez-Vera, J.M., 115 King, R.B., 57 Romerosa, A., 115 Widenhoefer, R.A., 81 Kivekas, R., 115 Rosenberger, C., 323 Winter, M., 241 Fabretti, A.C., 87 Kooijman, H., 289 Rossetti, R., 69 Woo, L.K., 337 Fallon, G.D., 139 Krogstad, D.A., 31 Rothfuss, H., 165 Falvello, L.R., 105 Kuroya, H., 251 Ruiz, J., 115 Yang, K., 1 Fanwick, P.E., 23, 157 Kwon, Y.-U., 219 Fehlhammer, W.P., 207 Sakiyama, H., 183 Zanello, P., 311 Felicissimo, A.M.P., 31 Laschi, F., 311 Sarneski, J.E., 135 Zubieta, J., 199 Elsevier Sequoia a ee <aa x Sas oe Inorganica Chimica Acta, 212 (1993) 343-348 Subject Index of Volume 212 Alkoxide complexes interpretation of the »(CO) vibrational spectra of cluster borane cluster photochemistry. 2. Photochemical alcoholysis compounds: Ru3;(CO)o(j13-77:77:7?-CsH,), 69 of the octahydrotriborate(1—) anion, 317 interpretation of the »(CO) vibrational spectra of cluster Aquo compiexes compounds: tetrahedral anions [Fe,Ir,(CO),,]*~, substitution of methanol-d, for the coordinated water in [HFe,Ir,(CO),2]~ and [FelIr,(CO),2], 75 the trinuclear complexes, [M3(3-O)(u-CH;COO),- binding modes of cyanide at trinuclear clusters. Crystal (H,0)3]* (M3;=Ru3, Rh3 or Ru,Rh) in methanol-d,, structure of [Pt3(43-CO)(CN)(dppm);][PF,], 191 175 selective substitution and oxidative addition reactions at Aryl complexes the iridium vertex in [Re7C(CO),,Ir(CsH,,)(CO)}?~ and synthesis and reactivity of 1,1,2,2-tetraphenyl 1,2-digermyl- related clusters, 303 dilithium, 51 electrochemical behaviour of tropone diiron pentacarbonyl complexes, Fe,(CO),[(RC,R),;CO] (R=Me, Et, n-Pr). Formation of a carbon-carbon bond upon reduction, Bidentate ligand complexes 311 reactions of the electron-rich triply bonded dirhenium(I]) reaction of unsymmetrical thioalkynes R-C=C-SC,H,, coimplexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. R=CH;, C,H, with iron and ruthenium carbonyls. Paii II. The synthesis and structural characterization How to build a polynuclear compound using the C-S of the complexes ReOCl,(dppmO) (dppmO= cleavage, 323 Ph,PCH,P(O)Ph.) and Re2(u-O)CI,(u-dppm),, 23 Carboxylate complexes Bidentate phosphine ligand complexes structure and magnetic properties of a syn-anti carboxylate tetrahedrane cluster and phosphorus ligand activation in bridged linear trinuclear copper(II) complex with ferro- the reaction between PhCCo,(CO), and 2,3-bis- magnetic exchange interaction, 115 (diphenylphosphino)maleic anhydride. Molecular struc- substitution of methanol-d, for the coordinated water in ture of Co;(CO),(12-7?-7'-C(Ph)C=C(PPh,)C(O)OC- the trinuclear complexes, [M3(3-O)(u-CH3;COO),- (O))(#2-PPh;), 1 (H,0)3]* (M3;=Ru3, Rh; or Ru,Rh) in methanol-d,, Bimetallic complexes 175 structures and magnetic properties of Co(II)Cu(II) and Chelate complexes Ni(II)Cu(II) compounds incorporating the obp= reactions of the electron-rich triply bonded dirhenium(II) oxamidobis(N,N’-propionato) ligand, 271 complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. Binuclear complexes Part II. The synthesis and structural characterization formation of a high valent di-u-oxo manganese dimer in of the complexes ReOCl,(dppmO) (dppmO= aqueous solution, 135 Ph,PCH,P(O)Ph,) and Re2(y-O)Cl,(u-dppm),, 23 synthesis and *'P and '°Pt NMR characterisation of the Chromium complexes first binuclear platinum(I) complex [Pt,Cl,(u-dppm),(p- structural and magnetic characterization of an adamantane- Bu'CP)] containing a p-parallel ligated phospha-alkyne, like complex ion of chromium(III) and 1,3,5-triamino- 265 cyclohexane, [Cr,(tach),(OH),], 281 Binucleating ligand complexes Cluster complexes iron(II) and sulfate binding by the binucleating ligands size and shape of molecular ions and their relevance to O-BISDIEN, O-BISTREN and O-BISBAMP, 15 the packing of the ‘soft salts’, 5 Boron complexes halide derivatives of palladium-gold cluster compounds. borane cluster photochemistry 2. Photochemical alcoholysis X-ray crystal and molecular structure of (I1)Pd(AuPPh;),- of the octahydrotriborate(1—) anion, 317 (Aul),, 31 metal cluster topology. 