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Handbook of Combustion, Volume 2 (Combustion Diagnostics and Pollutants) PDF

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j 1 1 An Overview of Combustion Diagnostics AlfredLeipertz,SebastianPfadler,andRobertSchießl 1.1 Introduction Duringthepastthirtyyears,tremendousprogresshasbeenmadeinthedevelopment ofdiagnostictoolsforcombustionresearch.Theresultsobtainedbyapplyingthese diagnostic techniques has contributed greatly to the current understanding of combustion, to the improvement of practical combustion devices with a lesser impactontheenvironment,andtothedevelopmentofnewcombustionprocesses. Thefieldhasgrownquickly,especiallyduringthepasttwodecades,suchthattoday combustiondiagnosticsareusedformanifoldpurposesthatincludefundamental researchinacademia,powerplantcontrol(fordiagnosingpollutantemissionsand ensuringreliableoperation),orproductiontechnology(tooptimizetheproduction processesforcommercialgoods).Asitisdifficulttoprovideabriefoverviewthatfully meetstherequirementsofallthesegroups,thischapterneednotincludeacomplete anddetailedoverview.Rather,itincludesthedetailsofdedicatedtechniquesandtheir use in both scientific and technical applications. Consequently, only the essential propertiesofparticulardiagnostictechniques,togetherwithsomeexamplesoftheir uses,arediscussedhere.Hence,amoregeneraldiscussionoftheroleofdiagnostics withinthefieldofcombustionscienceandtechnologyisprovided. First,thosequantitiesandphenomenathatarerelevanttocombustionprocesses, and which are therefore targets for diagnostic approaches, are outlined. It is also shown that the appropriate choice of suitable measurement techniques depends heavily on the particular properties of the combustion process to be investigated. Basedonthesegeneralaspects,severaldiagnostictechniquesaredescribedthatare commonly used to investigate combustion phenomena. These techniques can be splitintotwoclasses,namelythosebasedonmechanicalprobing,andthosewhich utilize optical diagnostics. The discussion of each technique includes a short treatmentoftheunderlyingphysics,anassessmentoftheapplicabilityofthemethod incombustionprocessesatbothlaboratoryandtechnicalscale,andoftheabilityof HandbookofCombustionVol.2:CombustionDiagnosticsandPollutants EditedbyMaximilianLackner,FranzWinter,andAvinashK.Agarwal Copyright(cid:1)2010WILEY-VCHVerlagGmbH&Co.KGaA,Weinheim ISBN:978-3-527-32449-1 j 2 1 AnOverviewofCombustionDiagnostics themethodtofulfilltheneedsforspatialandtemporalresolution,nonintrusiveness, androbustness. Afurthersectionisdedicatedtoimagingandmultidimensionaldiagnosticsand,in describingthesimultaneoususeofthedifferentmeasurementtechniques,thestate of the art of laser diagnostics in combustion research is highlighted. Finally, the potentialoflaser-diagnosticstovalidatethoseapproachesusedinnumericalsimula- tionsisdiscussed.Theoverviewiscompletedbytheprovisionofaccessiblequantities andrelevantdiagnostictechniques,detailingcomprehensiveinformationrelatingto theapplicationofdifferentcombustiondiagnostictechniques. Theadventoflasersmayberegardedasthemainstartingpointforthetremendous developmentofspectroscopicmethodsforcombustiondiagnostics.Previously,both emissionandabsorptionspectroscopyhadcontributedtothecombustionsciences well before the onset of laser technologies. Indeed, the existence in flames of (cid:1) (cid:1) (cid:1) (cid:1) (cid:1) important intermediate species such as OH , CH , HCO , NH or C had been 2 provenbyusingspectroscopicmethods.Yet,spectroscopybasedonlasersoffered novel,vastlyrefinedwaysinwhichthecombustionphenomenacouldbeobserved.By employing the small spectral bandwidth of laser light, it became possible to