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Gas usage & value : the technology and economics of natural gas use in the process industries PDF

346 Pages·2006·15.815 MB·English
by  SeddonDuncan
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BookSed.indb 1 1/24/06 11:23:56 AM BookSed.indb 2 1/24/06 11:23:56 AM THE TECHNOLOGY AND ECONOMICS OF NATURAL GAS USE IN THE PROCESS INDUSTRIES DR. DUNCAN SEDDON BookSed.indb 3 1/24/06 11:23:58 AM DISCLAIMER The recommendations, advice, descriptions, and the methods in this book are presented solely for educational purposes. The author and publisher assume no liability whatsoever for any loss or damage that results from the use of any of the material in this book. Use of the material in this book is solely at the risk of the user. Copyright © 2006 by PennWell Corporation 1421 South Sheridan Road Tulsa, Oklahoma 74112-6600 USA 800.752.9764 +1.918.831.9421 [email protected] www.pennwellbooks.com www.pennwell.com Director: Mary McGee Managing Editor: Marla Patterson Production / Operations Manager: Traci Huntsman Production Manager: Robin Remaley Assistant Editor: Amethyst Hensley Book Designer: Robin Remaley Cover Designer: Charles Thomas Library of Congress Cataloging-in-Publication Data Available on Request Seddon, Duncan Gas Usage & Value: The Technology and Economics of Natural Gas Use in the Process Industries ISBN 1-59370-073-3 All rights reserved. No part of this book may be reproduced, stored in a retrieval system, or transcribed in any form or by any means, electronic or mechanical, including photocopying and recording, without the prior written permission of the publisher. Printed in the United States of America 1 2 3 4 5 10 09 08 07 06 BookSed.indb 4 1/24/06 11:23:58 AM To Judith BookSed.indb 5 1/24/06 11:23:58 AM BookSed.indb 6 1/24/06 11:23:58 AM Contents Preface ...........................................................................................xii 1 Introduction .............................................................................1 Burning and Feedstock: Why Convert Gas? .....................................3 Units ................................................................................................4 Approximate Conversion Factors ......................................................6 Economic Analysis ...........................................................................6 Approximations to the Economic Analysis ....................................8 Data Sources ....................................................................................9 References ......................................................................................10 2 Gas Availability .......................................................................11 World Supply and Demand for Gas ................................................11 Overview of Large Gas Reserves ....................................................14 Eastern Europe: Western and Central Russia .............................14 Middle East ................................................................................15 Africa ..........................................................................................16 North and South America ...........................................................17 Asia Pacific .................................................................................19 Western Europe ..........................................................................22 Alternative Sources of Gas .............................................................23 Gas from in situ coal: coalbed methane (CBM) .........................23 Natural gas hydrates ...................................................................27 Tight gas .....................................................................................26 Synthetic natural gas ...................................................................26 References ......................................................................................28 vii BookSed.indb 7 1/24/06 11:23:58 AM Gas Usage & Value 3 Gas Composition ...................................................................31 Variation in Gas Composition: Nonhydrocarbons ...........................32 Water ..........................................................................................32 Nitrogen ......................................................................................33 Helium ........................................................................................34 Oxygen ........................................................................................34 Mercury ......................................................................................35 Sulfur ..........................................................................................35 Carbon dioxide ............................................................................38 Variation in Hydrocarbon Content .................................................40 General Approaches to Gas Treatment ...........................................43 Low-sulfur, low-carbon dioxide gas .............................................43 High-sulfur, high-carbon dioxide gas ...........................................44 Gas Treatment to Remove LPG and Ethane ..................................45 LPG removal by turbo expansion ................................................45 Refrigerated absorption plants ....................................................48 Gas treatment for LNG manufacture .........................................50 Offshore gas processing ..............................................................51 Gas Specifications ..........................................................................52 Gas Production Costs: Order of Magnitude Estimates ..................55 Gas recovery costs at the wellhead .............................................55 Case study: economics of large gas plants ...................................58 Greenhouse Emissions ...................................................................61 Carbon geosequestration ............................................................63 Capture costs of carbon dioxide ..................................................65 Sequestration costs .....................................................................66 Methane emissions .....................................................................67 References ......................................................................................68 4 Comparison of Energy Fuels .................................................73 Natural Gas Use: Project Scale of Operation .................................73 Properties of alternative fuels: coal and petroleum products .......................................................74 Heating Values (HHV and LHV) ....................................................76 Ratio of heating values ................................................................76 Determining liquid fuel heating values .......................................77 Nonconventional Energy Sources ...................................................78 Relative Environmental Impact ......................................................78 Carbon dioxide content of some natural gases ............................79 Comparative environmental effects ............................................79 viii BookSed.indb 8 1/24/06 11:23:58 AM

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