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Synthesis and Tribological Applications of Hybrid Materials Synthesis and Tribological Applications of Hybrid Materials Edited by Mohammad Jawaid, Rajini Nagarajan, Jacob Sukumaran, and Patrick De Baets Editors All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and Dr. Mohammad Jawaid publisher do not warrant the information Universiti Putra Malaysia contained in these books, including this book, Institute of Tropical Forestry and Forest to be free of errors. Readers are advised to keep Products (INTROP) in mind that statements, data, illustrations, Serdang procedural details or other items may 43400 Selangor inadvertently be inaccurate. Malaysia Library of Congress Card No.: applied for Dr. Rajini Nagarajan Kalasaingam University British Library Cataloguing-in-Publication Data Dept. of Mechanical Engineering A catalogue record for this book is available Anand Nagar from the British Library. 626126 Krishnankoil, Tamil Nadu India Bibliographic information published by the Deutsche Nationalbibliothek Dr. Jacob Sukumaran The Deutsche Nationalbibliothek Ghent University lists this publication in the Deutsche Laboratory Soete Nationalbibliografie; detailed bibliographic Technologiepark Zwijnaarde 903 data are available on the Internet at <http:// 9052 Zwijnaarde dnb.d-nb.de>. Belgium © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Prof. Patrick De Baets Boschstr. 12, 69469 Weinheim, Germany Ghent University Dept. Electr. Energy, Systems, Automat. All rights reserved (including those of Sint-Pietersnieuwstraat 25 translation into other languages). No part of 9000 Gent this book may be reproduced in any form – by Belgium photoprinting, microfilm, or any other means – nor transmitted or translated into a machine Cover: © nikkytok/Shutterstock language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law. Print ISBN: 978-3-527-34301-0 ePDF ISBN: 978-3-527-80861-8 ePub ISBN: 978-3-527-80859-5 oBook ISBN: 978-3-527-80858-8 Typesetting SPi Global, Chennai, India Printing and Binding Printed on acid-free paper 10 9 8 7 6 5 4 3 2 1 v Contents Preface xi 1 Tribological Assessment on Accelerated Aging Bones in Polymeric Condition 1 Ramdziah M. Nasir, Law C. Gan, and Abdul Y. Saad 1.1 Introduction 1 1.2 Bone 2 1.3 Methodology 4 1.3.1 Phase I: Planning 4 1.3.2 Phase II: Design of Experiment 5 1.3.3 Phase III: Conduct of Experiment 5 1.3.4 Phase IV: Observation and Analysis 8 1.4 Results and Discussion 9 1.4.1 Accelerated Weathering Study 9 1.4.2 Effects of Increase in Temperature and Decrease in Relative Humidity (RH) on Maximum Load Withstood by Bone 12 1.4.3 Comparison of Bovine and Goat Bone Strength at Normal and Increased Temperatures 15 1.5 Conclusion 28 1.A Relative Humidity Chart 28 References 29 2 Nanofracture and Wear Testing on Natural Bones 33 Ramdziah M. Nasir, Muhammad A.A. Muhmad, and Abdul Y. Saad 2.1 Introduction 33 2.2 M ethodology 38 2.3 R esults and Discussion 42 2.4 C onclusion 51 References 51 3 Tribological Behaviors of Glass Fiber with Fillers Reinforced Hybrid Polymer Composites 53 T. P. Sathishkumar 3.1 Introduction 53 3.2 Wear and Mechanisms of Wear 54 vi Contents 3.2.1 Adhesion Wear 54 3.2.2 Abrasive Wear 54 3.3 Tribo Wear Test Methods 55 3.3.1 Wear and Friction Test Using Pin‐on‐disk 55 3.3.2 Wear and Friction Test Using Ball‐on‐disk 57 3.4 Tribo Characterization Hybrid Polymer Composites 57 3.4.1 Polyamide 6 and HDPE Glass Fiber Reinforced Hybrid Composites 57 3.4.2 Silicon Carbide, Graphite Particle, and Glass Fiber Reinforced Hybrid Composites 62 3.4.3 Case Study 67 3.5 Conclusion 69 References 70 4 Tribological Characterization of Jute/Glass Hybrid Composites 71 Narayanan Venkateshwaran, Aziz Alavudeen, and Vajjiram Santhanam 4.1 Introduction 71 4.2 Materials and Method 72 4.3 Results and Discussion 74 4.4 Micrograph Analysis 77 4.5 Conclusions 79 References 80 5 Glass Fiber Hybrid Effects in Assessing the Abrasive Wear Mechanisms of Naturally Woven Fabric/Polymer Composites Under Dry Conditions 83 Irulappasamy Siva, Manoharan Thirukumaran, Jebas T.W. Jappes, Bhimappa Suresha, Subramaniyan A. Kumar, and