distinguishortoisolatedifferentspectralfeaturesofatomsandmoleculesatmuch greaterresolutionthanintheabsenceofacoherentlightsource,whiletheabilityto produceultra-short laserpulsesmadepossibletheresolutionandanalysis ofvery rapidandtransientprocesses.Notably,laserbeamscanbeformedveryeasilyinto well-defined,sharpgeometricshapesthataremorepointlike,line-likeandplane-like thanispossiblewithconventionallightsources,whilstthedirectionofpropagationof laserlightcanbecontrolledwithgreatprecision.Consequently,itbecamepossibleto defineirradiated(probed)volumeswithgreataccuracy,andoververylargedistances. Taken together, this collection of unique properties led to laser diagnostics becomingthemostwidelyusedprocedures,notonlyinfundamentalandapplied combustionresearchbutalsofortheinvestigationandcontrolofpracticalcombus- tionsystems. 1.2 DiagnosticsinCombustion:TasksandRequirements Asitisdifficulttounderstandthetasksandneedsofcombustiondiagnosticswithout any prior knowledge of the properties of combustion, a brief description of such properties shouldhelpto explain how certain requirements are imposed ondiag- nostictechniques. The desired temporal and spatial resolution of a measurement depends on the governingtimeandlengthscalesofthesystemtobecharacterized.Anestimateof these scales for a small collection of different combustion applications is shown inTable1.1. Combustionoftenoccursasaspatiallyextremelyinhomogeneousprocessinthin, sheet-likeregions(flames).Since,inmostrealisticcombustionsystems,thethick- ness of these layers is on the order of some ten to hundred micrometers, an j 1.2 DiagnosticsinCombustion:TasksandRequirements 3 Table1.1 Timeandlengthscalesofsomedifferentcombustionsystems[1]. Application Timescale(ms) Lengthscale(m) Flamemeasurement–laminar 105–106 10(cid:2)4–10(cid:2)2 Flamemeasurement–turbulent 10(cid:2)2–102 10(cid:2)5–10(cid:2)2 Fireresearch 102–103 10(cid:2)5–10(cid:2)2 Jetengine;compressorinlet 103–104 10(cid:2)4–10(cid:2)1 Gasturbineburner 10(cid:2)1–101 10(cid:2)5–10(cid:2)4 Afterburner 10(cid:2)1–100 10(cid:2)5–10(cid:2)4 investigationofthesetinystructureswillrequireahighspatialresolution,aprecise alignment,andanaccuratedefinitionofthemeasurementvolume.Figure1.1shows, foranadditionalillustrationofthelengthscales,thecomplexstructureofasteady laminar flame (taken from a numerical simulation) by species mass fraction and temperatureprofilesacrosstheflamefront. Combustion also involves a wide range of time scales; some relevant chemical reactionsoccurwithinafewnanoseconds,whilemanychemicalspeciesthatplaykey rolesincombustionchemistryexistforonlyveryshorttimeintervals,intherangeof hundredsofnanosecondsormicroseconds. Aninabilitytoresolvetheseshorttimescalesmeansthatmanyoftheessential aspects of combustion measurements may be missed. However, the use of lasers allowsthetemporalresolutionorshortmeasurementtimesrequiredtoobservethese rapidprocessestobeachieved,oneexamplebeingthestructureshiddeninaflame (Figure1.2). Otheraspectsofcombustionthatimposehighdemandsondiagnostictechniques include the complexity and high parametric sensitivity of many combustion pro- cesses.Duetothestrongnonlinearityoftheequations(mostlythechemicalsource Figure1.1 (a)Structureofapremixedmethane/airflameat20bar(simulation).Thespatialextent ofthesceneshownis0.1mm;(b)Sketchofthetemporalandspatialscalesrelevantincombustion. j 4 1 AnOverviewofCombustionDiagnostics Figure1.2 Temperaturestructureofaturbulentflametakenbytwo-dimensionalRayleigh scattering(falsecolorrepresentation,topright)whichishiddeninflamephotography(bottom left)[2]. term)thatgovernthedynamicsofacombustionsystem,thosespeciesthatexistin tinyamounts[downtomassfractionsintheparts-per-million(ppm)scale]mayexert