Green Polymer Chemistry.. Biocatalysis and Biomaterials PDF
Preview Green Polymer Chemistry.. Biocatalysis and Biomaterials
Green Polymer Chemistry: 1 0 ubs.acs.org 0-1043.fw0 Biocatalysis and Biomaterials p1 http://bk-20 1 | 21/ 10 01 er 22, 2doi: 10. mb0 | e1 v0 o2 n N11, 8.58 ougust 6.A 3.22eb): 9W 1 ed by Date ( nloadation wc Doubli P In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. 1 ubs.acs.org 0-1043.fw00 p1 http://bk-20 1 | 21/ 10 01 er 22, 2doi: 10. mb0 | e1 v0 o2 n N11, 8.58 ougust 6.A 3.22eb): 9W 1 ed by Date ( nloadation wc Doubli P In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. 1043 ACS SYMPOSIUM SERIES Green Polymer Chemistry: Biocatalysis and Biomaterials H. N. Cheng, Editor 1 Southern Regional Research Center ubs.acs.org 0-1043.fw00 USRDiAch-aAgrrdicuAlt.urGalrRoessse,acEhdSietrovrice p1 http://bk-20 PolytechnicInstituteofNewYorkUniversity(NYU-POLY) 1 | 21/ 10 01 er 22, 2doi: 10. mb0 | e1 v0 o2 n N11, 8.58 ougust 6.A 3.22eb): 9W 1 ed by Date ( nloadation wc Doubli P Sponsored by the ACS Division of Polymer Chemistry AmericanChemicalSociety,Washington,DC In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. LibraryofCongressCataloging-in-PublicationData pubs.acs.org 10-1043.fw001 eGdIIrSnietcBeoplnruN.sdp.c9eoms7ly.8bm--i-0be-l(r8iAo4cgC1hr2eaSm-p2shi5ysi8cmtra1ypl-o7r:esb(fiaiueolrmkce.anstpceaaerlpysieesasirns);da1ni0nd4d3be)ixo.materials/H.N.Cheng,RichardA.Gross, http://bk-20 a1p.plBiciaotdioegnrsa--dCabolnegprelasssteisc.s3--.CBoinogproelsysmese.r2s.--ECnovnigrroensmseesn.taI.lCchheemngis,tHry.-N-I.nIdIu.Gstrrioasls,Richard 1 | 21/ A.,1957- 10 01 TP1180.B55G742010 er 22, 2doi: 10. 547’.7--dc22 2010023453 mb0 | e1 v0 o2 n N11, 8.58 ougust TSthaendpaarpderfourseIdnfionrtmhiastipounbSlicciaetniocnesm—eePtesrmthaenmeninciemoufmPraepqeurirfeomr PenritnstoefdALmiberraircyanMNaatetiroianlasl, 3.226.eb): A ANSIZ39.48n1984. 9W 1 Copyright©2010AmericanChemicalSociety ed by Date ( DistributedbyOxfordUniversityPress nloadation AllRightsReserved. ReprographiccopyingbeyondthatpermittedbySections107or108 wc Doubli oftheU.S.CopyrightActisallowedforinternaluseonly,providedthataper-chapterfeeof P $40.25plus$0.75perpageispaidtotheCopyrightClearanceCenter,Inc.,222Rosewood Drive,Danvers,MA01923,USA.Republicationorreproductionforsaleofpagesinthis bookispermittedonlyunderlicensefromACS.Directtheseandotherpermissionrequests toACSCopyrightOffice,PublicationsDivision,115516thStreet,N.W.,Washington,DC 20036. Thecitationoftradenamesand/ornamesofmanufacturersinthispublicationisnottobe construedasanendorsementorasapprovalbyACSofthecommercialproductsorservices referenced herein; nor should the mere reference herein to any drawing, specification, chemicalprocess, orotherdataberegardedasalicenseorasaconveyanceofanyright or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce,use,orsellanypatentedinventionorcopyrightedworkthatmayinanywaybe relatedthereto. Registerednames,trademarks,etc.,usedinthispublication,evenwithout specificindicationthereof,arenottobeconsideredunprotectedbylaw. PRINTEDINTHEUNITEDSTATESOFAMERICA In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. Foreword The ACS Symposium Series was first published in 1974 to provide a mechanism for publishing symposia quickly in book form. The purpose of the series is to publish timely, comprehensive books developed from the ACS sponsoredsymposiabasedoncurrentscientificresearch. Occasionally,booksare 1 developed from symposia sponsored by other organizations when the topic is of ubs.acs.org 0-1043.fw00 keenBinefteorreesatgtoretehinegchtoempuisbtlriyshaaudbioeonkce,.theproposedtableofcontentsisreviewed p1 forappropriateandcomprehensivecoverageandforinteresttotheaudience. Some http://bk-20 papersmaybeexcludedtobetterfocusthebook;othersmaybeaddedtoprovide 1 | 21/ comprehensiveness. When appropriate, overview or introductory chapters are 0110 added. Draftsofchaptersarepeer-reviewedpriortofinalacceptanceorrejection, er 22, 2doi: 10. andmanuscriptsarepreparedincamera-readyformat. mb0 | As a rule, only original research papers and original review papers are e1 ov20 included in the volumes. Verbatim reproductions of previous published papers n N11, arenotaccepted. 