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INDUSTRIAL CORROSION AND CORROSION CONTROL TECHNOLOGY H.M. Shalaby A. Al-Hashem M. Lowther J. Al-Besharah (Editors) Published By Kuwait Institute for Scientific Research INDUSTRIAL CORROSION AND CORROSION CONTROL TECHNOLOGY 1996 Sponsored by the Kuwait Institute for Scientific Research (KISR), the Kuwait Foundation for the Advancement of Science (KFAS), the Kuwait National Petroleum Company (KNPC), the Kuwait Oil Company (KOC), Ministry of Electricity and Water (MEW), Kuwait University (KU), Ministry of Oil (MO), the Gulf Cooperation Council-General Secretariat (GCC), Kuwait Chemical Society (KCS), Organization of Arab Petroleum Exporting Countries (OAPEC), and Petrochemical Industries Company (PIC). INDUSTRIAL CORROSION AND CORROSION CONTROL TECHNOLOY Proceedings of the 2nd Arabian Corrosion Conference Kuwait, October 12-15, 1996 Editors H.M. Shalaby, A. Al-Hashem, M. Lowther and J. Al-Besharah PUBLISHED BY KUWAIT INSTITUTE FOR SCIENTIFIC RESEARCH P.O. BOX 24885, 13109 SAFAT, KUWAIT Published by Kuwait Institute for Scientific Research P.O. Box 24885, 13109 Safat, Kuwait Publication Number: KISR 4890 Copyright ® 1996 by Kuwait Institute for Scientific Research The papers were reviewed for their technical contents. Editing was restricted to matters of format, general organization and retyping. The editors assume no responsibility for the accuracy, completeness or usefulness of the information disclosed in this book. Unauthorized use might infringe on privately owned patents of publication right. Please contact the individual authors for permission to reprint or otherwise use information from their papers This book was printed in Kuwait The 2nd Arabian Corrosion Conference FOREWORD The 2nd Arabian Corrosion Conference was held in the state of Kuwait during the period 12- 15 October, 1996 under the auspices of H.H. Sheikh Saad Al-Abdullah Al-Salem Al-Sabah, Kuwait’s Crown Prince and Prime Minister. The present conference was scheduled to be held in Kuwait during 27-30 April, 1991, however, it was postponed due to the events that encompassed Kuwait and the Gulf region in 1990-1991. The 1st Arabian Corrosion Conference was held in Kuwait during 4-8 February, 1984. It was attended by over 300 scientists and engineers, representing 26 countries. The conference proceedings were published in two volumes by Pergamon Press under the title “Corrosion: Industrial Problems, Treatment and Control Techniques”. The conference provided a forum for the exchange of ideas between scientists and engineers from the region with their counterparts from the industrialized countries. The patronage of the present conference, the organizing bodies, and the emphasis on industrial corrosion and corrosion prevention reflect the keen interest of the countries in the region in actively combating corrosion problems. This also reflect the recognition of the economic impact resulting from the corrosion of materials. Kuwait and the other Arab countries rely heavily on the utilization of metallic materials in their oil-based industries. Seawater derived from the Arabian Gulf is used in water desalination and as an industrial cooling media. The salinity of the Arabian Gulf seawater is very high when compared to other seawater bodies. The Arabian Gulf countries are located in an arid environmental zone where the temperature during the summer months could reach 50oC and the humidity during the autumn season could become 80% in some of the Gulf states. All these factors contribute to the enhancement of the rate of corrosion of metals and/or cause unpredictable service failures. The program of the present conference includes a field visit to one of Kuwait’s modern refineries and a trip to one of Kuwait’s oil fields. The success of the conference is perhaps difficult to assess. However, the quality of the papers in this volume provides some indication. The Editors v PREFACE The technical program of the present conference includes five plenary lectures and fifty three scientific presentations from about twenty two countries. A number of honorary speakers, carefully selected from high ranking officials and policy makers, were also invited to address the conference. The honorary speakers are expected to provide an overview of the magnitude of corrosion related problems in the Middle East as well as the avenues of linkage between corrosion science and industrial applications. The conference papers were carefully selected to include a blend of fundamental and applied research, and industrial experience. Such a blend was thought to be essential for providing the participants from both industry and academia with a chance to become familiar with the challenges facing each group and the preventive actions to meet them. The papers were refereed in terms of scientific and technical content and format in accordance with internationally accepted standards. The papers in the proceedings are grouped in the following sections for quick reference: • Plenary Lectures • Oil Field Corrosion • Corrosion in Refinery and Petrochemical Industries • Seawater Corrosion • Corrosion in the Building Industry • Fundamental Aspects • Corrosion Protection and Monitoring • Corrosion Management • Novel Techniques The plenary papers are mostly reviews covering important topic related to the objectives of the conference. The remaining papers cover various topics of major importance to corrosion in general and particularly to the oil-based and desalination industries. A good number of papers delt with corrosion protection and new techniques for corrosion monitoring. The task of editing this volume was facilitated by the efforts of the International Advisory Committee and the Scientific Committee for the conference who reviewed all the papers. The editorial board gratefully acknowledge these efforts; the cooperation, time and effort of all authors ; and the management of the Kuwait Institute for Scientific Research for allocating the required resources to prepare the manuscript of this volume. The Editors vi TABLE OF CONTENTS Foreword............................................................................................................................................v Preface...............................................................................................................................................vi Organizing Committees......................................................................................................................xi Acknowledgement.............................................................................................................................xii