a greater influence on the system’s behavior than those which are abundantly present,inthepercentrange.Theabilitytodetectandmeasurethese“key”species (cid:1) (cid:1) (e.g.,OH ,CH inFigure1.1),withoutinterferencefromthemuchmoreabundant “bath”ofhundredsorthousandsofotherspecies,representsamajorrequirementfor thesuccessfulexperimentalanalysisofcombustion. Thepotentiallyhighsensitivityofcombustionwithrespecttovariationsinphysical boundaryconditionscanrenderprohibitivetheuseofmeasurementtechniquesthat greatly alter the physical conditions during an experiment. Clearly, a diagnostic technique should not alter the system that it is attempting to measure; indeed, a majorindicatorforthequalityofadiagnostictechniqueinthisrespectwouldbeits level of nonintrusiveness. Recognized diagnostic techniques can be quite sharply separated,basedontheirlevelofintrusion,withmostopticaltechniquesconsidered nonintrusive,andthoseinvolvingmechanicalprobeshighlyintrusive. Finally,majorconstraintsexistwhenadiagnostictechniqueistobeusedwithina technical combustion environment. Unlike laboratory systems, most practical en- vironmentsarenotdesignedspecificallytoalloworalleviatediagnosticproceduresto becarriedout.Hence,diagnostictechniquesmustoftenbeappliedunderconditions thatarenotoptimallysuitedtotheunderlyingmeasuringprinciples.Animportant propertyofadiagnostictechniqueis,therefore,its“robustness”–thatis,itsabilityto functionreasonablywellunderconditionsthatmaydeviatestronglyfromthosefor j 1.3 InvasiveTechniques 5 which the technique was originally designed. Robustness also implies that the instruments used for diagnostics can operate under the adverse conditions (e.g., hightemperaturesandpressures,presenceofhighlyreactivesubstances)encoun- tered in combustions. The ideal diagnostic technique must be sufficiently robust enoughtosurvivehostileenvironments,andtoprovidealargeamountofcombus- tion-relatedinformation. 1.3 InvasiveTechniques Traditionalapproachesforcombustiondiagnosticsaretypicallybasedontechniques whereamechanicalprobeisinserteddirectlyintoaregionofinterest.Thismaybe either a sensitive part of the measurement system, or a device that samples the mediumofinterest(eithercontinuouslyorbatchwise)atthemeasurementpointfora subsequentexsituanalysis.Althoughthefollowingapproachesareoftenusedfor measurementsunderpracticalconditions,themostundesirablepropertyofinvasive probes–thatis,alocalinteractionwiththemeasurementsystemtobeanalyzed– remainsunavoidable,andtheoftennon-negligibleinherentsystematicerrorsmust be carefullyweighed if themeasured quantity istobe rated.Therelevance ofthe problemscausedbymechanicalprobesdependsonthemechanicalsizeoftheprobe relativetothesizeofthecombustionfieldunderinvestigation. 1.3.1 Temperature Fortechnicalapplications,thetemperatureinsideacombustionchamberisprobably themostimportantstatevariabletobemeasured.Thesameholdsforfundamental investigationsindownscaledmodelflames,wheretremendousprogresshasrecently beenmadewithregardstotheanalysisoftemperaturedistributions. 1.3.1.1 Thermocouples Byfarthemostwidelyuseddevicesfordeterminingtemperaturesincombustion systems are thermocouples. Here, the underlying physical principle is the Seebeck effect,whichdescribestheoccurrenceofamaterial-dependentelectricvoltagewhena temperaturedifferenceexistsbetweenthejunctionpointsoftwodifferentconductor materials that form a closed loop. In practice, the two different materials provide standardized (albeit nonlinear) voltage–temperature characteristics over the appli- cabletemperature ranges.Thedetails ofsome different materialpairsofthermo- couplesandtheirapplicationrange,thatcanbeusedincombustionsystemsarelisted inTable1.2.Dependingonthetemperaturerangeencountered,themeasurement accuracyis0.5–0.75%oftheindicatedtemperature,althoughatleast(cid:3)2K[3]canbe improveduponbyusinganappropriatecalibration. Aswithallinvasivetechniques,themaindrawbackofthermocouplesisthatthe probe(s) must be placed directly into the measurement volume, where it can j 6 1 AnOverviewofCombustionDiagnostics Table1.2 Pairsofthermocouplematerialsandtheirapplicationranges(typesJ,K,R,BafterRef.