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Geometric methods for the most general Ginzburg-Landau model with two order parameters I. P. Ivanov∗ Interactions Fondamentales en Physique et en Astrophysique, Universit´e de Li`ege, All´ee du 6 Aouˆt 17, bˆatiment B5a, B-4000 Li`ege, Belgium and Sobolev Institute of Mathematics, Koptyug avenue 4, 630090, Novosibirsk, Russia The Landaupotential in thegeneral Ginzburg-Landau theorywith two orderparameters andall 8 possible quadratic and quartic terms cannot be minimized with the straightforward algebra. Here, 0 a geometric approach is presented that circumventsthiscomputational difficulty and allows one to 0 get insight intomany properties of the model in the mean-field approximation. 2 n a Introduction. The Ginzburg-Landau (GL) theory of- ing fact is that this question cannot be answered by a J fers a remarkably economic description of phase tran- straightforward calculation. Differentiating the Landau 6 sitions associated with breaking of some symmetry [1]. potential in respect to ψ leads to a system of coupled i 2 This breaking is described with an order parameter ψ: algebraic equations that cannot be solved explicitly. the high symmetry phase corresponds to ψ = 0, while InthisLetterweshowthatdespitethiscomputational ] n the low symmetry phase is described by ψ 6=0. In order difficulty,onecanstilllearnmuchaboutthemostgeneral o to find when a given system is in high or low symmetry 2OP GL model. Namely, one can study the number and c phase, one constructs a Landau potential that depends the properties of the minima of the Landau potential, - r on the order parameter, and then find its minimum. Its classify possible symmetries and study when and how p classic form is they are broken. In short, one can describe the phase u s b diagram of the model, at least in the mean-field approx- t. V(ψ)=−a|ψ|2+ 2|ψ|4+o(|ψ|4). (1) imation, without explicitly minimizing the potential. a There exists, in fact, an extensive literature dating m Higherordertermso(|ψ|4)areusuallyassumedtobeneg- back to 1970’s on minimization of group-invariant po- - ligible. The values of the coefficients a and b and their tentials with severalOPswith the aid ofstratificationof d dependence on temperature, pressure, etc. can be either n the orbit space, see e.g. [1, 13]. Here we show that in calculated from a microscopic theory, if it is available, o thecaseoftwoorderparametersrealizingthesamegroup or considered as free parameters in a phenomenological c representationtheanalysiscanbeextendedmuchfarther [ approach. Thephasetransitionassociatedwiththesym- than in the general case, with important physical conse- metry breaking takes place when an initially negative a 1 quences. For a particular application of this formalism v becomes positive, and the minimum of the potential (1) to the 2HDM, see [14, 15]. 4 shifts from zero to |ψ|= a/b. Theformalism. Letusfocusonthesimplestcasewhen 8 Many systems are knowpn, in which two competing or- twoOPsψ andψ arejustcomplexnumbers. Themost 0 der parameters (OP) coexist. Among them are general 1 2 4 general quadratic plus quartic Landau potential is O(m)⊕O(n)-symmetricmodels,[2],modelswithtwoin- . 1 teracting N-vector OPs with O(N) symmetry, [3]; spin- V = −a |ψ |2−a |ψ |2−a (ψ∗ψ )−a∗(ψ∗ψ ) 0 1 1 2 2 3 1 2 3 2 1 density-wavesincuprates,[4]; SO(5) theoryofantiferro- b b 08 magnetism and superconductivity, [5]; multicomponent, + 21|ψ1|4+ 22|ψ2|4+b3|ψ1|2|ψ2|2 (2) : [6],spin-tripletp-wave,[7],andtwo-gap,[8,9],supercon- b iv ductivity, with its application to magnetism in neutron + (cid:20) 24(ψ1∗ψ2)+b5|ψ1|2+b6|ψ2|2(cid:21)(ψ1∗ψ2)+c.c. X stars, [10]; two-band superfluidity, [11]; various mech- r anisms of spontaneous breaking of the electroweak sym- It contains 13free parameters: reala1, a2, b1, b2, b3 and a metrybeyondtheStandardModelsuchasthetwo-Higgs- complex a , b , b , b . For the illustration of the main 