PLENARY LECTURES Corrosion Management V. Ashworth........................................................................................................................................1 The Deterministic Prediction of Damage D.D. Macdonald...............................................................................................................................17 Relevance of Laboratory Corrosion Tests in Corrosivity Assessment and Materials Selection: Case Studies R.D. Kane.........................................................................................................................................37 Corrosion of Condensers in Multi Stage Flash Evaporation Distillers A.M. Shams El Din...........................................................................................................................49 Correct Materials Selection for Desalination -The Key To Plant Reliability J.W. Oldfield....................................................................................................................................67 OIL FIELD CORROSION Corrosivity Prediction for Co /H s Production Environments 2 2 S. Srinivasan and R.D. Kane.............................................................................................................89 Testing of Drilling Fluids Formulated From Tabuk Formation Clays M.N.J. Al-Awad, A.S. Dahab and M.E. El-Dahshan........................................................................111 Preventing Sulfate Scale Deposition in Oil Production Facilities C.J. Hinrichsen, M.J. McKinzie, S. He, J. Oddo, A.J. Gerbino, A.T. Kan, and M.B. Tomson...........127 Concerns Over the Selection of Biocides for Oil Fields and Power Plants: A Laboratory Corrosion Assessment J. Alhajji and M. Valliappan...........................................................................................................135 Evaluation of Microbially Influenced Corrosion Risks and Control Strategies in Seawater and Produced Water Injection Systems, Kuwait P.F. Sanders, M. Salman and K. Al-Muhanna.................................................................................149 Hydrogen Degradation of Steel - Diffusion and Deterioration M. Farzam...................................................................................................................................................165 Control Strategies for Thermophilic Sulphate-Reducing Bacteria P.F. Sanders, H.M. Lappin-Scott and C.J. Bass...............................................................................179 Corrosion Evaluation of Austenitic and Duplex Stainless Steels in Simulated Hydrogen Sulphide Containing Petrochemical Environments K. Saarinen and E. Hamalainen......................................................................................................191 vii Damage of Pump Linkages and Tool Joints Caused by Crack Corrosion A. Kinzel.........................................................................................................................................201 Analysis of Soils Possibility to Give Rise to Pipe Metal Stress Corrosion Cracking V.G. Antonov and S.A. Loubenski....................................................................................................209 A Mysterious Downhole Corrosion Failure in an Oil Well A. Husain and A. Hasan..................................................................................................................215 CORROSION IN REFINERY AND PETROCHEMICAL INDUSTRIES Methodologies for Assessment of Crude Oil Corrosivity in Petroleum Refining S. Tebbal and R.D. Kane.................................................................................................................225 New Nickel Alloys Solve Corrosion Problems of Various Industries D.C. Agarwal and W.R. Herda....................................................................................................................233 Macro-Micro Segregation Bands (MMB) as a Main Factor Influencing Steel Applicability for the Petroleum Industry A. Mazur.........................................................................................................................................245 Fluid Catalytic Cracking Interstage and High-Pressure Cooler Corrosion S.M. Halawani................................................................................................................................255 Assessment of Cracks in a High Pressure Multilayered Reactor for its Fitness for Purpose A.M. Askari, M.I. AL-Kandari and P.K. Mukhopadhyay.................................................................263 Polythionic Acid Stress Corrosion Cracking of Incoloy 800: Case Study and Failure Analysis M.S. Mostafa and S.A. Hajaj...........................................................................................................273 Corrosion of Tube Heaters in Refineries: Symptoms and Cures A. Attou , A. Rais and H. Smamen...................................................................................................283 SEAWATER CORROSION Super Duplex Grade UNS S32750 for Seawater Cooled Heat Exchangers P.A. Olsson and M.B. Newman.......................................................................................................289 Evaluation of Aluminum Alloy 5083 Weldments to Stress Corrosion Cracking in Seawater A. Saatchi, M.A. Golozar and R. Mozafarinia.................................................................................301 Cavitation Corrosion Behavior of Some Cast Alloys in Seawater A. Al-Hashem, P.G. Caceres and H.M. Shalaby..............................................................................311 Microbiologically Induced Corrosion of a Stainless Steel Pipe H.H. Lee, M. Ali and K. Al-Omrani................................................................................................323 A Laboratory Study of Service Failure of Al-Brass Tubes in Arabian Gulf Seawater H.M. Shalaby, W.T. Riad and V.K. Gouda......................................................................................329 CORROSION IN THE BUILDING INDUSTRY Corrosion of Reinforced Concrete Structures and the Effects of the Service Environment S. Al-Bahar and E.K. Attiogbe........................................................................................................341 Corrosion of Concrete in Seawater viii

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The 2nd Arabian Corrosion Conference was held in the state of Kuwait during the period 12-. 15 October, 1996 under INTRODUCTION. The purpose of . They feel a measure of personal control and perceive a personal benefit.
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