Green Sustainable Process for Chemical and Environmental Engineering and Science: Green Solvents for Biocatalysis PDF
Preview Green Sustainable Process for Chemical and Environmental Engineering and Science: Green Solvents for Biocatalysis
GREEN SUSTAINABLE PROCESS FOR CHEMICAL AND ENVIRONMENTAL ENGINEERING AND SCIENCE This page intentionally left blank GREEN SUSTAINABLE PROCESS FOR CHEMICAL AND ENVIRONMENTAL ENGINEERING AND SCIENCE Green Solvents for Biocatalysis Edited by INAMUDDIN Assistant Professor,Department of AppliedChemistry, Faculty of Engineering and Technology, Aligarh Muslim University, Aligarh,India RAJENDER BODDULA CAS Key Laboratory of Nanosystemsand Hierarchical Fabrication, NationalCenterforNanoscience and Technology, Beijing, China MOHD IMRAN AHAMED DepartmentofChemistry,FacultyofScience,AligarhMuslimUniversity, Aligarh, India ABDULLAH M. ASIRI Professor, Department of Chemistry,Facultyof Science, King AbdulazizUniversity, Jeddah, Saudi Arabia Elsevier Radarweg29,POBox211,1000AEAmsterdam,Netherlands TheBoulevard,LangfordLane,Kidlington,OxfordOX51GB,UnitedKingdom 50HampshireStreet,5thFloor,Cambridge,MA02139,UnitedStates ©2021ElsevierInc.Allrightsreserved. Nopartofthispublicationmaybereproducedortransmittedinanyformorbyanymeans,electronicormechanical, includingphotocopying,recording,oranyinformationstorageandretrievalsystem,withoutpermissioninwriting fromthepublisher.Detailsonhowtoseekpermission,furtherinformationaboutthePublisher’spermissionspolicies andourarrangementswithorganizationssuchastheCopyrightClearanceCenterandtheCopyrightLicensingAgency, canbefoundatourwebsite:www.elsevier.com/permissions. ThisbookandtheindividualcontributionscontainedinitareprotectedundercopyrightbythePublisher(otherthanas maybenotedherein). Notices Knowledgeandbestpracticeinthisfieldareconstantlychanging.Asnewresearchandexperiencebroadenour understanding,changesinresearchmethods,professionalpractices,ormedicaltreatmentmaybecomenecessary. Practitionersandresearchersmustalwaysrelyontheirownexperienceandknowledgeinevaluatingandusingany information,methods,compounds,orexperimentsdescribedherein.Inusingsuchinformationormethodsthey shouldbemindfuloftheirownsafetyandthesafetyofothers,includingpartiesforwhomtheyhaveaprofessional responsibility. Tothefullestextentofthelaw,neitherthePublishernortheauthors,contributors,oreditors,assumeanyliabilityfor anyinjuryand/ordamagetopersonsorpropertyasamatterofproductsliability,negligenceorotherwise,orfromany useoroperationofanymethods,products,instructions,orideascontainedinthematerialherein. LibraryofCongressCataloging-in-PublicationData AcatalogrecordforthisbookisavailablefromtheLibraryofCongress BritishLibraryCataloguing-in-PublicationData AcataloguerecordforthisbookisavailablefromtheBritishLibrary ISBN:978-0-12-819721-9 ForinformationonallElsevierpublications visitourwebsiteathttps://www.elsevier.com/books-and-journals Publisher:SusanDennis AcquisitionsEditor:KostasKIMarinakis EditorialProjectManager:EmeraldLi ProductionProjectManager:KumarAnbazhagan CoverDesigner:ChristianJ.Bilbow TypesetbySPiGlobal,India Contents Contributors xi 1. Biocatalysis inindustrialbiodiesel andbioethanol production 1 DipeshKumar,AyanBanerjee,andBhaskarSingh 1. Introduction 1 2. Biodieselproduction 1 3. Biocatalystsinlignocellulosicethanolproduction 18 4. Conclusion 23 References 23 2. Anticancer potentialof green solvents 29 D.JiniandA.Anitha 1. Introduction 29 2. Greensolvents 30 3. Anticancerpotentialofgreensolvents 33 4. Useofgreensolventsintheextractionofoilanditsanticanceractivity 43 5. Conclusionandfuturedirections 44 References 46 3. Supercritical CO for biocatalysis 55 2 ShokufehBagheri,HamidrezaBagheri,MohammadAminSedghamiz,and MohammadRezaRahimpour 1. Introduction 55 2. Kindsofnonaqueoussolventsusedforbiocatalysis 58 3. Supercriticalfluid 59 4. Applicationsofsupercriticalcarbondioxide(SC-CO )solventsinbiocatalysts 65 2 5. Conclusionsandfuturetrends 69 References 70 4. Biocatalysis:Fundamentals and solvent parameters 73 HilalAcidereli,EdaGokırmakSogut,SibelDemirogluMustafov, MehmetGulcan,andFatihSen 1. Introduction 73 2. Biocatalysis 74 v vi Contents 3. Futureperspectives 82 4. Conclusion 82 References 82 5. Biosolvents for biocatalysis 85 MahmoudEl-Maghrabey,MohamedAmin,AbdelazizElgaml,and RaniaEl-Shaheny 1. Introduction 85 2. Classificationofbiosolventsaccordingtotheirchemicalstructure 