High pressure phase transformations - a handbook

614 Pages·2.216 MB·English

by  E. Yu Tonkov

High Pressure Phase Transformations

Volume 4

High Pressure Phase Transformations
A Handbook

Volume 4

by

E. Yu. Tonkov

Institute of Solid State Physics, Chernogolovka, Russia

Editor V. F. Fortov

Translated from Russian by E. Yu. Tonkov
i

Contents

Notations
Preface
List of Substances
Substances

Notations

P – pressure
T – temperature
T – temperature of superconducting transition
c
T – Curie temperature
C
T – Néel temperature
N
∆H – enthalpy change in phase transition
∆V – specific volume change in phase transition
∆V – specific volume of initial phase
0
ii

PREFACE

During many years phase transformations and phase diagrams
were a subject of an extensive study under high pressure all over
the world. Abundant set of experimental data was obtained and
published in thousands of the research papers so it becomes
more and more difficult to deal with these data without special
feference books. A series of handbooks compiled by E. Yu.
TONKOV substantially solves this problem. The present
volumes, No. 4 and 5 continues the three-volume series under
the general title “High Pressure Phase Transformations: A
Handbook “ (volumes 1 and 2, 1992, volume 3, 1996), Gordon
and Breach Publishers, which was considerable interest for
many researchers. This Handbook is a unique work in the world
literature that most completely summarizes available data on the
phase transformations under high static and dynamic pressures
published up to 2007.
Remarkable is that the high-pressure methods are widely
used and developed now by the researchers working in solid
state physics, crystallography, mineralogy, as well as they are
applied for synthesis of new materials with unordinary
mechanical, magnetic and superconducting properties. Volumes
4 and 5 compiles the latest data on the phase transfor-mations of
the elements (1993–1997) and the chemical compounds
including nanocrystalline, sometimes rather complex, but also of
binary and multicomponent alloys. A special section is devoted
to organic superconductors which were studied world-wide in
the recent years. The index of 5200 compounds opening the
Handbook is ordered more conveniently than previously on
correspondence with the chemical symbols of the elements.
iii

Doubtless, the new volumes will be interesting and
useful for a wide research community, and it will compel as
much attention as the previous three volumes of this series.
iv

List of Substances

A general list of substances is presented in the previous
handbooks: TONKOV, E. Yu. (1992–1996) “High Pressure
Phase Transformations: A Handbook, Gordon and Breach
Publishers, Switzerland, volume 1 – [1], volume 2 – [2], volume
3 –[3], the present volume – [4] and also in handbook
TONKOV, E. Yu. (1998) “Alloys and Compounds under High
Pressure: A Handbook, Gordon and Breach Publishers,
Switzerland – [7]. The substances and systems are arranged in
alphabetical order according to chemical symbols of elements.
An asterisks denotes substances, for which phase diagrams are
represented graphically; high-pressure-induced phases obtained
in the metastable state by
quenching at 0.1 MPa and room temperature are denoted by the
letter M; modifications, which are determined under pressure
are denoted by the letter S; compounds first synthesized under
pressure are denoted by letter F, nanomaterials are denoted by
letter N. Compounds for which superconducting and nagnetic
phase transformations were studied at high pressure are
denotrd by T and T , respectively. The names of natural
c M
minerals are also presented.

Silver 1 [4], (N) Ag–Bi (AgBi ) 1 [3], (M)
2
Ag–Al 1 [4] (Ag Bi) 1 [4], (M)
3
Ag–Au 1 [6] Ag–Br
v

