Initiators for Acrylics manufacturing

17 Pages·2017·3.27 MB·English

Initiators for
Acrylics manufacturing
2 3
Contents
AkzoNobel creates every AkzoNobel is consistently ranked as one of the Acrylics
Chemicals industry leaders on the Dow Jones
day’s essentials to make Sustainability World Indexes (DJSI), showing that Polymerization initiators 7
people’s lives more livable we take our obligations seriously - to the planet, Main areas of application - product selection 8
to our customers and to our own people. We
and inspiring believe the only way to grow is by developing Safety 10
sustainable, innovative solutions that benefit our
Packaging 12
customers and we’re constantly looking for ways
As a leading global paints and coatings company
to reduce our impact on the environment. Product list 14
and a major producer of specialty chemicals, we
supply essential ingredients, essential protection Kinetic data & half-life chart 24
We’re committed to Responsible Care®.
and essential color to industries and consumers
Initiators for cast acrylic lenses
Product Stewardship and REACH.
worldwide. We have approximately 45,000 people
in around 80 countries and are dedicated to ener- Trigonox® and Perkadox® 26
gizing cities and communities while creating a pro- Sustainability is at the heart
Antifouling Agents
tected, colorful world where life is improved by
of everything we do
what we do. Noxol® and Everplus 28
Superconductive carbon blacks
We produce everyday essentials for the global We are committed to making all our products,
polymer and electronic industries. Our product services and partnerships as sustainable as pos- Ketjenblack® 29
portfolio includes organic peroxides, metal alkyls, sible. It’s one of the company’s strategic reputa-
Functional Methacrylates
organometallic specialties and polymer additives, tion builders, as well as being one of our core
which are essential ingredients for the thermoplas- principles. Nourycryl® 30
tic, composite and rubber industries.
Sustainability is critical for the future success of
We supply customers around the world with in- our company, our society and our planet. Planet
gredients for the manufacture of life’s essentials. Possible is how we explain our sustainability
Specialty chemicals are used in, among others, strategy on an economic, environmental and so-
paints, detergents, foods, plastics, cosmetics, cial level. It is our commitment to doing more with
construction, pulp and paper, pharmaceuticals, less: creating more value from fewer resources. It
electronics, agriculture and for plastics. Our prod- is about developing a more sustainable business
ucts can be used in a variety of ways. For exam- and increasing our resource efficiency across the
ple, as basic building blocks of manufactured entire value chain.
products, in the processing of raw materials, as
intermediates used to produce finished goods, or
they may be used to enhance the functionality
and durability of manufactured products.
You’ll find us in the food you eat, the buildings you We engage our employees, suppliers and cus-
live and work in, the vehicles and roads you use tomers on sustainability and form partnerships to
to move around, as well as everyday items such drive the agenda. By working closely with these
as paper products and your children’s toys. key stakeholders, we can ensure that our value
chain is as sustainable and delivers business
benefits for all. We can help make life more liv-
able, healthy and inspiring.
Our researchers are based in dedicated custom-
er-focused business teams. They perform re-
search, product and process development and
technical support in order to translate market
needs into new products. They understand the
needs of our customers and are committed to
their success.
4 5
Polymerization initiators
Laurox®, Perkadox®, Trigonox®
Our manufacturing sites and distribution centers are found
all around the globe. Our global distribution network allows
us to deliver our products to you anywhere around the
world. That’s how we ensure security of supply and easy
access to quality products wherever you are.
All our sites are ISO 9001 and ISO 14001 certified to ensure the highest product quality and strict
compliance with environmental regulations. We continually invest in manufacturing techniques,
high quality standards, safety, innovation, active technical support and a reliable supply chain.
A global partner
AkzoNobel’s range of organ- We have a long history in organic peroxides, start- This product guide provides an overview of our
ing with dibenzoyl peroxide used for the bleaching main, commercially available initiators for the
ic peroxides for the manu-
of flour in the early 1920s. Since then, we have free radical polymerization of (meth)acrylate
facture of acrylics is the added many new organic peroxides to our prod- monomers. In addition we offer reactor additives
uct portfolio, including those which produce plas- such as antifouling agents, which are marketed
world’s largest. We cover
tics used in everyday life. Today, we are the under the well-known trademarks of Noxol and
classes such as peroxy(di) world’s leading producer of organic peroxides. Everplus.
