Green Chemical Syntheses and Processes

355 Pages·2000·29.24 MB·English

by  Paul T. Anastas

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In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Dedication
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was named after Dr. Joseph J. Breen. Joe Breen was an
inspiration to people around the world because of the
passion and enthusiasm with which he articulated the
need and the goals of green chemistry and engineering
for sustainability. Joe's premature death in the summer of
1999 is a tragedy to all who knew him and a loss to the
causes he championed. This book is dedicated to the
memory of Dr. Joseph J. Breen.
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
ACS SYMPOSIUM SERIES 767
Green Chemical Syntheses
and Processes
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6 on 5, 20 Tracy C. Williamson, EDITOR
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American Chemical Society, Washington, DC
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Library of Congress Cataloging-in-Publication Data
Green chemical syntheses and processes / Paul T. Anastas, Lauren G. Heine, Tracy C. Williamson
[editors].
p. cm.—(ACS symposium series ; 767)
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s.or001 Includes bibliographical references and index.
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er 17, 2010.1021/ V.I .S Aernieass.t as, Paul T..., 1962- II. Heine, Lauren G., 1957- III. Williamson, Tracy C., 1963- IV. Title.
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6 on 5, 20 The paper used in this publication meets the minimum requirements of American National Standard
31
4.1ust for Information Sciences—Permanence of Paper for Printed Library Materials, ANSI Z.39.48-1984.
3g
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Do 01923, USA. Republication or reproduction for sale of pages in this book is permitted only under
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PRINTED IN THE UNITED STATES OF AMERICA
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Foreword
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Sept00 | terest to the audience. Some papers may be excluded in order to better
6 on 5, 20 focus the book; others may be added to provide comprehensiveness.
34.13gust 1 WDrhaeftns oafp pchroapprteiartse ,a roev epreveire-wre voierw eindt rpordiourc ttoor yf incahla patcecresp taarnec ea dodr erde.
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d bon pers are included in the volumes. Verbatim reproductions of previ
deati ously published papers are not accepted.
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Do ACS BOOKS DEPARTMENT
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Foreword
g
s.or001 THE ACS SYMPOSIUM SERIES was first published in 1974 to provide
2 | http://pubs.ack-2000-0767.fw apose poamesredec ch ohf.rf ao Ontmhicse cmA ass eCfioorSirne aspspl ulioybsn, l sibtsooohr oiepnkdugs b ssalyyirsmmeh pp dtooiemssviieaael l oyqbp,ua esicdceokd mfl ryopo nirmne h cbsueyonrmorskeipvn eofto s rsibmacoi eo.s npkTtosihn fidesco ep rvrueeerdl
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ember 17, 20doi: 10.1021/ biissyt r royet Bvhaieueefrdwo iroeeernd gc aaefgon.r riez eaaitpniopgnr, ostop w rpihauetbenl iastnhhde a tc boopomoicpk r,i set hhoeefn pksirevoeepn o cisonevtdeer rteaasgbtel et o ao ntfhd ce of ncohtree inmnt s
Sept00 | terest to the audience. Some papers may be excluded in order to better
6 on 5, 20 focus the book; others may be added to provide comprehensiveness.
34.13gust 1 WDrhaeftns oafp pchroapprteiartse ,a roev epreveire-wre voierw eindt rpordiourc ttoor yf incahla patcecresp taarnec ea dodr erde.
89.163.ate: Au jectioAns, aan rdu mle,a nounslycr ioprtisg ianrael p rreespeaarrecdh ipna cpaemrse raan-rde aodriyg ifnoarml raetv. iew pa
y D
d bon pers are included in the volumes. Verbatim reproductions of previ
deati ously published papers are not accepted.
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Do ACS BOOKS DEPARTMENT
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Errata Sheet
ACS Symposium Series 767
Green Chemical Syntheses and Processes
Paul T. Anastas, Lauren G. Heine, and Tracy C. Williamson
On page ii, the Dedication should read as follows: This book is dedicated to the
memory of Dr. Joseph J. Breen. Joe Breen was a founding co-chair of the Green
Chemistry and Engineering Conference from which this book is derived. He was