(AgBr)1 [1], 2 [4] (S) Ag–Gd (AgGd) 4 [1], 1 [3]
Ag–Cd 2 [6] Ag–Ge 5* [6], 6 [4] (S)
Ag–Ce Ag–I (AgI)4* [1], 7 [4] (M)
(CeAg) 2 [1], 3 [4] (Tm) Ag–In 7 [6]
Ag–Cl Ag–K (K Ag) 8 [4] (F)
3
(AgCl) 2 * [1], 3 [4] (M) (K Ag) 8 [4] (F)
2
Ag–Cu 4 [6], 5 [4] (Kag ) 8 [4] (F)
2
Ag–Er (ErAg ) 5 [4] (T ) Ag–La
2 M
Ag–F (AgF) 3 [1], 5 [4] (S) (LaAg) 7 [1], 9 [4] (M)
(AgF ) 3 [1], 5 [4] Ag–Nd (NdAg) 10 [4] S)
2
Ag–Ga 4 [6]
Ag–O (AgO)10 [4] (CeCd Ag ) 12 [4]
1-x x
(Ag O) 8* [1] Ag–Ce–Sb
2
Ag–Pb 10 [4] (CeAgSb ) 12 [4] (T )
2 M
Ag–Pd 9 [6] Ag–Ce–Zn
Ag–Pr (AgPr) 12* [1] (CeAg Zn ) 13 [4]
1-x x
Ag–Pt 9 [6] Ag–Cl–O (AgClO ) 9* [1]
4
Ag–S (Ag S) 13* [1] Ag–Cr–O (Ag CrO ) 9* [1]
2 2 4
Ag–Se (Ag Se) 16* [1] Ag–Cu–I
2
Ag–Tb (AgTb) 5 [3] (Cu Ag I) 13 [4] (M)
x 1-x
Ag–Te Ag–Cu–O (AgCuO ) 13 [4]
2
(Ag Te, hessite) 21* [1] Ag–Cu–Y
2
(AgTe ) 5 [3] (YCu Ag ) 14 [4]
3 1-x x
Ag–Zn (AgZn) 23 [1] Ag–Cu–Yb
Ag–Al–S (AgAlS ) 14 [1] (YbCu Ag) 14 [4]
2 4
Ag–As–S (Ag AsS )3 [3] Ag–Ga–S
3 3
Ag–B–F (AgBF ) 3 [1] (AgGaS , thiogallate)
4 2
Ag–Bi–Se 14 [1], 14 [4] (S)
(AgBiSe ) 4 [3], 11 [4]( M) Ag–Ga–Se
2
Ag–Br–Cl (AgGaSe )16 [1], 16 [4] (S)
2
(AgBr Cl ) 11 [4] Ag–Ga–Te (AgGaTe )
1-x x 2
Ag–Br–S (Ag SBr) 14 [1] 21 [1], 17 [4] (S)
3
Ag–C–N (AgCN) 7 [1] (Ag Ga Te ) 5 [3]
2 6 10
Ag–Cd–Ce Ag–Gd–In
vi

(GdAg In ) 6 [1] Ag–Nb–O (AgNb O ) 2 [3]
1-x x 3 8
Ag–Ge–S Ag–O–P (Ag P O ) 12 [1]
4 2 7
(Ag GeS , argyrodite)14 [1] Ag–O–Re (AgReO ) 3 (3]
8 6 4
Ag–Ge–Se Ag–O–S (Ag SO ) 15* [1]
2 4
(Ag GeSe ) 17* [1] Ag–O–Sb (AgSbO ) 16 [1]
8 6 3
Ag–Ge–Te Ag–O–Se
(Ag GeTe ) 22* [1], 18 [4] (Ag SeO ) 19* [1]
8 6 2 4
Ag–Ge–Yb Ag–Pd–Si (Pd Ag Si )
75 5 20
(YbAgGe) 18 [4] (T ) 21 [4] (A)
m
Ag–H–Pd Ag–S–Sb (Ag SbS ) 3 [3]
3 3
(PdAgH ) 19 [4] (F) (Ag SbS ) 4 [3]
x 5 4
(Pd Ag H ) Ag–S–Si (Ag SiS ) 19* [1]
0.93 0.07 x 8 6
19 [4] (F,T ) Ag–S–Sn (Ag SnS ) 20* [1]
c 8 6
Ag–D–Pd) (AgSnS ) 4 [3]
2
(Pd Ag D) 20 [4] (F,T ) Ag–Sb–Se
x 1-x c
Ag–Hg–I (Ag HgI ) 5* [1] (AgSbSe ) 4 [3], 21 [4] (F)
2 4 2
Ag–I–K (KAg I ) 6* [1] Ag–Sb–Te
4 5
Ag–I–O (AgIO ) 10 [1] (AgSbTe ) 22 [4] (S,A)
3 2
Ag–I–Rb (RbAg I ) 13 [1] Ag–Se–Si
4 5
Ag–In–La (Ag SiSe ) 19* [1]
8 6
(LaAg In ) 7 [1] Ag–Se–Sn
0.5 0.5
Ag–In–O (AgInO ) 10 [1] (AgSnSe ) 20 [1]
2 2
Ag–In–S (AgInS ) 15 [1]
2
Ag–In–Se (Ag SnSe ) 20* [1]
8 6
(AgInSe )17* [1], 20 [4] (F) (Ag SnSe ) 4 [3]
2 2 3
Ag–In–Te Ag–Si–Te
(AgInTe ) 22 [1], 5 [3] (Ag SiTe )23* [1]
2 8 6
Ag–Mo–S (Ag Si Te ) 5 [3]
15 15 70
(AgMo S ) 15 [1] Ag–Al–In–Se
6 8
Ag–Mo–Se (AgInAl Se ) 18 [1]
4 8
(AgMo Se ) 18 [1] Ag–Bi–In–Se
6 8
(Ag Mo Se ) 21 [4] (T ) (AgBi In Se ) 22 [4] (F)
0.7 4 5 c x 1-x 2
Ag–N–O (AgNO ) 11* [1] Ag–Br–In–S
3
(AgNO ) 10* [1] (AgIn S Br) 15 [1]
2 2 3
vii

