Handbook of Corrosion Data Edited by Bruce D. Craig David B. Anderson Manager, Book Acquisitions Veronica Flint Production/Design Dawn R. Levicki The ate als ~nlormalonb loc~sty ASM lnternationalB Materials Park, OH 44073 Copyright1995 by ASMInternational@ Allrightsreserved Nopartofthisbookmaybereproduced,storedinaretrievalsystem,ortransmitted,inanyformorby anymeans,electronic,mechanical,photocopying,recording,orotherwise,withoutthewrittenpermission ofthecopyrightowner. Firstprinting,June1995 Secondprinting,December1997 Thirdprinting,April2002 Thisbookisacollectiveeffortinvolvinghundredsoftechnicalspecialists.Itbringstogetherawealthof information from worldwide sourcesto helpscientists, engineers, and technicians solve currentand longrangeproblems. 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Nothingcontainedinthisbookshallbeconstruedasagrantofanyrightofmanufacture,sale,use,or reproduction,inconnectionwithanymethod,process,apparatus,product,composition,orsystem,whether or notcoveredby letters patent,copyright. ortrademark, andnothingcontained in thisbookshallbe construedasadefenseagainstanyallegedinfringementofletterspatent,copyright,ortrademark,orasa defenseagainstliabilityforsuchinfringement. Comments,criticisms.andsuggestionsareinvited,andshouldbeforwardedtoASMInternational. LibraryofCongressCatalogingCardNumber:94-73644 ISBN:0-87170-518-4 SAN:204-7586 ASMInternational's MaterialsPark,OR44073-0002 www.asminternational.org PrintedintheUnitedSillIesofAmerica Preface TheHandbookofCorrosionDataisorganizedonthebasisofenvironment(chemicalcompound)ratherthanalong thelinesofaspecificalloysystem.However,thedesignerorapplicationsengineerismoreoftenfacedwithchoos inganalloyforaspecificenvironment.Therefore,moreanalysismaybenecessarytoprovideacompletecompari son. Bookssuch as the CorrosionDataSurvey,6thEdition,NACE(1985) are an excellentcomplementto this handbook. Thereaderiscautionedthatcorrosionisindeedacomplexsubjectandthatsimplylookingupthemajorchemical componentinasystemmaynotbesufficienttoentirely define thealloys thataresuitablefor application.Infact, itisfarmore commonthatrelativelysmallconcentrationsofother chemicalconstituentsmay beamore control lingfactor intheselectionofmaterialsthanthemajorcomponent. Thus, itisincumbentonthereadertoconsider allthechemicalspeciesexpectedintheenvironment,aswellastheeffectsoftemperature,pressure,flowrate,etc. oncorrosion. AgoodresourceistheMetalsHandbook,Volume13,publishedbyASMInternational,whichalso includeskeyreferencesonspecificalloysandenvironments. TheHandbookofCorrosionDataisintendedtoprovideastartingpointfromwhichmore detailedanalysisofthe literaturemaybeinitiatedtodullyevaluatetheperformanceofmetalsincorrosiveenvironments.Abookthatpre sentsprimarilytables andgraphscannotinclude alloftheimportantsupportdataavailableintheoriginalpaper. Therefore,theoriginalpapersmustbeconsultedforimportantparametersthataffectcorrosion,suchastestdura tion,solutioncomposition,temperature,stresslevel,heattreatment,etc.Finalselectionofmetalsforaspecificen vironment should be based on more detailed literature surveys and/or testing in the actual or a simulated environment. Thepurposeofthisbookistoprovidethose involved with the corrosionofmetals andalloys astartingpointto quicklyandeasilyassesstherecentliteratureonmetalsincorrosiveenvironments.Thishandbookisnotintended toprovideallofthedataavailableintheliteratureoneveryenvironmentthatexists.Forcertainenvironments(i.e. sulfuricacid), asignificantamountofworkhasbeenperformedoverthe years,suchthatspecificdata orgraphs have beenadoptedasclassicreferencematerialonthesubject. Theseclassicpieceshavebeenincludedtoaidthe readerin"cominguptospeed"onaspecificenvironment. Finally,thisbookisacomplementtothecorrosiondatabasefromASMInternational.Whilethehandbookcontains somegraphicalmaterialnotincludedinthedatabase,allofthetabulardataareidentical.Thedatabasecompilation was atimeconsuming,tediousprocessforwhichIthankmyco-editor,DavidAnderson. Withouthiseffortsand attentiontodetail,thedatabase,andthereforethishandbook,couldnothavebeenproduced. BruceCraig Denver,Colorado September,1994 References/991 References Used in Compiling the Environment Introduction and Summaries G,S, Brady and H.R. Clauser, Ed" Materials Handbook, 11th ed. MetalsHandbook, 9thed, Voll3,Corrosion,ASMInternational,Met McGraw-HilI,NewYork,1977,1011 pages alsPark,OH,1987 Guidelines/ortheUse0/AluminumwithFoodandChemicals,5thed. C.D,Hodgman,RC.WeastandS,M.Selby,Ed" Handbookof'Chemis TheAlwninumAssociation,Inc.,Washington,DC,1984 tryandPhysics,42nded, TheChemicalRubberPublishingCo.,Cleve land,1961,3481pages Lead/orCorrosionResistantApplications:A Guide, LeadIndustries Association,NewYork,NY S.P.Parker,Ed" McGraw-HiliDictionaryof'Chemistry; McGraw-Hili, NewYork,1984,665pages Zinc: Its CorrosionResistance,InternationalLeadZincResearchOr ganization,Inc" NewYork,NY,1983 RL, Shriner,RC.Fuson,andD,y' Curtin,TheSystematicIdentifica tionof'OrganicCompounds:ALaboratoryManual,5thed. JohnWiley Productliteraturefromthefollowingproducers:INCOAlloysInterna &Sons,NewYork,1964,458pages tional,AlleghenyLudlumCorporation,CarpenterTechnologyCorpo ration, Haynes International, Teledyne Wah Chang, Ampco Metal HH.Sister,C,A.VanderWerf,andA.WDavidson,CollegeChemistry: Company,DowChemical,CyclopsCorp.,MetallwerkPlanseeGmbH, A SystematicApproach, 2nd ed., MacMillan, New York, 1961,709 ImperialMetalsIndustries,Ltd" JessopSteelCompany,ClimaxMolyb pages denum,TheDurironCompany,Inc.,Armco,Inc. 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