8.58 ougust 6.A 3.22eb): ACSBooksDepartment 9W 1 ed by Date ( nloadation wc Doubli P In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. Preface Green Polymer Chemistry is a crucial area of research and product development that continues to grow in its influence over industrial practices. Developments in these areas are driven by environmental concerns, interest in sustainability, desire to decrease our dependence on petroleum, and commercial 1 opportunitiestodevelop“green”products. Publicationsandpatentsinthesefields g 00 orpr are increasing as more academic, industrial, and government scientists become ubs.acs.0-1043. involTvheedpinurrpeosseearocfhtahnisdbcooomkmisertcoiapluabcltiisvhitnieesw. workfromacutting-edgegroup p1 1 | http://21/bk-20 oicnofsrtlrieetausdptiioonnngdsi.innBgteerpcnuaaubtsliioecnaoatfilothrneessmetaeurncldthidetoirsscbfieprolsimpnraeraaycdandaoetuumtrieoavo,efgrGonvrueeemrnnemProeounlyst,mjaoenurdrCniahnlesdm.usiTstrthriayisl, 10 mber 22, 200 | doi: 10.1 obfoothkTebhbririsneagbdsottohhkeasniesdpdbaeappseetrhdsotoofngaecctthoivenirttrisiebosutithniaotGntsrheebeynrePaodoraelylrmcaanenrdCgpahoiensmtaeirsbteprtyrte.esreanptperrsecaiattitohne ve01 international symposium, Biocatalysis in Polymer Science, held at the ACS o2 n N11, National Meeting in Washington D.C. on August 17-20, 2009. Whereas many 8.58 ougust apsaprteicctuslaorfeGmrpeheansiPsowlyamseprlaCcehdemoinstbryiocwaetarelysciosvaenreddbdioubriansgedthmeasteyrmiaplso.siuMma,nya 3.226.eb): A eaxdcdiittiinogn,nseevwerfialnldeiandgesrsininbthaessicearreesaesarwchhoawndereapupnlaibcaletiotonsattwenedrethreepsoyrmtepdo.siuImn 9W d by 1Date ( cporonvtriidbeusteadgoimodporretparnetsernevtaiteiwons ooffatchteiviritioensgaotinthgewfoorrekf.ronAtsofarerseesaurlcththinisGbroeoenk den Downloaublicatio cPhoelymTmihceairslCbehoneogmkiniewsetirrlysl,ebmbeipouhcshaesefuimzliintcogalsacecinteigvniitntiiseetessrisan,nbdmioaectneagrtiianalleyessricssiea(ncnthdiesbtmsio,isbmtasis,cebrdoiobcchiohelemomgisiisstrttyss,,. P molecular biologists, and enzymologists) as well as graduate students who are engagedinresearchanddevelopmentsinpolymerbiocatalysisandbiomaterials. Itcanalsobeausefulreferencebookforthoseinterestedinthesetopics. Wethanktheauthorsfortheirtimelycontributionsandtheircooperationwhile themanuscriptswerebeingreviewedandrevised. Inadditionwealsothankthe ACS Division of Polymer Chemistry, Inc. for sponsoring the 2009 symposium andprovidinggenerousfundingforthesymposium. xi In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. H. N. Cheng SouthernRegionalResearchCenter USDA–AgriculturalResearchService 1100RobertE.LeeBlvd. NewOrleans, LA70124 RichardA.Gross 1 g 00 HermanF.MarkProfessor orpr s.3. Director: NSFI/UCRCforBiocatalysisandBioprocessingofMacromolecules s.ac104 PolytechnicInstituteofNYU(NYU-POLY) pub10- SixMetrotechCenter 1 | http://21/bk-20 Brooklyn, NY11201 10 01 er 22, 2doi: 10. mb0 | ve01 o2 n N11, 8.58 ougust 3.226.eb): A 9W d by 1Date ( den nloaatio Dowublic P xii In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. Chapter 1 Green Polymer Chemistry: Biocatalysis and Biomaterials‡ H. N. Cheng1,* and Richard A. Gross2 1 g 00 pubs.acs.or10-1043.ch 1So2uNtShFerIn/URC1e1Rg0iCo0nRfaolorRbBeerisotecaEar.tcaLhlyeCesiesBnaltvendrd,.,UBNSieoDwpArOo/Acreglsersaiicnnusg,ltoLufArMe7Ra0ce1rs2oe4amrochlecSuelrevsi,ce, http://bk-20 PolytechnicInstituteofNYU(NYU-POLY),SixMetrotechCenter,Brooklyn, 1 | 21/ NY11201,http://www.poly.edu/grossbiocat/ 