[3]; typeDafterRef.[5]). Internationalcodeletter Material Applicationrange((cid:4)C) J Fe/Constantan (cid:2)210–1200 K Ni-Cr/Ni-Al (cid:2)270–1372 R Pt-(13%)Rh/Pt 0–50–1768 B Pt-(30%)Rh/Pt-(6%)Rh (cid:2)000–1820 D W-(26%)Re/W-(5%)Re 00-0–2315 influencetheflameviaanumberofmechanisms.However,inviewoftherobust measurementprinciplethesewell-knowndisadvantagesareoftenacceptedformany applications.Dependingonthedimensionsoftheprobeandtheflowconditionsof the measurement object, the local flow field in the probed volume can be greatly influenced;themixingoffuelandoxidizerortheturbulence–chemistryinteraction canalsobeaffectedbysuchnonisokineticsampling.Furthermore,theheatbalance of the flame may be affected by heat conduction and radiation, mainly from the surrounding burning chamber walls. In addition, certain materials on the sensor surfaceareknowntoactaschemicalcatalysts,andthismustbedifferentiatedagainst thereactionofthethermocouplematerial(mostlyplatinum;seeTable1.2)byusing chemically active species that increase the decomposition of the normally stable refractoryceramicswhich,inmostcases,serveasaninsulationmaterialintheflames or at high-temperature atmospheres. Heitor and Moreira [4] have provided an excellent overview of the drawbacks and successful applications of these sensors inthefieldofcombustiondiagnostics. 1.3.1.2 ResistanceThermometry Resistance thermometry represents another invasive technique for temperature measurements,inwhichtemperature-dependentchangesintheelectricalresistance of a conductor material are used to determine local temperatures with point-wise precision. Despite the perfect linearity of resistance-based thermometers and the availabilityofstandardizedtypes(e.g.,withplatinum;Pt100),themaindrawbackof resistancethermometry,whencomparedtothermocouples,isitslimitedapplication rangeofuptoabout1300Kandthelongresponsetimesrequired.Theaccuracyofthe techniqueexceedsthatofthethermocouple,however[6]. 1.3.1.3 ThermochromePaintings Inrecentyears,thermochromepaintingshavebecomepopularforprovidingamore crudeestimationof,forexample,thesurfacetemperaturesofcomponents.Thebasic principlebehindsuchcolorformationistheabilityofcertainmaterialstoreversibly change their color as a function of the ambient temperature, this being due to changesinthematerials’crystalloidormolecularstructures.Anadditional,recently developed method of temperature measurement employs temperature-sensitive paints(TSPs);thisisbasedonthesensitivityoftheluminescentmoleculestotheir j 1.3 InvasiveTechniques 7 thermalenvironmentfollowing(ultraviolet)excitation[7].Ariseintemperatureof the luminescent molecule raises the probability that the molecule will return to groundstateviaanonradiationprocess,ratherthanemitaphoton.Thisthermally inducedphosphorescencequenchingformsthebasisofthetemperaturemeasure- mentviaaquantitativedetectionoftheemissionattenuation. 