Green Sustainable Process for Chemical and Environmental Engineering and Science: Switchable Solvents PDF
Preview Green Sustainable Process for Chemical and Environmental Engineering and Science: Switchable Solvents
GREEN SUSTAINABLE PROCESS FOR CHEMICAL AND ENVIRONMENTAL ENGINEERING AND SCIENCE This page intentionally left blank GREEN SUSTAINABLE PROCESS FOR CHEMICAL AND ENVIRONMENTAL ENGINEERING AND SCIENCE Switchable Solvents Edited by INAMUDDIN Department of Applied Chemistry,Zakir Husain College of Engineering and Technology, Facultyof Engineering and Technology, Aligarh Muslim University, Aligarh,India RAJENDER BODDULA CAS Key Laboratory of Nanosystemsand Hierarchical Fabrication, NationalCenterforNanoscience and Technology, Beijing, China ABDULLAH M. ASIRI Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia Elsevier Radarweg29,POBox211,1000AEAmsterdam,Netherlands TheBoulevard,LangfordLane,Kidlington,OxfordOX51GB,UnitedKingdom 50HampshireStreet,5thFloor,Cambridge,MA02139,UnitedStates Copyright©2022ElsevierInc.Allrightsreserved. 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Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusingany information,methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodsthey shouldbemindfuloftheirownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessional responsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,oreditors,assumeanyliability foranyinjuryand/ordamagetopersonsorpropertyasamatterofproductsliability,negligenceorotherwise,orfrom anyuseoroperationofanymethods,products,instructions,orideascontainedinthematerialherein. LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary ISBN:978-0-12-819850-6 ForinformationonallElsevierpublications visitourwebsiteathttps://www.elsevier.com/books-and-journals Publisher:SusanDennis AcquisitionsEditor:AnitaKoch EditorialProjectManager:EmeraldLi ProductionProjectManager:KumarAnbazhagan CoverDesigner:ChristianJ.Bilbow TypesetbySTRAIVE,India Contents Contributors ix 1. Switchablesolvents for bio-refinery applications 1 MuhammadZubairandAmanUllah 1. Introduction 1 2. Conceptofbiorefinery 2 3. Switchablesolventsforbiorefinery 4 4. Concludingremarksandfutureperspectives 15 References 16 2. Polarity-changing solvents for CO capture 21 2 ZeynabRezaeiyan,ShokufehBagheri,MohammadAminSedghamiz, andMohammadRezaRahimpour 1. Introduction 21 2. SwitchablesolventforCO capture 27 2 3. SwitchableionicliquidsolventforCO capture 32 2 4. Conclusions 34 References 35 3. Applications ofswitchable solventsinscience and technology 39 MohammadFarazAhmerandQasimUllah 1. Introduction 39 2. Switchablewater(SW) 45 3. Technologicalandanalyticalapplicationsofswitchablesolvents 47 4. Conclusions 54 References 54 4. Switchablesolvents for CO capture 61 2 SatishKumar 1. Introduction 61 2. EnvironmentalchallengesduetoCO 64 2 3. SwitchablesolventsforthedetectionofCO 66 2 4. SwitchablesolventsforCO extraction 67 2 5. ReversibleionicliquidsolventsforthecaptureofCO 90 2 v vi Contents 6. Conclusions 94 Acknowledgments 94 References 94 5. Switchable water 101 Dr.ElsaCherian 1. Introduction 101 2. Switchablepolaritysolvents 101 3. Switchablehydrophilicitysolvents 103 4. Switchablewater 104 5. Conclusion 106 References 106 6. Switchable solvents as alternative solvents for green chemistry 109 DivyaBajpaiTripathy,AnjaliGupta,AnuradhaMishra,M.A.Quraishi, MohammadLuqman,andMohd.FarhanKhan 1. Introduction 109 2. Discoveryofswitchablesolvents 111 3. Typesofswitchablesolvents 111 