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HW 2 PTV 1. On a commercial airline flight you drink most of a bottle of water and then store it in your seatpocket. Justbeforelanding,youtakeitoutagainastheflightattendantiscollectingtrash. The bottle has now collapsed some looking crushed. Using what you know about gas laws, collisions, and forces explain the shape change. (Make sure to describe what happened to ALLvariables) Assuming that you opened the bottle at above the cabin altitude (the altitude at which atmospheric pressure is equivalent to the pressure in the cabin, which is maintained by the airplane’s internal systems,) the pressure will be less than that just before landing. Thus, by Boyle’sLaw,aspressureincreaseswhiletemperatureandnumberofmolesareheldconstant, thevolumeofthegasdecreases. Sketchapressurevs. volumegraphofwhathappenedtothebottleastheplanedescended. 2. Aprocessisrepresentedonagraphinthefigurebelow. Usingasmuchdetailaspossible, describewhatishappeningatthemolecularlevel. Provideapracticalexampleoftheprocess. 1 The gas molecules are gaining kinetic energy, as the temperature is increasing. Thus, these molecules are hitting the container more often, creating a larger pressure on the con- tainer. An example would be heating a hollow glass ball for some purpose (which makes this practical), in which case the (mostly) rigid, closed ball would be more greatly pressed upon fromtheinsideafterbeingheated. 3. Usingthegraphingskillsyouweretaughtlastsemester,determinewhatvaluethearea(the shadedpartunderthehorizontalline)underthepressurev. volumegraphrepresents. F PV = ( )(A×d) = F ·d =Work done to increase the volume while keeping pressure A constant 2 4. Agasisinasealedcontainerwithaheavytopthatisfreetomove. Thetopmovesupward against the constant external pressure pushing down on the top causing the volume of the gastoincrease. Sketchthegraphoftheprocessbelow,namethegaslawthatisrepresented andwriteanappropriatemathematicalexpression. ThedirectrelationbetweenvolumeandtemperatureisdescribedbyBoyle’sLaw. PV = constant 5. A completely closed rigid container of gas is taken from the oven and placed in ice wa- ter. Which graph does NOT represent the process? Name the gas law that explains this phenomenon. Gay-Lussac’sLawdescribesthedirectrelationshipoftemperatureandpressure. 3 Disn’tappropriatebecausethevolumeisinactualityunchanging. 6a. Sketch a pressure vs. volume graph that illustrates the following process: A sealed container of gas is originally at a temperature of T , a pressure of P , and a volume of V . 1 1 1 The pressure of the gas is tripled, however the volume of the gas is held constant. Once this new pressure (P ) is achieved the volume of the gas is allowed to double while keeping the 2 pressureconstantatP . 2 6b. As compared to the original temperature of the gas (T ) what is the new temperature of 1 thegas? EXPLAINhowyoudeterminedthisanswer. The temperature must triple in the first stage because the pressure triples. The tempera- turestaysthesameinthesecondstagebecausethepressurestaysthesame. Thus,thenew temperaturemustbe 3T 1 4

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