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Hydrogels for aqueous lithium/air battery cells PDF

27 Pages·2013·2.15 MB·English
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Preview Hydrogels for aqueous lithium/air battery cells

US 20090311567A1 (19) United States (12) Patent Application Publication (10) Pub. No.: US 2009/0311567 A1 Visco et al. (43) Pub. Date: Dec. 17, 2009 (54) HYDROGELS FOR AQUEOUS LITHIUM/AIR (22) Filed: Jun. 12, 2009 BATTERY CELLS Related US. Application Data (75) Inventors: Steven J. Visco, Berkeley, CA (60) Provisional application No. 61/061,972, ?led on Jun. (US); Lutgard C. De Jonghe, 16, 2008, provisional application No. 61/078,294, Lafayette, CA (US); Yevgeniy S. ?led on Jul. 3, 2008, provisional application No. Nimon, Danville, CA (U S); Alexei 61/159,786, ?led on Mar. 12,2009. Petrov, Walnut Creek, CA (U S); Publication Classi?cation Kirill Pridatko, Walnut Creek, CA (Us) (51) Int. Cl. H01M 4/02 (2006.01) H01M 6/04 (2006.01) Correspondence Address: Weaver Austin Villeneuve & Sampson LLP (52) us. c1. ........................................ .. 429/27; 29/6231 PO. BOX 70250 (57) ABSTRACT OAKLAND, CA 94612-0250 (US) Li/ air battery cells are con?gurable to achieve very high energy density. The cells include a protected a lithium metal (73) Assignee: POLYPLUS BATTERY or alloy anode and an aqueous catholyte in a cathode com COMPANY, Berkeley, CA (US) partment. In addition to the aqueous catholyte, components of the cathode compartment include an air cathode (e.g., oxygen (21) Appl. No.: 12/484,081 electrode) and a variety of other possible elements. 11 4 M Patent Application Publication Dec. 17, 2009 Sheet 1 0f 12 US 2009/0311567 A1 7 6 Figure 1A 0 \ 2 000000000000 000000 00000 0 OOOOOO 000000 n 0 Figure 1B Patent Application Publication Dec. 17, 2009 Sheet 2 0f 12 US 2009/0311567 A1 202 0 w%/////////////4 Figure 2A Figure 2B Figure 2C Figure 2D Patent Application Publication D u m 6 7 A 1 .U 7i Hw2ncoqmmt o o mW65E:. w. " w2w%.E ac“v0cn6 w NmEQ6ZE mw, “$E399625:0022 00 cIozw?w v moowwfi Ie ww r2- c0coc0So9ooom»mww :*2i:@302933t0032c23s8m2 5 2 A1 MumoN- w8 oF____ /Qm, m.m

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Jun 12, 2009 (43) Pub. Date: Dec. OAKLAND, CA 94612-0250 (US) . brane/catholyte interface during storage under open circuit . active salt is a nitrate (e. g., NH4NO3) or a halide or an ammo .. components or manufacturing, handling, storage or external . enhance the safety of a cell incorporatin
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