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Inorganica Chimica Acta 1993: Vol 203 Index PDF

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Inorganica Chimica Acta, 203 (1993) 265 265 Author Index of Volume 203 Addison, A. W., 29 de Haar, V. W., 157 Kraakman, M. J. A., 129, Peterson, L. K., 87 Al-Baker, S. A., 121 de Koning, T. C., 145 145, 157 Piraino, P., 101 Alcock, N. W., 81 de Lange, P. P. M., 145 Poli, R., 223 Alessio, E., 205 Duesler, E. N., 11 Labella, L., 55 Raithby, P. R., 93 Alzuet, G., 257 Labisbal, E., 67 Rheingold, A. L., 223 Amano, R., 9 Edwards, A. J., 93 Leciejewicz, J., 81 Rodriguez, T., 1 Andersson, C., 235 Elsevier, C. J., 129, 157 Lever, A. B. P., 171 Romero, J., 67 Andrade, C. G., 115 Englert, U., 67 Licoccia, S., 107 Attia, W. M., 205 English, R. B., 219 Lopez Solera, M.-I., 93 Sawada, K., 61 Azevedo Batista, A., 185 Ernsting, J.-M., 129 Lo Schiavo, S., 101 Shang, M., 55 Ertan, A., 21 Lucken, E. A. C., 239 Shibata, A., 37 Balducci, G., 205 Evans, D. J., 253 Lumetta, G. J., 121 Shiokawa, Y., 9 Sinn, E., 51 Banbury, F. A., 93 Eve, D. J., 219 Lutman, A., 205 Snaith, R., 93 Bandini, A. L., 127 Solans, X., 229, 257 Banovetz, J. P., 179 Macias, A., 67 Fackler, Jr., J. P., 73 Sousa, A., 1, 67 Bastida, R., 1 Mak, T. C. W., 97 Fanciullo, M., 107 Spek, A. L., 145, 157 Becker, C. A. L., 175 Mailer, L., 21 Fenton, D. E., 1, 67 Speroni, F., 127 Borras, J., 257 Manzur, J., 73 Ferrer, S., 257 Spodine, E., 73 Boschi, T., 107 Martinez, M., 229 Font-Bardia, M., 229, 257 Stalke, D., 93 Bould, J., 193 McCabe, D. J., 11 Staples, R. J., 73 Bovino, S. C., 179 Meline, R. L., 11 Straus, D. A., 179 Garcia-Vazquez, J. A., 67 Bruni, S., 127 Mestroni, G., 205 Suzuki, T., 61 Garland, M. T., 73 Butcher, R. J., 51 Milletti, M. C., 43 Gomez, C., 67 Miyamoto, H., 61 Thornton-Pett, M., 193 Gonzalez, G., 229 Tresoldi, G., 101 Calligaris, M., 205 Miyoshi, K., 249 Goubitz, K., 129 Trzcinska-Bancroft, B., 73 Cariati, F., 127 Mizuta, T., 249 Centeno Cordeiro, L. A., Moberg, C., 21 Vrieze, K., 129, 145, 157 185 Handa, M., 61 Morgante, E., 107 Howells, A. R., 43 Wang, J., 249 Chen, X.-M., 97 Huang, S., 87 Warnmark, K., 21 Coates, G. W., 179 Nasir, M. S., 5 Waymouth, R. M., 179 Conary, G. S., 11 Whitehead, M. A., 239 Cotton, F. A., 55 Jacobson, R. R., 5 Oliva, G., 185 Wright, D. S., 93 Crivelli, I. G., 115 Jeliazkova, B. G., 201 Owens-Waltermire, B. E., Crook, J. E., 193 223 Xu, Q., 121 Cs6regh, I., 21 Karlin, K. D., 5 Yip, W.-H., 97 Kemp, T. J., 81 Paine, R. T., 11 Yordanov, N. D., 201 Darby, W. L., 51 Kennedy, J. D., 193 Pang, L., 239 Yukawa, Y., 61 Datta, T., 55 Khokhar, A. R., 121 Paolesse, R., 107 Davidson, M. G., 93 Kitamura, Y., 37 Pavlishchuk, V. V., 29 Ziller, J. W., 179 de Blas, A., 1 Kooijman, H., 145 Persson, C., 235 Zubieta, J., 5 Elsevier Sequoia Inorganica Chimica Acta, 203 (1993) 267-271 267 Subject Index of Volume 203 Acetylacetonato complexes fluxional behaviour of the carbonyl ligands in formation of acetylacetonato iron complexes in acetonitrile Fe,Ru(CO),9(R-Pyca), 129 and their resonance Raman spectra, 61 synthesis of the monohydride complexes Alkyne complexes HRu,(X)(CO),(‘Pr-N = CHCH = N-'Pr) (X=Cl, I); C-C coupling and C-H activation occurring in reactions of hydrogenation of the central C—C bond of the coordi- FeRu(CO),('Pr-Pyca) (‘Pr-Pyca = C;H,N-2-CH = N-'Pr) nated a-diimine ligands. X-ray single crystal structure of with activated alkynes RC=CR’ (R=R’=C(O)OMe; HRu,(Cl)(CO),(‘Pr-N = CHCH = N-'Pr), 157 R=H, R’=C(O)Me), 145 electrochemical formation and X-ray structure of the five- Amide complexes coordinated ruthenium(II) [RuCl(dppp),.](PF,) complex, coordination behaviour of methazolamide [N(-4-methyl-2- 185 sulfamoyl-A?