1.3.2 FlowVelocity 1.3.2.1 PitotTubes Traditionally, Pitot tubes have been used to measure the total pressure of moving fluids;bycombiningtheinformationacquiredwiththatrelatingtothesurrounding staticpressure,theflowvelocitycanbededucedfromthedynamicpressure(whichis thedifferencebetweenthetotalandstaticpressures).Prandtltubes(Pitotstatictubes) areusedtomeasurethetotalanddynamicpressuresimultaneously.Whereas,Pitot statictubesarestillusedinmodernairplanestomeasurethepressureandpressure differences simultaneously to determine both altitude and airspeed, the invasive probingtechniquesused tomeasure flowvelocityonapointwise basishavebeen largelysupersededbytheadventofnoninvasivelaserdiagnostics. Dibble et al. [8] have compared the velocities measured by laser Doppler ane- mometry(LDA;seeSection1.4.6.1)withPitottubemeasurements,inanonreacting jetflowandnonpremixedjetflames.ThediscrepanciesbetweenthePitotprobeand LDA measurements were within the range of 5% for the jet flow. However, an additionalsystematicerrorwasobservedintheturbulentflamewhenmeasuringthe dynamicpressurethatisattributedtoheattransfertothePitottube.Despitethese problems,Pitot-typesensorsarestillusedtodayinavarietyofapplications,onesuch examplebeingtosupportthenumericalsimulationsofdustexplosions[9].Inthis case, dust- and temperature-resistant Pitot-type anemometers used to measure turbulenceintensitieswerecombinedwithahigh-speedcameratovisualizeflame displacementandsimultaneouslyaccesstheratiobetweenturbulentflamespeedand turbulenceintensityunderdifferentoperatingconditions 1.3.2.2 HotWireAnemometry Thebasicprincipleofhotwireanemometry(HWA)canbeusedtodetermineflow velocitiesbymeasuringthecoolingofheatedwiresbyforcedconvectioninaflowthat isdependentontheflowvelocity(e.g.,Ref.[10]).AlthoughHWAisrecognizedasa classicdiagnosticmethodforturbulenceresearch,itcanonlybeusedtoinvestigate combustion systems in the unburned region of the flame to be analyzed. This is mainlyduetothefactthat,eveniftheanemometermaterialwereabletowithstand thehightemperaturesintheflames,therequiredtemperaturecorrectionswouldbe impracticable. Nevertheless, HWA is often used to characterize the turbulence conditions of combustion systems pointwise in the reactant zone. For example, HWAhasbeenusedforin-cylindermeasurementsinaninternalcombustionengine inacar[11],aswellastostudythepropagationofpremixednaturalgasairflamesina rectangularductwhichwasclosedatoneend[12]. j 8 1 AnOverviewofCombustionDiagnostics 1.3.2.3 IonizationProbes Analternativeinvasiveapproachfortheexaminationofflame-relevantvelocitiesis thatofionization(alsoLangmuir)probes,whereanelectricalfieldisappliedacross theflame.Thesubsequentlymeasuredcurrentsandpotentialscanthenbeusedto measureionconcentrations(e.g.,Ref.[13]),flamepositions(e.g.,Ref.[14]),orflame propagationspeeds(e.g.,Ref.[15]).Alternatively,forenginediagnosticsasparkplug hasbeenusedastheprobe[16]. 1.3.3 SpeciesConcentrations Measurementoftheconcentrationsofminorityandmajorityspeciespriorto,during, and/or after the actual combustion process, is essential not only for investigating fundamental combustion phenomena but also for process control applications. Differentprobingstrategiesareappliedingeneral,mainlydependingonthemea- surementprinciple,anddueinpartalsototheregularizedorhistoricallyestablished methodofsampling.Forexample,constantvolumesampling(CVS)hasbeenusedfor manydecadestosupportthetestingofvehicleemissions,wherebyaconstanttotal flowrateofavehicleexhaustplusdilutionairismaintained.Inorderforthistooccur, astheexhaust flowincreases, the dilutionair must be automaticallydecreased. In this case, a bag measurement of the emissions represents the key method for legislativepurposes,asitprovidesasinglevalueforthemajorexhaustspeciesofa completetestcycle,includingthedifferentphasesofaccelerationandconstantspeed. Although the sampling may be conducted in a continuous manner by using a suitableejectororprobingdevice(e.g.,Pitottubeorlow-pressuresampling),followed byadditionaldilutionstages,thequantitativeanalysisofthespeciesconcentration canbeperformedbatchwiseinthecaseofsomediagnostictechniques.Anexample ofthisisthegas-chromatographicmeasurementofspeciesinengineexhaustgases, althoughthisisalsooftenappliedtoananalysisofbasicpropertiessuchasheating valueandthecompositionofgaseoushydrocarbonfuelsforcombustioninstationary gasturbines. 