Amsterdam We are home to the best known brands in the
carbonates, diacyl peroxides,
Rotterdam Deventer business. Examples include Laurox, Perkadox As a company of innovation, we have recently
Chicago Mons Adria peroxyketals, peroxyesters, and Trigonox. introduced new initiators, which have an im-
Tianjin proved performance in selectivity and HSE pro-
dialkyl peroxides and hydro-
Pasadena La Porte Asa Our products are used in a huge range of indus- file, including such products as Trigonox 421 and
Shanghai peroxides. In addition we trial and consumer goods, such as solvent and Trigonox 301.
Ningbo
Dubai water based coating resins, acrylic sheets and
Los Reyes Mahad supply azo (N=N) and car-
castings, toner and inks, adhesives and sealants, Please visit www.akzonobel.com/polymer for
bon-carbon (C-C) initiators. acrylic fibers, super absorbers, detergents and complete product listings. Formulations with
flocculants and many others. Our range of initia- phlegmatizers or concentrations other than those
You name it, we produce it.
tors meet the requirements in each area of appli- indicated can also be made available.
cation, from polymerization temperature, rate of
radical formation and storage facilities.
Paulinía
Itupeva
Scan QR code to
watch our short video
on how we help
Regional headquarters make polymers.
Manufacturing sites
Research, Development & Innovation
Transfilling & blending stations
Warehouses
6 7
Main areas of application

End use Coating resins Sheets & castings Toners & inks Adhesives & sealants Fibers Super absorbers Detergents Flocculants
Segment Solvent based Water based P(M)MA bulk Styrene-Acrylics toner Water based Solvent Acrylic & modacrylic Water soluble resins
resin based
Application Medium solids High solids Clear coat Latex Water treatment
1) 2) 3)
Process
Solution & solvent polymerisation • • • • • • • • •
Suspension & emulsion polymerisation Emulsion Suspension Suspension Both Emulsion Both
Bulk & mass polymerization • •
Inversed emulsion & slurry polymerisation • •
Temperature during polymerization 70 90-140 180 50-180 70-180 90 90-110 70-90 60-70 90-100 90-100
Initiator t½ 1 hr
Perkadox 16 / Perkadox 16-W75 15 64 • • • • •
Trigonox EHPS 64 • • • •
Trigonox 23 α 64 • α α •
Perkadox 24L 14 65 • • •
Trigonox 25-C75 α 75 • • α α • • •
Trigonox 36-C75 77 • • • •
Laurox S or W40 α 15 79 • • α α • • • • • •
Perkadox AIBN 16 82 • • • • • • • • • • • • •
Perkadox AMBN-GR 11 15 84 • • • • • • • • • • • •
Trigonox 421 α 12 88 • • α • • • • • • • • • •
Trigonox 121 α 91 • • α α • • • •
Perkadox L-W75 / Perkadox L-W40 SN 7 15 91 • • • • • • • 5 • 5 • • • • • • • •
Trigonox 21S α 91 • • α α • • • • • •
Trigonox 27 93 • 8
Perkadox ACCN 103 • • • • • • •
Trigonox 29 105 • • • •
Perkadox 12-XL25 106 • 9 • 9
Trigonox 131 113 • • •
Trigonox 22-C80 113 •
Trigonox 42S 114 • • • • • • •
Trigonox 133-CK60 114 •
Trigonox D-C50 116 • •
Trigonox BPIC-C75 117 • • • • •
Trigonox 117 117 • • • • 10
Trigonox 127 7 118 • • •
Trigonox F-C50 119 • • • • • •
Trigonox C 7 122 • • • • • • • • • • • •
Perkadox BC-FF 132 • •
Trigonox 101 134 • •
Trigonox T 13 136 • •
Trigonox B 141 • • • • • 6 •
Trigonox 301 146 • • •
Trigonox K-90 / Trigonox K-80 166 • • • • •
Trigonox A-W70 / Trigonox A-80 185 • • • • • • • • • •
Persulphates 4 n.a. • • • • •
• Industry standard 4 Persulphates are not part of our portfolio 10 Monomer cut for suspension process
• Recommended grade 5 General purpose 11 Less toxic decomposition product and better solubilty than Perkadox AIBN
α Alpha branched (selective) peroxide. Relevant for high solid acrylics and clear coats 6 Higher temp polymerization for lower MW 12 Maximized beta-scission for low polydispersity and optimized radical efficiency
1 Moulding & extrusion 7 Benzene containing decomposition products 13 Liquid dicumylperoxide
