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1 Hydraulic Fracturing: 0 0 w 6.f 1 Environmental Issues 2 1 5- 1 0 2 k- b 1/ 2 0 1 0. 1 oi: d 5 | 1 0 2 5, 1 er b m e c e D b): e W e ( at D n o ati c bli u P In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. 1 0 0 w 6.f 1 2 1 5- 1 0 2 k- b 1/ 2 0 1 0. 1 oi: d 5 | 1 0 2 5, 1 er b m e c e D b): e W e ( at D n o ati c bli u P In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. 1216 ACS SYMPOSIUM SERIES Hydraulic Fracturing: Environmental Issues Donna L. Drogos, Editor 1 0 University of Wyoming 0 w 6.f Laramie, Wyoming 1 2 1 5- 1 0 2 k- b 1/ 2 0 1 0. 1 oi: d 5 | 1 0 2 5, 1 er b m e c e D b): e W e ( at D on Sponsored by the ati c ACSDivisionofEnvironmentalChemistry,Inc. bli u P AmericanChemicalSociety,Washington,DC DistributedinprintbyOxfordUniversityPress In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. LibraryofCongressCataloging-in-PublicationData Names:Drogos,DonnaL.,1943-editor.|AmericanChemicalSociety.Division ofEnvironmentalChemistry. Title:Hydraulicfracturing:environmentalissues/DonnaL.Drogos,editor, 1 UniversityofWyoming,Laramie,Wyoming;sponsoredbytheACSDivisionof 0 0 EnvironmentalChemistry. w 6.f Description:Washington,DC:AmericanChemicalSociety,[2015]|[Oxford]: 1 DistributedinprintbyOxfordUniversityPress|Series:ACSsymposium 2 5-1 series;1216|Includesbibliographicalreferencesandindex. 01 Identifiers:LCCN2015046407(print)|LCCN2015047109(ebook)|ISBN 2 k- 9780841231221(alk.paper)|ISBN9780841231214() b 1/ Subjects: LCSH:Hydraulicfracturing--Environmentalaspects. 2 0 Classification:LCCTD195.G3H93752015(print)|LCCTD195.G3(ebook)|DDC 1 0. 363.738--dc23 1 oi: LCrecordavailableathttp://lccn.loc.gov/2015046407 d 5 | 1 0 2 5, 1 er b ThepaperusedinthispublicationmeetstheminimumrequirementsofAmericanNational m e Standard for Information Sciences—Permanence of Paper for Printed Library Materials, c e D ANSIZ39.48n1984. b): We Copyright©2015AmericanChemicalSociety e ( at DistributedinprintbyOxfordUniversityPress D n atio AllRightsReserved. ReprographiccopyingbeyondthatpermittedbySections107or108 ublic o$f40th.2e5Up.Slu.sC$o0p.y7r5igphetrApacgtiesiasllpoawidedtofothreinCteorpnyarliguhsetConlelya,rapnroceviCdeednttehra,tIancp.e,r2-2c2haRpotesrefweoeoodf P Drive,Danvers,MA01923,USA.Republicationorreproductionforsaleofpagesinthis bookispermittedonlyunderlicensefromACS.Directtheseandotherpermissionrequests toACSCopyrightOffice,PublicationsDivision,115516thStreet,N.W.,Washington,DC 20036. Thecitationoftradenamesand/ornamesofmanufacturersinthispublicationisnottobe construedasanendorsementorasapprovalbyACSofthecommercialproductsorservices referenced herein; nor should the mere reference herein to any drawing, specification, chemicalprocess, orotherdataberegardedasalicenseorasaconveyanceofanyright or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce,use,orsellanypatentedinventionorcopyrightedworkthatmayinanywaybe relatedthereto. Registerednames,trademarks,etc.,usedinthispublication,evenwithout specificindicationthereof,arenottobeconsideredunprotectedbylaw. PRINTEDINTHEUNITEDSTATESOFAMERICA In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. Foreword The ACS Symposium Series was first published in 1974 to provide a mechanism for publishing symposia quickly in book form. The purpose of the series is to publish timely, comprehensive books developed from the ACS sponsoredsymposiabasedoncurrentscientificresearch. Occasionally,booksare 1 0 developed from symposia sponsored by other organizations when the topic is of 0 w 6.f keeninteresttothechemistryaudience. 