1.3.3.1 FlameIonizationDetectors Traditionally, flame ionization detectors (FIDs) [17] are used to measure the con- centrations of hydrocarbons downstream in coiled columns that separate the inflowingspeciestobeanalyzedonthebasisoftheirdifferentretentiontimeson the column surface [18]. For exhaust gas analysis, these detectors can be used as stand-alone systems in order to quantify the amounts of unburned hydrocarbons (UHCs)asacomposite.ThephysicalprincipleofFIDsdependsonthefactthatapure hydrogenflameproducesverylittleionizationoftheinvolvedspecies,whereasthe addition of traces of hydrocarbons causes a drastic increase in the degree of ionization. Consequently, FIDs are composed of a hydrogen diffusion flame into whichthegastobeanalyzedisinserted;thisresultsinameasurabledirectcurrent (DC) signal of an applied electrostatic field in close vicinity to the flame in the presenceofUHCs. j 1.3 InvasiveTechniques 9 1.3.3.2 ChemiluminescenceDetectors Theanalysisofoxidesofnitrogen(NO )inexhaustgasesistypicallyconductedusing x chemiluminescence detectors, where the primary principle is a photo-physical (cid:1) detectionofthesignalemittedaselectronicallyexcitedNO decaystotheground 2 statefollowingthechemicalreactionofNOwithozone.TheNO concentrationsare 2 acquiredindirectlyviaanadditionalmeasurementoftheconcentrationofNOaftera preceding total conversion of the complete NO -load to NO; this is followed by a x simultaneous measurement of the NO concentration, without conversion and subtractionoftheobtainedconcentrations. 1.3.3.3 NondispersiveInfraredAnalysis The nondispersive infrared (NDIR) analyzer is a robust device which is used to measurecarbonmonoxide(CO)concentrationsinexhaustgases,bymakinguse ofthestrongbroadbandabsorptionnear4.7mm.Thedevicetypicallyconsistsof a reference and a probe cuvette, both of which are irradiated with IR light. The useofachopperwheelpermitsanalternatingIRradiationofboththegastobe analyzed and the reference gas mixture, such that no absorption occurs at the probed band of the spectrum. Often, an opto-pneumatic detector is applied that measures the flow between two additional absorption chambers located beneath the probe and the reference cell. Due to the different absorption rates in the latter cells, the IR-absorbing gases in the detector chambers feature different heating rates (and thus volumetric expansions) which are balanced by the flow through a microchannel. The latter effect is converted to an electric current that is proportional to the CO concentration in the probe volume. With this apparatus it is also possible to monitor CO , SO , NH , H O and other 2 2 3 2 exhaust gas components, by using appropriate absorption wavelengths (see Section 1.4.3). Concentrationsofoxygencanbemeasuredbymakinguseoftheelectrochemicalor paramagneticpropertiesofthedimer.Theelectrochemicalapproachisutilizedinthe exhaust ducts of almost all Otto engines with integrated three-way catalysts, for measuringandcontrollingthecompositionofthefuel–airmixture.Theprincipleof thepotentiometriclambdaoxygensensor(seealsoVol.2,Ch.4)isbasedontheoxygen ion conductivity of a ZrO -membrane with exhaust gas passing by on one side 2 (outer Pt electrode) and ambient air on the other side as a reference (the “inner Pt-electrode”). Theparamagneticapproachtomeasuringoxygenconcentrationsisbasedonthe strong magnetic susceptibility. In this case, a magnetomechanical principle is implemented that is based on a