2 Moulding & extrusion to beads & powders 8 For low VOC formulation 14 Improved solubility and less deconmposition products compared to Perkadox 16
3 Casted & extruded sheet & injection and extrusion grades 9 For higher MW production 15 Oil soluble peroxide for inversed suspension polymerization
8 9
Your safety
Our priority
AkzoNobel is recognized as
Sharing our experience in safety is one of the Storage temperatures
the global leader in organic most important resources we offer. Through our
safety programs we provide expert advice on SADT: Self-Accelerating Decomposition
peroxide safety. Our proven the handling of our products including: Temperature
success in safely handling The SADT is the lowest temperature at which
• classroom review of how to safely handle self-accelerating decomposition may occur
organic peroxides is due to organic peroxides with a substance in the packaging as used in
• consultation on storage and dosing facility transport. Transportation temperatures are de-
our long-term commitment
design rived from the SADT according to the recom-
to developing and maintain- • demonstrations on the safe use, handling mendations by the United Nations Committee Table 1. Classification of organic peroxides
and control of organic peroxides of Experts on the Transport of Dangerous
ing high safety standards.
Goods. UN NO. CLASSIFICATION AKZONOBEL MAXIMUM
At AkzoNobel we always Our Safety Research Laboratory in Deventer, HAZARD RATING CONTAINER SIZE
place safety as our top The Netherlands is heavily involved in R&D, Ts max. 3101 type B; liquid Very high 25 kg (55 lb)
ensuring the development of safe products and The Ts max. given in the product list on pages 3103 type C; liquid
priority. processes. Studies are carried out, in order to 12-21 is the recommended maximum storage
provide a high level of safety in the manufactur- temperature at which the product is stable and 3104 type C; solid
High 50 kg (110 lb)
ing, handling and transport of dangerous goods. quality loss will be minimal. 3113 type C; liquid, temperature controlled
3114 type C; solid, temperature controlled
In general organic peroxides are thermally Ts min.
unstable compounds, decomposing at relatively A minimum storage temperature (Ts min.) is 3105 type D; liquid
low temperatures. However, knowledge of given if phase separation, crystallization or 3106 type D; solid
proper handling techniques, carefully designed solidification of the product is known to occur Medium 50 kg (110 lb)
3115 type D; liquid, temperature controlled
facilities and thorough training of personnel can below the temperature indicated. We recom-
overcome the hazards. Personnel who under- mend that you store the product above the Ts 3116 type D; solid, temperature controlled
stand and pay proper attention will be able to min. indicated for quality and in some cases
3107 type E; liquid Low 400 kg (880 lb)
handle organic peroxides confidently and safely. safety reasons.
3117 type E; liquid, temperature controlled Low
Survey of thermal stability Tem: Emergency temperature 3108 type E; solid
The Tem is derived from the SADT and is the
ure Thermal Explosion temperature at which emergency procedures 3109 type F; liquid
at must be implemented. 3110 type F; solid
er
p
m 3119 type F; liquid, temperature controlled
Te Induction Time Tc: Control temperature
None Non-dangerous good No Unrestricted
Runaway The Tc is also derived from the SADT and is the
maximum temperature at which the product SELF-REACTIvE SUBSTANCES
SADT Unstable can be safely transported. A Tc is not required 3234 type C; solid, temperature controlled High 50 kg (110 lb)
if the SADT exceeds 50°C.
3236 type D; solid, temperature controlled
Emergency Temperature Quality Loss
Both the Tem and Tc are related to safety and
Maximum Storage Temperature Stable do no apply to product quality. To maintain
product quality the recommended storage
temperatures (Ts min. and max.) have to be ob-
served.