Buradagunta R. Sunil 5.1 Introduction 83 5.2 Experimental Details 84 5.2.1 Fiber and Matrix 84 5.2.2 Fiber Surface Treatment 84 5.2.3 Composite Fabrication 85 5.2.4 Mechanical Testing 85 5.2.5 Abrasive Wear Test 86 5.3 Results and Discussion 87 5.3.1 Mechanical Properties 87 5.3.2 Hardness (Shore‐D) of Composites 88 5.3.3 Specific Wear Rate 88 5.4 Conclusion 93 Acknowledgement 94 References 94 6 Wear Properties of Acid and Silane Modified CNT Filled Hybrid Glass/ Kenaf Epoxy Composites 97 Napisah Sapiai, Aidah Jumahat, and Jamaluddin Mahmud 6.1 Introduction 97 6.2 Methodology 99 6.2.1 Materials 99 Contents vii 6.2.2 Fabrication of Epoxy/Kenaf/Glass Fiber/CNT Composites 100 6.2.2.1 Acid Treatment and Silane Modification Process on CNT 100 6.2.2.2 Fabrication of the Composites 100 6.2.3 Abrasive Wear Test 100 6.2.4 Characterization of the Abraded Surface of the Composites 101 6.3 Results and Discussion 101 6.3.1 The Effect of Incorporating PCNT to Hybrid Glass/Kenaf Composites on the Wear Properties of the Composites 101 6.3.2 The Effect of Incorporating ACNT and SCNT to Glass/Kenaf Composite on the Wear Properties of the Composites 107 6.4 Conclusion 111 Acknowledgement 112 References 112 7 Hybrid Natural Fiber Composites as a Friction Material 115 Patric D. Neis and Ney F. Ferreira 7.1 Friction Material Components 115 7.1.1 Friction Materials Requirements 116 7.1.2 Braking Test Procedures 117 7.2 Natural Fibers Used in Friction Materials Composites 118 References 135 8 Comparative Wear Model on Hybrid Natural Fiber Composites as Substitutions for UHMWPE Made Knee Implants 139 Gusztáv Fekete and Mátyás Andó 8.1 Introduction 139 8.1.1 Basics of Reinforced Polymers, Composites, and Their Testing 139 8.1.2 Classification of Polymers 139 8.1.3 Classification of Composites 142 8.1.4 Basics of Tribo‐testing 145 8.1.5 Hybrid Natural Fiber Composites and Their Possible Use in Total Knee Replacements (TKR) 147 8.2 Aims 148 8.3 Methods 149 8.3.1 Wear Modeling 149 8.3.2 Force Modeling for Wear Equation 150 8.3.3 Slide–Roll Modeling for Wear Equation 152 8.4 Results 157 8.5 Discussion 158 Acknowledgments 159 References 159 9 Fabrication and Tribological Behavior of Epoxy Hybrid Composites 163 Bheemappa Suresha and Rajashekaraiah Hemanth 9.1 Introduction 163 9.1.1 Matrix Material 163 9.1.2 Reinforcements 164 viii Contents 9.1.2.1 Fiber Reinforcements 164 9.1.2.2 Particulate Reinforcements 166 9.1.3 Friction and Wear 167 9.2 Materials and Methods 168 9.2.1 Matrix Material 168 9.2.2 Reinforcement Materials 168 9.2.3 Particulate Fillers 169 9.2.3.1 Molybdenum Disulfide 170 9.2.3.2 Aluminum Oxide 170 9.2.4 Composite Fabrication 171 9.2.5 Dry Sliding Wear Test 172 9.2.6 Three‐Body Abrasive Wear Test 174 9.3 Results and Discussion 176 9.3.1 Dry Sliding Wear Performance of Carbon‐Epoxy Composites 176 9.3.1.1 Wear Volume Loss 176 9.3.1.2 Specific Wear Rate 179 9.3.1.3 Coefficient of Friction 181 9.3.1.4 Worn Surface Morphology 183 9.3.2 Abrasive Wear Performance 184 9.3.2.1 Abrasive Wear Volume Loss 184 9.3.2.2 Specific Wear Rate 186 9.3.2.3 Consequences of Factors on Wear Volume Loss 187 9.3.2.4 Worn Surface Morphology 188 9.4 Conclusions 192 References 193 10 Dry Sliding Wear Behavior of Copper Based Hybrid Metal Matrix Composite 197 Ponnambalam Balamurugan, Marimuthu Uthayakumar, and Sundaresan Thirumalai Kumaran 10.1 Introduction 197 10.2 Materials and Methods 200 10.2.1 Materials 200 10.2.2 Preparation of the Composite by Powder Metallurgy Process 201 10.2.3 Wear Studies 202 10.3 Results and Discussion 203 10.4 Conclusion 210 References 211 11 Morphological Examination of Worn out Surfaces of Basalt Fiber‐PEI Composites with Varying Loading Conditions 215 Kalimuthu Mayandi, Subramanian Karthikeyan, Nagarajan Rajini, and Azeez B. Alavudeen 11.1 Introduction 215 11.2 Materials Used 216 11.3 Fabrication of the Composite Materials 216 11.4 Testing of Composite Materials 217 Contents ix 11.4.1 Density Test 217 11.4.2 Hardness Test 217 11.4.3 Wear Test 217 11.5 Results and Discussion 218 11.5.1 Wear Performance of Basalt Fiber Reinforced Thermoplastic Composite 218 11.5.2 Morphological Analysis of Worn out Samples 