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Geology and Geochemistry of Oil and Gas PDF

391 Pages·2005·4.62 MB·English
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52 DEVELOPMENTS IN PETROLEUM SCIENCE geology and geochemistry of oil and gas i 52 DEVELOPMENTS IN PETROLEUM SCIENCE Volumes 1-7, 9-18, 19b, 20-29, 31, 34, 35, 37-39 are out of print. 8 Fundamentals of Reservoir Engineering 19a Surface Operations in Petroleum Production, I 30 Carbonate Reservoir Characterization: A Geologic-Engineering Analysis, Part I 32 Fluid Mechanics for Petroleum Engineers 33 Petroleum Related Rock Mechanics 36 The Practice of Reservoir Engineering (Revised Edition) 40a Asphaltenes and Asphalts, I 40b Asphaltenes and Asphalts, II 41 Subsidence due to Fluid Withdrawal 42 Casing Design – Theory and Practice 43 Tracers in the Oil Field 44 Carbonate Reservoir Characterization: A Geologic-Engineering Analysis, Part II 45 Thermal Modeling of Petroleum Generation: Theory and Applications 46 Hydrocarbon Exploration and Production 47 PVT and Phase Behaviour of Petroleum Reservoir Fluids 48 Applied Geothermics for Petroleum Engineers 49 Integrated Flow Modeling 50 Origin and Prediction of Abnormal Formation Pressures 51 Soft Computing and Intelligent Data Analysis in Oil Exploration 52 Geology and Geochemistry of Oil and Gas ii 52 DEVELOPMENTS IN PETROLEUM SCIENCE geology and geochemistry of oil and gas G.V. Chilingar, L.A. Buryakovsky, N.A. Eremenko & M.V. Gorfunkel Amsterdam – Boston – Heidelberg – London – New York – Oxford Paris – San Diego – San Francisco – Singapore – Sydney – Tokyo iii ELSEVIER B.V. ELSEVIER Inc. ELSEVIER Ltd ELSEVIER Ltd Radarweg 29 525 B Street, Suite 1900 The Boulevard, Langford Lane 84 Theobalds Road P.O. Box 211, 1000 AE San Diego, CA92101-4495 Kidlington, Oxford OX5 1GB London WC1X 8RR Amsterdam, The Netherlands USA UK UK © 2005 Elsevier B.V. All rights reserved. This work is protected under copyright by Elsevier B.V., and the following terms and conditions apply to its use: Photocopying Single photocopies of single chapters may be made for personal use as allowed by national copyright laws. Permission of the Publisher and payment of a fee is required for all other photocopying, including multiple or systematic copying, copying for advertising or promotional purposes, resale, and all forms of document delivery. Special rates are available for educational institutions that wish to make photocopies for non-profit educational classroom use. Permissions may be sought directly from Elsevier's Rights Department in Oxford, UK: phone (+44) 1865 843830, fax (+44) 1865 853333, e-mail: [email protected]. Requests may also be completed on-line via the Elsevier homepage (http://www.elsevier.com/locate/permissions). In the USA, users may clear permissions and make payments through the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA01923, USA; phone: (+1) (978) 7508400, fax: (+1) (978) 7504744, and in the UK through the Copyright Licensing Agency Rapid Clearance Service (CLARCS), 90 Tottenham Court Road, London W1P 0LP, UK; phone: (+44) 20 7631 5555; fax: (+44) 20 7631 5500. Other countries may have a local reprographic rights agency for payments. Derivative Works Tables of contents may be reproduced for internal circulation, but permission of the Publisher is required for external resale or distribution of such material. Permission of the Publisher is required for all other derivative works, including compilations and translations. Electronic Storage or Usage Permission of the Publisher is required to store or use electronically any material contained in this work, including any chapter or part of a chapter. Except as outlined above, no part of this work may be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, mechanical, photocopying, recording or otherwise, without prior written permission of the Publisher. Address permissions requests to: Elsevier's Rights Department, at the fax and e-mail addresses noted above. Notice No responsibility is assumed by the Publisher for any injury and/or damage to persons or property as a matter of products liability, negligence or otherwise, or from any use or operation of any methods, products, instructions or ideas contained in the material herein. Because of rapid advances in the medical sciences, in particular, independent verification of diagnosesand drug dosages should be made. First edition 2005 ISBN-13: 978-0-444-52053-1 ISBN-10: 0 444 52053 8 ISSN: 0376-7361 (Series) The paper used in this publication meets the requirements of ANSI/NISO Z39.48-1992 (Permanence of Paper). Printed in The Netherlands. iv v DEDICATION This Book is dedicated to His Highness Sheikh Hamad Bin Khalifa Al Thani The Emir of the State of Qatar And Her Highness Sheikha Mozah Bint Nasser Al Missned For their global vision and dedication to democratic reform, education, and valiant efforts in promoting peace in the region This page intentionally left blank vi vii FOREWORD Thegeologyandgeochemistryofpetroleumarebecomingevermoreimportantas the demand for fossil fuels increases worldwide. We must find new hydrocarbon reserves that are hidden in almost inaccessible areas. Our knowledge of petroleum geology and geochemistry is the best intellectual tool that we have for the never- endingsearchforrichnewdepositsofhydrocarbons.Thegeologyoftherocksunder deep oceans and on continental shelves has become much more important as advances in technology permit drilling in these areas. Developments in petroleum geology and geochemistry, and advances in seismic and well-logging measurements, provide a better understanding of the evolution of subsurface sedimentary deposits and the migration, entrapment, and production of hydrocarbons. This book touches upon the great strides that are being made through electronic innovationsininstrumentalmeasurementsofgeologicandgeochemicalsystems.The