0110 *[email protected] er 22, 2doi: 10. h‡oNwaemveers,othfeprUoSdDuActsnaeritehnerecgeusasarrayntteoesrenpoorrtwfaarcrtaunatlslythoensatvaanidlaabrldesdoafttah;e mb0 | products,andtheuseofthenameUSDAimpliesnoapprovaloftheproducts e1 v0 o2 totheexclusionofothersthatmayalsobesuitable. n N11, 8.58 ougust 6.A 3.22eb): Thisoverviewbrieflysurveysthepracticeofgreenchemistryin 9W 1 polymerscience. Eightrelatedthemescanbediscernedfromthe nloaded by ation Date ( 4cbu)lorrcreekncstyrcaelnsindegaracoghfraiccputoilvltyuitmriaeelsr:p1pr)orbodiduouccctastt,saly3ans)idsd,e2cga)rtbaaildoya-sbbtslae,se5dp)oblueyinmldeeringrsgy, wc Doubli generation or minimization during use, 6) optimal molecular P design and activity, 7) benign solvents, and 8) improved synthesis to achieve atom economy, reaction efficiency, and reducedtoxicity. Alloftheseareasareexperiencinganincrease in research activity with the development of new tools and technologies. Examples are given of recent developments in green chemistry with a focus on biocatalysis and biobased materials. ©2010AmericanChemicalSociety In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010. Introduction Greenchemistryisthedesignofchemicalproductsandprocessesthatreduce oreliminatetheuseorgenerationofhazardoussubstances(1). Sustainabilityrefers tothedevelopmentthatmeetstheneedsofthepresentwithoutcompromisingthe abilityoffuturegenerationstomeettheirownneeds(2). Inthepastfewyearsthese concepts have caught on and have become popular topics for research. Several booksandreviewarticleshaveappearedinthepastfewyears(3–6). Inthepolymerarea,thereisalsoincreasinginterestingreenchemistry. Thisis evidentbymanyrecentsymposiaorganizedonthistopicatnationalACSmeetings. Inourview,developmentsingreenpolymerchemistrycanberoughlygroupedinto thefollowingeightrelatedthemes. Theseeightthemesalsoagreewellwithmost ofthethemesdescribedinrecentarticlesandbooksongreenchemistry(3–6). 1 g 00 pubs.acs.or10-1043.ch 12)) GDburivieleednrisneegrcfbealetoadclskytsso)tcsk(eb.gas.,eb(ioescpaetacliyaslltyssaugcrhicauslteunrzaylmpreosdauncdtswahnodlebcioelblas)sed http://bk-20 3) Degradablepolymersandwasteminimization 1 | 21/ 4) Recyclingofpolymerproductsandcatalysts(e.g.,biologicalrecycling) 0110 5) Energygenerationorminimizationofuse er 22, 2doi: 10. 67)) OBepntiimgnalsomlvoelenctusl(aer.gd.e,swigantear,nidonaicctilviiqtuyids,orreactionswithoutsolvents) mb0 | 8) Improved syntheses and processes (e.g., atom economy, reaction e1 v0 o2 efficiency,toxicityreduction) n N11, 8.58 ougust In this article, we provide an overview of green polymer chemistry, with 6.A a particular emphasis on biocatalysis (7, 8) and biobased materials (9, 10). 3.22eb): Examplesaretakenfromtherecentliterature,especiallyarticlesinthissymposium 9W 1 volume (11–39) and the preprints (40–62) from the international symposium on nloaded by ation Date ( “DBCioicnaAtaulygsuisstin20P0o9l.ymer Science” at the ACS national meeting in Washington, wc Doubli P Green Polymer Chemistry - The Eightfold Path Biocatalysts Biocatalysis is an up-and-coming field that has attracted the attention and participation of many researchers. Several reviews (7) and books (8) are availableonbiocatalysis. Thiscurrentsymposiumvolumedocumentsimportant new research that uses biocatalysis and biobased materials as tools to describe practical and developing strategies to implement green chemistry practices. A total of 22 articles (and 17 symposium preprints) describe biocatalysis and biotransformations. Among these papers, 31 articles focus on cell-free enzyme catalystsand8utilizewhole-cellcatalyststoaccomplishbiotransformations. 2 In Green Polymer Chemistry: Biocatalysis and Biomaterials; Cheng, H., et al.; ACS Symposium Series; American Chemical Society: Washington, DC, 2010.
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