Time
UN Numbers
All products accepted for transport are assigned
to generic entry numbers according to classifi-
cation principles as described in the recom-
mendations by the United Nations Committee Scan QR code to
of Experts on the Transport of Dangerous watch our short
Goods. An explanation of all relevant UN video on our
numbers is given in Table 1. safety services.
10 11
Packaging
We continuously develop
Liquid organic peroxides The AkzoNobel development of a cooled trailer Table 2. Standard packages for liquid peroxides Table 3. Standard packages for solid initiators
new and innovative packag- Liquid peroxides from AkzoNobel are available with IBC’s connected to a manifold eliminates
in packages shown in Table 2. Package sizes the in-house handling and transport of IBC’s. PACKAGE vOLUME NET WEIGHT COMMENTS PACKAGE NET COMMENTS
ing to make logistics more expressed in gallons are only available in Organic peroxide formulations can be directly WEIGHT
efficient and according to North America. pumped into storage tanks by a leak-free, Bottle 1 gallon 7-8 lb packaged as 4 polyethylene bottles Carton varies with polyethylene bags
dry-break connection. All unloading facilities are per non-returnable carton product inside non-returnable
safety standards beyond We also understand the need to innovate our present on the trailer. HDPE can 20-30 liter 15-25 kg single component, polyethylene container cardboard box
(5.3-8 gallon) (6.8-11.3 lb) (Nourytainer®) Crate varies polyethylene bags
packaging. For instance our Nourytainer®.
existing transport regula- Developed by AkzoNobel it is recognized as the Our continuous investment in refrigerated Drum 200 liter 150 kg steel drum with inner inside returnable
package plastic crate
tions. From bottles to tank world’s benchmark in liquid organic peroxide trucks, bulk tankers and dedicated reefers 220 liter 165-190 kg returnable polyethylene drum
Drum 20-25 kg fiber drum
packaging. AkzoNobel also was the first organic (refrigerated containers) specifically designed to 15 gallon 100 lb returnable polyethylene drum
trucks we offer a variety of (45-55 lb)
peroxide producer to introduce intermediate safely transport our products is another 55 gallon 300-410 lb polyethylene or steel drum
packaging options for both bulk containers (IBC’s). And we’re continually demonstration of our commitment to security IBC 1000 liter 800-1000 kg recollectable composite container
looking for new ways to optimize safe transport, of supply. (for emulsions and suspensions)
liquid and solid organic
handling and storage of organic peroxides. 1000 liter 800-1000 kg recollectable, conductive composite
peroxides. Solid initiators container
Most recently we’ve led the way with our Standard packages for our solid initiators are 1250 liter 850-1000 kg reusable stainless steel container
new unique composite IBC’s for dilute type F shown in Table 3. 330 gallon 2000 lb reusable stainless steel container
organic peroxides. Due to their weight and Tank truck 7000 gallon for transport of bulk shipments of dilute
dimensions, these IBC’s offer benefits in safety Most solid initiators are packaged in polyet hylene 20 m3 varies with product type F organic peroxides
and handling during transport and storage while bags inside non-returnable corrugated boxes.
giving all the advantages of our stainless steel The number of bags per box varies, depending
containers. The specially designed lid, used as on the weight of initiator per bag.
an emergency vent, is an AkzoNobel invention
and has been patented. In addition, they are For the availability of our products in IBC’s, bulk
readily available and have a lower environ - or non-standard packages, please consult your
mental impact. We provide recollection and AkzoNobel account manager.
recycling, showing our commitment to
developing new products and packages which
are more sustainable, without compromising
on performance.
Scan QR code to
watch our short
video on our
composite IBC’s.
12 13
Our initiators for acrylics
PRODUCT NAME CHEMICAL NAME [CAS NUMBER] GENERAL DATA STORAGE KINETIC DATA SAFETY DATA STANDARD
DATA T (°C) for t1/2 PACKAGE TYPE
Molecular Assay (%) Active oxygen (%) Physical form Ts Ts 0.1 h 1.0 h 10 h A (1/s) Ea SADT Tem Tc UN See page 13
weight max. min. (kJ/mole) (°C) (°C) (°C) No.