221 11.6 Conclusions 223 References 225 Index 227 xi Preface Nowadays, from day‐to‐day activities of human life to high‐end sophisticated applications, tribology has a role to play in any one of the aspects. Hence, the need to understand the process, materials, techniques, and mechanism related to tribological concepts is as an important factor to be considered by the research community. Moreover, tribology is a system‐dependent phenomenon that cov- ers a wide range of science and technology fields including materials science, mechanical engineering, lubricant engineering, biomaterials, chemistry, physics, biology, and many more, encompassing micro as well as nanotechnology. Major organizations and academic institutions in developing countries have also realized the importance of industrial tribology and its relevance to modern design and maintenance as a result of immense savings on declining material and energy losses and decrease in cost of mass production. Accordingly, the design of eco‐friendly material for the tribological components is found to be the primary factor in the energy saving sector as well as for a green environment. One such material system is the bio‐degradable natural fiber reinforced self‐lubricating polymer composite, which can be a suitable alternative for external lubricant tribo systems. Nowadays, the research advancement of degradable natural fiber reinforced polymer composites in the field of automotive, aerospace, and con- struction industries has been appreciable because it provides much economic benefit due to its inherent quality of higher specific strength to weight ratio. Although the structural properties are important for tribological applications, priority will have to be given for enhancing the wear and friction behavior. Natural fiber based polymer composites have attracted researchers attention for tribological applications because of their excellent structural performance and have excelled over conventional materials in industrial systems such as bearings, automobile parts, gears, and chute liners while the advantage of reinforcing two fiber materials in one matrix or one fiber in polymer blends through hybridiza- tion effect. The development of hybrid composites helps attain a combination of the exceptional mechanical properties of different fibers/fillers. Scientists have also investigated the tribological characteristics of natural fiber composites hybridized with secondary fillers with varying operational parameters such as the type of fillers, grid size, and wt % matrix. Generally, it has been found that nano‐ or micro‐sized inorganic particles can significantly influence the tribo- logical properties of polymeric materials. xii Preface This book covers versatile topics such as tribological assessment on acceler- ated aging bones in polymeric condition, nano fracture and wear testing on natural bones, tribological behavior of glass fiber with fillers reinforced hybrid polymer composites and jute/glass hybrid composites, wear properties of glass fiber hybrid, and acid‐ and silane‐modified CNT filled hybrid glass/kenaf epoxy composites, hybrid natural fiber composites as a friction material, comparative wear model on hybrid natural fiber composites, tribological behavior of particu- late and carbon fiber reinforced epoxy hybrid composites, and dry sliding wear behavior of copper based hybrid metal matrix composites. We are highly thankful to all authors who contributed the chapters and pro- vided their valuable ideas and knowledge on tribology in this edited book. We have attempted to gather all the information from recognized researchers from Malaysia, India, Brazil, and Hungary in the areas of tribological properties and have finally completed this venture in a fruitful manner. We greatly appreciate the contributors’ commitment and their support to compiling our ideas in reality. We are highly thankful to the Wiley team for their generous cooperation at every stage of the book production. Mohammad Jawaid, Malaysia Rajini Nagarajan, India Jacob Sukumaran, Belgium Patrick de Baets, Belgium

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