Table Of ContentGels, Genes, Grafts and Giants
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GELS, GENES, GRAFTS AND GIANTS
Festschrift on the occasion of the 70th birthday of Allan S. Hoffman
Edited by
STUART L. COOPER, THOMAS A. HORBETT,
BUDDY D. RATNER and PATRICK S. STAYTON
VSP
Leiden • Boston
2005
CRC Press
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Contents
Foreword
T. Horbett, B. Ratner and P. Stayton 1
Preface
Allan Hoffman: A 70th Birthday Celebration
B. D. Ratner 3
Some personal reflections on the career of Allan Hoffman in honor of his
70th birthday
T. Horbett, B. Ratner and P. Stayton 1
Drug delivery
Cellular evaluation of insulin transmucosal delivery
7. E. Lopez and N. A. Peppas 15
Hydrogel probe for iontophoresis drug delivery to the eye
E. Eljarrat-Binstock, E Raiskup, 7. Frucht-Pery and A, 7. Domb 27
Aqueous N,N-diethylnicotinamide (DENA) solution as a medium
for accelerated release study of paclitaxel
N. Baek, J. Lee and K. Park 45
Novel carboxymethylcellulose-based microporous hydrogels suitable for drug
delivery
R. Barbucci, G. Leone and A. Vecchiullo 61
IgG responses to intranasal immunization with cholera-toxin-immobilized
polymeric nanospheres in mice
T. Kaneko, S. Shimomai, M. Miyazaki, M. Baba and M. Akashi 75
Water-soluble polymers with low critical solution temperature (LCST)
as carriers for protein drug delivery
N. A. Plate, I. L. Valuev and L. I. Valuev 85
Polymeric drugs with prolonged sustained delivery of specific anti-aggregant
agents for platelets: kinetic analysis of the release mechanism
A. Gallardo, G. Rodriguez, M. Fernandez, M. R. Aguilar and J. S, Roman 93
Promotion of U937 cell adhesion on polypropylene surfaces bearing
phosphorylcholine functionalities
Y.-K. Gong, F Mwale, M. R. Wertheimer and F M. Winnik 105
Controlled release of plasmid DNA from biodegradable scaffolds fabricated
using a thermally-induced phase-separation method
K. W. Chun, K. C Cho, S. K Kim, J, H. Jeong and T. G. Park 117
VI Contents
PEGylated dextran as long-circulating pharmaceutical carrier
A. N. Lukyanov, R. M. Sawant, W. C. Hartner and V. P. Torchilin 131
Enhanced ileal absorption of a hydrophilic macromolecule, pentosan polysulfate
sodium (PPS)
L. Dong, A. Yum, J. Nguyen and P Wong 141
Gene delivery: intelligent but just at the beginning (Review)
E. Pi§kin, S. Dinger and M. Turk 153
Anti-inflammatory drug delivery from hyaluronic acid hydrogels
S. K. Hahn, S. Jelacic, R. V. Maier, P. S. Stay ton and A. S. Hoffman 175
Design and characterisation of new nanoparticulate polymer blends for drug
delivery
N. Csaba, L. Gonzalez, A. Sanchez andM. J. Alonso 185
Semi-interpenetrating network of poly(ethylene glycol) and poly(D,L-lactide)
for the controlled delivery of protein drugs
C. D. Brown, P S. Stay ton and A. S. Hoffman 201
Preparation of cationic comb-type copolymer having guanidino moieties and its
interaction with DNAs
S. W Choi, Y Sato, T. Akaike and A. Maruyama 215
Effect of a dextran derivative associated with TGF-$ 1 or FGF-2 on dermal
fibroblast behaviour in dermal equivalents
L. Frank, C. Lebreton-Decoster, G. Godeau, B. Coulomb and /. Jozefonvicz 227
Novel biodegradable cholesterol-modified polyrotaxane hydrogels for cartilage
regeneration
W. Tachaboonyakiat, T. Furubayashi, M. Katoh, T. Ooya and N. Yui 245
Biodegradable poly(terephthalate-co-phosphate)s: synthesis, characterization
and drug-release properties
H.-Q. Mao, I. Shipanova-Kadiyala, Z Zhao, W. Dang, A. Brown