(°C) (°C)
Di(4-tert-butylcyclohexyl) peroxydicarbonate [15520-11-3] 398.5 4.01 82 64 48 7.44E+15 126.39
PERKADOX 16S 96 3.85 powder 20 40 35 30 3114 carton
PERKADOX 16 CH3 O O CH3 95.5 3.83 powder 20 40 35 30 3114 carton
PERKADOX 16-W75 75 3.01 wet powder or cake 20 40 35 30 3114 carton
CH C O C O O C O C CH
PERKADOX 16-W40 3 3 40 1.61 suspension in water 20 0 40 35 30 3119 HDPE can / IBC
CH CH
3 3
Di(2-ethylhexyl) peroxydicarbonate [16111-62-9]] 244.4 6.55 84 64 46 1.52E+14 115.47
TRIGONOX EHPS 98 4.53 liquid -20 0 -10 -20 3113 HDPE can
O O
CH3 (CH2)3 CH CH2 O C O O C O CH2 CH (CH2)3 CH3
C2H5 C2H5
tert-Butyl peroxyneodecanoate [26748-41-4] 244.4 6.55 84 64 46 1.52E+14 115.47
TRIGONOX 23 95 6.22 liquid -10 -30 15 5 -5 3115 HDPE can
TRIGONOX 23-C75 R O CH 75 4.91 solution in odorless mineral spirits -10 -20 20 10 0 3115 HDPE can
1 3
TRIGONOX 23-C30 30 1.96 solution in odorless mineral spirits -10 20 10 0 3119 IBC
R C C O O C CH
3
-10 0 -5 -10 3119 Bulk
R CH
TRIGONOX 23-W50 2 3 50 3.27 emulsion in water and methanol -10 -25 20 10 0 3119 HDPE can
R + R1 + R2 = C8H19 -10 -25 15 5 -5 3119 IBC
Dicetyl peroxydicarbonate [26322-14-5] 570.9 2.80 84 65 48 3.02E+15 124.30
PERKADOX 24L 91 2.55 powder 20 40 35 30 3116 carton
O O
CH (CH ) O C O O C O (CH ) CH
3 215 215 3
tert-Butyl peroxypivalate [927-07-1] 174.2 9.18 94 75 57 7.09E+14 123.59
TRIGONOX 25-C75 75 6.89 solution in odorless mineral spirits -5 -15 20 10 0 3113 HDPE can
CH O CH
3 3
CH C C O O C CH
3 3
CH CH
3 3
Di(3,5,5-trimethylhexanoyl) peroxide [3851-87-4] 314.5 5.09 96 77 59 2.84E+15 128.34
TRIGONOX 36-C75 75 3.82 solution in odorless mineral spirits 0 -10 20 10 0 3115 HDPE can
50
CH3 CH3 O O CH3 CH3
CH C CH CH CH C O O C CH CH CH C CH
3 2 2 2 2 3
CH3 CH3
Dilauroyl peroxide [105-74-8] 398.6 4.01 99 79 61 3.92E+14 123.37
LAUROX S 99 3.97 powder 30 50 45 40 3106 carton
LAUROX W-40 40 1.61 suspension in water 20 0 50 45 40 3109 HDPE can / IBC
O O
CH (CH ) C O O C (CH ) CH
3 210 210 3
14 15
Our initiators for acrylics
* UN 3117 in US
PRODUCT NAME CHEMICAL NAME [CAS NUMBER] GENERAL DATA STORAGE KINETIC DATA SAFETY DATA STANDARD
DATA T (°C) for t1/2 PACKAGE TYPE
Molecular Assay (%) Active oxygen (%) Physical form Ts Ts 0.1 h 1.0 h 10 h A (1/s) Ea SADT Tem Tc UN See page 13
weight max. min. (kJ/mole) (°C) (°C) (°C) No.