-1,3,4-thiadiazolin-5-ylidene)] acetamide, an °C] nuclear quadrupole resonance and crystal structures of inhibitor of carbonic anhydrase enzyme. Synthesis, small guest molecules in tris(2,4-pentanedionate)M(III) crystal structure and properties of inclusion compounds, 239 bis(methazolamidate)tetrammine nickel(II), 257 Binuclear complexes Amine complexes heterobinuclear (Cu-M) complexes containing an endoge- preparation and the covalent hydration of a hexafluoro-2,4- nous benzimidazolate bridge, 1 pentanedionatotetraaminecobalt(III]) complex, 37 copper complexes with di-pyridylmethane. The synthesis Calcium complexes and X-ray structures of bis(di-pyridylmethane)copper(I) a thiouracil—-Ca?* complex containing two tautomeric forms perchlorate, bis(di-pyridylmethane)copper(II) perchlorate of the thiouracilyl anion: synthesis and crystal structure and dichloro-yu-dichloro-bis(di-pyridyl- of [(thiouracilyl),Ca-2DMSO-H,O],, 93 methane)dicopper(II), 73 Carbon ligand complexes crystal structures of bis(L(— )prolinato-N)(trans-R,R-1,2-di- a revision on gold(I)-carbon stretching frequencies, 127 aminocyclohexane)platinum(II) and bis(L{ — )prolinato- Carbonyl complexes N)-(cis-1,2-diaminocyclohexane)platinum(II) complexes, 121 hydrogen migration in Fe3(CO),CHy,, 43 Amino acid complexes preferential displacement of fluorophosphine ligands from fluorophosphinetungstencarbonyl complexes by reaction mixed amino acid binding of Fe,S, clusters: a ‘H NMR study, 253 with trimethylamine oxide, 87 Ammine complexes preparation of the new heteronuclear a-diimine complexes kinetic studies on sterically hindered pentaaminecobalt(III) FeRu(CO),(R-Pyca) and Fe,Ru(CO),9(R-Pyca) complexes. Synthesis, anation reactions and crystal (R-Pyca =C;H,N-2-CH=NR); “°C NMR study of the structure of [Co(EtNH,);H,O](ClO,);-2H,O, 229 fluxional behaviour of the carbonyl ligands in coordination behaviour of methazolamide [N(-4-methy]-2- Fe,Ru(CO),9(R-Pyca), 129 sulfamoyl-A?-1,3,4-thiadiazolin-5-ylidene)] acetamide, an C-C coupling and C-H activation occurring in reactions of inhibitor of carbonic anhydrase enzyme. Synthesis, FeRu(CO),(‘Pr-Pyca) (‘Pr-Pyca = C;H,N-2-CH = N-'Pr) crystal structure and properties of with activated alkynes RC=CR’ (R=R’=C(O)OMe; bis(methazolamidate)tetrammine nickel(II), 257 R=H, R’=C(O)Me), 145 Aqua complexes Carboxylate complexes the molecular structure of sodium a polymeric silver(I) complex containing triply carboxylato- (aqua)(ethylenediaminetetraacetato)-titanate(III) O,O'-bridged dinuclear cores, dihydrate, Na[Ti(H,O)(edta)]-2H,O, as determined by [{Ag,(Me3NCH,CO>)¢},,](ClO4)a n, 97 X-ray crystal analysis, 249 Chelate complexes a volatile thallium chelate, (2,2,6,6-tetramethyl-3,5-heptane- dionato)TI(I), 9 Bidentate ligand complexes preparation and the covalent hydration of a hexafluoro-2,4- a volatile thallium chelate, (2,2,6,6-tetramethyl-3,5-heptane- pentanedionatotetraaminecobalt(III) complex, 37 dionato)TI(I), 9 copper complexes with di-pyridylmethane. The synthesis preparation and the