Inorganic Nanosheets and Nanosheet-Based Materials: Fundamentals and Applications of Two-Dimensional Systems PDF
Preview Inorganic Nanosheets and Nanosheet-Based Materials: Fundamentals and Applications of Two-Dimensional Systems
Nanostructure Science and Technology Series Editor: David J. Lockwood Teruyuki Nakato Jun Kawamata Shinsuke Takagi Editors Inorganic Nanosheets and Nanosheet-Based Materials Fundamentals and Applications of Two-Dimensional Systems Nanostructure Science and Technology Series editor David J. Lockwood, FRSC National Research Council of Canada Ottawa, Ontario, Canada More information about this series at http://www.springer.com/series/6331 Teruyuki Nakato Jun Kawamata (cid:129) Shinsuke Takagi Editors Inorganic Nanosheets and Nanosheet-Based Materials Fundamentals and Applications of Two-Dimensional Systems 123 Editors Teruyuki Nakato ShinsukeTakagi Kyushu Institute of Technology Tokyo MetropolitanUniversity Kitakyushu Hachioji Japan Japan Jun Kawamata Yamaguchi University Yamaguchi Japan ISSN 1571-5744 ISSN 2197-7976 (electronic) Nanostructure Scienceand Technology ISBN978-4-431-56494-2 ISBN978-4-431-56496-6 (eBook) DOI 10.1007/978-4-431-56496-6 LibraryofCongressControlNumber:2017932786 ©SpringerJapanKK2017 Thisworkissubjecttocopyright.AllrightsarereservedbythePublisher,whetherthewholeorpart of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilms or in any other physical way, and transmission orinformationstorageandretrieval,electronicadaptation,computersoftware,orbysimilarordissimilar methodologynowknownorhereafterdeveloped. The use of general descriptive names, registered names, trademarks, service marks, etc. in this publicationdoesnotimply,evenintheabsenceofaspecificstatement,thatsuchnamesareexemptfrom therelevantprotectivelawsandregulationsandthereforefreeforgeneraluse. The publisher, the authors and the editors are safe to assume that the advice and information in this book are believed to be true and accurate at the date of publication. Neither the publisher nor the authorsortheeditorsgiveawarranty,expressorimplied,withrespecttothematerialcontainedhereinor for any errors or omissions that may have been made. The publisher remains neutral with regard to jurisdictionalclaimsinpublishedmapsandinstitutionalaffiliations. Printedonacid-freepaper ThisSpringerimprintispublishedbySpringerNature TheregisteredcompanyisSpringerJapanKK Theregisteredcompanyaddressis:ChiyodaFirstBldg.East,3-8-1Nishi-Kanda,Chiyoda-ku,Tokyo101-0065,Japan Preface Zhuangzi(ChaungTzu),aphilosopherofancientChina,wrote“lookingatthesky through a tube” as a metaphor for shortsighted recognition (in Autumn Floods, an outerchapterofZhuangzi).Asseeninchildren’sgames,however,“lookingthrough a tube” often gives attractive and stimulating landscapes. The restricted and low-dimensional sight can clarify unusual aspects of the scenery hidden in an ordinary view. Does it hold for materials chemistry? The answer is yes. From the last quarter of the twentieth century, chemical science has discovered structuraldesignatnanometerscales,beinglargerthanthesizeofsinglemolecules but much smaller than that of practical materials, as an important key for devel- oping novel advanced materials. Shape anisotropy has also been found as another key that facilitates gradient functions in a system by asymmetric location of functional moieties. Research interests have created various nano-objects and nanospaces in the materials world. Today, they are recognized as important buildingblocksormatrixesforconstructingadvancedmaterialswiththeintegration of plural functional moieties. Inorganic nanosheets are two-dimensional particles with nm-level thickness. In particular, they mean crystalline inorganic monolayers provided by exfoliation of inorganic layered crystals. The exfoliation has been developed as an extension of intercalation phenomena that are the events in the two-dimensional interlayer spaces of the layered crystals. In fact, the exfoliated inorganic nanosheets and the interlayerspaces,beingtwosidesofthesamecoin,havecontributedasanisotropic nano-objects or nanospaces to developing nanostructured materials. Various nanosheet-based architectures have been constructed often with immobilizing functionalmoleculesinthenanospacesoronthenanosheetsthemselves.Recently, theresearchfieldhasbeenprogressingandexpandingmoreandmoreasstimulated by the Nobel Prize for graphene in 2010. Publications including the word “nanosheet”exceeded2,800in2015,althoughtheywerefewerthan10in2000(by SciFinder). Basedonsuchresearchdevelopment,wedecidedtosummarizecurrentmaterials