1 2 1 5- Beforeagreeingtopublishabook,theproposedtableofcontentsisreviewed 1 0 forappropriateandcomprehensivecoverageandforinteresttotheaudience. Some 2 bk- papersmaybeexcludedtobetterfocusthebook;othersmaybeaddedtoprovide 1/ 2 comprehensiveness. When appropriate, overview or introductory chapters are 0 1 0. added. Draftsofchaptersarepeer-reviewedpriortofinalacceptanceorrejection, 1 oi: andmanuscriptsarepreparedincamera-readyformat. d 15 | As a rule, only original research papers and original review papers are 0 5, 2 included in the volumes. Verbatim reproductions of previous published papers er 1 arenotaccepted. b m e c e D b): ACSBooksDepartment e W e ( at D n o ati c bli u P In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. Editor’s Biography Donna L. Drogos 1 Donna L. Drogos, P.E., holds a Bachelor’s of Science degree in Civil 0 ot0 Engineering from the University of California at Berkeley, 1988; a Master’s 16. of Science degree in Environmental Engineering from the Georgia Institute of 2 5-1 Technology, 2014; and is a Registered Civil Engineer in the state of California. 1 0 Currently, she is pursuing a Doctorate in Civil Engineering at the University 2 k- of Wyoming. Her professional practice has focused on soil and groundwater b 21/ contamination, groundwater remediation, and contaminant hydrogeology, and 0 0.1 shehasexperienceasaregulator,responsibleparty,andconsultantforsubsurface 1 oi: contamination sites. Ms. Drogos also managed an engineering division at a 5 | d regulatory agency and is a member of the American Chemical Society and the 1 NationalGroundwaterAssociation. 0 2 5, 1 er b m e c e D b): e W e ( at D n o ati c bli u P ©2015AmericanChemicalSociety In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. Preface High volume hydraulic fracturing of deep shale deposits has transformed the oil and gas industry, catapulting the United States (U.S.) into the biggest oil and natural gas producer in the world, surpassing Russia as of June 2015. Hydraulic fracturing has been a game changer providing an important measure 1 0 of energy independence for the U.S. As one expert put it, “Shale deposits are 0 6.pr a gift from God.” Hydraulic fracturing operations in North Dakota’s Bakken 1 2 Shale, in the Marcellus formation in Pennsylvania, West Virginia, and Ohio, in 1 5- Texas’EagleFordandBarnettShale,andinthevicinityofPavillion,Wyoming, 1 0 2 Bainbridge,Ohio,andDimockandDunkardCreek,Pennsylvaniaarethesubject k- 1/b of increased media, public, and regulatory attention. New potential shale plays 2 0 acrosstheU.S.arealsobeingexamined,includingtheMontereyshaleformation 1 10. inCaliforniawherehydraulicfracturingisatimelyandsignificantenvironmental oi: issue with California’s recently enacted hydraulic fracturing regulations and d 5 | published scientific studies. Heightened interest in hydraulic fracturing is also 1 20 foundworldwide,particularlyintheUnitedKingdom,France,andPolandwhere 15, development of natural gas from unconventional sources are seen as a path to ber energyindependence. Morethanhalfoftheworld'sshaleoilresourcesarelocated m e in Russia, China, Argentina, and Libya, and development of these resources is c e D justbeginning. b): Concurrent with the increased development of unconventional hydrocarbon e W resources are concerns over perceived risks to the environment that have been e ( at raised at hydraulic fracturing locations throughout the U.S. The injection of D n millions of gallons of drilling fluids with chemical additives in boreholes o ati extending for miles to crack the shale and release oil and methane has led to c bli reports of contaminated water supplies, releases of chemically contaminated u P flowback fluids, air pollution, increased greenhouse gas emissions, and induced earthquakes. Proposals for acid fracturing have also raised concerns for the environment. The2015U.S.EnvironmentalProtectionAgency(USEPA)report determinedthathydraulicfracturinghasnotledtowidespreadimpactstodrinking water resources. However, the USEPA noted specific instances could lead to contamination, such as wells with inadequate casing and cementing, improperly handledortreatedflowbackandproductionfluids,andstimulationinformations containingbothoilandgasanddrinkingwaterresources. Highvolumefracturingofdeepshaledepositsalsoproduceslargequantities of wastewater over the production life of the well. The wastewaters are a mixture