covalent hydration of a hexafluoro-2,4- and X-ray structures of bis(di-pyridylmethane)copper(I) pentanedionatotetraaminecobalt(III) complex, 37 formation of acetylacetonato iron complexes in acetonitrile perchlorate, bis(di-pyridylmethane)copper(II) perchlorate and their resonance Raman spectra, 61 and dichloro-y-dichloro-bis(di-pyridyl- copper complexes with di-pyridylmethane. The synthesis methane)dicopper(II), 73 and X-ray structures of bis(di-pyridylmethane)copper(I) crystal structures of bis(L( — )prolinato-N)(trans-R,R-1,2-di- perchlorate, bis(di-pyridylmethane)copper(II) perchlorate aminocyclohexane)platinum(II) and bis(L( — )prolinato- and dichloro-y-dichloro-bis(di-pyridyl- N)-(cis-1,2-diaminocyclohexane)platinum(II) complexes, methane)dicopper(II), 73 121 preparation of the new heteronuclear a-diimine complexes synthesis of the monohydride complexes FeRu(CO),(R-Pyca) and Fe,Ru(CO),o(R-Pyca) HRu,(X)(CO),('Pr-N = CHCH = N-'Pr) (X=Cl, 1); (R-Pyca =C,;H,N-2-CH=NR); °C NMR study of the hydrogenation of the central C-C bond of the coordi- Elsevier Sequoia 268 nated a-diimine ligands. X-ray single crystal structure of octadecadehydro-2,16,22,23-tetraazatetra- HRu,(Cl)(CO),(‘Pr-N = CHCH = N-'Pr), 157 cyclo[15.4.0.1*%.1!°*]tricosane, 21 electrochemical formation and X-ray structure of the five- synthesis, spectroscopic and redox behaviour of copper(II) coordinated ruthenium(II) [RuCl(dppp).](PF,) complex, complexes with quinquedentate thiaaza ligands, 29 185 first observation of a-bonding in triple decker pyrrolyl 35C] nuclear quadrupole resonance and crystal structures of complexes. Crystal structure of [(7°-tetramethy]l- small guest molecules in tris(2,4-pentanedionate)M{(III) pytrolyl)Co],(C,Et,B3H3), 51 inclusion compounds, 239 stabilizing of the Ru,°* core. Use of highly charged Chromium complexes ligands such as sulfate and phosphate, 55 crystal structures of (7°-C;Me;)(7°-2,4-C,H,;)Cr and (7°- the synthesis of zinc(II) complexes of 2-(2-mercapto- C;Me;)(7°-2,4-C7H,,)CrCO. An example of ‘S’ 2,4-di- phenyl)-imino-phenol by electrochemical cleavage of a methylpentadienyl ligand geometry, 179 disulfide bond; the crystal structure of{(2,2’-bipyri- Cluster complexes dine)[2-(2-mercaptophenyl)imino- phenoxy]}zinc(II), 67 ten-vertex metallaborane clusters: action as a B-frame sup- copper complexes with di-pyridylmethane. The synthesis port for heterobimetallic species: [7,7-(PMe3)2-9,9,9- and X-ray structures of bis(di-pyridylmethane)copper(I) H(PPh,)(Ph,P-ortho-C,H,)-nido-7,9-PtIrB,H,9-4 |] and perchlorate, bis(di-pyridylmethane)copper(II) perchlorate related compounds, 193 and dichloro-y-dichloro-bis(di-pyridyl- mixed amino acid binding of Fe,S, clusters: a ‘H NMR methane)dicopper(II), 73 study, 253 crystal and molecular structures of sulfonato complexes of Cobalt complexes dioxouranium(VI) ion: role of steric effects on coordi- preparation and the covalent hydration of a hexafluoro-2,4- nation structure, 81 pentanedionatotetraaminecobalt(III) complex, 37 a thiouracil—Ca** complex containing two tautomeric forms first observation of a-bonding in triple decker pyrrolyl of the thiouracilyl anion: synthesis and crystal structure complexes. Crystal structure of [(7°-tetramethyl- of [(thiouracilyl),Ca-2DMSO-H,O}],, 93 pyrrolyl)Co],(C,Et,B3H3), 51 a polymeric silver(I) complex containing triply carboxylato- synthesis