14. Fusion of octahedra in metal carbonyl clusters, 57 Cadmium complexes interpretation of the »(CO) vibrational spectra of cluster polyethylene glycol complexation of Cd**. Structures of compounds: Ru3(CO)o(y3-77:77:n7-CsH,), 69 triethylene glycol complexes of CdCl,, CdBr, and Cdl), 225 interpretation of the »(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe,Ir,(CO),.|’~, new insights into the constitution of solutions containing [HFe,Ir,(CO),2]~ and [FelIr,(CO),2], 75 labile, polynuclear compounds: an electrospray mass spectrometric study of mercury- and cadmium-rich preparation of the new species [W3(u3-O)(u-Cl).(u- dithiocarbamato cations, 233 O,CMe),Cl3]~ and [Mo3(3-O)(u-Cl)4(4-O,CMe),CL- Carbonyl complexes (PMe;),.]~ that bracket, structurally, the very common tetrahedrane cluster and phosphorus ligand activation in M;(3-O)(u-X)3(u-O2CR3)3L, type of cluster compound, the reaction between PhCCo,(CO), and 2,3-bis- 95 (diphenylphosphino)maleic anhydride. Molecular struc- hydrothermal syntheses and structures of reduced and ture of Co;(CO)¢(1.-7?-n'-C(Ph)C=C(PPh,)C(O)OC- mixed valence polyoxovanadium clusters with capped (O))(#2-PPh;), 1 cage cores: K3[H;2(AsO)(AsO,)V¢'”V,”O3.]-12H,O and metal cluster topology. 14. Fusion of octahedra in metal Rb;[(As,O),(VO)2V12'¥03,Cl] -2H,O, 199 carbonyl clusters, 57 clusters in the step-by-step growth of solids, 219 Elsevier Sequoia 344 sele :tive substitution and oxidative addition reactions at structure and magnetic properties of a syn-anti carboxylate the iridium vertex in [Re;C(CO) ,Ir(C3H,,)(CO)}?~ and bridged linear trinuclear copper(II) complex with ferro- related clusters, 303 magnetic exchange interaction, 115 Cluster topology retention of dinitrogen in the reactions of some diazo- metal cluster topology. 14. Fusion of octahedra in metal alkanes with a dirhodium complex. Crystal and molecu- carbonyl clusters, 57 lar structures of (n-C;H;),Rh,{CF,;C,CF;-CO-N,CRR’}, Cobalt complexes RR’=MePh and (t-Bu),, 139 tetrahedrane cluster and phosphorus ligand activation in palladium-thallium interactions in dinuclear complexes with the reaction between PhCCo,(CO), and 2,3-bis- structural components that place the two metal centers (diphenylphosphino)maleic anhydride. Molecular struc- in close proximity, 149 ture of Co;(CO),(u2-7?-n'-C(Ph)C=C(PPh,)C(O)OC- dirhenium complexes of the tripodal phosphine CH;C- (O))(H2-PPhz), 1 (CH,PPh,)3 (triphos). The isolation and characterization reaction of NO with Cp*;Co3(u-H), preserves the tricobalt of the confacial bioctahedral species [(triphos)- cluster and produces Cp*3;Co;(13-NO)., 81 Re(u-X)3;Re(triphos)]"* (n=1 or 0), 157 structures and magnetic properties of Co(II)Cu(II) and a chain copolymer from WCI,(PMe-,Ph), and [TIOCH,- Ni(II)Cu(II) compounds incorporating the obp= CF3]4, 165 oxamidobis(N,N'-propionato) ligand, 271 dinuclear nickel(II) complexes of a series of dinucleating Copolymer complexes macrocycies with similar or dissimilar coordination sites: a chain copolymer from WCI1,(PMe,Ph), and [TIOCH,- synthesis, structure and physicochemical property, 183 CF;],, 165 binding modes of cyanide at trinuclear clusters. Crystal Copper complexes structure of [Pt;(43-CO)(CN)(dppm)3][PF,], 191 molecular structure and magnetic properties of