sensor in which a rotator comprising two nitro- gen-filledspheres(diamagnetic)isarrangedwithinasymmetricmagneticfield.Ifan oxygen-containing gas passes through the sensor, the oxygen is drawn into the magnetic field due to its paramagnetic property, thus strengthening the field. In contrast, any nitrogen inside the glass spheres will have an opposite magnetic polarizationandbeforcedoutofthefield,causingarotation.Thedegreeofdeflection thuscausedisproportionaltotheoxygenconcentration. j 10 1 AnOverviewofCombustionDiagnostics 1.3.3.4 GasChromatography/MassSpectrometry Inadditiontotheabove-mentionedspecies-specificdiagnostictechniquesthatare used widely in commercial sensor systems to characterize species concentrations under technically relevant conditions, gas chromatography (GC) and mass spec- trometry (MS) are each applied to investigate fundamental phenomena (see also Vol.2,Ch.2).Both,GCandMSsystemsoffertheopportunityofquantitativetrace analysis for a large number of species, based on a single-sensor system. Axford etal.[19]haveappliedMStothesamplingofionsfromatmosphericflamestostudy theeffectsofappliedelectricfields.Thekineticaspects[20]orspecialissuesinthe analysisofexhaustgascompositionofinternalcombustionengineshaveeachalso beeninvestigatedusingMSconcentrationmeasurements,anexamplebeingthatof oilemissions[21]. Flame studies have been performed using GC alone (e.g., Ref. [22]) or in combinationwithMS[23]. 1.3.4 Pressure Inthecaseoftechnicalapplications,measurementoftheburningchamberpressures (respectivelythepressureatfiringconditionsasavariableofstate)playsanimportant role,notonlywithregardstostabilityissuesbutalsotosecurityissues.Moreover, knowledgeofthelowerandupperprocesspressures,forexampleoftheidealJoule cycle, would provide direct information on the thermal efficiency. In the case of automotiveapplicationsinparticular,themeasurementofengineandcompressor cylinderpressurescanprovideadecisiveindicationofcompleteengineperformance, sinceitcanberelatedtotheengine’spower,efficiency,throughput,andleakstatus. Thetime-basedevolutionofcylinderpressureisalsoindicativeofthe“health”ofa machine,andenablescondition-basedmaintenance. Depending on the apparent temperature range, working atmosphere and pres- sure,andalsoonthetemporalresolution,differenttypesofpressuremeasurement methodsmaybeused.Foralmostallpressurerangesandlowsamplefrequencies,a simplemanometer-typepressuregaugecanbeusedinconjunctionwithresistive, capacitive,orinductivetransducers.Agoodexampleoftheapplicationofthissensor typeisinthemeasurementoffuelpressureinthesupplylinesofadomesticgasoroil burner. Piezoelectricorthin-filmstraingauge-typepressuresensorsareoftenusedwhen high sampling frequencies are necessary. This may apply especially to in-cylinder measurements,wherethesensorsmaybeintegratedintothesparkorglowplug(e.g., Ref. [24]). Another specific application for pressure measurements within harsh environmentsisintheinvestigationofcombustion-drivenpressureoscillationsin lean premixed gas turbines, where a feedback between heat release fluctuations and the burning chamber acoustics can result in severe combustion noise, with pressure amplitudes of several hundreds of millibars. In this case, piezoelectric pressuresensorsarebestsuitedfordetectingandmeasuringthedynamicpressure

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This five-volume reference work on combustion represents the first complete, in-depth coverage of the field. The contents range from an up-to-date presentation of gas, liquid and solid combustion, via pollutant formation and new technologies to combustion diagnostics and safety. Written by world-lea
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