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Industrial Pollution Prevention PDF

371 Pages·1995·8.094 MB·English
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Environmental Engineering Series Editors: U. Forstner, R. J. Murphy, W. H Rulkens Thomas T. Shen Industrial Pollution Prevention With 26 Figures Springer-Verlag Berlin Heidelberg GmbH Series Editors Prof. Dr. U. Forstner Arbeitsbereich Umweltschutztechnik Technische Universitat Hamburg-Harburg EiBendorfer StraBe 40 D-21073 Hamburg, Germany Prof. Robert J. Murphy Dept. of Civil Engineering and Mechanics College ofE ngineering University of South Florida 4202 East Fowler Avenue, ENG 118 Tampa, FL 33620-5350, USA Prof. Dr. ir. W. H. Rulkens Wageningen Agricultural University Dept. of Environmental Technology Bomenweg 2, P.O. Box 8129 NL-6700 EV Wageningen, The Netherlands Author Professor Thomas T. Shen 146 FembankAvenue Delmar, NY 12054 USA ISBN 978-3-662-03112-4 ISBN 978-3-662-03110-0 (eBook) DOI 10.1007/978-3-662-03110-0 Cip data applied for This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in other ways, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer-Verlag Berlin Heidelberg GmbH. Violations are liable for prosecution act under German Copyright Law. © Springer-Verlag Berlin Heidelberg 1995 Origina1ly published by Springer-Verlag Berlin Heidelberg New York in 1995 Softcover reprint oft he hardcover 1st edition 1995 The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Typesetting: Data-conversion by Fotosatz-Service Kohler OHG, Wiirzburg SPIN:I0085963 61/3020-5 432 1 0 -Printed on acid-free paper Preface The inexorable growth in the scale of industrial production has resulted in the inexorable growth in environmental pollution worldwide. Although pollution control has improved in environmental quality to a certain extent, but in general, it not only fails tp eliminate pollutants but also often transfers them from one medium to another. Pollution prevention is the current environmental manage ment strategy to minimize pollution problems. It seeks to establish a society oriented approach towards sustainable development by encouraging society to prevent pollution so as not to waste our natural resources. This book is conceived as a reference and a training textbook for those who are interested in and responsible for pollution prevention. It will help readers understand the principles and practices of industrial pollution prevention with guidelines for pollution prevention projects and explanations of the benefits of pollution prevention. This book suggests ways to conduct pollution prevention feasibility analyses and to establish and implement pollution prevention pro grams; illustrates how to measure progress of pollution prevention programs; relates some of the essential governmental and industrial pollution prevention programs and projects; discusses subjects such as toxic chemicals, industrial and hazardous wastes, materials and product design for the environment; and covers policy issues and economic analyses. Industrial pollution prevention begins in the early stages of process develop ment and product design. Because the author addresses the most recent develop ments in theory and methodology for environmentally and economically viable solutions, this book is an important and handy reference for environmental lawyers, economists, ecologists, and politicians, as well as a valuable textbook for graduate engineering and business students. The book consists of 16 chapters with appendi ces which comprise of forms, worksheets, checklists and reading suggestions. I would like to especially thank the following individuals who have assisted me in reviewing the manuscript chapters: Joseph T. Ling, Ph.D., Retired Vice President of 3M Company Frances Irwin, Ph.D., Director of Pollution Prevention Office, World Wildlife Foundation Edward Chian, Ph.D., Professor of Georgia Institute of Technology Joyce Shen Shavers, 1.D. , Associate of Simpson Thacher & Bartlett Mary Warner, Section Chief, Pollution Prevention Unit, NYS Dept. of Env. Conservation VI Preface I would also like to thank Dr. Ling of 3M Company and Dr. Granville Sewell (deceased) of Columbia University for their early encouragement and inspiration; Mr. and Mrs. Nei-juin Zhou for their continual help in preparing the tables and figures; Mr. John Iannotti for the material on Section 16.1 of the New York State Pollution Prevention Programs; and my wife, Cynthia and two daughters, Joyce and Grace, for their support, while this book would have been impossible without the aid and support of all these individuals. Foreword Sustainable economic development is necessary to improve the standard of living and quality of life in the developing countries. It is also required to maintain or enhance their attributes for those lands already commercially developed. Past experience indicates that one of the most important elements in the economic growth is the development of industry. It should be also recognized that develop ing industry, if pursued according to the traditional means, entails the additional inefficient consumption of limited national resource and generation of large amount of residue that called industrial pollution. In general, industry has three generations of pollution problems. The first generation pollution problem is from the manufacturing facilities. The second generation pollution problem is related to the use of the products after leaving the site of manufacturing. The final disposal of the used or unused products repre sents the third-generation pollution problem for industry. The traditional way of controlling pollution by industry is