copper(II), manganese(II) and iron(II) croconate tri-hydrate, 87 hydrothermal syntheses and structures of reduced and mixed valence polyoxovanadium clusters with capped structure and magnetic properties of a syn—anti carboxylate cage cores: K,[H,,(AsO),(AsO,)V,IYV,"’O36]-12H,O and bridged linear trinuclear copper(II) complex with ferro- Rb,[(As,O),(VO)2V12'¥03,Cl]-2H,O, 199 magnetic exchange interaction, 115 a bis(u-isocyanide diiron) complex as chelating ligand structures and magnetic properties of Co(II)Cu(II) and towards iron(II), palladium(I]), zinc(II) and cadmium- Ni(II)Cu(II) compounds incorporating the obp= oxamidobis(N,N’-propionato) ligand, 271 (II). X-ray structural assessment of a novel isocyanide bridging mode, 207 synthesis, characterization, crystal structures and magnetic properties of di- and polynuclear bis(y-3-pyridin-2-yl- polyethylene glycol complexation of Cd?*. Structures of triethylene glycol complexes of CdCl,, CdBr, and Cdl), 1,2,4-triazolato)copper(II) compounds containing 225 N-methylimidazole, pyrazole or 4,4’-bipyridine as co-ligands, 289 synthesis, structure and magnetism of a tetranuclear Fe(III) complex containing an [Fe,(j3-O),]*®* core, 241 Croconate complexes syntheses and characterization of cubane-type clusters, molecular structure and magnetic properties of copper(II), [Mo,S,(edta)2]"~ (2 =2-4), [Mo,S,(H,0),2]"* (=4-6) manganese(II) and iron(II) croconate tri-hydrate, 87 and [Mo,S,(NH3),2]**. X-ray structures of Na,- Crystal structures [Mo,S,(edta),]-6H,O, Ca, ;[Mo,S,(edta),]-13H,O, tetrahedrane cluster and phosphorus ligand activation in Mg,[Mo,S,(edta),]-20H,O, [Mo,S,(H,0)2}(CH3C.H,- the reaction between PhCCo,(CO), and 2,3-bis- SO;);-14H,O and [Mo,S,(NH3),2]Cl,-7H,O, 251 (diphenylphosphino)maleic anhydride. Molecular struc- ture of Co;(CO)¢(j2-7?-n'-C(Ph)C=C(PPh,)C(O)OC- structures and magnetic properties of Co(II)Cu(II) and (O))(u2-PPhz), 1 Ni(II)Cu(II) compounds incorporating the obp= reactions of the electron-rich triply bonded dirhenium(II) oxamidobis(N,N’-propionato) ligand, 271 structural and magnetic characterization of an adamantane- complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. like complex ion of chromium(III) and 1,3,5-triamino- Part II. The synthesis and structural characterization cyclohexane, [Cr,(tach),(OH),], 281 of the complexes ReOCl,(dppmO) (dppmO= Ph,PCH,P(O)Ph,) and Re,(u-O)CI,(u-dppm),, 23 synthesis, characterization, « ystal structures and magnetic halide derivatives of palladium—gold cluster compounds. properties of di- and polynuclear bis(-3-pyridin-2-yl- 1,2,4-triazolato)copper(II) compounds containing X-ray crystal and molecular structure of (I)Pd(AuPPh;),- (Aul),, 31 N-methylimidazole, pyrazole or 4,4’-bipyridine as a polymeric tetraimine Schiff base macrocyclic complex of co-ligands, 289 reaction of unsymmetrical thioalkynes R-C=C-SC,H,, silver(I), 65 reaction of NO with Cp*;Co3(u-H), preserves the tricobalt R=CH;, C.Hs, with iron and ruthenium carbonyls. cluster and produces Cp*3;Co;(13-NO),, 81 How to build a polynuclear compound using the C-S molecular structure and magnetic properties of copper(II), cleavage, 323 manganese(II) and iron(II) croconate tri-hydrate, 87 synthesis, characterization, and X-ray crystal structure of a preparation of the new species [W3(3-O)(u-Cl)(u- trimetallic diporphyrin complex, 337 O,CMe),Cl;]~ and [Mo3(j3-O)(-Cl),(4-O,CMe),Cl,- Cubane-type complexes (PMe;)2]~ that bracket, structurally, the very common syntheses and characterization of cubane-type clusters, M;(43-O)(-X)3(4-O2CR;)3L, type of cluster compound, [Mo,S,(edta),}"" (n=2-4), [Mo,S,(H,0),2]"* (n=4-6) 95 and [Mo,S,(NH3),2]**. X-ray structures of Na,- pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear [Mo,S,(edta).]