3 4 5 6 doublet model (2HDM), [12]. idea, we place no restriction on |ψ | from above. Note i To describe such a situation within the GL model, thatpotential(2)containsquartictermsthatmixψ and 1 one constructs a Landau potential similar to (1), which ψ . Such terms are usually absent in particular applica- 2 depends on two order parameters, ψ and ψ . Coeffi- tionsofthe2OPGLmodel(forarareexception,see[9]), 1 2 cients of this potential, a and b , can be considered in- but inthe approachpresentedhere it is essentialthatall i i dependent, although in each particular application they possible terms are included from the very beginning. might obey specific relations. One thus arrives at the Once potential (2) is written, the physical nature of mostgeneraltwo-order-parameter(2OP)GLmodelwith OPs becomes irrelevant. One can consider them as com- quadratic and quartic terms. ponents of a single complex 2-vector Φ = (ψ ,ψ )T. 1 2 A natural question arises: what is the ground state The key observation is that the most general poten- of the most general 2OP GL model? A rather surpris- tial (2) keeps its generic form under any regular linear 2 transformation between ψ and ψ : Φ → Φ′ = T ·Φ, Finding eigenvalues Bµν explicitly in terms of a , b 1 2 i i T ∈ GL(2,C). It can be also accompanied with a suit- requires solution of a fourth-order characteristic equa- able transformation of the coefficients a , b , so that one tion,whichconstitutesone ofthe computationaldifficul- i i arrives at exactly the same potential as before. Thus, ties of the straightforward algebra. We reiterate that in the problem has some reparametrization freedom with ouranalysiswenever usethese explicit expressions. The the reparametrization group GL(2,C). Among 13 free analysis relies only on the fact that the eigenvalues are parameters,only 6 play crucialrole inshaping the phase real and satisfy (6). diagram of the model, while the other 7 just reflect the Minima of the Landau potential. Let us first find how way we look at it. many extrema the potential (4) can have in the orbit Let us now introduce a four-vector rµ = (r , r ) = space. Since extrema lie on the surface of LC+, we use 0 i (Φ†σµΦ) with components theLagrangemultipliermethodtoarriveatthefollowing simultaneous equations: r = (Φ†Φ)=|ψ |2+|ψ |2, 0 1 2 2Re (ψ1∗ψ2) Bµνhrνi−λhrµi=Aµ, hrµihrµi=0. (7) ri = (Φ†σiΦ)=|2ψIm|2(−ψ1∗|ψψ2|)2  . (3) Here, hrµi labels the position of an extremum. This sys- 1 2   tem cannotbe solvedexplicitly in the mostgeneralcase, Here, index µ = 0,1,2,3 refers to components in the howeveronecanestablishhow manyextremaagivenpo- internal space and has no relation with the space-time. tential has. Multiplying ψi by a common phase factor does not To find it, we rewrite hrii=hr0ini, where ni is a unit changerµ,soeachrµparametrizesaU(1)-orbitintheψi- 3D vector; then (7) becomes space. Since the Landaupotentialis alsoU(1)-invariant, it can be defined in this 1+3-dimensional orbit space. [A0−(B0−Bi)hr0i]ni =Ai. (8) The SL(2,C)⊂GL(2,C) group of transformations of Assume for simplicity that A > 0 and B < B < ΦinducestheproperLorentzgroupSO(1,3)oftransfor- 0 1 2 mations of rµ. This group includes 3D rotations of the B3. The l.h.s. of (8) at fixed hr0i and all unit vec- tors n parametrizes an ellipsoid with semiaxes A − vector r as well as “boosts” that mix r and r , so the i 0 i 0 i (B − B )hr i. As hr i increases from zero to infin- orbit space gets naturally equipped with the Minkowski 0 i 0 0 space structure. Since r >0 and rµr ≡r2− r2 =0, ity, this ellipsoid first shrinks, then grows, collapsing at the orbit space is given0by the “forwaµrdlig0htcoPne”iLC+ r0(i) ≡A0/(B0−Bi) to planar ellipses. One can see that during these transformations for hr i = [0,∞) it sweeps in the Minkowski space. 