building costly waste treatment facilities added-on to the end of manufacturing processes. Industry also has to commit continuous funding to maintain and operate these facilities for their entire life span. The waste treatment facilities were supposed to solve the manufacturing related pollution problem for industry, i.e., the first generation problem. In fact, these facilities, in according to the Law of Conser vation, do not make the pollution disappeared. They only transform, accumulate and generate residues of different forms which create separate control problems of their own. This becomes a Catch 22 situation. It take resources to remove pollution; pollution removal generates residue. It take more resources to dispose of these residues. Disposal of these residues also produces pollution. It can be visualized that this approach will not be able to provide a final solution to the industry's first-generation pollution problem and leaves the second and third generation pollution problem untouched. It becomes very clear that, solving the industrial pollution problem more effi ciently and effectively, a new approach is needed. The concept of pollution pre vention was born. The primary purpose of this book is to provide industry with the needed information and methods to plan and implement pollution prevention programs, and with successful examples. The book can also be used as a course manual or references for education and training purposes. The very first coordinated company-wide industrial pollution prevention pro gram was initiated in 1975 in the 3M Company, a multi-national enterprise with operations in over 50 countries. The basic concept of this program, i.e., Pollution VIII Foreword Prevention Pays Program (3P Program, in short), was that eliminating or reducing the pollution at the source will eliminate or reduce the clean-up costs and it will also provide some solutions to the second- and third-generation pollution problems. Since most pollutants are actually valuable raw materials passing through the manufacturing processes, preventing the generation of pollution will also conserve raw materials and make the manufacturing processes more effi ciently and less costly. The 3P program in 3M Company consisted of two parts. Part I is Process Environmental Assessment which is to· solve the first-generation pollution problems. The Product Environmental Assessment (Part II) is to looking for solutions to the second-and third-generation pollution problems. In the first year, the 3P program achieved significant environmental gain and produces a saving of some 20 million dollars. At the invitation of the United Nations Economic Commission (UNEC) for Europe, the results of 3P program were presented to the Conference of Non-waste Technology and Production in Paris in 1976. The presentation was very well received. The UNEC requested if a book could be prepared about this 3P new approach so that many industries in other countries could be benefited. Due to the many other commitments, I declined to the request but committed to prepare a 30-page booklet "Low- or Non-Pollution Technology Through Pollution Prevention". It was published and widely distributed by the United Nations Environment program (UNEP) at its Annual Meeting in Nairobi, Kenya. Meanwhile Dr. Michael Rayston of the Center For Education in International Management in Geneva volunteered to prepare a book with the title of "Pollution Prevention Pays" and I was honored to write the Foreword. Since then, many countries and many international organiza tions and industries established their oWn instruments to promote and implement the preventive concept in their environmental programs, including the United Nations Environmental Program (UNEP) and Organization of Economic Coope ration and Development (OECD). In the United States, the US Environmental Protection Agency (USEPA) and US Department of Commerce also indicated their interest in the pollution pre vention approach. In 1977, they jointly sponsored four regional conferences in Chicago, Boston, Dallas and San Francisco to encourage other industry elimina ting pollution at the sources. However, U.S. Congress did not recognize the merit of the preventive approach until the hazardous wastes became an issue. Because the distribution of hazardous wastes was so widely scattered and the control tech nology was lacking, the Congress called for preventing and minimizing the gene ration hazardous waste when the Resources Conservation and Recovery Act (RCRA) was amended in 1984. In 1989, the USEPA established an Office of Pol lution Prevention and issued a national policy statement on pollution prevention. Finally, the Congress adopted the Pollution Prevention Act in 1990. USEPA also funded the American Institute For Pollution Prevention (AIPP) to promote the preventive approach and I was honored to be the first chairman. It took 20 years before the benefit of pollution prevention is fully recognized. The Clinton Administration declared that pollution prevention is the "Comer Foreword IX Stone" of its environmental program. Chapter 14 of this book has compiled a number of successful pollution prevention examples. In spite of these positive results, a large number of industries are not taking the advantage of this preven tive approach as yet. This is especially true for the small-and medium-sized com panies, and even more true for many of new and old industrial facilities in most developing countries. It is my sincere hope that the book will provide additional encouragement to those who may want to start their own pollution prevention programs. The very first worldwide environmental concern was