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Industrial Minerals and Rocks PDF

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Further titles in this series 1. I.L. ELLIOT and W. K. FLETCHER (Editors) GEOCHEMICAL EXPLORATION 1974 2. P.M. D. BRADSHAW (Editor) CONCEPTUAL MODELS IN EXPLORATION GEOCHEMISTRY The Canadian Cordillera and Canadian Shield 3. G.J. S. GOVETT and M. H. GOVETT (Editors) WORLD MINERAL SUPPLIES Assessment and Perspective 4. R.T. S HUE Y SEMICONDUCTING ORE MINERALS 5. J.S. SUMNER PRINCIPLES OF INDUCED POLARIZATION FOR GEOPHYSICAL EXPLORATION 6. R. A. RICH, H. D. HOLLAND and U. PETERSEN HYDROTHERMAL URANIUM DEPOSITS 7. J.G. MORSE (Editor) NUCLEAR METHODS IN MINERAL EXPLORATION AND PRODUCTION 8. M. KUlVART and M. BÖHMER PROSPECTING AND EXPLORATION FOR MINERAL DEPOSITS 9. C.R. M. BUTT and I. G. P. WILDING (Editors) GEOCHEMICAL EXPLORATION 1976 10. G.B. FETTWEIS WORLD COAL RESOURCES Methods of Assessments and Results 11. R.G. TAYLOR GEOLOGY OF TIN DEPOSITS 12. H.K. GUPTA GEOTHERMAL RESOURCES An Energy Alternative 13. C. RM. BUTT and R E. SMITH (Editors) CONCEPTUAL MODELS IN EXPLORATION GEOCHEMISTRY, 4 Australia 14. G. BÁRDOSSY KARSTIC BAUXITES 1 5. A. W. ROSE and H. GUNDLACH (Editors) GEOCHEMICAL EXPLORATION 1980 16. R. W. BOYLE GEOCHEMICAL PROSPECTING FOR THORIUM AND URANIUM DEPOSITS 17. G. R. PARSLOW (Editor) GEOCHEMICAL EXPLORATION 1982 18. M. KUlVART INDUSTRIAL MINERALS AND ROCKS Developments in Economic Geology, 18 INDUSTRIAL MINERALS AND ROCKS MILOS KUZVART Associate Professor Department of Geology at the Fatuity of Natural Sciences, Charles University, Prague ELSEVIER Amsterdam - Oxford - New York - Tokyo 1984 Scientific Editor Doc. RNDr. Jan Petránek, DrSc. Reviewer RNDr. Vaclav Harms, CSc. Published in co-edition with ACADEMIA, Publishing House of the Czechoslovak Academy of Sciences, Prague Distribution of this book is being handled by the following publishers for the U. S. A. and Canada Elsevier Science Publishing Company, Inc. 52 Vanderbilt Avenue New York, N. Y. 10017, U. S. A. for the East European Countries, China, Northern Korea, Cuba, Vietnam and Mongolia Academia, Publishing House of the Czechoslovak Academy of Sciences, Prague for all remaining areas Elsevier Science Publishers B. V. P. O. Box 211, 1000 AE Amsterdam/The Netherlands Library of Congress Cataloging in Publication Data Ku£vart, MiloS. Industrial minerals and rocks. (Developments in economic geology ; 18) Translated from the Czech. Bibliography: p. Includes index. 1. Mines and mineral resources. 2. Geology, Economic. I. Title. II. Series. TN263.K89 198U 553 8I+-60U0 ISBN 0-4kk- 99605-2 ISBN 0 - 444 - 99605 - 2 (Vol. 18) ISBN 0 - 444 - 41250 - 6 (Series) With 100 Illustrations © M. Kuzvart, Prague 1984 Translation © H. Zárubová 1984 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording,or otherwise, without the prior written permission of the publishers Printed in Czechoslovakia This book is dedicated to two outstanding specialists in the field of industriel minerals and rocks to Professor Emeritus of the Ohio state University Robert L. Bates and to the memory of Professor of the Gorny Institute in Leningrad Pavel Mikhailovich Tatarinov 5 An aura of adventure and romanoe has grown up about the search for 011 and the aristocratic metals; we have recently ob served one being built up around uranium. While the gold rush mS7 never be matohed by a sand-and-gravel rush, nevertheles. some nonmetallics came tro. deposit. com parable in value to the richer metal de posits. Robert L. Bates (1969): GeologJ of the Industrial Minerals and Rooks 7 Preface This handbook has grown out of the lectures the author has giren at the Faculty of Sciences at Charles University. It takes into consi- deration the world literature on the subject and the work done by Czech and Slovak economic geologists since the establishment of centralized geological servioe in Czechoslovakia in 1952; these results were pub- lished in scientific journals, archive reports, and especially in mo- nographs on the industrial minerals* Czechoslovakia provides a particularly suitable setting for the study of industrial mineral deposits· More than 800 such deposits (In- cluding building materials) are being worked there at the present time, and have been the subject of exploration in the last thirty