0 at least once the entire Minkowski space and at least Allthisallowsustorewrite(2)inaverycompactform: twice the interior of the sphere of radius A . In ad- 0 1 V =−A rµ+ B rµrν, (4) dition, there are two cusped regions, such as shown in µ µν 2 Fig. 1, whose interior is swept twice more. So, by check- with ing whether Ai lies inside these regions, one can get the 1 number of solutions of (8) without finding them explic- Aµ = (a1+a2, −2Re a3, 2Im a3, −a1+a2) , itly. 2 b+12 +b −Re b+ Im b+ −b−12 2 3 56 56 2 Bµν = 1−Re b+56 Re b4 −Im b4 Re b−56 .(5) 2 Im b+ −Im b −Re b −Im b−   56 4 4 56   −b−12 Re b− −Im b− b+12 −b   2 56 56 2 3  Here, b± ≡b ±b , b± ≡b ±b . 12 1 2 56 5 6 One usually requires that the quartic term of the po- tentialincreasesin alldirections inthe OP-space. In the orbit space, this was proved in [14] to be equivalent to FIG. 1: The envelope of ellipsoids for r(1) <r <r(2) in the 0 0 0 the statement that Bµν is diagonalizable by an SO(1,3) Ai-space. transformation and after diagonalization it takes form Bµν =diag(B0, −B1, −B2, −B3) with Inthe 1+3-dimensionalspaceofAµ, these 3Dregions serve as bases of corresponding conical regions with dif- B >B ,B ,B . (6) 0 1 2 3 ferent numbers of extrema of the potential. Namely, at Sincerµr =0,thematricesBµν andB˜µν =Bµν−Cgµν least one non-trivial solution of (7) exists, if Aµ lies out- µ are equivalent. This degree of freedom in the definition side the past lightcone LC− (otherwise the global mini- of Bµν shifts all the eigenvalues by a common constant. mumofthepotentialisattheorigin,hψ i=0). IfAµ lies i 3 inside the future lightcone LC+, then there are at least also invariant under the same group of transformations, two non-trivial solutions. If in addition Aµ lies inside we say that the symmetry is preserved; otherwise, we one or both caustic cones, then two additional extrema saythattheexplicitsymmetryisspontaneouslyviolated. per cone exist. In total, the potential can have up to six In most applications, the Landau potential does possess non-trivialextremaintheorbitspace. Thisfactwasalso some explicit symmetry, so whether it is preservedor vi- found independently in [16]. olated can have profound physical consequences. The above construction does not distinguish a mini- An explicit symmetry corresponds to such a map of mumfromasaddlepoint(withcondition(6),thereareno the Minkowski space that leaves invariant, separately, non-trivialmaximaintheorbitspace). Astraightforward B rµrν andA rµ. Inageneralsituation,itmightbefar µν µ method for finding a minimum, which consists in check- from evident that the potential has any explicit symme- ing that the hessian eigenvalues are all non-negative, is try. The following criterion helps recognize the presence again of little use here. Instead, one can still use geome- of a hidden explicit symmetry and tells what symmetry try to study the properties of the minima. it is: As described above, physically realizable points of the Proposition 2. Suppose that the potential is explicitly orbit space lie on LC+. Nevertheless, let us consider ex- invariant under some transformations of rµ. Let G be pression(4) inthe entire Minkowskispace. Let us define the maximal group of such transformations. Then: an equipotential surface MV as a set of all vectors rµ (a) G is non-trivial if and only if there exists an eigen- with the same value of V. These equipotential surfaces vector of B orthogonal to A ; donotintersect,arenestedintoeachother,andhavevery µν µ (b) G is one of the following groups: Z , (Z )2, (Z )3, simple geometry: they are second-order 3-dimensional 2 2 2 O(2), O(2)×Z , O(3). manifolds (3-quadrics). Since LC+ is also a specific 3- 2 quadric, finding points in the orbit space with the same Theproofwillbegivenin[17](seealso[18]forasimilar value of V amounts to finding intersections of these two statementin 2HDM). In the case ofa discrete symmetry 3-quadrics. In particular, to find a local minimum of the the following Propositions can be easily proved: potentialintheorbitspace,onehastofindanequipoten- tialsurfacethattouchesLC+inanisolatedpoint(wesay