andK.WLeong 261
Synthesis and characterization of stimuli-sensitive hydrogels having a different
length of ethylene glycol chains carrying phosphate groups: loading and release
of lysozyme
K. Nakamae, T. Nishino, K. Kato, T. Miyata and A. S. Hoffman 289
Poly(propylacrylic acid)-mediated serum stabilization of cationic lipoplexes
C. K Cheung, P. S. Stayton and A. S. Hoffman 301
Surfaces, modification and characterization
Platelet adhesion to radiofrequency glow-discharge-deposited fluorocarbon
polymers preadsorbed with selectively depleted plasmas show the primary role
of fibrinogen
W.-B. Tsai, Q. Shi, J. M. Grunkemeier, C. Mc Far land and T. A. Horbett 321
Contents vn
pH-dependent elution profiles of selected proteins in HPLC having a stationary
phase modified with pH-sensitive sulfonamide polymers
S. /. Kang and Y H Bae 345
Molecular composition and mechanical properties of biopolymer interfaces
studied by sum frequency generation vibrational spectroscopy and atomic force
microscopy (Review)
T. S. KoffaSy E. Amitay-Sadovsky, J. Kim and G. A. Somorjai 361
Surface characteristics of block-type copolymer composed of semi-fluorinated
and phospholipid segments synthesized by living radical polymerization
Y Inoue, J. Watanabe, M. Takai and K. Ishihara 397
Grafting copolymerization of 2-methacryloyloxyethyl phosphorylcholine
(MPC) onto pre-irradiated cellulose films
J. Chen, Y C Nho and A. S. Hoffman 411
Cells on surfaces
Cell-adhesive and blood-coagulant properties of ultrathin poly(methyl
methacrylate) stereocomplex films
T. Serizawa, K. Yamashita and M. Akashi 423
Macrophage behavior on surface-modified polyurethanes
J. A. Jones, M. Dadsetan, T. O. Collier, M. Ebert, K. S. Stokes, R. S. Ward,
R A. Hiltner and J. M. Anderson 439
Oral administration of biochemically active microcapsules to treat uremia:
new insights into an old approach
/. A. O'Loughlin, J. M. Bruder and M. J. Lysaght 457
Formulation of chitosan-DNA nanoparticles with poly(propyl acrylic acid)
enhances gene expression
T. Kiang, C. Bright, C Y Cheung, R S. Stayton, A. S. Hoffman and K. W, Leong 473
Monocyte activation on polyelectrolyte multilayers
7. J. Hwang, S. Jelacic, N. T. Samuel, R. V Maier, C. T. Campbell,
D. G. Castner, A. S. Hoffman and R S. Stayton 491
Smart polymers, surfaces and hydrogels
The effect of pH on the LCST of poly(N-isopropylacrylamide)
and poly(N-isopropylacrylamide-co-acrylic acid)
Y Pei, J. Chen, L. Yang, L. Shi, Q. Tao, B. Hui and J. Li 509
A hydrogel system for stimulus-responsive, oxygen-sensitive in situ gelation
A. Goessl, N. Tirelli and J. A. Hubbell 519
Preparation of reversibly glucose-responsive hydrogels by covalent
immobilization of lectin in polymer networks having pendant glucose
T. Miyata, A. Jikihara, K. Nakamae and A. 5. Hoffman 529
Vlll Contents
Poly(N-isopropylacrylamide)-based semi-interpenetrating polymer networks
for tissue engineering applications. Effects of lineai' poly(acrylic acid) chains
on rheology
R. A. Stile, E. Chung, W. R. Burghardt and K. E. Healy 543
Poly(/V-isopropylacrylamide)-grafted gelatin as a thermoresponsive
cell-adhesive, mold-releasable material for shape-engineered tissues
T. Matsuda 551
Characteristics of chemically cross-linked myosin gels
A. Kakugo, S. Sugimoto, K. Shikinaka, J. P. Gong and Y Osada 567
Tissue responses to thermally-responsive hydrogel nanoparticles
H. Weng, J. Zhou, L. Tang and Z. Hu 583
Plasma protein adsorption to surfaces grafted with dense homopolymer