-6H,0, Ca; ;[Mo,S,(edta),]-13H,O, [Pt,Hg.] anionic complexes containing unbridged Pt-Hg Mg,[Mo,S,(edta),]-20H,O, [Mo,S,(H2O),2](CH3C.H,- bonds and OH bridges, 105 SO;)5-14H,O and [Mo,S,(NH3),2]Cl,-7H,O, 251 Cyanide complexes Gold complexes binding modes of cyanide at trinuclear clusters. Crystal halide derivatives of palladium-gold cluster compounds. structure of [Pt3;(43-CO)(CN)(dppm),][PF,], 191 X-ray crystal and molecular structure of (I)Pd(AuPPh;,),- Cyclopentadienyl complexes (Aul),, 31 reaction of NO with Cp*;Co;(y-H), preserves the tricobalt cluster and produces Cp*;Co3(13-NO),, 81 Halide complexes Diazoalkane complexes halide derivatives of palladium-gold cluster compounds. retention of dinitrogen in the reactions of some diazo- X-ray crystal and molecular structure of (I)Pd(AuPPh;),- alkanes with a dirhodium complex. Crystal and molecu- (Aul),, 31 lar structures of (7-C;H;)2Rh.{CF3;C,CF;-CO-N,CRR’}, polyethylene glycol complexation of Cd?*. Structures of RR’=MePh and (t-Bu),, 139 triethylene glycol complexes of CdCl,, CdBr, and Cdl,, Dinuclear complexes 225 reactions of the electron-rich triply bonded dirhenium(I]) Hydroborate complexes complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. borane cluster photochemistry. 2. Photochemical alcoholysis Part II. The synthesis and structural characterization of the octahydrotriborate(1—) anion, 317 of the complexes ReOCl,(dppmO) (dppmO= Hydroxo complexes Ph,PCH,P(O)Ph2) and Re2(u-O)CI,(u-dppm),, 23 pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear further considerations on the structure and bonding in [Pt,Hg2] anionic complexes containing unbridged Pt-Hg edge-sharing bioctahedral complexes, 123 bonds and OH bridges, 105 retention of dinitrogen in the reactions of some diazo- alkanes with a dirhodium complex. Crystal and molecu- lar structures of (7-Cs;H;),Rh2{CF3;C,CF;-CO-N,CRR’}, Infrared spectroscopy RR’=MePh and (t-Bu),, 139 interpretation of the »(CO) vibrational spectra of cluster palladium-thallium interactions in dinuclear complexes with compounds: Ru;(CO)o(413-77:77:n?-C,H,), 69 structural components that place the two metal centers interpretation of the »(CO) vibrational spectra of cluster in close proximity, 149 compounds: tetrahedral anions [Fe,Ir,(CO),.]*~, dinuclear nickel(II) complexes of a series of dinucleating [HFe,Ir,(CO),2]~ and [FelIr,(CO),.], 75 macrocycles with similar or dissimilar coordination sites: Ion complexes synthesis, structure and physicochemical property, 183 size and shape of molecular ions and their relevance to electrochemical behaviour of tropone diiron pentacarbonyl the packing of the ‘soft salts’, 5 complexes, Fe,(CO),;[(RC,R);CO] (R=Me, Et, n-Pr). Iridium complexes Formation of a carbon-carbon bond upon reduction, interpretation of the »(CO) vibrational spectra of cluster 311 compounds: tetrahedral anions [Fe,Ir,(CO),|*~, Dithiocarbamato complexes [HFe,Ir,(CO),2]~ and [FelIr,(CO),.], 75 new insights into the constitution of solutions containing selective substitution and oxidative addition reactions at labile, polynuclear compounds: an electrospray mass the iridium vertex in [Re;C(CO),,Ir(CsH;,)(CO)?~ and spectrometric study of mercury- and cadmium-rich related clusters, 303 dithiocarbamato cations, 233 Iron complexes iron(II) and sulfate binding by the binucleating ligands Electrochemistry O-BISDIEN, O-BISTREN and O-BISBAMP, 15 syntheses and characterization of cubane-type clusters, interpretation of the »(CO) vibrational spectra of cluster [Mo,S,(edta)}"~ (n=2-4), [Mo,S,(H20),2]"* (1 =4-6) compounds: tetrahedral anions [Fe,Ir,(CO),.