(°C) (°C)
2,2’-Azobis(isobutyronitrile) [78-67-1] 164.2 101 82 64 2.89E+15 130.23
PERKADOX AIBN 98 solid 25 50 45 40 3234 carton / fiber drum
CH CH
3 3
CH C N N C CH
3 3
CN CN
2,2’-Azobis(2-methylbutyronitrile) [13472-08-7] 192.3 104 84 66 1.38E+15 128.93
PERKADOX AMBN 98 solid 25 45 40 35 3236 carton
PERKADOX AMBN-GR CH CH 98 granules 25 45 40 35 3236 carton / fiber drum
3 3
CH CH C N N C CH CH
3 2 2 3
CN CN
1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate [22288-43-3] 272.4 5.87 109 88 69 1.62E+14 123.80
TRIGONOX 421 90 5.29 liquid 5 -20 30 20 15 3115 HDPE can
O CH CH
3 3
CH (CH ) CH C O O C CH C CH
3 23 2 3
CH CH CH
2 5 3 3
tert-Amyl peroxy-2-ethylhexanoate [686-31-7] 230.3 6.95 111 91 73 1.77E+15 132.11
TRIGONOX 121 95 6.60 liquid 5 -20 35 25 20 3115 HDPE can
TRIGONOX 121-C75 O CH 75 5.21 solution in odorless mineral spirits 10 35 25 20 3115 HDPE can
3
CH (CH ) CH C O O C CH
3 23 2 5
CH CH
2 5 3
Dibenzoyl peroxide [94-36-0] 242.2 6.61 113 91 71 6.94E+13 122.35
PERKADOX L-W75 75 4.95 wet powder 40 80 3104 carton
PERKADOX L-W40 O O 40 2.64 suspension in water 30 0 60 3109 HDPE can
C O O C
tert-Butyl peroxy-2-ethylhexanoate [3006-82-4] 216.3 7.40 113 91 72 1.54E+14 124.90
TRIGONOX 21S 97 7.17 liquid 10 -30 35 25 20 3113 HDPE can
TRIGONOX 21-C70 CN ONC CH 70 5.18 solution in odorless mineral spirits 10 -30 35 25 20 3113 HDPE can
3
TRIGONOX 21-C50 N N 50 3.70 solution in odorless mineral spirits 10 -30 40 35 30 3119 *HDPE can / IBC
CH (CH ) CH C O O C CH
3 23 3
TRIGONOX 21-C30 30 2.22 solution in odorless mineral spirits 10 -10 40 35 30 3119 IBC
CH CH
2 5 3 10 -10 25 20 15 3119 Bulk
tert-Butyl peroxydiethylacetate [2550-33-6] 188.3 8.50 113 93 75 2.45E+15 134.00
TRIGONOX 27 96 8.16 liquid 15 -30 35 25 20 3113 HDPE can
O CH
3
CH CH C O O C CH
2 5 3
CH CH
2 5 3
16 17
Our initiators for acrylics
PRODUCT NAME CHEMICAL NAME [CAS NUMBER] GENERAL DATA STORAGE KINETIC DATA SAFETY DATA STANDARD
DATA T (°C) for t1/2 PACKAGE TYPE
Molecular Assay (%) Active oxygen (%) Physical form Ts Ts 0.1 h 1.0 h 10 h A (1/s) Ea SADT Tem Tc UN See page 13
weight max. min. (kJ/mole) (°C) (°C) (°C) No.
(°C) (°C)
1,1’-Azodi(hexahydrobenzonitrile) [2094-98-6] 244.3 123 103 85 1.10E+16 142.