Proposition 3. The maximal violation of any discrete explicit symmetry consists in removing only one Z fac- that two surfaces “touch” if they have parallel normals 2 tor: (Z )k →(Z )k−1. at the intersection points). The global minimum cor- 2 2 responds to the unique equipotential surface that only Proposition 4. For any explicit discrete symmetry, touches but never intersects LC+. The fact that the minimathatpreserveandspontaneouslyviolate thissym- search for the global minimum is reformulated in terms metry cannot coexist. ofcontactoftwo3-quadricsleadstoseveralPropositions listed below. Both Propositions follow from Proposition 1 and the Let us now find how many among the extrema are factthatthesetofallminimapreservestheexplicitsym- minima. Let us fix Bµν and move Aµ continuously in metry group G. the parameter space. We first note that the signature of If a discrete symmetry is spontaneously violated, then the hessian can change only when the total number of there are two generate minima in the orbit space. One extrema changes. A saddle point cannot simply become canalsoprovethe converse,i.e. the twodegeneratemin- a minimum; it can only split into several extrema, one imacanariseonlyviaspontaneousviolationofadiscrete of them being a minimum, or it can merge with other symmetry of the potential, [15]. Thus, the criterion for extrema to produce a minimum. Therefore, the conical the spontaneous violation of a discrete symmetry is that 3-surfaces described above (LC−, LC+, caustic cones) Aµ lies inside a caustic cone associated with the largest separate regions in the Aµ-space with a definite number eigenvalue. of minima. One can then check a representative point For a concrete example, suppose that all eigenvalues Aµ = (A0, 0, 0, 0) (in the basis where Bµν is diagonal) of Bµν are distinct and that A3 =0, while other compo- of the innermost region in the Aµ space and find that nents Ai 6= 0. This potential has an explicit Z2 symme- there are two distinct minima in this case. This proves try generatedby reflections of the third coordinate. The the following Proposition: global minimum spontaneously violates this symmetry (i.e. hr i=6 0), if B >B , B and 3 3 1 2 Proposition1. The most general quadratic plus quartic potentialwith twoorderparameters can have at mosttwo A2 A2 A2 1 + 2 < 0 . (9) distinct local minima in the orbit space. (B −B )2 (B −B )2 (B −B )2 3 1 3 2 0 3 Symmetries and their violation. The potential can The proofis basedonthe “shrinkingellipsoid”construc- have an additional explicit symmetry, i.e. it can remain tion described above and will be given in detail in [17]. invariant under some transformations of ψ (or coeffi- Local order parameters. In this Letter we have illus- i cients) alone. If the position of the global minimum is trated the idea using the global OPs ψ . The approach i 4 canbe easilyextendedtomodels,whereOPsaredefined ent symmetry properties (in 2HDM it corresponds to a locally, ψ (x). In this case, one considers the free-energy charge-breakingvacuum). One can easilyformulate con- i functional F[ψ ] = d3x[K(ψ ) + V(ψ )] with kinetic ditions when it is the global minimum of the model, so i i i term K and potentiaRl V. In the general model the ki- thephasediagramremainsequallytractableinthiscase. netic term must include all quadratic combinations of In conclusion, we considered the most general the gradient terms: Ginzburg-Landau model with two order parameters, in- cluding all possible quadratic and quartic terms in the K =κ1|D~ψ1|2+κ2|D~ψ2|2+κ3(D~ψ1)∗(D~ψ2)+c.c., (10) Landau potential. Since the minimization of the poten- tial cannot be done explicitly, we developed a geomet- where D~ is either ∇~ or the covariant derivative. It can ric approach based on the reparametrization properties berewritteninthereparametrizationinvariantformK = of the model and used it to study the ground state of