GREEN CHEMISTRY FOR SUSTAINABLE BIOFUEL PRODUCTION GREEN CHEMISTRY FOR SUSTAINABLE BIOFUEL PRODUCTION Edited by Veera Gnaneswar Gude, PhD Apple Academic Press Inc. Apple Academic Press Inc. 3333 Mistwell Crescent 9 Spinnaker Way Oakville, ON L6L 0A2 Canada Waretown, NJ 08758 USA © 2018 by Apple Academic Press, Inc. Exclusive worldwide distribution by CRC Press, a member of Taylor & Francis Group No claim to original U.S. Government works International Standard Book Number-13: 978-1-77188-639-0 (Hardcover) International Standard Book Number-13: 978-1-315-09935-4 (eBook) All rights reserved. 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Gude, Veera Gnaneswar, 1978-, editor TP339.G74 2018 660.028'6 C2018-900011-2 C2018-900012-0 Library of Congress Cataloging-in-Publication Data Names: Gude, Veera Gnaneswar, 1978- editor. Title: Green chemistry for sustainable biofuel production / editor, Veera Gnaneswar Gude, PhD. Description: Toronto ; New Jersey : Apple Academic Press, 2018. | Includes bibliographical references and index. Identifiers: LCCN 2017061143 (print) | LCCN 2018000089 (ebook) | ISBN 9781315099354 (ebook) | ISBN 9781771886390 (hardcover : alk. paper) Subjects: LCSH: Biomass energy. | Green chemistry. Classification: LCC TP339 (ebook) | LCC TP339 .G74 2018 (print) | DDC 660.028/6--dc23 LC record available at https://lccn.loc.gov/2017061143 Apple Academic Press also publishes its books in a variety of electronic formats. Some content that appears in print may not be available in electronic format. For information about Apple Academic Press products, visit our website at www.appleacademicpress.com and the CRC Press website at www.crcpress.com DEDICATION To my late father Gude Bhaskar Rao, my mother Gude Fathima, my sister Gude Veera Nirmala Kalyani, my brothers Gude Veera Kiran and Gude Veera Chitti Karunakar, and to Preeti Muire CONTENTS Dedication ........................................................................................................v About the Editor ..............................................................................................ix List of Contributors .........................................................................................xi List of Abbreviations ......................................................................................xv Preface ..........................................................................................................xix Acknowledgments ..........................................................................................xxi PART 1: BIOFUELS FROM RENEWABLE AND ALTERNATIVE FEEDSTOCK AND GREEN PROCESSES .........................................................1 1. Green Chemistry and Engineering for Sustainable Biofuel Production .....................................................................3 Veera Gnaneswar Gude 2. Biofuel Feedstock: Challenges and Opportunities ....................................15 Cannayen Igathinathane and Matt Sanderson 3. Fuels from Recycled Carbon .......................................................................57 Michele Aresta and Angela Dibenedetto 4. Green Catalysts and Catalytic Processes for Biofuel Production ..........131 Atal Shivhare, Karen Wilson, and Adam F. Lee PART 2: BIOFUEL CHEMISTRY AND PROCESS INTENSIFICATION ..........................................................................................163 5. Process Intensification and Parametric Optimization in Biodiesel Synthesis Using Microwave Reactors .......................................................165 Pranjali D. Muley and Dorin Boldor 6. Process Intensification and Parametric Optimization in Biodiesel Synthesis Using Hydrodynamic Cavitation Reactors .............................203 Parag R. Gogate and Ashish V. Mohod 7. Hydrothermal Processes for Biofuel and Bioenergy Production ................................................................................243 M. Toufiq Reza viii Contents 8. Sustainable Biofuels and Chemicals Production Using Ionic Liquids ....................................................................................287 P. N. Amaniampong, R. Behling, N. Araji, S. Valange, K. De Oliveira Vigier, and G. Chatel PART 3: BIOFUELS FROM MICROALGAE AND OTHER WASTE SOURCES AND BIOREFINERY CONCEPTS ..............................................333 9. Algae as a Sustainable Feedstock for Biofuel Production ......................335 Martin Gross, Ashik Sathish, and Zhiyou Wen 10. Bioenergy from Activated Sludge and Wastewater .................................357 Andro Mondala, Rafael Hernandez, Todd French, Emmanuel Revellame, Dhan Lord Fortela, and Marta Amirsadeghi 11. Bioelectrochemical Systems for Biofuel (Electricity, Hydrogen, and Methane) and Valuable Chemical Production .................................435 Mobolaji Shemfe, Kok Siew Ng, and Jhuma Sadhukhan PART 4: ENERGY BALANCE, TECHNO-ECONOMICS, AND LIFE-CYCLE INVENTORIES .........................................................................473 12. Energy Balance/Efficiency and Economic Analysis of Biofuel Production .................................................................................475 María González Alriols, Xabier Erdocia, María Angeles Andres, and Jalel Labidi 13. Techno-Economic Analysis of Microalgae and Algal Biofuel Production (As a Tool for Driving R&D Efforts) ....................................521 Florian Delrue 14. Mismatch of Life-Cycle Inventories for Bioenergy, Fossil Fuel, and Agricultural Resource Production ....................................................543 Sarah C. Davis, Kaitlin C. Straker, Abbey Rodjom, Esther Grossman, Alexander Jones, and Kim E. Miller Index .............................................................................................................573 ABOUT THE EDITOR Veera Gnaneswar Gude, PhD Associate Professor of Civil and Environmental Engineering, Mississippi State University, Mississippi, USA Veera Gnaneswar Gude, PhD, is a faculty member of Civil and Environmental Engineering Department at Mississippi State University. He has published over 125 scientific research articles focusing on biofuels, desalination, and water/wastewater treatment topics. He is the author of the book Microwave-Mediated Biofuel Production published by CRC Press in 2017. He holds two patents on novel processes in biofuels and desalination technical areas respectively. He is an editor or editorial board member of several reputed scientific journals in the areas of biofuels, environmental engineering and science, desalination and water research. He also serves on numerous scientific advisory boards and committees across the world.