and characterization of cobalt(III) complexes of O,O’-bridged dinuclear cores, meso-phenyl-substituted corroles, 107 [{Ag,(Me3NCH,CO>)¢},]}(C1O4)a n, 97 synthesis of paramagnetic tetrakis(benzylisocyanide)bis(tri-p- crystal structures of bis(L({ — )prolinato-N)(trans-R,R-1,2-di- tolylarsine oxide)cobalt(III) tetrafluoroborate. An exam- aminocyclohexane)platinum(II) and bis(L( — )prolinato- ple of oxidation of ligand and metal in reaction of N)-(cis-1,2-diaminocyclohexane)platinum(II) complexes, pentakis(arylisocyanide)cobalt(II) with triarylarsine, 121 175 preparation of the new heteronuclear a-diimine complexes kinetic studies on sterically hindered pentaaminecobalt(III) FeRu(CO),(R-Pyca) and Fe,Ru(CO),9(R-Pyca) complexes. Synthesis, anation reactions and crystal (R-= CP;H,yN-2c-CHa=NR ); “°C NMR study of the structure of [Co(EtNH,);H,O](ClO,)3-2H,O, 229 fluxional behaviour of the carbonyl ligands in Copper complexes Fe,Ru(CO);9(R-Pyca), 129 heterobinuclear (Cu-M) complexes containing an endoge- C-C coupling and C-H activation occurring in reactions of nous benzimidazolate bridge, 1 FeRu(CO),('Pr-Pyca) (‘Pr-Pyca = C;H,N-2-CH = N-'Pr) pyridine ligand donor substituent effects upon structure, with activated alkynes RC=CR’ (R=R’=C(O)OMe; redox properties and O, reactivity of xylyl dinuclear R=H, R’=C(O)Me), 145 copper(I) complexes, 5 synthesis of the monohydride complexes synthesis, spectroscopic and redox behaviour of copper(II) HRu,(X)(CO),('Pr-N = CHCH = N-'Pr) (X=Cl, I); complexes with quinquedentate thiaaza ligands, 29 hydrogenation of the central C-—C bond of the coordi- copper complexes with di-pyridylmethane. The synthesis nated a-diimine ligands. X-ray single crystal structure of and X-ray structures of bis(di-pyridylmethane)copper(I) HRu,(Cl)(CO),('Pr-N = CHCH = N-'Pr), 157 perchlorate, bis(di-pyridylmethane)copper(II) perchlorate crystal structures of (7°-C;Me;)(n°-2,4-C,H,,)Cr and (7°- and dichloro-y-dichloro-bis(di-pyridyl- CsMe;)(7°-2,4-C,H;;)CrCO. An example of ‘S’ 2,4-di- methane)dicopper(II), 73 methylpentadienyl ligand geometry, 179 Hush theory in a copper mixed valence bioinorganic model electrochemical formation and X-ray structure of the five- generated photochemically, 115 coordinated ruthenium(II) [RuCl(dppp),](PF,) complex, charge transfer photochemistry of 185 bis(diethyldithiocarbamato)copper(II) and bis(diiso- synthesis and characterization of two new classes of ruthe- propyldithiophosphato)copper(II) complexes, 201 nium(III)-sulfoxide complexes with nitrogen donor li- Corrole complexes gands (L): Na[trans-RuCl,(R,SO)(L)] and mer,cis- synthesis and characterization of cobalt(III) complexes of RuCl,(R,SO)(R2SO)(L). The crystal structure of meso-phenyl-substituted corroles, 107 Na[trans-RuCl,(DMSO)(NH3)]-2DMSO, Nafzrans- Crystal structure(s) RuCl,(DMSO)(Im)]-H,0,Me,CO (Im=imidazole) and pyridine ligand donor substituent effects upon structure, mer,cis-RuCl,(DMSO)(DMSO)(NH;), 205 redox properties and QO, reactivity of xylyl dinuclear ammonium di--oxalatotitanate(III) dihydrate: an eight- copper(I) complexes, 5 coordinate, polymeric titanium(III) complex, 219 synthesis and coordination chemistry of trifunctional the structure of two analogous 16-electron piano stool carbamoyl-bis-phosphonate alkane ligands, 11 molybdenum(IV) complexes, [YMoI,(PMe;).]