High-pressure Molecular Spectroscopy PDF
Preview High-pressure Molecular Spectroscopy
IanS.Butler(Ed.) High-pressureMolecularSpectroscopy Also of interest Micro-RamanSpectroscopy. TheoryandApplication Popp,Mayerhöfer(Eds.), ISBN----,e-ISBN(PDF)---- QuantumCrystallography Massa,Matta,Huang, ISBN----,e-ISBN(PDF)---- X-rayAbsorptionSpectroscopy George,Pickering, ISBN----,e-ISBN(PDF)---- EPRSpectroscopy Petasis,Hendrich, ISBN----,e-ISBN(PDF)---- InstrumentalAnalysis. ChemicalIT SchlemmerG,SchlemmerJ, ISBN----,e-ISBN(PDF)---- High-pressure Molecular Spectroscopy Edited by Ian S. Butler Editor Prof.em.IanS.Butler DepartmentofChemistry McGillUniversity 801SherbrookeSt.W. Montreal QC CanadaH3A0B8 ISBN978-3-11-066528-4 e-ISBN(PDF)978-3-11-066861-2 e-ISBN(EPUB)978-3-11-066544-4 LibraryofCongressControlNumber:2022940992 BibliographicinformationpublishedbytheDeutscheNationalbibliothek TheDeutscheNationalbibliothekliststhispublicationintheDeutscheNationalbibliografie; detailedbibliographicdataareavailableontheInternetathttp://dnb.dnb.de. ©2022WalterdeGruyterGmbH,Berlin/Boston Coverimage:SciencePhotoLibrary/Alexander,Max Typesetting:IntegraSoftwareServicesPvt.Ltd. Printingandbinding:CPIbooksGmbH,Leck www.degruyter.com Preface Pressureisavariablethatencompassesapproximately12ordersofmagnitude(10−6to 106atm),andavarietyofspecializedequipmenthasbeendesignedovertheyearsto investigateallkindsofmaterialsthroughoutmostofthispressurerange.Thepurpose ofthismonographistoexposethereadertoaselectionofhigh-pressurestudiesthat have been undertaken recently using various molecular spectroscopy techniques. Thereareeightchaptersinall,thefirstthreeofwhicharefocusedonapplicationsin- volvinginfraredandRamanspectroscopy.Initially,Dr.YangSongfromWesternUni- versity in Ontario, Canada, describes some of his research on pressure-mediated hydrogen bonding, pressure-inducedphotochemical reactions, and porous materials andguest–hostinteractions.Then,Dr.IanButler,atMcGillUniversityinQuebec,Can- ada,describeshisdiamond-anvilvibrationalresearchonsolidmaterials,especiallyor- ganometallic complexes. Next, Dr.Janice Musfeldt atthe Universityof Tennessee in theUSApresentssomeofherresearchonmolecule-basedmultiferroics.Thischapter isfollowed by onefromDr.Alexander Goncharovatthe CarnegieInstitution for Sci- ence inWashington, DC,USA, on recentexperimentaland theoretical investigations ofsimplemoleculesatveryhighpressuresapproachingandreachingmoleculardisso- ciation, and transformations to polymeric and monoatomic structures. In the next chapter,Dr.HelenWalkerattheRutherfordAppletonLaboratoryinHarwell,UK,de- scribesherresearchoninelasticneutronscatteringunderpressure.AnotherCanadian scientistDr.JohnTseattheUniversityofSaskatchewaninCanadaandDr.ErcanAlp at the Argonne NationalLaboratoryinIllinois,USA, presenta reportonthe applica- tion of inelasticscattering of X-raysathigh pressure.MovingontoBrazil, Dr.Naira BalzarettiattheUniversidadeFederaldoRioGrandedoSulinPortoAlegredescribes herluminescenceworkonlanthanide-dopedglassesunderhighpressure.Inthefinal chapter,Dr.ChristianReberattheUniversityofMontrealinQuebec,Canada,introdu- ces us to the application of variable-pressure fluorescence measurements on six- coordinate d-block compounds. One of the rationales for this particular monograph wasthatthefieldissteadilygrowing.Abriefsurvey,usingSciFinder,forthetwocon- cepts high-pressure spectroscopy and high-pressure molecular spectroscopy revealed thatthereare over 19,000 and 1,100 citations, respectively.Wetrust thatthe reader will enjoy our collection of different high-pressure studies and consequently will be stimulatedtoundertakefurtherresearchinthisfascinatingarea. IanS.Butler ProfessorEmeritusofChemistry McGillUniversity,Montreal QC,Canada https://doi.org/10.1515/9783110668612-202 Contents Preface V ListofContributors IX YangSong Characterizationofpressure-mediatedmolecularevolutionsinconfined spaceprobedbyinsituvibrationalspectroscopy 1 IanS.Butler Diamond-anvilcellmolecularspectroscopyofsolidmaterials 43 JaniceL.Musfeldt Introductiontomolecule-basedmultiferroics 63 AlexanderF.Goncharov Simplemoleculesathighpressures:transitionstoextendedandatomic states 91 H.C.Walker Inelasticneutronscatteringunderpressure 139 JohnS.Tse,E.ErcanAlp ApplicationofinelasticscatteringofX-raysathighpressure 159 IsraelRogerMontoyaMatos,AlvaroCarrilloHerrera,SilvioBuchner, NairaMariaBalzaretti Lanthanide-dopedglassesunderhighpressure 227 ChristianReber,ChahinezDab,Pierre-FrançoisBlanc Metal–ligandbondinginsix-coordinated-blockcomplexesprobedby luminescencespectroscopyatvariablepressure 239 Index 251 List of Contributors ChristianReber E.ErcanAlp Départementdechimie AdvancedPhotonSource UniversitédeMontréal ArgonneNationalLaboratory Canada Lemont,IL60439 [email protected] USA ChahinezDab AlexanderGoncharov Départementdechimie EarthandPlanetsLaboratory UniversitédeMontréal CarnegieInstitutionforScience Canada 5241BroadBranchRd.NW Washington,DC20015 Pierre-FrançoisBlanc USA Départementdechimie UniversitédeMontréal YangSong Canada DepartmentofChemistry WesternUniversity JaniceL.Musfeldt 1151RichmondStreet DepartmentsofChemistryandPhysics London UniversityofTennessee ON Knoxville,TN37996,USA CanadaN6A5B7 DrHelenWalker IsraelRogerMontoyaMatos MAPSInstrumentScientist DepartmentofCivilEngineering ISISNeutronandMuonSource UniversityofLima RutherfordAppletonLaboratory Lima,Peru Harwell,OxfordshireOX110QX UK AlvaroCarrilloHerrera DepartmentofPhysics IanS.Butler UniversidaddeAntioquia DepartmentofChemistry Medellin,Colombia OttoMaassBuilding,Room002 McGillUniversity SilvioBuchner 801SherbrookeStreetWest DepartmentofPhysics Montreal,QC UniversidadeFederaldoRio CanadaH3A0B8 GrandedoSul PortoAlegre,Brazil JohnS.Tse FellowofRoyalSociety,Canada NairaMariaBalzaretti DistinguishedProfessor DepartmentofPhysics CentennialEnhancementChair UniversidadeFederaldoRio DepartmentofPhysicsandEngineering GrandedoSul Physics PortoAlegre,Brazil UniversityofSaskatchewanSaskatoon Saskatchewan,SK CanadaS7N5E2 https://doi.org/10.1515/9783110668612-204
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