}~, and [Mo,S,(NH3),.]**. X-ray structures of Nap- [HFe,Ir(CO),2.]~ and [FelIr,(CO),.], 75 [Mo,S,(edta)]-6H,O, Ca, ;[Mo,S,(edta),]-13H,O, molecular structure and magnetic properties of copper(II), Mg.[Mo,S,(edta)2]-20H,O, [Mo,S,(H2O),2](CH3C.H,- manganese(II) and iron(II) croconate tri-hydrate, 87 SO3)5-14H,O and [Mo,S,(NH3),2]C7lH,2-O, 251 a bis(y-isocyanide diiron) complex as chelating ligand electrochemical behaviour of tropone diiron pentacarbonyl complexes, Fe,(CO),[(RC,R)3;CO] (R=Me, Et, n-Pr). towards iron(II), palladium(II), zinc(II) and cadmium- Formation of a carbon-carbon bond upon reduction, (II). X-ray structural assessment of a novel isocyanide bridging mode, 207 311 synthesis, structure and magnetism of a tetranuclear Electronic structures syntheses and characterization of cubane-type clusters, Fe(III) complex containing an [Fe,(y3-O),]** core, 241 [Mo,S,(edta),]"~ (n=2-4), [Mo,S,(H;0),.J"* (n=4-6) electrochemical behaviour of tropone diiron pentacarbonyl and [Mo,S,(NH3),.]**. X-ray structures of Na,- complexes, Fe,(CO),[(RC,R);CO] (R=Me, Et, n-Pr). [Mo,S,(edta)2]-6H,O, Ca, 5[Mo,S,(edta),]-13H,O, Formation of a carbon-carbon bond upon reduction, 311 Mg,[Mo,S,(edta)2]-20H,O, [Mo,S,(H2O);2](CH3C.H,- SO3);:14H,O and [Mo,S,(NH3)j2]Cl7H,2-O, 251 reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, R=CH;, C,H;, with iron and ruthenium carbonyls. Germanium complexes How to build a polynuclear compound using the C-S synthesis and reactivity of 1,1,2,2-tetraphenyl 1,2-digermyl- cleavage, 323 dilithium, 51 Isocyanide complexes Glycol complexes a bis(u-isocyanide diiron) complex as chelating ligand polyethylene glycol complexation of Cd?*. Structures of towards iron(II), palladium(I]), zinc(II) and cadmium- triethylene glycol complexes of CdCl,, CdBr, and Cdl), (II). X-ray structural assessment of a novel isocyanide 225 bridging mode, 207 346 Kinetics and mechanism and [Mo,S,(NH;),.]** X-ray structures of Na,- [Mo,S,(edta),]-6H,O, Ca;< [Mo,S,(edta),]-13H,0, substitution of methanol-d, for the coordinated water in Mg,[Mo,S,(edta)]-20H,O, [Mo,S,(H,0);2](CHsC.H,- the trinuclear complexes, [M3(3-O)(u-CH;COO),- (H,O)3]* (M3;=Ru3, Rh; or Ru,Rh) in methanol-d,, SO3);°14H,O and [Mo,S,(NH3);2]Cl,-7H2O, 251 175 Nickel complexes Macrocyclic ligand complexes dinuclear nickel(II) complexes of a series of dinucleating a polymeric tetraimine Schiff base macrocyclic complex of macrocycles with similar or dissimilar coordination sites: silver(I), 65 synthesis, structure and physicochemical property, 183 dinuclear nickel(II) complexes of a series of dinucleating clusters in the step-by-step growth of solids, 219 macrocycles with similar or dissimilar coordination sites: structures and magnetic properties of Co(II)Cu(II) and synthesis, structure and physicochemical property, 183 Ni(II)Cu(II) compounds incorporating the obp= Magnetism oxamidobis(N,N’-propionato) ligand, 271 molecular structure and magnetic properties of copper(II), synthesis, characterization, and X-ray crystal structure of a manganese(II) and iron(II) croconate tri-hydrate, 87 trimetallic diporphyrin complex, 337 structure and magnetic properties of a syn-anti carboxylate Nitrosyl complexes bridged linear trinuclear copper(II) complex with ferro- reaction of NO with Cp*,;Co3(u-H), preserves the tricobalt magnetic exchange interaction, 115 cluster and produces Cp*;Co3(3-NO),, 81 synthesis, structure and magnetism of a tetranuclear NMR Fe(III) complex containing an [Fe,(3-O),]** core, 241 a reinvestigation of isomerism in the Dawson structure: structures and magnetic properties of Co(II)Cu(II) and syntheses and '*W NMR structural characterization of Ni(II)Cu(II) compounds incorporating the obp= three new polyoxotungstates [X,W,s0,.]