Ag–Br–In–Se (AgPbSbS ) 4 [3]
3
(AgIn Se Br) 8 [1] Ag–Al–Cu–Ni–Zr 25 [4]
2 3
Ag–Br–In–Te Ag–C–H–N–O
(AgIn Te Br) 22 [1] (NH CH COOH·AgNO )
2 3 2 2 3
Ag–C–K–N 12 [1]

[KAg(CN) ] 18 [1], 1 [3] Ag–C–D–N–O
2
Ag–Ce–Cu–In (ND CD COOD AgNO )
2 2 3
[CeIn(Ag Cu ) ] 12[1]
1-x x 2
22 [4] (T ) Ag–Ca–Nd–O–Ti
M
Ag–Cl–In–S (Ca NdAgTi O )
2 4 12
(AgIn S Cl) 15 [1] 25 [4] (F)
2 3
Ag–Cl–In–Se Ag–In–S–Sb–Se 25 [4] (F)
(AgIn Se Cl) 18 [1]
2 3
Ag–Cl–In–Te
(AgIn Te Cl) 23 [1] Aluminium 26 [4]
2 3
Ag–Cu–Hg–I Al–As
(Ag Cu ) HgI 23 [4] (AlAs) 6 [3], 27 [4] (S)
1-x x 2 4
Ag–H–I–N Al–Au (AlAu) 6 [3]
(NH Ag I ) 7 [1] (AuAl ) 24 [1], 28 [4] (S)
4 4 5 2
Ag–I–In–Se (Al Au ) 7 [3]
11 6
(AgIn Se I) 18 [1] (Al Au ) 6 [3]
2 3 3 8
Ag–I–In–Te Al–B (AlB ) 28 [4]
2
(AgIn Te I) 23 [1] Al–Ba (BaAl ) 25 [1]
2 3 2
Ag–I–O–W Al–C 29 [4] (F)
(AgI WO ) 23 [4] Al–Ce
4 4
Ag–In–Sb–Se (CeAl ) 25 [1], 29 [4] (T )
2 M
(AgSb In1-xSe ) 24 [4] (F) (CeAl ) 25 [1], 29 [4]
x 2 3
Ag–N–Na–O (Ce Al) 7* [3]
3
(AgNa(NO ) ) 2 [3] (Ce Al ) 29 [4] (A)
2 2 1-x x
Ag–Nd–O–Ti Al–Co (AlCo) 31 [4]
(NdAgTi O ) 24 [4] (F) Al–Cr 13 [6], 31 [4] (T )
2 6 N
Ag–O–S–Tl Al–Cu 14 [6], 32 [4]
(AgTlSO ) 24 [4] Al–Dy (Dy Al ) 26 [1]
4 3 2
Ag–Pb–S–Sb Al–Eu (EuAl ) 32 [4] (T )
2 M