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Green polymer composites technology: properties and applications PDF

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GREEN POLYMER COMPOSITES TECHNOLOGY Properties and Applications GREEN POLYMER COMPOSITES TECHNOLOGY Properties and Applications Edited by Inamuddin CRC Press Taylor & Francis Group 6000 Broken Sound Parkway NW, Suite 300 Boca Raton, FL 33487-2742 © 2017 by Taylor & Francis Group, LLC CRC Press is an imprint of Taylor & Francis Group, an Informa business No claim to original U.S. Government works Printed on acid-free paper Version Date: 20160701 International Standard Book Number-13: 978-1-4987-1546-1 (Hardback) This book contains information obtained from authentic and highly regarded sources. Reasonable efforts have been made to publish reliable data and information, but the author and publisher cannot assume responsibility for the validity of all materials or the consequences of their use. The authors and publishers have attempted to trace the copyright holders of all material reproduced in this publication and apologize to copyright holders if permission to publish in this form has not been obtained. If any copyright material has not been acknowledged please write and let us know so we may rectify in any future reprint. Except as permitted under U.S. Copyright Law, no part of this book may be reprinted, reproduced, transmitted, or utilized in any form by any electronic, mechanical, or other means, now known or hereafter invented, including photocopying, microfilming, and recording, or in any information storage or retrieval system, without written permission from the publishers. For permission to photocopy or use material electronically from this work, please access www.copyright.com (http://www.copyright.com/) or contact the Copyright Clearance Center, Inc. (CCC), 222 Rosewood Drive, Danvers, MA 01923, 978-750-8400. CCC is a not-for-profit organization that provides licenses and registration for a variety of users. For organizations that have been granted a photocopy license by the CCC, a separate system of payment has been arranged. Trademark Notice: Product or corporate names may be trademarks or registered trademarks, and are used only for identification and explanation without intent to infringe. Library of Congress Cataloging‑in‑Publication Data Names: Inamuddin, 1980- editor. Title: Green polymer composites technology : properties and applications / edited by Inamuddin. Description: Boca Raton : Taylor & Francis Group, CRC Press, 2017. | Includes bibliographical references and index. Identifiers: LCCN 2016011520 | ISBN 9781498715461 (alk. paper) Subjects: LCSH: Polymeric composites. | Green chemistry. Classification: LCC TA455.P58 G74 2017 | DDC 620.1/920286--dc23 LC record available at https://lccn.loc.gov/2016011520 Visit the Taylor & Francis Web site at http://www.taylorandfrancis.com and the CRC Press Web site at http://www.crcpress.com Contents Preface..........................................................................................................................................................................................ix Acknowledgements ......................................................................................................................................................................xi Editor .........................................................................................................................................................................................xiii Contributors ................................................................................................................................................................................xv Chapter 1 Bio-Based New Materials for Packaging Applications ...........................................................................................1 Asier Martinez, Itziar Egüés, Oihana Gordobil, Jalel Labidi and Susana C.M. Fernandes Chapter 2 Innovative Green Foams: Opportunities and Challenges in Industrial Potential Applications ............................19 Fatima Charrier – El Bouhtoury Chapter 3 Properties and Applications of Polysaccharide Green Polymer Composites for Antibacterial and Anti-Fogging Coatings in Food ............................................................................................................................31 Vito Verardo, Javier Miguel Ochando-Pulido, Sandra Pimentel Moral, Antonio Segura-Carretero, Antonia Garrido-Frenich, Alberto Fernández-Gutiérrez and Antonio Martínez-Ferez Chapter 4 Binders Such as Adhesives, Gums, Wallpaper Paste, Resins, or Any Subclass in Polymer Division ..................49 R. Rajasekar, C. Moganapriya, P. Sathish Kumar, P. Navaneethakrishnan and Inamuddin Chapter 5 Active Bio-Packaging: Recent Developments and Applications ...........................................................................63 Franciele Maria Pelissari, Tanara