° (X=PY, oxamidobis(N,N’-propionato) ligand, 271 As’), 41 structural and magnetic characterization of an adamantane- like complex ion of chromium(III) and 1,3,5-triamino- Oxo complexes cyclohexane, [Cr,(tach),(OH),], 281 reactions of the electron-rich triply bonded dirhenium(II) synthesis, characterization, crystal structures and magnetic complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. properties of di- and polynuclear bis(-3-pyridin-2-yl- Part II. The synthesis and structural characterization 1,2,4-triazolato)copper(II) compounds containing of the complexes ReOCl,(dppmO) (dppmO= N-methylimidazole, pyrazole or 4,4’-bipyridine as Ph,PCH,P(O)Ph,) and Re2(u-O)Cl,(u-dppm),, 23 co-ligands, 289 a reinvestigation of isomerism in the Dawson structure: Manganese complexes syntheses and 'W NMR structural characterization of molecular structure and magnetic properties of copper(II), three new polyoxotungstates [X,W,s0,.]° (X=PY, manganese(II) and iron(II) croconate tri-hydrate, 87 As’), 41 formation of a high valent di-~-oxo manganese dimer in preparation of the new species [W3(13-O)(u-Cl)2(p- aqueous solution, 135 O,CMe),Cl3]~ and [Mo3(13-O)(-Cl)4(u-O,CMe),Cl,- Mass spectrometry (PMe;)2]~ that bracket, structurally, the very common new insights into the constitution of solutions containing M3(3-O)(-X)3(4-O2CR3)3L, type of cluster compound, labile, polynuclear compounds: an electrospray mass 95 spectrometric study of mercury- and cadmium-rich formation of a high valent di-~-oxo manganese dimer in dithiocarbamato cations, 233 aqueous solution, 135 Mercury complexes hydrothermal syntheses and structures of reduced and pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear mixed valence polyoxovanadium clusters with capped [Pt,Hg.] anionic complexes containing unbridged Pt-Hg cage cores: K3[H,,(AsO).(AsO,)V¢'YV,”O3.]-12H,O and bonds and OH bridges, 105 Rb.[(As,0),(VO),V;2'¥O3¢Cl]-2H,O, 199 new insights into the constitution of solutions containing synthesis, structure and magnetism of a tetranuclear labile, polynuclear compounds: an electrospray mass Fe(III) complex containing an [Fe,(j3-O),]** core, 241 spectrometric study of mercury- and cadmium-rich dithiocarbamato cations, 233 Palladium complexes Metal complexes halide derivatives of palladium-gold cluster compounds. size and shape of molecular ions and their relevance to X-ray crystal and molecular structure of (I)Pd(AuPPh;),- the packing of the ‘soft salts’, 5 (Aul),, 31 metal cluster topology. 14. Fusion of octahedra in metal palladium-thallium interactions in dinuclear complexes with carbonyl clusters, 57 structural components that place the two metal centers a bis(y-isocyanide diiron) complex as chelating ligand in close proximity, 149 towards iron(II), palladium(II), zinc(II) and cadmium- clusters in the step-by-step growth of solids, 219 (II). X-ray structural assessment of a novel isocyanide synthesis, characterization, and X-ray crystal structure of a bridging mode, 207 trimetallic diporphyrin complex, 337 Molybdenum complexes Phospha-alkyne complexes preparation of the new species [W3(3-O)(u-Cl)2(u- synthesis and *‘P and Pt NMR characterisation of the O,CMe),Cl]~ and [Mo3(s13-O)(u-Cl)4(4-O2CMe),Cl.