* (Y = Cp, the coordination chemistry of macrocyclic 13- and 14-mem- Cp*), 223 bered dipyridylmethaneamides; crystal structure of the kinetic studies on sterically hindered pentaaminecobalt(III) deprotonated Ni(II) complex of 3,15-dioxo-9-ethyl-9- complexes. Synthesis, anation reactions and crystal methoxy-1,4,5,6,7,8,10,11,12,13,14,17,18,19,20,21,22,23- structure of [Co(EtNH,);H,O](ClO,);-2H,O, 229 269 °C] nuclear quadrupole resonance and crystal structures of Hydride complexes small guest molecules in tris(2,4-pentanedionate)M(III) synthesis of the monohydride complexes inclusion compounds, 239 HRu,(X)(CO),(‘Pr-N = CHCH = N-'Pr) (X=Cl, I); the molecular structure of sodium hydrogenation of the central C-C bond of the coordi- (aqua)(ethylenediaminetetraacetato)titanate(III) nated a-diimine ligands. X-ray single crystal structure of dihydrate, Na[Ti(H,O)(edta)]-2H,O, as determined by HRu,(Cl)(CO),(‘Pr-N = CHCH=N-'Pr), 157 X-ray crystal analysis, 249 Hydrogen complexes coordination behaviour of methazolamide [N(-4-methyl-2- hydrogen migration in Fe;(CO)sCH,, 43 sulfamoyl-A?-1,3,4-thiadiazolin-5-ylidene)] acetamide, an Hydrolysis inhibitor of carbonic anhydrase enzyme. Synthesis, preparation and covalent hydration of a hexafluoro-2,4- crystal structure and properties of pentanedionatotetraaminecobalt(III) complex, 37 bis(methazolamidate)tetrammine nickel(II), 257 Cyclopentadienyl complexes crystal structures of (7°-C;Me;)(°-2,4-C,H;,)Cr and (7°- Iridium complexes C;Mes)(n°-2,4-C,H,;)CrCO. An example of ‘S’ 2,4-di- ten-vertex metallaborane clusters: action as a B-frame sup- methylpentadienyl ligand geometry, 179 port for heterobimetallic species: [7,7-(PMe3).-9,9,9- the structure of two analogous 16-electron piano stool H(PPh;)(Ph2P-ortho-C,H,)-nido-7,9-PtIrByHj9-4 ] and molybdenum(IV) complexes, [YMoI,(PMe;).]*(Y =Cp, related compounds, 193 Cp*), 223 Iron complexes hydrogen migration in Fe,;(CO),CH,, 43 formation of acetylacetonato iron complexes in acetonitrile Dinuclear complexes and their resonance Raman spectra, 61 interactions of the Rh,** formamidinate complex Rh,(p- preparation of the new heteronuclear a-diimine complexes form) 2(u-O,CCF;)2(H,O), (form =N, N’-di-p-tolyl- FeRu(CO),(R-Pyca) and Fe,Ru(CO),9(R-Pyca) formamidinate anion) with nucleobases and (R-= CP;H,yN-2c-CHa=NR ); “°C NMR study of the nucleosides, 101 fluxional behaviour of the carbonyl ligands in Hush theory in a copper mixed valence bioinorganic model Fe,Ru(CO),o(R-Pyca), 129 generated photochemically, 115 C-C coupling and C-H activation occurring in reactions of Dithiocarbamato complexes FeRu(CO),(‘Pr-Pyca) (‘Pr-Pyca = C;H,N-2-CH = N-'Pr) charge transfer photochemistry of with activated alkynes RC=CR’ (R=R’=C(O)OMe; bis(diethyldithiocarbamato)copper(II) and bis(diiso- R=H, R’=C(O)Me), 145 propyldithiophosphato)copper(II) complexes, 201 mixed amino acid binding of Fe,S, clusters: a ‘H NMR Dithiophosphato complexes study, 253 charge transfer photochemistry of Isocyanide complexes bis(diethyldithiocarbamato)copper(II) and bis(diiso- synthesis of paramagnetic tetrakis(benzylisocyanide)bis(tri-p- propyldithiophosphato)copper(II) complexes, 201 tolylarsine oxide)cobalt(III) tetrafluoroborate. An exam- ple of oxidation of ligand and metal in reaction of Electrochemistry pentakis(arylisocyanide)cobalt(II) with triarylarsine, 175 pyridine ligand donor substituent effects upon structure, redox