of the salts, metals, radionuclides, organics, and microorganisms in deep groundwater and dissolved from the geologic formation, as well as the introducedhydraulicfracturingfluids. Theexactcompositionvariesconsiderably ix In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. and depends upon the specific shale composition, the fracturing fluid chemical formulation tailored to that formation, and the source water for the hydraulic fracturing fluid. It is also dependent upon whether the wastewater is the initial flowbackwaterproducedinthefirstweeksofwelldevelopmentorthelong-term production waters generated over the lifetime of the well. The composition of theinjectedfracturingfluidalsoaltersthechemicalcompositionoftheformation waterandtheresultingproductionwater. These biogeochemical changes occurring in the millions of gallons of hydraulic fracturing wastewater creates a unique dilemma for the disposal and potential reuse of these waters. Traditional disposal options, such as municipal wastewatertreatmentplantsanddeepinjectionwells,arenowlessavailabledue to public concern over subsequent discharge to streams used as drinking water 1 sources and the increasing reports of induced seismicity. Existing treatment 0 0 pr options such as desalinization become cost prohibitive in treating wastewaters 16. that are many times saltier than seawater. Water reuse is becoming common 2 5-1 oftenrequiringnewtreatmenttechnologiestomakethewatersuitableforreusein 1 0 the hydraulic fracturing process. These technical challenges posed by hydraulic 2 bk- fracturing have fostered increased research into the technologies needed to 21/ developtheseoilandgasresourcesinanenvironmentallysoundmanner. 0 0.1 The American Chemical Society (ACS) symposiums were the catalyst 1 oi: for the chapters in this volume focusing on the latest information on the 5 | d environmental aspects of hydraulic fracturing, including technical challenges, 1 environmental effects, and the political and regulatory climate. These works 0 2 5, provide an opportunity to explore the results of ongoing research and consider 1 er multidisciplinary approaches needed to meet the challenges posed by this b m technology. e ec Ithankthemanyauthorswhocontributedtheirworkstothisvolume, ACS, D b): andtheACSEnvironmentalChemistryDivisionfortheirsupportofthehydraulic We fracturingsymposiums. IespeciallythankRafaelDelgadilloforhisunwavering e ( supportandencouragementonthisprojectandonallofmyotherprofessionaland at D educationalpursuits. n o ati c bli Pu DonnaL.Drogos DepartmentofCivil&ArchitecturalEngineering UniversityofWyoming 1000E.UniversityAve. Laramie,Wyoming82071,UnitedStates [email protected](e-mail) x In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. ©2015AmericanChemicalSociety brineandfresh. orco-occupyingspacewithsubterraneanwaterreservoirs,both forming weathered or bacterial altered deposits near surface, absent,thehydrocarbonsriseviabuoyancytowardsthesurface reservoirs,butwhenthesereservoirsarefilledorwhentheyare of the shales and may be trapped in rock containments called 27, 5, 313-321). As oil and gas is produced, some moves out –itsDepositionandDiagenesis. ClaysandClayMinerals,1979, periodsandinmostpartsoftheworld(Toutelot,H.BlackShale richshalesthatweredepositedthroughoutmanygeologictime Sourcesofmanyofthesehydrocarbonsincludetheorganic- carbonslaiddownwiththesediments. 1 pressure driven maturation reaction of some forms of organic 0 0 h simultaneously produced by naturally occurring thermal and c 16. alkanestoringcompoundsofbenzene,tolueneandxylenes,are 2 5-1 gas,withamyriadofco-generatedhydrocarbonmoleculesfrom 01 resultoffracturing. Theseissuesarecomplicatedsinceoiland 2 k- that may occur either as routine production activities or as a b 21/ ground water contamination, air pollution and other problems 0 0.1 thatmustbeconsidered. Concernshavebeenraisedrecentlyof 1 oi: industrial activity, there are risks, both immediate and latent 5 | d Technology. SPE JPT 2010, 62, 12, 