- first binuclear platinum(I) complex [Pt,Cl,(u-dppm),(u- (PMe;).]” that bracket, structurally, the very common Bu'CP)] containing a p-parallel ligated phospha-alkyne, M(43-O)(u-X)3(4-O2CR;)3L, type of cluster compound, 265 95 Phosphine complexes syntheses and characterization of cubane-type clusters, dirhenium complexes of the tripodal phosphine CH;C- [Mo,S,(edta),]"~ (n=2-4), [Mo,S,(H2O),2]"* (n=4-6) (CH,PPh,2); (triphos). The isolation and characterization of the confacial bioctahedral species [(triphos)- Rhenium complexes Re(yu-X)3Re(triphos)]"* (m=1 or 0), 157 reactions of the electron-rich triply bonded dirhenium(II) Photochemistry complexes Re,X,(u-dppm), (X=Cl, Br) with dioxygen. borane cluster photochemistry. 2. Photochemical alcoholysis Part II. The synthesis and structural characterization of the octahydrotriborate(1—) anion, 317 of the complexes ReOCl,(dppmO) (dppmO = Platinum complexes Ph,PCH,P(O)Ph,) and Re2(u-O)Cl,(u-dppm),, 23 synthesis and reactivity of 1,1,2,2-tetraphenyl 1,2-digermyl- dirhenium complexes of the tripodal phosphine CH,C- dilithium, 51 (CH,PPh,); (triphos). The isolation and characterization pentafluorophenyl trinuclear [Pt,Hg] and hexanuclear of the confacial bioctahedral species [(triphos)- [Pt,Hg,] anionic complexes containing unbridged Pt-Hg Re(u-X)3Re(triphos)}"* (n=1 or 0), 157 bonds and OH bridges, 105 selective substitution and oxidative addition reactions at binding modes of cyanide at trinuclear clusters. Crystal the iridium vertex in [Re;C(CO),,Ir(CsH,,)(CO)}*~ and structure of [Pt;(43;-CO)(CN)(dppm)3][PF,], 191 related clusters, 303 synthesis and *'P and '*Pt NMR characterisation of the Rhodium complexes first binuclear platinum(I) complex [Pt,Cl,(u-dppm).(u- retention of dinitrogen in the reactions of some diazo- Bu'CP)] containing a p-parallel ligated phospha-alkyne, alkanes with a dirhodium complex. Crystal and molecu- 265 lar structures of (7-C;H;),Rh,{CF;C,CF,-CO-N,CRR’}, Polyaza macrocyclic complexes RR’=MePh and (t-Bu), 139 iron(II) and sulfate binding by the binucleating ligands substitution of methanol-d, for the coordinated water in O-BISDIEN, O-BISTREN and O-BISBAMP, 15 the trinuclear complexes, [M3(3-O)(u-CH;COO),- Polydentate ligand complexes (H,O)3]* (M3;=Ru;, Rh; or Ru,Rh) in methanol-d,, dirhenium complexes of the tripodal phosphine CH,C- 175 (CH,PPh,); (triphos). The isolation and characterization Ruthenium complexes of the confacial bioctahedral species [(triphos)- interpretation of the v(CO) vibrational spectra of cluster Re(u-X)3Re(triphos)]"* (n=1 or 0), 157 compounds: Ru3(CO)>(13-77:77:?-C,H,), 69 electrochemical behaviour of tropone diiron pentacarbonyl substitution of methanol-d, for the coordinated water in complexes, Fe,(CO);[(RC,R);CO] (R=Me, Et, n-Pr). the trinuclear complexes, [M3(3-O)(u-CH;COO),- Formation of a carbon-carbon bond upon reduction, (H,0)3]* (M3;=Ru;, Rh; or Ru,Rh) in methanol-d,, 311 175 Polynuclear complexes reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, a reinvestigation of isomerism in the Dawson structure: R=CH;, C;H;, with iron and ruthenium carbonyls. syntheses and '°W NMR structural characterization of How to build a polynuclear compound using the C-S three new polyoxotungstates [X2W1s0,.]° (X=PY, cleavage, 323 As’), 41 pentafluoropheny] trinuclear [Pt,Hg] and hexanuclear Schiff base complexes [Pt,Hg.] anionic complexes containing unbridged Pt-Hg a polymeric tetraimine Schiff base macrocyclic complex of bonds and OH bridges, 105 silver(I), 65 structure and magnetic properties of a syn-anti carboxylate Silver complexes bridged linear trinuclear copper(II) complex with ferro- a polymeric tetraimine Schiff base macrocyclic complex of magnetic exchange interaction, 115 silver(I), 65 new insights into the constitution of solutions containing Solid state labile, polynuclear compounds: an electrospray mass size and shape of molecular ions and their relevance to spectrometric study of mercury- and cadmium-rich