87 3. Applicationofbiosolventsinbiocatalysis 95 4. Conclusions 103 References 103 6. Immobilized ionic liquids for biocatalysis 109 M.J.Salar-GarcíaandV.M.Ortiz-Martínez 1. Introduction 109 2. Oxidoreductases 111 3. Hydrolases 118 4. Conclusions 121 References 121 7. Biocatalysis in nonaqueous media 125 MohdImranAhamed,NimraShakeel,andNaushadAnwar 1. Introduction 125 2. Selectionofnonaqueoussolvents 127 3. Propertiesofnonaqueoussolventmedia 128 4. Biocatalysisinsupercriticalfluids(enzymeactivity) 129 5. Biocatalysisinnonaqueousorganicsolvents 132 6. Biocatalysisinhydrophobicionicliquids 133 7. Conclusion 136 References 136 8. Green fluorosolvents for biocatalysis 143 MuhammadFaisal 1. Introduction 143 2. Applicationofgreenfluorosolventsinbiocatalyzedresolutionandsynthesis 147 3. Conclusion 159 References 159 Contents vii 9. State of the art andperspectivesofgreen solvents in biocatalysis 163 KrishnamoorthyLalitha,Y.SivaPrasad,andSubbiahNagarajan 1. Introduction 164 2. Reactionmediumforbiocatalysis 165 3. Supercriticalfluids 167 4. ApplicationsofscCO 169 2 5. Othergreensolvents 185 6. Conclusion 185 7. Futureperspectives 185 Acknowledgments 187 References 187 10. Ionic liquids as agreen solvents for drugsoras anactive pharmaceutical ingredient 193 FarahBashir,NawshadMuhammad,NajmulHassanKhan,AbdurRahim, PervaizAhamad,AmirSadaKhan,ZahoorUllah,andMuhammadSamie 1. Introduction 193 2. Properties 195 3. Pharmaceuticalapplications 195 4. ILsasactivepharmaceuticalingredients 196 5. SynthesisofAPI-ILs 199 6. ThefutureofILsasAPIs 201 7. ILsassolvents 202 8. Ionicliquidsinproductionofpharmaceuticaldrugsasanalternativemedium 202 9. Ionicliquidsindrugdelivery 204 10. Conclusion 206 References 206 11. Switchable solventsfor biocatalysis 211 RaniaEl-Shaheny,MahmoudEl-Maghrabey,andFathallaBelal 1. Introduction 211 2. Classificationofswitchablesolvents 211 3. MechanismofthereactionofCO withaminesandalcohols 217 2 4. Applicationsofswitchablesolvents 219 5. (Un)greennessofbiocatalysis:Facts,solutions,andmotivesforusingswitchable solvents 220 6. Realapplicationsofswitchablesolventsinbiocatalysis 224 7. Conclusions 231 References 231 viii Contents 12. Ionic liquids for biocatalysis 235 NaushadAnwarandMohdImranAhamed 1. Introduction 236 2. Selectionofthecomponents 239 3. ILsasmediaforbiocatalyticreactions 240 4. Conclusions 248 References 248 13. Organic carbonate as a green solvent for biocatalysis 253 CongChienTruong,DineshKumarMishra,andVivekMishra 1. Greensolvents 253 2. Organiccarbonates 253 3. Syntheticroutes 254 4. Carbonatesasthesolvents 257 5. Applicationsofgreenorganiccarbonatesinchemicaltransformation 258 6. Applicationinbiocatalysis 265 References 269 14. Ionic liquid-mediated biocatalyzed organictransformations 277 BubunBanerjeeandAditiSharma 1. Introduction 278 2. Ionicliquid-mediatedorganictransformationsusingbiocatalysts 278 3. Conclusions 295 Acknowledgments 295 References 295 15. Applicationofsupercritical waterin biocatalytic processes 301 SetarehHeidari,ErfanSadatshojaei,JalalForoozesh,andMohammadLatifi 1. Introduction 301 2. Choiceofsolventforenzymaticreactions 302 3. ParametersaffectingSCF-biocatalyticsystems 304 4. Applicationofsupercriticalwatertechnologiesinbiocatalyticprocesses 315 5. Challengesandlimitations 318 6. Conclusion 319 References 319 Contents ix 16. The potential use of supercriticalCO as a sustainablesolvent 2 in biocatalytic reactions 325 ErfanSadatshojaei,SetarehHeidari,andReihanehHaghniaz 1. Introduction 325 2. BiocatalysisinscCO 327 2 3. Biocatalysisreactions 327 4. Challengesandopportunities 337 5. Conclusion 338 References 338 17. Sustainableapproachinbiocatalyticpreparationofantibioticpeptide 345 ErfanSadatshojaei,SetarehHeidari,andDavidA.Wood 1. Introduction 345 2. Antibioticpeptides:Characteristicsandfunctionality 347 3. Cyclicpeptidesandrelatedpeptidemolecularcomplexities 350 4. Peptidesynthesis 352 5. Conclusions 363 References 363 18. Ionic liquids andtheirbeneficial contributions to enzyme-catalyzed reactions, catalytic biomassconversion and energy conversion and storage systems 369 SetarehHeidari,ErfanSadatshojaei,andDavidA.Wood 1. Introduction 369 2. Ionic-liquidsynthesis 371 3. Recentlydevelopedionic-liquidapplications 382 4. Conclusion 399 References 400 Index 409
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