PERKADOX ACCN 98 powder 35 80 3226 fiber drum
1,1-Di(tert-butylperoxy)-3,3,5-trimethylcyclohexane [6731-36-8] 302.5 10.58 128 105 85 7.59E+13 127.52
TRIGONOX 29 95 10.05 liquid 25 60 3101 HDPE can
CH3 CH3
TRIGONOX 29-B90 90 9.52 solution in dibutyl phthalate 25 -10 60 3103 HDPE can
CH3 C O O O O C CH3
TRIGONOX 29-C75 75 7.93 solution in odorless mineral spirits 25 60 3103 HDPE can
CH3 CH3
CH3
CH3 CH3
2,2-Di(4,4-di(tert-butylperoxy)cyclohexyl)propane [1705-60-8] 560.8 25 128 106 87 8.79E+14 135.56 55
PERKADOX 12-XL25 CH3 CH3 2.9 liquid <35 3107 10 kg can
CH3 C CH3 CH3 C CH3
O O
O CH3 O
C
O H H O
O CH3 O
CH3 C CH3 CH3 C CH3
CH3 CH3

1,1-Di(tert-butylperoxy)cyclohexane [3006-86-8] 260.4 12.29 134 113 94 3.47E+15 142.40
TRIGONOX 22-C80 80 9.83 solution in odorless mineral spirits 25 60 3103 HDPE can
CH3 CH3
CH3 C O O O O C CH3
CH3 CH3
tert-Amylperoxy 2-ethylhexyl carbonate [70833-40-8] 260.4 6.14 134 113 95 2.22E+16 148.41
TRIGONOX 131 94 5.77 liquid 20 55 3105 HDPE can
O CH
3
CH (CH ) CH CH O C O O C CH
3 23 2 2 5
CH CH
2 5 3
tert-Amyl peroxyacetate [690-83-5] 146.2 10.94 134 114 96 6.59E+16 152.16
TRIGONOX 133-CK60 60 6.57 solution in odorless mineral spirits 30 60 3105 HDPE can
O CH
3
CH C O O C C H
3 2 5
CH
3
18 19
Our initiators for acrylics
PRODUCT NAME CHEMICAL NAME [CAS NUMBER] GENERAL DATA STORAGE KINETIC DATA SAFETY DATA STANDARD
DATA T (°C) for t1/2 PACKAGE TYPE
Molecular Assay (%) Active oxygen (%) Physical form Ts Ts 0.1 h 1.0 h 10 h A (1/s) Ea SADT Tem Tc UN See page 13
weight max. min. (kJ/mole) (°C) (°C) (°C) No.
(°C) (°C)
tert-Butyl peroxy-3,5,5-trimethylhexanoate [13122-18-4] 230.3 6.95 135 114 94 1.94E+15 140.78
TRIGONOX 42S 97 6.74 liquid 25 -20 55 3105 HDPE can
CH3 O CH3
CH C CH CH CH C O O C CH
3 2 2 3
CH CH CH
3 3 3
2,2-Di(tert-butylperoxy)butane [2167-23-9] 234.3 13.66 136 116 98 9.30E+16 154.08
TRIGONOX D-C50 50 6.83 solution in odorless mineral spirits 30 70 3103 HDPE can
TRIGONOX D-E50 CH CH CH 50 6.83 solution in mineral oil 30 80 3103 HDPE can
3 3 3
CH C O O C O O C CH
3 3
CH CH CH
3 2 5 3
tert-Butylperoxy isopropyl carbonate [2372-21-6] 176.2 9.08 137 117 98 2.49E+16 150.15
TRIGONOX BPIC-C75 75 6.81 solution in odorless mineral spirits 25 -20 70 3103 HDPE can
O CH3
CH CH O C O O C CH
3 3
CH CH
3 3
tert-Butylperoxy 2-ethylhexyl carbonate [34443-12-4] 246.3 6.49 137 117 98 4.07E+16 151.72
TRIGONOX 117 95 6.17 liquid 20 60 3105 HDPE can
O CH
3
CH (CH ) CH CH O C O O C CH
3 23 2 3
CH CH
2 5 3
tert-Amyl peroxybenzoate [4511-39-1] 208.3 7.68 139 118 99 8.38E+15 147.02
TRIGONOX 127 94 7.22 liquid 20 60 3103 HDPE can
O CH
3
C O O C C H
2 5
CH
3
tert-Butyl peroxyacetate [107-71-1] 132.2 12.11 139 119 100 1.57E+16 149.36
TRIGONOX F-C50 50 6.05 solution in odorless mineral spirits 10 -15 70 3103 HDPE can
O CH
3
CH C O O C CH
3 3
CH
3
tert-Butyl peroxybenzoate [614-45-9] 194.2 8.24 142 122 103 2.23E+16 151.59
TRIGONOX C 98 8.07 liquid 25 10 60 3103 HDPE can
TRIGONOX C-C75 O CH 75 6.18 solution in odorless mineral spirits 25 0 60 3105 HDPE can
3
C O O C CH
3
CH
3