the packing of the ‘soft salts’, 5 dithiocarbamato cations, 233 Stability constants synthesis, structure and magnetism of a tetranuclear iron(II) and sulfate binding by the binucleating ligands Fe(III) complex containing an [Fe,(j13-O),]** core, 241 O-BISDIEN, O-BISTREN and O-BISBAMP, 15 structural and magnetic characterization of an adamantane- Structure and bonding like complex ion of chromium(III) and 1,3,5-triamino- further considerations on the structure and bonding in cyclohexane, [Cr,(tach),(OH),], 281 edge-sharing bioctahedral complexes, 123 reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, Sulfur complexes R=CH;, C,Hs, with iron and ruthenium carbonyls. syntheses and characterization of cubane-type clusters, How to build a polynuclear compound using the C-S cleavage, 323 [Mo,S,(edta),]"" (”=2-4), [Mo,S,(H20),2]"* (n=4-6) and [Mo,S,(NH3),.]**. X-ray structures of Na,- Porphyrin complexes [Mo,S,(edta)2]-6H,0, Ca, ;[Mo,S,(edta),]-13H,O, synthesis, characterization, and X-ray crystal structure of a Mg,[Mo,S,(edta),] -20H,0, [Mo,S,(H20);2](CH3CsH,- trimetallic diporphyrin complex, 337 SO;);-14H,O and [Mo,S,(NH3);2]Cl,-7H,O, 251 Potentiometry iron(II) and sulfate binding by the binucleating ligands O-BISDIEN, O-BISTREN and O-BISBAMP, 15 Tellurium complexes clusters in the step-by-step growth of solids, 219 Raman spectroscopy Thallium complexes interpretation of the (CO) vibrational spectra of cluster palladium-thallium interactions in dinuclear complexes with compounds: Ru3(CO)o(3-7:77:7?-CgH,), 69 structural components that place the two metal centers interpretation of the (CO) vibrational spectra of cluster in close proximity, 149 compounds: tetrahedral anions [Fe,Ir,(CO),2]”~, a chain copolymer from WCI,(PMe,Ph), and [TIOCH,- [HFe,Ir,(CO),.]~ and [FelIr,(CO),2], 75 CF3],, 165 348 Thiazole complexes (H,O)3]* (M3;=Ru;, Rh; or Ru,Rh) in methanol-d,, synthesis, characterization, crystal structures and magnetic 175 properties of di- and polynuclear bis(u-3-pyridin-2-yl- binding modes of cyanide at trinuclear clusters. Crystal 1,2,4-triazolato)copper(II) compounds containing structure of [Pt3(43-CO)(CN)(dppm)3][PF.], 191 N-methylimidazole, pyrazole or 4,4’-bipyridine as Tungsten complexes co-ligands, 289 a reinvestigation of isomerism in the Dawson structure: Thioalkyne complexes syntheses and '*W NMR structural characterization of reaction of unsymmetrical thioalkynes R-C=C-SC,Hs, three new polyoxotungstates [X;W sO0,2]° (X=PY, R=CH;, C,Hs, with iron and ruthenium carbonyls. As’), 41 How to build a polynuclear compound using the C-S preparation of the new species [W3(13-O)(u-Cl)2(y- cleavage, 323 O,CMe),4Cl3]~ and [Mo3(43-O)(-Cl),(u-O,CMe),Cl,- Transition metal complexes (PMe;)2]” that bracket, structurally, the very common further considerations on the structure and bonding in M;(413-O)(u-X)3(u4-O2CR3)3L, type of cluster compound, edge-sharing bioctahedral complexes, 123 Tridentate ligand complexes a chain copolymer from WCI,(PMe,Ph), and [TIOCH,- structural and magnetic characterization of an adamantane- CF3],, 165 like complex ion of chromium(III) and 1,3,5-triamino- cyclohexane, [Cr,(tach),(OH)<,], 281 Trinuclear complexes Vanadium complexes reaction of NO with Cp*;Co3(u-H), preserves the tricobalt hydrothermal syntheses and structures of reduced and cluster and produces Cp*3;Co3(u3-NO)., 81 mixed valence polyoxovanadium clusters with capped substitution of methanol-d, for the coordinated water in cage cores: K,[H;.(AsO),(AsO,)V6'YV,”O3,]-12H,O and the trinuclear complexes, [M3(3-O)(u-CH;COO),- Rb;[(As2O),(VO)2V12'¥O3¢Cl] -2H2O, 199

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