properties and QO, reactivity of xylyl dinuclear copper(I) complexes, 5 Kinetics and mechanism the synthesis of zinc(II) complexes of 2-(2-mercapto- kinetic studies on sterically hindered pentaaminecobalt(IIT) phenyl)-imino-phenol by electrochemical cleavage of a complexes. Synthesis, anation reactions and crystal disulfide bond; the crystal structure of{(2,2’-bipyri- structure of [Co(EtNH,);H,O](ClO,)3-2H,O, 229 dine)[2-(2-mercaptopheny])iminophenoxy]}zinc(II), 67 electrochemical formation and X-ray structure of the five- coordinated ruthenium(II) [RuCl(dppp).](PF.) complex, Macrocyclic ligand complexes 185 the coordination chemistry of macrocyclic 13- and 14-mem- bered dipyridylmethaneamides; crystal structure of the Fluorophosphine complexes deprotonated Ni(II) complex of 3,15-dioxo-9-ethyl-9- preferential displacement of fluorophosphine ligands from methoxy-1,4,5,6,7,8,10,11,12,13,14,17,18,19,20,21,22,23- fluorophosphinetungstencarbonyl complexes by reaction octadecadehydro-2,16,22,23-tetraazatetra- cyclo[15.4.0.1*°.1'°'*]tricosane, 21 with trimethylamine oxide, 87 synthesis, spectroscopic and redox behaviour of copper(II) complexes with quinquedentate thiaaza ligands, 29 Gadolinium complexes Metal complexes synthesis and coordination chemistry of trifunctional heterobinuclear (Cu-M) complexes containing an endoge- carbamoylI-bis-phosphonate alkane ligands, 11 nous benzimidazolate bridge, 1 Gold complexes *°Cl nuclear quadrupole resonance and crystal structures of a revision on gold(I)-carben stretching frequencies, 127 small guest molecules in tris(2,4-pentanedionate)M(III) inclusion compounds, 239 Halide complexes Metallaborane complexes reduction of tungsten(VI) and molybdenum(V) by allyltri- ten-vertex metallaborane clusters: action as a B-frame sup- methylsilane and cyclopentene. Simple high yield port for heterobimetallic species: [7,7-(PMe;3)2-9,9,9- syntheses of MoCl,(OEt,),, MoCl,(dme), WC1,(thf),, H(PPh;)(Ph2P-ortho-C,H,)-nido-7,9-PtIrByHj9-4 ] and WCI,(dme) and WOCI,(thf)., 235 related compounds, 193 270 Metallophthalocyanine complexes Photochemistry derivation of metallophthalocyanine redox potentials via Hush theory in a copper mixed valence bioinorganic model Hammett parameter analysis, 171 generated photochemically, 115 Molecular orbital study charge transfer photochemistry of hydrogen migration in Fe;(CO),CHy,, 43 bis(diethyldithiocarbamato)copper(II) and bis (diiso- Molybdenum complexes propyldithiophosphato)copper(II) complexes, 201 the structure of two analogous 16-electron piano stool Platinum complexes molybdenum(IV) complexes, [YMoI,(PMe;).]* (Y = Cp, crystal structures of bis(L( — )prolinato-N)(trans-R,R-1,2-di- Cp*), 223 aminocyclohexane)platinum(II) and bis— ()prLoli(nat o- reduction of tungsten(VI) and molybdenum(V) by allyltri- N)-(cis-1,2-diaminocyclohexane)platinum(II) complexes, methylsilane and cyclopentene. Simple high yield 121 syntheses of MoCl,(OEt,)., MoCl,(dme), WCl,(thf),, ten-vertex metallaborane clusters: action as a B-frame sup- WCl,(dme) and WOCI,(thf)2, 235 port for heterobimetallic species: [7,7-(PMe;),-9,9,9- H(PPh;)(Ph,P-ortho-C,H,)-nido-7,9-PtIrByH19-4 |] and related compounds, 193 Nickel complexes Polydentate ligand complexes the coordination chemistry of macrocyclic 13- and 14-mem- the molecular structure of sodium bered dipyridylmethaneamides; crystal