years· The author has had the privilege of complementing his experience In the exploration of various non-metalllo deposits in Czechoslovakia, mainly of talc, magneslte, kaolin and clay, by visits to deposits of industrial minerals abroad· During 1956-1976 he had the opportunity ol studying the deposits of cement materials in Egypt and Guinea, of ce- ramic and other raw materials in Japan, Mongolia, Turkey, Iraq, Nige- ria, Ghana, Spain, England, France, F.R.G·, G.D.R., Poland, Hungary and Bulgaria· The practical Importance of industrial minerals lies in their ap- plication in modern industry· Progress in atomic and nuclear technique, in space research and in the protection of the human environment often demands new non-metallic materials or leads to new applications for those already known· Industrial minerals are typical raw materials of the second industrial revolution; they are the raw materials of the third mlllenlum· 13 1. INTRODUCTION The geology of mineral raw materials deals with ores,industrial minerals and rocks, coal, oil and natural gas· Together with hydrogeo- logy, engineering geology, applied geophysics, and the prospecting for and exploration of the deposits of raw materials,it forms part of eco- nomic geology, which is based on the theoretical results of all geolo- gical and allied sciences· The theoretical basis of economic geology uses the results of applied mathematics, physics and chemistry· The study of mineral deposits utilises theoretical and practical results of mineralogy, geochemistry, petrology, stratigraphies! and structural geology, mining, geodesy, economics, technical sciences and other scien- tific branches· The geology of the deposits of industrial minerals and rocks pro- vides the mining industry with data on the location, size and quality of deposits that are a prerequisite for their utilization. The use of industrial minerals is of extraordinary importance for the civilization and culture of mankind »In the U.S.A.. the exploitation of non-metallic minerals and metals amounts to 18 tons per oaplta per year in 1979· The energy consumption corresponds to the performance of twelve horses working day and night for every single inhabitant of the U.S.A. The consumption of mineral raw materials and energy by the Austra- lian aborigines, from whom an idea of the technological knowledge and cultural requirements of Stone Age Man can be formed, makes a few kilo- grams of stone and several faggots of wood per year (leaving aside the heating value of a hairless breed of dogs providing a source of warmth at night)· The main discrepancy of the modern world - the difference between highly industrialized and developing countries - is also manifested in the exploitation and consumption of mineral materials. The industrial countries with 30 % of world population govern 80 % of the world eco- nomy. The developing countries furnish to the industrial countries with 15 % of their intake of raw materials· The world commerce in mineral raw materials comprises about one fourth of the total world commerce. 1.1 The term "Industrial minerals and rocks" The term "industrial mineral" is not defined so strictly as the term "ore", which is mostly a source of metal, or as that of "fossil fuel" (coal, oil, natural gas), which is predominantly a source of 14 energy· In both the latter oases the characteristic feature is the che- mistry of the ore (besides the content of impurities,dressability,etc·) or fuel (besides the content of dirt bands, sulphur, etc.)· The charac- teristic features of industrial minerals, however, lie in their physi- cal properties (e*g·, fibrosity of asbestos, insulatory properties of mica, the high specific gravity of barite)· Therefore, not only geolo- gical, but also technological evaluation of raw material is of importan- ce in the study of industrial minerals· In this handbook raw materials of several types are considered under the term "industrial minerals and rocks"ι 1. raw materials that are used in industry in variously prepared forms of minerals (e.g. talc, asbestos, diamond) or rooks (e.g., diatoma- ceous earth, bentonite, ochre); 2. raw materials that serve as a source of non-metallic elements (py- rite as a source of sulphur, fluorite for fluorine, apatite for phosphorus) or their simple compounds (e.g· borates for ELBO^ cr B 0 ); 2 3 3· raw materials of non-metallic habit that are sources of metals, and also of their compounds employed in other than metallurgical indus- tries (e.g· beryl as a source of BeO, magnesite of MgO, and bauxite or Al-laterite as a source of AlgO^j all these three oxides are re- fractory materials· Nickel-bearing latérite, which is a source of nickel does not belong in this category); 4· building materials (e.g. granite, gravel and sand, brickloam)· In the division of mineral raw materials (except for fossil fuels) the term "non-ore" is only used in the Czech and older German and Polish literature· The Anglo-Saxon and Russian literatures use the terms "non- -metallio" or "industrial minerals or rocks" to denote the "non-ores"; on the other hand, the term "ore" is also employed, for example, for asbestos, talc, magnesite and similar raw materials· Some raw materials have a twofold use· Hematite, for example, is a Fe-mineral and simultaneously a component of mineral pigment,or chro- mite is a chromium ore and refractory material and abrasive material as well· 1.2 Classification of industrial minerals and rocks and principal textbooks on this subject The classification principles, their advantages and drawbacks and a list of the principal textbooks are given in Table 1. Opinions on the genesis of non-metallic deposits, their use in industry and their economic usefulness are changing with the development of investigatory 15 - k- dn. ni eig s s cis t . i t r mi les iaed(e)jt ec te olc cc en p e nacs oasti s m ocul slplo a a cisa spurp r eg i a oow l a onr erue a p ,lee yrgli c coet la fv ig r s inwa l t gn e k thtm asn+c oi h c ece cle ig lk td a nebw iaremn oc oe b et a tretoi na t w g r eefink hl yt a de nnfroc c ni r onge eiiaca es am D naav gmdbel ti mo s ion ex c w rd-a- k t d ie oc o aon dti ci o tti nev cl r s n an ap e eg+ ef p d g in ogo na n a rit i o a t odn mys io n re olt st s a yot ntn i n l v scn ori vgo a d aco cao ini r A eac epp dit e n i s m ' , d 105 c ndustrial s of worlure yers, 195 ed., I96 197ed.f 1967 VakanJ ae f1969 c,1970 1970 ki, 1974 i et Mn i a s la -od , v j , w n pr osn a o n e o o me olo n k a n l at dlf a n k i z s xi aie r a a l o k El LGL B J V K K o o b , t s l l , ons and basic tex ect ngement of ma-als from abra-s to zeolites ngement after ical system of rals(element s, ids,hydroxides, ) sion of non-ores elements,crystalrals and rocks sion into chemicarals (source of ents) and physicarals (used as rals) sion into igneousmentary,metamor-ed, hydro thermal-asomatic rooks i j aie ameo. ioe iemee iist t b rrv renlc vtn vnenn vdoe a u xei rhiat ini iilii iehm c S ets acmhe dim dmemm dsp- i f i l l s l -a a as al ca coic ic l c i ih h c e i g gp p l t - o oa -l -a 1 of ip be coal algr coca icgr able ist rino lpha hemiiner ineretro hemihysi enet etro T L P a cm mp cp gp - h c e - - te o i g r l g n +a o o i n l k cs he s o c it cr i n a mc ea he l oe t t cr np s c ea s os dt e t i ca nc p s e ae s +t y l p a c g ,a cs ce o ccg iag cg ipg l iin m n in msn o tgi oli ti oai n eok nak ek n k h nlc occ nc olc c eoa cia ea caa e gnl egl gl ecl t n ref ) e oho -lgt - k- ft iann tsai s giiec rtts egse cf otnmi on nn lntp io larpts piwoo biiy m opeoet moeci adst ot nsclnc ipi t tio nnw o+neee voa ivpl oie rlovgp ot tr uiel coi hace s wnfne sdda epv cc(d+a taoid * 968 955; al.,I96464; 69; 69; 72 ht,1962 \ni,19681 1968,· ., 1969 1 1t9999 gi,d i, , e 11 1,1 rirtij e 69 ck ovkio,, v,yk ,WMaskov 19 e nstvoz t vn i iwaonc t,oi , w rennuz ezkr s a ajirzs ntia e r taviru rnlt t o aramor ueua a M TKCSBG BBKT B - s , -t l s sl f,o - ts a l- -pa osi,o , so i ao eur argil-+ loose l types ,non-oreo magmatatheringetamorph chemicalaterialscommon s workedle (indud rare corked on(industr w materinetic pr ion into lnd«minhese groon (mineneous, tc.) lstem m lanw ae sdtiee into solids of a (orel) inic, wary, intoding intoteriage scks) aials scale) of rnerog diviks anthin divisendogary, n,l nsitt nlnarcr s ni cci t osa otoin oiomaoell om iowcsn iui ii te iui lrtla i s mr ike sor ss,ame sbsp aar sre o ;tom iee iolmii i iaalmme iec n.seoi vct vpagdn vdve a sn vtn odlnrd iaa ieoeee inihniy i ifi cnae e dlm ddcpsg dadcorlam dav eirg+s , l a c i l physical genetic t echnologeconomic regional-geologica genetic- economic

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