4. ChemistryanddevelopmentofSS 120 5. GenerallydesirablepropertiesofSS 122 6. Acceptabilityofswitchablesolventsforgreenchemistry 123 7. Applicationsofswitchablesolventsasgreenalternatives 124 8. Futureprospectsandconclusions 127 References 127 7. Nanomaterials synthesis inswitchable solvents 133 AnjaliGupta,DivyaBajpaiTripathy,MeenuAggarwal,MohammadLuqman, andMohd.FarhanKhan 1. Introduction 133 2. Ionicliquidsasswitchablesolvents 134 3. Reversemicellesfornanoparticlessynthesis 136 4. Reversemicro-emulsionsfornanoparticlesynthesis 141 5. Reversiblecappingagentsbasedonamines 143 6. Conclusion 144 References 145 8. CO -triggered switchable polaritysolvents and their advancements 149 2 PinkiChakraborty,AnupamaSharma,MohammadLuqman,Mohd.FarhanKhan, andKarthikaySankhydhar 1. Introduction 149 2. ChemistryofCO -triggeredSPS 150 2 Contents vii 3. CO -triggeredSPS 151 2 4. Challengesandfutureconsiderations 154 5. Conclusion 155 References 155 9. Switchablegreen solvents for lipidsextraction from microalgae 157 DebanjanSanyal,G.VenkataSubhash,NishantSaxena,WrijuKargupta,AjitSapre, andSantanuDasgupta 1. Introduction 157 2. Greensolvents 158 3. Microalgaelipidandextractionprocess 158 4. Perspectiveandconclusion 170 References 170 Furtherreading 174 10. CO triggered switchable and tunable solventsfor biocatalysis 177 2 K.K.AthiraandRameshL.Gardas 1. Introduction 177 2. Tunablesolventsforbiocatalysis 178 3. Switchablesolventsforbiocatalysis 180 4. Conclusionsandfutureperspectives 187 Acknowledgments 187 References 187 11. Basicsynthesisandsolvatochromicparametersinswitchablesolvents 191 NaushadAnwar,NimraShakeel,andMohdImranAhamed 1. Introduction 191 2. Chemicalsynthesisinaswitchablesolvent 192 3. Theoryonsolvatochromismprocess 193 4. Solvatochromicparameters 194 5. Conclusion 197 References 197 12. Switchable solventsfor catalysis 201 SaurabhJain,ShashankSharma,MohammadLuqman, andMohd.FarhanKhan 1. Introduction 201 2. Switchablehydrophilicsolvents 202 3. Solventswithswitchablepolarity 207 4. Switchablewater 209 viii Contents 5. Surfaceoperation(switchablecationic/anionicsurfactants) 212 6. Materialsthatrespondtostimuli 214 7. Applicationofswitchablesolventsascatalyst 215 8. Switchablesolventsforbiocatalysis 216 9. Conclusions 217 References 217 Index 225 Contributors Meenu Aggarwal Departmentof Chemistry,Aggarwal College, Faridabad, Haryana, India Mohd ImranAhamed Departmentof Chemistry,Aligarh Muslim University, Aligarh,Uttar Pradesh, India MohammadFaraz Ahmer Departmentof Electrical and Electronics Engineering, Mewat Engineering College, Nuh, Haryana, India Naushad Anwar Departmentof Chemistry,Aligarh Muslim University, Aligarh,Uttar Pradesh, India K.K. Athira Departmentof Chemistry,Indian Institute of Technology Madras,Chennai, India Shokufeh Bagheri Departmentof Chemical Engineering, Shiraz University, Shiraz, Iran Pinki Chakraborty School of Basic &Applied Sciences, Galgotias University, Greater Noida,India Dr. Elsa Cherian Departmentof Food Technology, SAINTGITS College of Engineering, Kottayam, Kerala, India Santanu Dasgupta Reliance Industries Limited, Jamnagar,Gujarat, India Ramesh L. Gardas Departmentof Chemistry,Indian Institute of Technology Madras,Chennai, India Anjali Gupta DepartmentofChemistry,SchoolofBasicandAppliedSciences,GalgotiasUniversity,Greater Noida, India Saurabh Jain Departmentof Biotechnology, MGIMT, Banthra, Lucknow, India Wriju Kargupta Monash University, Melbourne, VIC, Australia ix
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