Handbook of elastomers PDF
Preview Handbook of elastomers
Second Edition, Revised and ExDanded edited by ANI1 K. BHOWMICK Rubber Technology Centre Indian Institute of Technology Kharagpur, India HOWARD L. STEPHENS The University of Akron Akron, Ohio MARCEL 95 MARCEL DEKKIENRC,. NEWY ORK BASEL DEKKER ISBN: 0-8247-0383-9 This book is printed on acid-free paper. Headquarters Marcel Dekker, Inc. 270 Madison Avenue, New York, NY l0016 tel: 2 12-696-9000; fax: 2 12-685-4540 Eastern Hemisphere Distribution Marcel Dekker AG Hutgasse 4, Postfach 812. CH-4001 Basel, Switzcrland tell 4 1 -6 1-7-61- 8482; fax: 4 1-6 1-26 1-8896 World Wide Web tlttp://www.dekker.com The publisher offers discounts on this book when ordered in bulk quantitics. For more information, write to Special SaleslProfessional Marketing at thc headquartcrs addrcss abovc. Copyright 0 2001 by Marcel Dekker, Inc. All Rights Reserved. Neithcr this book nor any part may be reproduced or transmitted in any form or by any mcans. electronic or mechanical, including photocopying, microfilming, and recording. or by any information storagc and retricval systcm. without permission in writing from the publisher. Current printing (last digit): 1 0 9 8 7 6 5 4 3 2 1 PRINTED IN THE UNITED STATES OF AMERICA TO Jatindra Mohan Bhowmick Hem Prova Bhowmick Kundakali Bhowmick Asmit Bhowmick Marian Stephens This Page Intentionally Left Blank Preface Exactly 10 years have glidedb y since the first edition of Hardbook of Elastomers was published. Wherever we have traveled, we have heard good words about the book. It has been found to be useful for teaching, research, and business purposes. The overwhelming response from around the world prompted us to undertake a second edition. Considering the success of the first edition, the style of the book has not been changed. New chapters have been included and materials no longer in vogue have been deleted. Most of the chapters from the first edition have been updated with new information and technology, and only a few have been retained in their original form because no significant new developments have occurred. Readers’ suggestions have been incorporated in many places. We wish to thank all the authors for their fine contributions and sharing of their expertise. We are grateful to many rubber companies, polymer institutes, and research and development organizations around the world for valuable suggestions and assistance. We acknowledge our indebtedness to our family members, especially to Asmit Bhowmick, Dr. S. K. Biswas, and Ms. K. Biswas, for their patient understanding. Last, but not least, we are thankful to Russell Dekker, Chief Publishing Officer, and EricS tannard, Production Editor, of Marcel Dekker, Inc., for their wholehearted support and guidance. We hope that the second edition of Handbook of Elastomers will be even more useful to our readers. Ani1 K. Bhownick Howard L. Stephens V This Page Intentionally Left Blank Contents ... 111 .vi 1. Guayule Rubber 1 D. Mclrltyre, Ho~turclL . Stephens, W. W. Schlorwnn, Jr., crr~clA ni1 K. Bhon*nlick 2. Helw Natural Rubber 29 A. H. Eng mtl E. L. Or1g 3. Modified Natural Rubber 61 Crispirl S. L. Brrkrr 4. Chemical Modification of Synthetic Elastomers 109 Dorltrltl N. Sch~rl:m tl A~~I~III0L. IPIatIil~ II 5. Liquid Rubber 133 Douglcrs C. Ed1cwrd.s 6. Powdered Rubber 167 Colirl W. EIWS 7. Rubber-Rubber Blends: Part I 197 C. Miclwel Roltrrltl 8. Rubber-Rubber Blends: Part 11. New Developments 227 C. Micl~nelU olcrd 9. Short Fiber-Filled Rubber Composites 241 Lloyd A. Goc.tt1L.r arlcl Willimu F. Cole 10. Thermoplastic Elastomeric Rubber-Plastic Blends 265 Aubert Y. Cotm 11. Thermoplastic Styrenic Block Copolymers 321 Geojfrey Holrlerl mrl C11rrrles U. Wilder vii viii Contents 12. PolyesterT hermoplasticE lastomers:P art I 353 Rorleric P. Quirk unci Qizkuo Zhuo 13. PolyesterT hermoplasticE lastomers:P art I1 367 H. M. J. C. Creerwers 14. Thermoplastic Polyurethane Elastomers 387 CIzarles S. Schollenberger 15. Thermoplastic Polyamide Elastomers 417 Anil K. Bhowrnick 16. Ionomeric Thermoplastic Elastomers 433 Kurnal K. Kar and Ani1 K. Bhowrnick 17. Miscellaneous Thermoplastic Elastomers 479 Anil K. BhoMmick 18. Halogen-Containing Elastomers 515 Daniel L. Hertz, Jr. 19. Tetrafluoroethylene-Propylene Rubber 547 Gen Kojirna and Masayuki Saito 20. Carboxylated Rubber 561 John R. Dunrl 21. Polyphosphazene Elastomers 591 D. Frederick Lohr and Harold R. Penton 22. Advances in Silicone Rubber Technology: Part I, 1944-1986 605 Keith E. Polrnarzteer 23. Advances in Silicone Rubber Technology: Part 11, 1987-Present 649 Jerome M. Klosowski 24. Acrylic-Based Elastomers 659 Piero Anrlreussi und Arturo Carrano 25. Poly(propy1ene oxide) Elastomers 683 Dotninic A. Berta ancl Edwin J. Vandenberg 26. Polyalkenylenes 697 Adolf Drusler 27. Polytetrahydrofuran 723 P. Dreyfuss Contents ix 28. Crosslinked Polyethylene 735 Bllarot Dave' 29. Millable Polyurethane Elastomers 753 Klalrss Knoerr and Uwe HofSlnann 30. Cast Polyurethane Elastomers 765 Klaw Reeker 31. Polynorbornene Rubber 775 Ani1 K. Bhonwick, C. Stein, and Ho~~rLr.d S tephens 32. Nitrile and Hydrogenated Nitrile Rubber 785 Saclzio Huycrslli 33. Diene-Based Elastomers 817 Jcrdit E. Plrskas 34. Recycling of Rubber 835 Willianl H. Klingerwnith and Krishna C. Bararntwl 35. EPDM Rubber Technology 845 Richard Karpeles mrl Anthony V. Grossi 36. Isobutylene-Based Elastomers 877 Neil F. Nert-rnnrt and James V. Flrsco Ind ex 909
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