Handbook of Solid State Batteries

818 Pages·2015·66.535 MB·English

by  Nancy J. Dudney, William C. West, Jagjit Nanda

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B1. Vol. 6 Handbook of Solid State Batteries (2nd Edition)
State 187.5 edited by Nancy J. Dudney (Oak Ridge National Laboratory, USA),
d 8. William C. West (Nagoya University, Japan) and
of Soliby 7 Jagjit Nanda (Oak Ridge National Laboratory, USA)
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db Nancy J Dudney
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Oak Ridge National Laboratory, USA
William C West
Nagoya University, Japan
Jagjit Nanda
Oak Ridge National Laboratory, USA
World Scientific
NEW JERSEY • LONDON • SINGAPORE • BEIJING • SHANGHAI • HONG KONG • TAIPEI • CHENNAI • TOKYO
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ISBN 978-981-4651-89-9
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June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pagev
Preface
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an high specific energy lithium metal anodes resulting in high active-
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massbasisspecificenergy.
Sincethelasteditionofthisbook,significantstridesinthefield
of solid-state batteries have been achieved. In this second edition
ofthisbook,wehaveboughttogethermanysubject-matterexperts
v
June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pagevi
vi Preface
in the field of solid-state batteries, covering a wide range of topics.
Herein,theauthorssummarizeadvancementsin:
◦
Very high ionic conductivity sulfide- and oxide-based solid elec-
trolyteswithionicconductivitynearlyon-parwithliquidlithium-
ionelectrolytes
◦
Newsolidelectrolytesforthinfilmbatteriespreparedbyanumber
ofdifferenttechniques
◦
Adaptation of powerful characterization tools including syn-
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of Soliby 7 tions,structuralmotifs,andadditivesforimprovedionicconduc-
k tivityandmechanicalstability
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research activities focus on the ionic transport and electrochemical
reactions of a single material, yet the challenge for devices hinge
on the stability and unimpeded motion of ions across interfaces
betweentheelectrode-electrolyteandinsomecasesbetweenmulti-
pleelectrolytes.Celldesignsutilizingthick,energydenseelectrodes
with a relatively small electrolyte contact area will be particularly
challenging due to the high current density. The community also
needs to investigate and provide avenues for practical industrial
processingandmassproduction.
June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pagevii
Preface vii
While a commercially viable solid-state battery competitive with
conventional lithium-ion batteries has yet to be fully realized, we
anticipate further advancements that will soon bring this exciting
newtechnologytofruition.
NancyJDudney
OakRidgeNationalLaboratory
WilliamCWest
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June18,2015 11:19 HandbookofSolidStateBatteries... (2ndEdn) 9inx6in b1801-fm pageix
Contents
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State 187.5 Chapter2. In-situNeutronTechniquesforLithium
of Solid by 78. IYounpianngdHSeoalindd-SHtaotweaRrdecWhaanrggeableBatteries 51
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StudiesofAtomicandElectronic
StructureinBatteries 79
FaisalM.AlamgirandSamsonY.Lai
Chapter4. AnalyticalElectronMicroscopy—Study
ofAllSolid-StateBatteries 109
ZiyingWangandYingShirleyMeng
ix
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x Contents
Chapter5. Li-ionDynamicsinSolidsasSeenVia
RelaxationNMR 133
ViktorEppandMartinWilkening
Chapter6. CrystallineInorganicSolidElectrolytes:
ComputerSimulationsandComparisons
withExperiment 191
M.D.JohannesandN.A.W.Holzwarth
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atteries 48 on 1 Chapter9. ThinFilmLithiumElectrolytes 307
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State 187.5 JeaCho,JaneChang,AmyPrieto
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Ha All-Solid-StateRechargeable

LithiumBatteries 337
YasutoshiIriyamaandZempachiOgumi
Chapter11. CrystallineSulfideElectrolytes
forLi-SBatteries 365
GayatriSahuandChengduLiang
Chapter12. Super-ionicConductingOxideElectrolytes 391
JeffSakamoto