structure of the (aqua)(ethylenediaminetetraacetato)titanate(III) deprotonated Ni(II) complex of 3,15-dioxo-9-ethyl-9- dihydrate, Na[Ti(H,O)(edta)]-2H,O, as determined by methoxy-101, 1,1,142,1,3,514,,17,618,,19,720,,218,22,,23 - X-ray crystal analysis, 249 octadecadehydro-2,16,22,23-tetraazatetra- Polyfunctional ligand complexes cyclo[15.4.0.1*°.1'°"*]tricosane, 21 synthesis and coordination chemistry of trifunctional coordination behaviour of methazolamide [N(-4-methyl-2- carbamoyl-bis-phosphonate alkane ligands, 11 sulfamoyl-A?-1,3,4-thiadiazolin-5-ylidene)] acetamide, an Polymeric complexes inhibitor of carbonic anhydrase enzyme. Synthesis, a polymeric silver(I) complex containing triply carboxylato- crystal structure and properties of O,O'-bridged dinuclear cores, bis(methazolamidate)tetrammine nickel(II), 257 Nitrogen ligand complexes [{Ag.4(Me3NCH2CO>)¢},,](C1O4)4n,. 97 Pyrrolyl complexes synthesis and characterization of two new classes of ruthe- first observation of z-bonding in triple decker pyrrolyl nium(IIT)—sulfoxide complexes with nitrogen donor li- complexes. Crystal structure of [(7°-tetramethyl- gands (L): Na[trans-RuCl,(R,SO)(L)] and mer,cis- pyrrolyl)Co],(C,Et,B3H;3), 51 RuCl,(R2,SO)(R,SO)(L). The crystal structure of Nal[trans-RuCl,(DMSO)(NH;)]-2DMSO, Na[trans- RuCl,(DMSO)(Im)]-H,0,Me,CO (Im=imidazole) and Redox potentials mer,cis-RuCl;(DMSO)(DMSO)(NH;), 205 derivation of metallophthalocyanine redox potentials via Nucleobase complexes Hammett parameter analysis, 171 interactions of the Rh,** formamidinate complex Rh,(p- Reduction form),(u4-O,CCF;).(H,O), (form =N, N’-di-p-tolyl- reduction of tungsten(VI) and molybdenum(V) by allyltri- formamidinate anion) with nucleobases and nucleosides, methylsilane and cyclopentene. Simple high yield 101 syntheses of MoCl,(OEt,)2, MoCl,(dme), WCl,(thf),, Nucleoside complexes WCl1,(dme) and WOCI,(thf)., 235 interactions of the Rh,** formamidinate complex Rh,(p- Rhodium complexes form),(4-O,CCF;).(H,O), (form =N, N’-di-p-tolyl- interactions of the Rh,** formamidinate complex Rh2(p- formamidinate anion) with nucleobases and nucleosides, form) (4-O,CCF;).(H,O), (form=N, N’-di-p-tolyl- 101 formamidinate anion) with nucleobases and nucleosides, 101 Oxalato complexes Ruthenium complexes ammonium di-y-oxalatotitanate(III) dihydrate: an eight- stabilizing of the Ru,°* + core. Use of highly charged li- coordinate, polymeric titanium(III) complex, 219 gands such as sulfate and phosphate, 55 Oxo complexes preparation of the new heteronuclear a-diimine complexes crystal and molecular structures of sulfonato complexes of FeRu(CO),(R-Pyca) and Fe,Ru(CO)j9(R-Pyca) dioxouranium(VI) ion: role of steric effects on coordi- (R-= CP;H,yN-2c-CHa=NR ); °C NMR study of the nation structure, 81 fluxional behaviour of the carbonyl ligands in Oxygen complexes Fe,Ru(CO),9(R-Pyca), 129 pyridine ligand donor substituent effects upon structure, C-C coupling and C-H activation occurring in reactions of redox properties and O, reactivity of xylyl dinuclear FeRu(CO),('Pr-Pyca) ('Pr-Pyca = C;H,N-2-CH = N-'Pr) copper(I) complexes, 5 with activated alkynes RC=CR’ (R=R’=C(O)OMe; R=H, R’=C(O)Me), 145 Paramagnetism synthesis of the monohydride complexes synthesis of paramagnetic tetrakis(benzylisocyanide )bis(tri-p- HRu,(X)(CO),(‘Pr-N = CHCH =N-'Pr) (X=Cl, 1); tolylarsine oxide)cobalt(III) tetrafluoroborate. An