26-32). As with any 1 C., Smith, M. Hydraulic Fracturing: History Of An Enduring 0 2 5, (U.S.)productionofmostoilandgasresources(Montgomery, 1 er for over sixty years and is critical to today’s United States b m stimulation technique that has been in play in various forms e ec Hydraulic fracturing is an established oil and gas well D b): e W e ( at n D *E-mail: [email protected] o Houston,Texas77056-4400,UnitedStates ati blic ApacheCorporation,2000PostOakBlvd.,Suite100, u P George E. King and Danny Durham * Fracturing: What Are the Facts? Environmental Aspects of Hydraulic Chapter 1 In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015. 2 intersectioninunconventionalcompletions. in conventional formations (non-shales), but is usually an acceptable flow transverse fracture with the horizontal wellbore may be a tortuosity restriction direction in which the horizontal well is drilled, Figure 1. The intersection of a may travel along the wellbore or at an angle to the wellbore depending on the barriers and rock stresses stop the growth. Fractures leaving a horizontal well developalongthewellbore,growingupwarduntilthelimitingfactorsofleak-off, easiertopushbackthantheσhmax). Fracturesleavingaverticalwellwillusually thefracturetogrowperpendiculartotheminimumhorizontalstress(theσhminis push apart. Native stress fields within the rock, namely σhmax and σhmin, force stress environment will be vertical as the lower horizontal stresses are easier to σhmax, ortheminimumhorizontalstress, σhmin; meaningfracturescreatedinthis 1 stress, σv, which is usually greater that either the maximum horizontal stress, 0 h0 about a thousand feet, the weight of the overlying rock forms a large vertical c 6. lateral orientation dictated by stresses within the rocks. At depths greater than 1 2 1 of a few hundred feet along vertical and horizontal planes within the rock with 5- 1 Fractureshapevarieswiththespecificconditionsbutisusuallyintherange 0 2 k- whereoilandgasisevolvedandoftentrapped. b 1/ Added to complexity is the widely varying depositional geology of the earth 2 0 1 therefore must be monitored remotely by various fit-for-purpose technologies. 0. oi: 1 visibly examined beyond the limited extent of the well’s interior piping, and d product; in this case the well and the hydraulically-formed fractures, cannot be 15 | fracturing are relatively unique among engineering endeavors in that the final 0 5, 2 wellbore. Sub-surface elements of oil and gas well developments and hydraulic er 1 flowcapacitytoenablehydrocarbonfluidstoflowfromtheformationtowardthe mb dependonthegeologiccharacteristicsoftherockandtherequirementsoffracture e c pressure is released. Selection of types and volumes of both fluid and proppant e D b): to maintain a stable flow path along the fracture after the hydraulic fracturing e the fracture by the injected fluid, packing the fracture with sufficient proppant W e ( rate,aproppantmaterial,usuallyroundsandorman-madeceramic,iscarriedinto Dat Afterthefractureisinitiatedatthewellboreandwidenedbyincreasinginjection on createafracturethatmaygrowverticallyandlaterallyoutwardfromthewell(1). cati oil or gas-based fluid to oppose insitu stresses and rock strata tensile strength to ubli fracturethroughhydrocarbonbearingrockusingpressureandaninjectedwater, P Oil and gas well fracturing, in the most simple of terms, creates a crack or Hydraulic Fracturing: What Is It? performanceandscientificallysoundresearchmethods. development as a secondary effort, using both historical asaprimarytargetandtheassociatedactivitiesofhydrocarbon chapter will examine the direct impact of hydraulic fracturing construction, hydrocarbon production or distribution. This fracturing are actually concerns of materials transport, well Many concerns of potential pollution from hydraulic In Hydraulic Fracturing: Environmental Issues; Drogos, Donna L.; ACS Symposium Series; American Chemical Society: Washington, DC, 2015.

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