and copolymer brushes containing poly(N-isopropylacrylamide)
J. Janzen, Y Le, J. N. Kizhakkedathu and D. E. Brooks 597
Hydrogels
Preparation and characterization of pH-sensitive hydrogel
of chitosan/poly(acrylic acid) co-polymer
L. Shi, L. Yang, J. Chen, Y. Pei, M. Chen, B. Hui and J. Li 615
Fibroin hydrogels for biomedical applications: preparation, characterization
and in vitro cell culture studies
A. Motta, C. Migliaresi, F. Faccioni, P. Torricelli, M. Fini and R. Giardino 625
Synthesis of 3,4-dihydroxyphenylalanine (DOPA) containing monomers
and their co-polymerization with PEG-diacrylate to form hydrogels
B. P Lee, K. Huang, F N. Nunalee, K. R. Shall and P B. Messersmith 639
Hydrogen-bonding-driven spontaneous gelation of water-soluble phospholipid
polymers in aqueous medium
M. Kimura, K. Fukumoto, J. Watanabe and K. Ishihara 655
Tethered protein/peptide-surface-modified hydrogels
J. Bi, J. C. Downs and J. T Jacob 669
Enhancement of stability of glucose oxidase by immobilization onto metal
ion-chelated poly(N-vinyl imidazole) hydrogels
N. Pekel B. Salih and 0. Giiven 681
y
Immobilization of biomolecules
Design of highly specific ligands of fibrin for therapeutic applications
A. M. Bianucci, L Massarelli, F. Chiellini, C. Eidelman and E. Chiellini 697
Synthesis of segmented poly(ether urethane)s and poly(ether urethane urea)s
incorporating various side-chain or backbone functionalities
F. I. Simonovsky, S. C. Porter and B. D. Ratner 117
Contents IX
Immobilization of streptavidin-horseradish peroxidase onto a biotinylated
poly (aery lie acid) backbone that had been radiation-grafted to a PTFE film
P Sadurni, A. Alagon, R. Aliev, G. Burillo and A. S. Hoffman 735
The relevance of the transfer of molecular information between natural
and synthetic materials in the realisation of biomedical devices
with enhanced properties (Review)
G. Ciardelli, D. Silvestri, C. Cristallini, N. Barbani and P. Giusti 743
Tissue engineering scaffolds, entrapped cells, degradable polymers
Capillary zone electrophoresis as a tool to monitor the last stages
of the degradation of water-sensitive polymers
C. Braud 763
Electrically conductive 2D-PAN-containing surfaces as a culturing substrate
for neurons
R. Oren, R. Sfez, N. Korbakov, K Shabtai, A. Cohen, H. Erez, A. Dormann,
H. Cohen, J. Shappir, M. E. Spira and S. Yitzchaik 789
Controlled synthesis of biodegradable lactide polymers and copolymers using
novel in situ generated or single-site stereoselective polymerization initiators
Z. Zhong, R J. Dijkstra and J. Feijen 809
Manufacture of elastic biodegradable PLCL scaffolds for mechano-active
vascular tissue engineering
S. I. Jeong, S. H. Kim, Y. H Kim, Y Jung, J H. Kwon, B.-S. Kim and Y M. Lee 827
Bioactive glasses for in situ tissue regeneration (Review)
L. L. Bench, I. D. Xynos and J. M. Polak 843
Xyloglucan as a synthetic extracellular matrix for hepatocyte attachment
S.-J. Seo I.-K. Park, M.-K. Yoo, M. Shirakawa, T. Akaike and C.-S. Cho 863
f
Development of perforated microthin poly(£-caprolactone) films as matrices
for membrane tissue engineering
A. S. Htay, S. H. Teoh and D. W. Hutmacher 877
Amido-modified poly lactide for potential tissue engineering applications
N. K. Abayasinghe, K. P. U. Perera, C Thomas, A. Daly, S. Suresh, K. Burg,
G. M. Harrison and D. W. Smith, Jr. 895
Hyaluronic-acid-based semi-interpenetrating materials
X. Xin, A. Borzacchiello, P. A. Netti, L. Ambrosio and L. Nicolais 907