chemistry of the inorganic nanosheets in this book. We aimed at bundling diverse aspects of inorganic nanosheets, e.g., nanosheet preparation, hybridization with v vi Preface other materials, and various applications, to give a concise summary of the inor- ganic nanosheets and nanosheet-based materials. Fortunately, we succeeded in collecting contributions from many leading researchers involved in this area. This book is composed of two parts. Part I provides fundamental aspects. The research area is overviewed, and preparation, properties, and fabrications of rep- resentativeinorganicnanosheets,i.e.,clayminerals,oxometallates,graphene,metal dichalcogenides, are summarized. Interactions of the nanosheets and their 2D interlayer spaces with organic and polymer species, which are the critical basis of fabricating nanosheet-based assemblies, are described. Moreover, colloidal prop- erties of the nanosheets are also depicted, exploring their utilization in the field of soft matter. PartIIcollectsapplicationsofthenanosheet-basedmaterials.Theyareextended to various fields: adsorption, sensing, electric, optic, energy conversion, and bio- logical functions, covering broad state-of-the-art research topics. Among them, photochemical and electrochemical functions related to energy conversion and storage are described in detail because these functions are highly sensitive to microenvironmentsandhierarchicalarrangementsofthereactionmoleculesasseen in natural photosynthetic systems. Finally,we expressoursincere thanks toalltheauthorswho contributedtothis book with their deep insights into this field. Kitakyushu, Japan Teruyuki Nakato Yamaguchi, Japan Jun Kawamata Hachioji, Japan Shinsuke Takagi Contents Part I Fundamental Aspects of Inorganic Nanosheets 1 Materials Chemistry of Inorganic Nanosheets—Overview and History ... .... .... ..... .... .... .... .... .... ..... .... 3 Teruyuki Nakato, Jun Kawamata and Shinsuke Takagi 2 Clay Minerals as Natural Nanosheets ... .... .... .... ..... .... 33 Robert A. Schoonheydt and Yasushi Umemura 3 Synthetic Nanosheets from Ion-Exchangeable Layered Solids. .... 55 Teruyuki Nakato 4 Graphene: Synthesis and Functionalization... .... .... ..... .... 101 Tomo-o Terasawa and Koichiro Saiki 5 Chalcogenide Nanosheets: Optical Signatures of Many-Body Effects and Electronic Band Structure... .... .... .... ..... .... 133 Ivan Verzhbitskiy and Goki Eda 6 Inorganic–Organic Interactions .... .... .... .... .... ..... .... 163 Tomohiko Okada and Makoto Ogawa 7 Hybridization with Polymers .. .... .... .... .... .... ..... .... 187 Yoshiaki Fukushima and Kenji Tamura 8 Colloidal Nanosheets.... ..... .... .... .... .... .... ..... .... 201 Nobuyoshi Miyamoto, Yutaka Ohsedo and Teruyuki Nakato Part II Functions and Applications of the Inorganic Nanosheets 9 Adsorbents Derived from Layered Solids .... .... .... ..... .... 263 Tomohiko Okada and Makoto Ogawa 10 Sensors... .... .... .... ..... .... .... .... .... .... ..... .... 303 Takuya Fujimura and Ryo Sasai vii viii Contents 11 Energy Storage Systems . ..... .... .... .... .... .... ..... .... 315 Wataru Sugimoto and Dai Mochizuki 12 Graphene Oxide Based Electrochemical System for Energy Generation .. ..... .... .... .... .... .... ..... .... 331 Kazuto Hatakeyama, Shinya Hayami and Yasumichi Matsumoto 13 Nanosheet-Based Electronics .. .... .... .... .... .... ..... .... 347 Minoru Osada 14 Photoenergy Conversion. ..... .... .... .... .... .... ..... .... 357 Yohei Ishida and Shinsuke Takagi 15 Photofunctional Nanosheet-Based Hybrids ... .... .... ..... .... 373 Jayavant L. Gunjakar, In Young Kim and Seong-Ju Hwang 16 Efficient Photocatalytic Systems Integrated with Layered Materials Promoters .... ..... .... .... .... .... .... ..... .... 395 Yusuke Ide 17 Semiconductor Nanosheets.... .... .... .... .... .... ..... .... 409 Shintaro Ida 18 Hybrids with Functional Dyes . .... .... .... .... .... ..... .... 419 Juraj Bujdák 19 Optical Materials... .... ..... .... .... .... .... .... ..... .... 467 Yasutaka Suzuki and Jun Kawamata 20 Chirality and Its Application .. .... .... .... .... .... ..... .... 483 Hisako Sato and Akihiko Yamagishi 21 Applications of Nanoclay-Containing Polymer Nanocomposites.... .... ..... .... .... .... .... .... ..... .... 501 Jayita Bandyopadhyay and Suprakas Sinha Ray 22 Biological Materials. .... ..... .... .... .... .... .... ..... .... 523 Challa Vijaya Kumar Part I Fundamental Aspects of Inorganic Nanosheets
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