structureofthebookisactuallyabalanceoffourtopicalsections.Thefundamental aspects of petroleum geology, geochemistry, and accumulation, evaluation, and production of subsurface fluids are discussed in the first three sections followed by the fourth section on mathematical modeling of geologic systems. Chapters 1–3 introduce a systematic approach to understanding sedimentary rocks and their role in the evolution and containment of subsurface fluids. This is discussedinrelationtothephysicalconditionsofhydrocarbonreserves(e.g.,atvery high temperatures and pressures). Chapters 4–6 discuss the physical and chemical properties of subsurface waters, crude oils and natural gases. The physical and chemical properties are especially important to production engineering and mathematical simulation because they impact the relative motions of fluids as saturation changes during production: (1) wettability of rocks affects production characteristics and ultimate recovery; (2) relative permeability affects fluid movement to the production wells; (3) density differences between immiscible fluids affect gravity drainage from one part of the reservoirtoanother asthereservoirfluidsaredepleted;(4)viscosityoffluidsaffects the relative mobility of each fluid; and (5) fluid chemistry affects the absorption, ultimate recovery and monetary value of the produced hydrocarbons. Chapters 7–10 discuss the formation and accumulation of crude oils and natural gases: (1) changes in the chemical composition of hydrocarbons that originate from the debris of living plants to form crude oils; (2) the origins of hydrocarbons in different areas of a single reservoir; also, the conditions which determine the distributionofwater,oil,andgasinthereservoir;(3)migrationofsubsurfacefluids untiltheyeventuallyaccumulateinisolatedgeologictraps;and(4)adiscussionofthe oil traps as a function of sedimentary geology. viii FOREWORD Chapter 11 explains the analytical and statistical approaches to modern mathematical modeling of both static and dynamic geologic systems. Modeling of staticsystems(i.e.,simulationofthestructureandcompositionofgeologicsystems)is doneregardlessoftimetodevelopabasisforgeologicexplorationandhydrocarbon reserve estimation, whereas dynamic models capture any changes taking place with respect to time for use in studying production and field development. This book is recommended to the geologists, geochemists, petroleum engineers, and graduate university students studying petroleum geology, engineering, and geochemistry. E.C. Donaldson Managing Editor of Journal of Petroleum Science and Engineering Wynnewood, Oklahoma ix PREFACE The progress in the oil and gas industry is related closely to the acceleration of discovery rates, exploration, development, and production of hydrocarbon resourc- es. Exploration, development, and production of hydrocarbon resources must be based on reliable information, which helps to predict subsurface conditions and properties of oil- and gas-bearing formations. Main oil and gas reserves are found in sedimentary basins composed of ter- rigenous (siliciclastic), carbonate, and, sometimes, volcanic or volcaniclastic rocks. Preservation of high reservoir pressure and good properties of reservoir rocks and seals(caprocks)inthesebasinsdependsgreatlyontheiroriginandfurtherevolution. The process of sedimentation, and the following processes of diagenesis (i.e., phys- ical, chemical and biochemical processes, which occur in the sediments after sed- imentation and through lithification at near-surface temperature and pressure) and catagenesis (or epigenesis) (i.e., physical and chemical processes, which occur in the sedimentary rocks at high temperatures and pressures after lithification and up to metamorphism), cause alterations, which may enable one to predict oil and gas potential. Considering an interest demonstrated by petroleum geologists and reservoir en- gineers, this book discusses the major theoretical and practical problems of petro- leumgeologyandgeochemistryastheyareviewedattheendofthe20thcenturyand the beginning of the 21st century. The treatment of the material is non-uniform in the sense that the accepted scientific concepts are treated cursorily, just to maintain thecompletenessandcontinuityofthestory,whereasthedisputableandinnovative issues are handled in more detail. The discussion is conducted from a position of the science of petroleum geology, geochemistry, and other related disciplines. For instance, in describing oil-bearing sequences, the main brunt is on depositional environments and such features as reservoir and fluid-sealing properties. A considerable attention is devoted to the transformations within the rock– water–organic matter system of the Earth’s crust with changes in the subsurface temperature and pressure. New reservoir and accumulation types are identified and their exploration/development features are defined. A variety of common reservoir engineering problems can be solved during field development and production by the integration of geological, geochemical, and en- gineering studies. For example, such studies can identify reservoir compartment- alization, allocate commingled production, identify completion problems (such as tubing leaks or poor casing cementing jobs), predict fluid properties (viscosity, den- sity) prior to production tests, characterize induced fracture geometry, monitor the waterfloodprocessandwaterencroachment,orexplainthecausesofproducedsludge.

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This book discusses the progress that is being made through innovations in instrumental measurements of geologic and geochemical systems and their study using modern mathematical modeling. It covers the systems approach to understanding sedimentary rocks and their role in evolution and containment o
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