Sartori, Fabiana Helen dos Santos, Gustavo Molina and Florencia Cecilia Menegalli Chapter 6 Utilities Such as Purchase Bags, Goods Packaging and Composting Bags ..........................................................83 Alethia Vázquez-Morillas, Jéssica Paola Hermoso-López Araiza, Juan Carlos Álvarez-Zeferino, Margarita Beltrán-Villavicencio, Rosa María Espinosa-Valdemar, Xochitl Quecholac-Piña, Perla Xochitl Sotelo-Navarro and Maribel Velasco-Pérez Chapter 7 Smart Coatings Including Antibacterial Coatings, Anti-Fogging Coatings and Self-Healing Materials .............93 Jahan B. Ghasemi, Behrouz Arab and Shahram Seidi Chapter 8 Application of Technical Lignin in Wood Adhesive ...........................................................................................127 Sheng Yang, Tong-Qi Yuan and Run-Cang Sun Chapter 9 Food Packaging Applications of Renewable Polymers Incorporating Nanocomposites ....................................149 Adriano Brandelli and Stela Maris Meister Meira Chapter 10 Poly(Hydroxyalkanoates) Composites and Their Applications ..........................................................................163 Iza K. Radecka, Guozhan Jiang, David J. Hill and Marek M. Kowalczuk Chapter 11 Biodegradation Properties of Bioplastic-Based Planting Pots ............................................................................177 Kang Chiang Liew, Rahmatiah Al Faruqy, Chui Yee Chang and Wei Ling Moung v vi Contents Chapter 12 Biomedical Implants for Bone Tissue Replacement and Regeneration ..............................................................189 Piotr Szczepańczyk, Krzysztof Pazdan, Kinga Pielichowska and Jan Chłopek Chapter 13 Starch Modifications and Their Influence on the Development and Characteristics of Biodegradable Films: A Comparative Review .............................................................................................................................211 Charanjit Singh Riar and Sakshi Sukhija Chapter 14 Green Recycled Cellulose Aerogels: Properties and Applications .....................................................................237 Hai Minh Duong and Son Truong Nguyen Chapter 15 Chitosan-Based Composite Materials for Anti-microbial Food Packaging ........................................................251 Shakeel Ahmed and Saiqa Ikram Chapter 16 Recent Achievements in the Synthesis of Biosafe Poly(Vinyl Alcohol) Nanocomposite ...................................261 Shadpour Mallakpour and Elham Khadem Chapter 17 High-Performance Polylactide and Its Composites .............................................................................................279 Purba Purnama and Soo Hyun Kim Chapter 18 Green Polymer Nanocomposites: Preparation, Properties and Biomedical Applications ..................................289 Aniruddha Chatterjee and Dharmesh P. Hansora Chapter 19 Synthetic Derivatization of Inulin and Its Applications .......................................................................................315 Rahul and Gautam Sen Chapter 20 Mixing Index of a Starch Composite Extruder for Food Packaging Application ................................................331 Adeshina Fadeyibi, Zinash Delebo Osunde, Gbabo Agidi and Egwim Chidi Evans Chapter 21 Advances in Polymers and Tissue Engineering Scaffolds ..................................................................................343 Nandini A. Pattanashetti, Chinmay Hiremath, Nuno Alves and Mahadevappa Y. Kariduraganavar Chapter 22 Recent Advances in Green Polymers and Their Pharmaceutical Applications ..................................................355 Nitin Kumar Saun, Anuja Vohra and Reena Gupta Chapter 23 Drug Delivery by Green Nanoparticles ..............................................................................................................367 Niteesh Kumar Pandey, Kalpana Hiteshi and Reena Gupta Chapter 24 Grafted Nano-ZnO, TiO , and CuO by Biosafe Coupling Agents and Their Applications for the Green 2 Polymer Nanocomposites Fabrication .................................................................................................................381 Shadpour Mallakpour and Vajiheh Behranvand Contents vii Chapter 25 Advances in Polymer Composites: Green and Nanotechnology .........................................................................397 Mitali Saha and Prasanta Sutradhar Chapter 26 An Account of Commercially Important Polysaccharide Derivatives and Their Industrial Applications .........403 Kamalesh Prasad and A.K. Siddhanta Chapter 27 Advances in Polymeric Implants for Biomedical Applications ...........................................................................413 Geetha B. Heggannavar, Nandini A. Pattanashetti, Artur Mateus and Mahadevappa Y. Kariduraganavar Chapter 28 Polycarbonate: Synthesis, Properties and Its Applications .................................................................................423 Jin-Gang Yu Chapter 29 Polylactic Acid (PLA) Synthesis and Catalytic Mechanism ................................................................................431 Joon Ching Juan and Chin Hua Chia Chapter 30 Use of Green Composites for Removal of Metal Ions and Dyes ........................................................................437 Jayshree Ramkumar and S. Chandramouleeswaran Chapter 31 New Advances in Bio-Based Resins ...................................................................................................................445 Itziar Egüés, Xabier Erdocia, Ane Sequeiros and Jalel Labidi Chapter 32 Clean and Effective Lignin Upgrading Pathway as Green Polymer Feedstock: Strategies to Break Through the Restrictions of Lignin Heterogeneity .............................................................................................459 Guanhua Wang and Hongzhang Chen Chapter 33 Properties and Applications of Chitosan and Its Derivatives in the Pharmaceutical and Food Sectors ............471 Patrícia Severino, Marco Vinicius Chaud, Francine Ferreira Padilha, Antonello Santini, and Eliana Barbosa Souto Chapter 34 Refinery of Eucommia ulmoides Oliv.: From Pharmaceutical Value to Green Polymers Application ..............479 Lan-Zhi Qin and Hongzhang Chen Chapter 35 Design Strategies of Green Polymer Nanocomposites Containing Amino Acid Linkages ................................491 Shadpour Mallakpour and Mashal Javadpour Chapter 36 Biopolymers in Drug-Delivery Applications .......................................................................................................513 Chinmay Hiremath, Geetha B. Heggannavar, Geoffrey R. Mitchell and Mahadevappa Y. Kariduraganavar Chapter 37 Poly(ε-caprolactone) (PCL): Application in Biodegradable Films and Bags ......................................................527 Arantzazu Valdés, Ana Beltrán, Ana Cristina Mellinas and María Carmen Garrigós viii Contents Chapter 38 Starch-Based Biocomposites ...............................................................................................................................537 Preetha Balakrishnan, Sabu Thomas, and M.S. Sreekala Chapter 39 New Approach towards the Studies of Starch Modification: Processing and Characterization .........................547 Dorota Kołodyńska, Magdalena Kozioł, Andrzej Łodyga and Zbigniew Hubicki Index .........................................................................................................................................................................................579 Preface In a broad sense, materials are said to be ‘green’ when they of polymers and composites has deeply influenced the devel- are biodegradable and renewable and of course environment opment of modern technological societies leading to a high friendly and fully sustainable in every respect. These are standard of living. considered alternatives to the synthetic polymers. Synthetic Cutting-edge research is being carried out to develop and polymers have posed great challenges to the environment and deploy environment-friendly polymer composites in critical users due to issues such as degradation, incineration, global areas of human endeavour such as basic utilities from c arrier warming, their high cost of production, cross contamination bags to prosthetic implants. Engineered materials using during recycling and consumer toxicity risks. However, green advanced green polymer composites are finding extensive use polymer composites can be easily disposed of at the end of in sectors such as automotive, aerospace, agriculture, house- their service life without causing any harmful effects to the hold goods, hygiene products, building and construction mate- environment or users. Thus, the challenge of green compos- rials, paints and adhesives and biomedical and biomedicine. ites requires the sourcing of ‘green’ polymers that can be This book is intended to compile and broadly explore used as matrices for the production of composites. Nowadays, the latest developments and applications of green polymer green polymer composites are being developed using renew- composites in the areas such as goods packaging and able polymers of natural origin such as starch, lignin, cellu- composting bags, green foams, anti-bacterial, anti-microbial lose acetate, poly-lactic acid (PLA), polyhydroxylalkanoates and anti-fogging coatings for food stuff, adhesives, gums, (PHA) and polyhydroxylbutyrate (PHB). wallpaper paste, resins, self-healing materials, tissue engi- Green polymer composites have in fact percolated every neering scaffolds, pharmaceutical applications, drug delivery, aspect of our daily life. The extensive use of green poly- bone tissue replacement and regeneration. mer composites in the manufacturing of basic utilities from carrier bags to engineered materials has revolutionized the Inamuddin human life style as well as the industrial scenario. The use Aligarh Muslim University ix

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