initiated at the World Conference on Human and the Environment sponsored in the United Nations in Stockholm in 1972. The most visible result of the Conference was the creation of the United Nations Environment Program (UNEP). As UNEP promoting en vironmental enhancement program around the world, it encountered tremendous resistance during the 1970's when many countries suffered much economic diffi culties. It was then realized that when governments are busy fighting the unem ployment and other economic and social issues, environment becomes an unim portant matter. In responses to this significant revelation, the United Nations General Assembly created a World Commission on Environment and Develop ment in 1984. After 3-year deliberation, this Commission issued its final report "Our Common Future" which called for "Sustainable Development". This con cept was further confirmed by the United Nations Conference on Environment and Development which was held in Rio de Janeiro in 1992. The Conference con cluded that "Sustainable Development" is the realistic way to meet the needs of the present without compromising the ability of future generation to meet their own needs. Of course, maintaining a livable environment is a very important ele ment in the "Sustainable Development". To follow-up the recommendation of "Sustainable Development", the United Nations established an UN Commission on Sustainable Development. The Clin ton Administration also formed a President's Commission on Sustainable Devel opment. It is clear that "Sustainable Development" is the pew challenge for the years to come and industry has a major role to playas described in Chapter 12 of this book. It is my believe that tl:te most important contribution of industry to the "Sustainable Development" is the developing and marketing environmentally compatible products with minimum use of non-renewable resources. Industry can achieve this by intelligently applying the pollution prevention concept with pro duct life cycle analysis and assessment approach in the product design, and con sidering environmental problems not constrains but opportunities, and producing no or minimum environmental impact as the design objective. In other words, pollution prevention remains as a very valuable tool to meet this new challenge. More detailed discussions are presented in Chapter 10 of the book. It is essential that other sectors of society, in addition to industry, must also cooperate to accomplish this goal of "Sustainable Development". This includes government and the general public as discussed in Chapter 15 of this book. The government must build resource and environmental concerns into its existing and x Foreword new policies, regulations, programs, covering not only in the environmental field but also in the areas related to economic development, land use, city planning, transportation, agriculture, mining and energy development. The public must demand and support appropriate governmental actions and private initiatives to encourage environmentally friendly programs. The public should also open to the idea of modifying life style and consuming habits to reduce their own impact to the environment and the associated non-renewable resource. Experience revealed that it does not always require highly sophisticated tech nology nor large sum of expenditure for preventing the pollution at its source. When pollution prevention is properly implemented, industry will not only be able to meet their environmental requirements efficiently but also work toward the goal of the new challenge "Sustainable Development". The advantages of pollution prevention are many as described in this book. Dr. Shen took tremendous effort of collecting, reviewing, and compiling a large amount of useful information and data, and carefully explained the essential knowledge required and the steps to be taken in planning and implementing in dustrial pollution prevention programs. This is an excellent guidebook for those industries, governments, universities and professionals who are contemplating to start or plan a pollution prevention program. Because of the immense challenge and tremendous opportunity present ed, Dr. Shen's book is especially timely and welcome. Dr. Joseph T. Ling, Ph. D. Vice President (Retired) Responsible for Environmental Quality 3M Company Contents 1 Introduction . . . . . . . . . 1 1.1 The Environmental Challenge 1 1.2 Industrial Pollution Problems 2 1.3 Environmental Management Strategies 9 1.4 Purpose.............. 12 2 Industrial Pollution Prevention 15 2.1 What is Pollution? . . . . . . . . 16 2.2 What is Pollution Prevention? . . 17 2.3 Benefits of Pollution Prevention 19 2.4 The U. S. Pollution Prevention Program 22 2.5 USEPA's Pollution Prevention Research Program 32 2.6 Education and Training ........ . 33 3 Toxic Chemicals and Processes Wastes 37 3.1 Industrial Processes .. 38 3.2 Industrial Wastes .... 40 3.3 Waste Characterization 44 3.4 Toxic Chemicals .... 45 3.5 Legislation and Regulation. 50 4 Pollution Prevention Technology . 59 4.1 Improved Plant Operations. 59 4.2 In-Process Recycling. . . . . . . . 63 4.3 Process Modification ...... . 64 4.4 Materials and Product Substitutions 65 4.5 Materials Separation . . . . . . . 67 4.6 Technology Update ...... . 70 4.7 Solvent Alternative Technologies 73 4.8 Risk Assessment . . . . . . . . . 74 5 Environmental Management Audit 83 5.1 Why Audit? . . . . . . . . . . . . 83 5.2 Why Waste is Generated? ..... 84 5.3 Environmental Management Audit 87 5.4 Facility Environmental Auditing .. 91 5.5 Development and Implemention of Environmental Auditing 93

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