Kµρµ with ρµ ≡(D~Φ)†σµ(D~Φ) andKµ defined in terms the model. Future research should include dynamics of of κi similarly to Aµ defined in terms of ai. the fluctuations above the ground state, corrections to The presence of Kµ leads only to minor complications the potential beyond the quartic term, renormalization oftheaboveanalysis. Alltheconclusionsaboutthenum- group flow, as well as modifications of the results at fi- ber of extrema and minima remain unchanged, however nite temperature and in the presence of external fields. one should now distinguish symmetries of the potential and of the entire free energy functional, see [17] for de- tails. I thank Ilya Ginzburgfor useful comments. This work Two localOPsalso leadto the existence of quasitopo- wassupportedbyFNRS andpartlyby grantsRFBR05- logical solitons. This possibility has been known for 02-16211and NSh-5362.2006.2. some time; for example, in [19], a soliton in the one- dimensional two-band superconductor with a simple in- terband interaction term was described. Such a soliton corresponds to the relative phase between the two con- ∗ densates that changes continuously from zero to 2π as Electronic address: [email protected] [1] J.-C. Tol´edano, P. Tol´edano, “The Landau theory of x goes from −∞ to +∞, and it is stable against small phase transitions”, World Scientific, 1987. perturbations. The general origin of such quasitopologi- [2] P. Calabrese, A. Pelissetto, E. Vicari, Phys. Rev. B 67, cal solitons is obvious from the above construction. The 054505 (2003). orbit space of all non-zero configurations of OPs is the [3] A. Pelissetto, E. Vicari, Cond. Matt. Phys.(Ukraine) 8, forward lightcone without the apex, which is homotopi- 87 (2005). callyequivalenttoa2-sphereS2. Dependingontheexact [4] M. De Prato, A. Pelissetto, E. Vicari, Phys. Rev. B 74, shape of the potential, it can support either closed lin- 144507 (2006). [5] E.Demler.W.Hanke,S.-C.Zhang,Rev.Mod.Phys.76, ear paths, which correspond to domain walls, or closed 909 (2004). 2-manifolds, which corresponds to strings. [6] E.Babaev,N.W.Ashcroft,NaturePhysics3,530(2007). Multicomponent order parameters. In many physical [7] E. Di Grezia, S. Esposito, G. Salesi, arXiv:0710.3482 situations one encounters multicomponent OPs. Exam- [cond-mat]. ples include 2HDM, superfluidity in 3He, spin-density [8] A. J. Leggett, Prog. Theor. Phys. 36, 901 (1966). waves, etc. The formalism developed here works also [9] A. Gurevich, Physica C 456, 160 (2007). for these cases. Just to mention some characteris- [10] P. B. Jones, Mon. Not. Roy. Astron. Soc. 371, 1327 (2006). tic features, leaving a detailed discussion for [17], we [11] M. Iskin and C. A. R. S´a de Melo, Phys. Rev. B 74, note that SU(N)-symmetric potential depends on N- 144517 (2006). vectors only via combinations (ψi†ψj). Since in general [12] T. D. Lee, Phys. Rev. D 8, 1226 (1973); I. F. Ginzburg (ψ†ψ )(ψ†ψ ) 6= |ψ |2|ψ |2, one gets a new term in the and M. Krawczyk, Phys.Rev.D 72, 115013 (2005). 1 2 2 1 1 2 potential (2) with its own coefficient. The definition of [13] M. Abudand G. Sartori, Annals Phys.150 (1983) 307. rµ remains the same, but rµr ≥ 0, so rµ can lie not [14] I.P. Ivanov,Phys.Rev.D 75, 035001 (2007), [Erratum- µ ibid. D 76, 039902 (2007)]. onlyonthesurface,butalsointheinteriorofLC+. This [15] I. P. Ivanov,Phys.Rev.D 77, 015017 (2008). makesdefinitionofB unique,fixesits eigenvalues,and µν [16] M. Maniatis, A. von Manteuffel, O. Nachtmann and depending on their signs, one has to consider separately F. Nagel, Eur. Phys. J. C 48 805 (2006). severalcases. Modificationsto the overallresults aremi- [17] I. P. Ivanov,in preparation. nor, see [14, 15] for a 2HDM analysis. One obtains a [18] I. P. Ivanov,Phys.Lett. B 632, 360 (2006). new phase,with hrµi lying inside LC+, which has differ- [19] Y. Tanaka, Phys. Rev.Lett. 88, 017002 (2002).

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