exam- hydrogenation of the central C—C bond of the coordi- ple of oxidation of ligand and metal in reaction of nated a-diimine ligands. X-ray single crystal structure of pentakis(arylisocyanide)cobalt(II) with triarylarsine, 175 HRu,(Cl)(CO),(‘Pr-N = CHCH = N-'Pr), 157 Phosphate complexes electrochemical formation and X-ray structure of the five- stabilizing of the Ru,°* core. Use of highly charged coordinated ruthenium(II) [RuCl(dppp),.](PF,) complex, ligands such as sulfate and phosphate, 55 185 271 synthesis and characterization of two new classes of ruthe- Sulfur complexes nium(III)-sulfoxide complexes with nitrogen donor li- mixed amino acid binding of Fe,S, clusters: a ‘'H NMR gands (L): Na[trans-RuCl,(R,SO)(L)] and mer,cis- study, 253 RuCl,(R,SO)(R,SO)(L). The crystal structure of Na[trans-RuCl,(DMSO)(NH;)]:2DMSO, Naltrans- Thallium complexes RuCl,(DMSO)(Im)]-H,0,Me,CO (Im= imidazole) and a volatile thallium chelate, (2,2,6,6-tetramethyl-3,5-heptane- mer,cis-RuCl;(DMSO)(DMSO)(NH3), 205 dionato)TI(1), 9 Thiouracyl complexes a thiouracil—Ca”* complex containing two tautomeric forms of the thiouracilyl anion: synthesis and crystal structure of [(thiouracilyl),Ca-2DMSO-H,O},, 93 Schiff base complexes Titanium complexes the synthesis of zinc(II) complexes of 2-(2-mercapto- ammonium di-y-oxalatotitanate(III) dihydrate: an eight- phenyl)-imino-phenol by electrochemical cleavage of a coordinate, polymeric titanium(III) complex, 219 disulfide bond; the crystal structure of{(2,2’-bipyri- the molecular structure of sodium dine)[2-(2-mercaptophenyl)imino- phenoxy]}zinc(II), 67 (aqua)(ethylenediaminetetraacetato)titanate(III) Silver complexes dihydrate, Na[Ti(H,O)(edta)]-2H,O, as determined by a polymeric silver(1) complex containing triply carboxylato- X-ray crystal analysis, 249 O,O'-bridged dinuclear cores, Tungsten complexes [{Ag,(Me3;NCH,CO,).},,](ClO4)«,; 97 preferential displacement of fluorophosphine ligands from Spectroscopy fluorophosphinetungstencarbonyl complexes by reaction a revision on gold(I)-carbon stretching frequencies, 127 with trimethylamine oxide, 87 Sulfate complexes reduction of tungsten(VI) and molybdenum(V) by allyltri- stabilizing of the Ru,°* + core. Use of highly charged li- methylsilane and cyclopentene. Simple high yield gands such as sulfate and phosphate, 55 syntheses of MoCl,(OEt,)., MoCl,(dme), WCl,(thf),, Sulfonato complexes WCl,(dme) and WOCI,(thf),, 235 crystal and molecular structures of sulfonato complexes of dioxouranium(VI) ion: role of steric effects on coordi- Uranium complexes nation structure, 81 crystal and molecular structures of sulfonato complexes of Sulfoxide complexes dioxouranium(VI) ion: role of steric effects on coordi- synthesis and characterization of two new classes of ruthe- nation structure, 81 nium(III)-sulfoxide complexes with nitrogen donor li- gands (L): Na[trans-RuCl,(R,SO)(L)] and mer,cis- Zinc complexes RuCl,(R,SO)(R2SO)(L). The crystal structure of the synthesis of zinc(II) complexes of 2-(2-mercapto- Na|[trans-RuCl,(DMSO)(NH;)]:2DMSO, Na|trans- phenyl)-iminophenol by electrochemical cleavage of a RuCl,(DMSO)(Im)]-H,0,Me,CO (Im =imidazole) and disulfide bond; the crystal structure of{(2,2’-bipyri- mer,cis-RuCl,(DMSO)(DMSO)(NH;), 205 dine)[2-(2-mercaptopheny])iminophenoxy]}zinc(II), 67

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