an inspiration to people around the world because of the passion and enthusiasm
g with which he articulated the needs and goals of green chemistry and engineering
s.or001 for sustainability. Joe's premature death in the summer of 1999 is a tragedy to all
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31 erature citations should read:
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d bon 1. Raber, Linda R. (1998). "Green Chemistry Here to Stay." Chemical & Engi
deati neering News, July 6, pp. 25-26.
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wnloPubli 2. Miller, J. P. (1993). "Firms Give Chemistry Green Light." The Wall Street
Do Journal, December 7, B6.
3. Anastas, P. T. and Williamson, T. C. (1998). Green Chemistry: Theory and
Practice, Oxford University Press, Oxford.
4. U.S. Environmental Protection Agency. (1998). The Presidential Green
Chemistry Challenge Awards Program: Summary of 1998 Award Entries and
Recipients. EPA744-R-98-001.
5. Anastas, P. T. and Williamson, T. C. (1996). "Green Chemistry: An Over
view." In Green Chemistry: Designing Chemistry for the Environment,
American Chemical Society Symposium Series, No. 626, (ed. P. T. Anastas
and T. C. Williamson), pp. 1-17. American Chemical Society.
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Preface
Scientific innovation is at the heart of Green Chemistry. The same flame of
innovation that powered industry and economic growth since science's beginnings
is now also powering the protection of human health and the environment. This
g book contains chapters by individuals from different disciplines, different sectors
012 | http://pubs.acs.or1/bk-2000-0767.pr001 Twtit(nhhinhoceodrrl suokmuedues oitgdnnroh oygtn bo, t. clhg aeJoeic usntag hsqpdoteua eaarmesl srsta ii,iacsn ti e, gtt hne a atmtanuosmdar oby n sge,wy o tem ovintlweela rrtnaphnrryriamdb otgl veetosnih cdadteil)eei s, sn u tehacnhaaneiesfv d eiaeees n ddn,b di gcfge foiteeonemrnaceelhb n sntaoethtoft ai lcnsootoug guuts ytanth aktauwirensnias eagcs sbehu .r itaslhI,i ltneldaye no mnetwdngha genreniso vny tuet heocgn ea th h osg rues oocsamiia,nce atdhgnhni ceettievotoyy.e
22
7, 10 ward sustainability.
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Septe00 | d PAUL T. ANASTAS1
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TRACY C. WILLIAMSON
U.S. Environmental Protection Agency
Waterside Mall, Mail Code 7406
401 M. Street, SW
Washington, DC 20460
1Visiting Professor at Department of Chemistry, The University of Nottingham, University Park,
Nottingham NG7 2RD, United Kingdom.
xi
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.
Chapter 1
Green Chemical Syntheses
and Processes: Introduction
Paul T. Anastas1,4, Lauren G. Heine2, and Tracy C. Williamson3
1White House Office of Science, Technology and Policy,
1600 Pennsylvania Avenue, Washington, DC 20500
2 | http://pubs.acs.org k-2000-0767.ch001 2Ze3Irnod WustarsitaeWl ACalth3lei6eram2sni4dic ceeSa ,. lMWIsn aB.t ler1lWr,a0 nnMtaahcsta hhiAio,li nnvUCgae.tlonS odSu.n euEe, ,s7n DtP4avC0oiinr 6ra2ot, b0ln4a4lm0en61 de0 Dn,M eOtav RSle Plt or9rep7oem2tte0,e c1Snt iWto nF, oAugnednactyio, n,
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31
4.1ust examples of excellent green chemistry techniques being commercialized. This can be
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89.1ate: Presidential Green Chemistry Challenge Awards given annually at the National
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minimized hazard must be viewed as a performance criterion. Moreover, hazard must
also be viewed as a physical/chemical property that is possible to manipulate and
control at the molecular level.
By using the same skills, techniques, and expertise that is central to traditional
chemistry, the practices of green chemistry are realizing some notable and in some
cases, dramatic, results in the protection of human health and the environment.
This book presents a number of the innovations that have been developed recently
in the emerging area of green chemistry. The chapters of the book are derived from
presentations made at the Green Chemistry and Engineering Conference at the
National Academy of Sciences, Washington, D.C. This conference was established to
4Visiting Professor at Department of Chemistry, The University of Knottingham, University Park,
Nottingham NG7 2RD, United Kingdom.
© 2000 American Chemical Society 1
In Green Chemical Syntheses and Processes; Anastas, P., et al.;
ACS Symposium Series; American Chemical Society: Washington, DC, 2000.